共查询到20条相似文献，搜索用时 31 毫秒
1.
Nina Daneu Aleksander Rečnik Takashi Yamazaki Tadej Dolenec 《Physics and Chemistry of Minerals》2007,34(4):233-247
The atomic scale structure and chemistry of (111) twins in MgAl2O4 spinel crystals from the Pinpyit locality near Mogok (Myanmar, formerly Burma) were analysed using complementary methods
of transmission electron microscopy (TEM). To obtain a three-dimensional information on the atomic structure, the twin boundaries
were investigated in crystallographic projections
and
Using conventional electron diffraction and high-resolution TEM (HRTEM) analysis we have shown that (111) twins in spinel
can be crystallographically described by 180° rotation of the oxygen sublattice normal to the twin composition plane. This
operation generates a local hcp stacking in otherwise ccp lattice and maintains a regular sequence of kagome and mixed layers. In addition to rotation, no other translations are present
in (111) twins in these spinel crystals. Chemical analysis of the twin boundary was performed by energy-dispersive X-ray spectroscopy
(EDS) using a variable beam diameter (VBD) technique, which is perfectly suited for analysing chemical composition of twin
boundaries on a sub-nm scale. The VBD/EDS measurements indicated that (111) twin boundary in spinel is Mg-deficient. Quantitative
analyses of HRTEM (phase contrast) and HAADF-STEM (Z-contrast) images of (111) twin boundary have confirmed that Mg2+ ions are replaced with Be2+ ions in boundary tetrahedral sites. The Be-rich twin boundary structure is closely related to BeAl2O4 (chrysoberyl) and BeMg3Al8O16 (taaffeite) group of intermediate polysomatic minerals. Based on these results, we conclude that the formation of (111) twins
in spinel is a preparatory stage of polytype/polysome formation (taaffeite) and is a result of thermodynamically favourable
formation of hcp stacking due to Be incorporation on the {111} planes of the spinel structure in the nucleation stage of crystal growth. The
twin structure grows as long as the surrounding geochemical conditions allow its formation. The incorporation of Be induces
a 2D-anisotropy and exaggerated growth of the crystal along the (111) twin boundary. 相似文献
2.
T.L. Daulton T.J. Bernatowicz S. Messenger S. Amari 《Geochimica et cosmochimica acta》2003,67(24):4743-4767
Silicon carbide (SiC) is a particularly interesting species of presolar grain because it is known to form on the order of a hundred different polytypes in the laboratory, and the formation of a particular polytype is sensitive to growth conditions. Astronomical evidence for the formation of SiC in expanding circumstellar atmospheres of asymptotic giant branch (AGB) carbon stars is provided by infrared (IR) studies. However, identification of the crystallographic structure of SiC from IR spectra is controversial. Since >95% of the presolar SiC isolated from meteorites formed around carbon stars, a determination of the structure of presolar SiC is, to first order, a direct determination of the structure of circumstellar SiC. We therefore determined the polytype distribution of presolar SiC from the Murchison CM2 carbonaceous meteorite using analytical and high-resolution transmission electron microscopy (TEM). High-resolution lattice images and electron diffraction of 508 individual SiC grains demonstrate that only two polytypes are present, the cubic 3C (β-SiC) polytype (79.4% of population by number) and the hexagonal 2H (α-SiC) polytype (2.7%). Intergrowths of these two polytypes are relatively abundant (17.1%). No other polytypes were found. A small population of one-dimensionally disordered SiC grains (0.9%), whose high density of stacking faults precluded classification as any polytype, was also observed. The presolar origin of 2H α-SiC is unambiguously established by tens-of-nanometers-resolution secondary ion mass spectroscopy (NanoSIMS). Isotopic maps of a TEM-characterized 2H α-SiC grain exhibit non-solar isotopic compositions of 12C/13C = 64 ± 4 and 14N/15N = 575 ± 24. These measurements are consistent with mainstream presolar SiC thought to originate in the expanding atmospheres of AGB carbon stars. Equilibrium condensation calculations together with inferred mineral condensation sequences predict relatively low SiC condensation temperatures in carbon stars. The laboratory observed condensation temperatures of 2H and 3C SiC are generally the lowest of all SiC polytypes and fall within the predictions of the equilibrium calculations. These points account for the occurrence of only 2H and 3C polytypes of SiC in circumstellar outflows. The 2H and 3C SiC polytypes presumably condense at different radii (i.e., temperatures) in the expanding stellar atmospheres of AGB carbon stars. 相似文献
3.
