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1.
Antitaxial non‐deforming strain fringes from Lourdes, France, show complex quartz, calcite and chlorite fibre patterns that grew around pyrite in a slate during non‐coaxial progressive deformation. Development of these fringes was modelled using a computer program ‘Fringe Growth 2.0’ which can simulate incremental growth of crystal fibres around core‐objects of variable shape. It uses object‐centre paths as input, which are obtained from fibre patterns in thin section. The numerical experiments produced fibre patterns that show complex intergrowth of displacement‐controlled, face‐controlled and intermediate fibres similar to those in the natural examples. The direction of displacement‐controlled growth is only dependent on the relative movement between core‐object and fringe, so that core‐object rotation with respect to the fringe influences the fibre patterns and produces characteristic asymmetric fibre curvature. Object‐centre paths should be used for kinematic analysis of strain fringes instead of single fibres since these paths represent the fringe as a whole. The length along the path can be interpreted in terms of finite strain and path curvature in terms of rigid body rotation of fringes with respect to an external reference frame.  相似文献   

2.
Measurements of total, incremental and progressive strains associated with the development of small scale crenulation cleavage in some low-grade metamorphic rocks from Australia and Switzerland are applied to a discussion of the mechanical significance of the cleavage.Limits are placed on the amount of incremental and total slip or simple shear possible along the cleavage by the observation that the XY principal plane trace of bulk total crenulation strain coincides within 4° of the crenulation cleavage trace in all cases where this strain has been measured or estimated. The measurements are made on eight specimens using deformed porphyroblasts, crystal fibres in pressure-shadows around pyrite and flattened folds and include deformations with coaxial and non-coaxial histories.Further measurements derived from pressure-shadow fibres (eight specimens) show that the style and orientation of incremental deformation are essentially independent of the crenulation cleavage, except for a limit (43°) to the obliquity of the principal incremental extension axis during a given cleavage episode. The only special deformation related to the cleavage is the coaxial one. An indication of passive cleavage behaviour at high strain is shown by the progressive strain history of one specimen. Evidence for passive rotation of a transected axial plane is shown by another. A model is proposed to account for these observations, especially the conditions necessary for initiation and continued development of a new cleavage fabric.Some further applications of existing strain measurement techniques are described: of the Rf/Øf method to heterogeneously superposed tectonic strains and of an improved procedure of t′α/α flattening analysis.  相似文献   

