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1.
To better understand the formation conditions of ferromagnesian chondrules from the Renazzo‐like carbonaceous (CR) chondrites, a systematic study of 210 chondrules from 15 CR chondrites was conducted. The texture and composition of silicate and opaque minerals from each observed FeO‐rich (type II) chondrule, and a representative number of FeO‐poor (type I) chondrules, were studied to build a substantial and self‐consistent data set. The average abundances and standard deviations of Cr2O3 in FeO‐rich olivine phenocrysts are consistent with previous work that the CR chondrites are among the least thermally altered samples from the early solar system. Type II chondrules from the CR chondrites formed under highly variable conditions (e.g., precursor composition, redox conditions, cooling rate), with each chondrule recording a distinct igneous history. The opaque minerals within type II chondrules are consistent with formation during chondrule melting and cooling, starting as S‐ and Ni‐rich liquids at 988–1350 °C, then cooling to form monosulfide solid solution (mss) that crystallized around olivine/pyroxene phenocrysts. During cooling, Fe,Ni‐metal crystallized from the S‐ and Ni‐rich liquid, and upon further cooling mss decomposed into pentlandite and pyrrhotite, with pentlandite exsolving from mss at 400–600 °C. The composition, texture, and inferred formation temperature of pentlandite within chondrules studied here is inconsistent with formation via aqueous alteration. However, some opaque minerals (Fe,Ni‐metal versus magnetite and panethite) present in type II chondrules are a proxy for the degree of whole‐rock aqueous alteration. The texture and composition of sulfide‐bearing opaque minerals in Graves Nunataks 06100 and Grosvenor Mountains 03116 suggest that they are the most thermally altered CR chondrites.  相似文献   

2.
The ungrouped carbonaceous chondrite Acfer 094 is among the least altered samples of the early solar system. We have studied concentric sulfide–oxide aggregates from this meteorite by transmission electron microscopy (TEM) and nanoscale secondary ion mass spectrometry (NanoSIMS). The main minerals present are magnetite, pentlandite, and pyrrhotite/troilite. The outer parts of the aggregates include μm-sized olivine and pyroxenes with variable Mg/Fe ratios. One aggregate contains taenite (56.7 wt% Ni) within its central part that is surrounded by pentlandite and magnetite. We conclude that both phases have formed by oxidation and sulfidization of metal and, based on the metal and sulfide Fe/Ni ratio, a (sulfide)-formation temperature of 400–550 °C can be constrained. This temperature is higher than any temperature that could be expected to have occurred on the Acfer 094 parent body, and also textural evidence indicates that the aggregates formed before parent-body accretion. We therefore conclude that the formation of the sulfide–oxide aggregates occurred most likely in the solar nebular at highly variable H2O and H2S fugacities. Oxygen-isotopic compositions of magnetite within these assemblages show that they are indistinguishable from the meteorite's matrix (δ17OSMOW ≈ 4 ± 8‰, δ18OSMOW ≈ 10 ± 6‰, and ∆17OSMOW ≈ −1 ± 5‰). An enrichment of 17,18O relative to chondrules of Acfer 094 suggests a link between the formation of the sulfide–oxide aggregates and the preaccretionary processing of matrix grains in a volatile-enriched nebular environment.  相似文献   

3.
Abstract— The CH carbonaceous chondrites contain a population of ferrous (Fe/(Fe + Mg) ? 0.1‐0.4) silicate spherules (chondrules), about 15–30 μm in apparent diameter, composed of cryptocrystalline olivinepyroxene normative material, ±SiO2‐rich glass, and rounded‐to‐euhedral Fe, Ni metal grains. The silicate portions of the spherules are highly depleted in refractory lithophile elements (CaO, Al2O3, and TiO2 <0.04 wt%) and enriched in FeO, MnO, Cr2O3, and Na2O relative to the dominant, volatile‐poor, magnesian chondrules from CH chondrites. The Fe/(Fe + Mg) ratio in the silicate portions of the spherules is positively correlated with Fe concentration in metal grains, which suggests that this correlation is not due to oxidation, reduction, or both of iron (FeOsil ? Femet) during melting of metal‐silicate solid precursors. Rather, we suggest that this is a condensation signature of the precursors formed under oxidizing conditions. Each metal grain is compositionally uniform, but there are significant intergrain compositional variations: about 8–18 wt% Ni, <0.09 wt% Cr, and a sub‐solar Co/Ni ratio. The precursor materials of these spherules were thus characterized by extreme elemental fractionations, which have not been observed in chondritic materials before. Particularly striking is the fractionation of Ni and Co in the rounded‐to‐euhedral metal grains, which has resulted in a Co/Ni ratio significantly below solar. The liquidus temperatures of the euhedral Fe, Ni metal grains are lower than those of the coexisting ferrous silicates, and we infer that the former crystallized in supercooled silicate melts. The metal grains are compositionally metastable; they are not decomposed into taenite and kamacite, which suggests fast postcrystallization cooling at temperatures below 970 K and lack of subsequent prolonged thermal metamorphism at temperatures above 400–500 K.  相似文献   

