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1.
Caprock has the most important role in the long term safety of formation gas storage. The caprocks trap fluid accumulated beneath, contribute to lateral migration of this fluid and impede its upward migration. The rapid upward passage of invasive plumes due to buoyancy pressure is prevented by capillary pressure within these seal rocks. In the present study, two main seal rocks, from the Zagros basin in the southwest of Iran, a shale core sample of Asmari formation and an anhydrite core sample of Gachsaran formation, were provided. Absolute permeabilities of shale and anhydrite cores, considering the Klinkenberg effect, were measured as 6.09 × 10−18 and 0.89 × 10−18 m2, respectively. Capillary sealing efficiency of the cores was investigated using gas breakthrough experiments. To do so, two distinct techniques including step by step and residual capillary pressure approaches were performed, using carbon dioxide, nitrogen and methane gases at temperatures of 70 and 90 °C, under confining pressures in the range 24.13–37.92 MPa. In the first technique, it was found that capillary breakthrough pressure of the cores varies in the range from 2.76 to 34.34 MPa. Moreover, the measurements indicated that after capillary breakthrough, gas effective permeabilities lie in range 1.85 × 10−21 – 1.66 × 10−19 m2. In the second technique, the minimum capillary displacement pressure of shale varied from 0.66 to 1.45 MPa with the maximum effective permeability around 7.76 × 10−21 – 6.69 × 10−20 m2. The results indicate that anhydrite caprock of the Gachsaran formation provides proper capillary sealing efficacy, suitable for long term storage of the injected CO2 plumes, due to its higher capillary breakthrough pressure and lower gas effective permeability. 相似文献
2.
Continental collision between Iranian and Arabian plates resulted in the formation of the Zagros fold–thrust belt and its associated foreland basin. During convergence, pre-existing faults in the basement were reactivated and the sedimentary cover was shortened above two different types of basal decollement (viscous/frictional). This led to heterogeneous deformation which segmented not only the Zagros fold–thrust belt but also its foreland basin into different compartments resulting in variation in facies, thickness and age of the sediment infill.Based on this concept, a new tectono-sedimentary model is proposed for one of the most important syn-tectonic sedimentary unit, the Gachsaran salt in the Zagros foreland basin. In this proposed model, it is argued that differential propagation of the deformation front above decollements with different mechanical properties (viscous versus frictional) results in along-strike irregularity of the Zagros deformation front whereas movement along pre-existing basement faults leads to development of barriers across the Zagros basin. The irregularity of the deformation front and the cross-basin barriers divided the Zagros foreland basin into six almost alternating sub-basins where Gachsaran salt and its non-salt equivalents are deposited. In the salt sub-basins, two different processes were responsible for the deposition of Gachsaran salt: (1) evaporation, and (2) dissolution of extruding Hormuz salt and its re-precipitation as Gachsaran salt. Re-precipitation was probably the most significant process responsible for the huge deposit of Gachsaran salt in the extreme south-east part of the Zagros foreland basin. 相似文献
3.
Organic contaminant and total mercury concentrations were compared in four species of lamniform sharks over several age classes to examine bioaccumulation patterns and gain insights into trophic ecology. Contaminants found in young of the year (YOY) sharks were assumed to be derived from maternal sources and used as a proxy to investigate factors that influence maternal offloading processes. YOY white (Carcharodon carcharias) and mako (Isurus oxyrinchus) sharks had comparable and significantly higher concentrations of PCBs, DDTs, pesticides, and mercury than YOY thresher (Alopias vulpinus) or salmon (Lamna ditropis) sharks. A significant positive relationship was found between YOY contaminant loads and maternal trophic position, suggesting that trophic ecology is one factor that plays an important role in maternal offloading. Differences in organic contaminant signatures and contaminant concentration magnitudes among species corroborated what is known about species habitat use and may be used to provide insights into the feeding ecology of these animals. 相似文献
4.
Military sonar has the potential to negatively impact marine mammals. To investigate factors affecting behavioral disruption in California sea lions (Zalophus californianus), fifteen sea lions participated in a controlled exposure study using a simulated tactical sonar signal (1 s duration, 3250–3450 Hz) as a stimulus. Subjects were placed into groups of three and each group received a stimulus exposure of 125, 140, 155, 170, or 185 dB re: 1 μPa (rms). Each subject was trained to swim across an enclosure, touch a paddle, and return to the start location. Sound exposures occurred at the mid-point of the enclosure. Control and exposure sessions were run consecutively and each consisted of ten, 30-s trials. The occurrence and severity of behavioral responses were used to create acoustic dose–response and dose–severity functions. Age of the subject significantly affected the dose–response relationship, but not the dose–severity relationship. Repetitive exposures did not affect the dose–response relationship. 相似文献
5.
