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1.
Coronite-bearing anorthositic granulites consisting of olivine, orthopyroxene, clinopyroxene, garnet and plagioclase assemblages are particularly well preserved at Gaupås and Holsnöy in the Bergen Arc of West Norway. The coronites are considered to have formed near T= 900° C and P=10 Kb by two stages of subsolidus reaction from an anorthositic gabbro parent. The first reaction involved ol+plagcpxI+opxI+sp and the second cpxI+opxI+sp+plcpxII+opxII+gn. The incomplete reaction products are preserved to varying extents in different corona structures. Sm-Nd isotopic data for each of four coronas yield precise isochrons, and demonstrate isochronism both between the constituent phases of the corona assemblages and dispersed ground mass phases. Three individual coronas not associated with shear zones yield ages of 907±9 my, 912±18 my and 905±37 my. Eclogite facies mineralogy is developed locally in shear zones, which are shown by Sm-Nd and Rb-Sr analyses to be Caledonian in age. Where relict corona structures survive unsheared within these zones, Nd exchange between the constituent phases cannot be resolved. This observation together with sympathetic Ca/Mg and Sm/Nd zoning preserved at T900° C in the garnet mantles of coronites places a limit on the diffusivity of Nd in pyropic garnets which is no higher than published experimental values for Mg in pyrope-almandine garnets. Consequently even in slowly-cooled granulite terrains, garnet grains are expected to yield Sm-Nd chronologies very close to the time of mineral growth.  相似文献   

2.
A very uncommon garnet-zoning—Ca poor centre and Ca rich margin—has been observed, in a granulite facies rock. Calculation of equilibrium at each stage of the garnet growth led to apply in this particular case, as well as for the most garnet-zoning instances, the Rayleigh fractionation model, the fractionation factor Ca being less than 1 at the beginning of the crystallization. Subsequent coronitisation, at lower P and/or higher T, involved the development of orthopyroxene and plagioclase in equilibrium with a thin (15 thick) Ca-Mg poor and Fe rich outer cuticle of the garnet: thus the garnet lattice appears to be not so refractory as previously admitted, and in most coronitisation processes involving garnet such an outer cuticle must be considered as a component of the new mineral assemblage.  相似文献   

3.
Feldspathic hornblende granulites from Doubtful Sound, New Zealand with the assemblage plagioclase+hornblende+clinopyroxene+orthopy-roxene +oxide+apatite are criss-crossed by a network of garnetiferous anorthosite veins and pegmatites. The feldspathic gneiss in contact with anorthosite has a reaction zone containing the assemblage plagioclase +garnet+clinopyroxene+quartz+rutile+apatite. The garnet forms distinctive coronas around clinopyroxene. The origin of these rocks is discussed in the light of mineral and whole rock chemical analyses and published experimental work.It is thought that under conditions leading up to 750 °C, 8 kb load pressure and 5 kb H2O pressure, partial melting occured in feldspathic hornblende granulites. The melt migrated into extensional fractures and eventually crystallised as anorthosite pegmatites and veins. The gneisses adjacent to the pegmatites from which the melt was extracted changed composition slightly, by the loss of H2O and Na2O, so that plagioclase reacted simultaneously with hornblende, orthopyroxene, and oxide to form garnet, clinopyroxene, quartz and rutile.  相似文献   

