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The isotopic composition of dissolved boron, in combination with the elemental concentrations of B, Cl and salinities in freshwater-seawater mixed samples taken from the estuary of the Changjiang River, the largest one in China, was investigated in detail in this study. Brackish water and seawater samples from the estuary of the Changjiang River were collected during low water season in November, 1998. Boron isotopic compositions were determined by the Cs2BO^＋2-graphite technique with a analytical uncertainty of 0.2‰ for NIST SRM 951 and an average analytical uncertainty of 0.8‰ for the samples. The isotopic compositions of boron, expressed in δ^11B, and boron concentrations in the Changjiang River at Nanjing and seawater from the open marine East Sea, China, are characterized by δ^11B values of -5.4‰ and 40.0‰, as well as 0.0272 and 4.43 mg B/L, respectively. Well-defined correlations between δ^11B values, B concentrations and Cl concentrations are interpreted in terms of binary mixing between fiver input water and East Sea seawater by a process of straightforward dilution. The offsets of δ^11B values are not related to the contents of clastic sediment and to the addition of boron. These relationships favor a conservative behavior of boron at the estuarine of the Changjiang River. 相似文献
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The paper presents a study of the gneissic granitoids of the Malkhan Complex and the intruisve granitoids of the Daur and Bichur complexes developed within the Khilok–Vitim fold belt of Central Transbaikalia. In the state geological map, these complexes have been attributed to the Early and Late Paleozoic. New 40Ar/39Ar geochronological data indicate that these rocks are Mesozoic rather than Paleozoic in age, which suggests the much broader manifestation of the Mesozoic granitoid complexes in this area. The studied Mesozoic granitoid massifs exhibit temporal and compositional zoning reflected in a westward decrease in age (from Early to Late Mesozoic) and increase in total alkalinity and potassium content at the appropriate trace-element characteristics. The obtained results of study of the Khilok–Vitim Belt are interpreted in the framework of the model of the formation of domal–cupola structures by the multiple activity of deep thermochemical plumes. 相似文献
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Analysis of the degree of contamination and evolution in the last 100 years of the composition of the bed sediments of the Anllóns Basin 总被引：3，自引：2，他引：1
Rosa Devesa-Rey M. T. Barral J.-M. Jouanneau F. Díaz-Fierros 《Environmental Earth Sciences》2010,61(7):1401-1417
In this study, five cores of the Anllóns River bed sediments were analyzed in order to evaluate the downcore and downstream
variations in their chemical composition. The first step was the evaluation of the metal distribution in the bulk (<2 mm)
and fine fractions (<63 μm). The analysis revealed that most of the metals followed the same trend in both fractions, although
the fine fraction presented usually higher concentrations. However, the concentration of both fractions tended to equalize
with increasing contamination. No general increase was observed in the metal concentrations toward the surface which could
be attributed to recent anthropogenic contributions. Instead, the distributions were homogeneous or peaked at various depths
downcore. The most important historical feature was observed at the mouth of the river, at 96-cm depth, corresponding to the
end of the eighteenth century. Upcore increased metal concentrations in parallel with increased fine fraction occurred from
this depth, which were attributed to a bridge construction and consequent changes in sediment dynamics. As the metal concentrations
can be influenced by variations in texture or other sediment characteristics, the second step was to evaluate the efficiency
of several normalized indexes in the assessment of the degree of contamination, by calculating the enrichment factor (EF),
the geoaccumulation index (I
GEO) and the pollution load index (PLI). The EFs obtained were <10, thus revealing little anthropogenic inputs to the basin.
