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1.
Ferrous granulites in the area of Tidjénouine (Central Hoggar) exhibit a remarkable mineralogical composition characterized by the association orthoferrossilite–fayalite–quartz. These granulites are metamorphosed mafic igneous rocks showing the juxtaposition of different metamorphic parageneses. Peak paragenesis with garnet–clinopyroxene–amphibole–plagioclase–quartz reach to assemblage with orthopyroxene–plagioclase2. Secondary orthopyroxene reacted with garnet to produce symplectites with fayalite + plagioclase + quartz. The latest stage corresponds to an orthopyroxene–fayalite–quartz–plagioclase assemblage. The metamorphic history of the ferrous granulites is inferred by combining the study of phase relations with the construction of a petrogenetic grid and pseudosection in the CFMASH and CFAS systems using the Thermocalc program of [J. Metamorph. Geol. 6 (1988) 173]. The evolution of paragenetic minerals indicates a metamorphic P–T path through the following conditions: 7.1 ± 1 kbar at 880 °C, 4.9 ± 1.6 kbar at 750 °C and 3–4 kbar at 700 °C, which is consistent with a clockwise P–T path recorded throughout the area.  相似文献   

2.
L. Millonig  A. Zeh  A. Gerdes  R. Klemd 《Lithos》2008,103(3-4):333-351
The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.  相似文献   

3.
Recent U–Pb age determinations and P–T estimates allow us to characterize the different levels of a formerly thickened crust, and provide further constraints on the make up and tectono-thermal evolution of the Grenville Province in the Manicouagan area. An important tectonic element, the Manicouagan Imbricate zone (MIZ), consists of mainly 1.65, 1.48 and 1.17 Ga igneous rocks metamorphosed under 1400–1800 MPa and 800–900 °C at 1.05–1.03 Ga, during the Ottawan episode of the Grenvillian orogenic cycle, coevally with intrusion of gabbro dykes in shear zones. The MIZ has been interpreted as representing thermally weakened deep levels of thickened crust extruded towards the NW over a parautochthonous crustal-scale ramp. Mantle-derived melts are considered as in part responsible for the high metamorphic temperatures that were registered.New data show that mid-crustal levels structurally above the MIZ are represented by the Gabriel Complex of the Berthé terrane, that consists of migmatite with boudins of 1136±15 Ma gabbro and rafts of anatectic metapelite with an inherited monazite age at 1478±30 Ma. These rocks were metamorphosed at about the same time as the MIZ (metamorphic zircon in gabbro: 1046±2 Ma; single grains of monazite in anatectic metapelite: 1053±2 Ma) and under the same T range (800–900 °C) but at lower P conditions (1000–1100 MPa). They are mainly exposed in an antiformal culmination above a high-strain zone, which has tectonic lenses of high P–T rocks from the MIZ and is intruded by synmetamorphic gabbroic rocks. This zone is interpreted as part of the hangingwall of the MIZ during extrusion. A gap of 400 MPa in metamorphic pressures between the tectonic lenses and the country rocks, together with the broad similarity in metamorphic ages, are consistent with rapid tectonic transport of the high P–T rocks over a ramp prior to the incorporation of the mafic lenses in the hangingwall.Between the antiformal culmination of the Gabriel Complex and the MIZ 1.48 Ga old granulites of the Hart Jaune terrane are exposed. They are intruded by unmetamorphosed 1228±3 Ma gabbro sills and 1166±1 Ma anorthosite. Hart Jaune Terrane represents relatively high crustal levels that truncate the MIZ-Gabriel Complex contact and are preserved in a synformal structure.Farther south, the Gabriel Complex is overlain by the Banded Complex, a composite unit including 1403+32/−25 Ma granodiorite and 1238+16/−13−1202+40/−25 Ma granite. This unit has been metamorphosed under relatively low-P (800 MPa) granulite-facies conditions. Metamorphic U–Pb data, limited to zircon lower intercept ages (971±38 Ma and 996±27 Ma) and a titanite (990±5 Ma) age, are interpreted to postdate the metamorphic peak.The general configuration of units along the section is consistent with extrusion of the MIZ during shortening and, finally, normal displacement along discrete shear zones.  相似文献   

