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1.
The occurrence of dental/skeletal fluorosis among the people in the study area provided the motivation to assess the distribution, severity and impact of fluoride contamination in groundwater of Bankura district at Simlapal block, West Bengal, India. To meet the desired objective, groundwater samples were collected from different locations of Laxmisagar, Machatora and Kusumkanali regions of Simlapal block at different depths of tube wells in both pre- and post-monsoon seasons. Geochemical results reveal that the groundwaters are mostly moderate- to hard-water type. Of total groundwater samples, 37% are situated mainly in relatively higher elevated region containing fluoride above 1.5 mg/L, indicating that host aquifers are severely affected by fluoride contamination. Machatora region is highly affected by fluoride contamination with maximum elevated concentration of 12.2 mg/L. Several symptoms of fluorosis among the different age-groups of people in Laxmisagar and Machatora areas are indicating consumption of fluoridated water for prolonged period. The groundwater samples were mainly Na–Ca–HCO3 type and rock dominance indicating the dissolution of minerals taking place. Ion exchange between OH? ion and F? ion present in fluoride-bearing mineral is the most dominant mechanism of fluoride leaching. High concentration of Na+ and HCO3 ? increases the alkalinity of the water, providing a favorable condition for fluoride to leach into groundwater from its host rocks and minerals.  相似文献   

2.
High fluoride in groundwater has been reported from many parts of India. However, a systematic study is required to understand the behaviour of fluoride in natural water in terms of local hydrogeological setting, climatic conditions and agricultural practices. Present study is an attempt to assess hydrogeochemistry of groundwater in Ajmer district in Rajasthan to understand the fluoride abundance in groundwater and to deduce the chemical parameters responsible for the dissolution activity of fluoride. Ajmer district falls in the semi-arid tract of central Rajasthan and is geologically occupied by Precambrian rocks (granites, pegmatites, gneisses, schists etc) where groundwater occurs under unconfined condition. A total of 153 well-water samples, representing an area of 8481 km2 (further subdivided into eight blocks), were collected and chemically analyzed. The results of chemical analyses (pre-monsoon 2004) show fluoride abundance in the range of 0.12 to 16.9 mg/l with 66% of the samples in excess of permissible limit of 1.5 mg/l. Presence of fluoride bearing minerals in the host rock, the chemical properties like decomposition, dissociation and dissolution and their interaction with water is considered to be the main cause for fluoride in groundwater. Chemical weathering under arid to semi-arid conditions with relatively high alkalinity favours high concentration of fluoride in groundwater. Dental and skeletal fluorosis are prevalent in the study area which can be related to the usage of high fluoride groundwater for drinking. The suggested remedial measures to reduce fluoride pollution in groundwater include dilution by blending, artificial recharge, efficient irrigation practices and well construction.  相似文献   

3.
The groundwaters from Zhongxiang City, Hubei Province of central China, have high fluoride concentration up to 3.67 mg/L, and cases of dental fluorosis have been found in this region. To delineate the nature and extent of high fluoride groundwaters and to assess the major geochemical factors controlling the fluoride enrichment in groundwater, 14 groundwater samples and 5 Quaternary sediment samples were collected and their chemistry were determined in this study. Some water samples from fissured hard rock aquifers and Quaternary aquifers have high fluoride concentrations, whereas all karst water samples contain fluoride less than 1.5 mg/L due to their high Ca/Na ratios. For the high fluoride groundwaters in the fissured hard rocks, high HCO3 − concentration and alkaline condition favor dissolution of fluorite and anion exchange between OH− in groundwater and exchangeable F− in some fluoride-bearing minerals. For fluoride enrichment in groundwaters of Quaternary aquifers, high contents of fluoride in the aquifer sediments and evapotranspiration are important controls.  相似文献   

