共查询到18条相似文献，搜索用时 156 毫秒
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硅灰石表面改性实验研究 总被引：18，自引：0，他引：18
实验以湖北大冶硅灰石为原料，初步探讨了硅灰石表达改性的工艺条件。经沉降体积法、表面接触角、红外光谱等方法检测和填充橡胶试验证实，硅灰石得到了改性且其填充性能有明显的提高。 相似文献
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选用气流磨超音速气流作为机械力,对硅灰石、硬脂酸进行超细粉碎－表面改性。应用透射电子显微镜分析、观察硅石灰／硬脂酸复合粉体界面微观形貌及成分（Ｃａ、Ｓｉ、Ｃ）的变化规律。ＴＥＭ能谱分析结果表明：从硅灰石到硬脂酸,Ｃａ、Ｓｉ含量逐渐降低,Ｃ含量则逐渐升高。 相似文献
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纤维状硅灰石/聚丙烯复合材料界面性能研究 总被引：3，自引：0，他引：3
以未改性纤维状硅灰石粉、硬脂酸改性纤维状硅灰石粉与聚丙烯混炼制成聚丙烯复合材料。利用平衡接触角仪间接测得聚丙烯基体和矿物粉体的表面自由能。计算出纤维状硅灰石／聚丙烯界面的粘附功Wa和界面张力γSL等热力学参数。分析探讨了聚丙烯及矿物粉体表面特性、纤维状硅灰石／聚丙烯界面行为与复合材料力学性能的关系。结果表明：复合两相界面的粘附功Wa和界面张力γSL,共同作用影响复合材料的强度。界面粘附功Wa大,说明两相结合牢固．则复合材料强度大;界面张力γSL小。则粉体在基体中的分散性能好,有利于增加两相间总的接触面积,使复合材料强度增大。研究复合两相的界面行为．找出粘附功Wa和界面张力γSL间的最佳组合。将有助于设计出性能优良的复合材料。为合理地选择和改性填料提供科学依据。 相似文献
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硅灰石的表面改性与特性研究 总被引：2，自引：0，他引：2
利用湖北某矿生产的硅灰石粉，探讨了以兼价的表面活性剂ＡＳ对硅灰石进行表面改性的条件流程，改性后的硅灰石转变为生硅灰石，并对其特性进行了研究，已用于管带橡胶，ＰＶＣ电缆填料和涂料颜料的试验。 相似文献
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非金属矿物作为填料应用，可以发挥矿物的物理、化学、光、电、热学功能，对高分子树脂进行改性，提高综合性能。高性能复合材料的研制开发已成为促进高科技发展的主流。矿物填料工艺学是非金属矿物走向高分子材料领域的应用科学，目前已发展到研究矿物与树脂的微粒子“界面工程”微观学术领域，并利用矿物功能来改善复合材料的界面结构，提高力学性能。 相似文献
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改性粘土矿物在橡胶中的应用 总被引：7，自引：0，他引：7
改性矿物取代部分炭黑做橡胶填料的研究是目前国内外材料及化工领域为活跃的科研课题，粘土矿物结构独特，有较高的化学反应活性，具有吸附某些离子并把这些离子保护于交换状态的性能，这些性能特点使粘土矿物经表面改性填充于橡胶成为可能，粘土矿物填料的研究主要包括粘土矿物的结构特点，在橡胶中的作用，典型的粘土矿物寺料的性能特点，尤其是针对不同的橡胶体系和性能要求，选取适当的改性剂及改性处理方法及增大填料的填充量等问题，这方面研究的进展对我国矿产资源的开发利用及橡胶工业的发展有着重要意义。 相似文献
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A mechanism for the solid state replacement of clinopyroxene by pyroxenoids has been derived from consideration of the crystal structures. The mechanism involves the propagation of partial dislocations, with Burgers vectors of 1/4 \([2\bar 3\bar 1]\) , through the clinopyroxene matrix to generate a resultant shear; the passage of one dislocation gives rise to a single chain-repeat unit of wollastonite in each silicate chain. Pyroxenoids may thus be formed from clinopyroxene by the periodic introduction of these dislocations on parallel slip-planes, and pyroxenoid to pyroxenoid inversions may proceed by the introduction and removal of such shears by the propagation of the correct combination of partial dislocations. The Burgers vectors for these dislocations in each of the pyroxenoid mineral structures has been calculated. A two step mechanism is proposed for clinopyroxene to bustamite, and pyroxenoid to bustamite inversions, which utilises the same shear as above which generates a wollastonite structure. The second step is a shear of 1/2[001] on the plane \((1\bar 10)\) of this wollastonite intermediate, to give a bustamite structure. 相似文献
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矿物粉体作为硅橡胶增强填料尚不多见。传统的硅橡胶增强填料是气相白碳黑。它的粒度细,比表面积大,聚集态结构优良,增强效果佳［１］;但其生产能耗大,成本高,价格昂贵,限制了具有优良性能的硅橡胶制品的广泛使用。如果能通过某些物理化学处理,把价格低廉的天然矿物加工成硅橡胶增强剂,不仅能促进硅橡胶工业的发展,而且可为矿物的高增值开发利用找到一条新的途径［２］。填料的粉体性质（包括粒度、表面积、形状、晶态等）是决定其增强性能的关键因素之一。本文分析探讨了矿物粉体的种类和粉体性质与增强性能的关系。１ 实验部分… 相似文献
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Contrasting mineral parageneses in high-temperature calc-silicate granulites: examples from the Eastern Ghats, India 总被引：3，自引：0，他引：3
