首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Summary ¶Fine- to coarse-grained plutonic nodules within the Petrazza pyroclastics (Paleo-Stromboli I period) consist of gabbroic rocks with variable amounts of interstitial material. They are characterised by cumulate textures and low pressure modal mineralogy formed by plagioclase (An96–87)+clinopyroxene (Mg-v 82–94)+olivine (Fo83–74)±amphibole±opaque minerals; the interstitial material consists of newly crystallised microlites (quenching) of plagioclase (An73–55)+amphibole+clinopyroxene±olivine±biotite±opaques and highly variable amounts of residual glasses that range in composition from shoshonite and high-K basaltic andesite to high-K andesite and latite. The interstitial material has a relatively high but variable degree of vesicularity. The whole rock incompatible element abundances are lower than – but the patterns are typical of – in subduction related magmas and the incompatible trace-elements are well correlated with the amount of the interstitial material. The Sr, Pb and Nd isotopic ratios resemble those of the extrusive rocks of Stromboli older series and the mineral chemistry of the gabbros is similar to that of the HKCA Paleo-Stromboli lavas. Modal mineralogy, mineral chemistry and chemical-isotopic whole rock compositions suggest that the cumulus portions of the gabbroic nodules crystallised from basaltic magmas compositionally compatible with those erupted by Stromboli volcano. The interstitial material does not represent the residual liquid after in situ crystallisation of the gabbros; it is also distinct from the juvenile host andesite magma. Textural evidence, Fe–Mg mineral/liquid partioning and mass balance calculations indicate that the interstitial material (quench crystals and vesicular glass) derived from infiltrated hydrous basaltic liquid undercooling and vesiculation of which occurred during the eruption of the Petrazza pyroclastics.Received April 17, 2002; revised version accepted November 14, 2002 Published online June 2, 2003  相似文献   

2.
A 525-m-long drill core (DDH-221) through the Partridge Riverintrusion has been divided into four zones on the basis of changesin mineral abundances, compositions and grain size. The igneousrocks in the core consist of cumulate gabbro, troctolite andolivine gabbronorite, in which the original cumulate frameworkof plagioclase and olivine contained varying amounts of trappedintercumulus (pore) liquid. The compositions of the unzoned olivine (Fo31–71) havebeen modified by reaction with Fe-rich in situ intercumulusliquid, but the plagioclase cores (An59–73) have not.The compositions of postcumulus Ca-rich pyroxene, restrictedto En36–44, and the more variable Ca-poor pyroxene (En45–74),follow a downward Fe-enrichment trend similar to the Fe-enrichmentin the olivine. The cumulus olivine expected to be in equilibriumwith plausible parental magmas to these rocks was not preservedin the drill core, nor is the chilled margin to the intrusionsufficiently primitive to account for all the olivine. Revisedmass balance estimates of the primary magmatic compositionsof olivine are Fo67–85. The new limiting value for theprimary olivine is similar to the Fo83–85 olivine expectedto crystallize from the chilled margin to the nearby PigeonPoint olivine diabase sill under equilibrium conditions. Thechanges in the mineral compositions in core DDH-221 do not adequatelydescribe the behavior of parental melts on an equilibrium coolingpath, implying that the cumulus plagioclase and olivine crystallizedelsewhere, and were mixed with varying amounts of intercumulusliquid before introduction to the present crustal site of thePartridge River intrusion. Rock density increases with depth from 2?76 to 3?21, with amean of 2?98 g/cm3. Estimated trapped liquid densities rangefrom 2?56 to 2?92 g/cm3 at high temperatures. This is interpretedto mean that the intercumulus liquid could not have been expelledupward by compaction of the cumulate pile. The dense intercumulusliquid increased downward in abundance to form a series of rocksthat range continuously from variously packed framework cumulatesto chilled non-cumulate rocks in the basal zone. In situ crystallizationis concluded to be the dominant mode of solidification of thePartridge River intrusion, in which infiltration metasomatismis precluded by the high liquid density.  相似文献   

