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1.
东南沿海分布大面积的白垩纪晚期侵入岩。这些岩石可分为两期:其中115~100Ma以钙碱性系列岩石为主,岩石组合为辉长岩-闪长岩-花岗闪长岩-二长花岗岩-碱性长石花岗岩;而100~86Ma的岩石为碱性系列,岩石组合为石英二长斑岩-正长斑岩-碱性长石花岗岩。115~100Ma的辉长岩以角闪辉长岩为主,具有极高的CaO、MgO和Al_(2)O_(3)含量,具有极低的SiO_(2)(42.9%~53.8%)、全碱(K_(2)O+Na_(2)O:0.86%~5.28%)、Ba、Nb、Th、Rb和Zr含量,也具有极低的FeO^(T)/MgO、La/Yb和Zr/Hf比值,较高的Eu/Eu^(*)、Sr/Y比值和Sr含量,为基性-超基性堆晶岩。与辉长岩同期的闪长岩和细粒暗色包体具有较高的SiO_(2)(50.34%~63.68%),较低的CaO、P_(2)O_(5)、MgO、Al_(2)O_(3)含量,相对低的Eu/Eu^(*)和Sr/Y比值,变化较大的La/Yb和Zr/Hf比值,代表了从基性岩浆储库中抽取的富硅熔体。115~100Ma的花岗闪长岩和二长花岗岩类岩石为准铝质岩石,SiO_(2)含量变化较大(61.7%~75.3%),具有较低的FeO^(T)/MgO、Ga/Al比值和Nb、Zr及Nb+Zr+Ce+Y元素含量,显示出典型I型花岗岩的特征。这些花岗岩具有相对高的La/Yb、Eu/Eu^(*)和Zr/Hf比值和高的Sr、Ba和Zr含量。结合岩相学特征,这些花岗岩为堆晶花岗岩。而115~100Ma的碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),低的Eu/Eu^(*)、La/Yb、Zr/Hf和Sr/Y比值,具有低的Ba、Sr和Zr含量和高的Rb、Nb、Y和Th含量和Rb/Sr比值,表明这些花岗岩是由富硅岩浆储库中抽离的高硅熔体侵入地壳形成。100~86Ma期间形成的二长斑岩和正长斑岩具有极高的全碱含量,可以达到8%~12%,其SiO_(2)主要集中在60%~70%,具有极高的Zr、Sr和Ba含量和Eu/Eu^(*)、La/Yb和Sr/Y比值,显示出堆晶花岗岩的特征。而100~86Ma期间形成的大部分碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),并显示出A型花岗岩的特征,具有高的Rb/Sr比值和高的Rb、Y和Th和低的Ba、Sr含量和低的Zr/Hf、La/Yb、Eu/Eu^(*)和Sr/Y比值,表明它们是由富硅岩浆储库抽离的高硅熔体侵入浅部地壳形成。东南沿海高硅花岗岩的形成和穿地壳岩浆系统密切相关,高硅花岗岩是由浅部地壳内晶体-熔体分异产生的熔体侵入地壳所形成,而高硅花岗岩的地球化学特征与岩浆储库的水及挥发份含量密切相关。115~100Ma期间,从富水的岩浆储库抽离的熔体形成具有低高场强元素含量和低Rb/Sr比值的高硅花岗岩,这一过程与古太平洋板块俯冲有关;100~86Ma期间,从富挥发份的岩浆储库抽离的熔体形成碱性特征、富含高场强元素和具有高的Rb/Sr比值的高硅花岗岩,这一过程和古太平洋板块回撤软流圈上涌有关。  相似文献   

2.
Geological, petrological and geochemical studies indicated that there are two distinct types of granitoid rocks: older quartz diorites to granodiorite assemblage and younger granitoids, the latter occurring in two phases. The older granitoids have a meta-aluminous chemistry and a calc-alkaline character, with high MgO, Fe2O3, TiO2, CaO, P2O5, Sr and low SiO2, K2O, and Rb. Their major and trace elements data, together with low 87Sr/ 86Sr ratios (0.7029±0.0008) are indicative of I-type affinities. The second-...  相似文献   