4.
Abstract— Ningqiang is an anomalous CV chondrite (oxidized subgroup) containing a high abundance of aggregational inclusions (13.7 vol.%) and low abundances of refractory inclusions (1.0+1.0–0.5 vol.%) and bulk refractory lithophiles (～0.82 × CV). Ningqiang may have agglomerated after most refractory inclusions at the nebular midplane had already been incorporated into other objects. Coarse-grained rims surround only ～5% of Ningqiang chondrules, compared to ～50% in normal CV chondrites. Aggregational inclusions appear to have formed by incipient melting of fine-grained aggregates at relatively low temperatures in the solar nebula, possibly by the mechanism responsible for chondrule formation. Granoblastic porphyritic chondrules, which contain olivines forming 120° triple junctures and no mesostasis, probably formed in the solar nebula by incomplete melting of precursor materials that were olivine normative and had relatively low concentrations of Si, Ca, Al, Fe and Na.  相似文献   

5.
Compositional and structural analyses of CI chondrite iron–nickel sulfide grains reveal heterogeneity both across and within the Orgueil and Alais meteorites. Orgueil grains with the 4C monoclinic pyrrhotite structure have variable metal‐to‐sulfur ratios and nickel contents. These range from the nominal ratio of 0.875 for Fe7S8 with <1 atom% nickel to a high metal‐to‐sulfur ratio of 0.97 with 15 atom% nickel. These data reveal a previously unrecognized low‐temperature solid solution between Fe7S8 and Fe5Ni3S8. We have also identified 6C monoclinic pyrrhotite among the Orgueil iron–nickel sulfides. The occurrence of pentlandite in Orgueil is confirmed for the first time crystallographically. In contrast, sulfide grains in Alais do not show the same spread in composition and structure; rather they represent the endmembers: low‐Ni 4C monoclinic pyrrhotite and pentlandite. We investigate possible formation/alteration scenarios: crystallization from a melt, solid‐state diffusion and/or exsolution, oxidation of pre‐existing sulfides, and precipitation from a fluid. Sulfide grains are sensitive to alteration conditions; these data suggest that the structures and compositions of the sulfide assemblages in Orgueil and Alais were established by late‐stage parent body aqueous alteration, followed in some cases by low‐temperature solid‐state processes. The samples record different alteration histories, with Orgueil experiencing lower equilibration temperatures (25 °C) than Alais (100–135 °C). We conclude that millimeter‐scale heterogeneity existed in alteration conditions (e.g., temperature, pH, oxygen fugacity, sulfur fugacity, duration of alteration) on the parent body. This variability is evidenced by the diversity among sulfide grains located within millimeters of one another.  相似文献   

