首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 437 毫秒
1.
We present revised tremolite powder thermal decomposition kinetics using previous and newly acquired data from longer time (years instead of months) and lower temperature experiments (<1073 K). We also present kinetic results for decomposition of millimeter- to centimeter-sized tremolite grains. Natural tremolite samples were heated at ambient pressure in flowing CO2 or N2 gas from 1023-1238 K. The tremolite decomposition products are a physical mixture of two pyroxene solid solutions (with the bulk composition Dp59En41), a silica polymorph, and water vapor. Decomposition rates were calculated by using the mass loss of the heated samples. Tremolite crystals and crystalline powder decompositions follow different but related Avrami-Erofe'ev (nucleation and growth) kinetic models. The rate equations for thermal decomposition of tremolite crystalline powder and the larger crystal grains are log10kpowder (h−1)=18.69(±0.19)−23,845(±833)/T and log10kcrystal (h−1)=19.82(±0.07)−25,670(±916)/T. The associated apparent activation energies are 456(±16) kJ mol−1 and 491(±18) kJ mol−1, respectively. We propose a decomposition mechanism and suggest that decomposition and dehydroxylation occur simultaneously. The rate-limiting step is proposed to be structural rearrangement of the amphibole structure to the two pyroxenes and silica. This step and the overall decomposition rate are predicted to be independent of pressure from 1 to 100 bars. These kinetic analyses strengthen our previous conclusion (Johnson and Fegley, 2000, Icarus 146, 301-306) that if hydrous minerals, such as tremolite, formed on Venus during a wetter past, then these minerals could still exist at current conditions on Venus' surface today.  相似文献   

2.
We used thermochemical equilibrium calculations to predict stabilities of pure rock-forming hydrous silicates on Venus' surface as a function of elevation, atmospheric H2O and SO2concentrations, and oxygen fugacity (fO2). About 50 different hydrous silicates were included in our calculations. We find that many of these are unstable on Venus's surface because of the low atmospheric H2O content of 30–45 parts per million by volume (ppmv) and the high surface temperatures (660 K on Maxwell Montes to 740 K in the plains). Hydrous Fe2+-bearing silicates are unstable due to oxidation to magnetite and/or hematite at the fO2of the near-surface atmosphere. Ca-bearing hydrous silicates are unstable because of sulfatization to anhydrite. Some Fe-free micas (e.g., eastonite, eastonite–phlogopite micas), and some alkali amphiboles might be stable on Venus' surface, especially in the lower temperature highlands. We discuss hydrous mineral formation in the interior and on the surface of Venus. We review the literature on mica and amphibole thermal decomposition and find that dehydration of phlogopitic micas and fibrous amphiboles produces (metastable) dehydroxylated anhydrides that decompose to more stable minerals at temperatures hundreds of degrees higher than the onset of dehydroxylation. These observations raise the possibility that anhydrides formed from hydrous silicates, which may have been present during a wetter period in Venus' history, may persist somewhere on Venus' present surface. We discuss experiments that could be used on future spacecraft missions to detect hydroxyl in rocks and hydrous silicates on Venus. Finally, we review estimates of the amount of water and OH (hydroxyl) in the Earth's mantle. Based on this review, we suggest that even if no hydrous silicates are stable on Venus, significant amounts of water are plausibly present in surface rocks as OH in nominally anhydrous minerals.  相似文献   

3.
We propose a mechanism for the oxidation of gaseous CO into CO2 occurring on the surface mineral hematite (Fe2O3(s)) in hot, CO2-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO2 on Venus and could at least partly address the CO2 stability problem in Venus’ stratosphere, since our results suggest that atmospheric CO2 is produced from CO oxidation via surface hematite at a rate of 0.4 petagrammes (Pg) CO2 per (Earth) year on Venus which is about 45% of the mass loss of CO2 via photolysis in the Venusian stratosphere. We also investigated CO oxidation via the hematite mechanism for a range of planetary scenarios and found that modern Earth and Mars are probably too cold for the mechanism to be important because the rate-limiting step, involving CO(g) reacting onto the hematite surface, proceeds much slower at lower temperatures. The mechanism may feature on extrasolar planets such as Gliese 581c or CoRoT-7b assuming they can maintain solid surface hematite which, e.g. starts to melt above about 1200 K. The mechanism may also be important for hot Hadean-type environments and for the emerging class of hot Super-Earths with planetary surface temperatures between about 600 and 900 K.  相似文献   

