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1.
为了评价豫东地区煤系烃源岩生烃潜力,基于有机碳含量（TOC）、镜质体反射率、干酪根类型及显微组成等测试分析结果,探讨了豫东地区不同区块煤系烃源岩的有机地球化学特征,对比分析了不同区块煤系气资源潜力,提出煤系气勘探有利区块。结果表明:区内煤系烃源岩的有机碳含量偏低（小于1.5%）;干酪根类型以Ⅲ型为主,偶见Ⅱ2型干酪根,利于生气;煤系经历了中二叠-中晚三叠世和晚侏罗-早白垩世2个大量生烃阶段,烃源岩热演化程度较高,镜质体反射率（Rran）为1.44%~3.80%,平均2.83%,有机质进入高成熟-过高成熟阶段,生烃量较充足。总体上,区内烃源岩生烃潜力属于差-中级别,砂泥岩储集性能相对较好,含气量高。煤系盖层主要为封盖性好的细砂岩、煤层、泥质岩类,煤系烃源岩气体保存条件好。研究认为研究区的睢西区块烃源岩具有埋藏深度较浅、有效厚度大、孔隙度高、含气量和含气饱和度高、有机质成熟度高的特点,为豫东煤系气勘探的有利区块。   相似文献   

2.
Based on gas chromatography and gas chromatography mass spectrometry techniques, the authors examined biomarker characteristics of the Ganquan Formation source rocks in the area of Dahulishan, Ejina, and analyzed the information and petroleum geological significance that were indicated by the source of organic matter, sedimentary environment and maturity and so on. Gas chromatography peak of saturated hydrocarbons from the Ganquan Formation source rocks showed "the former peak" of the single peak distribution, the main peak of carbon being C18 , indicating the main sources of organic matter with marine organic matter. Pr/Ph ranges from 0.3 to 0.6, indicating a strongly reducing sedimentary environment. Biomarker assemblages of the Ganquan Formation source rocks are abundant in tricyclic terpane with long side chains, with a high level of gammacerane, showing dominant distribution of C27 sterane. High contents of gammacerane in organic matter show organic facies of source rocks in the saltwater sedimentary environment. That average hopane/sterane ratio is 0.59, showing that algae have made more contributions to organic matter than bacteria. And the high level of C27 steranes shows that algae are the main source of hydrocarbon precursors. The Ganquan Formation’s methylphenanthrene index, which is an effective molecular parameter index to measure thermal evolution of organic matter, ranges from 0.35 to 0.50, and the conversion of vitrinite reflectance Rc from it is within the range of 2.00-2.09, indicating that the Ganquan Formation source rocks are in the over-mature stage of thermal evolution.  相似文献   

3.
Characteristics have been studied of light hydrocarbons (C1–C7) from crude oils and source rocks ranging from Devonian to Triassic in age in the Jurong Basin where carbonate rocks are dominating. The results show that light hydrocarbon compositions (C1–C7) can be used to classify organic matter types and maturities as well as to make oil-source rock correlations. It is also an effective method in organic geochemical studies of oils, gases and source rocks in terrains of old carbonate rocks.  相似文献   

4.
Coal beds of the Upper Cretaceous Fruitland Formation in the San Juan Basin of northwestern New Mexico and southwestern Colorado have significant liquid hydrocarbon generation potential as indicated by typical Rock-Eval Hydrogen Indexes in the range of 200–400 mg hydrocarbon/g organic carbon (type II and III organic matter). Small, non-commercial quantities of oil have been produced from the coal beds at several locations. The oils are characterized by high pristane/phytane (ca 4) and pristane/n-C17 ratios (ca 1.2), abundant C21+ alkanes in the C10+ fraction with a slight predominance of odd carbon-numbered n-alkanes, abundant branched-chain alkanes in the C15+ region, and a predominance of methylcyclohexane in the C4----C10 fraction. The oils are indigenous to the Fruitland Formation coals and probably migrated at thermal maturities corresponding to vitrinite reflectance values in the range 0.7–0.8%. Although the oils found to date are not present in commercial amounts, these findings illustrate the potential of some coals to generate and expel oil under conditions of moderate thermal heating.  相似文献   