6.
Abstract— The Carcote meteorite, detected in 1888 in the northern Chilean Andes, is a brecciated, weakly shocked H5 chondrite. It contains a few barred olivine chondrules and, even more rarely, fan-shaped or granular orthopyroxene chondrules. The chondrules are situated in a fine-grained matrix that consists predominantly of olivine and orthopyroxene with accessory clinopyroxene, troilite, chromite, merrillite, and plagioclase. The metal phase is mainly kamacite with subordinate taenite and traces of native Cu. In its bulk rock composition, Carcote compares well with other H5 chondrites so far analysed, except for a distinctly higher C content. Microprobe analyses revealed the following mineral compositions: olivine (Fa16.5–20), orthopyroxene (Fs14–17.5), diopsidic clinopyroxene (FS6–7), plagioclase (An15–20). Troilite is stoichimetric FeS with traces of Ni and Cr; chromite has Cr/(Cr + Al) of 0.86, Fe2+/(Fe2+ + Mg) of 0.80-0.88 and contains considerable amounts of Ti, Mn, and Zn. Merrillite is close to the theoretical formula Ca18(Mg, Fe)2Na2(PO4)14, although with a Na deficiency not compensated for by excess Ca; the Mg/(Mg + Fe2+) ratio of the Carcote merrilite is 0.93-0.95. Kamacite and taenite have Ni contents of 5.6–7.2 and 17.1–23.4 wt%, respectively. Native Cu contains about 3.1–3.3 wt% Fe and 1.6 wt% Ni. Application of different geothermometers to the Carcote H5 chondrite yielded apparently inconsistent results. The highest temperature range of 850–950 °C (at 1 bar) is derived from the Ca-in-opx thermometer. From the cpx-opx solvus geothermometers and the two-pyroxene Fe-Mg exchange geothermometer, a lower temperature range of 750–840 °C is estimated, whereas lower and more variable temperatures of 630–770 °C are obtained from the Ca-in-olivine geothermometer. Recent calibrations of the olivine-spinel geothermometer yielded a still lower temperature range of 570–670 °C, which fits well to the temperature information derived from the Ni distribution between kamacite and taenite. Judging from crystal chemical considerations, we assume that these different temperatures reflect the closure of different exchange equilibria during cooling of the meteorite parent body.  相似文献   

7.
Models of planetary core formation beginning with melting of Fe,Ni metal and troilite are not readily applicable to oxidized and sulfur-rich chondrites containing only trace quantities of metal. Cores formed in these bodies must be dominated by sulfides. Siderophile trace elements used to model metallic core formation could be used to model oxidized, sulfide-dominated core formation and identify related meteorites if their trace element systematics can be quantified. Insufficient information exists regarding the behavior of these core-forming elements among sulfides during metamorphism prior to anatexis. Major, minor, and trace element concentrations of sulfides are reported in this study for petrologic type 3–6 R chondrite materials. Sulfide-dominated core-forming components in such oxidized chondrites (ƒO2 ≥ iron-wüstite) follow metamorphic evolutionary pathways that are distinct from reduced, metal-bearing counterparts. Most siderophile trace elements partition into pentlandite at approximately 10× chondritic abundances, but Pt, W, Mo, Ga, and Ge are depleted by 1–2 orders of magnitude relative to siderophile elements with similar volatilities. The distribution of siderophile elements is further altered during hydrothermal alteration as pyrrhotite oxidizes to form magnetite. Oxidized, sulfide-dominated core formation differs from metallic core formation models both physically and geochemically. Incongruent melting of pentlandite at 865°C generates melts capable of migrating along solid silicate grains, which can segregate to form a Ni,S-rich core at lower temperatures compared to reduced differentiated parent bodies and with distinct siderophile interelement proportions.  相似文献   

8.
The polymict Kaidun microbreccia contains lithologies of C‐type chondrites with euhedral iron sulfide crystals of hydrothermal origin. Our FIB‐TEM study reveals that acicular sulfides in a CM1 lithology are composed of Fe‐rich pyrrhotite with nonintegral vacancy superstructures (NC‐pyrrhotite), troilite, and pentlandite, all showing distinct exsolution textures. Based on phase relations in the Fe‐Ni‐S system, we constrain the temperature of formation of the originally homogeneous monosulfide solid solution to the range of 100–300 °C. In some crystals the exsolution of pentlandite and the microtextural equilibration was incomplete, probably due to rapid cooling. We use thermodynamic modeling to constrain the physicochemical conditions of the extreme hydrothermal alteration in this lithology. Unless the CM1 lithology was sourced from a large depth in the parent body (internal pressure >85 bar) or the temperatures were in the lower range of the interval determined, the water was likely present as vapor. Previously described light δ34S compositions of sulfides in Kaidun's CM1 lithology are likely due to the loss of 34S‐enriched H2S during boiling. Platy sulfide crystals in an adjacent, intensely altered CI1 lithology are composed of Fe‐poor, monoclinic 4C‐pyrrhotite and NC‐pyrrhotite and probably formed at lower temperatures and higher fS2 relative to the CM1 lithology. However, a better understanding of the stability of Fe‐poor pyrrhotites at temperatures below 300 °C is required to better constrain these conditions.  相似文献   