3.
New geochemical and isotopic data for post-collisional Early Eocene and Late Miocene adakitic rocks from the eastern part of the Sakarya Zone, Turkey, indicate that slab and lower crustal melting, respectively, played key roles in the petrogenesis of these rocks. The Early Eocene Yoncal?k dacite (54.4 Ma) exhibits high Sr/Y and La/Yb ratios, low Y and HREE concentrations, moderate Mg# (44–65), and relatively high εNd and low ISr values, similar to adakites formed by slab melting associated with subduction. Geochemical composition of the Yoncal?k dacite cannot be explained by simple crystal fractionation and/or crustal contamination of andesitic parent magma, but is consistent with the participation of different proportions of melts derived from subducted basalt and sediments. Sr/Y correlates horizontally with Rb/Y, and Pb/Nd correlates vertically with Nd isotopic composition, indicating that Sr and Pb budgets are strongly controlled by melt addition from the subducting slab, whereas positive correlations between Th/Nd and Pb/Nd, and Rb/Y and Nb/Y point to some contribution of sediment melt. In addition to low concentrations of heavy rare earth elements (~2–3 times chondrite), a systematic decrease in their concentrations and Nb/Ta ratios with increasing SiO2 contents suggests that slab partial melting occurred in the garnet stability field and that these elements were mobilized by fluid flux. These geochemical and isotopic signatures are best explained by slab breakoff and fusion shortly after the initiation of collision. Although the Late Micone Tavda?? rhyolite (8.75 Ma) has some geochemical features identical to adakites, such as high Sr/Y and La/Yb ratios, low Y and HREE concentrations, other requirements, such as sodic andesite and/or dacite with relatively high MgO and Mg# (>50), relatively high Ni and Cr, low K2O/Na2O (<0.4), high Sr (>400 ppm), for slab-derived adakites are not provided. It is sodic in composition and shows no traces of fractionation from dacitic parent magma. Low Nd and high Sr isotope ratios suggest derivation by partial fusion of calc-alkaline, juvenile crust with high Sr/Y and La/Yb ratios.  相似文献   

4.
Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO2 (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO2, P2O5, MnO, Al2O3 and Fe2O3 define linear trends with negative slopes against SiO2, whilst Na2O and K2O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO2, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (LaN/YbN = 4.5–6.4) with moderate HREE fractionation (SmN/YbN = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the 87Sr/86Sr initial ratios vary from 0.704432 to 0.705989, and the 143Nd/144Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.  相似文献   

5.
~(40)Ar/~(39)Ar and zircon U-Pb geochronological and whole-rock geochemical analyses for the Laozanggou intermediate-acidic volcanic rocks from the western Qinling orogenic belt,Central China,constrain their petrogenesis and the nature of the Late Mesozoic lithospheric mantle.These volcanic rocks yield hornblende or whole-rock ~(40)Ar/~(39)Ar plateau ages of 128.3-129.7 Ma and zircon U-Pb age of131.3±1.3 Ma.They exhibit Si02 of 56.86-66.86 wt.%,K_2 O of 0.99-2.46 wt.% and MgO of 1.03-4.47 wt.%,with Mg# of 42-56.They are characterized by arc-like geochemical signatures with significant enrichment in LILE and LREE and depletion in HFSE.All the samples have enriched Sr-Nd isotopic compositions with initial ~(87)Sr/~(86)Sr ratios ranging from 0.7112 to 0.7149 and ε_(Nd)(t) values from 10.2 to 6.3.Such geochemical signatures suggest that these volcanic rocks were derived from enriched lithospherederived magma followed by the assimilation and fractional crystallization(AFC)process.The generation of the enriched lithospheric mantle is likely related to the modification of sediment-derived fluid in response to the Triassic subduction/collision event in Qinling orogenic belt.The early Cretaceous detachment of the lithospheric root provides a reasonable mechanism for understanding the petrogenesis of the Laozanggou volcanic sequence in the western Qinling orogenic belt.  相似文献   