4.
Located at western portion of northern margin of North China craton, the Baotou–Bayan Obo district is one of the most important Fe–REE–Nb and Au metallogenic provinces in China. Presently, about 52 gold deposits and prospects have been discovered, explored and mined, among which Shibaqinhao, Laoyanghao, Houshihua, Saiyinwusu, Wulashan and Donghuofang are the most important ones. All these gold occurrences can be subdivided into three groups (or types) according to its host rocks: (1) hosted by Archean high-grade metamorphic rocks; (2) hosted by Proterozoic sedimentary rocks; (3) hosted by or related to Hercynian alkaline intrusive rocks. The first group contains the Shibaqinhao, Laoyanghao and Houshihua gold deposits. Gold mineralization at these three deposits occurs within Archean amphibolite, gneiss and granulite as gold-bearing quartz veins and veinlet groups containing native gold, electrum, pyrite and chalcopyrite. The Saiyinwusu deposit belongs to the second group, and occurs within Proterozoic sandstone, quartzite and carbonaceous slate as quartz veins and replacement bodies along the fracture zones. Pyrite, marcasite, arsenopyrite, native gold and electrum are identified. The third group includes the Wulashan, Donghuofang and Luchang deposits. Gold mineralization at these three deposits occurs predominantly within the Hercynian alkaline syenite or melagabbro stocks and dyke swarms or along their contacts with Archean metamorphic wall rocks as K-feldspar–quartz veins, dissemination and veinlets. Pyrite, galena, chalcopyrite, native gold and calaverite are major metallic minerals.δ34S value of sulfides (pyrite, galena and pyrrhotite) separates from groups 1 and 2 varies from −4.01‰ to −0.10‰ and −3.01‰ to 2.32‰, respectively. δ34S values of Archean and Proterozoic metamorphic wall rocks for groups 1 and 2 deposits range from −20.2‰ to −17.0‰ and −15.8‰ to −16.2‰, respectively. The values are much lower than their hosted gold deposits. All these pyrite separates from Hercynian alkaline intrusions associated with the gold deposits show positive δ34S values of 1.3‰ to 4.8‰, which is higher than those Precambrian metamorphic wall rocks and their hosted gold deposits. δ34S values of the sulfides (pyrite and galena) from the Donghuofang and Wulashan deposits (group 3) increase systematically from veins (−14.8‰ to −2.4‰) to the Hercynian alkaline igneous wall rocks (2.8‰ to 4.8 ‰). All of these deposits in groups 1, 2 and 3 show relatively radiogenic lead isotopic compositions compared to mantle or lower crust curves. Most lead isotope data of sulfides from the gold ores plot between the Hercynian alkaline intrusions and Precambrian metamorphic wall rocks. Data are interpreted as indicative of a mixing of lead from mantle-derived alkaline magma with lead from Precambrian metamorphic wall rocks.Isotopic age data, geological and geochemical evidence suggest that the ore fluids for the groups 1 and 2 deposits were generated during the emplacement of the Hercynian alkaline syenite and mafic intrusions. The Hercynian alkaline magma may provide heat, volatiles and metals for these groups 1 and 2 deposits. Evolved metamorphic fluids produced by the devolatilization, which circulated the wall rocks, were also progressively involved in the alkaline magmatic hydrothermal system, and may have dominate the ore fluids during late stage of ore-forming processes. Most of these gold deposits hosted by Archean high-grade metamorphic rocks occur at or near the intersections of the NE- and E–W-trending fracture systems. The ore fluid of the group 3 deposits may have resulted from the mixing of Hercynian alkaline magmatic fluids and evolved meteoric waters. The deposits are believed to be products of Hercynian alkaline igneous processes along deep-seated fault zones within Archean terrain.  相似文献   

5.
In the W Hoggar (Algeria), the major transcurrent N–S East Ouzzal shear zone (EOSZ) hosts several world-class gold deposits over a 100-km length. The late Pan-African EOSZ separates two contrasting Precambrian domains: the Archaean In Ouzzal block to the west (orthogneisses with subordinate metasediments, reworked and granulitized in the c. 2 Ga Eburnean event) and a Middle Proterozoic block to the east (again orthogneisses and metasediments, involved in the c. 600 Ma Pan-African event). The EOSZ is a mylonite belt, 1–3 km wide, with a 50-m-wide ultramylonite belt hosting numerous quartz veins and lenses (giant hydrothermal quartz system) associated with a quartz-sericite-pyrite-carbonate (beresite) alteration. These hydrothermal events occurred under ductile (evolving towards brittle) conditions, between 500 and 300 MPa, at 500–300°C, with aqueous-carbonic fluids derived both from underlying devolatilized metamorphic rocks and a mantle source, as recorded by stable (C, O) isotope data. No gold mineralization was associated with these typical mesothermal events. Following a pressure drop (to 130 MPa), related to the inception of extensional tectonics, the EOSZ was later percolated by a new set of hydrothermal fluids, evolved from basinal waters that deeply penetrated into the In Ouzzal basement. These fluids were Ca-bearing brines (up to 25% wt. eq. NaCl), characterized by high δD (-9 to + 18‰ range), mobilized by the thermal energy released by the late Pan-African granite magmatism (Taourirt granites). As demonstrated by Pb isotope data, the brines leached Au from the In Ouzzal granulites (which contain 3 ppb Au). Fluid inclusion studies indicate that gold was deposited from these brines in the EOSZ at a depth of c. 5 km, due to mixing and cooling with descending diluted fluids.  相似文献   