9.
Abstract— This paper reports one of the first attempts to investigate by analytical transmission electron microscopy (ATEM) the microstructures and compositions of Fe‐Ni metal grains in ordinary chondrites. Three ordinary chondrites, Saint Séverin (LL6), Agen (H5), and Tsarev (L6) were selected because they display contrasting microstructures, which reflects different thermal histories. In Saint Séverin, the microstructure of the Ni‐rich metal grains is due to slow cooling. It consists of a two‐phase assemblage with a honeycomb structure resulting from spinodal decomposition similar to the cloudy zone of iron meteorites. Microanalyses show that the Ni‐rich phase is tetrataenite (Ni = 47 wt%) and the Ni‐poor phase, with a composition of ～25% Ni, is either martensite or taenite, these two occurring adjacent to each other. The observation that the Ni‐poor phase is partly fcc resolves the disagreement between previous transmission electron microscopy (TEM) and Mössbauer studies on iron meteorites and ordinary chondrite metal. The Ni content of the honeycomb phase is much higher than in mesosiderites, confirming that mesosiderites cooled much more slowly. The high‐Ni tetrataenite rim in contact with the cloudy zone displays high‐Ni compositional variability on a very fine scale, which suggests that the corresponding area was destabilized and partially decomposed at low temperature. Both Agen and Tsarev display evidence of reheating and subsequent fast cooling obviously related to shock events. Their metallic particles mostly consist of martensite, the microstructure of which depends on local Ni content. Microstructures are controlled by both the temperature at which martensite forms and that at which it possibly decomposes. In high‐Ni zones (>15 wt%), martensitic transformation started at low temperature (<300 °C). Because no further recovery occurred, these zones contain a high density of lattice defects. In low‐Ni zones (<15 wt%), martensite grains formed at higher temperature and their lattice defects recovered. These martensite grains present a lath texture with numerous tiny precipitates of Ni‐rich taenite (Ni = 50 wt%) at lath boundaries. Nickel composition profiles across precipitate‐matrix interfaces show that the growth of these precipitates was controlled by preferential diffusion of Ni along lattice defects. The cooling rates deduced from Ni concentration profiles and precipitate sizes are within the range 1–10 °C/year for Tsarev and 10–100 °C/year for Agen.  相似文献   

10.
Abstract– Queen Alexandra Range (QUE) 94204, an enstatite achondrite, is a coarse‐grained, highly recrystallized, chondrule‐free and unbrecciated rock dominated (about 70 vol%) by anhedral, equigranular crystals of orthoenstatite of nearly endmember composition (Fs0.1–0.4, Wo0.3–0.4) with interstitial plagioclase, kamacite, and troilite. Abundance of approximately 120° triple junctions and the close association of metal–sulfide and plagioclase‐rich melts indicate that QUE 94204 has undergone limited partial melting with inefficient melt extraction. Mineral chemistry indicates a high degree of thermal metamorphism. Kamacite in QUE 94204 contains between 2.09 and 2.55 wt% Si, similar to highly metamorphosed EL chondrites. Plagioclase has between 4.31 and 6.66 wt% CaO, higher than other E chondrites but closer in composition to plagioclase from metamorphosed EL chondrites. QUE 94204 troilite contains up to 2.55 wt% Ti, consistent with extensive thermal metamorphism of an E chondrite‐like precursor. Results presented in this study indicate that QUE 94204 is the result of low degree, (about 5–20 vol%, probably toward the lower end of this range) partial melting of an E chondrite protolith. Textural and chemical evidence suggests that during the metamorphism of QUE 94204, melts formed first at the Fe,Ni‐FeS cotectic near approximately 900 °C, followed by plagioclase‐pyroxene silicate partial melts near approximately 1100 °C. Neither the Fe,Ni‐FeS nor the plagioclase‐pyroxene melts were efficiently segregated or extracted. QUE 94204 belongs to a grouplet of similar “primitive enstatite achondrites” that are analogous to the acapulcoites‐lodranites, but that have resulted from the partial melting of an E chondrite‐like protolith.  相似文献   