6.
对大兴安岭北段图里河地区满克头鄂博组火山岩进行了锆石U-Pb年代学及岩石地球化学研究,以便对其岩石成因和构造背景给予制约。流纹岩LA-ICP-MS锆石U-Pb定年结果表明,该地区满克头鄂博组火山岩形成时代为晚侏罗世(157±1Ma)。该组火山岩具有高硅(Si O2=69.09%~75.92%)、富碱(K2O+Na2O=8.04%~9.23%),贫镁、铁、钙的特征,属高钾钙碱性、偏铝质-弱过铝质岩石;稀土元素配分曲线呈轻稀土富集的右倾形式,(La/Yb)N=5.85~13.53,无铕异常或具有较弱的铕负异常;火山岩样品富集Rb、Th、U、K等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素。Mg#值为12.14~31.01,平均值22,Nb/Ta值(6.67~27.17,平均值12.23),Rb/Sr值(0.35~3.63,平均值1.58),显示火山岩岩浆源区为下地壳。依据岩石地球化学特征、构造判别图解,结合区域构造演化特征,认为满克头鄂博组火山岩形成于蒙古—鄂霍茨克洋闭合的造山后伸展背景。  相似文献   

7.
The Late Triassic igneous rocks in the Yidun terrane can provide vital insights into the evolution of Plaeo-Tethys in western China. We present new zircon U-Pb, whole-rock geochemistry, and Sr-Nd-Pb-Hf isotopic data for the Litang biotite monzogranites, Yidun terrane. The biotite monzogranites have a zircon U-Pb age of 206.1±1.0 Ma(MSWD=1.9,n=30), which indicates Late Triassic magmatism. The biotite monzogranites display I-type affinity, high Na_2O(3.38-3.60 wt%) contente,medii SiO_2(67.12-69.13 wt%), and low P_2 O_5 contents(0.10～0.12 wt%). They enriched in Rb,and Ba and depleted in Nb and Ta, with negative Eu anomalies(Eu/Eu*=0.74—0.81). They have evolved Sr-Nd-Pb-Hf isotopic composition, i.e.,(~(87) Sr/~(86 )Sr)i=0.714225 to 0.714763, negative ?_(Nd(t)) values of -2.0 to-2.6 with two-stage Nd model ages ranging from 1.01 to 1.05 Ga, negative ?_(Ht)(t)) values o f-3.4 to-4.1 with two-stage Hf model ages of 1.85 to1.88 Ga, suggesting a matured crustal sources. Their low Al_2O_3/TiO_2 ratios and medium Cao/Na_2O ratios, medium Mg~# and SiO_2 contents, low [molar Al_2O_3/(MgO+FeO~T)] values, and high [molar Cao/(MgO+FeO~T)] values indicate that the Litang biotite monzogranite was formed by partial melting of metabasaltic rocks. Based on the previous studies, we propose that the Litang biotite monzogranite derived from the westward subduction and closure of the Ganzi-Litang ocean during the Late Triassic-The mantle wedge-derived mafic melts provided sufficient heat for partial melting of ancient metabasalt protolith within the middle-lower crust.  相似文献   

8.
Precise Fe/Mn ratios and MnO contents have been determined for basalts from the Hawaiian shields of Ko’olau and Kilauea by inductively coupled plasma mass spectrometry. It is well known that the youngest Ko’olau (Makapu’u-stage) shield lavas define a geochemical endmember for Hawaiian lavas in terms of CaO and SiO2 contents and isotopic ratios of O, Sr, Nd, Hf, Pb, and Os. We find that their MnO content is also distinct. Despite the small range in MnO, 0.146 to 0.176 wt%, the precision of our data is sufficient to show that among unaltered Ko’olau lavas MnO content is correlated with Nd-Hf-Pb isotopic ratios, La/Nb and Al2O3/CaO elemental ratios, and contents of SiO2, MgO and Na2O + K2O adjusted for olivine fractionation. These trends are consistent with two-component mixing; one endmember is a SiO2-rich, MnO-, and MgO-poor dacite or andesite melt, generated by low degree (10-20%) partial melting of eclogite. Since this low-MgO endmember (dacite or andesite melt) has very low FeO and MnO contents, mixing of high Fe/Mn dacite or andesite melt with a MgO-rich picritic melt, the other endmember, does not significantly increase the Fe/Mn in mixed magmas; consequently, Ko’olau and Kilauea lavas have similar Fe/Mn. We conclude that the high Fe/Mn in Hawaiian lavas relative to mid-ocean ridge basalt originates from the high MgO endmember in Hawaiian lavas.  相似文献   