Fine textures of exsolution lamellae and interface boundaries between augite and pigeonite in augite crystals from Skaergaard ferrogabbro 4430 have been studied by high resolution electron microscopy and X-ray methods. Thick pigeonite lamellae have higher densities of (100) stacking faults than thin lamellae. The displacement vector of the faults has been determined as 5/6c from the measured density of faults and the relative rotation of the augite and pigeonite lattices. The augite and pigeonite lattices are apparently coherent, and no growth ledges were observed at the interfaces. The stacking faults are often combined with the antiphase boundary of pigeonite resulting in a total displacement vector of 1/2(a+b)+5/6c. The observation of thick and thin pigeonite lamellae indicated that the thickening of (001) pigeonite lamellae was controlled by coherency strains accumulated at the interfaces between augite and pigeonite. 相似文献
4.
J. Ingrin 《Physics and Chemistry of Minerals》1993,20(1):56-62
A study of polytypism in synthetic polycrystalline pseudowollastonite has been made using conventional and high resolution transmission electron microscopy (TEM and HRTEM). Three polytypes of 2, 4 and 6-layers coexist in the one sample in the form of lamellae parallel to (001). From the electron microscopy images the lamellae are interpreted as combinations of the stacking fault vectors: 1/3 [010], 1/6 [310] and 1/6 [3 $\bar 1$ 0], which are probably all equivalent at high temperatures. The polytype lamellae are stable even after prolonged annealing at high temperatures greater than 1700K. These observations suggest that the most frequently reported 4-layer polytype is not the only high-temperature stable polytype. No evidence of melt is detected in samples annealed in the regime where premelting behaviour of pseudowollastonite has previously been reported (above 1600 K). 相似文献
5.
根据HRTEM研究，在四川西昌地区的钙稀土氟碳酸盐矿物衍生多晶体中发现了四种不同的B10S8型[即氟碳怖矿（B）／直氟碳钙铈矿（S）为10：8]新规则混层矿物（B10S8－I，B10S8－Ⅱ，B10S8-Ⅱ和B10S8－Ⅳ）。用SAED和HREM方法确定了四种新规则混层矿物的晶体结构对称性、晶胞参数、结构堆垛模式及晶体化学式等。四种B10S8新规则混层矿物结构中，Ce－F离子层的堆垛层序以及两个Ce－F离子层之间的碳酸根离子层的排列方式均不同。同时还观察到该类矿物中的畸结构及堆垛层错等。 相似文献
6.
The characteristic lamellar-twinning of the right-handed (R) and left-handed (L) structures in the major rhombohedral growth sectors of amethyst quartz has been studied by optical techniques, X-ray topography and transmission electron microscopy (TEM). The TEM observations show that the region of each Brewster fringe consists of fine-scale Brazil twin lamellae parallel to one of the r, z{10 \(\overline {\text{1}} \) 1} planes, and structural considerations suggest that it is one of the r-planes. The twin boundary corresponding to a Brewster fringe has the form of a zig-zag structure consisting of Brazil twin boundaries on two r{10 \(\overline {\text{1}} \) 1} planes, with one predominating. The Brewster fringes appear black between crossed polarizers because light travelling along the optic axis [001] passes through almost equal distances of R and L quartz, giving essentially zero optical rotation. From the visibility of the Brazil twin boundaries in electron micrographs and the visibility of the Brewster fringes in X-ray topographs, the fault vector R and the corresponding composition plane of the major Brazil twin associated with each Brewster fringe has been determined. The streaking of the Brewster fringes observed optically and in the X-ray topographs appears to be due to the stair-rod dislocations at the intersections of the Brazil twin boundaries. Experiments in which synthetic quartz was grown hydrothermally on untwinned seeds and on twinned amethyst seeds showed that the initiation of Brazil twins and the development of Brewster fringes was dependent upon the presence of iron in the growth solution. 相似文献
7.