11.
NWA 2737, a Martian meteorite from the Chassignite subclass, contains minute amounts (0.010 ± 0.005 vol%) of metal‐saturated Fe‐Ni sulfides. These latter bear evidence of the strong shock effects documented by abundant Fe nanoparticles and planar defects in Northwest Africa (NWA) 2737 olivine. A Ni‐poor troilite (Fe/S = 1.0 ± 0.01), sometimes Cr‐bearing (up to 1 wt%), coexists with micrometer‐sized taenite/tetrataenite‐type native Ni‐Fe alloys (Ni/Fe = 1) and Fe‐Os‐Ir‐(Ru) alloys a few hundreds of nanometers across. The troilite has exsolved flame‐like pentlandite (Fe/Fe + Ni = 0.5–0.6). Chalcopyrite is almost lacking, and no pyrite has been found. As a hot desert find, NWA 2737 shows astonishingly fresh sulfides. The composition of troilite coexisting with Ni‐Fe alloys is completely at odds with Chassigny and Nahkla sulfides (pyrite + metal‐deficient monoclinic‐type pyrrhotite). It indicates strongly reducing crystallization conditions (close to IW), several log units below the fO2 conditions inferred from chromites compositions and accepted for Chassignites (FMQ‐1 log unit). It is proposed that reduction in sulfides into base and precious metal alloys is operated via sulfur degassing, which is supported by the highly resorbed and denticulated shape of sulfide blebs and their spongy textures. Shock‐related S degassing may be responsible for considerable damages in magmatic sulfide structures and sulfide assemblages, with concomitant loss of magnetic properties as documented in some other Martian meteorites.  相似文献   

12.
Abstract— Dendrites in the metal-troilite spherules in both shock-induced melt veins and a melt pocket of the Yanzhuang chondrite show zoning in their microstructures. This feature is indicative of nonequilibrium solidification of the metal phases. Dendrites in the melt pocket have a typical crust-core structure consisting of martensitic interiors (7.5–8.1 wt% Ni) and Ni-rich rims (12.5–23.3 wt% Ni). In comparison, the dendrites in melt veins have three microstructural areas: (1) core (6.4–7.3 wt% Ni); (2) martensite between the core and rim (7.4–8.5 wt.% Ni); (3) Ni-rich rim (12.8–21.4 wt% Ni). It is suggested that the difference in cooling rates following shock-induced high temperature melting might be an important factor in producing the different dendritic microstructures in melt veins and melt pocket. Cooling rates deduced from measurements of secondary dendritic arm spacings are 100–400 °C/s in the melt veins and 6–30 °C/s in the melt pocket, respectively, and lie in the temperature interval 950 to 1400 °C.  相似文献   

13.
We have studied the petrologic characteristics of sulfide‐metal lodes, polymineralic Fe‐Ni nodules, and opaque assemblages in the CR2 chondrite Graves Nunataks (GRA) 06100, one of the most altered CR chondrites. Unlike low petrologic type CR chondrites, alteration of metal appears to have played a central role in the formation of secondary minerals in GRA 06100. Differences in the mineralogy and chemical compositions of materials in GRA 06100 suggest that it experienced higher temperatures than other CR2 chondrites. Mineralogic features indicative of high temperature include: (1) exsolution of Ni‐poor and Ni‐rich metal from nebular kamacite; (2) formation of sulfides, oxides, and phosphates; (3) changes in the Co/Ni ratios; and (4) carbidization of Fe‐Ni metal. The conspicuous absence of pentlandite may indicate that peak temperatures exceeded 600 °C. Opaques appear to have been affected by the action of aqueous fluids that resulted in the formation of abundant oxides, Fe‐rich carbonates, including endmember ankerite, and the sulfide‐silicate‐phosphate scorzalite. We suggest that these materials formed via impact‐driven metamorphism. Mineralogic features indicative of impact metamorphism include (1) the presence of sulfide‐metal lodes; (2) the abundance of polymineralic opaque assemblages with mosaic‐like textures; and (3) the presence of suessite. Initial shock metamorphism probably resulted in replacement of nebular Fe‐Ni metal in chondrules and in matrix by Ni‐rich, Co‐rich Fe metal, Al‐Ti‐Cr‐rich alloys, and Fe sulfides, while subsequent hydrothermal alteration produced accessory oxides, phosphates, and Fe carbonates. An extensive network of sulfide‐metal veins permitted effective exchange of siderophile elements from pre‐existing metal nodules with adjacent chondrules and matrix, resulting in unusually high Fe contents in these objects.  相似文献   