9.
Petrochemical studies on acid plutonic (granite, microgranite) and volcanic (rhyolite, trachyte) rocks occurring in the Siner area of the Siwana Ring Complex, Malani Igneous Suite have been carried out. These rocks are characterized by high concentrations of SiO2, Na2O, K2O, Zr, Nb, Y and REE (except Eu) but low in MgO, Fe2O3(t), CaO, Cr, Ni, Sr; indicating their A-type affinity. Field studies in conjunction with the geochemical characteristic indicate that the magmatism in the Siner area is generally represented by peralkaline suite of rocks which are formed due to rift tectonics. It is also suggested that these acidic rocks could have been derived by low degree partial melting of crustal material. Characteristics of certain pathfinder elements such as Rb, Ba, Sr, K, Zr, Nb, REE and the ratios of K/Rb, Zr/Rb, Ba/Rb along with the multi elemental primitive mantle normalized spidergrams suggest that the Siner peralkaline granites and microgranites have the potential for rare metal and rare earth mineralizations.  相似文献   

10.
The Mt. Erciyes stratovolcano was built up in an intraplate tectonic environment as a consequence of Eurasian and Afro-Arabian continental collision. However, the volcanic products generally exhibit a calc-alkaline character; minor amounts of tholeiitic basalts are also present. Tholeiitic basalts show high Fe2O3, MgO, CaO, low K2O, and depleted Ba, Nb, and especially Rb (2.3-5.97 ppm) contents, low 87Sr/86Sr (0.703344-0.703964), and high 143Nd/144Nd (0.512920-0.512780) isotopic ratios. These compositional features show that they were derived from a depleted asthenospheric mantle source, possibly a MORB-like source component. In contrast, calc-alkaline basaltic rocks exhibit relatively high large-ion-lithophile and high-field-strength elements, high 87Sr/86Sr (0.704591-0.70507) and low 143Nd/144Nd (0.51272-0.512394) isotopic ratios.

The bulk-rock chemistry of the tholeiitic basalts reflects the chemical composition of the extracted source component. Furthermore, trace-element concentrations may be calculated from an accepted mantle source component (starting composition) for different degrees of partial melting. These calculations also provide a sensitive approach to the origin of tholeiitic basalts. Modeled trace-element compositions of tholeiitic basalts are calculated from a primitive mantle composition. Calculated trace-element compositions imply that tholeiitic basalts are derived by minor fractional melting (1-1.5 %), in the absence of assimilation or deep-crustal melting. The calc-alkaline basalts were subsequently produced from initially tholeiitic basalts by the way of an AFC (assimilation-fractional crystallization) process, with a crustal assimilation of 10-15 %.

The geochemical data, partial melting, and AFC modeling all indicate that basaltic products have a complex evolutionary history involving partial melting from a MORB-like mantle source. The assimilation and fractional crystallization processes are considered as providing an example for the chemical evolution of basaltic products, from tholeiitic to calc-alkaline, in an intraplate environment.  相似文献   

11.
The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite porphyry. The K2O content of majority of these rocks is greater than 3%, and, in the K2O-SiO2 diagram, all the samples fall into the high-K calc-alkaline to shoshonitic fields. They are enriched in light rare earth elements (LREEs) and depleted in heavy rare earth elements (HREEs; LaN/YbN = 14.3-21.2), and show slightly negative Eu anomalies (δEu = 0.77-1.00). These rocks have high K, Rb, Sr, and Ba contents; moderate to high enrichment of compatible elements (Cr = 36.7-79.9 ppm, Co = 9.6-16.4 ppm, and MgO = 2.2%-3.4%); low Nb, Ta, and Ti contents, and characteristic of low high field strength elements(HFSEs) versus incompatible elements ratios (Nb/Th = 0.75, Nb/La = 0.34) and incompatible elements ratios (Nb/U = 3.0 and Ce/Pb = 5.1, Ba/Rb = 12.0). These rocks exhibit restricted Sr and Nd isotopic compositions, with (87Sr/86Sr) i values ranging from 0.7044 to 0.7069 and εNd(t) values from -2.8 to -2.2. The Sr-Nd isotope systematic and specific trace element ratios suggest that Langdu high-K calc-alkaline intrusive rocks derived from a metasomatized mantle source. The unique geochemical feature of intrusive rocks can be modeled successfully using different members of a slightly enriched mantle, a slab-derived fluid, and terrigenous sediments. It can be inferred that the degree of partial melting and the presence of specific components are temporally related to the tectonic evolution of the Zhongdian island arc. Formation of these rocks can be explained by the various degrees of melting within an ascending region of the slightly enriched mantle, triggered by the subduction of the Garzê-Litang ocean, and an interaction between the slab-derived fluid and the terrigenous sediments.  相似文献   