4.
Summary Eclogitic rocks are hosted within gneisses and migmatites of the Hercynian basement of NE Sardinia. They are characterized by two compositional layers: garnet-pyroxene rich-layers and amphibole-plagioclase layers. The former contain structural, mineralogical and compositional relics of eclogite facies re-equilibration. Four stages of evolution have been identified: an eclogite stage, a granulite stage and a retrograde amphibolite to greenschist stage. A possible pre(?)-eclogite stage is documented by inclusions of euhedral tschermakitic amphibole + zoisite within the core of garnet. This early stage was followed by an increase in pressure under which the eclogite climax developed (T up to 700 °C, P =13-15 kbar), as documented by omphacite inclusions towards the rim of garnet.Characteristic mineral reactions after the eclogitic stage are: omphacite diopside + plagioclase (symplectite) and garnet orthopyroxene + plagioclase. These reactions testify the presence of a granulite stage during which the peak of metamorphism was reached (T up to 870'C, P 10 kbar). The orthopyroxene cummingtonite + quartz and garnet + diopside hornblende + plagioclase (kelyphite) transformations indicate extensive amphibolite retrogression (T = 550650 °C, P = 3-7 kbar). Finally, actinolite and chlorite developed (greenschist stage) at falling temperature and pressure (T = 300-400 °C, P < 2-3 kbar).
Mehrstufige metamorphe Reequilibration eklogitischer Gesteine aus dem hercynischen Basement NE Sardiniens (Italien)
Zusammenfassung Eklogitische Gesteine kommen in Gneisen und Migmatiten des hereynischen Basements in NE Sardinien vor. Sie sind durch einen modalen Zweitagenbau von einerseits Granat-Pyroxen andererseits Amphibol-Plagioklas charakterisiert. In ersteren sind Relikte einer strukturellen, mineralogischen und mineralchemischen Reequilibration unter eklogitfaziellen Bedingungen enthalten. Vier Entwicklungstadien sind unterscheidbar: ein Eklogit-, ein Granulit-, sowie ein retrogrades Amphibolit- und Grünschieferstadium. Ein mögliches prä(?)-eklogitisches Stadium ist durch die Einschlüsse von tschermakitischem Amphibol + Zoisit in Granatkernen angedeutet. Auf dieses Frühstadium folgte, dokumentiert durch Omphaziteinschlüsse im Granatrandbereich, Druckzunahme und es wurden eklogitfazielle Bedingungen (T bis zu 700 °C, P = 13-15 kbar) erreicht.Charakteristische Mineralreaktionen nach der Eklogitbildung sind Omphazit Diopsid + Plagioklas (Symplektite) und Granat Orthoyroxen + Plagioklas. Diese Reaktionen belegen das Vorliegen eines Granulitstadiums, während dem der Metamorphosehöhepunkt (T bis 870°C, P 10 kbar) erreicht wurde. Die Umwandlungen von Orthopyroxen Cummingtonit + Quarz und Granat + Diopsid Hornblende + Plagioklas (Kelyphit) belegen eine intensive retrograde amphibolitfazielle Überprägung (T = 550-650°C, P = 3-7 kbar). Aktinolith und Chlorit (Grünschieferstadium) bildeten sich bei weiter fallenden Temperaturen und Drucken (T = 300-400 °C, P < 2-3 kbar).
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5.
Ferric iron contents of coexisting ortho- and clinopyroxene from spinel lherzolite xenoliths were measured with Mössbauer spectroscopy and found to be significant. In orthopyroxene, the range in Fe3+/Fe is from 0.04 to 0.14; in clinopyroxene, the range is from 0.12 to 0.24. Reactions involving coexisting olivine, orthopyroxene, and clinopyroxene, where either the esseneite (CaFe3+ AlSiO6) or the acmite (NaFe3+Si2O6) component in the clinopyroxene is considered, are used to calculate oxygen fugacities. These oxygen fugacities agree well with those calculated with the olivine-orthopyroxene-spinel oxybarometer. Because these reactions do not involve garnet, spinel, or plagioclase, they may be applied to lherzolites to give internally-consistent oxygen fugacities across the pressure-dependent facies boundaries between plagioclase, spinel, and garnet lherzolite. Another application of this method is to predict the Fe3+/Fe in clinopyroxene coexisting with olivine and orthopyroxene given pressure, temperature, , and the compositions of the coexisting phases in either experimental or natural assemblages. At values of equal to those of the synthetic fayalite-magnetite-quartz buffer, for example, 15–35% of the iron in the clinopyroxenes from these xenoliths would be ferric. The simplifying assumption that all Fe is divalent in silicate phases at geologically — reasonable oxygen fugacities must be re-evaluated.  相似文献   