4.
Hydrochemical studies were carried out in Mulugu-Venkatapur Mandals of Warangal district, Telangana state, India to find out the causes of high fluorides in groundwater and surface water causing a widespread incidence of fluorosis in local population. The fluoride concentration in groundwater ranges from 0.28 to 5.48 mg/l with a mean of 1.26 mg/l in pre-monsoon and 0.21 to 4.43 mg/l with a mean 1.45 mg/l in post-monsoon. About 32% and 34% of samples in pre and post-monsoon containing fluoride concentrations that exceed the permissible limit. The Modified Piper diagram reflects that, water belong to Ca+2-Mg+2-HCO3 - to Na+-HCO3 - facies. Negative chloroalkali indices in both the seasons prove that ion exchange took place between Na+ & K+ with Ca+2 and Mg+2 in aquatic solution in host rock. Different plots for major ions and molar ratios suggest that weathering of silicate rocks and water-rock interaction is responsible for major ion chemistry of water. High fluoride content in groundwater attributed to continuous water-rock interaction during the process of percolation with fluorite bearing country rocks under arid, low precipitation, and high evaporation conditions. The low calcium content in rocks and soils, and the presence of high content of sodium bicarbonate in soils and waters are important factors favouring high levels of fluoride in waters. The basement rocks provide abundant mineral sources of fluoride in the form of amphibole, biotite, fluorite, mica and apatite.  相似文献   

5.
Fluoride (F) contamination study had been carried out to see its allocation in Kurmapalli watershed, Nalgonda district, Andhra Pradesh, India. The study area is located about 60 km SE of Hyderabad city. The groundwater is the main source of water for their living. The groundwater in villages and its surrounding are affected by fluoride contamination and consequently the majority of the people living in these villages has health hazards and is facing fluorosis. The purpose of this study is to identify the wells with high F, raise awareness in people, study the water chemistry, and also find out the source of F in groundwater. A total of 32 groundwater samples were collected from different wells in both shallow aquifers and deeper fractures zones during October 2004. The chemical analysis of groundwater has been done. Fluoride values vary from 0.7 to 19.0 mg/l. It is noted that the maximum value (19.0 mg/l) is one of the highest values found in groundwater in India and 78% of the total samples show F concentrations that exceeds the permissible limit value (1.5 mg/l). The highest value of F is found at Madanapur bore well which is located at central part of the watershed. The F value of this bore well was monitored from October 2004 to October 2006. During this period the F concentration varies from 17.8 to 21.0 mg/l with mean 19.3 mg/l. There is no correlation of F with chemical parameters except calcium. The Ca has shown inverse proportional with F. Water–rock interaction studies were also carried out to understand the behavior of F in groundwater at prominent F affected areas. Rock samples were collected and analyzed, and found their enrichment of F. The anthropogenic possibility of F is almost negligible. The rocks of this area are enriched in F from 460 to 1,706 mg/kg. It is indicated that the rock–water interaction is the main source of F in groundwater. The highest values of F are found in middle part of the region and are related to the occurrence of fluoride rich rocks and their chemical kinetic behavior with groundwater.  相似文献   

6.
Dental fluorosis occurs because of fluoride over-absorption during tooth calcification and maturation. We studied fluoride concentration in water and soil samples of the Koohbanan region in Kerman province of southeastern Iran and the effects of calcium chloride and gypsum treatments in decreasing the amount of fluoride in water samples of this region. The results indicate that the high amount of fluoride in the water samples of Koohbanan region is not in agreement with the recommended amount of fluoride concentration for drinking water by World Health Organization (that is 1–1/5 mg/l). Applying calcium chloride and gypsum treatments decreased the amount of fluoride in the water samples showing that utilizing calcium chloride (6 mg/l) or gypsum (12 mg/l) can lower the fluoride concentration in the water samples of Koohbanan, and thus solve the observed dental fluorosis problem.  相似文献   

