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1.
《Ore Geology Reviews》2008,33(3-4):674-680
U–Pb SHRIMP results of 2672 ± 14 Ma obtained on hydrothermal monazite crystals, from ore samples of the giant Morro Velho and Cuiabá Archean orogenic deposits, represent the first reliable and precise age of gold mineralization associated with the Rio das Velhas greenstone belt evolution, in the Quadrilátero Ferrífero, Brazil. In the basal Nova Lima Group, of the Rio das Velhas greenstone belt, felsic volcanic and volcaniclastic rocks have been dated between 2792 ± 11 and 2751 ± 9 Ma, coeval with the intrusion of syn-tectonic tonalite and granodiorite plutons, and also with the metamorphic overprint of older tonalite–trondhjemite–granodiorite crust. Since cratonization and stable-shelf sedimentation followed intrusion of Neoarchean granites at 2612 + 3/− 2 Ma, it is clear that like other granite–greenstone terranes in the world, gold mineralization is constrained to the latest stages of greenstone evolution.  相似文献   

2.
The Cuiabá Gold Deposit is located in the northern part of the Quadrilátero Ferrífero, Minas Gerais State, Brazil. The region constitutes an Archean granite–greenstone terrane composed of a basement complex (ca. 3.2 Ga), the Rio das Velhas Supergroup greenstone sequence, and related granitoids (3.0–2.7 Ga), which are overlain by the Proterozoic supracrustal sequences of the Minas (< 2.6–2.1  Ga) and Espinhaço (1.7 Ga) supergroups.The stratigraphy of the Cuiabá area is part of the Nova Lima Group, which forms the lower part of the Rio das Velhas Supergroup. The lithological succession of the mine area comprises, from bottom to top, lower mafic metavolcanics intercalated with carbonaceous metasedimentary rocks, the gold-bearing Cuiabá-Banded Iron Formation (BIF), upper mafic metavolcanics and volcanoclastics and metasedimentary rocks. The metamorphism reached the greenschist facies. Tectonic structures of the deposit area are genetically related to deformation phases D1, D2, D3, which took place under crustal compression representing one progressive deformational event (En).The bulk of the economic-grade gold mineralization is related to six main ore shoots, contained within the Cuiabá BIF horizon, which range in thickness between 1 and 6 m. The BIF-hosted gold orebodies (> 4 ppm Au) represent sulfide-rich segments of the Cuiabá BIF, which grade laterally into non-economic mineralized or barren iron formation. Transitions from sulfide-rich to sulfide-poor BIF are indicated by decreasing gold grades from over 60 ppm to values below the fire assay detection limit in sulfide-poor portions. The deposit is “gold-only”, and shows a characteristic association of Au with Ag, As, Sb and low base-metal contents. The gold is fine grained (up to 60 μm), and is generally associated with sulfide layers, occurring as inclusions, in fractures or along grain boundaries of pyrite, the predominant sulfide mineral (> 90 vol.%). Gold is characterized by an average fineness of 0.840 and a large range of fineness (0.759 to 0.941).The country rocks to the mineralized BIF show strong sericite, carbonate and chlorite alteration, typical of greenschist facies metamorphic conditions. Textures observed on microscopic to mine scales indicate that the mineralized Cuiabá BIF is the result of sulfidation involving pervasive replacement of Fe-carbonates (siderite–ankerite) by Fe-sulfides. Gold mineralization at Cuiabá shows various features reported for Archean gold–lode deposits including the: (1) association of gold mineralization with Fe-rich host rocks; (2) strong structural control of the gold orebodies, showing remarkable down-plunge continuity (> 3 km) relative to strike length and width (up to 20 m); (3) epigenetic nature of the mineralization, with sulfidation as the major wall–rock alteration and directly associated with gold deposition; (4) geochemical signature, with mineralization showing consistent metal associations (Au–Ag–As–Sb and low base metal), which is compatible with metamorphic fluids.  相似文献   