3.
Calcite in former aragonite–dolomite-bearing calc-schists from the ultrahigh-pressure metamorphic (UHPM) oceanic complex at Lago di Cignana, Valtournanche, Italy, preserved different kinds of zoning patterns at calcite grain and phase boundaries. These patterns are interpreted in terms of lattice diffusion and interfacial mass transport linked with a heterogeneous distribution of fluid and its response to a changing state of stress. The succession of events that occurred during exhumation is as follows: As the rocks entered the calcite stability field at T=530–550 °C, P ca. 1.2 GPa, aragonite occurring in the matrix and as inclusions in poikilitic garnet was completely transformed to calcite. Combined evidence from microstructures and digital element distribution maps (Mn-, Mg-, Fe- and Ca–Kα radiation intensity patterns) indicates that transformation rates have been much higher than rates of compositional equilibration of calcite (involving resorption of dolomite and grain boundary transport of Mg, Fe and Ca). This rendered the phase transformation an isochemical process. During subsequent cooling to T ca. 490 °C (where lattice diffusion effectively closed), grains of matrix calcite have developed diffusion-zoned rims, a few hundred micrometres thick, with Mg and Fe increasing and Ca decreasing towards the phase boundary. Composition profiles across concentrically zoned, large grains in geometrically simple surroundings can be successfully modelled with an error function describing diffusion into a semi-infinite medium from a source of constant composition. The diffusion rims in matrix calcite are continuous with quartz, phengite, paragonite and dolomite in the matrix. This points to an effective mass transport on phase boundaries over a distance of several hundred micrometres, if matrix dolomite has supplied the Mg and Fe needed for incorporation in calcite. In contrast, diffusion rims are lacking at calcite–calcite and most calcite–garnet boundaries, implying that only very minor mass transport has occurred on these interfaces over the same T–t interval. From available grain boundary diffusion data and experimentally determined fluid–solid grain boundary structures, inferred large differences in transport rates can be best explained by the discontinuous distribution of aqueous fluid along grain/phase boundaries. Observed patterns of diffusion zoning indicate that fluid was distributed not only along grain-edge channels, but spread out along most calcite–white mica and calcite–quartz two-grain junctions. On the other hand, the inferred non-wetting of calcite grain boundaries in carbonate-rich domains is compatible with fluid–calcite–calcite dihedral angles >60° determined by Holness and Graham (1995) for a wide range of fluid compositions under the P–T conditions of interest. Whereas differential stress has been very low at the stage of diffusion zoning (T > 490 °C), it increased as the rocks were cooling below 440 °C (at 0.3–0.5 GPa). Dislocation creep and the concomitant increase of strain energy in matrix calcite induced migration recrystallisation of high-angle grain boundaries. For that stage, the compositional microstructure of recrystallised calcite grain boundary domains indicates significant mass transport along calcite two-grain junctions, which at the established low temperatures is likely to have been accomplished by ionic diffusion within a hydrous grain boundary fluid film (“dynamic wetting” of migrating grain boundaries). Received: 10 January 2000 / Accepted: 10 April 2000  相似文献   

4.
The Bunker Hill Mine in Idaho's Coeur d'Alene mining district produces approximately 10 m3/minute of acid water containing high concentrations of heavy metals. Field and laboratory studies indicate that much of the acid water is produced in a single ore body in the upper part of the mine. The ore of this body contains mainly sphalerite, galena, and pyrite in a siderite-quartz gangue. Ground water recharges this ore body through a near-vertical zone of high permeability, which is the result of mining by the caving technique. Ore samples from the caving area contained oxidized forms of iron and produced acid in a laboratory leaching test. Leaching experiments with several ore samples from the mine also indicated that the ratio of pyrite to calcite in the samples strongly controlled the resultant pH values. Oxidation of pyrite to sulfuric acid and compounds of iron is apparently responsible for the production of acid water in the mine. In contrast, dissolution of calcite in water results in a basic solution, with pH around 8.3, that can neutralize the acid produced by the oxidation process. Methods for prevention of acid mine drainage in this and other similar mines are noted.  相似文献   

5.
One of the key-principles of the iron-sulphur world theory is to bring organic molecules close enough to interact with each other, using the surface of pyrite as a substrate in a hydrothermal setting. The present paper explores the relationship of pyrite and organic matter in a hydrothermal setting from the geological record; in hydrothermal calcite veins from Carboniferous limestones in central Ireland. Here, the organic matter is accumulated as coatings around, and through, pyrite grains. Most of the pyrite grains are euhedral-subhedral crystals, ranging in size from ca 0.1-0.5 mm in diameter, and they are scattered throughout the matrix of the vein calcite. The organic matter was deposited from a hydrothermal fluid at a temperature of at least 200°C, and gives a Raman signature of disordered carbon. This study points to an example from a hydrothermal setting in the geological record, demonstrating that pyrite can have a high potential for the concentration and accumulation of organic materials.  相似文献   

6.
With the help of two-dimensional numerical models this paper investigates three aspects of heterogeneous deformation around rigid objects: (1) the nature of particle paths; (2) the development of strain shadow zones; and (3) the drag patterns of passive markers. In simple shear, spherical objects develop typically a concentric vortex motion, showing particle paths with an eye (double-bulge)-shaped separatrix. The separatrix has no finite dimension along the central line, parallel to the shear direction. Under a combination of pure shear and simple shear, the particle paths assume a pattern with a bow-tie shaped separatrix. With increase in the ratio of pure shear to simple shear (Sr), the separatrix around the object shrinks in size. The axial ratio of the object (R) is another important factor that controls the geometry of particle paths. When R<1.5, the loci of a particle close to the object form an elliptical shell with the long axis lying along the central line. With increase in axial ratio R, the loci form a doublet elliptical shell structure. Objects with R>3 do not show closed particle paths, but give rise to elliptical or circular spiral particle paths.