6.
Mafic and ultramafic gneisses (blastomylonites) characterised by a strongly developed planar lenticular foliation-layering are developed in lower crustal (high pressure) cumulates of the stratiform Kalka Intrusion in central Australia. The gneisses occur in two distinct zones, the Numbunja and West Kalka Gneissic Belts, parallel to or at low angles to igneous layering. They developed during and shortly after the final stages of crystallization of the intrusion at temperatures between about 1000 and 1200 ° C, and represent an incipient thrusting deformation probably with associated high strain rates. The most deformed textures in the centre of the belts typically consist of megacrysts of orthopyroxene, clinopyroxene, olivine and plagioclase showing abundant features of extreme ductile flow within a finegrained syntectonically recrystallized matrix of the same material. Mineral elongation, kink band orientation and matrix petrofabrics indicate that the maximum principal elongation and the maximum principal shortening occurred parallel to the lineation and normal to the foliation respectively.Single crystal deformation features (some unique to these rocks) include flow elongation of orthopyroxene and plagioclase (up to at least 400% elongation without recrystallization), kinking of orthopyroxene, clinopyroxene, olivine and plagioclase, production of rare clinoenstatite in orthopyroxene, and an unusual fingerprint texture in clinopyroxene. The occurrence of either flow elongation or kinking of orthopyroxene is dependent on crystal orientation relative to the maximum principal elongation/shortening directions. Detailed analysis shows that the flow orthopyroxenes and possibly the flow plagioclases deformed by simple shear. The results have relevance in studies of possible deformation mechanisms in the upper mantle, and in alpine peridotites.  相似文献   

7.
Some of the garnets in eclogites within the quartzo-feldspathic gneisses of Nordfjord, West Norway, are zoned with higher calcium, iron and manganese in the cores and more magnesium at the rims. The zoning is discussed in terms of the apparent distribution coefficients of Fe2+/Mg between garnet and clinopyroxene (which will be aberrantly high for the garnet cores) and in terms of the metamorphic evolution of the eclogites.Publication nr. 32 in The Norwegian geotraverse project.  相似文献   

8.
We have simulated the dehydration-melting of a natural, low-K, calcic amphibolite (67.4% hornblende, 32.5% anorthite) in piston-cylinder experiments at 10 kbar and 750–1000°C, for 1–9 days. The solidus temperature is lower than 750°C; garnet appears at 850°C. The overall reaction is: Hb+PL+Cpx+Al-Hb+Ca-Hb+Ga+Opx. Three stages of reaction are: (1) melting dominated by the growth of clinopyroxene and garnet, with little change in composition of liquid or garnet, (2) a reversal of this reaction between 875°C and 900°C, with decreases in the amounts of liquid and garnet, and (3) a large increase in liquid along with the loss of hornblende and decrease of plagioclase while clinopyroxene and garnet increase. Garnet is enriched in pyrope and zoned from Fe-cores to Mg-edges (range 3 mol % pyrope); liquid composition is enriched first in An (to 950°C) and then in Ab. The liquids are more calcic and aluminous than natural tonalites, which is attributed to the plagioclase composition (An90). The formation of peraluminous liquid from the metaluminous amphibolite is caused by anorthite — not H2O-saturated conditions. The results are consistent with an amphibolite phase diagram with relatively high solidus temperatures in the garnet-absent field (900–1000°C), but with a solidus backbend at 7–9 kbar, coincident with the garnet-in boundary. Hornblende breakdown due to garnet formation in a closed system must make H2O available for H2O-undersaturated melting right down to the H2O-saturated solidus, below 700°C, which defines a large low-temperature PT area where hydrous granitoid melts can be generated with residual garnet and hornblende.  相似文献   