4.
We review two models describing the Venus climate system: the carbonate and pyrite models. It has been argued carbonate and pyrite are potentially important minerals controlling the climate of Venus, though existence of either minerals has not been confirmed. Although it used to be proposed that carbonation reaction might explain the Venus’ atmospheric CO2 abundance, it is unlikely Venus’ surface is reactive enough to control the Venus’ massive CO2 atmosphere. Venus’ surface carbonate is also able to affect the climate through the reaction with atmospheric SO2 to form anhydrite. Under the carbonate model the climate state is not in equilibrium and would be unstable due to the reaction between carbonate and SO2. On the other hand, pyrite-magnetite reaction is proposed to explain the Venus’ atmospheric SO2 abundance. Under pyrite-magnetite reaction, however, the climate would be stabilized such that the existing climate state is maintained over a geological timescale, while some observational facts such as atmospheric abundance of SO2 and surface temperature could also be reasonably explained.  相似文献   

5.
While CO, HCl, and HF, that were considered in the first part of this work, have distinct absorption lines in high-resolution spectra and were detected four decades ago, the lines of HDO, OCS, and SO2 are either very weak or blended by the telluric lines and have not been observed previously by ground-based infrared spectroscopy at the Venus cloud tops. The H2O abundance above the Venus clouds is typically below the detection limit of ground-based IR spectroscopy. However, the large D/H ratio on Venus facilitates observations of HDO. Converted to H2O with D/H ≈ 200, our observations at 2722 cm−1 in the Venus afternoon show a H2O mixing ratio of ∼1.2 ppm at latitudes between ±40° increasing to ±60° by a factor of 2. The observations in the early morning reveal the H2O mixing ratio that is almost constant at 2.9 ppm within latitudes of ±75°. The measured H2O mixing ratios refer to 74 km. The observed increase in H2O is explained by the lack of photochemical production of sulfuric acid in the night time. The recent observations at the P-branch of OCS at 4094 cm−1 confirm our detection of OCS. Four distributions of OCS along the disk of Venus at various latitudes and local times have been retrieved. Both regular and irregular components are present in the variations of OCS. The observed OCS mixing ratio at 65 km varies from ∼0.3 to 9 ppb with the mean value of ∼3 ppb. The OCS scale height is retrieved from the observed limb darkening and varies from 1 to 4 km with a mean value of half the atmospheric scale height. SO2 at the cloud tops has been detected for the first time by means of ground-based infrared spectroscopy. The SO2 lines look irregular in the observed spectra at 2476 cm−1. The SO2 abundances are retrieved by fitting by synthetic spectra, and two methods have been applied to determine uncertainties and detection limits in this fitting. The retrieved mean SO2 mixing ratio of 350 ± 50 ppb at 72 km favors a significant increase in SO2 above the clouds since the period of 1980-1995 that was observed by the SOIR occultations at Venus Express. Scale heights of OCS and SO2 may be similar, and the SO2/OCS ratio is ∼500 and may be rather stable at 65-70 km under varying conditions on Venus.  相似文献   