3.
Larkman Nunatak (LAR) 06319 is an olivine-phyric shergottite whose olivine crystals contain abundant crystallized melt inclusions. In this study, three types of melt inclusion were distinguished, based on their occurrence and the composition of their olivine host: Type-I inclusions occur in phenocryst cores (Fo77-73); Type-II inclusions occur in phenocryst mantles (Fo71-66); Type-III inclusions occur in phenocryst rims (Fo61-51) and within groundmass olivine. The sizes of the melt inclusions decrease significantly from Type-I (∼150-250 μm diameter) to Type-II (∼100 μm diameter) to Type-III (∼25-75 μm diameter). Present bulk compositions (PBC) of the crystallized melt inclusions were calculated for each of the three melt inclusion types based on average modal abundances and analyzed compositions of constituent phases. Primary trapped liquid compositions were then reconstructed by addition of olivine and adjustment of the Fe/Mg ratio to equilibrium with the host olivine (to account for crystallization of wall olivine and the effects of Fe/Mg re-equilibration). The present bulk composition of Type-I inclusions (PBC1) plots on a tie-line that passes through olivine and the LAR 06319 whole-rock composition. The parent magma composition can be reconstructed by addition of 29 mol% olivine to PBC1, and adjustment of Fe/Mg for equilibrium with olivine of Fo77 composition. The resulting parent magma composition has a predicted crystallization sequence that is consistent with that determined from petrographic observations, and differs significantly from the whole-rock only in an accumulated olivine component (∼10 wt%). This is consistent with a calculation indicating that ∼10 wt% magnesian (Fo77-73) olivine must be subtracted from the whole-rock to yield a melt in equilibrium with Fo77. Thus, two independent estimates indicate that LAR 06319 contains ∼10 wt% cumulate olivine.The rare earth element (REE) patterns of Type-I melt inclusions are similar to that of the LAR 06319 whole-rock. The REE patterns of Type-II and Type-III melt inclusions are also broadly parallel to that of the whole-rock, but at higher absolute abundances. These results are consistent with an LAR 06319 parent magma that crystallized as a closed-system, with its incompatible-element enrichment being inherited from its mantle source region. However, fractional crystallization of the reconstructed LAR 06319 parent magma cannot reproduce the major and trace element characteristics of all enriched basaltic shergottites, indicating local-to-large scale major- and trace-element variations in the mantle source of enriched shergottites. Therefore, LAR 06319 cannot be parental to the enriched basaltic shergottites.  相似文献   

4.
The Jinchuan Ni–Cu sulfide deposit is hosted by an elongated, olivine-rich ultramafic body that is divided by subvertical strike-slip faults into three segments (central, eastern, and western). The central segment is characterized by concentric enrichments of cumulus olivine crystals and interstitial sulfides (pyrrhotite–pentlandite–chalcopyrite intergrowth), whereas the eastern and western segments are characterized by an increase of sulfides toward the lower contacts. In all segments sulfides are concentrated at the expense of intercumulus silicates. Olivine re-crystallization is found to be associated with actinolite alteration in some samples. The compositional variations of primary olivine from the sulfide-poor samples can be explained by a small degree of olivine crystallization (<5%) from a basaltic magma followed by local re-equilibration of the olivine with up to 30% trapped silicate liquid. In the sulfide-bearing samples the compositions of primary olivine record the results of olivine-sulfide Fe–Ni exchange that occurred after the trapped silicate liquid crystallized. Our olivine data indicate that Ni in the original sulfide liquids increased inward in the central segment and laterally away from the lower contact in the eastern segment. Variations in the compositions of sulfide liquids are thought to result from fractional segregation of immiscible sulfide liquid from a basaltic magma in a staging chamber instead of in situ differentiation. High concentrations of olivine crystals (mostly >50 modal%) and sulfide (averaging ~5 wt%) in the rocks are consistent with the interpretation that the Jinchuan deposit was formed by olivine- and sulfide-laden magma successively ascending through a conduit to a higher, now-eroded, level. Sulfide enrichment toward the center in the central segment and toward the lower contact in the eastern and western segments may have, in part, resulted from flow differentiation and gravitational settling during magma ascent, respectively.Editorial handling: P. Lightfoot  相似文献   

5.
Tertiary volcanism in the İkizce region at the western edge of the eastern Pontides paleo-magmatic arc is represented by basaltic and andesitic rocks associated with sediments deposited in a shallow basin environment. The basaltic rocks contain plagioclase (An58–80), olivine (Fo82–84), clinopyroxene (Wo44–48En35–42Fs7–17), hornblende (Mg# = 0.68–0.76) phenocrysts, and magnetite microcrysts, whereas the andesitic rocks include plagioclase (An25–61), clinopyroxene (Wo46–49En38–43Fs11–13), hornblende (Mg# = 0.48–0.81), biotite (Mg# = 0.48–0.60) phenocrysts, titanomagnetite, apatite, and zircon microcrysts.Geochemical data indicate magmatic evolution from tholeiitic-alkaline transitional to calc-alkaline characteristics with medium-K contents. The geochemical variation in the rocks can be explained by fractionation of common mineral phases such as clinopyroxene, olivine, hornblende, plagioclase, magnetite, and apatite. The trace elements’ distributions of the volcanic rocks show similarities to those of E-Type MORB, have a shape that is typical of rocks from subduction-related tectonic setting with enrichment in LILE and to a lesser extent in LREE, but depletion in HFSE. The rocks evolved from a parental magma derived from an enriched source formed by subduction induced metasomatism of basaltic rocks, the latter formed through clinopyroxene ± olivine controlled fractionation in a high level magma chamber. The andesitic rocks developed through hornblende ± plagioclase controlled fractionation in shallow level magma chamber(s).  相似文献   

