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1.
In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052 kg/m3, 1.303 kWh/m3 and 0.256 US$/m3, respectively. Dye removal kinetic followed first order kinetics. It can be concluded that electrocoagulation process by aluminum electrode is very efficient and clean process for reactive dye removal from colored wastewater.  相似文献   

2.
In this study, domestic wastewater was used as the electrolyte. The work was carried out with an up-flow tubular reactor, made of stainless steel that was used as cathode, while the anode electrode material was aluminum and varying values of flow regime (25, 50, 75 and 100 mL/s for continuous system), initial pH value (5, 6, 7 and 7.8) and current intensity (10, 15 and 20 A) were applied. For domestic wastewater with natural pH, the effluent pH was >9 in the batch system, while in the continuous system the pH was 8–8.5. Likewise, while the effluent temperature was up to 60°C in the batch system, it was at most 35°C in the continuous system. However, the energy consumption values in the continuous system were considerably lower compared with the batch system. At a current intensity of 10 A, 80 kWh of energy per unit volume was consumed in the batch system, while it was 50 kWh for the continuous system. The present results show that the batch system can be used for small wastewater streams whereas the continuous system can be used for large wastewater streams for domestic wastewater treatment.  相似文献   

3.
Moringa oleifera (MO) seed extract coupled with electrocoagulation (EC) was used to remove fluoride from water. Different MO extract volumes (5.0, 12.5, and 25.0 mL of MO extract per water liter) were coupled with EC, using aluminum electrodes at different current density values (J = 0.7, 2.0, and 3.3 mA/cm2) and different electrode separations (1.0, 2.0, and 4.0 cm), tested in batch and recirculation experiments. Control experiments using MO extract and EC alone achieved 5% and 54% water defluoridation, respectively. Best experimental batch conditions were achieved using 12.5 mL of MO extract followed by EC (3.3 mA/cm2) with a 1.0 cm electrode separation, producing >90% fluoride removal. Recirculation experiments with the EC reactor were performed with DI water and tap water using 1.0 cm electrode separation, 12.5 mL of MO extract and different current densities. More than 90% fluoride removal was achieved with the EC/MO process, using 3.3 mA/cm2, in both DI and tap water after 30 and 60 min, respectively. An energy consumption index (ECI) was developed, which showed that 1.51 and 0.67 W/h/mg were achieved for batch experiments of EC alone and EC/MO extract, respectively. For EC/MO extract, recirculation experiments with tap and DI water resulted in 0.35 and 0.22 W/h/mg, respectively. A cost analysis showed that $0.18 will be needed to treat one cubic meter of water.  相似文献   

4.
This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO4 or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO4. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO4 and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.  相似文献   

5.
Purification of Wastewaters Containing Azo Dyes This study describes the degradability of the azo dye C.I. Reactive Violet 5 by a continuous flow biological treatment system consisting of three rotating disc reactors. The azo dye was first decolorized in an anaerobic reactor. Decolorization was improved by adding an auxiliary substrate (yeast extract and acetic acid). Although severe operating conditions were experienced due to failures in the temperature and pH-controllers, the reactor recovered quickly and continued to decolorize reliably. The removal of the auxiliary substrate in the anaerobic reactor was not satisfactory, probably due to the copper in the azo dye. Batch experiments showed that copper was removed from the dye molecule and precipitated during the decolorization. In the continuous flow reactor, the copper precipitate on the disc can redissolve due to a pH-gradient in the fixed biomass becoming toxic again for the bacteria. In the following two aerobic reactors, the auxiliary substrate was degraded, but mineralization of the dye metabolites was insufficient. The aromatic amines produced by the anaerobic decolorization are more toxic in the bacterial luminescence test than the azo dye. Therefore, decolorization alone cannot be used to treat colored wastewater. Since the amines can also be produced in anaerobic parts of rivers, the dyes have to be removed in a more efficient way. That is the reason why in further experiments ozonation is being tested to increase the biological degradability of the azo dye for a following aerobic stage. Either ozonation can be used after the two stage treatment of the dye in anaerobic/aerobic reactors or the dye can be oxidized directly, making the addition of auxiliary substrate unnecessary. These configurations are being tested with the goal to degrade the dye with the least ozone consumption.  相似文献   

6.
Desalination experiments by means of electrodialysis were carried out with a pilot plant of Soviet origin. Brackish water of the Bulgarian Black Sea coast with different fresh-water concentrations and 135… 700 mg/1 salt was used as the salt water. The applied electrode voltages were 100… 400 V. In dependence on other conditions such as flow rate, temperature etc., there were determined the energy demand (referred to the removal of 1 kg salt) and the desalination effect. A mathematical model for calculating the energy consumption is derived from the experimental findings.  相似文献   