14.
Abstract— The Frontier Mountain (FRO) 93001 meteorite is a 4.86 g fragment of an unshocked, medium‐ to coarse‐grained rock from the acapulcoite‐lodranite (AL) parent body. It consists of anhedral orthoenstatite (Fs13.3 ± 0.4Wo3.1 ± 0.2), augite (Fs6.1 ± 0.7Wo42.3 ± 0.9; Cr2O3 = 1.54 ± 0.03), and oligoclase (Ab80.5 ± 3.3Or3.1 ± 0.6) up to >1 cm in size enclosing polycrystalline aggregates of fine‐grained olivine (average grain size: 460 ± 210 μm) showing granoblastic textures, often associated with Fe,Ni metal, troilite, chromite (cr# = 0.91 ± 0.03; fe# = 0.62 ± 0.04), schreibersite, and phosphates. Such aggregates appear to have been corroded by a melt. They are interpreted as lodranitic xenoliths. After the igneous (the term “igneous” is used here strictly to describe rocks or minerals that solidified from molten material) lithology intruding an acapulcoite host in Lewis Cliff (LEW) 86220, FRO 93001 is the second‐known silicate‐rich melt from the AL parent asteroid. Despite some similarities, the silicate igneous component of FRO 93001 (i.e., the pyroxene‐plagioclase mineral assemblage) differs in being coarser‐grained and containing abundant enstatite. Melting‐crystallization modeling suggests that FRO 93001 formed through high‐degree partial melting (≥35 wt%; namely, ≥15 wt% silicate melting and ?20 wt% metal melting) of an acapulcoitic source rock, or its chondritic precursor, at temperatures ≥1200 °C, under reducing conditions. The resulting magnesium‐rich silicate melt then underwent equilibrium crystallization; prior to complete crystallization at ?1040 °C, it incorporated lodranitic xenoliths. FRO 93001 is the highest‐temperature melt from the AL parent‐body so far available in laboratory. The fact that FRO 93001 could form by partial melting and crystallization under equilibrium conditions, coupled with the lack of quench‐textures and evidence for shock deformation in the xenoliths, suggests that FRO 93001 is a magmatic rock produced by endogenic heating rather than impact melting.  相似文献   

15.
Gibeon IVA iron meteorite fragment was characterized using optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), magnetization measurements, and Mössbauer spectroscopy. Optical microscopy and SEM made on the polished section of the meteorite, show the presence of α-Fe(Ni, Co) and γ-Fe(Ni, Co) phases and plessite structures. There are no troilite inclusions observed in the studied section. EDS studies indicate some variations in the Ni concentrations: (i) within the α-Fe(Ni, Co) phase in the range ~5.0 ± 0.1 – ~7.5 ± 0.1 at% and (ii) within the γ-Fe(Ni, Co) phase in the range ~26.0 ± 0.2 – ~36.1 ± 0.2 at%. The latter Ni concentration range indicates the presence of small amount of the paramagnetic γ-phase in addition to the ferromagnetic γ-phase. EDS also shows that Ni content in two plessite structures is varying in the range ~16–37 at%, which can indicate the presence of only the α2-Fe(Ni, Co) and γ-Fe(Ni, Co) phases in the duplex plessite structure. This may be a result of the γ-phase decomposition with the incomplete martensitic transformation: γ → α2 + γ due to a faster cooling rate. XRD indicates the presence of ~1.3 wt% of the γ-Fe(Ni, Co) phase in Gibeon VIA. The saturation magnetization moment of 185(2) emu g−1 obtained also confirms the presence of phases with low and high Ni concentrations. The most appropriate fit of the Gibeon IVA Mössbauer spectrum demonstrates the presence of five magnetic sextets and one paramagnetic singlet which are assigned to the ferromagnetic α2-Fe(Ni, Co), α-Fe(Ni, Co), γ-Fe(Ni, Co), and paramagnetic γ-Fe(Ni, Co) phases. The relative average Fe contents in these phases are: 13.4% in the α2-Fe(Ni, Co) phase, 78.3% in the α-Fe(Ni, Co) phase, and 8.3% in the ferromagnetic and paramagnetic γ-Fe(Ni, Co) phases.  相似文献   