3.
The Quadrilátero Ferrífero is a classic gold province on a global scale, with hundreds of individual gold occurrences in the Archean greenstone belt comprising the Rio das Velhas Supergroup. There are numerous small gold deposits, including Faria, Esperança III, Bicalho, Bela Fama, Juca Vieira, Brumal, Boa Vista, Fernandes, Moita, Roça Grande, Bico de Pedra and Pari, as well as the world-class deposits of Morro Velho and Cuiabá. All these deposits, whether large or small, are structurally controlled and related to either shear zones or folds. Extensive down-plunge continuity is a consistent feature of the deposits. In the Rio das Velhas greenstone belt, six main styles of gold mineralization are recognized. These are deposits hosted within: (1), Lapa seca (e.g., Morro Velho, Bicalho, Bela Fama), (2), Banded iron formations (e.g., Cuiabá, São Bento, Raposos, Faria, Brumal, Roça Grande), (3), Quartz veins (e.g., Juca Vieira, Fernandes), (4), Disseminated sulfides with quartz veinlets (e.g., Moita), (5), Amphibolites (e.g., Pari), and (6), Disseminated to massive base-metal sulfides (e.g., Bico de Pedra). The first four types of deposits are epigentic (orogenic) gold deposits, similar to those found in greenstone belts worldwide. The last two are unusual types of gold deposit, peculiar to the Quadrilátero Ferrífero. Bico de Pedra is a polymetallic Au–Ag–Zn–Pb–Cu deposit related to an aplite intrusion, whereas Pari is a stratiform Au-bearing-banded iron formation metamorphosed to epidote–amphibolite metamorphic facies.  相似文献   

4.
Archean terrains of the Quadrilátero Ferrífero comprise a greenstone belt association surrounded by granitoid–gneiss complexes, mainly composed of banded TTG gneisses whose igneous protoliths are older than 2900 Ma. This early continental crust was affected by three granitic magmatic episodes during the Neoarchean: ca. 2780 to 2760 Ma; 2720 to 2700 Ma; and 2600 Ma. Dating of felsic volcanic and volcaniclastic rocks defines a felsic magmatic event within the greenstone belt association around 2772 Ma, contemporaneous with emplacement of several of the granitic plutons and constrains a major magmatic and tectonic event in the Quadrilátero Ferrífero. Lead isotopic studies of lode–gold deposits indicate that the main mineralization episode occurred at about 2800 to 2700 Ma.Proterozoic evolution of the Quadrilátero Ferrífero comprises deposition of a continental-margin succession hosting thick, Lake Superior-type banded iron formations, at ca. 2500 to 2400 Ma, followed by deposition of syn-orogenic successions after 2120 Ma. The latter is related to the Transamazonian Orogeny. The western part of the Quadrilátero Ferrífero was also affected by the Brasiliano Orogeny (600 to 560 Ma).  相似文献   

5.
The Rio das Velhas greenstone belt is located in the Quadrilátero Ferrífero region, in the southern extremity of the São Francisco Craton, central-southern part of the State of Minas Gerais, SE Brazil. The metavolcano–sedimentary rocks of the Rio das Velhas Supergroup in this region are subdivided into the Nova Lima and Maquiné Groups. The former occurs at the base of the sequence, and contains the major Au deposits of the region. New geochronological data, along with a review of geochemical data for volcanic and sedimentary rocks, suggest at least two generations of greenstone belts, dated at 2900 and 2780 Ma. Seven lithofacies associations are identified, from bottom to top, encompassing (1) mafic–ultramafic volcanic; (2) volcano–chemical–sedimentary; (3) clastic–chemical–sedimentary, (4) volcaniclastic association with four lithofacies: monomictic and polymictic breccias, conglomerate–graywacke, graywacke–sandstone, graywacke–argillite; (5) resedimented association, including three sequences of graywacke–argillite, in the north and eastern, at greenschist facies and in the south, at amphibolite metamorphic facies; (6) coastal association with four lithofacies: sandstone with medium- to large-scale cross-bedding, sandstone with ripple marks, sandstone with herringbone cross-bedding, sandstone–siltstone; (7) non-marine association with the lithofacies: conglomerate–sandstone, coarse-grained sandstone, fine- to medium-grained sandstone. Four generations of structures are recognized: the first and second are Archean and compressional, driven from NNE to SSW; the third is extensional and attributed to the Paleoproterozoic Transamazonian Orogenic Cycle; and the fourth is compressional, driven from E to W, is related to the Neoproterozoic Brasiliano Orogenic Cycle. Gold deposits in the Rio das Velhas greenstone belt are structurally controlled and occur associated with hydrothermal alterations along Archean thrust shear zones of the second generation of structures.Sedimentation occurred during four episodes. Cycle 1 is interpreted to have occurred between 2800 and 2780 Ma, based on the ages of the mafic and felsic volcanism, and comprises predominantly chemical sedimentary rocks intercalated with mafic–ultramafic volcanic flows. It includes the volcano–chemical–sedimentary lithofacies association and part of the mafic–ultramafic volcanic association. The cycle is related to the initial extensional stage of the greenstone belt formation, with the deposition of sediments contemporaneous with volcanic flows that formed the submarine mafic plains. Cycle 2 encompasses the clastic–chemical–sedimentary association and distal turbidites of the resedimented association, in the eastern sector of the Quadrilátero Ferrífero. It was deposited in the initial stages of the felsic volcanism. Cycle 2 includes the coastal and resedimented associations in the southern sector, in advanced stages of subduction. In this southern sedimentary cycle it is also possible to recognize a stable shelf environment. Following the felsic volcanism, Cycle 3 comprises sedimentary rocks of the volcaniclastic and resedimented lithofacies associations, largely in the northern sector of the area. The characteristics of both associations indicate a submarine fan environment transitional to non-marine successions related to felsic volcanic edifices and related to the formation of island arcs. Cycle 4 is made up of clastic sedimentary rocks belonging to the non-marine lithofacies association. They are interpreted as braided plain and alluvial fan deposits in a retroarc foreland basin with the supply of debris from the previous cycles.  相似文献   

