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1.
A method for selective annealing of cosmic-ray tracks has been developed, permitting determination of fission-track ages in the presence of a large background of cosmic-ray tracks. The mesosiderite Bondoc contains 41 fission tracks/cm2, of which about 75% are due to neutron-induced fission of U235 during cosmic-ray exposure. Its net fission-track age is 140 ± 40 Myr, nearly identical to its cosmic-ray exposure age of 150 Myr. The mesosiderite Mincy has a fission-track age of 1500 ± 400 Myr.Nakhla (nakhlite) contains an excess of apparent fission tracks, which may be either genuine fission tracks from Pu244 or etch pits mimicking fission tracks in length, thermal stability, random orientation, and other characteristics. On the assumption that they are fission tracks, the Pu244/U238 ratio at the onset of track retention in Nakhla was (3.1 ± 1.3) × 10?3, nearly an order of magnitude lower than the initial solar system ratio. This may reflect a chemical fractionation of Pu and U, or a late impact or magmatic event. Different minerals of the Washougal howardite have different Pu244/U238 ratios, from (24 ± 7) × 10?3 to (2.3 ± 0.7) × 10?3. This may imply a succession of impacts over a period of time. Additionally, Pu and U may have been chemically fractionated from each other in this meteorite.Shocked meteorites show no consistent pattern in the retentivity of fission tracks and of fissiogenic or radiogenic noble gases. Some meteorites, e.g. Bondoc, Serra de Magé, and Mincy, retain gases more completely than tracks; others, e.g. Nakhla and Allende, retain them less completely.Uranium was determined in feldspar and/or pyroxene from 19 Ca-rich achondrites and mesosiderites. For most, only upper limits of 0.01–0.03 ppb were obtained. Apparently the uranium in these meteorites resides almost exclusively in minor phases, as in terrestrial and lunar rocks.  相似文献   

2.
We have used a direct imaging technique, in situ atomic force microscopy (AFM), to observe the dissolution of the basal biotite surface by oxalic acid over a range of temperatures close to ambient conditions, using a specially designed AFM liquid cell and non-invasive intermittent contact mode of operation. From the 3-dimensional nanometre-resolution data sets, we observe a process characterised by the slow formation of shallow etch pits in the (0 0 1) surface and fast growth of etch pits from the resulting steps, which represent proxies for the {h k 0} surface. Measurements of dissolution rates as a function of temperature allow a determination of an apparent activation energy (Ea,app) for the process, via mass-loss calculations from image analysis. We obtain a value of Ea,app = 49 ± 2 kJ mol−1, which is consistent with separate calculations based on planar area etch pit growth, and measurements of etch pit perimeters, indicating that this value of Ea,app is representative of {h k 0} surface dissolution. The measurement of etch pit perimeters also enables an estimation of apparent activation energy as a function of step density indicating substantially higher apparent activation energy, up to Ea,app = 140 kJ mol−1, on extrapolation towards a pristine surface with no defects. We suggest that this higher value of Ea,app represents the slow formation of etch pits into the (0 0 1) surface.  相似文献   

3.
Charged particle tracks were studied in the Angra dos Reis and Moore County meteorites, both of which contain an unexplained excess of He4. A selective annealing method was used to resolve cosmic-ray tracks from fission tracks. It gave the following cosmic-ray and fission-track densities, in units of 106cm?2: Angra dos Reis 1.3–4.4 and 7.8; Moore Co. feldspar 1.9–3.0 and 0.51; Moore Co. pigeonite 2.0–2.9 and 0.078–0.35. The fission-track densities are 10–100 times higher than expected from U238; the excess is probably due to extinct Pu238. The Pu244/U238 ratios at the start of track retention were 0.003 for Angra dos Reis and 0.002–0.03 for Moore Co. No evidence was found for fission tracks attributable to the unknown progenitor of excess He4 in these meteorites; the fission branch of this progenitor comprises less than 10?5 the α-branch. A search for pleochroic halos also gave negative results.The preatmospheric radii of the two meteorites are ≥13 and ≥7cm. According to meteor theory, this implies geocentric velocities of ≥ 19 and ≥ 6 km/sec.The etching behavior of Angra dos Reis augite is highly anomalous, giving rise to spurious angular anisotropies and skewed length distributions. This confirms similar observation by Fleischer et al. (1970) on lunar augite.  相似文献   