6.
In the Sanandaj-Sirjan zone of metamorphic belt of Iran, the area south of Hamadan city comprises of metamorphic rocks, granitic batholith with pegmatites and quartz veins. Alvand batholith is emplaced into metasediments of early Mesozoic age. Fluid inclusions have been studied using microthermometry to evaluate the source of fluids from which quartz veins and pegmatites formed to investigate the possible relation between host rocks of pegmatites and the fluid inclusion types. Host minerals of fluid inclusions in pegmatites are quartz, andalusite and tourmaline. Fluid inclusions can be classified into four types. Type 1 inclusions are high salinity aqueous fluids (NaCleq >12 wt%). Type 2 inclusions are low to moderate salinity (NaCleq <12 wt%) aqueous fluids. Type 3 and 4 inclusions are carbonic and mixed CO2-H2O fluid inclusions. The distribution of fluid inclusions indicate that type 1 and type 2 inclusions are present in the pegmatites and quartz veins respectively in the Alvand batholith. This would imply that aqueous magmatic fluids with no detectable CO2 were present during the crystallization of these pegmatites and quartz veins. Types 3 and 4 inclusions are common in quartz veins and pegmatites in metamorphic rocks and are more abundant in the hornfelses. The distribution of the different types of fluid inclusions suggests that CO2 fluids generated during metamorphism and metamorphic fluids might also contribute to the formation of quartz veins and pegmatites in metamorphic terrains.  相似文献   

7.
We report for the first time the evidence for prograde high-pressure (HP) metamorphism preceding a peak ultrahigh-temperature (UHT) event in the northernmost part of the Madurai Block in southern India. Mg–Al-rich Grt–Ged rocks from Komateri in Karur district contain poikiloblastic garnet with numerous multi-phase inclusions. Although most of the inclusion assemblages are composed of gedrite, quartz, and secondary biotite, rare staurolite + sapphirine and spinel + quartz are also present. The XMg (=Mg/[Fe+Mg]) of staurolite (0.45–0.49) is almost consistent with that reported previously from Namakkal district in the Palghat–Cauvery Shear Zone system (XMg = 0.51–0.52), north of the Madurai Block. The HP event was followed by peak UHT metamorphism at T = 880–1040 °C and P = 9.8–12.5 kbar as indicated by thermobarometric computations in the Grt–Ged rock and associated mafic granulite. Symplectic intergrowth of spinel (XMg = 0.50–0.59, ZnO < 1.7 wt.%) and quartz, a diagnostic indicator of UHT metamorphism, probably formed by decompression at UHT conditions. The rocks subsequently underwent retrograde metamorphism at T = 720–760 °C and P = 4.2–5.1 kbar. The P–T conditions and clockwise exhumation trajectory of the Komateri rocks, comparable to similar features recorded from the Palghat–Cauvery Shear Zone system, suggest that the Madurai Block and the Palghat–Cauvery Shear Zone system underwent similar HP and UHT metamorphic history probably related to the continent–continent collision during the final stage of amalgamation of Gondwana supercontinent.  相似文献   

8.
Gold mineralization at Jonnagiri, Dharwar Craton, southern India, is hosted in laminated quartz veins within sheared granodiorite that occur with other rock units, typical of Archean greenstone–granite ensembles. The proximal alteration assemblage comprises of muscovite, plagioclase, and chlorite with minor biotite (and carbonate), which is distinctive of low- to mid-greenschist facies. The laminated quartz veins that constitute the inner alteration zone, contain muscovite, chlorite, albite and calcite. Using various calibrations, chlorite compositions in the inner and proximal zones yielded comparable temperature ranges of 263 to 323 °C and 268 to 324 °C, respectively. Gold occurs in the laminated quartz veins both as free-milling native metal and enclosed within sulfides. Fluid inclusion microthermometry and Raman spectroscopy in quartz veins within the sheared granodiorite in the proximal zone and laminated auriferous quartz veins in inner zone reveal the existence of a metamorphogenic aqueous–gaseous (H2O–CO2–CH4 + salt) fluid that underwent phase separation and gave rise to gaseous (CO2–CH4), low saline (~ 5 wt.% NaCl equiv.) aqueous fluids. Quartz veins within the mylonitized granodiorites and the laminated veins show broad similarity in fluid compositions and P–T regime. Although the estimated P–T range (1.39 to 2.57 kbar at 263 to 323 °C) compare well with the published P–T values of other orogenic gold deposits in general, considerable pressure fluctuation characterize gold mineralization at Jonnagiri. Factors such as fluid phase separation and fluid–rock interaction, along with a decrease in f(O2), were collectively responsible for gold precipitation, from an initial low-saline metamorphogenic fluid. Comparison of the Jonnagiri ore fluid with other lode gold deposits in the Dharwar Craton and major granitoid-hosted gold deposits in Australia and Canada confirms that fluids of low saline aqueous–carbonic composition with metamorphic parentage played the most dominant role in the formation of the Archean lode gold systems.  相似文献   