16.
Twelve stones, ranging up to 504 g (total weight 2.92 kg), of a very fresh eucrite have been collected from a 1 km2 area on the Nullarbor Plain in Western Australia. The location is approximately 75 km N6°E from Nurina Siding on the Trans-Australian Railway; coordinates 30°19′S, 126°37′E. This eucrite consists almost entirely of pyroxene (mean composition Wo 16 Fs 49) and plagioclase (mean composition An 85) in approximate proportions 3: 2, with 2% almost pure Fe metal and accessory amounts of troilite, ilmenite, and an SiO2 phase. Gabbroic and doleritic clasts are present in a groundmass of comminuted pyroxene and plagioclase. The chemical composition (weight per cent) is: SiO2 49.53, TiO2 0.74, Al2O3 12.49, Cr2O3 0.33, FeO 16.07, MnO 0.56, MgO 6.31, CaO 10.41, Na2O 0.49, K2O 0.04, P2O5 < 0.01, H2O + < 0.1, H2O — 0.07, Fe metal 2.07, Ni < 0.01, Co < 0.01, FeS 0.19, C 0.03, sum 99.33.  相似文献   

17.
Using Shell-Model Monte Carlo (SMMC) method and Random Phase Approximation (RPA) theory, the electron capture (EC) and the electron capture cross section (ECCS) of nuclei 55Co and 56Ni are investigated. We also discuss the rates of the change of electron fraction (RCEF) and the error factor C, which is compared our results with those of AFUD, which calculated by the method of Aufderheide. The results show that the ECCS and the EC rates for 55Co and 56Ni increased about four orders of magnitude at relative high temperature (such as T 9=5,7,9). On the other hand, the RCEF for two nuclides decreased greatly, and even exceed four orders of magnitude. The error factor shows ours is agreed reasonably well with AUFD under the higher density surroundings (e.g. ρ7=106, Y e =0.43; ρ7=506, Y e =0.42; ρ7=4010, Y e =0.41). But under the lower density surroundings (e.g. ρ7=3.36, Y e =0.48) the maximum error is ～14.5 % for 55Co but is ～14.0 % for 56Ni. The error is ～9.5 % and ～9.0 % for 55Co, 56Ni at ρ7=5.86, Y e =0.47 respectively.  相似文献   

18.
Abstract— Watson, which was found in 1972 in South Australia, contains the largest single silicate rock mass seen in any known iron meteorite. A comprehensive study has been completed on this unusual meteorite: petrography, metallography, analyses of the silicate inclusion (whole rock chemical analysis, INAA, RNAA, noble gases, and oxygen isotope analysis) and mineral compositions (by electron microprobe and ion microprobe). The whole rock has a composition of an H-chondrite minus the normal H-group metal and troilite content. The oxygen isotope composition is that of the silicates in the HE iron meteorites and lies along an oxygen isotope fractionation line with the H-group chondrites. Trace elements in the metal confirm Watson is a new HE iron. Whole rock Watson silicate shows an enrichment in K and P (each ～2X H-chondrites). The silicate inclusion has a highly equilibrated igneous (peridotite-like) texture with olivine largely poikilitic within low-Ca pyroxene: olivine (Fa20), opx (Fs17Wo3), capx (Fs9Wo41) (with very fine exsolution lamellae), antiperthite feldspar (An1–Or5) with <1 μm exsolution lamellae (An1–3Or>40), shocked feldspar with altered stoichiometry, minor whitlockite (also a poorly characterized interstitial phosphate-rich phase) and chromite, and only traces of metal and troilite. The individual silicate minerals have normal chondritic REE patterns, but whitlockite has a remarkable REE pattern. It is very enriched in light REE (La is 720X C1, and Lu is 90X C1, as opposed to usual chonditic values of ～300X and 100–150X, respectively) with a negative Eu anomaly. The enrichment of whole rock K is expressed both in an unusually high mean modal Or content of the feldspar, Or13, and in the presence of antiperthite. Whole rock trace element data for the silicate mass support the petrography. Watson silicate was an H-chondrite engulfed by metal and melted at > 1550 °C. A flat refractory lithophile and flat REE pattern (at ～1x average H-chondrites) indicate that melting took place in a relatively closed system. Immiscible metal and sulfide were occluded into the surrounding metal host. Below 1100 °C, the average cooling rate is estimated to have been ～1000 °C/Ma; Widmanstätten structure formed, any igneous zoning in the silicates was equilibrated, and feldspar and pyroxene exsolution took place. Cooling to below 300 °C was completed by 3.5 Ga B. P. At 8 Ma, a shock event took place causing some severe metal deformation and forming local melt pockets of schreibersite/metal. This event likely caused the release of Watson into interplanetary space. The time of this event, 8Ma, corresponds to the peak frequency of exposure ages of the H-chondrites. This further confirms the link between HE irons and the H-chondrites, a relationship already indicated by their common oxygen isotope source. Watson metal structures are very similar to those in Kodaikanal. Watson, Kodaikanal and Netschaëvo form the young group of HE meteorites (ages 3.7 ± 0.2 Ga). They appear to represent steps in a chain of events that must have taken place repeatedly on the HE parent body or bodies from which they came: chondrite engulfed in metal (Netschaëvo); chondrite melted within metal (Watson); and finally melted silicate undergoing strong fractionation with the fractionated material emplaced as globules within metal (Kodaikanal). Watson fills an important gap in understanding the sequence of events that took place in the evolution of the IIE-H parent body(ies). This association of H-chondrite with HE metal suggests a surface, or near surface process-a suggestion made by several other researchers.  相似文献   