9.
Six crystalline mixtures, picrite, olivine-rich tholeiite, nepheline basanite, alkali picrite, olivine-rich basanite, and olivine-rich alkali basalt were recrystallized at pressures to 40 kb, and the phase equilibria and sequences of phases in natural basaltic and peridotitic rocks were investigated.The picrite was recrystallized along the solidus to the assemblages (1) olivine+orthopyroxene+ clinopyroxene +plagioclase+spinel below 13 kb, (2) olivine+orthopyroxene+clinopyroxene+spinel between 13 kb and 18 kb, (3) olivine+orthopyroxene+clinopyroxene+ garnet+spinel between 18 kb and 26 kb, and (4) olivine+clinopyroxene+garnet above 26 kb. The solidus temperature at 1 atm is slightly below 1,100° and rises to 1,320° at 20 kb and 1,570° at 40 kb. Olivine is the primary phase crystallizing from the melt at all pressures to 40 kb.The olivine-rich tholeiite was recrystallized along the solidus into the assemblages (1) olivine+ clinopyroxene+plagioclase+spinel below 13 kb, (2) clinopyroxene+orthopyroxene+ spinel between 13 kb and 18 kb, (3) clinopyroxene+garnet+spinel above 18 kb. The solidus temperature is slightly below 1,100° at 1 atm, 1,370° at 20 kb, and 1,590° at 40 kb. The primary phase is olivine below 20 kb but is orthopyroxene at 40 kb.In the nepheline basanite, olivine is the primary phase below 14 kb, but clinopyroxene is the first phase to appear above 14 kb. In the alkali-picrite the primary phase is olivine to 40 kb. In the olivine-rich basanite, olivine is the primary phase below 35 kb and garnet is the primary phase above 35 kb. In the olivine-rich alkali basalt the primary phase is olivine below 20 kb and is garnet at 40 kb.Mineral assemblages in a granite-basalt-peridotite join are summarized according to reported experimental data on natural rocks. The solidus of mafic rock is approximately given by T=12.5 P Kb+1,050°. With increasing pressure along the solidus, olivine disappears by reaction with plagioclase at 9 kb in mafic rocks and plagioclase disappears by reaction with olivine at 13 kb in ultramafic rocks. Plagioclase disappears at around 22 kb in mafic rocks, but it persists to higher pressure in acidic rocks. Garnet appears at somewhat above 18 kb in acidic rocks, at 17 kb in mafic rocks, and at 22 kb in ultramafic rocks.The subsolidus equilibrium curves of the reactions are extrapolated according to equilibrium curves of related reactions in simple systems. The pyroxene-hornfels and sanidinite facies is the lowest pressure mineral facies. The pyroxene-granulite facies is an intermediate low pressure mineral facies in which olivine and plagioclase are incompatible and garnet is absent in mafic rocks. The low pressure boundary is at 7.5 kb at 750° C and at 9.5 kb at 1,150° C. The high pressure boundary is 8.0 kb at 750° C and 15.0 kb at 1,150° C. The garnet-granulite facies is an intermediate high pressure facies and is characterized by coexisting garnet and plagioclase in mafic rocks. The upper boundary is at 10.3 kb at 750° C and 18.0 kb at 1,150° C. The eclogite facies is the highest pressure mineral facies, in which jadeite-rich clinopyroxene is stable.Compositions of minerals in natural rocks of the granulite facies and the eclogite facies are considered. Clinopyroxenes in the granulite-facies rocks have smaller jadeite-Tschermak's molecule ratios and higher amounts of Tschermak's molecule than clinopyroxenes in the eclogite-facies rocks. The distribution coefficients of Mg between orthopyroxene and clinopyroxene are normally in the range of 0.5–0.6 in metamorphic rocks in the granulite facies. The distribution coefficients of Mg between garnet and clinopyroxene suggest increasing crystallization temperature of the rocks in the following order: eclogite in glaucophane schist, eclogite and granulite in gneissic terrain, garnet peridotite, and peridotite nodules in kimberlite.Temperatures near the bottom of the crust in orogenic zones characterized by kyanitesillimanite metamorpbism are estimated from the mineral assemblages of metamorphic rocks in Precambrian shields to be about 700° C at 7 kb and 800° C at 9 kb, although heat-flow data suggest that the bottom of Precambrian shield areas is about 400° C and the eclogite facies is stable.The composition of liquid which is in equilibrium with peridotite is estimated to be close to tholeiite basalt at the surface pressure and to be picrite at around 30 kb. The liquid composition becomes poorer in normative olivine with decreasing pressure and temperature.During crystallization at high pressure, olivine and orthopyroxene react with liquid to form clinopyroxene, and a discontinuous reaction series, olivine orthopyroxene clinopyroxene is suggested. By fractional crystallization of pyroxenes the liquid will become poorer in SiO2. Therefore, if liquid formed by partial melting of peridotite in the mantle slowly rises maintaining equilibrium with the surrounding peridotite, the liquid will become poorer in MgO by crystallization of olivine, and tholeiite basalt magma will arrive at the surface. On the other hand, if the liquid undergoes fractional crystallization in the mantle, the liquid may change in composition to alkali-basalt magma and alkali-basalt volcanism may be seen at a late stage of volcanic activity.Publication No. 681, Institute of Geophysics and Planetary Physics, University of California, Los Angeles.  相似文献   