9.
The Gemericum is a segment of the Variscan orogen subsequently deformed by the Alpine–Carpathian orogeny. The unit contains abundant siderite–sulphide and quartz–antimony veins together with stratabound siderite replacement deposits in limestones and stratiform sulphide mineralization in volcano-sedimentary sequences. The siderite–sulphide veins and siderite replacement deposits of the Gemericum represent one of the largest accumulations of siderite in the world, with about 160 million tonnes of mineable FeCO3. More than 1200 steeply dipping hydrothermal veins are arranged in a regional tectonic and compositional pattern, reflecting the distribution of regional metamorphic zones. Siderite–sulphide veins are typically contained in low-grade (chlorite zone) sedimentary, volcano-sedimentary or volcanic Lower and Upper Paleozoic rocks. Quartz–antimony veins are hosted by higher-grade units (biotite zone). Siderite–sulphide veins are dominated by early siderite followed by a complex set of stages, including quartz–sulphide (chalcopyrite, tetrahedrite), barite, tourmaline–quartz, and sulphide-remobilization stages. The temporal evolution of these stages is difficult to study because of the widespread and repeated tectonic processes, within-vein replacement and recrystallization. Siderite–sulphide veins show considerable vertical (up to 1200 m) and lateral (up to 15 km) extent, and a thickness typically reaching several metres. Carbonate-replacement siderite deposits of the Gemericum are hosted by a Silurian limestone belt and are similar to stratabound siderite deposits of the Eastern Alps (e.g., Erzberg, Austria).Based on a review of geological, petrological and geochronological data for the Gemericum, and extensive stable and radiogenic isotope data and fluid inclusion data on hydrothermal minerals, the siderite–sulphide veins and siderite replacement deposits are classified as metamorphogenic in a broad sense. The deposits were formed during several stages of regional crustal-scale fluid flow. Isotope (S, C, Sr, Pb) fingerprinting identifies the metamorphosed rock complexes of the Gemericum as a source of most components of hydrothermal fluids. Fluid inclusion and stable isotope data evidence the participation of several contrasting fluid types, and the existence of contrasting P–T conditions during vein evolution. A high-δ18O, medium- to high-salinity, H2O-type fluid is the most important component during siderite deposition, whereas H2O–CO2-type fluid inclusion containing dense liquid CO2 and corresponding to minimal pressures between 1 and 3 kbar were found in a younger tourmaline–quartz stage. Younger quartz–ankerite(±siderite)–sulphide stages are characterized by high-salinity (17 to 35 wt.% NaCl equivalent) and low-temperature (Th=90 to 180 °C) H2O-type fluids.The vein deposits are interpreted as a result of multistage hydrothermal circulation, with Variscan and Alpine mineralization phases. Based on available indirect data, the most important mineralization phase was related to regional fluid flow during the uplift of a Variscan metamorphic core complex, producing siderite–sulphide (±barite) mineralization, while tourmaline–quartz stage and sulphide remobilization stages are related to Alpine processes. Two phases of vein evolution are evident from two groups of 87Sr/86Sr isotope ratios of Sr-rich, Rb-poor hydrothermal minerals: 0.71042–0.71541 in older barite and 0.7190–0.7220 in late-stage celestine and strontianite.  相似文献   

10.
This paper reports a study of the metamorphic evolution of pelitic, semi-pelitic migmatites and mafic granulites of the Chafalote Metamorphic Suite (CMS), Uruguay, which represents the southernmost exposures of high-grade metamorphic rocks in the Dom Feliciano Belt, Uruguain—Sul-Rio-Grandense shield, South America. This belt is one of the Brasiliano orogens that crop out along the Brazilian and Uruguayan Atlantic margin, and the CMS is one of several disconnected segments of supracrustal rock in a dominantly granitic terrain. Petrological evidence from CMS mafic granulites and semi-pelitic migmatites indicates four distinct metamorphic assemblages. The early prograde assemblage (M1) is preserved only as inclusions in porphyroblasts of the peak-metamorphic (M2) assemblage. Peak-metamorphism was followed by near-isothermal decompression (M3), which resulted in symplectites and coronitic textures in the mafic granulites and compositional zoning of Ca in garnet (decreasing rimwards) and plagioclase (increasing rimwards) in the semi-pelitic migmatites. The retrograde metamorphic assemblage (M4) is represented by hydration reaction textures replacing minerals of the M2 and M3 assemblages. Average P–T calculations using the program THERMOCALC and conventional thermobarometric methods yield peak-metamorphic (M2) P–T conditions of 7–10 kbar and 830–950 °C, near-decompressional (M3) P–T conditions of 4.8–5.5 kbar and 788–830 °C and M4 retrograde P–T conditions of 3–6 kbar and 600–750 °C. The calculated P–T path for the CMS rocks is ‘clockwise’ and incorporates a near-isothermal decompression segment followed by minor cooling, consistent with a history of crustal thickening followed by extensional collapse at ca. 650–600 Ma. The metamorphism recorded by rocks of this crustal segment may be correlated with 650 Ma metamorphism in the Coastal Terrane of the Kaoko Belt in Namibia, being the first unequivocal match between South America and Africa provided by crystalline rocks south of the Congo Craton.  相似文献   