Grain boundaries influence many physical and chemical properties of crystalline materials. Here, we perform molecular dynamics simulations to study the structure of a series of [100] symmetric tilt grain boundaries in Mg2SiO4 forsterite. The present results show that grain boundary energies depend significantly on misorientation angle. For small misorientation angles (up to 22°), grain boundary structures consist of an array of partial edge dislocations with Burgers vector $\frac{1}{2}[001]$ associated with stacking faults and their energies can be readily fit with a model which adds the Peach-Koehler equation to the Read-Shockley dislocation model for grain boundaries. The core radius of partial dislocations and the spacing between the partials derived from grain boundary energies show that the transition from low- to high-angle grain boundaries occurs for a misorientation angle between 22° and 32°. For high misorientation angles (32.1° and 60.8°), the cores of dislocations overlap and form repeated structural units. Finally, we use a low energy atomic configuration obtained by molecular dynamics for the misorientation of 12.18° as input to simulate a high-resolution transmission electron microscopy (HRTEM) image. The simulated image is in good agreement with an observed HRTEM image, which indicates the power of the present approach to predict realistic atomic structures of grain boundaries in complex silicates. 相似文献
8.
Hugues Raimbourg Toshihiro Kogure Tsuyoshi Toyoshima 《Contributions to Mineralogy and Petrology》2011,162(5):1093-1111
A prominent feature of a granulite-facies shear zone from the Hidaka Main Zone (Japan) is the folding of orthopyroxene (opx)
porphyroclasts. Dislocation density estimated by transmission electron microscope (TEM) and chemical etching in homogeneously
folded domains is too low to account for the amplitude of crystallographic bending, leading us to propose a model similar
to “flexural slip” folding, where folded layers are micrometer-wide opx layers between thin planar clinopyroxene (cpx) exsolutions.
Extension (compression) in the extrados (intrados) of the folded layer is accommodated by dislocations at the cpx–opx interfaces.
Alternatively to distributed deformation, crystal bending also localizes in grain boundaries (GBs), mostly oriented close
to the (001) plane and with various misorientation angles but misorientation axes consistently close to the b-axis. For misorientation up to a few degrees, GBs were imaged as tilt walls composed of regularly spaced (100)[001] dislocations.
For misorientation angles of 7°, individual dislocations are no longer visible, but high-resolution TEM (HRTEM) observation
showed the partial continuity of opx tetrahedral chains through the boundary. For 21° misorientation, the two adjacent crystals
are completely separated by an incoherent boundary. In spite of these atomic-scale variations, all GBs share orientation and
rotation axis, suggesting a continuous process of misorientation by symmetric incorporation of (100)[001] dislocations. In
addition to the dominant GBs perpendicular to the (100) plane, boundaries at low angle with (100) planes are also present,
incorporating dislocations with a component of Burgers vector along the a-axis. The two kinds of boundaries combine to delimit subgrains, which progressively rotate with respect to host grains around
the b-axis, eventually leading to recrystallization of large porphyroclasts. 相似文献
9.
10.
The defect structure of zeolite (K+, TMA+) — ZK-14, a synthetic chabazite, has been studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). SEM together with TEM bright field (BF) and dark field (DF) micrographs indicate that the hexagonal, platelet ZK-14 crystals are built up of crystalline blocks joined by twinning along (00.1). High resolution transmission electron microscopy (HRTEM) reveals faulting of the ideal AABBCC single 6-ring stacking sequence of ZK-14. This is consistent with an observed line broadening in its X-ray powder diffraction profile. Channel apertures are imaged, even for thick specimens. 相似文献
11.
The olivine-beta phase transformation in Co2SiO4 has been studied in a large-volume high-pressure apparatus (USSA-2000). The experimental conditions straddle the univariant phase boundaries due to the presence of a substantial temperature gradient (150–200° C over the 3-mm length of the sample). At conditions close to equilibrium, the transformation mechanism is one of limited nucleation with rapid growth of large crystals of the beta phase. Transmission electron microscopy (TEM) analysis shows that the cation stacking faults in Co2SiO4-spinel are identical to those seen in numerous spinels. The 010 faults in beta-Co2SiO4 are found to be identical to those seen in beta-(Mg,Fe)2SiO4 found in shocked veins in meteorites. 相似文献
12.