S. DASGUPTA 《Journal of Metamorphic Geology》1993,11(2):193-202
Abstract Three types of mineral associations are described from calc-silicate granulites from the Eastern Ghats, India, where geothermobarometry in associated rocks suggests extremely high P–T conditions of metamorphism ( c . 9 ± 1 kbar, 950° C). These mineral associations are: (i) calcite + quartz + scapolite + plagioclase, (ii) calcite + scapolite + wollastonite + porphyroblastic garnet + coronal garnet and (iii) calcite + quartz + wollastonite + scapolite + porphyroblastic garnet + coronal garnet, all coexisting with K-feldspar, titanite and clinopyroxene. The first two associations evolved through nearly isobaric cooling retrograde paths, whereas the third evolved through a nearly isothermal decompression path followed by an isobaric cooling retrograde path. Textural and compositional characteristics suggest the following mineral reactions in the calc-silicate granulites: calcite + quartz = wollastonite + CO2 , calcite + plagioclase = scapolite, calcite + scapolite + wollastonite = porphyroblastic garnet ± quartz + CO2 , CaTs + wollastonite = coronal garnet (association ii) and wollastonite + scapolite = coronal garnet (association iii) + quartz + CO2 . Andradite content in garnet was buffered by the redox equilibria wollastonite + hedenbergite + O2 = andradite + quartz (association iii) and wollastonite + andradite + CaTs + scapolite = hedenbergite + calcite + grossular + O2 (association ii). The contrasting mineral parageneses have been ascribed to interplay of variables such as X CO2 , f O2 , f HCl in the fluid, bulk Na content and the nature of the retrograde P–T–X CO2 paths through which the rocks evolved. 相似文献
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多种矿物合理组合对工程塑料增强效果显著 总被引：3，自引：0，他引：3
硅灰石、滑石、绢云母与工程塑料ABS复合的系统实验表明：单一矿物参与复合时，矿物晶体产生的形态效应和结构效应对复合材料性能起主要影响作用，不同晶体形态和结构的矿物合理组合产生的协同效应对复合材料性能的影响作用更大。复合材料性能优于纯ABS，多矿物复合材料的性能最优，且复合体系的加工性能良好。 相似文献
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硅灰石质白色颜料的研制 总被引：4，自引：0，他引：4
针对硅灰石作为白色颜料的主要不利因素，对其进行超细粉碎和表面化学改性处理，改进硅灰石粉体粒度、粉体表面组成和表面结构，提高粉体的白度和折射率，进而提高遮盖力。改性后的硅灰石超细粉体具有良好的高级白色颜料性能。 相似文献
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《矿物学报》2013,(Z1)
This paper studied the reciprocity effect between wollastonite and a strain silicate bacterium from purple soil. We analyzed the changes of pH value, glucose (GLU) residual concentration, electrolyte and Mn, Si, Fe etc. in the culture liquid with wollastonite after 48 h. The results show that the GLU wastage of silicate bacteria with wollastonite is 2.5 times of the bacterial contrast. It showed wollastonite could obviously accelerate silicate bacteria growth, but bacterial cell broken and distorted badly have been found by SEM analysis. The solubilization of silicate bacteria to Si element of wollastonite reached above 10 times. At the same time, three apices in FTIR of wollastonite (898 cm-1, 925 cm-1, 962 cm-1) descended obviously after the action of silicate bacteria, which shows that a great deal of Si has dissolved out. So we can get that wollastonite has remarkable effect to the growth of silicate bacteria and silicate bacteria has obvious solubilization to Si of wollastonite. 相似文献