6.
James L. Gooding 《Icarus》1978,33(3):483-513
Chemical weathering on Mars is examined theoretically from the standpoint of heterogeneous equilibrium between solid mineral phases and gaseous O2, H2O, and CO2 in the Martian atmosphere. Thermochemical calculations are performed in order to identify important gas-solid decomposition reactions involving the major mineral constituents of mafic igneous rocks. Where unavailable in the thermochemical literature, Gibbs free energy and enthalpy of formation are estimated for certain minerals and details of these estimation procedures are given. Partial pressure stability diagrams are presented to show pertinent mineral reaction boundaries at 298 and at 240°K. In the present Martian environment, the thermodynamically stable products of gas-solid weathering of individual minerals at 240°K should be Fe2O3, as hematite or maghemite (from fayalite, magnetite, and Fe-bearing pyroxenes), quartz (from all silicates), calcite (from Ca-bearing pyroxenes and plagioclase), magnesite (from forsterite and Mg-bearing pyroxenes), corundum (from all Al-bearing silicates), Ca-beidellite (from anorthite), and szomolnokite, FeSO4 or FeSO4·H2O (from iron sulfides). Albite, microcline, and apatite should be stable with respect to gas-solid decomposition, suggesting that gas-solid weathering products on Mars may be depleted in Na, K, and P (and, possibly, Cl and F). Certain montmorillonite-type clay minerals are thermodynamically favorable intermediate gas-solid decomposition products of Al-bearing pyroxenes and may be metastable intermediate products of special mineral surface reaction mechanisms. However, the predicted high thermodynamic susceptibility of these clay minerals to subsequent gas-solid decomposition implies that they should ultimately decompose in the present Martian surface environment. Kaolinite is apparently the only clay mineral which should be thermodynamically stable over all ranges of temperature and water vapor abundance in the present environment at the Martian surface. Considering thermodynamic criteria, including possible gas-solid decomposition reactions, it is doubtful that significant amounts of goethite and clay minerals can be currently forming on Mars by mechanisms known to operate to Earth. If major amounts of goethite and clay minerals occur on Mars, they probably owe their existence to formation in an environment characterized by the presence of liquid water or by mechanism possibly unique to Mars. In any case, any goethite or montmorillonite-type clay mineral on Mars must ultimately decompose.  相似文献   

7.
By means of the comparison between dynamical figures of Venus and the Earth, we confirmed that the nonhydrostatic moment difference ratios of the two celestial bodies are approximately equal. The hydrostatic flattening of the external equipotential surface of Venus according to the theory of internal field is equal to about 6 × 10–8, but the observed value of Venusian equatorial flattening is equal to 6.8 × 10–6. The latter is two orders of magnitude more than the former. These facts indicate that Venus itself is far from hydrostatic equilibrium.  相似文献   

8.
Ground-based and spacecraft photometry covering phase angles from 2° to 179° has been acquired in wavelength bands from blue to near infrared. An unexpected brightness surge is seen in the B and V bands when the disk of Venus is less than 2% illuminated. This excess luminosity appears to be the result of forward scattering from droplets of H2SO4 (sulfuric acid) in the high atmosphere of Venus. The fully sunlit brightness of Venus, adjusted to a distance of one AU from the Sun and observer, was found to be V=−4.38, and the corresponding geometric albedo is 67%. The phase integral is 1.35 and the resulting spherical albedo is 90%. Comparison between our data and photometry obtained over the past 50 years indicates a bias in the older photoelectric results, however atmospheric abundance variations suggest that brightness changes may have occurred too.  相似文献   