12.
The northern Noorabad area in western Iran contains several gabbro and basalt bodies which were emplaced along the Zagros suture zone. The basalts show pillow and flow structures with amygdaloidal textures, and the gabbroic rocks show massive and foliated structures with coarse to fine-grained textures. The SiO2 contents of the gabbros and basalts are similar and range from 46.1–51.0 wt.%, and the Al2O3 contents vary from 12.3–18.8 wt.%, with TiO2 contents of 0.4–3.0 wt.%. The Nb concentrations of some gabbros and basalts are high and can be classified as Nb-enriched arc basalts. The positive εNd(t) values (+3.7 to +9.8) and low 87Sr/86Sr(initial) ratios (0.7031–0.7071) of both bodies strongly indicate a depleted mantle source and indicate that the rocks were formed by partial melting of a depleted lithospheric mantle and interaction with slab fluids/melts. The chemical composition of trace elements, REE pattern and initial 87Sr/86Sr-143Nd/144Nd ratios show that the rocks have affinities to tholeiitic magmatic series and suggest an extensional tectonic regime over the subduction zone for the evolution of these rocks. We propose an extensional tectonic regime due to the upwelling of metasomatized mantle after the late Cretaceous collision in the Harsin-Noorabad area. These rocks can be also considered as Eocene back arc magmatic activity along the Zagros suture zone in this area.  相似文献   

13.
We present new geochemical data (major- and trace-elements, as well as Sr and Nd isotopic compositions) of volcanic rocks erupted from Popocatépetl volcano during the volcanic event from December 2000 to January 2001. These data along with an exhaustive compilation of geochemical and Sr, Nd, and Pb isotope data reported for Popocatépetl rocks and nearby volcanic areas are used to examine the origin and geochemical evolution of the magmas in the central Mexican volcanic belt (CMVB). During this period of volcanic eruptions Popocatépetl produced ash columns as high as 7 km. Pyroclastic flows and lahars were observed after the completion of the activity. Samples of banded pumice and a bomb fragment transported by the lahar were chemically analysed for this work. Rocks show an andesitic composition with 58.5–61.7 wt.% SiO2 and 5.9–4.0 wt.% MgO. Contents of large ion lithophile elements (LILE), rare-earth elements (REE) and Zr are nearly constant through the compositional range. No significant Eu anomaly is present, but the samples show Nb-anomaly relative to LILE and high-field strength elements (HFSE). Nd- and Sr-isotopic compositions of these samples range from 143Nd/144Nd = 0.51291 to 0.51287 and 87Sr/86Sr = 0.70399 to 0.70422. Comparison of Popocatépetl products with volcanic rocks from the nearby areas shows that the magmas in CMVB were generated in a heterogeneously veined-mantle source enriched in LILE, HFSE, and REE. Additional crustal assimilation as well as fractional crystallization could account for the great chemical variability of rocks in the CMVB. Statistical comparison of the geochemical compositions of the volcanic products ejected from 1994 to 2000 to those ejected during the 2001 event shows that most geochemical parameters (major- and trace-elements, normative minerals, Sr and Nd isotopic composition, as well some elemental ratios) present no statistically significant differences. Statistically significant differences in the mean only were computed for the major-elements SiO2, FeO, MgO, CaO, and K2O, as well as for the rare-earth elements Nd, Sm, Eu, Gd, Dy, Ho, Tm, and Yb.  相似文献   