The development of strain shadow zones against equant rigid bodies depends strongly on the strain ratio Sr. When Sr=0 (simple shear), they develop opposite to the extensional faces of the object, forming a typical σ-type tail. The structure has a tendency to die out with an increase in the pure shear component of the bulk deformation (Sr). The initial angle of the long axis of the object with the shear direction (φ) and the axial ratio of the object (R) determine the development of strain shadow zones near inequant rigid objects. Objects with large R and φ between 60 and 120° form pronounced zones of low finite strain, giving rise to strain shadow structures. A geometrical classification of diverse drag patterns of passive markers around rigid objects is presented along with their conditions of formation.  相似文献   


7.
Attempts to use rock deformation experiments to examine the elastic and plastic behaviour of polymineralic rocks are hampered by the fact that usually only whole sample properties can be monitored as opposed to the separate contribution of each phase. To circumvent this difficulty, room-temperature, uniaxial compression experiments were performed in a neutron beam-line on a suite of calcite + halite samples with different phase volume proportions. By collecting diffraction data during loading, the elastic strain and hence stress in each phase was determined as a function of load to bulk strains of 1–2%. In all cases, the calcite behaved elastically while the halite underwent plastic yielding. During the fully elastic part of the deformation, the composite elastic properties and the within-phase stresses are well-described both by recent shear lag models and by analyses based on Eshelby's solution for the elastic field around an ellipsoidal inclusion in a homogeneous medium. After the onset of yielding, the halite in situ stress/total strain curve may be reconstructed using the rule of mixtures. At calcite contents of greater than 30%, the in situ halite response may be significantly weaker or stronger than that obtained at lesser calcite contents. The results highlight the potential that such techniques offer for developing an explicitly experimental approach for determining the influence of microstructural variables on the mechanical properties of polymineralic rocks.  相似文献   

8.
This paper studies the flow heterogeneity around porphyroclasts associated with greenschist facies deformation of a calcite marble shear zone. Microstructural data from electron backscatter diffraction analyses (EBSD) are used to constrain the flow mechanics of this dominantly non-coaxial type of deformation. The microstructure of the undisturbed ultramylonite (grain-size range 5–100 μm, mean 40 μm) is interpreted to represent steady-state (time-independent) flow conditions with flow planes parallel to the shear zone boundary. Single calcite porphyroclasts (grain-size 1–3 mm) caused flow perturbation in the fine-grained marble ultramylonite. It is the shape, in particular, of these rigid porphyroclasts that controls their rotational behaviour during deformation and, therefore, the development of specific flow fabrics. The flow planes around elongated-rhomboidal, stable porphyroclasts change the orientation to become roughly parallel to the porphyroclast margin, whereas the geometry of flow planes around nearly equant, rotating porphyroclasts describes a δ-type flow pattern. We infer that to some extent decoupling at the clast–matrix interface has occurred to guarantee a stable orientation of elongated porphyroclasts, but was not sufficient to reduce the rotation rate of equant clasts to zero. According to the flow deflection, the general crystallographic preferred orientation (CPO) with its single c-axis maximum perpendicular to the flow plane is rotated about an axis which is (sub)parallel to the kinematic rotation axis of the shear zone. Ultramylonite microstructures, CPOs and misorientation data are best explained by the dual operation of grain-size-insensitive (dislocation creep with recovery and recrystallization) and grain-size-sensitive (diffusion creep) mechanisms. The limited grain-size reduction around porphyroclasts suggests that the grain-size-insensitive mechanisms controlled rheology.  相似文献   