7.
Hydrochemical studies were conducted in Chinnaeru river basin of Nalgonda district, Andhra Pradesh, India, to explore the causes of high fluorides in groundwater and surface water causing a widespread incidence of fluorosis in local population. The concentration of fluoride in groundwater ranges from 0.4 to 2.9 and 0.6 to 3.6 mg/l, stream water ranges from 0.9 to 3.5 and 1.4 to 3.2 mg/l, tank water ranges from 0.4 to 2.8 and 0.9 to 2.3 mg/l, for pre- and post-monsoon periods, respectively. The modified Piper diagram reflects that the water belongs to Ca2+–Mg2+–HCO3 ? to Na+–HCO3 ? facies. Negative chloroalkali indices in both the seasons prove that ion exchange between Na+ and K+ in aquatic solution took place with Ca2+ and Mg2+ of host rock. The interpretation of plots for different major ions and molar ratios suggest that weathering of silicate rocks and water–rock interaction is responsible for major ion chemistry of groundwater/surface water. High fluoride content in groundwater was attributed to continuous water–rock interaction during the process of percolation with fluorite bearing country rocks under arid, low precipitation, and high evaporation conditions. The low calcium content in rocks and soils, and the presence of high levels of sodium bicarbonate are important factors favouring high levels of fluoride in waters. The basement rocks provide abundant mineral sources of fluoride in the form of amphibole, biotite, fluorite, mica and apatite.  相似文献   

8.
Birbhum district in West Bengal, India, is one of the most severely affected districts by fluoride-contaminated groundwater. Fluoride content as high as 20.4 mg/L has been reported. Several cases of fluoride-related disorder such as dental fluorosis and skeletal fluorosis have been reported to be endemic in the district. Proper management of groundwater is very crucial. This contribution has been carried out for delineating potential fluoride-contaminated zones (PFCZ) in Birbhum district with the implementation of weighted overlay analysis in GIS environment. Twelve different potentially influential environmental parameters are integrated and evaluated. The final output map was categorised into two subclasses, i.e. ‘low’ and ‘high’, where the low region represents fluoride concentration of 1.5 mg/L and below and the high region represents fluoride concentration above 1.5 mg/L. The outcome reveals that approximately 24.35% of the study area falls under PFCZ, whereas about 75.65% of the study area falls under the safe zone with respect to potential fluoride contamination. On validation of the PFCZ, the reported fluoride contamination data in groundwater shows an overall 87.50% accuracy in prediction via superimposition method and 89.06 and 85.85% success and prediction rates, respectively, when validated with success and prediction rates.  相似文献   

9.
The contamination of aquifers by fluoride and arsenic is a major cause of concern in several parts of India. A study has thus been conducted to evaluate the extent and severity of fluoride contamination and also its seasonal variability. Two blocks (Purulia-1 and Purulia-2) were considered for this purpose. Twenty groundwater samples (in each season) were collected from tube wells during the pre-monsoon and post-monsoon seasons. In addition to fluoride, groundwater samples were also analyzed for major cations, anions, and other trace elements. The concentration of fluoride shows significant seasonal variation and ranges between 0.94–2.52 and 0.25–1.43 mg/l during the pre-monsoon and post-monsoon seasons, respectively. In pre-monsoon season, more than 40% of the water samples show fluoride concentrations higher than the WHO limit. However, during the post-monsoon season, none of the groundwater sample shows fluoride concentrations higher than the WHO limit. Lesser concentration during the post-monsoon season is attributed to the dilution effect by the percolating rainwater, which has also been reflected in the form of a decrease in concentrations of other elements. The petrographic studies of the rock samples collected from the study area show that the rocks are mainly composed of plagioclase, orthoclase, and quartz with abundant biotite. The weathering and dissolution of biotite plays an important role in controlling the fluoride concentrations in the groundwater of the study area.  相似文献   

10.
Rock–water interaction along with mineral dissolution/ precipitation plays a profound role in the control of fluoride ion concentration within the alluvial groundwater in a part of semi-arid northern India. In the premonsoon season, the alluvial region experiences evaporative processes leading to increase in Na+ ions which through reverse ion exchange processes are adsorbed onto suitable sites within the aquifer matrix in exchange for Ca2+ ion in solution. Increase in Ca2+ ions in solution inhibits fluorite mineral dissolution, thereby controlling premonsoon fluoride ion concentration within alluvial groundwaters (1.40?±?0.5 mg/l). In the postmonsoon season, however, higher average fluoride ion concentration within the alluvial aquifer samples (2.33?±?0.80 mg/l) is observed mainly due to increase in silicate weathering of fluoride-bearing rocks and direct ion exchange processes enabling Ca2+ ion uptake from solution accompanied with the release of fluoride ions. Combined effect of these processes results in average fluoride ion concentration falling above the WHO drinking water permissible limit (1.5 mg/l). Alternatively, the hard rock aquifer samples within the study area have an average fluoride ion concentration falling below the permissible limit in both the seasons.  相似文献   