6.
The orogenic banded iron formation (BIF)-hosted Au mineralization at São Bento is a structurally-controlled, hydrothermal deposit hosted by Archean rocks of the Rio das Velhas greenstone belt, Quadrilátero Ferrífero region, Brazil. The deposit has reserves of 14.3 t Au and historical (underground) production of 44.6 t Au between 1987 and 2001. The oxide-facies São Bento BIF is mineralized at its lower portion, where in contact with carbonaceous, pelitic schists, particularly in the proximity of sulfide-bearing quartz veins. Shear-related Au deposition is associated with the pervasive, hydrothermal sulfidation (mainly arsenopyrite) of the Fe-rich bands of the São Bento BIF. Auriferous, sulfide- and quartz-rich zones represent proximal alteration zones. They are enveloped by ankerite-dominated haloes, which reflect progressive substitution of siderite and magnetite within the BIF by ankerite and pyrrhotite, respectively. The São Bento BIF was intensely and extensively deformed, first into open, upright folds that evolved into tight, asymmetric, isoclinal folds. The inverse limb of these folds attenuated and gave way to sheath folds and the establishment of ductile thrusts. Mineralized horizons at São Bento result from early structural modifications imposed by major transcurrent and thrusts faults, comprising the Conceição, Barão de Cocais and São Bento shear zones. Dextral movement on the SW–NE-directed Conceição shear zone may have generated splays at a compressional side-stepping zone, such as the São Bento shear zone, which is the structural locus for the São Bento gold mineralization. Relaxation of the Conceição shear zone under more brittle conditions resulted in the development of dilatational zones where gold–sulfide–quartz veins formed. These structures are considered to have been generated in the Archean. Geochronological data are scarce, with Pb–Pb analyses of refractory arsenopyrite and pyrite from bedded and remobilized ore plotting on a single-stage growth curve at 2.65 Ga. A later compressional, ductile deformation of unknown age overprinted, rotated and flattened the original, N60E-directed structure of the whole rock succession, with development of planar and linear fabrics that appear similar to Proterozoic-aged structures. Fluid inclusion studies indicate low salinity, aqueous fluids, with or without CO2 and/or CH4, with extremely variable CO2/CH4 ratios, of probable metamorphic origin. Fluid evolution shows a paragenetic decrease in the carbonic phase from 10–15% to 5%, and increase in the H2O/(CO2 + CH4) and CO2/CH4 ratios, suggesting important interaction with carbonaceous sediment. Trapping conditions indicate a temperature of 300 °C at 3.2 kbar.  相似文献   