10.
Boninite series volcanic rocks have been recovered from three dredge hauls on the inner slope of the Mariana Trench. These hauls included olivine boninites, boninites, boninitic andesites and boninitic dacites, as well as island arc tholeiitic basalts and andesites. The boninite series volcanics range from 52 to 68% SiO2, and are characterized by very low abundances of high-field-strength cations and heavy-rare-earth elements. Boninites and olivine boninites have phenocrysts of olivine and orthopyroxene, the andesites phenocrysts of orthopyroxene and clinopyroxene, and the dacites orthopyroxene, clinopyroxene, and plagioclase. Most of the major and trace element variation in the series from boninite to boninitic dacite can be modelled by fractionation of olivine, orthopyroxene, clinopyroxene, and plagioclase in the proportions 2.5412, leaving 47% residual liquid. The fractionation must be in part open-system: reverse zoned phenocrysts, resorbed olivine and plagioclase xenocrysts, and bulk rock compositions which cannot be fit by simple closed system crystallization indicate some magma mixing and phenocryst accumulation. Two boninitic magma stems can be identified, with similar high-field-strength element abundances, but different amounts of Ca, Na, Al and light-rare-earth elements. There is also evidence for a magma stem transitional in chemistry from the boninites to arc tholeiites. The compositions of these boninites are consistent with hypotheses for boninite formation by partial melting of a depleted mantle mixed with an incompatible element enriched fluid. The Mariana forearc boninite series lacks a strong iron enrichment, but produces andesites with lower Ti, Al and Y/Zr, and higher Mg, Ni and Cr than typical calcalkaline arc andesites and dacites. Boninites in the Mariana system were erupted only in the earliest phases of subduction zone activity.  相似文献   

11.
We report the result of H2O-undersaturated melting experiments on charges consisting of a layer of powdered sillimanite-bearing metapelite (HQ36) and a layer of powdered tonalitic gneiss (AGC150). Experiments were conducted at 10 kbar at 900°, 925° and 950°C. When run alone, the pelite yielded 40 vol% strongly peraluminous granitic melt at 900°C while the tonalite produced only 5 vol% weakly peraluminous granitic melt. At 950°C, the pelite and the tonalite yielded 50 vol% and 7 vol% granitic melt, respectively. When run side by side, the abundance of melt in the tonalite was 10 times higher at all temperatures than when it was run alone. In the pelite, the melt abundance increased by 25 vol%. When run alone, biotite dehydration-melting in the tonalite yielded orthopyroxene and garnet in addition to granitic melt. When run side by side only garnet was produced in addition to granitic melt. Experiments of relatively short duration, however, also contained Al-rich orthopyroxene. We suggest that the large increase in melt fraction in the tonalite is mainly a result of increased activity of Al2O3 in the melt, which lowers the temperature of the biotite dehydration-melting reaction. In the pelite, the increase in the abundance of melt is caused by transport of plagioclase component in the melt from the tonalite-layer to the pelite-layer. This has the effect of changing the bulk composition of this layer in the direction of minimum-temperature granitic liquids. Our results show that rocks which are poor melt-producers on their own can become very fertile if they occur in contact with rocks that contain components that destabilize the hydrous phase(s) and facilitate dehydration-melting. Because of this effect, the continental crust may have an even greater potential for granitoid melt production than previously thought. Our results also suggest that many anatectic granites most likely contain contributions from two or more different source rocks, which will be reflected in their isotopic and geochemical compositions.  相似文献   