William L. Brown Martin R. Lee Kim A. Waldron I. Parsons 《Contributions to Mineralogy and Petrology》1997,127(3):305-313
Microperthitic feldspar crystals containing low microcline in a braid intergrowth often have distinctive microtextures including
coarse semi- to in-coherent grain-boundary pleated rims and fine coherent intracrystalline Ab- and Or-rich pleats (Lee et
al. 1997). The coarser pleated rims are generally separated from the braid microtexture in the crystal interior by a coherent
to semi-coherent transitional zone. Partial phase separation has occurred in the transitional zone in step with that in the Ab- and Or-rich pleats at the grain boundaries, such that
Ab-rich lamellar film micro-antiperthite alternates along (010) with more Or-rich lamellar film microperthite; the microtextures and phases are those expected for the respective local bulk compositions. Lamellar microtextures contain
tweed orthoclase, whereas low microcline is the only K-feldspar in the fine coherent pleats and braid microperthite. We propose
that the small coherent pleats developed from the braid microtexture by interaction of the spontaneous coherency strains with
discontinuities within or at the surface of the crystal, and that their initial spacing is guided by that of the braid microperthite.
We infer that the transitional zone formed by straightening of the zig-zag braid microtexture above the pleat heads during
coarsening and partial phase separation. We further infer that the resulting coherency shear strains induced a reversal of
the K-feldspar phase transformation, involving Si, Al disordering of low microcline into low sanidine, now tweed orthoclase, although the crystal was at a T within the hydrostatic T-stability of microcline.
Received: 10 June 1996 / Accepted: 12 December 1996 相似文献
13.
A systematic theoretical deduction of polytype structures of mica that can result by the spiral growth mechanism operating in faulted 1M, 2M 1 and 3T basic matrices is reported. As a prerequisite, all possible intrinsic and extrinsic stacking fault configurations in each of the basic matrices have been worked out and their stacking fault energy (SFE) estimated. The deduction of polytype structures on the basis of the “faulted-matrix model” takes into account (i) the introduction of each of the low energy fault configurations in the exposed ledge of the screw dislocations, (ii) the change in the layer-position of the fault within the exposed ledge and (iii) the variation of the strength of the generating screw dislocation. At each stage, the spirally-grown polytypes are deduced for each basic structure. The most probable structures are predicted on the basis of the lowest SFE for the same strength of the screw dislocation and are then compared with the polytype structures reported in the literature. It was found that the faulted matrix model accounts successfully for the origin of all the polytype structures in mica. Furthermore, it may provide a basis for limiting the number of trial structures for determining the structures of long period polytypes. 相似文献
14.
Genki Saito Yuji Kunisada Takahiro Nomura Norihito Sakaguchi Tomohiro Akiyama 《Physics and Chemistry of Minerals》2016,43(10):749-757
Twin formation in hematite during dehydration was investigated using X-ray diffraction, electron diffraction, and high-resolution transmission electron microscopy (TEM). When synthetic goethite was heated at different temperatures between 100 and 800 °C, a phase transformation occurred at temperatures above 250 °C. The electron diffraction patterns showed that the single-crystalline goethite with a growth direction of [001]G was transformed into hematite with a growth direction of [100]H. Two non-equivalent structures emerged in hematite after dehydration, with twin boundaries at the interface between the two variants. As the temperature was increased, crystal growth occurred. At 800 °C, the majority of the twin boundaries disappeared; however, some hematite particles remained in the twinned variant. The electron diffraction patterns and high-resolution TEM observations indicated that the twin boundaries consisted of crystallographically equivalent prismatic (100) (010), and (1\(\bar{1}\)0) planes. According to the total energy calculations based on spin-polarized density functional theory, the twin boundary of prismatic (100) screw had small interfacial energy (0.24 J/m2). Owing to this low interfacial energy, the prismatic (100) screw interface remained after higher-temperature treatment at 800 °C. 相似文献
15.
M. Dalla Torre Kenneth J. T. Livi David R. Veblen M. Frey 《Contributions to Mineralogy and Petrology》1996,123(4):390-405
Eleven samples from high-pressure/low-temperature (HP/LT) shales and shale-matrix melange from four areas in the Diablo Range were studied using electron microprobe (EMP), transmission
electron microscopy (TEM), and analytical electron microscopy (AEM) to provide information about white K-mica evolution and
about the controls on illite “crystallinity” (IC) in these areas. The data indicate that: (1) compositional gradients from
phengitic to muscovitic compositions occur along the long axis, perpendicular to c*, of white K-mica crystals; (2) compositional gradients parallel to c* were not observed, and thus coherent scattering domains along c* are homogeneous; (3) white K-mica crystals with compositions close to muscovite generally contain fewer planar defects and
have larger defect-free distances than those with more phengitic compositions; (4) muscovitic white K-mica is less common
than phengitic white K-mica. In the literature, grain growth has often been described to occur by the process of Ostwald ripening.