9.
Molar tooth (MT) structures are enigmatic, contorted millimetre‐ to decimetre‐long veins and spheroids of microcrystalline calcite that formed during very early diagenesis in Precambrian sediments. MT structures in the ca 2·6 Ga Monteville Formation are 600–800 Myr older than previously reported occurrences and establish that conditions necessary for MT genesis were met locally throughout much of the Precambrian. In the Monteville Formation, MT structures were formed shallow subtidally, extending to depths near storm wave base, in shale host sediments intercalated with storm‐generated carbonate sand lenses. They are filled with microcrystalline calcite and rare pyrite. Microcrystalline calcite identical to that in MT structures fills other pore space, including porosity between grains in carbonate sand lenses, moldic porosity in sand grains, sheet cracks in columnar stromatolites, and shallow cracks on sandy bedding planes. Relationships in the Monteville Formation demonstrate that microcrystalline CaCO3 precipitated in fluid‐filled cracks and pores; microcrystalline calcite characteristics, as well as the paucity of carbonate mud in host rocks, are inconsistent with injection of lime mud as the origin of MT structures. Locally, MT cracks were filled by detrital sediment before or during precipitation. Precipitation occurred in stages, and MT CaCO3 evolved from granular cores to a rigid mass of cores with overgrowths – allowing both plastic and brittle deformation of MT structures, as well as reworking of eroded MT structures as rigid clasts and lime mud. Crystal size distributions and morphology suggest that cores precipitated through nucleation, Ostwald ripening and size‐dependent crystal growth, whereas overgrowths formed during size‐independent crystal growth.  相似文献   

10.
M.-A. Kaczmarek  S.M. Reddy  N.E. Timms 《Lithos》2011,127(3-4):414-426
Magmatic zircons within two sheared gabbroic dykes from the peridotitic massif of Lanzo (Western-Alps, Italy) revealed evolution of deformation from crystal plasticity to rigid body rotation during shear zone evolution. This is the first time that multiple zircon grains have been analysed in a kinematic context in a shear zone. Zircon grains recorded crystal plastic deformation activating the commonly inferred <100>{001} and <001>{100} glide-systems to the newly identified <001>{110} glide-system. The exact selection of glide-system could be dependant of deformation conditions such as pressure, temperature, and strain rate. Moreover, the activation of one or several glide-systems within a single grain could be favoured by the primary orientation of the grains combined with a high strain rate. In these sheared gabbros, the deformation mechanisms evolve from plastic deformation at low strain rate conditions to increase strain, strain softening and localisation of deformation. The progressive shear zone development and the softening of the matrix relative to the zircon has lead to a switch from crystal-plasticity to rigid body rotation of zircon. The zircon grains rigid body rotation involved that their long axes became parallel to the lineation of the shear zone, causing reorientation and dispersion of the misorientation axes away from kinematic Y.  相似文献   

11.
Two methods are introduced for identifying states of pervasive prefold strain in the total-strain field of large domes or basins. The first method relies on the symmetry rule and is restricted to structures in which the planes of effective symmetry of the total-strain field are non-coincident with those of the fold form. The second method seeks to demonstrate the existence of a strain-induced anisotropy (foliation or lineation) prior to upright folding, and utilizes narrow décollement zones within homogeneous rock units of domes or basins. The methods are applied to large oval structures in two Precambrian gneiss terranes of Ontario.  相似文献   