11.
各类型氟中毒病区与各类地质环境存在着明显的一致性。中、重病区类型区分布于地下水迳流的区域汇水区 冲积湖积低平原 水化学作用的元素富集区。单一中病类型区分布在迳流区——汇水区的过渡带 风砂覆盖的冲积湖积平原和冲积湖积平原的结合部 水化学作用方向的砂丘水对致病水层的补给淡水。单一轻病类型区分布在地下水的迳流区 风砂覆盖的冲积湖积平原 水化学作用方向的元素迁移区。镶嵌于中、重病类型区内的轻病区分布在冲积平原(霍林河河漫滩) 水化学作用方向为河水的对致病水层补给淡化。饮水氟含量与氟骨症患病率呈定域正相关关系,当饮水氟含量超过6 mg/l时,患病率保持基本不变。影响氟中毒滋生的诸地质环境因素中地下水动力条件起着根本性作用。  相似文献   

12.
Excess fluoride in groundwater affects the human health and results in dental and skeletal fluorosis. Higher concentration of fluoride was noted in hard rock terrain of the south India, in the Krishnagiri district of Tamilnadu. The region has a complex geology ranging from ultra basic to acid igneous rocks, charnockite and gneissic rocks. Thirty-four groundwater samples were collected from this study area and analysed for major cations and anions along with fluoride. The order of dominance of cations is Na+?>?Mg2+?>?Ca2+?>?K+ and the anions in the following order HCO3 ??>?Cl??>?NO3 ??>?SO4 2?. It is found that nearly 58 % of the samples have more fluoride ranging from 1 to 3 mg/L. It is also noted that high fluoride waters correspond to magnesium water types. This is due to the release of fluoride from the magnesium-bearing minerals like, biotite, hornblende, etc., or weathering of apatite/hydroxyapatites found in charnockites.  相似文献   

13.
Geochemical study of groundwater from 58 selected fluoride-rich areas in different parts of India that includes eight states indicates that: 1. These groundwaters are alkaline in pH (7.4-8.8) and their electrical conductivity varies from 530-2,680 µS/cm and fluoride concentration from 1.7-6.1 mg/l. Presence of fluoride-bearing minerals in the host rocks and their interaction with water is considered to be the main cause for fluoride in groundwater. 2. The decomposition, dissociation and dissolution are the main chemical processes for the occurrence of fluoride in groundwater. During rock-water interaction, concentration of fluoride in rock, aqueous ionic species and residence time of interaction, etc. are also important parameters. 3. This study indicates that 85% groundwater samples have EC: 1,000-2,000 µS/cm, pH: 7.5-8.5, and HCO3/Ca (epm ratio): 0.8-2.3. 4. The Ca and HCO3 contents of groundwater samples have shown good correlation with fluoride.  相似文献   

14.
A study was undertaken to examine the content and spatial distribution of fluoride in drinking water. Water samples (735) from public water systems covering all Estonian territory were analysed using SPADNS method. In order to specify the natural source of fluoride, the chemistry data from five aquifer systems utilised for water supply were included into the study. Fluoride concentrations in tap water, to a great extent, ranged from 0.01 to 6.95 mg/l. Drinking water in southern Estonia, where terrigenous Middle-Devonian aquifer system is exploited, has a fluoride concentration lower than recommended level (0.5 mg/l), thus promoting susceptibility to dental caries. The western part of the country is supplied by water with excess fluoride content (1.5–6.9 mg/l). Groundwater abstracted for drinking purposes originates from Ordovician and Silurian carbonate rocks. The content of fluoride in Silurian–Ordovician aquifer system is associated with the groundwater abstraction depth and the main controlling factors of dissolved fluoride are the pH value and the chemical type of water.  相似文献   