Ostwald ripening is defined as an isochemical process and involves the reduction of surface free energy due to simultaneous
dissolution and growth by transferring material from smaller particles to larger ones. However, in the present case: (1) coherent
scattering domain boundaries often are created by intragranular faults such as dislocations, intergrown smectite layers (and
other polysomatic defects), or incoherent layer rotations, which interrupt the 1.0 nm periodicity; (2) recrystallization from
phengite to muscovite involves chemical changes. This implies that crystal growth can not be described by the term Ostwald
ripening. Therefore, grain growth of white K-mica from the Diablo Range is described as a function of several processes that
result in (1) reduction of surface free energy; (2) reduction of strain energy; (3) minimization of the Gibbs free energy
due to change in composition. During growth of muscovitic white K-mica, planar defects become less abundant, and the defect-free
distance (=coherent scattering domain size parallel to c*) increases. Strain energy decreases. Log-normal frequency distributions of coherent white K-mica scattering domains were
found for three samples. The mode of these data coincides with the number of unit cells parallel to c* as calculated from the Scherrer equation. Thus, IC values from shales and shale matrix melange from the Diablo Range are
the result of a physical mixture of numerous small phengitic coherent scattering domains and smaller numbers of slightly larger
muscovitic coherent scattering domains. This implies that IC from the Diablo Range does not directly reflect maximum temperatures
achieved by these rocks. It follows that IC data from terranes with a metamorphic evolution similar to that of the Diablo
Range must be interpreted with caution.
Received: 23 August 1995 / Accepted: 30 November 1995 相似文献
16.
Tomoki Taguchi Yohei Igami Akira Miyake Masaki Enami 《Journal of Metamorphic Geology》2019,37(3):401-414
To understand the preservation of coesite inclusions in ultrahigh‐pressure (UHP) metamorphic rocks, an integrated petrological, Raman spectroscopic and focussed ion beam (FIB) system–transmission electron microscope (TEM) study was performed on a UHP kyanite eclogite from the Sulu belt in eastern China. Coesite grains have been observed only as rare inclusions in kyanite from the outer segment of garnet and in the matrix. Raman mapping analysis shows that a coesite inclusion in kyanite from the garnet rim records an anisotropic residual stress and retains a maximum residual pressure of ~0.35 GPa. TEM observations show quartz is absent from the coesite inclusion–host kyanite grain boundaries. Numerous dislocations and sub‐grain boundaries are present in the kyanite, but dislocations are not confirmed in the coesite. In particular, dislocations concentrate in the kyanite adjacent to the boundary with the coesite inclusion, and they form a dislocation concentration zone with a dislocation density of ~109 cm?2. A high‐resolution TEM image and a fast Fourier transform‐filtered image reveal that a tiny dislocation in the dislocation concentration zone is composed of multiple edge dislocations. The estimated dislocation density in most of the kyanite away from the coesite inclusion–host kyanite grain boundaries is ~108 cm?2, being lower than that in kyanite adjacent to the coesite. In the case of a coesite inclusion in a matrix kyanite, using Raman and TEM analyses, we could not identify any quartz at the grain boundaries. Dislocations are not observed in the coesite, but numerous dislocations and stacking faults are developed in the kyanite. The estimated overall dislocation density in the coesite‐bearing matrix kyanite is ~108 cm?2, but a high dislocation density region of ~109 cm?2 is also present near the coesite inclusion–host kyanite grain boundaries. Inclusion and matrix kyanite grains with no coesite have dislocation densities of ≤108 cm?2. Dislocation density is generally reduced during an annealing process, but our results show that not all dislocations in the kyanite have recovered uniformly during exhumation of the UHP rocks. Hence, one of the key factors acting as a buffer to inhibit the coesite to quartz transformation is the mechanical interaction between the host and the inclusion that lead to the formation of dislocations in the kyanite. The kyanite acts as an excellent pressure container that can preserve coesite during the decompression of rocks from UHP conditions. The search for and study of inclusions in kyanite may be a more suitable approach for tracing the spatial distribution of UHP metamorphic rocks. 相似文献
17.