The I
GEO produced higher values when compared with the EFs. Instead of absolute EF or I
GEO absolute values, the use of cumulative probability plots allowed identifying more accurately potential outliers indicating
contamination. Only one population was identified for Zn and Pb, with a reduced number of outliers at the highest concentrations
for Pb. As shown, a more complex plot with the outliers identified at C4 and C5. Finally, the PLI allowed determining the
absence of a significant contamination in the bed sediments. The bioavailable and non-geogenic fractions contribute up to
a 90% of the total concentrations in the case of As and Cu, and showed similar (dissimilar) profiles in comparison with total
metals. Also, the quality guidelines were surpassed, so the high solubility of As, Zn, Pb and Ni in the sediments revealed
the need to monitor the bed sediment quality of the Anllóns River. 相似文献
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Vladimir Potemkin Tatjana Potemkina 《中国地球化学学报》2006,25(B08):135-136
Lakes Baikal （Russia） and Khubsugul （Mongolia） are rift freshwater water bodies. The maximal depth of Baikal is 1642 m, that of Khubsugul -238 m. One of the important aspects in the study of suspended matter is its geochemical composition which depends on mineralogy and granulometry of the suspended matter. As the concentration of suspended matter in the sites of deep lakes is not high - about 1 mg/L, to determine the elements in the suspended matter the monochromatized synchrotron radiation method （SRXFA, Novosibirsk, Russia） was used. Water sampling was conducted in three basins of Lake Baikal and in Lake Khubsugul on central vertical cross-sections and in near-coastal sites. The water samples were collected with 10-liter batometers. The suspension was extracted from the water by filtration under vacuum through ＂Nuclepore＂ filters of 47 mm in diameter with pore size of 0.4 mkm. The mean weight of dry suspension on the filters was about 1 rag. The results of study of lacustrine suspended matter show that such elements as Fe, Ca, Mn, Ti, V, Cr, Cu, Zn, Pb dominate in lakes Baikal and Khubsugul. The concentration of other elements is low. On the whole, the vertical distribution of total amount of suspended matter in open Baikal decreases from the surface to the bottom. As for Lake Khubsugul, it increases. 相似文献
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Sourovi Zaman Salah Uddin Siddiquee Masato Katoh 《Arabian Journal of Geosciences》2011,4(7-8):1315-1321
This study was conducted in the tropical moist deciduous forest in Bangladesh to describe the species composition, diversity, and the forest structure. There were three plots established in Ranishonkoil, Ruhia, and Baliadangi forest beat in Thakurgaon. A total of 126 tree species, 1,991 stems (663 ha?1) of ≥10-cm girth were listed. Tree communities in these forest region differed in dominance, composition, diversity, and structure; and tree stand density varied from 651 to 685 ha?1. Species diversity (H1) ranges from 3.11 to 3.48. Meliaceae, Myrtaceae, and Rubiaceae were the most abundant families within the three plot area. Study site 2 is more diverse at spatial scale and taxonomic levels due to high rainfall and favorable edaphic condition. This study will help the foresters as baseline information for monitoring and sustaining diversity of tropical moist deciduous forests in Bangladesh. 相似文献
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《Chemie der Erde / Geochemistry》2016,76(4):463-480
Since about half a century samples from the lunar and asteroidal regoliths been used to derive information about elemental and isotopic composition and other properties of the present and past solar wind, predominantly for the noble gases and nitrogen. Secular changes of several important compositional parameters in the solar wind were proposed, as was a likely secular decrease of the solar wind flux. In 2004 NASA’s Genesis mission returned samples which had been exposed to the solar wind for almost 2.5 years. Their analyses resulted in an unprecendented accuracy for the isotopic and elemental composition of several elements in the solar wind, including noble gases, O and N. The Genesis data therefore also allow to re-evaluate the lunar and meteorite data, which is done here. In particular, claims for long-term changes of solar wind composition are reviewed.Outermost grain layers from relatively recently irradiated lunar regolith samples conserve the true isotopic ratios of implanted solar wind species. This