11.
The metamorphic evolution of a key sector of the western Mediterranean internal Alpine orogenic belt (southern Calabrian Peloritani Orogen) is identified and described by means of P–T pseudosections calculated for selected metapelite specimens, showing evidence of multi-stage metamorphism.Attention focused on the two lowermost basement nappes of the Aspromonte Massif (southern Calabria), which were differently affected by poly-orogenic multi-stage evolution. After a complete Variscan orogenic cycle, the upper unit (Aspromonte Peloritani Unit) was involved in a late-Alpine shearing event. In contrast, the several underlying metapelite slices, here grouped together as Lower Metapelite Group, show exclusive evidence of a complete Alpine orogenic cycle.In order to obtain reliable P–T constraints, an integrated approach was employed, based on: a) garnet isopleth thermobarometry; and b) theoretical predictions of the P–T stability fields of representative equilibrium assemblages. This approach, which takes into account the role of the local equilibrium volumes in controlling textural developments, yielded reliable information about P–T conditions from early to peak metamorphic stages, as well as estimates of the retrograde trajectory in the pseudosection P–T space.According to inferred detailed P–T paths, the evolution of the Aspromonte Peloritani Unit is characterised by a multi-stage Variscan cycle, subdivided into an early crustal thickening stage with P–T conditions ranging from 0.56 ± 0.05 GPa at 570 ± 10 °C to 0.63–0.93 GPa at 650–710 °C (peak conditions) and evolving to a later crustal thinning episode in lower P–T conditions (0.25 GPa at 540 °C), as documented by the retrograde trajectory.Conversely, the prograde evolution of the rocks of the Lower Metapelite Group shows evidence of a HP-LT early Alpine multi-stage cycle, with P–T evolving from 0.75–0.90 GPa at 510–530 °C towards peak conditions, with pressure increasing northwards from 1.12 ± 0.02 GPa to 1.24 ± 0.02 GPa, and temperatures of 540–570 °C.A late-Alpine mylonitic overprint affected the rocks of both the Aspromonte Peloritani Unit and the Lower Metapelite Group. This overprint was characterised by an initial retrograde decompression trajectory (0.75 ± 0.05 GPa at 570–600 °C), followed by a joint cooling history, ranging from 0.38 ± 0.14 at temperature from 450 to 520 °C.These inferred results were then used: a) to interpret the Lower Metapelite Group as a single crystalline basement unit exclusively affected by a complete Alpine orogenic cycle, according to the very similar features of P–T paths, comparable petrography and analogous structural characteristics; b) as a tool for more reliable correlations between the Aspromonte Massif, the other Calabrian terranes and the north African Orogenic Complexes. They may therefore consider a contribution to the geodynamic modelling of the western Mediterranean.  相似文献   

12.
Metamorphic rocks in the Osor complex (Guilleries massif, NE Iberian Peninsula) show the following structural and compositional features: strong differentiation into quartz-rich gneissic semipelitic and quartz-absent, mica-rich schistose bands, higher density of igneous (both basic and leucogranitic) and quartz veins in the schistose domains and strong strain partitioning in the pelitic bands. Garnet is present in both kinds of lithologies, showing also differential textural and chemical features interpreted to be dependent on bulk composition, deformation and fluid interaction histories. Textures, mineral composition and thermobarometry suggest the operation of concurrent mechanical, mass transfer and thermal phenomena such as: (1) variations in strain style, (2) fluid infiltration, (3) magmatic injection and (4) HT–LP metamorphic and metasomatic episodes. The following sequence of events is suggested: initially the cooling of syntectonic high-T basic quartz diorite sheets promoted high strain rates, low dP/dT thermobaric evolution, incipient anatexis in the pelitic bands and devolatilization through a pervasive to vein-channelized prograde fluid flow. The prograde flow enhanced an ongoing compositional tectono-metamorphic differentiation and produced metasomatism through depletion of the Osor rocks in alkalis and calcium. Later injection and cooling of peraluminous leucogranitoid sheets, preferentially along pelitic bands, increased the ratio of magmatic/metamorphic components in the fluids and strongly enriched them in alkalis producing a second metasomatic episode. During crystallization of quartz and leucogranitoid veins, the pelitic bands were strongly enriched back again in alkalis, promoting the blastesis of big crystals of post-peak muscovite and albite as well as the retrogression of garnet. The metasomatic mica-rich levels must have been the preferred locus for development of a new deformation style dominated by shear band fabrics in metapelites and related to a release of the gravitational instability originated previously due to crustal thickening. The increasing decompressional component of the retrograde P–T path also suggests that this style of deformation was prevalent during, if not responsible for, a phase of exhumation of the metamorphic complex. It is suggested that similar patterns of thermomechanical and mass transfer phenomena could well be a fundamental characteristic common to all HT–LP metamorphic belts.  相似文献   