Offshore oil & gas industry is moving exploration and production activities into Arctic and deep water regions. Governmental regulations require environmental impact assessments before operations to evaluate the possible effects of accidental oil releases. These are often performed by numerical fate models, like the Oil Spill Contingency and Response (OSCAR) model, which has become an industry standard in Norway. In this model, biodegradation rates are adjusted to local conditions by temperature compensation according to a Q10 approach. Q10 is the multiplier by which rates of enzymatic reactions increase at a 10 °C temperature rise. Herein, this Q10 approach implemented in the OSCAR model is investigated based on published data and novel obtained results. Overall, biodegradation rate predictions calculated by temperature compensation are found to be questionable, and choosing one universal Q10 value is considered not feasible. The high variation in Q10 values is herein attributed to indirect effects of temperature. 相似文献
6.
Ancient lacustrine storm-deposits that act as petroleum reservoirs are seldom reported. The Lijin Sag, which is located in the southeastern corner of the Bohai Bay Basin in East China, is a NE–SW trending Cenozoic half-graben basin. Some of its Eocene deposits (Bindong deposits) were interpreted as lacustrine tempestites. The Bindong tempestites, which developed in the lower part of the upper fourth member of the Shahejie Formation (Es41), constitute a new kind of petroleum reservoir and are novel petroleum exploration targets in the Bindong Area. However, the characteristics of the Es41 Bindong tempestite reservoirs and their controlling factors are poorly understood. Point-count analyses of thin sections, scanning electron microscope image analyses, X-ray diffractometry data, and the petrophysical parameters of the Bindong tempestite reservoirs were utilized to estimate the reservoir quality. The reservoirs have undergone significant diagenetic alteration, which can be divided into negative and positive aspects. The negative alteration includes compaction, authigenic minerals, and cementation such as carbonates, clay minerals and overgrowths of quartz and feldspar. The uneven distribution of carbonate cement increased the reservoir’s heterogeneity, with carbonate cement commonly precipitating along the sandstone-mudstone contacts. The primary porosity was severely reduced because of compaction and extensive carbonate cementation. Positive alteration includes dissolution, carbonate cementation, undercompaction and fractures. Carbonate cementation exhibited both positive and negative effects on the reservoir quality. Overall, the objective reservoir quality is quite poor. A quantitative evaluation of the reservoirs’ potential was conducted. The cutoff values of several of the reservoir’s parameters were calculated. The lower limits of the porosity and permeability are 8.35–5.85% and 1.2587–0.2753 × 10–3 μm2, respectively, depending on the depth. The upper limits of the carbonate and mud content are approximately 18.5% and 9–10%, respectively. A fundamental understanding of these characteristics will provide necessary information for extracting hydrocarbons from analogous subsurface reservoirs. 相似文献
7.
Deep water fold and thrust belts (DWFTBs) are sedimentary wedges that accommodate plate-scale deformation on both active and passive continental margins. Internally, these wedges consist of individual structures that strongly influence sediment dispersal, bathymetry and fluid migration. Most DWFTB studies investigate basin- and intra-wedge- scale processes using seismic reflection profiles, yet are inherently limited by seismic resolution. Of critical importance is strain distribution and its accommodation on discrete faults compared to distributed deformation. Recent studies have considered strain distribution by investigating regional reflection DWFTBs profiles within coupled systems, which contain down-dip compression and up-dip extension. There is broad agreement of a mis-balance in compression versus extension, with ∼5% excess in the latter associated with horizontal compaction, yet this remains unproven.Using two exceptionally well exposed outcrops in the Spanish Pyrenees we consider deformation of DWFTB at a scale comparable to, and beyond, seismic resolution for the first time. By coupling outcrop observations (decametre to hectometre scale) with a re-evaluation of seismic profiles from the Orange Basin, South Africa, which contains one of the best imaged DWFTBs globally, we provide a unique insight into the deformation from metre to margin scale. Our observations reveal hitherto unrecognised second order structures that account for the majority of the previously recognised missing strain. This re-evaluation implies that ∼5% missing strain should be accounted for in all DWFTBs, therefore existing studies using restorations of the sediment wedge will have underestimated crustal shortening in active margins, or sedimentary shortening in gravity driven systems by this amount. In contrast to previous studies, our observations imply that the majority of this strain is accommodated on discrete fault surfaces and this can explain the occurrence and location of a range of intra-wedge processes that are intimately linked to structures including sediment dispersal, fluid migration pathways and reservoir compartmentalisation. 相似文献
8.