14.
Appinites are commonly derived from a mantle source and are potentially significant in constraining the tectonic nature and evolution of ancient orogens, yet they have received little attention because of their limited outcrop. Here we investigate the newly identified appinitic rocks from the Laoniushan complex in the eastern Qinling Orogen. The appinites are composed of coarse-grained hornblendite, medium- and fine-grained hornblende-gabbro, and diorite porphyrite in the field occurrence. Winthin the appinitic rocks, the hornblendite displays features of cumulates. This study presents LA-ICP-MS zircon U-Pb data, mineral chemistry and whole rock geochemistry of the appinites. Zircons in the mafic to ultramafic rocks yield a U-Pb age of 152 ± 1Ma. The geochemistry of the rocks displays: lower SiO2, higher Fe2O3T and MgO contents, relatively flat chondrite normalized REE patterns with slight enrichment in light REE and a minor negative Eu anomaly; enrichment in large-ion lithophile elements(LILE, e.g. Rb, Ba, Sr and P), and depletion in high field strength elements(HFSE, e.g. Nb, Zr, Hf and Ti). Such geochemical features, together with crust-like bulk Sr-Nd isotopic compositions(initial 87Sr/86Sr ratios of 0.7057–0.7072, εNd(t) = −17.2 to −9), suggest that the Laoniushan appinites likely originated from an ancient metasomatised mantle, followed by fractional crystallization in the petrogenetic process. The studied appinites were most likely generated in an intracontinental extensional environment in the Late Mesozoic.  相似文献   

15.
There has been little research on geochemistry and isotopic compositions in tholeiites of the Northern region from the Paraná Continental Flood Basalts (PCFB), one of the largest continental provinces of the world. In order to examine the mantle sources involved in the high-Ti (Pitanga and Paranapanema) basalt genesis, we studied Sr, Nd, and Pb isotopic systematics, and major, minor and incompatible trace element abundances. The REE patterns of the investigated samples (Pitanga and Paranapanema magma type) are similar (parallel to) to those of Island Arc Basalts' REE patterns. The high-Ti basalts investigated in this study have initial (133 Ma) 87Sr/86Sr ratios of 0.70538–0.70642, 143Nd/144Nd of 0.51233–0.51218, 206Pb/204Pb of 17.74–18.25, 207Pb/204Pb of 15.51–15.57, and 208Pb/204Pb of 38.18–38.45. These isotopic compositions do not display any correlation with Nb/Th, Nb/La or P2O5/K2O ratios, which also reflect that these rocks were not significantly affected by low-pressure crustal contamination. The incompatible trace element ratios and Sr–Nd–Pb isotopic compositions of the PCFB tholeiites are different to those found in Tristan da Cunha ocean island rocks, showing that this plume did not play a substantial role in the PCFB genesis. This interpretation is corroborated by previously published osmium isotopic data (initial γOs values range from +1.0 to +2.0 for high-Ti basalts), which also preclude basalt generation by melting of ancient subcontinental lithospheric mantle. The geochemical composition of the northern PCFB may be explained through the involvement of fluids and/or small volume melts related to metasomatic processes. In this context, we propose that the source of these magmas is a mixture of sublithospheric peridotite veined and/or interlayered with mafic components (e.g., pyroxenites or eclogites). The sublithospheric mantle (dominating the osmium isotopic compositions) was very probably enriched by fluids and/or magmas related to the Neoproterozoic subduction processes. This sublithospheric mantle region may have been frozen and coupled to the base of the Parana basin lithospheric plate above which the Paleozoic subsidence and subsequent Early Cretaceous magmatism occurred.  相似文献   

16.
Late Cenozoic intraplate basaltic rocks in northeastern China have been interpreted as being derived from a mantle source composed of DMM and EM1 components. To constrain the origin of the enriched mantle component, we have now determined the geochemical compositions of basaltic rocks from the active Baekdusan volcano on the border of China and North Korea. The samples show LREE-enriched patterns, with positive Eu and negative Ce anomalies. On a trace element distribution diagram, they show typical oceanic island basalt (OIB)-like LILE enrichments without significant Nb or Ta depletions. However, compared with OIB, they show enrichments in Ba, Rb, K, Pb, Sr, and P. The Nb/U ratios are generally within the range of OIB, but the Ce/Pb ratios are lower than those of OIB. Olivine phenocrysts are characterized by low Ca and high Ni contents. The radiogenic isotopic characteristics (87Sr/86Sr = 0.70449 to 0.70554; εNd = −2.0 to +1.8; εHf = −1.7 to +6.1; 206Pb/204Pb = 17.26 to 18.12) suggest derivation from an EM1-like source together with an Indian MORB-like depleted mantle. The Mg isotopic compositions (δ26Mg = −0.39 ± 0.17‰) are generally lower than the average upper mantle, indicating carbonates in the source. The 87Sr/86Sr ratios decrease with decreasing δ26Mg values whereas the 143Nd/144Nd and (Nb/La)N ratios increase. These observations suggest the mantle source of the Baekdusan basalts contained at least two components that resided in the mantle transition zone (MTZ): (1) recycled subducted ancient (∼2.2–1.6 Ga) terrigenous silicate sediments, possessing EM1-like Sr–Nd–Pb–Hf isotopic signatures and relatively high values of δ26Mg; and (2) carbonated eclogites with relatively MORB-like radiogenic isotopic compositions and low values of δ26Mg. These components might have acted as metasomatizing agents in refertilizing the asthenosphere, eventually influencing the composition of the MTZ-derived plume that produced the Baekdusan volcanism.  相似文献   