12.
The metamorphic evolution of the Western Gneiss Region of Norway (WGR) can be evaluated from examination of eclogites formed as an integral part of the gneiss terrain (ie. in situ). Petrologic data from one of the larger country-rock eclogites within the northwestern part of WGR have been used to construct a P, T, t-path for this crustal volume. Textural relations as well as mineral composition and zonation suggest an early period of amphibolite facies conditions, followed by movement along a very steep positive P/T-gradient towards very high pressure (P25 kb) and moderate temperature (T600° C). Orthopyroxene coexisting with garnet at such conditions was poor in Al (<0.5 wt% Al2O3) and is preserved in the cores of orthopyroxene grains in garnet websterites. The increasing Al-content of orthopyroxene towards garnet, and increasing edenite substitution rimwards in zoned amphiboles, suggest a period of decompression accompanied by heating, towards the metamorphic maximum at T 750° C, P20kb. Garnet zoning reflects a general prograde history, but the reactions that control the zoning are insensitive to pressure changes. Jadeitic pyroxenes may have formed in the gneisses at P-max, but would revert to plagioclase subsequent to the metamorphic maximum, giving rise to the observed mineralogy. Further decompression and cooling continued towards high-rank amphibolite facies conditions. This P, T, t-path reflects crustal thickening to 80–90 km during Caledonian time. The uplift path is qualitatively similar to theoretically derived paths in which uplift is assumed to be controlled by erosion. However, uplift following the metamorphic maximum may have been accelerated by a period of suture progradation.  相似文献   

13.
Anhydrous P-T phase relations, including phase compositions and modes, are reported from 10–31 kbar for a near-primary high-alumina basalt from the South Sandwich Islands in the Scotia Arc. The water content of natural subduction-related basalt is probably <0.5 wt.% and thus, these results are relevant to the generation of primary basaltic magmas in subduction zones. At high pressures (>27 kbar) garnet is the liquidus phase followed by clinopyroxene, then quartz/coesite at lower temperatures. At intermediate pressures (17–27 kbar), clinopyroxene is the liquidus phase followed by either garnet, quartz, plagioclase, then orthopyroxene or plagioclase, quartz, garnet, then orthopyroxene depending on the pressure within this interval. At all lower pressures, plagioclase is the liquidus phase followed at much lower temperatures (100° C at 5 kbar) by clinopyroxene. The absence of olivine from the liquidus suggests that the composition studied here could not have been derived from a more mafic parent by olivine fractionation at any pressure investigated, and supports the interpretation that it is primary. If so, these results also preclude an origin for this melt by partial melting of olivine-rich mantle periddotite and suggest instead that it was generated by partial melting of the descending slab (quartz eclogite) leaving clinopyroxene, garnet, or both in the residue. The generally flat REE patterns for low-K series subduction related basalts argue against any significant role for garnet, however, and it is thus concluded that the composition studied here was extracted at 20–27 kbar after sufficiently high degrees of partial melting (50%) to totally consume garnet in the eclogite source. Melting experiments on three MORB composition, although not conclusive, are in agreement with this mechanism. Results at 30 kbar support an origin for tonalite/trondhjemite series rocks by lower degrees of melting (15–30%), leaving both garnet and clinopyroxene in the residue.  相似文献   

14.
When reference frames and diffusing components are properly selected, the flux equations for diffusion of the major components in natural garnets may often be approximated by: J DC. In such cases it is shown that, for reasonable diffusion coefficients and boundary conditions, observed zoning profiles in natural garnets may be explained with pure diffusion models. These models allow for original inhomogeneities in the host rock and may be used to explain why single hand specimens may show such a variety of zoning profiles within a single mineral species.  相似文献   

15.
Co-existing plagioclase and alkali feldspars of the Sierra Nevada granites and plagioclases of the mafic inclusions have been analysed using an ARL EMX electron microprobe analyser. Each Sierran rock type contains co-existing feldspar pairs within specific compositional ranges. Core plagioclase compositions of the mafic inclusions are only slightly higher or lower in anorthite than the host rock plagioclases and cluster between An30 and An40. The chemical inhomogeneity of the Sierran potash feldspars and this effect on the Barth k value prohibits the use of the feldspars as geothermometers for these particular rocks. Results of the electron microprobe, x-ray, and petrographic study and the experimental hydrothermal investigation of the granites suggest but do not prove that both the plagioclase composition and the mafic inclusion mineralogy can be explained in terms of a model which considers the inclusions to be the refractory residue left over from the partial melting of crustal material.Submitted to the Faculty of the Department of the Geophysical Sciences, The University of Chicago, in partial fulfillment for the degree of Doctor of Philosophy.  相似文献   