13.
This investigation presents and interprets fluid inclusion data from different lithological units of the Cu skarn deposits at Mazraeh, north of Ahar, Azarbaijan, NW Iran. The results provide an assessment of the P–T conditions and mineral–fluid evolution and suggest new exploration parameters. Five types of inclusions are recognized from quartz and garnet. The temperature of homogenization of Type I inclusions with daughter minerals halite and sylvite ranges from 312° to 470 °C with total salinity of 52 to 63 wt.% NaCl equiv.; Type II and III inclusions with halite have homogenization temperatures of 230° to 520 °C and salinity of 31 to 50 wt.% NaCl equiv. The salinity of Types IV and V biphase (liquid + vapor) inclusions, based on their final ice melting temperature, varies between 10.2 to 20.8 wt.% NaCl equiv. Th vs. salinity plots of inclusions show that the salinity of the fluids correlates positively with temperature. The inclusions formed at low pressure. Changes in the temperature and salinity of the fluids can be reconstructed from the inclusions. Highly saline, high-temperature fluids were most abundant during the main chalcopyrite ore-forming phase in the skarn and mineralized quartz veins. Low-salinity aqueous fluids were abundant in barren veins, in which there is no evidence for early hot high-salinity brine, and might have resulted from late-stage dilution and mixing of hydrothermal fluids with meteoric water. Based on petrographic features and fluid-inclusion data, early-stage magnetite deposition is related to boiling of fluid at temperatures of about 500 °C. At a later stage, boiling at temperatures of around 320° to 400 °C favored the deposition of sulfides and Fe mobility was decreased at these lower temperatures. The following inclusion characteristics may be used as exploration parameters in the Mazraeh area. (i) Presence of high-temperature, salt-bearing inclusions, with Th between 300 and 500 °C; (ii) High-salinity fluid inclusions; and (iii) Inclusions showing evidence of boiling of the fluid. In addition, the presence of magnetite is an important exploration parameter.  相似文献   

14.
 Petrologic and oxygen isotope data indicate that water-rich fluids infiltrated metasedimentary rocks of the Waterville and Sangerville (formally Vassalboro) Formations, south-central Maine, during peak metamorphism, and depleted Sangerville rocks in alkalis but not equivalent Waterville rocks. Fluid inclusion data from two outcrops, ∼1 km apart, one of the Waterville and the other of the Sangerville Formations, suggest a cause for the geochemical difference between the two units. Postulated peak metamorphic inclusions, the texturally earliest of aqueous inclusions in the metasediments, approximate the water-rich compositions of peak fluids predicted by mineral-fluid equilibria, and have average salinity in the Sangerville Formation ∼ three times that of equivalent Waterville inclusions. The higher salinity in the Sangerville fluids could explain the greater alkali depletion in these rocks. Probable pre-peak or prograde inclusions are preserved in metasediments as the texturally earliest carbonic inclusions which contain CO2, CH4, N2±H2O, as determined by microthermometry and Raman spectrometry. They may have formed by breakdown of organic matter. Probable retrograde inclusions occur as texturally late aqueous inclusions in healed fractures with salinity ranges indistinguishable between the two formations. Synmetamorphic granitic dikes present in the two outcrops were ruled out as a source for fluids in metasediments because composition and density ranges of inclusions in dikes and metasediments are fundamentally different, and because there is no correlation between the abundance or composition of inclusions in a sample and proximity to dikes. Isochores for many of the inclusions in both metasediments and dikes are not consistent with the inferred P−T conditions of their trapping, but intersect at ∼300° to 400° C and 1 to 2 kbar. The intersections probably resulted because inclusion densities continued to equilibrate during uplift and cooling until quartz became rigid. The present densities are those at the last equilibration, not the time of trapping. In contrast, the clear distinctions in inclusion compositions between dikes and between dike and country rock show that the original compositional differences generally have been preserved. Received: 4 February 1994 / Accepted: 22 June 1994  相似文献   

15.
Application of hornblende thermobarometry and fluid inclusion studies to the Palaeoproterozoic (1.7 Ga) basement rocks from Maddhapara, NW Bangladesh, provide information on the pressure and temperature (P–T) conditions of crystallization, the emplacement depth and composition of magmatic fluid. The basement rocks are predominantly diorite or quartz diorite with a mineral assemblage of plagioclase, hornblende, biotite, quartz, K-feldspar, titanite, and secondary epidote and chlorite. The calculated P–T conditions of the dioritic rocks are 680–725 °C and 4.9–6.4 kbar, which probably correspond to crystallization conditions. Fluid inclusion studies suggest that low- to medium-salinity (0–6.4 wt.% NaCleq) H2O-rich fluids are trapped during the crystallization of quartz and plagioclase. The isochore range calculated for primary aqueous inclusions is consistent with the P–T condition obtained by geothermobarometry. The basement rocks likely crystallized at a depth of 17–22 km, with a minimum average exhumation rate of 12–15 m/Ma during Palaeoproterozoic to Lopingian time. Such slow exhumation indicates low relief continental shield surface during this period.  相似文献   