《Marine Policy》2017
Transition to low carbon sea transport is a logical response to the extreme dependency of the Pacific Islands region on imported fossil fuel, its significant vulnerability to the effects of climate change and the critical shipping needs of Pacific Island countries (PICs). Building on previous work in low carbon sea transport in the Pacific, this paper further considers the barriers to achieving such transition by assessing, through a ‘post-Paris Agreement’ lens, the Intended Nationally Determined Contributions (INDCs) submitted by PICs and contrasting these to the near total lack of investment and planning for low carbon transition in the transport sector with the parallel occurrence in the electricity sector where ~USD 2 billion of donor investment is deployed or queued despite electricity using only ~20% of fossil fuel across the region. Consistent with recent international studies, inadequate and inappropriate financing and policy have been identified as dominant transition barriers for low carbon sea transport development in PICs. This paper further examines the regional level barriers to policy development, and finds them inhibited by the silo nature of the major regional actors. The implications that the Paris Agreement has for climate financing to support the essential research and capacity development needed to underpin a successful low carbon sea transport transition strategy at any useful scale and speed are also considered in this paper. 相似文献
9.
During reservoir characterization all the geological uncertainties affecting the quantity and distribution of hydrocarbons should be captured to assess the risks affecting final recovery.In a typical modeling workflow the geological uncertainties are accounted for through the construction of a sufficiently large set of 3-D static models. Out of this set, a few representative models are selected and dynamically simulated so as to correlate the geological characteristics of the reservoir with its dynamic performance and to propagate the uncertainty onto the final recovery factors, yet maintaining the computational run time acceptable. In channelized depositional environments, which are strongly heterogeneous, the selection approach must also account for channel connectivity, which plays a key role in the possibility of efficiently draining the reservoir for a reasonable number of wells.This study can be seen as a step forward in the assessment of the risks associated to the development of channelized reservoirs under the assumption that a way to express the concept of channel connectivity is channel amalgamation. Channel amalgamation is here defined through amalgamation curves which are numerically described using a set of indexes whose combination provide spatial information of channel intersections. These indexes were calculated for a full set of 3-D geological models and used to steer the selection of a representative model sub-set for subsequent fluid flow simulations.The validity of the index-based selection was verified on different sets of synthetic reservoir models through the evaluation of the representativeness of the model sub-set in reproducing the uncertainty of the original dataset. Eventually, the existence of a strong correlation between channel amalgamation and production performance was proved. From a practical perspective, the possibility to include channel amalgamation in the assessment of the geological models can considerably improve the representativeness of the selected models for uncertainty propagation thus reducing significantly the number of geological models to be considered. 相似文献
10.
The Ukrainian Dniepr-Donets Basin (DDB) is a Late Palaeozoic intracratonic rift basin, with sedimentary thicknesses up to 19 km, displaying the effects of salt tectonics during its entire history of formation, from Late Devonian rifting to the Tertiary. Hundreds of concordant and discordant salt structures formed during this time. It is demonstrated in this paper that the variety of styles of salt structure formation in the DDB provide important constraints on understanding the triggering and driving mechanisms of salt kinematics in sedimentary basins in general. Salt movement in the DDB began during the Devonian syn-rift phase of basin development and exerted controls on the later distribution of salt structures though the geometry of basement faults is not directly responsible for the regular spacing of salt structures. Post-rift salt movements in the DDB occurred episodically. Episodes of salt movement were triggered by tectonic events, specifically two extensional events during the Carboniferous, an extensional reactivation at the end of Carboniferous–earliest Permian, and a compressional event at the end of the Cretaceous. Extensional events that induced salt movement were ‘thick-skinned’ (i.e. basement involved in deformation) rather than ‘thin-skinned’. Most overburden deformation related to salt movements is ductile regardless of sedimentary bulk lithology and degree of diagenesis, while the deformation of sedimentary cover in areas where salt is absent is mainly brittle. This implies that the presence of salt changes the predominant mode of deformation of overlying sedimentary rocks. Episodes of salt movement lasted longer than the periods of active tectonics that initiated them. Buoyancy, erosion, and differential loading all played a role in driving halokinesis once tectonic forces had pushed the salt-overburden system into disequilibrium; among these factors, erosion of overburden above growing salt structures acted as a key self-renewing force for development of salt diapirs. Very high sedimentation rates (related to high post-rift tectonic subsidence rates), particularly during the Carboniferous, were able to bury diapirs and to load salt bodies such that buoyancy, erosion, and differential loading forces eventually became insufficient to continue driving diapirism—until the system was perturbed by an ensuing tectonic event. In contrast, some salt anticlines and diapirs developed continuously during the entire Mesozoic because of much-reduced tectonic subsidence rates (and sedimentation supply) during this time. However, a Lower Permian salt series and overhangs of buried diapirs played an important role in preventing overburden piercing (and fracturing) during the Mesozoic and, specifically, during the Late Cretaceous salt diapirism phase. 相似文献
11.