17.
ABSTRACT

Late Jurassic ultramafic lamprophyre (UML) sills and dikes occur as 3 km-long intrusions within the allochthonous Whara Formation of the Batain nappes, eastern Oman. The sills and dikes comprise macrocrystic phlogopite and spinel-bearing aillikite and damtjernite. Aillikite is a light grey, massive fine-grained tuffaceous rock with euhedral laths of mica, while damtjernite is a dark grey, medium- to coarse-grained rock with abundant pelletal lapilli and globular segregationary textures. Both lithologies are composed of calcite, phlogopite, apatite, magnetite, spinel, diopside, and richterite. Orthoclase occurs only within damtjernite. The rocks are strongly silica undersaturated (17.6–33.7 wt.% SiO2), with low MgO (4.7–10.2 wt. %) and high Al2O3 (3.5–8.6 wt.%). The aillikites are distinguished from the damtjernites by their lower SiO2, Al2O3, and Na2O abundances, and their higher MgO, CaO, and P2O5 contents. The rare earth element (REE) patterns of both rock types are similar and show strong light REE (LREE) enrichment. Both are enriched in Ba, Th, U, Nb, and Ta, with normalized concentrations of up to 1000 times those of primitive mantle. Relative depletions are apparent for high REE (HREE), K, Rb, Pb, Sr, P, Zr, and Hf. The rocks have initial 87Sr/86Sr ratios of 0.70435–0.70646, whereas initial 143Nd/144Nd ratios vary between 0 · 512603 and 0 · 512716 (εNdi 2.6–3.2). Pb isotopic ratios are more varied among the aillikites and damtjernites: 208Pb/204Pbi = 38.97–39.39 and 207Pb/204Pbi = 15.35–15.58, 206Pb/204Pbi = 18.08–18.96. The abundance of phlogopite, apatite, and rutile and enrichment in LREEs, Ba, Th, U, Nb, and Ta in the Sal UMLs suggest metasomatic enrichment of these rocks following a low degree of partial melting of a depleted source region. Ar–Ar age dating of phlogopite macrocrysts from the aillikites and damtjernites (154 and162 Ma, respectively) correlates with large-scale tectonic events recorded in the proto-Indian Ocean at 140–160 Ma.  相似文献   

18.
The widespread Emeishan igneous province in southwestern China comprises the Emeishan continental flood basalts (ECFB) and associated mafie-ultramafic intrusions. The ECFB have variable SiO2, ranging from 43.6 to 52.1 wt%, Al2O3 from 5.0 to 12.6 wt%, and total alkali (K2O + Na2O) from 0.7 to 6.5 wt%. These oxides exhibit negative correlations with MgO (5.4 - 23.1 wt%), implying fractional crystallization of olivine and clinopyroxene, which occur as phenocrysts in the rocks. Linear correlations between Zr, Nb, and La suggest that crustal contamination is not important. The primitive-mantle-normalized trace-element patterns show that the ECFB are enriched in high-field-strength trace elements, large-ion-lithophile elements, and light-rare-earth elements, similar to ocean-island basalt. Incompatible element ratios of the ECFB, such as Zr/Nb (7-10), Th/La (0.1-0.15), and Rb/Nb (0.9-1.7), differ from those of primitive mantle, N-MORB, and continental crust, but are similar to ocean-island basalts from an enriched mantle source (EM-1). However, the ECFB have isotopic ratios (143Nd/144Nd = 0.51229 -0.51276 and 87Sr/86Sr = 0.70480-0.70647) that imply that the ECFB were derived from a homogeneous, primitive lower mantle carried upward by a mantle plume.