conclusion had been made before Genesis based on the agreement of He and Ne isotopic data measured in the aluminum foils exposed to the solar wind on the Moon during the Apollo missions with data obtained in the first gas release fractions of stepwise in-vacuo etch experiments. Genesis data allowed to strengthen this conclusion and to extend it to all five noble gases. Minor variations in the isotopic compositions of implanted solar noble gases between relatively recently irradiated samples (<100 Ma) and samples irradiated billions of years ago are very likely the result of isotopic fractionation processes that happened after trapping of the gases rather than indicative of true secular changes in the solar wind composition. This is particularly important for the 3He/4He ratio, whose constancy over billions of years indicates that hardly any 3He produced as transient product of the pp-chains has been mixed from the solar interior into its outer convective zone. The He isotopic composition measured in the present-day solar wind therefore is identical to the (D + 3He)/4He ratio at the start of the suns’s main sequence phase and hence can be used to determine the protosolar D/H ratio.Genesis settled the long-standing controversy on the isotopic composition of nitrogen in lunar regolith samples. The 15N/14N ratio in the solar wind as measured by Genesis is lower than in any lunar sample. This proves that nitrogen in regolith samples is dominated by non-solar sources. A postulated secular increase of 15N/14N by some 30% over the past few Ga is not tenable any longer. Genesis also provided accurate data on the isotopic composition of oxygen in the solar wind, invaluable for cosmochemisty. These data superseded but essentially confirmed one value – and disproved a second one – derived from lunar regolith samples shortly prior to Genesis.Genesis also confirmed prior conclusions that lunar regolith samples essentially conserve the true elemental ratios of the heavy noble gases in the solar wind (Ar/Kr, Kr/Xe). Several secular changes of elemental abundances of noble gases in the solar wind had been proposed based on lunar and meteoritic data. I argue here that lunar data – in concert with Genesis – provide convincing evidence only for a long-term decrease of the Kr/Xe ratio by almost a factor of two over the past several Ga. It appears that the enhancement of abundances of elements with a low first ionisation potential in the solar wind (FIP effect) changed with time.Finally, Genesis allows a somewhat improved comparison of the present-day flux of solar wind Kr and Xe with the total amount of heavy solar wind noble gases in the lunar regolith. It remains unclear whether the past solar wind flux has been several times higher on average than it is today. 相似文献
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《中国地球化学学报》2006,(Z1)
Lakes Baikal (Russia) and Khubsugul (Mongolia) are rift freshwater water bodies. The maximal depth of Baikal is 1642 m, that of Khubsugul -238 m. One of the important aspects in the study of suspended matter is its geochemical composition which depends on… 相似文献
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G. Mongelli 《Mineralogy and Petrology》1995,53(1-3):103-114
Summary Mineralogical composition and trace elements distribution in the < 2-m size fraction of Late Cretaceous-Oligocene shales from the Southern Apennines (Italy) are presented.The clay mineral assemblage consists of illite, smectite, kaolinite and minor chlorite. Analytical evidence points to a detrital micaceous precursor for illite and smectite. Accessory phases were also found. Chemical data, normalized with respect to the Post-Archean Australian Shales (PAAS), indicate depletion of Ba, Rb, Y, Zr and enrichment of Nb. PAAS-normalized REE-patterns exhibit a positive Eu anomaly and HREE depletion. A kaolinite-rich sample has high REE contents in contrast to smectite-rich fractions. A REE-pattern without appreciable Eu anomaly is displayed by the illite-rich sample.Statistical data processing indicates a link between Ti, P, Y, Zr, Nb and Yb, suggesting that accessory phases may play a role in controlling HREE and that the observed LREE/HREE fractionation may also be due to hydraulic sorting of these phases. An important La-kaolinite relationship accounts for the capability of this phase to host LREE. Smectite and, thus, adsorption mechanisms, appear to exert a limited role in distributing REE. The Eu anomaly is a source inherited feature, probably not determined solely by clay minerals.