6.
Abundant Fe–Ti oxide inclusions in cumulus olivine (Fo77–81) from the Panzhihua and Hongge intrusions, Emeishan large igneous province, SW China, document the first evidence for early crystallization of Fe–Ti oxides in ferrobasaltic systems in nature. The intrusions also contain significant stratiform Fe–Ti–V oxide ores. The oxide inclusions are sub-rounded or irregular, range from ∼5 to 50 μm in diameter, and are dominated by either titanomagnetite or ilmenite. The fact that the inclusions are either titanomagnetite- or ilmenite-dominant suggests that they are trapped crystals, instead of immiscible oxide melt, formed during growth of the host olivine. The absence of other silicate phases in the inclusion-bearing olivine is difficult to reconcile with a possible xenocrystic origin of the oxide inclusions. These oxide inclusions are thus interpreted to be cumulus minerals crystallized together and trapped in olivine from the same parental magma. In addition to Fe–Ti oxides, some inclusions contain amphibole + biotite ± fluorapatite that might have formed by reaction of trapped hydrous liquid with the host olivine. Numerical modeling of high-Ti Emeishan basalts using the MELTS program successfully simulates early crystallization of olivine (∼Fo81) and Fe–Ti spinel in the presence of a moderate amount of H2O (∼1.5 wt%) under pressure and fO2 conditions generally pertinent to the Panzhihua and Hongge intrusions. The modal mineralogy of the oxide inclusions is in good agreement with the bulk compositions of the ore, as inferred from whole-rock data, in a given intrusion. This is consistent with the interpretation that the stratiform oxide ores in the intrusions formed by accumulation of Fe–Ti oxide crystals that appeared on the liquidus with olivine and clinopyroxene.  相似文献   

7.
The development of orthopyroxene-Fe/Mg ferrite symplectites associated with olivine is discussed with respect to the chemical reactions by which they form. Previously proposed reactions are presented graphically and the differences between them are reviewed. With the exception of exsolution, these are all discontinuous reactions in the sense that olivine is replaced by the two-phase symplectite assemblage.Olivine-hosted symplectites developed in the margins of lherzolite xenoliths from Kauai, Hawaii, demonstrate a reaction mechanism which has not been previously documented from natural samples. Original Fo90 olivine in these samples oxidized to a new assemblage consisting of orthopyroxene (En92–95)-Fe/Mg ferrite (Mf35–50) symplectites developed within more magnesian olivine (Fo92–96) hosts. Thus, by this mechanism, olivine of a different composition persists as part of a final three-phase assemblage. As oxidation advanced, the compositions of all three product phases became continuously more magnesian and the stoichiometric coefficients of the orthopyroxene and Fe/Mg ferrite continuously increased, whereas those of the product olivine decreased in the mass-balance equations. These characteristics demonstrate that the reaction was controlled by oxygen diffusion into the xenoliths from the highly oxidized alkali picrite melt in which they were entrained. Thermodynamic calculations suggest that a gradient in oxygen fugacity of 100.9 bars existed across the xenolith rims and resulted in compositional gradients of 4 mol% fayalite and ferrosilite and 15 mol% magnetite.  相似文献   

8.
Whole-rock, major and trace element analyses and microprobe mineral analyses were conducted on serpentinized peridotites recovered from the walls of a MAR (Mid-Atlantic Ridge) 43° N fracture zone. These peridotites are extensively serpentinized; serpentine usually makes up 30–100 vol. percent of the bulk rocks. The relict minerals observed consist mainly of olivine and orthopyroxene with subordinate amounts of clinopyroxene and brown spinel. The range in olivine composition is very limited (Fo91–92). Orthopyroxene forms large, anhedral crystals with clinopyroxene exsolution lamellae and shows undulose extinction with bent cleavages and lamellae. Broad beam microprobe analyses indicate that the composition range of orthopyroxene is also limited (En89.1–87.6Fs8.2-8.0Wo2.7–4.4; Al2O3=1.82–2.64 wt%; Cr2O3=0.63–0.88 wt%). Clinopyroxene tends to fringe large orthopyroxene crystals or fills the interstices between them. The Mg/Fe ratios of clinopyroxene are practically constant; however, the Ca/(Ca + Mg + Fe) ratios range from 0.48 to 0.45. The Cr/(Cr+Al) and Mg/(Mg+ Fe2+) ratios of brown spinel range from 0.57 to 0.36 and 0.69 to 0.56, respectively. The geothermometers utilizing coexisting spinel lherzolite mineral assemblages suggest that the MAR 43° N peridotites attained equilibrium at temperatures from 1100° to 1250° C.Peridotites recovered from the ocean floor are generally considered to have been subjected to partial melting processes and are regarded as residues left after primary magma was removed. Major element chemistry of the MAR 43° N peridotites are compared with those of the ocean-floor ultramafic tectonites reported previously and used together with those published data to demonstrate that the major element abundances of the oceanfloor peridotites define an average trend which is compatible with removal of primary magma from these peridotites at moderate pressures (10–15 kb). Then, the most primitive abyssal tholeiite glasses could be produced by ca. 10% olivine fractionation of such primary magma. Extensive fractionation of olivine and/or orthopyroxene from picritic liquids which are in equilibrium with the lherzolitic or harzburgitic mantle sources at higher pressures (>20 kb) could not yield the majority of the most primitive abyssal tholeiite glasses.  相似文献   