7.
The Morro Velho gold deposit, Quadrilátero Ferrífero region, Minas Gerais, Brazil, is hosted by rocks at the base of the Archean Rio das Velhas greenstone belt. The deposit occurs within a thick carbonaceous phyllite package, containing intercalations of felsic and intermediate volcaniclastic rocks and dolomites. Considering the temporal and spatial association of the deposit with the Rio das Velhas orogeny, and location in close proximity to a major NNW-trending fault zone, it can be classified as an orogenic gold deposit. Hydrothermal activity was characterized by intense enrichment in alteration zones of carbonates, sulfides, chlorite, white mica±biotite, albite and quartz, as described in other Archean lode-type gold ores. Two types of ore occur in the deposit: dark gray quartz veins and sulfide-rich gold orebodies. The sulfide-rich orebodies range from disseminated concentrations of sulfide minerals to massive sulfide bodies. The sulfide assemblage comprises (by volume), on average, 74% pyrrhotite, 17% arsenopyrite, 8% pyrite and 1% chalcopyrite. The orebodies have a long axis parallel to the local stretching lineation, with continuity down the plunge of fold axis for at least 4.8 km. The group of rocks hosting the Morro Velho gold mineralization is locally referred to as lapa seca. These were isoclinally folded and metamorphosed prior to gold mineralization. The lapa seca and the orebodies it hosts are distributed in five main tight folds related to F1 (the best examples are the X, Main and South orebodies, in level 25), which are disrupted by NE- to E-striking shear zones. Textural features indicate that the sulfide mineralization postdated regional peak metamorphism, and that the massive sulfide ore has subsequently been neither metamorphosed nor deformed. Lead isotope ratios indicate a model age of 2.82 ± 0.05 Ga for both sulfide and gold mineralization. The lapa seca are interpreted as the results of a pre-gold alteration process and may be divided into carbonatic, micaceous and quartzose types. The carbonatic lapa seca is subdivided into gray and brown subtypes. Non-mineralized, gray carbonatic lapa seca forms the hanging wall to the orebodies, and is interpreted as the product of extreme CO2 metasomatism during hydrothermal alteration. This dolomitic lapa seca ranges in composition from relatively pure limestone and dolomite to silty limestone and dolomite. The brown carbonatic and micaceous lapa secas are the host rocks to gold. These units are interpreted to correspond to the sheared and hydrothermal products of metamorphosed volcaniclastic and/or volcanic rocks of varying composition from dacitic to andesitic, forming various types of schists and phyllites. The high-grade, massive sulfide orebodies occur at the base of the gray carbonatic lapa seca. Both disseminated mineralization and quartz veins are hosted by micaceous lapa seca. The data are consistent with a model of epigenetic mineralization for the lapa seca, from a hydrothermal fluid derived in part from the Archean basement or older crust material.  相似文献   

8.
SHRIMP U–Pb zircon dating of gabbro, anorthosite, trondhjemite and granodiorite from the Jinshajiang ophiolitic mélange of southwestern China provides geochronological constraints on the evolution of Paleo-Tethys. The ophiolitic mélange is exposed for about 130 km along the Jinshajiang River where numerous blocks of serpentinite, ultramafic cumulate, gabbro, sheeted dikes, pillow lavas and radiolarian chert are set in a greenschist matrix. A cumulate gabbro-anorthosite association and an amphibole gabbro have ages of 338 ± 6 Ma, 329 ± 7 Ma and 320 ± 10 Ma, respectively, which constrain the time of formation of oceanic crust. An ophiolitic isotropic gabbro dated at 282–285 Ma has the same age as a trondhjemite vein (285 ± 6 Ma) cutting the gabbro. These ages probably reflect a late phase of sea-floor spreading above an intra-oceanic subduction zone. At the southern end of the Jinshajiang belt, a granitoid batholith (268 ± 6 Ma), a gabbro massif (264 ± 4 Ma), and a granodiorite (adakite) intrusion (263 ± 6 Ma) in the ophiolitic mélange constitute a Permian intra-oceanic plutonic arc complex. A trondhjemite dike intruded serpentinite in the mélange at 238 ± 10 Ma and postdates the arc evolution of the Jinshajiang segment of Paleo-Tethys.  相似文献   