5.
1 IntroductionThe compositional characteristics of natural gasesand their carbon isotopic composition are controlledmainly by the type of organic matter and the degree ofits thermal evolution in the source rocks (Song Yan,1995; Xu Yongchang et al., 1994; …  相似文献   

6.
Surma Group is the most important geological unit of Bengal basin, Bangladesh, because petroleum resources occur within this group. It is mainly composed of alternation of shale and sandstone and the shale fraction has long been considered as source rocks and the sandstone fraction as reservoir. These source and reservoir rocks have been studied by different authors by different approach but none of them adopted organic geochemistry and organic petrology as a means of study of source rock and their possible depositional environment. A total of thirty shale core samples have been collected from eight different gas fields to fulfill the short coming. The collected samples have been subjected to Source Rock Analysis (SRA) and/or Rock-Eval (RE) followed by pyrolysis gas chromatography (PyGC), gas chromatography mass spectrometry (GCMS), elemental analysis (EA) and organic petrological study such as vitrinite reflectance measurement and maceral analysis. The analyzed organic matter extracted from the shales of Surma Group consists mainly of Type III along with some Type II kerogen. The studied shales are mostly organically lean (TOC ±1%) and the extracted organic matter is fair to moderate. Based on these results, the analyzed shales have been ranked as poor (mostly) to fair quality source rock. The organic matter of the analyzed shale samples is thermally immature to early mature for hydrocarbon generation considering their Tmax and measured mean vitrinite reflectance values. The hopane 22S/(22S + 22R), moretane/hopane ratio and sterane parameters are also in good agreement with these thermal maturity assessments. The predominance of odd carbons over even carbons (most common) and/or even carbons over odd carbon numbered n-alkanes, moderate Pr/Ph ratio, low to high Tm/Ts ratio, comparative abundance of sterane C29 (i.e., C29 >C27>C28), Pr/nC17 — Ph/nC18 values, C/S ratio and dominance of vitrinite macerals group with the presence of liptinite macerals demonstrate that the organic matter has derived mainly from terrestrial inputs with an insignificant contribution from the marine sources. The condition of deposition alternates from oxic to anoxic.  相似文献   

7.
陆相低成熟烃源岩有机硫与热解成烃动力学关系初探   总被引：5，自引：0，他引：5  
沈忠民  周光甲 《沉积学报》1998,16(4):133-139
对陆相低成熟烃源岩（Ro≤ 0.5 %）有机硫与成烃动力学关系进行了研究。结果表明:①有机硫含量与镜质体反射率（Ro）之间呈负相关关系,即有机硫含量随成熟度提高而减少;②源岩的平均活化能（E）有随有机硫含量增大而减小的趋势;③有机硫含量与源岩活化能分布最小值（Emin）和经可溶有机质抽提后的活化能分布最小值（Emin）之间存在正相关关系;④活化能分布范围Emin～ESEmin（ESEmin＞Emin）内的可溶有机质生烃能力与有机硫含量具有一定的相关性;⑤综上结果推断东营凹陷南斜坡东段沙四段（Es4）源岩中的有机硫在成烃过程中可能起到了一定的作用。  相似文献   

8.
There are several source rock units in the Zagros Basin, but the Cretaceous Kazhdumi and Paleogene Pabdeh formations probably have produced the majority of the commercial hydrocarbons in this area. Among the hydrocarbon provinces of Iran, the Dezful Embayment, which is located southwest of Zagros Mountains, is one of the most prolific regions in the Middle East. Numerous studies have been made in the northern part of the Dezful Embayment, but relatively few have been done in its southern part. The present study focuses on organic matter characterization of two potential source rocks (Kazhdumi and Pabdeh formations) in southern part of the Dezful Embayment. Cuttings samples (114) were collected from 10 wells and evaluated using Rock–Eval pyrolysis and organic petrography in order to characterize the content and type of organic matter and thermal maturity. The results showed that the average total organic carbon (TOC) content of Kazhdumi and Pabdeh formations are 2.48 and 1.62 wt%, respectively. The highest TOC contents for both formations are found in the northern compartment and decreased gradually toward the south. Pyrolysis data reveal that organic matter has a fair to very good hydrocarbon generation potential and are classified as Type II–III and Type III. Rock–Eval Tmax and vitrinite reflectance show that the majority of samples are in the early mature to mature stage of the oil generation window.  相似文献   