9.
The Delakhari sill (maximum thickness cf. 200 m) is the most extensive Deccan Trap instrusion which occurs in central India, between longitutdes 78°3835 to 78°2240 and latitudes 22°26 and 22°2230. Based on petrographic examination, the sill is divided, from bottom to top, into (1) the Lower Chilled Zone (LCZ), up to 8 m thick, marked by abundant interstitial glass and an overall fine grain size, (2) the Olivine-Rich Zone (ORZ), 27 m thick, enriched in olivine (relative to the other zones in the sill), (3) the Central Zone (CZ), 70 m thick, marked by depletion in olivine and overall coarse grain size, (4) the Upper Zone (UZ), 55 m thick, marked by the presence of two chemically and morphologically distinct olivine types and abundant interstitial granophyre, and (5) the Upper Chilled Zone (UCZ), 10–25m thick, marked by abundant interstitial glass.Compositions of the pyroxenes and olivines show an overall increase in Fe/Mg with crystallization, but extensive interzonal and intrazonal variations and overlaps exist. Olivine ranges from Fa24 (ORZ) to Fa95 (UZ). In the UZ and inner UCZ, an equant (Fa44–50, called type-A olivine) and interstitial skeletal olivine (Fa70–95, called type-B olivine) occur together. Compositions of the Ca-rich and Ca-poor pyroxenes fall in the range Wo38En34Fs28 to Wo33En8Fs59 and Wo14En41Fs45 to Wo16En19Fs65, respectively. Overall, the two pyroxene trends converge with Fe-enrichment except for one anomalous sample from the UZ which contains a Ca-rich (Wo34En8Fs58) and a Ca-poor (Wo10En18Fs72) pyroxene well within the Forbidden Zone of Smith (1972).Compositions of coexisting oxide minerals indicate that the sill crystallized at oxygen fugacities from 10–10 atm (ORZ) to 10–13 (UZ). The magma prior to intrusion appears to have been derived from a more primitive melt from which a considerable amount of olivine and plagioclase have fractionated out. A model of open, interrupted fractional crystallization in the sill is proposed to explain the compositional variations exhibited by the major mineral phases.A previous study (Crookshank 1936) concluded that the sill is actually a multiple intrusion and has given rise to the lowermost (flow I) and the topmost (flow III) lava flows in the neighboring area around Tamia (78°4015, 22°2035). The olivines of flows I and III have compositions Fo87 and Fo88 respectively, and are much more Mg-rich than the maximum Mg-rich olivine (Fo76) of the Delakhari sill, refuting the possibility of the sill being the feeder of the lava flows I and III.Geosciences Department, University of Texas at Dallas Contribution No. 338  相似文献   

10.
Petrogenetic relationships between melilitite and lamproite   总被引：3，自引：0，他引：3  
A detailed petrological study of the S. Venanzo olivine melilitite and Cupaello kalsilitite, located at the NE margin of the Roman Comagmatic Region of Italy has provided new data to evaluate their genetic relationships and related tectonic/magmatic conditions. Early crystallized olivine (Fo92) from S. Venanzo is compatible with crystallization from near primary mantle melts, while late-crystallized olivine from both rocks (Fo88–79) reflects primarily the high Ca of the host liquids, attained under the volcanic crystallization regime. Magnesiochromite inclusions in the early-crystallized olivine are consistent with near-primary melts close to lamproite in composition. Nepheline and kalsilite from both lavas contain high alkalis (+Ca), relative to Al, and thus correspond more closely with nepheline compositions from carbonatite-related assemblages, than with those from a wide compositional range of Alban Hills lavas. Coexisting melilite has high (Na+K)/Al, reflecting the Peralkalinity Index of the bulk rocks. Diopside and phlogopite from both lavas are characteristic of lamproites and groundmass kimberlites in their high Mg/(Mg+Fe2+) ratio (0.86–0.95; 0.80–0.90, respectively) and T-site (Si+Al) deficiencies. Götzenite, Ca2Na[Zr, Ti]Si2O7(O, OH, F)2, identified in both lavas, is typical of nephelinite-ijolite assemblages. On the other hand, khibinskite, K4Zr2Si4O14, found in the Cupaello lava, may be regarded as a Si-poor variety of wadeite, a mineral characteristic of lamproites. Clinopyroxene and monticellite, coexisting as late-crystallized phases in both lavas, suggest a common P-T liquid path of thermal descent in the system CaMgSi2O7–CO2 in the presence of excess CO2, but with different intersections with the åkermanite stability field. Substantial differences in SiO2 saturation combined with high Mg number and liquidus temperatures experimentally determined at atmospheric pressure in both lavas (1276° C and 1260° C, respectively) indicate that a parent-daughter relationship is unlikely under the volcanic P-T regime. In La Roche's Rm-Ri-Rs diagram, the S. Venanzo composition fall close to the Oldoinyo Lengai alkalic pyroxenite trend of Donaldson and Dawson, while the Cupaello compositions follow a lamproitic trend, consistent with that indicated by the quartz-normative glass of the Gaussberg lava. Mantle compositions corresponding to wehrlite-clinopyroxenite and enriched in H2O, CO2, F, and LILE, are favoured as potential sources for the lavas. Their origin is probably related to subcrustal fluid transfer promoted by the Tyrrhenian mantle doming.  相似文献   