7.
The removal of Alphazurine FG (AF) dye from water by an electrocoagulation process has been studied. The effect of some operational parameters, such as anode material, current density, initial dye concentration, pH of solution, conductivity, and inter‐electrode distance, on the removal efficiency was investigated. Iron and aluminum were used as anodes in the electrocoagulation cell. It was found that the efficiency of the iron anode was better than that of the aluminum anode for AF removal. The factors that affected the removal efficiency were the current density and the initial dye concentration. The removal efficiency increased from about 35% at 25 A m–2 to about 97% at 100 A m–2, during 4 min of electrocoagulation. The results exhibited pseudo‐first‐order kinetics for AF removal by electrocoagulation. In addition, a mathematical model was successfully established for predicting the removal efficiency. A comparison between the model results and experimental data gave a high correlation coefficient (R2 = 0.9925), which indicates that the model is able to predict the removal efficiency of AF.  相似文献   

8.
沈林亚  吴娟  钟非  向东方  成水平 《湖泊科学》2017,29(5):1084-1090
本文研究了分级进水对阶梯垂直流人工湿地处理生活污水效果的影响.在保持总水力负荷为100 mm/d的情况下,分别将总进水量的0%、10%、20%和30%用于湿地第2级阶梯的进水,分析了系统对化学需氧量(COD)和氮、磷的总去除率和沿程变化.结果表明,不同分级进水比例条件下人工湿地对COD和总磷(TP)的去除率差异不明显,COD和TP的最高去除率分别为87.80%和81.17%,COD的去除主要集中在第1级,其贡献率平均为82.18%,TP的去除主要集中在第3级,贡献率平均为54.37%.分级进水对总氮(TN)去除率影响显著(P0.05),当2级进水比例为20%时,TN去除率最高,为61.70%±4.48%,且3个梯级对TN的去除贡献率分别为36.52%、42.11%和21.37%.相同组合形式的垂直流人工湿地处理生活污水的工程应用中,可根据需求设置20%左右的2级进水比例,以提高人工湿地对污染物的去除效果.  相似文献   

9.
Adsorption of reactive black 5 (RB5) from aqueous solution onto chitosan was investigated in a batch system. The effects of solution pH, initial dye concentration, and temperature were studied. Adsorption data obtained from different batch experiments were modeled using both pseudo first‐ and second‐order kinetic equations. The equilibrium adsorption data were fitted to the Freundlich, Tempkin, and Langmuir isotherms over a dye concentration range of 45–100 µmol/L. The best results were achieved with the pseudo second‐order kinetic and Langmuir isotherm equilibrium models, respectively. The equilibrium adsorption capacity (qe) was increased with increasing the initial dye concentration and solution temperature, and decreasing solution pH. The chitosan flakes for the adsorption of the dye was regenerated efficiently through the alkaline solution and was then reused for dye removal. The activation energy (Ea) of sorption kinetics was estimated to be 13.88 kJ/mol. Thermodynamic parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were evaluated by applying the van't Hoff equation. The thermodynamics of reactive dye adsorption by chitosan indicates its spontaneous and endothermic nature.  相似文献   

10.
We characterize the hydraulics of an extraction-injection well pair in arbitrarily oriented regional flow by the recirculation ratio, area, and average residence time in the recirculation zone. Erratic regional flow conditions may compromise the performance of the reactor between a single well pair. We propose an alternative four-well system: two downgradient extraction and two upgradient injection wells creating an inner cell nested within an outer cell. The outer cell protects the inner cell from the influence of regional flow. Compared to a two-well system, the proposed four-well system has several advantages: (1) the recirculation ratio within the nested inner cell is less sensitive to the regional flow direction; (2) a transitional recirculation zone between the inner and outer cells can capture flow leakage from the inner cell, minimizing the release of untreated contaminants; and (3) the size of the recirculation zone and residence times can be better controlled within the inner cell by changing the pumping rates. The system is applied at the Field Research Center in Oak Ridge, Tennessee, where experiments on microbial in situ reduction of uranium (VI) are under way.  相似文献   

11.
The electrogenerative removal of cobalt is conducted in a batch reactor equipped with three‐dimensional electrodes: Reticulated vitreous carbon (RVC) and porous graphite (PG‐25) as cathode materials. In this process, a chemical reaction takes place spontaneously in a divided cell where cobalt is reduced at the cathode and zinc is oxidized to produce electrical energy without an external supply of energy. The results obtained show that RVC serves as a more suitable cathode material than PG‐25 in this system. At optimum conditions, more than 99% of cobalt were removed and recovered in its metallic state after 10 h of operation with an initial 200 mg L?1 Co(II) solution at pH 4 in 0.2 M Na2SO4 and 0.4 M boric acid. Scanning electron microscopy and X‐ray diffraction analyses are performed to study the morphology and crystallographic patterns of cobalt deposits on the cathodes, respectively.  相似文献   