We propose that the original melts derived from the mantle plume were contaminated through interaction at shallower depth with an enriched lithospheric mantle. This model suggests that the lithospheric mantle beneath the ECFB was modified by subduction of an oceanic slab.  相似文献   

19.
Co-genetic pegmatites associated with the granite of the Kawadgaon area in the Bastar craton, Central India, contain a wide range of ore minerals of Nb, Ta, Be, Sn, Zr, Ti, and REE, including columbite-tantalite, ixiolite, pseudo-ixiolite, wodginite, tapiolite, microlite, fersmite, euxenite, aeschynite, beryl, cassiterite, monazite, xenotime, zircon, ilmenite, triplite, and magnetite. There is a distinct vertical zonation between the rare metal and tin pegmatites in apical parts of the host granite. Geochemically, these are LCT-S type, beryl-columbite-phosphate pegmatites that have notably high contents of SiO2 (av. 73.80%), Rb (av. 381 ppm), and Nb (av. 132 ppm). The investigated granites probably were derived from the melting of older crustal rocks, as indicated by a high initial 87Sr/86Sr isotopic ratio, and the major-element geochemistry of the granites and pegmatites. Plots of mol. CaO/(MgO+FeOt) vs. mol. Al2O3/(MgO+FeOt) suggest that the source rock was pelitic metasediments. Based on the available data, it is postulated that the derivation of pegmatites from the parent granite occurred shortly after granite emplacement in the late Archaean-early Proterozoic (~2500 Ma). The K/Rb, Ba/Rb, and Rb/Sr ratios of the felsic bodies reveal that a substantial part of the granite formed from evolved melts, and further fractionation produced the co-genetic pegmatites and associated rare metal and rare earth deposits.  相似文献   

20.
Geological and geochemical data indicate that the formation of the granulite-like rocks in the contact aureole of the Yurchik gabbronorite intrusion of the Ganal Range, Kamchatka, was caused by the contact metamorphism, metasomatism, and local melting of the initial volcanosedimentary rocks of the Vakhtalka Sequence of the Ganal Group. The temperature in the inner part of the aureole reached 700–800°C and caused the transformation of the basic volcanic rocks of the sequence into two pyroxene-plagioclase, clinopyroxene-amphibole-plagioclase, and amphibole-plagioclase hornfelses, while sedimentary rocks were converted into garnet-biotite ± cordierite hornfelses. The hornfelsed basic volcanic rocks were locally subjected to metasomatic alteration and magmatic replacement with formation of biotite-orthopyroxene-plagioclase metasomatic bodies containing biotite-orthopyroxene-plagioclase ± garnet veinlets and aggregates. During these processes, sedimentary interlayers were converted into garnet enderbites at 700–800°C and 3.2–4.8 kbar. The comparison of the chemical composition of basic volcanic rocks of the Vakhtalka Sequence and their transformation products indicates that the metasomatic alteration and magmatic replacement correspond to siliceous-alkaline metasomatism (granitization) and cause subsequent and uneven influx of SiO2, Al2O3, Na2O, K2O, Rb, Ba, Zr, Nb, and Cl and removal of Fe, Mg, Mn, Ca, Cr, Co, Ti, Y, and S. REE data on basic metavolcanic rocks, hornfelses, and metasomatites suggest that the processes of hornfelsation, metasomatism, and magmatic replacement of the initial volcanic rocks were accompanied by significant increase in LREE and slight decrease in HREE. The Sr and Nd isotope study of the rocks in the aureole showed that the initial basic volcanic rocks of the Vakhtalka Sequence are isotopically close to both mature island arc tholeiites and mid-ocean ridge basalts. The metasomatic alteration and magmatic replacement of volcanic rocks in the aureole lead to the decrease of 143Nd/144Nd and increase of 87Sr/86Sr approximately parallel to mantle array. Pb isotopic ratios in the studied rocks become more radiogenic from initial metavolcanic rocks to metasomatites. It is suggested that the processes of metamorphism, metasomatism, and magmatic replacement were caused by highly mineralized mantle fluids, which percolated along magmatic channels serving as pathways for gabbroid magma.  相似文献   

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