11.
Glass inclusions in olivine and diopside phenocrysts from pyroclasts of various eruptions of Vesuvius are representative of the magmas that supplied the volcano in the last 4–5000 years. During this interval the volcano alternated between open conduit activity (e.g. 1944 and 1906 eruptions) with long pauses interupted by Plinian and sub-Plinian eruptions (e.g. 3360 B.P. Avellino, A.D. 79 Pompei, A.D. 472 Pollena). The eruptive behaviour was conditioned in all cases by the presence of shallow reservoirs: two cases are distinguished: (1) small and very shallow, 1906-type; (2) large and deeper Plinian-sub-Plinian magma chamber. Lapilli of 1906 lava fountains contain olivine (Fo89.5–90.4) including Cr-spinel [Cr/(Cr+Al)] (Cr#>75) and volatile-K-rich tephritic glasses, which represent the first recognized Vesuvius primary magmas. Mg-poorer olivine (Fo83–89) also occurs in 1906 and 1944 products; it formed within the shallow reservoir, together with pyroxene and leucite, between 1200 and 1130°C, from K-tephritic melts (MgO=6–8 wt%). The Plinian and sub-Plinian pumices contain diopside, phlogopite and minor olivine (Fo85–87) representing adcumulates wrenched from the chamber walls. Glass inclusions in diopside (and some olivine) range from K-basalt to K-tephrite (MgO=6–8 wt%), with homogenization temperature of 1130–1170°C. They have been regarded as representative of the magmas supplying the Plinian-sub-Plinian chamber(s). The Avellino glass inclusions have K-basaltic compositions, contrasting with the mostly K-tephritic Pompei and Pollena inclusions. They display lower C1 and P contents with respect to the younger tephritic melts, and these variations should reflect primary features of the mantle-derived magmas. The primary and the near-primary Vesuvius magmas, as illustrated by melt inclusions, emphasize high K, P and volatile (H2O, Cl, F, S) contents, with high K2O/H2O (2–2.5), Cl/F (2.5) and Cl/S (2–3) ratios, consistent with a metasomatized mantle source, and distinguishing the Vesuvius potassic primary magmas from those of the northern part of the Roman Province.  相似文献   

12.
The Tin Zebane gabbro–anorthosite layered mafic intrusion represented by plagioclase-rich cumulates forms a set of small lenticular to round-shaped mainly undeformed bodies intruding the Pan-African high-pressure metamorphic rocks from western Hoggar (Tuareg shield, southwest Algeria). The coarse-grained anorthosites are mainly made of slightly zoned bytownite (An86–74) with the higher anorthite content at the cores. Anorthosites are interlayered with leucogabbros and gabbros that show preserved magmatic structures and with olivine gabbros characterised by coronitic textures. The primary assemblage in gabbros includes plagioclase (An93–70), olivine (Fo77–70), zoned clinopyroxene (En43–48Fs05–13Wo41–49 with Al2O3 up to 4.3 wt.%) and rare orthopyroxene (En73–78). Pyroxenes and olivine are commonly surrounded by Ca-amphibole. The olivine–plagioclase contact is usually marked by a fine orthopyroxene–Cr-spinel–amphibole symplectite. A magnesian pigeonite (En70–75Fs19–20Wo6–10) is also involved in corona. The coronitic minerals have equilibrated with the primary mineral rims at P–T–aH2O conditions of 797 ± 42 °C for aH2O=0.5 and 808 ± 44 °C for aH2O=0.6 at 6.2 ± 1.4 kbar. The Tin Zebane gabbroic rocks are depleted in REE with a positive Eu anomaly, high Sr (>10 * chondrite) and Al2O3 concentrations (17–33%) that support plagioclase accumulation with the extreme case represented by the anorthosites. The REE patterns can be modelised using plagioclase, clinopyroxene and orthopyroxene REE signature, without any role played by accessory minerals. High MgO content points to olivine as a major cumulate phase. Anorthositic gabbros Sr and Nd isotopic initial ratios are typical of a depleted mantle source (Sri=0.70257–0.70278; Nd=+5.9 to +7.8). This isotopic signature is identical to that of the 10-km wide 592 Ma old dyke complex composed of alkaline to peralkaline granites and tholeiitic gabbros and one single bimodal complex can be inferred. The source of the Tin Zebane basic rocks corresponds to the prevalent mantle (PREMA). The Tin Zebane complex was emplaced along the mega-shear zone bounding to the west the Archaean In Ouzzal metacraton. The model proposed suggests a linear lithospheric delamination along this rigid and cold terrane due to post-collisional transtensional movements. This allowed the asthenosphere to rise rapidly and to melt by adiabatic pressure release. Transtension along a rigid body allowed these mantle melts to reach the surface rapidly without any crustal contamination.  相似文献   