9.
The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.  相似文献   

10.
The Teplá–Barrandian unit (TBU) of the Bohemian Massif shared a common geological history throughout the Neoproterozoic and Cambrian with the Avalonian–Cadomian terranes. The Neoproterozoic evolution of an active plate margin in the Teplá–Barrandian is similar to Avalonian rocks in Newfoundland, whereas the Cambrian transtension and related calc-alkaline plutons are reminiscent of the Cadomian Ossa–Morena Zone and the Armorican Massif in western Europe. The Neoproterozoic evolution of the Teplá–Barrandian unit fits well with that of the Lausitz area (Saxothuringian unit), but is significantly distinct from the history of the Moravo–Silesian unit.The oldest volcanic activity in the Bohemian Massif is dated at 609+17/−19 Ma (U–Pb upper intercept). Subduction-related volcanic rocks have been dated from 585±7 to 568±3 Ma (lower intercept, rhyolite boulders), which pre-dates the age of sedimentation of the Cadomian flysch ( t chovice Group). Accretion, uplift and erosion of the volcanic arc is documented by the Neoproterozoic Dob í conglomerate of the upper part of the flysch. The intrusion age of 541+7/−8 Ma from the Zgorzelec granodiorite is interpreted as a minimum age of the Neoproterozoic sequence. The Neoproterozoic crust was tilted and subsequently early Cambrian intrusions dated at 522±2 Ma (T ovice granite), 524±3 Ma (V epadly granodiorite), 523±3 Ma (Smr ovice tonalite), 523±1 Ma (Smr ovice gabbro) and 524±0.8 Ma (Orlovice gabbro) were emplaced into transtensive shear zones.  相似文献   

11.
The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO2 and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.  相似文献   

12.
The El Valle-Boinás copper–gold deposit is located in the southern part of the Rio Narcea Gold Belt 65 km west of Oviedo (NW Spain), within the Cantabrian Zone (Iberian Hercynian Massif). The deposit is related to the Boinás stock, which ranges from quartz-monzonite to monzogranite and intruded (303 Ma) the carbonated Láncara Formation (early Cambrian) and the siliciclastic Oville Formation (middle-late Cambrian).A copper–gold skarn was developed along the contact between the igneous rock and the carbonated sedimentary rocks. The skarn distribution and mineralogy reflects both structural and lithologic controls. Two types of skarn exists: a calcic skarn mainly developed in the upper calcic member of the Láncara Formation, and a magnesian skarn developed in the lower dolomitic and organic-rich member. The former mainly consists of garnet, pyroxene and wollastonite. Retrograde alteration consists of K-feldspar, epidote, quartz, calcite, magnetite, ferroactinolite, titanite, apatite, chlorite and sulfides. Magnesian skarn mainly consists of diopside with interbedded forsterite zones. Pyroxene skarn is mainly altered to tremolite, with minor phlogopite and serpentine. Olivine skarn is pervasively altered to serpentine and magnetite, and is commonly accompanied by high sulfide and gold concentrations. This altered skarn results in a very dark rock, referred to as “black skarn”, which has great importance in gold reserves. Sulfide mineralization mainly consists of chalcopyrite, bornite, arsenopyrite, pyrrhotite and pyrite, while wittichenite, sphalerite, digenite, bismuthinite, native bismuth and electrum occur as accessory minerals.After extensive erosion, reactivation of the northeast-trending fracture zone provided conduits for the subsequent emplacement of porphyritic dikes (285±4 Ma) and diabasic dikes (255±5 Ma). Alteration, characterized by sericitization, silicification, carbonatization and hypogene oxidation took place, as did sulfide mineralization (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, bournonite, and Fe–Pb–Sb sulfosalts). Veins with quartz, carbonate, adularia and sulfide minerals crosscut all previous lithologies. Jasper and jasperoid breccias developed at the upper parts of the deposits.The fluid inclusion and stable isotope studies suggest a predominantly magmatic prograde-skarn fluid characterized by high-salinity (26–28 wt.% KCl and 32–36 wt.% NaCl) and high temperature, above 580°C. This fluid evolved into two immiscible fluids: a CO2- and/or CH4-rich, high-salinity aqueous fluid. Temperatures for the first retrograde-stage are between 350 and 425°C. A second stage is related to a more diluted aqueous fluid (3–6.2 wt.% NaCl eq.) and temperatures from 280 to 325°C. The fluid inclusion study performed on quartz from low-temperature mineralization indicates a very low salinity (0.2–6.2 wt.% NaCl eq.), low-temperature aqueous fluid (from 150 to 250°C), and trapping pressure conditions less than 0.2 kbar. In addition, the stable isotope study suggests that an influx of metamorphic waters derived from the country rocks produced these lower temperature fluids. The last control for the Au mineralization is the Alpine tectonism, which developed fault breccias (cataclasites to, locally, protomylonites) and gold remobilization from previous mineralization.  相似文献   