9.
Based on thermal simulation experiment, interactions between volcanic fluids and source rocks were studied. Gas generations in the dry system and fluid system under different temperatures were analyzed. The results showed that the various types of source rocks are similar in composition, containing gaseous C1-C5 hydrocarbons, H2 and CO2 whose gas yields increase with increasing temperature. The gas yield of source rocks of type I is the high- est, followed by type II, and that of source rocks of type III is the lowest, indicating that the yield of hydrocarbon gases is related to their hydrocarbon generating potential. Although the generating potential of type III is the lowest, it can still be regarded as a useful gas source when it is buried deeply enough. The basic volcanic fluid restrains the generation of gaseous hydrocarbons in different types of source rocks, but promotes the generation of inorganic gases.  相似文献   

10.
李燕  邓运华  李友川 《现代地质》2021,35(4):1065-1077
河流-三角洲体系煤系烃源岩是重要的油气来源,传统的研究方法主要为单井点分析,对研究区的勘探程度和资料情况的依赖性大,而且认识滞后于勘探,很难在油气勘探和有利生烃洼陷的预测中发挥作用。对珠江口盆地恩平组煤系烃源岩进行系统研究,揭示煤系烃源岩发育的特征和有利地质条件,并将沉积微相分析与烃源岩的地球化学指标(有机质丰度、生烃潜量、氢指数)相结合,提出微相控烃的特点及机理,建立了珠江口盆地恩平组河流-三角洲体系煤系烃源岩的发育模式。珠江口盆地恩平组沉积时期构造稳定,沉积、沉降速率近平衡;气候温暖湿润,植被繁茂,并且河流和三角洲环境的广泛分布为煤系烃源岩的发育提供了有利条件。河流和三角洲环境发育的煤层均呈薄层状产出,纵向上发育层数多,横向连续性差;河流和三角洲环境发育的煤系烃源岩有机质丰度均较高,生烃潜力和氢指数相近,有机质主要来自陆生高等植物。研究区煤系烃源岩非均质性很强,呈现明显的微相控烃的特点,由河道、分流河道向远离河道、分流河道的河漫沼泽、沼泽有机质丰度增高,有机质类型变好,河流的河漫沼泽和三角洲平原沼泽微相是最有利的沉积相带。各微相的古地形、水动力条件、氧化还原条件等古地理条件的不同是造成各微相烃源岩发育差异的重要原因。在上述研究的基础上,建立了反映研究区河流和三角洲环境各微相烃源岩发育差异及煤层展布特征的煤系烃源岩发育模式。  相似文献   

11.
A suite of 27 oils from the Qinjiatun–Qikeshu oilfields in the Lishu Fault Depression of the Songliao Basin was analyzed using whole oil gas chromatography. In combination with the relative distribution of C27, C28, and C29 regular steranes, detailed geochemical analyses of light hydrocarbons in oil samples revealed crude oils characterized by the dual input of lower aquatic organisms and higher terrestrial plants. Several light hydrocarbon indicators suggest that the liquid hydrocarbons have maturities equivalent to vitrinite reflectances of around 0.78%–0.93%. This is consistent with the maturity determination of steranes C29 20S/(20S + 20R) and C29 ααβ/(ααα + αββ). Crude oils derived from the two distinct oilfields likely both have source rocks deposited in a lacustrine environment based on light hydrocarbon parameters and on higher molecular weight hydrocarbon parameters. The results show that light hydrocarbon data in crude oils can provide important information for understanding the geochemical characteristics of the Qinjiatun–Qikeshu oils during geologic evolution.  相似文献   