13.
The textural features and mineralogy of chrome-spinel bearing rocks from the layered ultrabasic intrusion of Rhum indicate that in situ reaction of chromite with olivine, plagioclase and interstitial liquid has taken place. The compositions of the chrome-spinels vary throughout parts of the intrusion and also in a systematic way across a thin picotite rich seam at a feldspar cumulate — olivine cumulate junction. The origin of the chrome-spinel is discussed in relation to other occurrences of chromite in layered ultrabasic rocks.  相似文献   

14.
The chemical compositions of melt inclusions in a primitive and an evolved basalt recovered from the mid-Atlantic ridge south of the Kane Fracture Zone (23°–24°N) are determined. The melt inclusions are primitive in composition (0.633–0.747 molar Mg/(Mg+Fe2+), 1.01–0.68 wt% TiO2) and are comparable to other proposed parental magmas except in having higher Al2O3 and lower CaO. The primitive melt inclusion compositions indicate that the most primitive magmas erupted in this region are not near primary magma compositions. Olivine and plagioclase microphenocrysts are close to exchange equilibrium with their respective basalt glasses, whose compositions are displaced toward olivine from 1 atm three phase saturation. The most primitive melt inclusion compositions are close to exchange equilibrium with the anorthitic cores of zoned plagioclases (An78.3-An83.1; the hosts for the melt inclusions in plagioclase) and with olivines more forsteritic (Fo89-Fo91) than the olivine microphenocrysts (the hosts for the melt inclusions in olivine). Xenocrystic olivine analyzed is Fo89 but contains no melt inclusions. These observations indicate that olivines have exchanged components with the melt after melt inclusion entrapment, whereas plagioclase compositions have remained the same since melt inclusion entrapment. Common denominator element ratio diagrams and oxide versus oxide variation diagrams show that the melt inclusion compositions, which represent liquids higher along the liquid line of descent, are related to the glass compositions by the fractionation of olivine, plagioclase and clinopyroxene (absent from the mincral assemblage), probably occurring at elevated pressures. A model is proposed whereby clinopyroxene segregates from the melt at elevated pressures (to account for its absence in the erupted lavas that have the chemical imprint of clinopyroxene fractionation). Zoned plagioclases in the erupted lavas are thought to be survivors of decompressional melting during magma ascent. Since similar primitive melt inclusions occur in olivine microphenocrysts and in the cores of zoned plagioclases, any model must account for all phases present.  相似文献   

15.
The Perseverance ultramafic complex is a body of olivine-richkomatiitic rocks spatially associated with the Agnew nickeldeposit, in the Agnew-Wiluna greenstone belt of the ArchaeanYilgarn Block in Western Australia. The complex consists ofa central lenticular body, up to 700 m thick, of olivine adcumulates,flanked by laterally extensive sheet-like bodies of olivineorthocumulates and spinifextextured komatiite flows. Rocks progressivelyfurther away from the central lens have chemical compositionsreflecting higher original proportions of komatiite liquid tocumulus olivine. Parent liquids had MgO contents between 25and 32% MgO, approximately chondritic Al/Ti ratios and HREEpatterns, and moderate depletion in LREE. Olivines within the adcumulate lens show a progressive increasein forsterite content from Fo93 at the bottom to Fo94?5, atthe top. Calculated original olivine compositions in the flankingrocks are similar to those at the base of the central lens.Original olivine nickel contents show a symmetrical variationfrom maximum values of 3500 ppm at the top of the central lens,through minimum values of 1000 ppm at the base and margins ofthe central lens to intermediate values in the distal rocks.The complex as a whole shows evidence for nickel depletion relativeto other komatiite suites. These observations are explained in terms of prolonged eruptionand flow of komatiitic lava down a major flow channel or lavariver. Adcumulates crystallized on the floor and sides of thecentral channel, which was formed at an early stage by thermalerosion of floor rocks. Episodic overflow of the central channelproduced distal ‘flood plain’ rocks consisting ofolivine orthocumulates and layered flows. Lavas became moremagnesian and nickel-rich with time, giving rise to the observedspatial variation in primary olivine composition. Nickel depletionof the earliest lavas is attributed to pre-eruption segregationof large volumes of immiscible Fe-Ni-sulfide, which were concentratedto form the underlying Agnew nickel deposit.  相似文献   