4.
Many etch-pits on olivine grains occur as a pair of cone-shaped pits sharing a base, which consequently appear as diamond-shaped etch-pits in cross-section. Quantitative image analysis of back-scattered electron images establishes empirical dimensions of olivine etch-pits in naturally weathered samples from Hawaii and North Carolina. Images of naturally etched olivine were acquired from polished thin-sections by scanning electron microscopy. An average cone-radius-to-height ratio (r:h) of 1.78 was determined for diamond-shaped cross-sections of etch-pits occurring in naturally weathered olivine grains, largely consistent with previous qualitative results. Olivine etch-pit shape as represented by r:h varies from slightly more than half the average value to slightly more than twice the average. Etch-pit shape does not appear to vary systematically with etch-pit size.  相似文献   

5.
The recent development of the coalbed methane (CBM) industry has a significant role in advancing hydraulic fracturing theory and technology. However, further development requires a better understanding of how fractures influence reservoir permeability. In situ stress data from 54 CBM wells in the southern Qinshui Basin, China, were obtained by the injection/falloff test method to analyse the effect of in situ stress on the permeability of the CBM reservoir. The types of in situ stress states were classified, and the coal reservoir permeability under different in situ stress states was analysed. The results indicate that the maximum horizontal principal stress (σH), minimum horizontal principal stress (σh) and vertical principal stress (σv) all have positive linear relationships with the coal seam burial depth. Three in situ stress states were observed from the shallow to deep regions of the CBM reservoir in the study area: σH?>?σh?>?σv, σH?>?σv?>?σh and σv?>?σH?>?σh, which account for 9, 76 and 15% of the test wells, respectively. Coal reservoir permeability decreases with increasing horizontal principal stress, whereas it first decreases with increasing σv, then increases and finally decreases. The variation in permeability with σv is due to the conversion of the in situ stress states. Coal reservoir permeability has obvious differences under different in situ stress states. The permeability is the largest when σv?>?σH?>?σh, followed by σH?>?σh?>?σv and smallest when σH?>?σv?>?σh. The permeability differences are caused by the fracture propagation shape of the rock strata under different in situ stress states.  相似文献   

6.
The combined influence of dip angle and adsorption heterogeneity on solute transport mechanisms in heterogeneous media can be understood by performing simulations of steady-state flow and transient transport in a heterogeneous aquifer with dipping anisotropy. Reactive and non-reactive contaminant transport in various types of heterogeneous aquifer is studied by simulations. The hydraulic conductivity (K) of the heterogeneous aquifer is generated by HYDRO_GEN with a Gaussian correlation spectrum. By considering the heterogeneity of the adsorption distribution coefficient (K d), a perfect negative correlation between lnK and lnK d is obtained by using the spherical grains model. The generated K and K d are used as input to groundwater flow and transport models to investigate the effects of dipping sedimentary heterogeneity on contaminant plume evolution. Simulation results showed that the magnitude of the dip angle strongly controls the plume evolution in the studied anisotropic and heterogeneous aquifer. The retarded average pore-water velocity (v/R) of the adsorption model significantly controls the horizontal spreading of the plume. The bottom plume is intensively retarded in the zones between the dipping lenses of lower hydraulic conductivity and the no-flow bottom boundary. The implications of these findings are very important for the management of contaminated heterogeneous aquifers.  相似文献   