16.
The western terranes exposed east of the Pan-African suture in western Hoggar (southwest Algeria), are reexamined in the light of new structural, petrologic and by the 40Ar/39Ar laser probe data on metamorphic micas and amphiboles. To the north, the Tassendjanet nappe includes the Paleoproterozoic basement, its Mesoproterozoic cover and mafic rocks representing the roots of a ca. 680 Ma arc overlain by Late Neoproterozoic andesites and volcanic greywackes. The nappe preserved at rather shallow crustal level in the east was emplaced southward (D1a) to southeastward (D2). In the south, two metamorphic suites are distinguished. The Tideridjaouine–Tileouine high-pressure metamorphic belt (T=550–600 °C, P=1.4–1.8 GPa) represents a slab of subducted continental material exposed along the western edge of the In Ouzzal granulite unit interpreted as a microcontinent. Differential exhumation of tectonic slices from the high-pressure belt occurred around 615–600 Ma through a system of west-directed recumbent folds (D1b). The Egatalis high grade belt in the west was intruded by syn-metamorphic gabbro–norite bodies. It includes unretrogressed low-pressure granulite facies rocks (T around 750–800 °C, P0.45 GPa) cooled at a rate of 15°/m.y. between 600 and 580 Ma, and followed by the emplacement of several late-kinematic granitic plutons. Final exhumation of the low-pressure, high-temperature metamorphic rocks, that are not found as pebbles in the molasse, took place in the Late Cambrian. The early and relatively fast cooling of the high-pressure and high-temperature metamorphic rocks of the southern part of the Tassendjanet terrane is at variance with the slow cooling of central Hoggar where repeated magmatic activity as young as Late Cambrian occurred [Lithos 45 (1998) 245].  相似文献   

17.
New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (TDM model ages of 1.54–1.78 Ga; εNd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show εNd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.  相似文献   

18.
Tin-polymetallic greisen-type deposits in the Itu Rapakivi Province and Rondônia Tin Province, Brazil are associated with late-stage rapakivi fluorine-rich peraluminous alkali-feldspar granites. These granites contain topaz and/or muscovite or zinnwaldite and have geochemical characteristics comparable to the low-P sub-type topaz-bearing granites. Stockworks and veins are common in Oriente Novo (Rondônia Tin Province) and Correas (Itu Rapakivi Province) deposits, but in the Santa Bárbara deposit (Rondônia Tin Province) a preserved cupola with associated bed-like greisen is predominant. The contrasting mineralization styles reflect different depths of formation, spatial relationship to tin granites, and different wall rock/fluid proportions. The deposits contain a similar rare-metal suite that includes Sn (±W, ±Ta, ±Nb), and base-metal suite (Zn–Cu–Pb) is present only in Correas deposit. The early fluid inclusions of the Correas and Oriente Novo deposits are (1) low to moderate-salinity (0–19 wt.% NaCl eq.) CO2-bearing aqueous fluids homogenizing at 245–450 °C, and (2) aqueous solutions with low CO2, low to moderate salinity (0–14 wt.% NaCl eq.), which homogenize between 100 and 340 °C. In the Santa Bárbara deposit, the early inclusions are represented by (1) low-salinity (5–12 wt.% NaCl eq.) aqueous fluids with variable CO2 contents, homogenizing at 340 to 390 °C, and (2) low-salinity (0–3 wt.% NaCl eq.) aqueous fluid inclusions, which homogenize at 320–380 °C. Cassiterite, wolframite, columbite–tantalite, scheelite, and sulfide assemblages accompany these fluids. The late fluid in the Oriente Novo and Correas deposit was a low-salinity (0–6 wt.% NaCl eq.) CO2-free aqueous solution, which homogenizes at (100–260 °C) and characterizes the sulfide–fluorite–sericite association in the Correas deposit. The late fluid in the Santa Bárbara deposit has lower salinity (0–3 wt.% NaCl eq.) and characterizes the late-barren-quartz, muscovite and kaolinite veins. Oxygen isotope thermometry coupled with fluid inclusion data suggest hydrothermal activity at 240–450 °C, and 1.0–2.6 kbar fluid pressure at Correas and Oriente Novo. The hydrogen isotope composition of breccia-greisen, stockwork, and vein fluids (δ18Oquartz from 9.9‰ to 10.9‰, δDH2O from 4.13‰ to 6.95‰) is consistent with a fluid that was in equilibrium with granite at temperatures from 450 to 240 °C. In the Santa Bárbara deposit, the inferred temperatures for quartz-pods and bed-like greisens are much higher (570 and 500 °C, respectively), and that for the cassiterite-quartz-veins is 415 °C. The oxygen and hydrogen isotope composition of greisen and quartz-pods fluids (δ18Oqtz-H2O=5.5–6.1‰) indicate that the fluid equilibrated with the albite granite, consistent with a magmatic origin. The values for mica (δ18Omica-H2O=3.3–9.8‰) suggest mixing with meteoric water. Late muscovite veins (δ18Oqtz-H2O=−6.4‰) and late quartz (δ18Omica-H2O=−3.8‰) indicate involvement of a meteoric fluid. Overall, the stable isotope and fluid inclusion data imply three fluid types: (1) an early orthomagmatic fluid, which equilibrated with granite; (2) a mixed orthomagmatic-meteoric fluid; and (3) a late hydrothermal meteoric fluid. The first two were responsible for cassiterite, wolframite, and minor columbite–tantalite precipitation. Change in the redox conditions related to mixing of magmatic and meteoric fluids favored important sulfide mineralization in the Correas deposit.  相似文献   