16.
Cretaceous alkaline intrusive rocks present in the Bitterfontein area comprise a suite having compositions ranging from olivine melilitite to syenite. These rocks which include some of lamprophyric affinity form part of the widespread dominantly alkaline suite of intrusives occurring in a broad zone parallel to the south western African coastal regions. This paper presents the petrology of the Bitterfontein alkaline rocks together with mineral and rock analyses. The chemistry of the rocks shows the suite to define a SiO2 enrichment trend linking the compositions of olivine melilitite to oversaturated basic rocks. This trend is compared with trends defined by essentially tholeiitic volcanics and kimberlite-olivine melilitite compositions and a genetic relationship with the latter is apparent. Polybaric crystallisation of a larnite normative liquid in a crustal environment coupled with fractionation especially of phlogopite is important in the generation of members of the Bitterfontein suite. Phlogopite fractionation represents a deviation by the Bitterfontein suite from the evolutionary trend predicted by experimental work for low pressure anhydrous compositions in the Fo-La-Ne-SiO2 system.  相似文献   

17.
The Kap Edvard Holm Layered Gabbro Complex is a large layeredgabbro intrusion (>300 km2) situated on the opposite sideof the Kangerdlugssuaq fjord from the Skaergaard Intrusion.It was emplaced in a continental margin ophiolite setting duringearly Tertiary rifting of the North Atlantic. Gabbroic cumulates, covering a total stratigraphic thicknessof >5 km, have a typical four-phase tholeiitic cumulus mineralogy:plagioclase, clinopyroxene, olivine, and Fe–Ti oxides.The cryptic variation is restricted (plagioclase An81–51,olivine Fo85–66, clinopyroxene Wo43–41 En46–37Fs20–11) and there are several reversals in mineral chemistry.Crystallization took place in a low-pressure, continuously fractionatingmagma chamber system which was periodically replenished andtapped. Fine-grained (0•2–0•4 mm) equigranular, thin(0•5–3 m), laterally continuous basaltic zones occurwithin an {small tilde}1000 m thick layered sequence in theTaco Point area. Twelve such zones define the bases of individualmacrorhythmic units with an average thickness of {small tilde}80m. The fine-grained basaltic zones grade upwards, over a fewmetres, into medium-grained (>1 mm) poikilitic, olivine gabbrowith smallscale modal layering. Each fine-grained basaltic zoneis interpreted as an intraplutonic quench zone in which magmachilled against the underlying layered gabbros during influxalong the chamber floor. Supercooling by {small tilde}50C isbelieved to have caused nucleation of plagioclase, olivine,and clinopyroxene in the quench zone. The nucleation rate isbelieved to have been enhanced as the result of in situ crystallizationin a continuously flowing magma. The transition to the overlyingpoikilitic olivine gabbro reflects a decreasing degree of supercooling. Compositional variation in the Taco Point sequence is typicalfor an open magma chamber system: olivine (Fo77–68 5)and plagioclase cores (An80–72) show a zig-zag crypticvariation pattern with no overall systematic trend. Olivinehas the most primitive compositions in the quench zones andmore evolved compositions in the olivine gabbro; plagioclasecores show the opposite trend. Although plagioclase cores arebelieved to retain their original compositions, olivines re-equilibratedby reaction with trapped liquid. Some plagioclase cores containrelatively sodic patches which retain quench compositions. Whole-rock compositions of nine different quench zones varyover a range from 10 to 18% MgO although the mg-number remainsconstant at {small tilde}0•78. The average composition(47•7% SiO2, 13•3%MgO, 1•57% Na2O+K2O) is takenas a best estimate of the parental magma composition, and isequivalent to a high-magnesian olivine tholeiite. The compositionalvariation of the quench zones is believed to reflect burstsof nucleation and growth of olivine and plagioclase during quenching. Magma emplacement is believed to have taken place by separatetranquil influxes which flowed along the interface between alargely consolidated cumulus pile and the residual magma. Theresident magma was elevated with little or no mixing. At certainlevels in the layered sequence the magma drained back into thefeeder system; such a mechanism is referred to as a surge-typemagma chamber system.  相似文献   

18.
Three major types of xenoliths, namely, dunite, spinel lherzolite, and pyroxenite suites, occur. The spinel lherzolite suite [ol: Fo86–92] is more refractory than the pyroxenite suite [Fo71–85], and is composed of olivine, orthopyroxene, Cr-diopside, and spinel. Spinel lherzolites represent metasomatically modified mantle residues that constitute the lithosphere underneath Oahu. Metasomatism has induced significant heterogeneity in terms of [Na]cpx in the spinel lherzolitic lithosphere: compared to other vents, Salt Lake xenoliths are anomalously high in [Na]cpx. The fluids responsible for such a process may have been released after crystallization of the hydrous phases in pyroxenite suite veins intrusive into the spinel lherzolites.The pyroxenite suite rocks range from clinopyroxenites, wehrlites, websterites, to lherzolites and a rare dunite. Garnet generally occurs as a secondary phase forming reaction rims around spinel or exsolved blebs in clinopyroxene. Phlogopite and amphibole are common. The garnet-bearing pyroxenite suite rocks last equilibrated in the mantle at 1000°–1150° C and 16–25 kb (50–75 kms depth). Similar temperature range is recorded by the spinel lherzolite suite and rare plagioclase lherzolites. This P-T path is significantly hotter than a calculated conductive geotherm indicating that the lithosphere was substantially warmed up by passing Hawaiian magmas.Contribution No. 585, Geosciences Program, University of Texas at Dallas  相似文献   