12.
A scientific exploration well(CK1) was drilled to expand the oil/gas production in the western Sichuan depression, SW, China. Seventy-three core samples and four natural gas samples from the Middle–Late Triassic strata were analyzed to determine the paleo-depositional setting and the abundance of organic matter(OM) and to evaluate the hydrocarbon-generation process and potential. This information was then used to identify the origin of the natural gas. The OM is characterized by medium n-alkanes(n C_(15)–n C_(19)), low pristane/phytane and terrigenous aquatic ratios(TAR), a carbon preference index(CPI) of ～1, regular steranes with C_(29) C_(27) C_(28), gammacerane/C_(30) hopane ratios of 0.15–0.32, and δD_(org) of-132‰ to-58‰, suggesting a marine algal/phytoplankton source with terrestrial input deposited in a reducing–transitional saline/marine sedimentary environment. Based on the TOC, HI index, and chloroform bitumen "A" the algalrich dolomites of the Leikoupo Formation are fair–good source rocks; the grey limestones of the Maantang Formation are fair source rocks; and the shales of the Xiaotangzi Formation are moderately good source rocks. In addition, maceral and carbon isotopes indicate that the kerogen of the Leikoupo and Maantang formations is type Ⅱ and that of the Xiaotangzi Formation is type Ⅱ–Ⅲ. The maturity parameters and the hopane and sterane isomerization suggest that the OM was advanced mature and produced wet–dry gases. One-dimensional modeling of the thermal-burial history suggests that hydrocarbon-generation occurred at 220–60 Ma. The gas components and C–H–He–Ar–Ne isotopes indicate that the oilassociated gases were generated in the Leikoupo and Maantang formations, and then, they mixed with gases from the Xiaotangzi Formation, which were probably contributed by the underlying Permian marine source rocks. Therefore, the deeply-buried Middle–Late Triassic marine source rocks in the western Sichuan depression and in similar basins have a great significant hydrocarbon potential.  相似文献   

13.
《Applied Geochemistry》1999,14(5):547-558
Major oil reserves in rift basins in eastern China are correlated with high quality source rocks. The high quality source rocks and their hydrocarbon generation are often related to volcanic activity in the basins. Three kinds of volcanic rocks in source rocks have been defined in the Songliao, Bohaiwan and North Jiangsu basins. Some of the volcanic rocks were formed in lacustrine environments during the deposition of source rocks. It is remarkable that a part of volcanic-derived materials serves as a source of nutrients for lacustrine organisms which resulted in the formation of the organic matter in source rocks with high organic C contents. Besides hydrothermal alteration, the volcanic minerals contributed catalysis and H2 to thermal alteration of organic matter into hydrocarbons during burial and diagenesis of source rocks and volcanics. A series of thermal laboratory simulations were performed with various combinations of immature source rocks and natural mineral assemblages. Results indicate that a significant volume of H2 was produced from the source rock mixed with olivine and zeolite; moreover, this combination provided a 3-fold increase in hydrocarbons. It is proposed that catalysis and hydrogenation by the volcanic minerals promote hydrocarbon generation, although organic matter type is significantly variable. Hydrocarbons are generated at a lower degree of thermal stress when the reaction mixture contains volcanic minerals, and have a heavier C isotopic composition, compared to the control set of experiments.  相似文献   

14.
柴达木盆地侏罗系发育泥岩、炭质泥岩、煤和油页岩等多种类型煤系烃源岩。受沉积环境控制,不同类型烃源岩之间有机质丰度、有机质类型及生排烃模式等差别很大。传统的评价方法低估了炭质泥岩和煤的生烃潜力。提出了基于单位岩石烃源岩产烃率的定量评价方法,对不同类型烃源岩的总生烃量和总资源量定量预测表明:炭质泥岩对侏罗系生烃总量和油气资源的贡献率分别达到44.8%和41.7%,整体提升了柴达木盆地侏罗系烃源岩的资源潜力,煤型气的资源潜力大幅度提高,对柴达木盆地天然气勘探具有重要指导意义。   相似文献   