19.
Abstract— To test whether aubrites can be formed by melting of enstatite chondrites and to understand igneous processes at very low O fugacities, we have conducted partial melting experiments on the Indarch (EH4) chondrite at 1000–1500 °C. Silicate melting begins at 1000 °C, and Indarch is completely melted by 1500 °C. The metal-sulfide component melts completely at 1000 °C. Substantial melt migration occurs at 1300–1400 °C, and metal migrates out of the silicate charge at 1450 °C and ～50% silicate partial melting. As a group, our experiments contain three immiscible metallic melts (Si-, P-, and C-rich), two immiscible sulfide melts (Fe- and FeMgMnCa-rich), and silicate melt. Our partial melting experiments on the Indarch (EH4) enstatite chondrite suggest that igneous processes at low fO2 exhibit several unique features. The complete melting of sulfides at 1000 °C suggests that aubritic sulfides are not relics. Aubritic oldhamite may have crystallized from Ca and S complexed in the silicate melt. Significant metal-sulfide melt migration might occur at relatively low degrees of silicate partial melting. Substantial elemental exchange occurred between different melts (e.g., S between sulfide and silicate, Si between silicate and metal), a feature not observed during experiments at higher fO2. This exchange may help explain the formation of aubrites from known enstatite chondrites.  相似文献   

20.
Abstract— Activities of chromite in multicomponent spinels with compositions similar to those of H chondrites were experimentally determined by equilibrating Pt‐alloys with spinel at known temperature and fO2. Our results are consistent with predictions based on the spinel solid solution model incorporated into the MELTS program. Therefore, we combined literature formulations for the activities of components in spinel, the ferromagnesian silicates, and alloys with measured and literature (bulk alloy) compositions of the meteoritic phases to constrain T‐fO2 conditions for the H‐group chondrites Avanhandava (H4), Allegan (H5), and Guareña (H6). Log10fO2 values based on the assemblage of olivine + orthopyroxene + metal are 2.19–2.56 log units below the iron‐wüstite (IW) buffer for any equilibration temperature between 740 and 990 °C, regardless of petrographic type. Only lower limits on fO2 could be determined from spinel + metal equilibria because of the extremely low concentrations of Cr in the alloys of equilibrated H chondrites (≤3 ppb). Log10fO2 values required by spinel + metal equilibria are inconsistent with those for olivine + orthopyroxene + metal if equilibration temperatures were at or above those inferred from olivine‐spinel thermometry. This probably indicates that the closure for spinel + metal equilibria occurred under retrograde conditions at temperatures below ～625 °C for Allegan and Guareña and below ～660 °C for Avanhandava.  相似文献   

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