12.
《Applied Geochemistry》1998,13(2):257-268
We report the hydrogeochemical modeling of a complicated suite of reactions that take place during the oxidation of pyrite in a marine sediment. The sediment was equilibrated in a column with MgCl2 solution and subsequently oxidized with H2O2. The oxidation of pyrite triggers dissolution of calcite, cation and proton exchange, and CO2 sorption. The composition of the column effluent was modeled with PHREEQC, a hydrogeochemical transport model. The model was extended with a formal ID transport module which includes dispersion and diffusion. The algorithm solves the advection-reaction-dispersion equation with explicit finite differences in a split-operator scheme. Also, kinetic reactions for pyrite oxidation, calcite dissolution and precipitation, and organic C oxidation were included. Kinetic relations for pyrite oxidation and calcite dissolution were taken from the literature, and a coefficient equivalent to the ratio A/V (surface over volume), was adjusted to fit the experimental data. The comparison of model and experiment shows that ion exchange and sorption are dominant chemical processes in regulating and buffering water quality changes upon the oxidation of pyrite. Cation exchange was assigned to the colloidal fraction ( < 2 μm) and deprotonated organic matter, proton buffering to organic matter, and CO2 sorption to amorphous Fe-oxyhydroxide. These processes have been neglected in earlier modeling studies of pyrite oxidation in natural sediments.  相似文献   

13.
Psammites from the Ballarat slate belt in SE Australia exhibit well-developed differentiated or spaced cleavage defined by alternating phyllosilicate- and quartz-rich domains (termed P- and Q-domains, respectively). Strain estimates derived from independent microstructural and chemical observations suggest that the P-Q fabrics developed in response to plane-strain deformation dominated by solution transfer with the principal finite shortening in the P-domains approximately twice that in the adjacent Q-domains. Significant finite extensions are indicated by ubiquitous quartz-albite-chlorite overgrowths in both P- and Q-domains, while pressure-shadow development around syntectonic pyrite porphyroblasts suggest finite extension of at least 100%. This estimate is comparable with the extension predicted for constant-volume deformation and consequently there appears to have been no significant bulk material loss or gain on the hand-specimen scale. These observations are consistent with solute transfer scales as little as a few centimetres via diffusion in a stationary fluid and do not require, although do not necessarily preclude, large-scale advective fluid transport through the slate belt during cleavage formation as suggested in previous studies.  相似文献   

14.
Twenty crescent-shaped diapiric models of silicone putty were made in two high-capacity centrifuges. The strain distribution within the models was studied by means of coloured rectangular elements, a method which led to large errors at random locations. Most elements affected by large errors could be identified in repeated experiments.The deformation pattern within the central segment of the diapiric ridges is dominated by two large regions of contrasting principal strain normal to the radial symmetry plane (axial plane of the crescents). This principal strain is tensile near the concave boundary of a ridge and compressive near the convex boundary of a ridge.Within the radial symmetry plane, the orientation pattern of long axes of the total-strain ellipses resembles an open fan which diverges toward the crest of the diapiric ridge. In the high-amplitude models, there is a narrow crestal region in which the long axes are subhorizontal. A similar region has been noted in comparable models of cylindrical diapiric ridges.In one of our models (WMS 20), the arcuate hinge line has pronounced culminations at both ends of the diapiric ridge. This results in a strong crestal depression at the radial symmetry plane where the strain analysis was performed. Accordingly, the characteristic region of tensile normal strain occupies most of the radial section.  相似文献   

15.
Stable oxygen isotopic fractionation during inorganic calcite precipitation was experimentally studied by spontaneous precipitation at various pH (8.3 < pH < 10.5), precipitation rates (1.8 < log R < 4.4 μmol m− 2 h− 1) and temperatures (5, 25, and 40 °C) using the CO2 diffusion technique.The results show that the apparent stable oxygen isotopic fractionation factor between calcite and water (αcalcite–water) is affected by temperature, the pH of the solution, and the precipitation rate of calcite. Isotopic equilibrium is not maintained during spontaneous precipitation from the solution. Under isotopic non-equilibrium conditions, at a constant temperature and precipitation rate, apparent 1000lnαcalcite–water decreases with increasing pH of the solution. If the temperature and pH are held constant, apparent 1000lnαcalcite–water values decrease with elevated precipitation rates of calcite. At pH = 8.3, oxygen isotopic fractionation between inorganically precipitated calcite and water as a function of the precipitation rate (R) can be described by the expressions
at 5, 25, and 40 °C, respectively.The impact of precipitation rate on 1000lnαcalcite–water value in our experiments clearly indicates a kinetic effect on oxygen isotopic fractionation during calcite precipitation from aqueous solution, even if calcite precipitated slowly from aqueous solution at the given temperature range. Our results support Coplen's work [Coplen T. B. (2007) Calibration of the calcite–water oxygen isotope geothermometer at Devils Hole, Nevada, a natural laboratory. Geochim. Cosmochim. Acta 71, 3948–3957], which indicates that the equilibrium oxygen isotopic fractionation factor might be greater than the commonly accepted value.  相似文献   