15.
Coal measure source rocks, located in the Xihu Sag of the East China Sea Shelf Basin, were analyzed to define the hydrocarbon generation potential, organic geochemistry/petrology characteristics, and coal preservation conditions. The Pinghu source rocks in the Xihu Sag are mainly gas-prone accompany with condensate oil generation. The coals and shales of the Pinghu Formation are classified from "fair" to "excellent" source rocks with total organic carbon(TOC) contents ranging from 25.2% to 77.2% and 1.29% to 20.9%, respectively. The coals are richer in TOC and S1+S2 than the shales, indicating that the coals have more generation potential per unit mass. Moreover, the kerogen type of the organic matter consists of types Ⅱ-Ⅲ and Ⅲ, which the maturity Ro ranges from 0.59% to 0.83%. Petrographically, the coals and shales are dominated by vitrinite macerals(69.1%–96.8%) with minor proportions of liptinite(2.5%–17.55%) and inertinite(0.2%–6.2%). The correlation between maceral composition and S1+S2 indicates that the main contributor to the generation potential is vitrinite. Therefore, the coals and shales of the Pinghu Formation has good hydrocarbon generation potential, which provided a good foundation for coal measure gas accumulation. Furthermore, coal facies models indicates that the Pinghu coal was deposited in limno-telmatic environment under high water levels, with low tree density(mainly herbaceous) and with low-moderate nutrient supply. Fluctuating water levels and intermittent flooding during the deposition of peat resulted in the inter-layering of coal, shale and sandstone, which potentially providing favorable preservation conditions for coal measure gas.  相似文献   

16.
We present results of geochemical studies of organic matter of the Jurassic–Cretaceous deposits in the west of the Yenisei–Khatanga regional trough. The studies were carried out on a representative set of well cores by a complex of modern organic-geochemistry methods (determination of organic-carbon content in rocks, pyrolysis, estimation of the carbon isotope composition in the kerogen of rocks, extraction, liquid and gas–liquid chromatography, and chromato-mass spectrometry). Based on the distribution of biomarkers in the studied bitumens and pyrolysis of rocks, two groups of the samples were recognized: with terrigenous (type III) and marine (type II) organic matter. The terrigenous bitumens are characterized by a low hydrogen index (HI) and a predominance of hydrocarbons C29 among steranes and C19 and C20 among tricyclanes. The marine bitumens, revealed in stratigraphic analogs of the Bazhenovo Formation and in the Malyshevka, Nizhnyaya Kheta, and Shuratovka Formations, show an even distribution of sterane homologues and a predominance of medium-molecular tricyclanes. The Pr/Ph and C35/C34 ratios and the presence of diahopanes testify to the burial of organic matter in suboxidizing sea coast environments. In the Yanov Stan (J3–K1), Gol’chikha (J2–K1), and, to a lesser extent, Malyshevka (J2), Nizhnyaya Kheta, and Shuratovka (K1) Formations, we have recognized widespread stratigraphic levels with marine organic matter of rocks. Its contents and degree of maturity permit these rocks to be considered oil-generating.  相似文献   

17.
This work characterizes the source rock potential of the Tarfaya Basin and enabled us to reconstruct its geochemical history. Outcrop samples covering different stratigraphic intervals, plus the northwestern part of the Zag/Tindouf Basin (Bas Draa area), were analyzed for total organic carbon (Corg) and total inorganic carbon contents and total sulfur content. Rock-Eval analysis and vitrinite reflectance measurements were performed on 56 samples chosen on the basis Corg content. A set of 45 samples were extracted and non-aromatic hydrocarbons were analyzed by way of gas chromatography-flame ionization detection (GC-FID) and GC-mass spectrometry (GC-MS). Non-isothermal open system pyrolysis at different heating rates was applied to obtain kinetic parameters for modelling petroleum generation from four different source rocks.High quality petroleum source rocks with high Corg content and hydrogen index (HI) values were found for samples of Eocene, Coniacian, Turonian and Cenomanian age. Most samples were carbonate rich and organic/sulfur values were high to moderate. Various maturity parameters indicated immature or possibly early mature organic matter. Based on organic geochemical and petrological data, the organic matter is of marine/aquatic origin (Cenomanian) or a mixture of aquatic and terrigenous material (Eocene). The Early Cretaceous interval did not contain high quality source rocks, but indications of petroleum impregnation were found.  相似文献   