15.
 The most appropriate and widely used source of drinking water for the populations of the upper regions of Ghana is groundwater. In general, groundwater quality is acceptable except for some parts of the Bolgatanga and Bongo Districts, where there are occurrences of elevated levels of natural groundwater fluoride. Concentrations of groundwater fluoride in excess of the World Health Organization (WHO) maximum guideline value (1.5 mg/l) in the Bongo area have been known since 1978. However, the effect of fluoride on people ingesting the water did not receive public and medical attention until October 1993, when health personnel were asked to investigate the cause of stained teeth in school children. The investigation established that 62% of the total population of school children in the Bongo area had dental fluorosis. Against this background, a study was initiated to understand the geochemistry, genesis, and distribution of fluoride in relation to the geology of the area. Groundwater fluoride in the upper regions ranges from 0.11 to 4.60 ppm, with the highest concentrations associated with the fluorine-enriched Bongo coarse-grained hornblende granite and syenite suite. The source of groundwater fluoride within the Bongo granitoids is dissolution of the mineral fluorite and dissolution of and anion exchange with micaceous minerals and their clay products. Applying the WHO recommended guideline values for fluoride in drinking water reveals that 49% of wells in the area deliver water below the optimum level of 0.5 mg/l F–; these populations are thus prone to dental caries. Twenty-eight percent of the wells fall within the optimum interval for good dental health (0.5–1.5 mg/l F–). Twenty-three percent of the wells have concentrations above the recommended maximum guideline limit of 1.5 mg/l F–; this population is susceptible to dental and possibly skeletal fluorosis. Climatic conditions of the area suggest that the individual water consumption is in the order of 3 to 4 l which is higher than the WHO estimate of 2 l/adult/day. In addition, dietary intake for the upper region population is probably higher than WHO baseline values (0.2–0.5 mg/day). This implies that a much higher population is susceptible to developing dental and skeletal fluorosis than originally suspected. Geochemical symbol plot maps help geochemists understand factors controlling the distribution and uptake of fluoride in the upper regions, but they are of minimal value to health officials responsible for planning epidemiological studies and dental health education programs in the region. By casting fluoride data into contoured 'geochemical health-risk maps' using intake interval guidelines more closely aligned to regional climatic and dietary conditions, health officals can better judge the impacts (regional and population based) of fluoride on segments of the population, such as various sex and age groups. Received: 11 March 1997 · Accepted: 17 June 1997  相似文献   

16.
Chemical characterization has been made of groundwater bodies at 294 locations in four village districts in north-central and northwestern Sri Lanka, with special focus on fluorine contamination. High fluoride contents in groundwater are becoming a major problem in the dry zone of Sri Lanka, and dental fluorosis and renal failures are widespread. Field measurements of temperature, pH, and electrical conductivity were made during sampling. Chemical analyses of the water samples were later made using atomic absorption spectroscopy, spectrophotometry, and titration. Fluoride concentrations in the study area vary from 0.01 to 4.34 mg/l, and depend on pH and the concentrations of Na, Ca, and HCO3 −. Basement rocks including hornblende biotite gneiss, biotite gneiss, and granitic gneiss seem to have contributed to the anomalous concentrations of fluoride in the groundwater. Longer residence time in aquifers within fractured crystalline bedrocks may enhance fluoride levels in the groundwater in these areas. In addition, elevated fluoride concentrations in shallow groundwater in intensive agricultural areas appear to be related to the leaching of fluoride from soils due to successive irrigation.  相似文献   

17.
Fluoride pollution is a widespread problem in Argentina, as it is in many areas of the World. Former investigations have demonstrated that the dissolution of volcanic glass disseminated in the loess-like sediments is the main source of fluoride in the Argentine pampas. Nevertheless, fluoride distribution is erratic and the factors controlling it are not yet well-known. A large amount of hydrochemical data collected in the Quequen Grande river catchment is used in order to contribute to the understanding of fluoride distribution and mobility in groundwater in the Argentine pampas. The Quequen Grande river catchment is 10,000 km2. It extends between two low hills ranges of Precambrian metamorphic rocks and sedimentary Paleozoic rocks, filled by a thick sequence of Cenozoic sediments, mainly silts and silt-clayed, with sand layers. These sediments form a multilayer phreatic aquifer, which is recharged from precipitation infiltration, discharging through streams directly into the sea. Fluoride concentration in surface water (n = 353) ranges between 0 and 6.5 mg/l, with an average value of 2.14 mg/l. Groundwater concentration (n = 135) is from 0 up to 5.7 mg/l, with an average of 1.84 mg/l. Considering the statistic distribution of fluoride, two groups of samples can be determined. A dominant group between 0 and 3 mg/l, with a mean value around 1.5 mg/l, corresponding to samples widely distributed in the catchment; and a second one group with fluoride contents between 3 and 6 mg/l, corresponding to a smaller area in the central-west border. Two different sources are proposed. Volcanic glass dissolution is responsible for dominant values in the catchment, while the weathering of biotite from the Paleozoic bedrock can be assumed to account for the higher concentrations in the second group.  相似文献   