7.
An analysis of a five-parameter family of cosmological models in a spatially flat Friedmann Universe with a zero Λ term is presented. The five parameters are (1) σ8, the dispersion of the mass fluctuations in a sphere with radius 8h ?1 Mpc, where h=H 0/100 km s?1 Mpc?1 and H 0 is the Hubble constant; (2) n, the slope of the density-perturbation spectrum; (3) Ωv, the normalized energy density of hot dark matter; (4) Ωb, the baryon density; and (5) h, the normalized Hubble constant. The density of cold dark matter is determined from the condition Ω cdm >1?Ωv?Ω b . Analysis of the models is based on comparison of computational results with observational data for: (1) the number density and mass function of galaxy clusters (a so-called Press-Schechter formalism) and (2) the cosmic microwave background anisotropy. The first method enabled us to determine the value σ8=0.52±0.01 with high accuracy. Using the resulting normalization of the density-perturbation spectrum, we calculated a model for the anisotropy of the cosmic microwave background radiation on large scales (l?10, where l is the harmonic number) and the required contribution of cosmological gravitational waves, characterized by the parameter T/S. The restrictions on T/S become weaker as Ωv increases. Nevertheless, even when Ωv≤0.4, models with h+n≥1.5 require a considerable contribution from gravitational waves: T/S?0.3. On the other hand, in models with Ωv≤0.4 and a scale-invariant density-perturbation spectrum (n=1), we find T/S ?10(h?0.47). The minimization of T/S is possible only for the family of models with red spectra (n<1) and small h (<0.6). The value of Ωv is determined most accurately by the data onΔT/T near the first acoustic peak (l?200). By imposing a general restriction on the amplitude of gravitational waves T/S∈[0, 3] and taking into account the available observational data on the amplitude of the acoustic peak of Sakharov oscillations, ranges of possible values n and Ωv are derived. If the baryon number is constrained by nucleosynthesis data, the models under consideration can have both moderately red and blue power spectra n∈[0.9, 1.2] with a rather high concentration of hot particles Ωv∈[0.2,0.4]. The conditions that n<0.9 and/or Ωv<0.2 decrease the relative amplitude of the acoustic peak by over 30% compared to its value in the standard cold-dark-matter (CDM) model normalized using COBE data.  相似文献   

8.
Recognizing the heterogeneity of hydraulic conductivity and hyporheic flow is critical for understanding contaminant transfer and biogeochemical and hydrological processes involving streams and aquifers. In this study, the heterogeneity of hydraulic conductivity and Darcian flux in a submerged streambed and its adjacent exposed stream banks were investigated in the Beiluo River, northwest China. In the submerged streambed, Darcian flux was estimated by measurement of vertical hydraulic conductivity (K v) and vertical head gradient (VHG) using in-situ permeameter tests. On exposed stream banks, both horizontal hydraulic conductivity (K h) and K v were measured by on-site permeameter tests. In the submerged streambed, K v values gradually decreased with depth and the higher values were concentrated in the center and close to the erosional bank. Compared to the exposed stream banks, the K v values were higher in the streambed. From stream stage to the topmost layer of tested sediment, through increasing elevation, the K h values increased on the erosional bank, while they decreased on the depositional bank. The values of VHG along the thalweg illustrate that downwelling flux occurred in the deepest area while upwelling flux appeared in the other areas, which might result from the change of streambed elevation. The higher value of the Darcian flux in the submerged streambed existed near the erosional bank.  相似文献   

9.
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10.
Magnesium inhibition of calcite dissolution kinetics   总被引：1，自引：0，他引：1  
We present evidence of inhibition of calcite dissolution by dissolved magnesium through direct observations of the (104) surface using atomic force microscopy (AFM) and vertical scanning interferometry (VSI). Far from equilibrium, the pattern of magnesium inhibition is dependent on solution composition and specific to surface step geometry. In CO2-free solutions (pH 8.8), dissolved magnesium brings about little inhibition even at concentrations of 0.8 × 10−3 molal. At the same pH, magnesium concentrations of less than 0.05 × 10−3 molal in carbonate-buffered solutions generate significant inhibition, although no changes in surface and etch pit morphology are observed. As concentrations exceed magnesite saturation, the dissolution rate shows little additional decrease; however, selective pinning of step edges results in unique etch pit profiles, seen in both AFM and VSI datasets. Despite the decreases in step velocity, magnesium addition in carbonated solutions also appears to activate the surface by increasing the nucleation rate of new defects. These relationships suggest that the modest depression of the bulk rate measured by VSI reflects a balance between competing reaction mechanisms that simultaneously depress the rate through selective inhibition of step movement, but also enhance reactivity on terraces by lowering the energy barrier to new etch pit formation.  相似文献   