合成氟金云母多型种类与含量对云母的物理化学性质具有重要的影响。然而在X射线粉晶衍射(XRD)制样过程中云母00l基面极易产生择优取向,严重制约了云母多型组成和含量的分析。传统撒样法可促使晶体取向随机分布,但制备的试样表面不够平坦。本文对传统撒样法进行改进,在撒样过程中使样品架均匀旋转,从而获得表面平坦的试样。XRD测试结果表明,旋转撒样法取向指数(OI=I_(001)/I_(060))为3.9,与无择优取向的理论值4.5接近,明显优于正压法和侧装法(OI值分别为38.7和18.1),表明旋转撒样法能够显著减弱云母择优取向。这主要是由于旋转撒样法使晶体颗粒之间形成犬牙交错分布,提高了云母各晶面随机分布概率。Rietveld全图拟合分析显示,旋转撒样法获得的XRD数据精修效果较好,计算出本文合成的氟金云母样品中1M和2M_1多型含量分别为86%和14%,8个工业合成的氟金云母样品中1M和2M_1多型含量分别为57%～72%和28%～43%,并且存在较多的堆垛层错。总之,旋转撒样法减弱择优取向效果显著,为研究云母晶体生长、多型成因以及结构与性能之间的关系提供了技术支撑。 相似文献
18.
The apparent lack of transformation-induced domains and stacking disorder defects in natural dolomites is considered in light of the different types of order in the dolomite structure. Experimentally produced twin domain boundaries and basal stacking defects are documented in a dolomite using high-resolution electron microscopy and electron diffraction techniques. Results reveal that upon cation ordering to form the dolomite structure, a twin domain is favored over an antiphase domain. The twin domain boundaries closely resemble antiphase boundaries (APB's) and are in contrast for superlattice reflections. However, background contrast within domains is shown to be different when imaged using certain fundamental reflections. The results allow speculation about the nature of ordering at low temperatures. Observations of twin domain boundaries in samples annealed at different temperatures allow estimation of the critical ordering temperature at 1,100°–1,150° C in stoichiometric dolomite. 相似文献
19.
Katharina Hartmann Richard Wirth Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(5):291-300
Several macroscopic physical and chemical properties, such as rheology, elasticity, or transport properties are governed by
grain boundary processes. An improved understanding of the structure and evolution of grain boundaries has thus become a key
challenge in geosciences and material sciences. Here, we report the structure of near Σ5 (210)/[100] grain boundaries in Y3Al5O12 (YAG), which were synthesised by the wafer direct bonding method. The produced grain boundaries were annealed at different
temperatures, ranging from 673 to 1,873 K. The grain boundaries annealed at different temperatures are not distinguishable
based on their flatness and apparent cohesiveness in high resolution TEM (HRTEM) micrographs, but show a considerable step
in their mechanical stability at around 1,273 K, a temperature that corresponds to roughly half the melting temperature of
YAG. This study further focuses on the effect of a slight misorientation of the two crystals on the grain boundary structure
and we discuss if the boundary can reach a state of minimum energy configuration during annealing. Along the grain boundaries,
we observed a long-range strain contrast with a periodicity of 40 nm, which has not been reported for high-angle grain boundaries
so far. We conclude that this contrast is caused by faceting along the grain boundary plane, which is needed to achieve minimum
energy configuration of the grain boundary plane. 相似文献
20.
Nephrite specimens from Longxi,sichuan,prepared by ion-thinning and dispersion techniques have been studied using TEM and SAED.A series of sub-microscopic textures such as (010)multiple-chain faults and related fault terminations.(001)mechanical twinning,sub-grain boundaries or fault walls,tremolite fibrous pseudoform of talc and intergrowth of tremolite and talc with (010)as interface are revealed .By analogy of metallographic textures,characteristics and mechanisms of the process of “deformation-recovery-recrystallization“ are discussed in detail,Topotactic reaction mechanism by which tremolite retrogresses to talc was studied and a retrogressive metamorphic origin of Longxi nephrite is proposed. 相似文献