9.
Hydroxyl nightglow is intensively studied in the Earth atmosphere, due to its coupling to the ozone cycle. Recently, it was detected for the first time also in the Venus atmosphere, thanks to the VIRTIS-Venus Express observations. The main Δν=1, 2 emissions in the infrared spectral range, centred, respectively, at 2.81 and 1.46 μm (which correspond to the (1-0) and (2-0) transitions, respectively), were observed in limb geometry (Piccioni et al., 2008) with a mean emission rate of 880±90 and 100±40 kR (1R=106 photon cm−2 s−1 (4πster)−1), respectively, integrated along the line of sight. In this investigation, the Bates-Nicolet chemical reaction is reported to be the most probable mechanism for OH production on Venus, as in the case of Earth, but HO2 and O may still be not negligible as mechanism of production for OH, differently than Earth. The nightglow emission from OH provides a method to quantify O3, HO2, H and O, and to infer the mechanism of transport of the key species involved in the production. Very recently, an ozone layer was detected in the upper atmosphere of Venus by the SPICAV (Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus) instrument onboard Venus Express (Montmessin et al., 2009); this discovery enhances the importance of ozone to the OH production in the upper atmosphere of Venus through the Bates-Nicolet mechanism. On Venus, OH airglow is observed only in the night side and no evidence has been found whether a similar emission exists also in the day side. On Mars it is expected to exist both on the day and night sides of the planet, because of the presence of ozone, though OH airglow has not yet been detected.In this paper, we review and compare the OH nightglow on Venus and Earth. The case of Mars is also briefly discussed for the sake of completeness. Similarities from a chemical and a dynamical point of view are listed, though visible OH emissions on Earth and IR OH emissions on Venus are compared.  相似文献   

10.
Mm-wave spectra of HDO in the Venus mesosphere (65-100 km) were obtained over the period March 1998 to June 2004. Each spectrum is a measurement of the hemispheric-average H2O vapor mixing ratio in the Venus mesosphere. Observations were conducted for wide ranges of Venus solar elongations (46° W to 47° E), and fractional disk illuminations (f=0% to 99%), yielding water vapor abundances on 17 dates and over a full range of local solar time (LST) at the sub-Earth point on Venus. Our mesopheric H2O values are more numerous and far more precise than the earliest mm-derived H2O measurements [Encrenaz, Th., Lellouch, E., Paubert, G., Gulkis, S., 1991. First detection of HDO in the atmosphere of Venus at radio wavelengths: An estimate of the H2O vertical distribution. Astron. Astrophys. 246, L63-L66; Encrenaz, Th., Lellouch, E., Cernicharo, J., Paubert, G., Gulkis, S., Spilker, T., 1995. The thermal profile and water abundance in the Venus mesosphere from H2O and HDO millimeter observations. Icarus 117, 162-172], allowing an analysis of variability that was previously impossible. Measured 65-100 km H2O ranged from 0.0±0.06 to 3.5±0.3 ppmv, with significantly different variability than found in previous infrared (lower altitude, cloudtop) studies. Strong global variability on a 1-2 month timescale is clear and unambiguous. A limited number of excellent s/n measurements tentatively indicate the 1-2 month variability manifests most rapidly as change in the lower mesosphere, and more slowly as change in the upper mesosphere. Neither long term (1998-2004) nor diurnal variability in 65-100 km H2O is evident. While six-year and/or diurnal variabilities are not ruled out, they are weaker than the 1-2 month timescale variation. These conclusions are supported by initial (2004) sub-mm measurements.  相似文献   

11.
George E. McGill 《Icarus》2004,172(2):603-612
A major ongoing controversy concerns the style of crustal evolution on Venus. At one extreme is a directional model that proposes a sequence of depositional and deformational events that occur at specific times in the evolution of the crust and that are global in extent. At the other extreme is a model that argues for different ages of these events in different places on the planet. A test of the directional model is here focused on whether wrinkle ridges formed at a single time in the recorded crustal history of Venus. Where sets of wrinkle ridges intersect it commonly is possible to determine that one set is older than the other. Also, the deformation responsible for wrinkle ridges is, in places, clearly progressive with respect to stratigraphic material units. These observations are not consistent with a specific single time for the formation of wrinkle ridges within the stratigraphic sequence. Within an area including about 1/3 of the surface of Venus 15% of craters that are younger than regional plains are older than wrinkle ridges, 85% are younger than wrinkle ridges. Taking 750 myr as a reasonable mean age for the regional plains, this implies that the mean age of wrinkle ridges is ∼110 myr younger than the mean age of plains. Solomon et al. (1999, Science 286, 87) propose that the emplacement of a large volume of plains lava would lead to a major atmospheric temperature increase. Their model predicts thermal stresses in the lithosphere that, at shallow depth, would reach peak compressive stresses in about 100 myr, a number very similar to the time lag between plains emplacement and wrinkle ridge formation indicated by the crater data. The thermal compressive stresses responsible for wrinkle ridges would be maintained at a level sufficient to deform basalt for at least 100 myr and possibly for as long as 350 myr. These time intervals are not really short compared to the mean age of the plains. Finally, because wrinkle ridges are demonstrably younger than the plains they deform, they cannot be related to the processes that formed the plains and thus should not be used to define a “plains with wrinkle ridges” unit.  相似文献   