Spurenelement-Verteilung und mineralogische Zusammensetzung der < 2m Fraktion von Schiefern aus dem südlichen Appenin (Italien)
Zusammenfassung Die mineralogische Zusammensetzung und die Verteilung der Spurenelemente in der < 2 m Fraktion von spät-kretazischen-oligozänen Schiefern aus dem südlichen Appenin (Italien) werden in Übersicht gebracht. Die Tonmineral-Vergesellschaftung besteht aus Illit, Smectit, Kaolinit und kleineren Mengen von Chlorit. Analytische Daten weisen darauf hin, daß Illit und Smectit aus einem detritischen Glimmermineral hervorgegangen sein dürften. Auch akzessorische Phasen kommen vor. Chemische Daten zeigen gegenüber post-Archaischen australischen Schiefern (PAAS) eine Verarmung in Ba, Rb, Y, Zr und eine Anreicherung von Nb. PAAS-normalisierte SEE-Verteilungsmuster zeigen eine positive Eu Anomalie und eine Verarmung an HSEE. Eine Kaolinit-reiche Probe zeigt hohe Gehalte an gesamten SEE im Gegensatz zu einer Smectit-reichen. Die Illit-reiche Probe zeigt ein SEE-Verteilungsmuster ohne deutliche Eu Anomalie.Statistische Verarbeitung der Daten läßt eine Verbindung zwischen Ti, P, Y, Zr, Nb und Yb erkennen; dies weist darauf hin, daß akzessorische Phasen einen Einfluß auf die HSEE-Verteilung haben und daß die beobachtete LSEE/HSEE Fraktionierung auch auf hydraulische Sortierung dieser Phasen zurückgehen könnte. Es gibt eine bedeutsame Beziehung zwischen La und Kaolinit und diese unterstreicht die Fähigkeit des Kaolinits für die Aufnahme von LSEE. Smectit und Adsorptionsmechanismen scheinen eine geringe Rolle für die Verteilung der SEE zu spielen. Die Eu Anomalie ist eine Erscheinung, die auf die Quelle der sedimentären Minerale zurückgeht und wahrscheinlich nicht ausschließlich durch Tonminerale bestimmt wird.相似文献
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R. Offler H. Zwingmann J. Foden F. L. Sutherland I. T. Graham 《Australian Journal of Earth Sciences》2013,60(8):1129-1144
AbstractDykes are common in the wave-cut platforms along the coast from Newcastle to Sydney. According to some authors, they may be related to the opening of the Tasman Sea that commenced ca 84?Ma ago. However, there are few detailed radiogenic dating and geochemical studies to evaluate this. We attempt to resolve this by K–Ar dating of plagioclase in and geochemical studies of, basaltic dykes intruding Permo-Triassic sequences on the wave-cut platforms and Carboniferous and Permo-Triassic sequences inland. The plagioclase separated from the dykes give K–Ar ages ranging from 266 to 53?Ma with the majority older than 84?Ma indicating that most dykes were emplaced before the Tasman Seafloor formation. The dykes are generally mildly alkaline, high-Ti basalts; fewer are tholeiitic and calc-alkaline, low-Ti basalts. Strongly light rare earth element (LREE)-enriched patterns typify the former and flat, LREE-depleted or slightly to moderately enriched LREE patterns, the latter. High-Ti basalts have ocean-island-basalt-like and low-Ti basalts, calc-alkaline or mid-ocean ridge basalt (MORB)-like patterns. Most high-Ti and some low-Ti basalts show plume-like characteristics, others N-type MORB and arc-like characteristics. Dykes intruding the Carboniferous sequences show a distinct contamination signature that could be crustal or due to subduction-related metasomatism of the subcontinental lithospheric mantle. The sources of the basaltic magmas vary substantially and in places changes with time. All alkali basalts are derived from enriched asthenospheric sources at varying depths (90–147?km) and most tholeiitic, low-Ti basalts have been extracted from asthenospheric and depleted asthenospheric–lithospheric sources indicating substantial compositional heterogeneity of the mantle. Further, Nd model ages varying from Neoproterozoic (940–580?Ma) to Paleozoic (460–370?Ma) suggest variation in the age of mantle sources for the basalts. 相似文献
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Liuting Song Congqiang Liu Zhongliang Wang Yanguo Teng Jinsheng Wang Lili Liang Li Bai 《中国地球化学学报》2011,30(4):444-452
The Aha Lake is a seasonal anoxic water system in the southwest of Guiyang City, Guizhou Province, China. Seasonal variations in SO42- concentrations and their isotopic compositions in lake water as well as in the tributaries were investigated in this study. The results showed that sulfate concentrations in river water range from 0.94 to 6.52 mmol/L and their δ34S values range from -14.9‰ and 0.9‰, while lake water has sulfate concentrations ranging from 1.91 to 2.79 mmol/L, and δ34S values from -9.8‰ to -5.9‰. It is suggested that coal mining drainage is the major source of SO42- in the Aha Lake. Rainfall, sewage discharge, sulfide oxidation and gypsum dissolution have made only limited contributions. Different depth-dependent distributions of dissolved SO42- and δ34S were de-veloped for both DB and LJK in summer and winter. Due to water overturn, δ34S values display homogenous vertical distributions in winter and spring. While in summer and autumn, significant positive shifts of δ34S were clearly ob-served in epilimnion and bottom strata as a result of water stratification. High δ34S values in epilimnion may result from the retention of rainwater during water stratification. Dissimilatory sulfate reduction by bacteria was thought to be responsible for the increase of δ34S value in hypolimnion. 相似文献