16.
Theoretical and experimental results show that determination of sense of rigid rotation from drag-patterns of foliation around a rigid spherical inclusion (such as a porphyroblast of garnet) is not as simple as was previously thought. An asymmetric drag-pattern can develop even when the bulk deformation is non-rotational, provided a pre-existing foliation was initially at an angle to the principal axes of strain.In simple shear, the drag-pattern of a pre-existing foliation around the rigid inclusion may belong to any one of the following four types:
1. (1) asymmetric pattern, with the same sense of drag all over the contact.
2. (2) more or less symmetrical pattern, with different senses of drag at different parts of the contact.
3. (3) asymmetrical pattern, with different senses of drag.
4. (4) pattern with inward bowing of foliation (i.e. convex toward the rigid inclusion).
The geometry of the distorted foliation will depend on the amount of simple shear and the initial angle between the pre-existing foliation and the direction of simple shear.If the development of schistosity and the subsequent development of drag around a rigid porphyroblast are results of the same continuous simple-shear movement, a wellpreserved drag-pattern may be utilized to confirm that the schistosity initially developed perpendicular to the maximum finite compressive strain, provided the total deformation is not very large.  相似文献   

17.
A series of large diameter calcite–muscovite aggregates has been prepared from calcite and muscovite powders, in order to gain a better understanding of how texture develops in impure carbonate rocks. The development of the microstructure and the crystallographic preferred orientation (CPO, texture) during the preparation process is described. The synthetic rocks have been fabricated from powders of calcite and muscovite by uniaxial cold-pressing at loads up to 400 MPa and subsequent hot isostatic pressing (HIPping) at pressures of 150 to 170 MPa and a temperature of 670 °C. The resulting textures and microstructures are homogeneous throughout the samples. The calcite CPO is generated by rigid body rotation and twinning during cold-pressing and is not significantly altered by recrystallization during HIPping. Grain growth during HIPping is observed in pure calcite samples, but is inhibited through high porosity and the presence of muscovite in the mixed aggregates. The preferred orientation of the calcite c-axes is found to increase with increasing uniaxial cold pressure, and to be independent of the muscovite content. The magnetic bulk susceptibility of the starting material has been changed by the formation of ferromagnetic impurities during fabrication. Comparison of the samples to natural calcite fabrics from fault zones show the potential of the experiments and fabric analyses presented to analyze and to better understand the deformation mechanisms of fault zones.  相似文献   