12.
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO2. O stimulates cooling by the emission at 15 μm in the collisions with CO2. (3) There is a great progress in the observations of photochemical tracers and minor constituents on Mars in the current decade. This progress is supported by progress in photochemical modeling, especially by photochemical GCMs. Main results in these areas are briefly discussed. The problem of methane presents the controversial aspects of its variations and origin. The reported variations of methane cannot be explained by the existing data on gas-phase and heterogeneous chemistry. The lack of current volcanism, SO2, and warm spots on Mars favor the biological origin of methane. (4) Venus’ chemistry is rich and covers a wide range of temperatures and pressures and many species. Photochemical models for the middle atmosphere (58-112 km), for the nighttime atmosphere and night airglow at 80-130 km, and the kinetic model for the lower atmosphere are briefly discussed.  相似文献   

13.
The Kelvin–Helmholtz instability gained scientific attention after observations at Venus by the spacecraft Pioneer Venus Orbiter gave rise to speculations that the instability contributes to the loss of planetary ions through the formation of plasma clouds. Since then, a handful of studies were devoted to the Kelvin–Helmholtz instability at the ionopause and its implications for Venus. The aim of this study is to investigate the stability of the two instability-relevant boundary layers around Venus: the induced magnetopause and the ionopause. We solve the 2D magnetohydrodynamic equations with the total variation diminishing Lax–Friedrichs algorithm and perform simulation runs with different initial conditions representing the situation at the boundary layers around Venus. Our results show that the Kelvin–Helmholtz instability does not seem to be able to reach its nonlinear vortex phase at the ionopause due to the very effective stabilizing effect of a large density jump across this boundary layer. This seems also to be true for the induced magnetopause for low solar activity. During high solar activity, however, there could occur conditions at the induced magnetopause which are in favour of the nonlinear evolution of the instability. For this situation, we estimated roughly a growth rate for planetary oxygen ions of about 7.6 × 1025 s−1, which should be regarded as an upper limit for loss due to the Kelvin–Helmholtz instability.  相似文献   

14.
An analysis of ion data from 390 Venus Express, VEX, orbits demonstrates that the flow of solar wind- and ionospheric ions near Venus is characterized by a marked asymmetry. The flow asymmetry of solar wind H+ and ionospheric O+ points steadily in the opposite direction to the planet’s orbital motion, and is most pronounced near the Pole and in the tail/nightside region. The flow asymmetry is consistent with aberration forcing, here defined as lateral forcing induced by the planet’s orbital motion. In addition to solar wind forcing by the radial solar wind expansion, Venus is also subject a lateral/aberration forcing induced by the planet’s orbital motion transverse to the solar wind flow.The ionospheric response to lateral solar wind forcing is analyzed from altitude profiles of the ion density, ion velocity and ion mass-flux. The close connection between decreasing solar wind H+ mass-flux and increasing ionospheric O+ mass-flux, is suggestive of a direct/local solar wind energy and momentum transfer to ionospheric plasma. The bulk O+ ion flow is accelerated to velocities less than 10 km/s inside the dayside/flank Ionopause, and up to 6000 km in the tail. Consequently, the bulk O+ outflow does not escape, but remains near Venus as a fast (km/s) O+ zonal wind in the Venus polar and nightside upper ionosphere. Furthermore, the total O+ mass-flux in the Venus induced magnetosphere, increases steadily downward to a maximum of 2 × 10−14 kg/(m2 s) at ≈400 km altitude, suggesting a downward transport of energy and momentum. The O+, and total mass-flux, decay rapidly below 400 km. With no other plasma mass-flux as replacement, we argue that the reduction of ion mass-flux is caused by ion-neutral drag, a transfer of ion energy and momentum to neutrals, implying that the O+ plasma wind is converted to a neutral (thermosphere) wind at Venus. Incidentally, such a neutral wind would go in the same direction as the Venus atmosphere superrotation.  相似文献   