18.
The Lower Yangtze region is one of the important marine sedimentation areas of oil and gas distribution in southern China,for its favorable source rocks,reservoirs and covers.However,the intense tectonic movements and complex hydrocarbon generation process made it highly impossible to form large-sized oil and gas reservoirs.So it was divided to different hydrocarbon-bearing preservation units in oil-gas exploration.Recent study shows that the Permian and Lower Triassic source rocks in the Lower Yangtze region are complicated in lithology.The hydrocarbon generation potential of limestone there is low while argillaceous source rocks are overall of high abundance with excellent organic types,now in the process of hydrocarbon generation,so differences in high maturity influence the evaluation of organic matter abundance and type.Biomarker characteristics indicate a reductive environment.n-alkanes are marked by a single peak,with no odd-even predominance.The composition and distribution of the carbon numbers of n-alkanes,and the high abundance of long-chain tricyclic terpanes are indicative of marine sedi-mentation.The high contents of pregnane,homopregnane,rearranged hopane suggest that the source rocks are of high maturity.There is a good linear correlation between methylphenanthrene index and vitrinite reflectance.The correlation of oil-source rocks indicated that the oil of Well HT-3 may come from the Permian Longtan Formation in the Huangqiao area,the oil of Wells Rong-2 and Juping-1 came from the Lower Triassic Qinglong Formation in the Jurong area.The exploration here is promising in those different source rocks which all have great potential in hy-drocarbon generating,and oil and gas were produced in the late stage of hydrocarbon generation.  相似文献   

19.
东营凹陷牛38井沙河街组烃源岩生排烃评价   总被引：17，自引：7，他引：10       下载免费PDF全文
陈中红  查明  金强 《地质科学》2004,39(3):356-366
东营凹陷牛38井沙河街组三段烃源岩从沙三下亚段向沙三中-上亚段为一从高水位深湖相向低水位前三角洲相发展的沉积旋回,该沉积环境控制从下向上发育不同类型的有机质。相应地,该段烃源岩品质从下向上变差,其中沙三中亚段上部及沙三中亚段中部烃源岩产烃能力小,沙三下亚段烃源岩整体品质好,局部存在优质烃源岩。其优劣性体现了在该段烃源岩中,Ⅰ型干酪根具有高的生产力,而Ⅲ型、Ⅱ2型干酪根生烃潜力很低,基本为无效有机质。计算结果显示不同数据点的烃源岩单位质量原始生烃潜量可相差3个数量级,体现了烃源岩存在强烈的非均质性。有机碳的非均质性分布为其提供了物质基础,而湖盆的旋回式沉积及湖平面的波动性变化是其内在原因。同时,本文也提供一种计算生排烃量的新方法,结果表明该方法较为有效可行。  相似文献   

20.
The Eocene Maoming oil shale from Guangdong Province occurs as a laterally uniform stratigraphic section, typically 20–25 m thick, from which the aliphatic hydrocarbon constituents of six representative samples were investigated using GC and C-GC-MS. The sediments evaluated included the basal lignite, a vitrinite lens from the overlying claystone, and four intervals from the massive oil shale bed. As expected, the lignite and vitrinite differ markedly from the oil shales. The lignite is dominated by bacterial hopanoids and components of higher plant origin, including C29 steroids and triterpenoids such as oleanenes. Visually, the oil shale samples show corroded and degraded phytoclasts, spores, wispy particles of fluorescent organic material attributable to dinoflagellates and, especially in the uppermost sample, colonial algal bodies. The distributions of biological markers in the oil shales show many features in common, notably a dominance of dinoflagellate-derived 4-methylsteroids, and a significant proportion of higher-plant derived n-alkanes with marked odd-over-even carbon number predominance. Overall, they exhibit several features that resemble characteristics of the Messel shale. The hydrocarbons of the lowest shale horizon suggest that there may have been a gradual transition between deposition of the original peat and the subsequent oil shales. The aliphatic hydrocarbons of the uppermost shale are dominated by a number of C31 and C33 botryococcane homologues and other unusual branched alkanes possibly derived from green algae. All of the samples are immature. Overall, molecular and microscopic examination of the stratigraphic succession of the Maoming oil shale suggests a shallow, lacustrine environment within which peats were deposited. This lake subsequently deepened to support abundant algal populations, especially dinoflagellates, culminating in a dominance of botryococcoid algae.  相似文献   

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