11.
In this article, we have established the energy matrices of the strong-field terms SΓ of the d 4 (d 6) electron configuration in a crystal-field with C 2v symmetry. When we used this procedure to calculate the spin-forbidden absorption bands of Fe2+ in the M(2) site in orthopyroxene, we substituted the single-electron crystal-field energy levels (determined by the experimental results of the spinallowed spectrum) into the energy matrices instead of the single-electron crystal-field matrix elements. Thus, by means of only one parameter B (C=4B), most of the spin-forbidden bands of Fe2+ have been determined. Furthermore, when a similar treatment was made of the M(1) site of O h symmetry, the entire spin-forbidden spectrum of Fe2+ in orthopyroxenes could be semiquantitatively explained. This shows that the method is particularly useful for the calculation of spin-forbidden spectra of complexes with the d 4 (d 6) configuration in a low-symmetry site.  相似文献   

12.
Direct measurements of calcite faces were performed using in situ atomic force microscopy (AFM) to reveal the dissolution processes as a function of solution saturation state and temperature. Time-sequential AFM images demonstrated that step velocities at constant temperature increased with increasing undersaturation. The anisotropy of obtuse and acute step velocities appeared to become more significant as solutions approached equilibrium and temperature increased. At saturation state Ω > 0.02, a curvilinear boundary was formed at the intersection of two acute steps and the initially rhombohedral etch pit exhibited a nearly triangular shape. This suggests that the and steps may not belong to the calcite-aqueous solution equilibrium system. Further increase in the saturation state (Ω ? 0.3) led to a lack of etch pit formation and dissolution primarily occurred at existing steps, in accordance with Teng (2004). Analysis of step kinetics at different temperatures yielded activation energies of 25 ± 6 kJ/mol and 14 ± 13 kJ/mol for obtuse and acute steps, respectively. The inconsistencies in etch pit morphology, step anisotropy, and step activation energies from the present study with those of studies far-from-equilibrium can be explained by increased influence of the backward reaction, or growth, near-equilibrium. We propose that the backward reaction occurs preferentially at the acute-acute kink sites. The kinetics and effective activation energies of near-equilibrium calcite dissolution presented in this work provide accurate experimental data under likely CO2 sequestration conditions, and thus are crucial to the development of robust geochemical models that predict the long-term performance of mineral-trapped CO2.  相似文献   

13.
Dissolution experiments on single crystals of uranophane and uranophane-β, Ca(H2O)5[(UO2)(SiO3(OH)]2, from the Shinkolobwe mine of the Democratic Republic of Congo, were done in an aqueous HCl solution of pH 3.5 for 3 h, in HCl solutions of pH 2 for 5, 10 and 30 min, and in Pb2+-, Ba-, Sr-, Ca- and Mg-HCl solutions of pH 2 for 30 min. The basal surfaces of the treated uranophane crystals were examined using atomic-force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). Solutions after dissolution experiments on single crystals and synthetic powders were analysed with inductively coupled plasma-optical emission spectroscopy (ICP-OES) and mass spectroscopy (ICP-MS). The morphology of the observed etch pits (measured by AFM) were compared to the morphology, predicted on the basis of the bond-valence deficiency of polyhedron chains along the edges of the basal surface. Etch pits form in HCl solutions of pH 2. Their decrease in depth with the duration of the dissolution experiment is explained with the stepwave dissolution model, which describes the lowering of the surrounding area of an etch pit with continuous waves of steps emanated from the etch pit into the rest of the crystal surface. Hillocks form in an HCl solution of pH 3.5, and the chemical composition of the surface (as indicated by XPS) shows that these hillocks are the result of the precipitation of a uranyl-hydroxy-hydrate phase. Well-orientated hillocks form on the surface of uranophane in a SrCl2-HCl solution of pH 2. They are part of an aged silica coating of composition Si2O2(OH)4(H2O)n. An amorphous layer forms on the surface of uranophane in a MgCl2-HCl solution of pH 2, which has a composition and structure similar to silicic acid. Small crystallites of uranyl-hydroxy-hydrate phases form on the surface of uranophane after treatment in Pb(NO3)2-HCl and BaCl2-HCl solutions of pH 2. Dissolution experiments on synthetic uranophane powders show that in the early stage of the experiments, the dissolution rate of uranophane increase in the sequence Pb(NO3)2-HCl < BaCl2-HCl < CaCl2-HCl < HCl < SrCl2-HCl < MgCl2-HCl, indicating that the dissolution of uranophane is more enhanced in solutions containing divalent cations of small ionic radii and high Lewis acidity (Mg, MgCl+).  相似文献   