19.
About 12.3 km3 of basaltic magma were erupted from the Lakagigar fissure in Iceland in 1783, which may have been derived from the high-level reservoir of Grimsvotn central volcano, by lateral flow within the rifted crust. We have studied the petrology of quenched, glassy tephra from sections through pyroclastic cones along the fissure. The chemical composition of matrix glass of the 1783 tephra is heterogeneous and ranges from olivine tholeiite to Fe–Ti rich basalt, but the most common magma erupted is quartz tholeiite (Mg#43.6 to 37.2). The tephra are characterized by low crystal content (5 to 9 vol%). Glass inclusions trapped in plagioclase and Fo86 to Fo75 olivine phenocrysts show a large range of compositions, from primitive olivine tholeiite (Mg#64.3), quartz tholeiite (Mg#43–37), to Fe–Ti basalts (Mg#33.5) which represent the most differentiated liquids and are trapped as rare melt inclusions in clinopyroxene. Both matrix glass and melt inclusion data indicate a chemically heterogeneous magma reservoir, with quartz tholeiite dominant. LREE-depleted olivine-tholeiite melt-inclusions in Mg-rich olivine and anorthitic-plagioclase phenocrysts may represent primitive magma batches ascending into the reservoir at the time of the eruption. Vesicularity of matrix glasses correlates with differentiation, ranging from 10 to 60 vol.% in evolved quartz-tholeiite glasses, whereas olivine-tholeiite glasses contain less than 10 vol.% vesicles. FTIR analyses of olivine-tholeiite melt-inclusions indicate concentrations of 0.47 wt% H2O and 430 to 510 ppm for CO2. Chlorine in glass inclusions and matrix glasses increases from 50 ppm in primitive tholeiite to 230 ppm in Fe–Ti basalts, without clear evidence of degassing. Melt inclusion analyses show that sulfur varies from 915 ppm to 1970 ppm, as total FeO* increases from 9 to 13.5 wt%. Sulfur degassing correlates both with vesicularity and magma composition. Thus sulfur in matrix glasses decreases from 1490 ppm to 500 ppm, as Mg # decreases from 47 to 37 and vesicularity of the magma strongly increases. These results indicate loss of at least 75% of sulfur during the eruption. The correlation of low sulfur content in matrix glasses with high vesicularity is regarded as evidence of the control of a major exsolving volatile phase on the degassing efficiency of the magma. Our model is consistent a quasi-permanent CO2 flux through the shallow-level magmatic reservoir of Grimsvotn. Following magma withdrawal from the reservoir and during eruption from the Lakagigar fissure, sulfur degassing was controlled by inherent CO2-induced vesicularity of the magma.  相似文献   

20.
The Vulsinian lavas are dominated by a suite of undersaturated leucite-bearing basic to intermediate compositions. The remaining lavas are mainly oversaturated and have shoshonitic affinities. One hundred and thirty-five samples have been analysed for major elements and most for 20 trace elements. Twenty-seven lavas have been analysed for REE. They are all perpotassic (for the undersaturated lavas: K2O/Na2O=2–8) and have very high LIL element concentrations, (e.g. Rb=400–800 ppm, Th=25–150 ppm, REE/REEcho=c.200, (LREE/HREE)cho=c.20) even in the most basic rocks.The undersaturated lavas appear to be interrelated by fractional crystallization of cpx±olivine (from 14 to 11 wt.% CaO), cpx+leu±plg±mica (from 11 to 8 wt.% CaO), cpx+leu+plg+apa+magnetite±mica (from 8 to 5 wt.% CaO), and additional sanidine (or hyalophane)±haüyne (from 5 to 3 wt.% CaO). The saturated lavas and the few slightly undersaturated shoshonite basalts are thought to be evolved from the undersaturated magma(s) by crustal contamination or mixing with silica-rich magmas. The parental Vulsinian magma having: Mg-value=c.73, Cr=300–700 ppm, Ni=100–125 ppm, Sc= 40–50 ppm, Fo89–92, Di77–97 approximates a primary, mantle-derived liquid. Enrichment in LIL elements (incl. REE) and LREE/HREE suggest a small degree of partial melting from fertile mantle; whereas the low concentrations of Na, Ti and P suggest larger degrees of partial melting. This indicates that either the primary magma or the parental mantle was metasomatized by a fluid, which previously equilibrated with subducted continental material. This model agrees with published high 18O, high 87Sr/86Sr and low 143Nd/144Nd.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号