18.
Detailed studies of a new, complete Marl Slate core in South Yorkshire have provided information on isotopic (δ13C, δ18O, δ34S) and geochemical variations (trace elements and C/S ratio) which enable the formulation of a model for carbonate and sulphide precipitation in the Late Permian Zechstein Sea. Calcite and dolomite are intimately associated; the fine lamination, organic character and absence of benthos in the sediments are indicative of anoxic conditions. Lithologically the core can be divided into a lower, predominantly sapropelic Marl Slate (2 m) and an upper Transition Zone (0·65 m) of alternating sapropel and calcite-rich and dolomite-rich carbonates. C/S ratios are 2·22 for the Marl Slate and 1·72 for the Transition Zone respectively, both characteristic of anoxic environments. δ18O in the carbonates shows a large and systematic variation closely mirrored by variations in calcite/dolomite ratio. The results suggest a fractionation factor equivalent to a depletion of 3·8% for 18O and 1·5% for 13C in calcite. The δ34S values of pyrite are isotopically light (mean value = - 32·7%) suggesting a fractionation factor for the Marl Slate of almost 44%, typical of anoxic basins. The results are related to stratification in the early Zechstein Sea. Calcite was precipitated in oxic upper layers above the halocline. Below the oxic/anoxic boundary framboidal pyrite was precipitated, resulting in lower sulphate concentration and elevated Mg/Ca ratio (due to calcite precipitation). As a result of this, dolomite formation occurred below the oxic/anoxic interface, within the anoxic water column and in bottom sediments. Variations in calcite/dolomite ratios, and isotopic variations, are thus explained by fluctuations in the relative level of the oxic/anoxic boundary in the Zechstein Sea.  相似文献   

19.
The rim-forming reaction quartz + olivine = orthopyroxene is used to investigate the effect of matrix rheology on rim growth rates. Orthopyroxene rim growth around olivine grains in quartz matrix is compared to rim growth around quartz grains in an olivine matrix. At constant P–T , within one single capsule, orthopyroxene rims grow faster around quartz clasts in olivine matrix than around olivine clasts in quartz matrix. Fourier transform infra-red spectra indicate that the entire samples are water saturated because of water adsorption on the reactant grain surfaces. The increased orthopyroxene growth rates in olivine matrix as opposed to quartz matrix are interpreted in terms of matrix rheology, where in the two different matrix-inclusion arrangements the olivine matrix behaves 'softer' and the quartz matrix 'more rigid'. The strain energy associated with accommodation of the negative reaction volume is higher for the quartz than the olivine matrix and reduces the free energy that drives orthopyroxene rim growth. Growth textures in both kinds of orthopyroxene rims indicate that the diffusivity of MgO slightly exceeds the diffusivity of SiO2. The relative mobility of MgO and SiO2 at given P , T , f H2O seems to be controlled by energy minimization during orthopyroxene growth at the compressive Ol/Opx interface. Our experiments provide evidence for two previously overlooked effects relevant to rim growth reactions in metamorphic rocks: (i) diffusivity along chemical potential gradients to reaction sites is a function of rheology and (ii) the relative diffusivity of components during reaction rim or corona growth is a function of local volume changes at the rim's interfaces.  相似文献   

20.
The microstructural evolution of polymineralic contact metamorphic calcite marbles (Adamello contact aureole) with variable volume fractions of second-phase minerals were quantitatively analyzed in terms of changes in grain size and nearest neighbor relations, as well as the volume fractions, dispersion and occurrences of the second phases as a function of changing metamorphic conditions. In all samples, the calcite grain size is controlled by pinning of grain boundaries by second phases, which can be expressed by the Zener parameter (Z), i.e., the ratio between size and volume fraction of the second phases. With increasing peak metamorphic temperature, both the sizes of matrix grains and second phases increase in dependence on the second-phase volume fraction. Two distinct coarsening trends are revealed: trend I with coupled grain coarsening limited by the growth of the second phases is either characterized by large-sized or a large number of closely spaced-second phase particles, and results finally in a dramatic increase in the calcite grain size with Z. Trend II is manifest by matrix controlled grain growth, which is retarded by the presence of single second-phase particles that are located on calcite grain boundaries. It is supported by grain boundary pinning induced by triple junctions, and the calcite grain size increases moderately with Z. The two different grain coarsening trends manifest the transition between relatively pure polymineralic aggregates (trend II) and microstructures with considerable second-phase volume fractions of up to 0.5. The variations might be of general validity for any polymineralic rock, which undergoes grain coarsening during metamorphism. The new findings are important for a better understanding of the initiation of strain localization based on the activation of grain size dependent deformation mechanisms.  相似文献   

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