14.
This study reports a range of etching and annealing experiments to establish the optimum conditions for the etching of fission tracks in monazite. The previously reported concentrated (12 M) HCl etchant at 90°C was found to cause grain loss from epoxy mounts and high degrees of grain corrosion, as did much longer etching times at lower temperatures. Using implanted 252Cf semi‐tracks, a series of experiments were performed on internal prismatic faces of monazite‐(Ce) crystals from the Palaeozoic Harcourt Granodiorite (Victoria, Australia) using an alternative 6 M HCl etchant, also at 90°C. Step‐etch results show optimal etching at 60–90 min. Further, an isothermal annealing experiment illustrated that the degree of annealing that can be expected during etching at 90°C under laboratory time scales is negligible. The etching rate between grains is not uniform, with a correlation demonstrated between over‐etched grains and high U and Th concentrations.  相似文献   

15.
The influence of background electrolytes on the mechanism and kinetics of calcite dissolution was investigated using in situ Atomic Force Microscopy (AFM). Experiments were carried out far from equilibrium by passing alkali halide salt (NaCl, NaF, NaI, KCl and LiCl) solutions over calcite cleavage surfaces. This AFM study shows that all the electrolytes tested enhance the calcite dissolution rate. The effect and its magnitude is determined by the nature and concentration of the electrolyte solution. Changes in morphology of dissolution etch pits and dissolution rates are interpreted in terms of modification in water structure dynamics (i.e. in the activation energy barrier of breaking water-water interactions), as well as solute and surface hydration induced by the presence of different ions in solution. At low ionic strength, stabilization of water hydration shells of calcium ions by non-paired electrolytes leads to a reduction in the calcite dissolution rate compared to pure water. At high ionic strength, salts with a common anion yield similar dissolution rates, increasing in the order Cl− < I− < F− for salts with a common cation due to an increasing mobility of water around the calcium ion. Changes in etch pit morphology observed in the presence of F− and Li+ are explained by stabilization of etch pit edges bonded by like-charged ions and ion incorporation, respectively. As previously reported and confirmed here for the case of F−, highly hydrated ions increased the etch pit nucleation density on calcite surfaces compared to pure water. This may be related to a reduction in the energy barrier for etch pit nucleation due to disruption of the surface hydration layer.  相似文献   

16.
The a and c unit cell parameters of M(OH)2, brucite-like structures with M=Mg, Ni, Co, Fe, Mn, Cd, and Ca, are considered in relation to M-O distances taken as the sum of the ionic radii, MVI and OIV. The a parameters are related to (M-O) by flattening of the octahedral coordination groups, with a flattening angle α=97.4±0.4°. The c parameters are divided into the octahedral layer thickness, h(oct), and the interlayer spacing h(inter). The latter is related to the (O-H) distances, which decrease as (M-O) increases. Infrared v(O-H) stretching frequencies vary with (M-O) in the same manner as h(inter) varies with (M-O). The values of v(O-H) decrease as h(inter) decreases and the atomic weight of the cations increases. The results are consistent with previous data for cation-substituted talcs. It is suggested that the M2+ ions associated with the O2? ions modify the reduced mass of the O-H vibrations so that v(O-H) decreases with increasing mass of M.  相似文献   