15.
A multi-wavelength radio frequency observation of Venus was performed on April 5, 1996, with the Very Large Array to investigate potential variations in the vertical and horizontal distribution of temperature and the sulfur compounds sulfur dioxide (SO2) and sulfuric acid vapor (H2SO4(g)) in the atmosphere of the planet. Brightness temperature maps were produced which feature significantly darkened polar regions compared to the brighter low-latitude regions at both observed frequencies. This is the first time such polar features have been seen unambiguously in radio wavelength observations of Venus. The limb-darkening displayed in the maps helps to constrain the vertical profile of H2SO4(g), temperature, and to some degree SO2. The maps were interpreted by applying a retrieval algorithm to produce vertical profiles of temperature and abundance of H2SO4(g) given an assumed sub-cloud abundance of SO2. The results indicate a substantially higher abundance of H2SO4(g) at high latitudes (above 45°) than in the low-latitude regions. The retrieved temperature profiles are up to 25 K warmer than the profile obtained by the Pioneer Venus sounder probe at altitudes below 40 km (depending on location and assumed SO2 abundance). For 150 ppm of SO2, it is more consistent with the temperature profile obtained by Mariner 5, extrapolated to the surface via a dry adiabat. The profiles obtained for H2SO4(g) at high latitudes are consistent with those derived from the Magellan radio occultation experiments, peaking at around 8 ppm at an altitude of 46 km and decaying rapidly away from that altitude. At low latitudes, no significant H2SO4(g) is observed, regardless of the assumed SO2 content. This is well below that measured by Mariner 10 (Lipa and Tyler 1979, Icarus39, 192-208), which peaked at ∼14 ppm near 47 km. Our results favor ≤100 ppm of SO2 at low latitudes and ≤50 ppm in polar regions. The low-latitude value is statistically consistent with the results of Bézard et al. (1983, Geophs. Res. Lett.20, 1587-1590), who found that a sub-cloud SO2 abundance of 130±40 ppm best matched their observations in the near-IR. The retrieved temperature profile and higher abundance of H2SO4(g) in polar regions are consistent with a strong equatorial-to-polar, cloud-level flow due to a Hadley cell in the atmosphere of Venus.  相似文献   

16.
Laura Schaefer 《Icarus》2004,168(1):215-219
Chemical equilibrium calculations of volatile metal geochemistry on Venus show that high dielectric constant compounds of lead and bismuth such as PbS (galena), Bi2S3 (bismuthite) or Pb-Bi sulfosalts condense in the venusian highlands and may be responsible for the low radar emissivities observed by Magellan and Pioneer Venus. Our calculations also show that elemental tellurium is unstable on Venus' surface and will not condense below 46.6 km. This is over 30 km higher than Maxwell Montes, the highest point on Venus' surface. Elemental analyses of Venus' highlands surface by laser induced breakdown spectroscopy (LIBS) and/or X-ray fluorescence (XRF) can verify the identity of the heavy metal frost on Venus. The Pb-Pb age of Venus could be determined by mass spectrometric measurements of the Pb207/Pb204 and Pb206/Pb204 isotopic ratios in Pb-bearing frosts. All of these measurements are technologically feasible now.  相似文献   