16.
In the system CaO-MgO-A12O3-SiO2 the tie lines connecting anorthite with other phases are sequentially broken down with increasing pressure according to the following univariant reactions: anorthite+ enstatitess+sillimanite pyrope-grossularss+quartz (3), anorthite+enstatitess pyrope-grossularss+diopsidess+quartz (2), anorthite+pyrope-grossularss+ quartz diopsidess+kyanite (4) and anorthite+diopsidess grossular-pyropess +kyanite+quartz (8). At 1,200 ° C these reactions occur at 14.5± 0.5, 15.5±0.5, 19.5±0.5 and 26.4±1 kilobar and have positive slopes (dP/dT) of 1±0.5, 2.8±0.5, 13.3±0.5 and 24±2bars/°C respectively. An invariant point involving kyanite rather than sillimanite, occurs at 850 °C±25 °C and 14.5±0.5kbar at the intersection of reactions (3), (2) and (4). Reaction(4) exhibits significant curvature with an increase in dP/dT from 13.3±0.5 to 18.5± 0.5 bars/°C between 1,050° and 850° C. The pressure at which the complete grossular-pyrope join is stable with quartz is estimated at 41 ± 1 kbar at 1,200 ° C. The pressure at which garnet appears according to reaction (2) is lowered by 5 kbar for a composition with anorthite and orthopyroxene (En0.5Fs0.5). Enstatite and plagioclase (An0.5Ab0.5) first produce garnet at 2 kbar higher pressure than enstatite and pure anorthite (reaction (2)). The calcium content of garnet in various divariant assemblages is relatively insensitive to temperature but very sensitive to pressure, it is therefore a useful geobarometer. At metamorphic temperatures of 700–850 °C pressures of 8–10 kbar are required for the formation of quartz-bearing garnet granulites containing calcic plagioclase and with (Mg/Mg+Fe) bulk = 0.5.  相似文献   

17.
A study has been made of clinopyroxene phenocrysts from within-plate dominant and subduction-related basic lavas, which are within the same volcanic pile of the Lower Namurian volcanic complex of Tazekka (Eastern Morocco). Twenty-one clinopyroxene phenocrysts (113 probe analyses in total) have been analysed from two thin sections of the within-plate lava sample, and 17 clinopyroxene phenocrysts (82 probe analyses in total) have been analysed from two thin sections of the subduction-related lava sample. Petrographic and microprobe data on clinopyroxene phenocrysts from the two lavas indicate specific textural and chemical features according to the source, namely: relatively low pressure and high temperature crystallisation conditions for the sector-zoned crystals from the basalt of the first group, although such a sector-zoned growth in clinopyroxenes is usually considered as evidence for a continental within-plate affinity of host-rocks; intermediate pressure and relatively low temperature crystallisation conditions for homogeneous crystals from the basalt of the second group. Thus distinct P-T conditions for equilibrium crystallisation of the pyroxenes in each host-magma are proposed. Clinopyroxene affinities observed in specific discriminative diagrams are in agreement with trace element geochemistry of the host-lavas, i.e. continental within-plate features for clinopyroxenes of the group 1 host-rock and subduction-related features for clinopyroxenes of the group 2 host-rock, which often exhibit extreme parameters highlighting the problem of petrogenesis of these basic lavas in an unusual continental crust subduction-related environment.  相似文献   