13.
The Amapá Block, southeastern Guiana Shield, represents an Archean block involved in a large Paleoproterozoic belt, with evolution related to the Transamazonian orogenic cycle (2.26 to 1.95 Ga). High spatial resolution dating using an electron-probe microanalyzer (EPMA) was employed to obtain U–Th–Pb chemical ages in monazite of seven rock samples of the Archean basement from that tectonic block, which underwent granulite- and amphibolite-facies metamorphism. Pb–Pb zircon dating was also performed on one sample.Monazite and zircon ages demonstrate that the metamorphic overprinting of the Archean basement occurred during the Transamazonian orogenesis, and two main tectono-thermal events were recorded. The first one is revealed by monazite ages of 2096 ± 6, 2093 ± 8, 2088 ± 8, 2087 ± 3 and 2086 ± 8 Ma, and by the zircon age of 2091 ± 5 Ma, obtained in granulitic rocks. These concordant ages provided a reliable estimate of the time of the granulite-facies metamorphism in the southwest of the Amapá Block and, coupled with petro-structural data, suggest that it was contemporaneous to the development of a thrusting system associated to the collisional stage of the Transamazonian orogenesis, at about 2.10–2.08 Ga.The later event, under amphibolite-facies conditions, is recorded by monazite ages of 2056 ± 7 and 2038 ± 6 Ma, and is consistent with a post-collisional stage, marked by granite emplacement and coeval migmatization of the Archean basement along strike-slip shear zones.  相似文献   

14.
The Xilamulun belt along the northern part of the North China Craton is located in eastern segment of the Central Asian Orogenic Belt and has great economic potential for Mo–Cu mineralization. More than ten medium to large ore deposits have been discovered in this region in the recent years. The major types of mineralization type include porphyry (Chehugou Mo–Cu, Kulitou Mo–Cu, Xiaodonggou Mo and Jiguanshan Mo), quartz vein (Nianzigou Mo, Xinjing Mo), epithermal (Hongshanzi Mo–U) and alteration assemblage (Liulingou Mo). The timing of mineralization was previously thought to be Yanshanian (208–290 Ma), however, Indosinian (260–208 Ma) ages for intrusions and mineralization have been recognized in recent years. Based on geochronologic data and regional geological evidence, it is suggested that the mineralization in the Xilamulun belt was formed during multiple events. The mineralization processes are related to a post-collisional extension stage (~ 258–210 Ma) with the generation of the porphyry molybdenum–copper deposit, a tectonic stress transformation from NS to EW (~ 185–150 Ma) that gave rise to vein or porphyry molybdenum deposit, and a lithospheric thinning stage (~ 140–110 Ma) with porphyry molybdenum deposit.  相似文献   

15.
The Altay orogenic belt (AOB), situated in the middle part of the Central Asian Orogenic Belt (CAOB), is one of the most important metallogenic belts in China. The Kangbutiebao Formation is a Late Paleozoic stratigraphic unit that hosts many important iron and Pb–Zn deposits. The Kangbutiebao Formation consists of intercalated volcanic and sedimentary rocks that have undergone regional greenschist to lower amphibolite facies metamorphism, and mainly outcrops in three NW-trending fault-bounded volcano–sedimentary basins, including the Maizi, Kelang, and Chonghuer basins. SHRIMP analyses of zircons from three metarhyolites of the Kangbutiebao Fm. in the Kelang Basin yield weighted mean 206Pb/238U ages of 412.6 ± 3.5 Ma, 408.7 ± 5.3 Ma and 406.7 ± 4.3 Ma, respectively, which can be interpreted as the eruption age of the Kangbutiebao silicic volcanic rocks in the Kelang Basin. These ages indicate that the Kangbutiebao Formation was formed during the Late Silurian to Early Devonian. They also demonstrate that the deposits hosted in the Kangbutiebao Formation were formed after 412–407 Ma. They play a key role in understanding the Paleozoic tectonic evolution and metallogenesis of the southern margin of the Chinese AOB.  相似文献   