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Mineralogy and Petrology - Contemporary mineralogy and geochemistry are concerned with understanding and deciphering processes that occur near the surface of the Earth. These processes are... 相似文献
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G. Yu. Pavlova P. Ya. Tishchenko N. D. Khodorenko M. G. Shvetsova S. G. Sagalaev 《Russian Journal of Pacific Geology》2012,6(3):251-262
The complex study of the river water and pore solutions from the bottom sediments in the lower reaches of the Razdol’naya River was conducted in February 2010. The major ion composition of the waters indicates the submarine origin of the near-bottom and pore waters in the lower reaches of the Razdol’naya River in the winter. The river estuary extends upstream for more than 20 km. It was established that the studied sediments are reduced oozes containing pyrite, hydrotroilite, and iron monosulfide, which is direct evidence for sulfate-reduction in the sediments. The diagenesis of organic matter is the main reason for the considerable decrease in the amount of sulfates and the increase in the alkalinity of the sediment pore water. The sedimentary pore water sampled from the deep river pits is characterized by excess alkalinity that cannot be explained by sulfate-reduction and methane genesis. It was suggested that the chemical weathering of silicate minerals and the bacterial mineralization of salts of organic acids could result in the excess alkalinity of the sediment pore water. 相似文献
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1IntroductionUp to now,eutrophication is still a problem af-fecting water quality in many developing countries.Themost important nutrients causing eutrophication arephosphates,nitrates and ammonia(Lijklema,1995;Horne and Goldman,1994).Eutrophic waters are… 相似文献
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Susanne M. Ullrich Huiwen HSIAO 《中国地球化学学报》2006,25(B08):238-239
The River Nura in central Kazakhstan has been heavily contaminated by mercury （Hg） from an acetaldehyde plant located in the industrial city of Temirtau. The plant released Hg-containing wastewater into the river from the 1950s until the mid 1990s and strongly contaminated the bed sediments up to 25 km downstream. In addition, a local power station released an estimated 6 million tonnes of fly-ash into the water which has adsorbed much of the Hg and has become mixed with the natural sediments. River water,fish and agricultural land in the floodplain are also contaminated by Hg. Humans are exposed to Hg primarily via the consumption of contaminated fish from the river. A survey was undertaken in June/July 2005 to investigate Hg concentrations in river water, drinking water, sediments and fish. To estimate the risk posed to the local population, approximately 300 hair samples were collected from people living in villages near the most contaminated section of the river, at a distance of between 5 and 30 km downstream of the acetaldehyde plant, and their dietary habits were recorded. Mercury concentrations in river water ranged from 2-3 ng/L upstream of the source of the pollution to 348 ng/L downstream of the factory outfall pipe. Some drinking water wells close to the river were contaminated, but deeper wells had Hg concentrations below the detection limit. 相似文献
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It is increasingly argued that we are entering into a “biotech century”, in which biotechnology promises major advances in agricultural productivity. The development of biotechnology is not a straightforward affair, however, and the advent of GMOs has led to public protest and consumer resistance. This paper draws upon a comparative Australian-UK project concerned with the role of regulation and governance in mediating the debates and managing the associated risks. Regulatory responses and the mediation of conflicts by the Australian and UK governments have been shaped by the institutional and policy environments in these two countries. The implications of these public debates and regulatory responses for the capture of competitive opportunities are considered. The fact that the two countries have broadly similar systems of governance and regulation reveals how alike the circumstances are in many respects. But at the same time there are important differences in both the style and the content of the policy debates. In both the UK and Australia, the respective central governments remain committed to a ‘biotechnology future’. Against this background, there is little doubt that the choices about biotechnology will play a defining role in shaping the future of rural places. 相似文献