18.
Origin and differentiation of picritic arc magmas,Ambae (Aoba), Vanuatu   总被引：3，自引：2，他引：1  
Key aspects of magma generation and magma evolution in subduction zones are addressed in a study of Ambae (Aoba) volcano, Vanuatu. Two major lava suites (a low-Ti suite and high-Ti suite) are recognised on the basis of phenocryst mineralogy, geochemistry, and stratigraphy. Phenocryst assemblages in the more primitive low-Ti suite are dominated by magnesian olivine (mg 80 to 93.4) and clinopyroxene (mg 80 to 92), and include accessory Cr-rich spinel (cr 50 to 84). Calcic plagioclase and titanomagnetite are important additional phenocryst phases in the high-Ti suite lavas and the most evolved low-Ti suite lavas. The low-Ti suite lavas span a continuous compositional range, from picritic (up to 20 wt% MgO) to high-alumina basalts (<5 wt% MgO), and are consistent with differentiation involving observed phenocrysts. Melt compositions (aphyric lavas and groundmasses) in the low-Ti suite form a liquid-line of descent which corresponds with the petrographically-determined order of crystallisation: olivine + Cr-spinel, followed by clinopyroxene + olivine + titanomagnetite, and then plagioclase + clinopyroxene + olivine + titanomagnetite. A primary melt for the low-Ti suite has been estimated by correcting the most magnesian melt composition (an aphyric lava with 10.5 wt% MgO) for crystal fractionation, at the oxidising conditions determined from olivine-spinel pairs (fo2 FMQ + 2.5 log units), until in equilibrium with the most magnesian olivine phenocrysts. The resultant composition has 15 wt% MgO and an mg Fe2 value of 81. It requires deep (3 GPa) melting of the peridotitic mantle wedge at a potential temperature consistent with current estimates for the convecting upper mantle (T p 1300°C). At least three geochemically-distinct source components are necessary to account for geochemical differences between, and geochemical heterogeneity within, the major lava suites. Two components, one LILE-rich and the other LILE- and LREE-rich, may both derive from the subducting ocean crust, possibly as an aqueous fluid and a silicate melt respeetively. A third component is attributed to either differnt degrees of melting, or extents of incompatible-element depletion, of the peridotitic mantle wedge.  相似文献   

19.
Eclogite xenoliths from the mantle have experienced a wide variety of processes and P-T conditions, many of which are recorded in the mineral compositions and textures. Exsolution of garnet from clinopyroxene is one such texture, occurring in a minority of mantle eclogites. New analyses of clinopyroxene and garnet of eclogite xenoliths from kimberlites at Bellsbank (South Africa) and Obnazhënnaya (Yakutia, Russia) are presented here, and these are combined with data from the literature. Exsolution of garnet from clinopyroxene is generally lamellar, although lens-shaped garnets are also present. Major- and trace-element characteristics show a wide range of compositions and include eclogite Groups A, B, and C. Rare-earth element (REE) concentrations of garnet and pyroxene were determined by SIMS, and the REE patterns are subtly different from those in ordinary eclogites. Differences include the absence of prominent Eu anomalies in samples of this study and differences in the slopes of chondrite-normalized REE patterns. It is possible that these signatures are unique to exsolved eclogites, a result of subsolidus elemental partitioning during exsolution. Some reconstructed whole-rock compositions are aluminuous; comparison with ordinary eclogites shows only minor differences, implying a similar origin. If the immediate precursor to the exsolved eclogites was a monomineralic pyroxenite, the excess aluminium was tied up in Tschermak's molecule, although the occasional presence of kyanite exsolution lamellae is indicative of a Ca-Eskola component. Reconstructed pyroxenes from kyanite- and corundum-rich samples contain unrealistic amounts of aluminium for mantle pyroxenes. A protolith (or parental pyroxene) threshold of 24% Al2O3 may exist, above which (as in a plagioclase cumulate) the final assemblage is kyanite- and/or corundum-bearing.  相似文献   

20.
Isothermal crystallization experiments on basalt have been carried out using an infrared heating furnace to investigate the effect of stirring. When stirring was not applied (static experiment), the results agreed well with previous experiments. But when stirring was applied and a flow of Reynolds number=10–3–4 was present (dynamic experiment), considerably different results were obtained, especially in respect to the nucleation rate and the morphology of crystals. At T=25° C essentially similar results were obtained on the nucleation rates and morphologies of crystals in both static and dynamic experiments. However, at supercoolings larger than 45° C, nucleation density increased drastically in dynamic experiments reaching up to ten times as large as that in static experiments. Crystals of plagioclase and clinopyroxene were small and adapted acicular morphology regardless of T in dynamic experiments, and hyalopilitic textures were formed. A TTT-diagram shows that the nucleation incubation time is shorter in dynamic experiments than in static experiments. No compositional difference in major elements was found in plagioclase and clinopyroxene produced in both static and dynamic experiments. However, minor element concentrations, e.g., Mg in plagioclase and Ti, Al in clinopyroxene, were found to increase with both T and flow velocity. All these results imply that although chemical diffusion in the melts did not play an important role in the dynamic experiments, interface kinetics were important. It is suggested that hyalopilitic texture commonly seen in natural basalt is mainly due to flow in magma.  相似文献   

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