17.
In this paper, the results of our observations on Al-method ionospheric absorption of radio waves on 1.8 and 2.2 MHz during the solar eclipse of 16 February 1980 are presented. The absorption decreased by about 41% and 46% of the normal value respectively at the above two frequencies at Ahmedabad following the maximum phase of the eclipse (about 77% of full disc) with a delay of 18 minutes. The quantityA T (f) which is a measure of εN vdh is now examined for better clarity of the influence of the changes in theE-layer. The results are discussed in relation to the observations of the ionizing radiations from the sun, changes in the electron density, recombination rate and absorption in the underlyingD andE regions.  相似文献   

18.
Chemical etching of dislocations has been studied in natural and synthetic quartz single crystals, in deformed synthetic quartz and in naturally and experimentally deformed quartzites. The ability of different etchants to produce polished or preferentially etched surfaces on quartz is described. Dislocation etching was achieved on all crystal planes examined by using a saturated solution of ammonium bifluoride as the etchant. Appropriate etching times were determined for etching quartzites for grain size, subgrain boundaries, deformation lamellae, dislocations and twins. Growth and polished surfaces of synthetic single crystal quartz were similarly etched and dislocation etch pits, characteristic of various orientations were found. The use of ammonium bifluoride proved to be expecially advantageous for the basal plane, producing a polished surface with etch pits, suitable for dislocation etch pit counting. “Double” etch pits have been found on Dauphiné twin boundaries on the basal plane and the first order prism, using this etchant. Slip lines and deformation bands were suitably etched on deformed synthetic crystal surfaces for identification of the slip planes. Other acidic etchants have been explored and their application to the study of deformation structures in quartz crystals is discussed.  相似文献   

19.
Information on the anisotropy of streambed hydraulic conductivity (K) is a necessity for analyses of water exchange and solute transport in the hyporheic zone. An approach is proposed for the determination of K, developed from existing in-situ permeameter test methods. The approach is based on determination of vertical and horizontal hydraulic conductivity of streambed sediments on-site and eliminates the effects of vertical flow in the hyporheic zone and stream-stage fluctuation, which normally influence in situ permeameter tests. The approach was applied to seven study sites on four tributaries of the Platte River in east-central Nebraska, USA. On-site permeameter tests conducted on about 172 streambed cores for the determination of vertical hydraulic conductivity (K v) and horizontal hydraulic conductivity (K h) at the study sites indicate that the study sites have relatively small anisotropic ratios, ranging from 0.74 to 2.40. The ratios of K h to K v from individual locations within a study site show greater variation than the anisotropic ratios from the mean or median K at each of the study sites.  相似文献   

20.
Dissolution kinetics at the aqueous solution-calcite interface at 50 °C were investigated using in situ atomic force microscopy (AFM) to reveal the influence of magnesium concentration and solution saturation state on calcite dissolution kinetics and surface morphology. Under near-equilibrium conditions, dissolved Mg2+ displayed negligible inhibitory effects on calcite dissolution even at concentrations of . Upon the introduction of , the solution saturation state with respect to calcite, , acted as a “switch” for magnesium inhibition whereby no significant changes in step kinetics were observed at Ωcalcite<0.2, whereas a sudden inhibition from Mg2+ was activated at Ωcalcite?0.2. The presence of the Ω-switch in dissolution kinetics indicates the presence of critical undersaturation in accordance with thermodynamic principles. The etch pits formed in solutions with exhibited a unique distorted rhombic profile, different from those formed in Mg-free solutions and in de-ionized water. Such unique etch pit morphology may be associated with the anisotropy in net detachment rates of counter-propagating kink sites upon the addition of Mg2+.  相似文献   

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