16.
U–Pb single zircon crystallization ages were determined using TIMS and sensitive high resolution ion microprobe (SHRIMP) on samples of granitoid rocks exposed in the Serrinha nucleus granite–greenstone terrane, in NE Brazil. Our data show that the granitoid plutons can be divided into three distinct groups. Group 1 consists of Mesoarchaean (3.2–2.9 Ga) gneisses and N-S elongated TTG (Tonalite-Trondhjemite-Granodiorite) plutons with gneissic borders. Group 2 is represented by ca. 2.15 Ga pretectonic calc-alkaline plutons that are less deformed than group 1. Group 3 is ca. 2.11–2.07 Ga, late to post-tectonic plutons (shoshonite, syenite, K-rich granite and lamprophyre). Groups 2 and 3 are associated with the Transamazonian orogeny. Xenocryst ages of 3.6 Ga, the oldest zircon yet recorded within the São Francisco craton, are found in the group 3 Euclides shoshonite within the Uauá complex and in the group 2 Quijingue trondhjemite, indicating the presence of Paleoarchaean sialic basement.Group 1 gneiss-migmatitic rocks (ca. 3200 Ma) of the Uauá complex constitute the oldest known unit. Shortly afterwards, partial melting of mafic material produced a medium-K calc-alkaline melt, the younger Santa Luz complex (ca. 3100 Ma) to the south. Subsequent TTG melts intruded in different phases now exposed as N-S elongated plutons such as Ambrósio (3162 ± 26 Ma), Araci (3072 ± 2 Ma), Requeijão (2989 ± 11 Ma) and others, which together form a major part of the Archaean nucleus. Some of these plutons have what appear to be intrusive, but are probably remobilized, contacts with the Transamazonian Itapicuru greenstone belt. The older gneissic rocks occur as enclaves within younger Archaean plutons. Thus, serial additions of juvenile material over a period of several hundred m.y. led to the formation of a stable micro-continent by 2.9 Ga. Evidence for Neoarchaean activity is found in the inheritance pattern of only one sample, the group 2 Euclides pluton.Group 2 granitoid plutons were emplaced at 2.16–2.13 Ga in a continental arc environment floored by Mesoarchaean crust. These plutons were subsequently deformed and intruded by late to post-tectonic group 3 alkaline plutons. This period of Transamazonian orogeny can be explained as a consequence of ocean closure followed by collision and slab break-off. The only subsequent magmatism was kimberlitic, probably emplaced during the Neoproterozoic Braziliano event, which sampled older zircon from the basement.  相似文献   

17.
The chemical composition and Rb–Sr ages of mica, feldspar, and whole rock samples from the emerald mineralisation of Capoeirana and Belmont, from emerald-barren pegmatites and of the Borrachudos granitic gneiss, Monlevade banded and granitic gneisses from the area of Nova Era–Itabira–Ferros (Minas Gerais, Brazil) as well as from the Guanhães gneiss (Minas Gerais, Brazil) have been determined. The Borrachudos granitic and Monlevade banded gneiss with connected pegmatitic schlieren and pegmatite veins, as well as the Guanhães gneiss, got their actual textures and mineralogical composition at about 1.9 Ga in the context of the Transamazonic tectonothermal event.The Monlevade banded gneiss belongs to a volcano-metasedimentary greenstone belt sequence, which is the typical country rock of the emerald occurrences. The main emerald-forming event at Belmont and Capoeirana was a metasomatic reaction of Be-rich anatectic pegmatites with Cr-rich ultrabasic rocks during the Transamazonic event. At Capoeirana, K–feldspar-bearing Be-rich pegmatites were transformed during the emerald-forming process into plagioclase–quartz rocks. Rb–Sr ages on biotite of about 480 Ma from the emerald mineralisation result from the rejuvenation of Transamazonic biotite by the Brasiliano event.The widespread macroscopically unmetamorphosed pegmatites of the study area formed in the Brasiliano event at 477±14 Ma. These pegmatites resulted to be emerald-barren although the differentiation degree, as given by diagrams such as Cs vs. K/Rb for muscovite and K–feldspar, starts from ceramic and ends with Be pegmatites. Some pegmatites display a marked internal differentiation.