17.
We report vertical thermal structure and wind velocities in the Venusian mesosphere retrieved from carbon monoxide (12CO J=2-1 and 13CO J=2-1) spectral line observations obtained with the Heinrich Hertz Submillimeter Telescope (HHSMT). We observed the mesosphere of Venus from two days after the second Messenger flyby of Venus (on 5 June 2007 at 23:10 UTC) during five days. Day-to-day and day-to-night temperature variations and short-term fluctuations of the mesospheric zonal flow were evident in our data. The extensive layer of warm air detected recently by SPICAV at 90-100 km altitude is also detected in the temperature profiles reported here.These data were part of a coordinated ground-based Venus observational campaign in support of the ESA Venus Express mission. Furthermore, this study attempts to cross-calibrate space- and ground-based observations, to constrain radiative transfer and retrieval algorithms for planetary atmospheres, and to contribute to a more thorough understanding of the global patterns of circulation of the Venusian atmosphere.  相似文献   

18.
Jeremy Bailey 《Icarus》2009,201(2):444-453
The discovery of the near infrared windows into the Venus deep atmosphere has enabled the use of remote sensing techniques to study the composition of the Venus atmosphere below the clouds. In particular, water vapor absorption lines can be observed in a number of the near-infrared windows allowing measurement of the H2O abundance at several different levels in the lower atmosphere. Accurate determination of the abundance requires a good database of spectral line parameters for the H2O absorption lines at the high temperatures (up to ∼700 K) encountered in the Venus deep atmosphere. This paper presents a comparison of a number of H2O line lists that have been, or that could potentially be used, to analyze Venus deep atmosphere water abundances and shows that there are substantial discrepancies between them. For example, the early high-temperature list used by Meadows and Crisp [Meadows, V.S., Crisp, D., 1996. J. Geophys. Res. 101 (E2), 4595-4622] had large systematic errors in line intensities. When these are corrected for using the more recent high-temperature BT2 list of Barber et al. [Barber, R.J., Tennyson, J., Harris, G.J., Tolchenov, R.N., 2006. Mon. Not. R. Astron. Soc. 368, 1087-1094] their value of 45±10 ppm for the water vapor mixing ratio reduces to 27±6 ppm. The HITRAN and GEISA lists used for most other studies of Venus are deficient in “hot” lines that become important in the Venus deep atmosphere and also show evidence of systematic errors in line intensities, particularly for the 8000 to 9500 cm−1 region that includes the 1.18 μm window. Water vapor mixing ratios derived from these lists may also be somewhat overestimated. The BT2 line list is recommended as being the most complete and accurate current representation of the H2O spectrum at Venus temperatures.  相似文献   

19.
In absence of other mechanisms, the main input of CO2into the Venusian atmosphere is via volcanic out gassing. Since Venus can be regarded as a planet-wide large igneous province, we can expect large quantities of CO2 being transferred into its atmosphere via volcanic out gassing. We have quantified the maximum possible amount of CO2 that can be out gassed via a single massive episode of resurfacing of the planet. This figure (5.6 × 1019 kg of CO2) is about 8 times smaller than the total CO2 present in the Venusian atmosphere (4.55 × 1020 kg CO2). The lack of planet-wide, efficient mechanisms for the recycling of CO2 on Venus indicates that CO2 has progressively accumulated in the atmosphere. Based on these considerations we suggest that the “equivalent” to eight global resurfacing episodes would be required to account for the present values of CO2 atmosphere. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

20.
We have obtained full-disk spatially resolved spectra of the Venus nightside at near-infrared wavelengths during July 2007 using the Anglo-Australian Telescope and Infrared Imager and Spectrograph 2 (IRIS2). The data have been used to map the intensity and rotational temperature of the O2(a1Δg) airglow band at . The temperatures agree with those obtained in earlier IRIS2 observations and are significantly higher than expected from the Venus International Reference Atmosphere (VIRA) profile. We also report the detection of the corresponding ν=0-1O2 airglow band at with a similar spatial distribution to the ν=0-0 band. Observations in the thermal window have been used to image surface topography using two different methods of cloud correction. We have also obtained images that can be used to study cloud motion.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号