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Carmen A. Nezat Joel D. Blum Charles T. Driscoll 《Geochimica et cosmochimica acta》2010,74(11):3129-7046
Forty-one metric tons of the mineral wollastonite (CaSiO3) was applied to an 11.8 hectare watershed at the Hubbard Brook Experimental Forest (HBEF; White Mountains, New Hampshire, USA) with the goal of restoring the Ca estimated to have been depleted from the soil exchange complex by acid deposition. This experiment provided an opportunity to gain qualitative information on whole watershed hydrologic flow paths by studying the response of stream water chemistry to the addition of Ca. Because the Ca/Sr and 87Sr/86Sr ratios of wollastonite strongly contrast that of other Ca sources in the watershed, the wollastonite-derived Ca can be identified and its amount estimated in various ecosystem components. Stream water chemistry at the HBEF varies seasonally due to shifts in the proportion of base flow and interflow. Prior to the wollastonite application, seasonal variations in 87Sr/86Sr ratios indicated that 87Sr/86Sr was higher during base flow than interflow, due largely to greater amounts of biotite weathering along deeper flow paths. After the application, Ca/Sr and 87Sr/86Sr changed markedly as the high Ca/Sr and low 87Sr/86Sr wollastonite dissolved and mixed with stream water. The Ca addition provided information on the response times of various flow paths and ion exchange processes to Ca addition in this small upland watershed. During the first year after the addition, wollastonite applied to the near stream zone dissolved and was partially immobilized by cation exchange sites in the hyporheic zone. In the second and third years after the addition we infer that much of this Ca and Sr was subsequently desorbed from the hyporheic zone and was exported from the watershed in stream flow. In the fourth through ninth years after the addition, Ca and Sr from wollastonite that had dissolved in upland soils was transported to the stream by interflow during wet periods when the ground water table was elevated. Between years three and nine the minimum annual Ca/Sr ratio (in late summer base flow) increased, providing evidence that Ca and Sr had increasingly infiltrated to the deepest flow paths. Strong seasonal variations in Ca/Sr and 87Sr/86Sr ratios of stream water resulted from the wollastonite addition to upland forest soils, and these ratios have become sensitive to changing flow paths during the annual cycle. Most notably, high flow events now produce large excursions in stream geochemistry toward the high Ca/Sr and low 87Sr/86Sr ratios of wollastonite. Nine years after the application we estimate that ∼360 kg of Ca from wollastonite has been exported from the watershed in stream flow. The rate of export of Ca from wollastonite dissolution has stabilized at about 11 kg of Ca per year, which accounts for ∼30% of the dissolved Ca in the stream water. Given that 19 metric tons of Ca were applied to the watershed, and assuming this current rate of loss, it should take over 1000 years for this added Ca to be transported from the watershed. 相似文献