Abstract

Foram determinadas as composições químicas e as idades Rb–Sr de mica branca, feldspato potássico e de rochas totais das mineralizações de esmeraldas de Capoeirana e Belmont, de pegmatitos sem esmeraldas e dos gnaisses Borrachudos, Monlevade e Guanhães da região de Nova Era–Itabira–Ferros (Minas Gerais, Brazil). Os gnaisses graníticos Borrachudos, os gnaisses bandados Monlevade, seus respectivos pegmatitos e veios/schlieren pegmatóides, e os gnaisses Guanhães, adquiriram suas texturas e composições mineralógicas atuais há cerca de 1.9 Ga no contexto do evento Transamazônico.As rochas regionais encaixantes típicas das ocorrências de esmeraldas são os gnaisses Monlevade que pertencem a uma sequência metavulcano-sedimentar de tipo greenstone belt. O evento principal de formação de esmeraldas em Belmont e Capoeirana foi uma reação metassomática dos pegmatitos anatéticos ricos em Be com rochas ultrabásicas ricas em Cr durante o evento Transamazônico em torno de 1.9 Ga. Em Capoeirana nesse contexto os pegmatitos com feldspato potássico ricos em Be foram transformados em rochas de plagioclasio–quartzo. As idades Rb–Sr de cerca de 480 Ma de minerais das mineralizações de esmeralda resultaram da reequilibração de biotitas e feldspatos Transamazônicos durante o evento Brasiliano.Os pegmatitos não-metamórficos e sem esmeralda da região estudada foram formados no evento Brasiliano há 477±14 Ma. O grau de diferenciação dos pegmatitos, estudado em diagramas indicadores específicos como por exemplo Cs vs. K/Rb de micas brancas e feldspatos potássicos, varia desde pegmatitos cerámicos até muscovita-pegmatitos, à pegmatitos de metais raros e até berilíferos. Alguns dos pegmatitos apresentam marcante diferenciação interna.  相似文献   

18.
The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (206Pb/204Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (206Pb/204Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (206Pb/204Pb = 17.12 to 17.41, 207Pb/204Pb = 15.47 to 15.54, 208Pb/204Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (206Pb/204Pb = 18.20 to 24.28 and 18.32 to 20.06, 207Pb/204Pb = 15.69 to 16.44 and 15.66 to 15.98, 208Pb/204Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.  相似文献   

19.
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20.
Hot collisional orogens are characterized by abundant syn-kinematic granitic magmatism that profoundly affects their tectono-thermal evolutions. Voluminous granitic magmas, emplaced between 360 and 270 Ma, played a visibly important role in the evolution of the Variscan Orogen. In the Limousin region (western Massif Central, France), syntectonic granite plutons are spatially associated with major strike–slip shear zones that merge to the northwest with the South Armorican Shear Zone. This region allowed us to assess the role of magmatism in a hot transpressional orogen. Microstructural data and U/Pb zircon and monazite ages from a mylonitic leucogranite indicate synkinematic emplacement in a dextral transpressional shear zone at 313 ± 4 Ma. Leucogranites are coeval with cordierite-bearing migmatitic gneisses and vertical lenses of leucosome in strike–slip shear zones. We interpret U/Pb monazite ages of 315 ± 4 Ma for the gneisses and 316 ± 2 Ma for the leucosomes as the minimum age of high-grade metamorphism and migmatization respectively. These data suggest a spatial and temporal relationship between transpression, crustal melting, rapid exhumation and magma ascent, and cooling of high-grade metamorphic rocks.Some granites emplaced in the strike–slip shear zone are bounded at their roof by low dip normal faults that strike N–S, perpendicular to the E–W trend of the belt. The abundant crustal magmatism provided a low-viscosity zone that enhanced Variscan orogenic collapse during continued transpression, inducing the development of normal faults in the transpression zone and thrust faults at the front of the collapsed orogen.  相似文献   

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