18.
This paper reports occurrence of high fluoride concentration in groundwater of Gharbar Village, Dhanbad District, Jharkhand, India. The concentration of fluoride varied from 0.3 to 14.9 mg/L in 27 groundwater samples. The correlation studies demonstrate that fluoride has strong positive correlation with pH and sodium and negative correlation with calcium. It indicates dominance of ion exchange activity and rock water interaction. Thermodynamic consideration shows that all the samples were oversaturated with calcite and most of the samples were under saturated with fluorite. The results indicate that occurrence of high concentration of fluoride is leading by geochemical composition of rocks, alkaline environmental condition, weathering of rocks and ion exchange processes.  相似文献   

19.
Groundwater is one of the most important natural resources of drinking water on the earth planet. In rural areas of Yemen, groundwater is the main resource for drinking as well as for domestic purposes. According to the World Health Organization, one of the most important elements that has to be found in drinking water is fluorine (fluoride) but within the range of concentration of 0.5 up to 1.5 mg/l. Otherwise, any concentration of fluoride out of that range may cause serious diseases in human’s body such as fluorosis, kidney chronic disease, and/or nephrotoxicity. Taiz City, the third important and largest city in Yemen, has been suffering from dental fluorosis for a few decades. The main resource for drinking water in this city and adjacent areas is Al-Howban Basin (the study area) from where 33 groundwater samples were collected from 33 stations. These samples were preserved and then chemically analyzed according to the American Public Health Association Standards. The results reflected high levels of fluoride concentrations up to 3.6 mg/l in groundwater of many stations. GIS mapping was used to produce a geospatial distribution map of fluoride concentrations using ArcGIS-inverse distance weighted (IDW) tool. As a result, three zones of risks were identified in the study area: mild risk zone which covers the major part of the study area, moderate risk zone, and zone of no risk (optimum level zone). The last two zones occupy small portions of the study area. Consequently, dental and skeletal fluorosis, kidney, and/or nephrotoxic diseases are highly expected to be detected in the study area. Groundwater treatment measurements and health precautions are strongly recommended to be taken by local authorities in the near future.  相似文献   

20.
The source of fluoride toxicity in Muteh area,Isfahan, Iran   总被引：1，自引：0，他引：1  
Endemic dental fluorosis has been observed in most inhabitants of three villages of Muteh area, located in northwest of Isfahan province, with mottled enamel related to high levels of fluoride in drinking water (1.8–2.2 ppm). Forty-seven groundwater samples from six villages were collected and fluoride concentrations along with physico-chemical parameters were analyzed. Fluoride concentration in this area varies from 0.2 to 9.2 mg/l with highest fluoride level at Muteh gold mine (Chahkhatun mine). Fluoride concentration positively correlates with pH and HCO3 − indicating that alkaline pH provides a suitable condition for leaching of fluoride from surrounding rocks. The district is mainly covered by three lithological units, namely, metamorphic and granite rocks, alluvial sediments, and carbonate rocks. Factor analysis shows that parameters can be classified into four components: electrical conductivity (EC), total dissolved solids (TDS), Cl−, Na+ and K+, pH and F−, SO4 2−and Mg2+, HCO3 − and Ca2 +. The groundwaters from the three geological units were compared using Mann–Whitney U test. The order of median fluoride concentration is: metamorphic and granite rocks > alluvial sediments > carbonate rocks. Hence, the fluoride content is most probably related to fluoride-bearing minerals such as amphibole and mica group minerals in metamorphic and granitic rocks. The concentration of fluoride in drinking water wells located near the metamorphic complex in Muteh area is above 2 ppm.  相似文献   

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