The Precambrian Dengying Formation is maximum buried carbonate reservoir in the Sichuan Basin. Reservoir types are thought to be dominated by sedimentary facies or karst controlled. Precursory sedimentary fabrics have been intensively superimposed by medium-to coarse-grained dolomite in most areas. Dolomitized intervals contain planar and saddle dolomite, quartz, and few hydrothermal replacive minerals. Fluid inclusion analyses of dolomite suggests that rocks are formed at temperatures ranging from 132.6°C to 218.7°C in the presence of dense brines, while the dolomite phases are demonstrated by negative δ18O and δ13C VPDB values. Strontium isotopes enriched in 87Sr, and the fluid source could support the conclusion. The dolomites of the Dengying Formation in central Sichuan Basin that formed around basement-rooted wrench faults, in turn mainly oriented towards the North-South and East-West strike-slip faults, are detectable. Lastly, the grabens take the form of negative flower structures-the result of an intra-cratonic rift that took place during the Sinian and early Cambrian period through tensional faulting.Our primary contention is that basement fault, which resulted in the magmatic or deep clastic fluids migration, was key for the formation of the obvious high-temperature coarse dolomite and saddle dolomite replacement. Subsequently, hot fluids that circulated within the matrix dolomite were aided by fractures or vugs and (1) leached into the dolomite, producing vugs and pores; (2) precipitated saddle dolomite, and (3) led to hydrofracturing, fractures enlargement, and further brecciation. The dolomite eventually formed porous hydrocarbon reservoirs through diagenesis. This model better illustrates how fluids that originated from deep basin migration along strike-slip transfer faults and fractures flowed out to structures in Precambrian basement-rooted faults, inheriting the rift in the Cambrian. The data involved offers a fresh perspective pertinent to deep hydrocarbon exploration of dolomite reservoirs in Southwestern China. 相似文献
12.
Rifting of continental margins is generally diachronous along the zones where continents break due to various factors including the boundary conditions which trigger the extensional forces, but also the internal physical boundaries which are inherent to the composition and thus the geological history of the continental margin. Being opened quite recently in the Tertiary in a scissor-shape manner, the South China Sea (SCS) offers an image of the rifting structures which varies along strike the basin margins. The SCS has a long history of extension, which dates back from the Late Cretaceous, and allows us to observe an early stretching on the northern margin onshore and offshore South China, with large low angle faults which detach the Mesozoic sediments either over Triassic to Early Cretaceous granites, or along the short limbs of broad folds affecting Palaeozoic to Early Cretaceous series. These early faults create narrow troughs filled with coarse polygenic conglomerate grading upward to coarse sandstone. Because these low-angle faults reactivate older trends, they vary in geometry according to the direction of the folds or the granite boundaries. A later set of faults, characterized by generally E–W low and high angle normal faults was dominant during the Eocene. Associated half-graben basement deepened as the basins were filling with continental or very shallow marine sediments. This subsequent direction is well expressed both in the north and the SW of the South China Sea and often reactivated earlier detachments. At places, the intersection of these two fault sets resulting in extreme stretching with crustal boudinage and mantle exhumation such as in the Phu Khanh Basin East of the Vietnam fault. A third direction of faults, which rarely reactivates the detachments is NE–SW and well developed near the oceanic crust in the southern and southwestern part of the basin. This direction which intersects the previous ones was active although sea floor spreading was largely developed in the northern part, and ended by the Late Miocene after the onset of the regional Mid Miocene unconformity known as MMU and dated around 15.5 Ma. Latest Miocene is marked by a regional basement drop and localized normal faults on the shelf closer to the coast. The SE margin of the South China Sea does not show the extensional features as well as the Northern margin. Detachments are common in the Dangerous Grounds and Reed Bank area and may occasionally lead to mantle exhumation. The sedimentary environment on the extended crust remained shallow all along the rifting and a large part of the spreading until the Late Miocene, when it suddenly deepened. This period also corresponds to the cessation of the shortening of the NW Borneo wedge in Palawan, Sabah, and Sarawak. We correlate the variation of margin structure and composition of the margin; mainly the occurrence of granitic batholiths and Mesozoic broad folds, with the location of the detachments and major normal faults which condition the style of rifting, the crustal boudinage and therefore the crustal thickness. 相似文献