19.
The metamorphic evolution of dolomitic marbles and associated calc-silicate rocks from Punta Tota (NE Tandilia belt, Buenos Aires province, Argentina) has been evaluated through petrographic, geothermobarometric, and fluid inclusion studies. Thin beds of dolomitic marble are intercalated in amphibolites and constitute the upper part of a stratified basement sequence, which starts at the base with garnet migmatites showing a great abundance of pegmatitic segregates, overlain by biotite–garnet gneisses. Peak metamorphic conditions are estimated at 750–800 °C and 5–6 kb, followed by near isobaric cooling to about 500–450 °C and 5.5–6.5 kb. Anhydrous progressive metamorphic assemblages in both marbles (Fo + Cal + Dol + Cpx + Spl) and adjacent calc-silicate rocks (Cpx + An + Cal + Qtz) strongly retrogressed to hydrous minerals (Tr, Tlc, Grs, Czo, Srp) with decreasing temperatures and increasing water activities. The intense rehydration of the rocks relates to the emplacement of volatile-rich pegmatitic bodies (Qtz + Pl + Kfs + Bt + Grt), which also resulted in the crystallization of clinochlore + phlogopite in the marble and biotite + muscovite in the adjacent calc-silicate rocks. Metamorphic reactions based on textural relations and evaluated on a suitable petrogenetic grid, combined with geothermobarometric results and fluid inclusion isochores, indicate a metamorphic evolution along a counterclockwise P–T path. Two probable geotectonic settings for the determined P–T trajectory are proposed: (1) thinning of the crust and overlying supracrustal basin in an ensialic intraplate tectonic setting and (2) development of a marginal back-arc basin, associated with an oceanic–continental convergent plate margin. In both models, the initial extensional regime is followed by a compressional stage, with overthickening of the basement and supracrustal rocks, during the climax of the Transamazonian cycle at approximately 1800 Ma ago. Continuous convergence and blockage of structures produce transition to transcurrent tectonics (transpression) with a consequent moderate uplift.  相似文献   

20.
The spinel–quartz-bearing Al–Fe granulites from Ihouhaouene (In Ouzzal, West Hoggar) have a migmatitic appearance with quartzo-feldspathic layers intercalated with restitic layers. These granulites are characterized by a hercynitic spinel–quartz assemblage typical of high grade terranes. The stability of the spinel–quartz assemblage is attributed to an elevation of temperature (from 800 to >1100 °C) at high pressures (10–11 kbar), followed by an isothermal decompression from 9 to 5 kbar, an evolution typical of the In Ouzzal clockwise P–T path. The Al–Fe granulites’ history can be subdivided into different successive crystallisation stages. During the first stage, the spinel–quartz assemblage formed, probably following a prograde event that also produced partial melting. During a second stage, the primary spinel–garnet–sillimanite–quartz paragenesis broke-down to give rise to the secondary assemblage. The metamorphic evolution and phase relations during this stage are shown in P–T–X pseudosections calculated for the simple FMASH system. These pseudosections show that the orthopyroxene–cordierite–spinel symplectite appeared during a high temperature decompression, as a product of destabilisation of garnet in sillimanite-free microdomains with high XMg values. At the same time, the spinel–quartz association broke-down into cordierite in Fe-rich microdomains. Average pressure and temperature estimates for the orthopyroxene–spinel–garnet–cordierite–quartz association are close to the thermal peak of metamorphism (1000 ± 116 °C at 6.3 ± 0.5 kbar). With decreasing temperatures garnet–sillimanite corona developed from the breakdown of the primary spinel–quartz assemblage in the Fe-rich microdomains, whereas cordierite–spinel formed at the expense of primary sillimanite and garnet in the Mg-rich microdomains.  相似文献   

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