12.
The mixtures of dried sewage sludge (DSS) and sewage sludge ash were studied for removal of acid red 119 (AR119) dye as a new, more environmental friendly, and low cost adsorbent. For this purpose, response surface methodology was applied to optimize the dye removal efficiency and turbidity of treated dye solutions as two individual responses. Results revealed that an optimum condition under specified constraints (dye removal efficiency >95% and turbidity <50 NTU) was obtained at a contact time of 60 min, 40 wt% DSS in the mixture, an initial pH of 6, and an initial dye concentration of 200 mg dye/L in distilled water. Under the optimal condition, dye removal efficiency of 94.98% and effluent turbidity of 24.9 NTU was observed. In further studies, at optimum condition, the effect of some additives on adsorption process and desorption/reusability of adsorbent was investigated. It was observed that removal efficiency was significantly decreased to 83.76% when a simulated dye wastewater (containing the selected dye, acetic acid, and Glauber's salt dissolved in tap water) was used. Desorption studies revealed that AR119 dye could be well removed from dye‐loaded adsorbent by 0.3 M NaOH solution.  相似文献   

13.
In this study, various amounts of oxygen were added to the anaerobic phase of an anaerobic‐aerobic sequencing batch reactor (SBR) receiving azo dye remazol brilliant violet 5R to mimic the input of oxygen into the anaerobic zones of biological textile wastewater treatment plants. The effect of oxygen on the anaerobic biodegradative capability of the mixed microbial culture for remazol brilliant violet 5R was investigated. To investigate the effect of oxygen on anaerobic azo dye biodegradation, the anaerobic phase of the SBR cultures were exposed to a very low limited amount of oxygen for various air flow rates. Initially, an air flow rate of 20 mL/min was applied, further on the air flow rate in the anaerobic phase was increased up to 40 mL/min. System performance was determined by monitoring chemical oxygen demand, color removal rate, activities of anaerobic (azo reductase) and aerobic enzymes (catechol 2,3‐dioxygenase, catechol 1,2‐dioxygenase). The results of percentage COD reduction at each stage were similar for all runs, giving an overall reduction of 96%. Anaerobic color removal efficiency and azo reductase activity of anaerobic microorganisms were adversely affected by the addition of oxygen. Color removal efficiencies of the anaerobic phases decreased from 80% down to 42 and 38% for the limited oxygen conditions of 20 mL/min and 40 mL/min, respectively. It was observed that the activity of catechol 2,3‐dioxygenase and catechol 1,2‐dioxygenase, involved in breakage of aromatic rings, increased after they are exposed to oxygen limited conditions compared to fully anaerobic conditions. It was also observed that catechol 1,2‐dioxygenase enzyme activity increased by increasing the oxygen level on oxygen limited conditions in the anaerobic zone.  相似文献   

14.
Adsorption is of significant importance for effluent treatment, especially for the treatment of colored effluent generated from the dyeing and bleaching industries. Low cost adsorbents have gained attention over the decades as a means of achieving very high removal efficiencies to meet effluent discharge standards. The present article reports on batch investigations for color removal from aqueous solutions of Methylene Blue (MB) and Congo Red (CR) using Rice Husk Ash (RHA) as an alternative low cost adsorbent. The performance analysis was carried out as a function of various operating parameters, such as initial concentration of dye, adsorbent dose, contact time, shaker speed, interruption of shaking and ionic concentration. Performance studies revealed that a very high percentage removal of color was achievable for both dyes. The maximum percentage removal of MB was 99.939%, while 98.835% removal was observed for CR. These percentage removals were better than existing systems. Detailed data analysis indicated that adsorption of MB followed the Temkin isotherm, while CR followed the Freundlich isotherm. These isotherms were feasible within the framework of experimentation. Batch kinetic data, on the other hand, indicated that pseudo second order kinetics governed adsorption in both cases. Sensitivity analysis further indicated that the effects of initial dye concentration, shaker speed, pH and ionic strength had no noticeable effect on the percentage dye removal at equilibrium. Batch desorption studies revealed that 50% acetone solution was optimum for CR, while desorption of MB varied directly with acetone concentration.  相似文献   

15.
微曝气生态浮床净化入湖河口污染河水原位模型实验   总被引：5，自引：1，他引：4  
针对污染河水黑臭缺氧、NH_4~+-N含量高等问题,研发了一种"漂浮载体悬挂弹性生物膜填料+水生植物并辅以人工微曝气系统"的微曝气生态浮床系统.通过原位模型实验,研究了其在大清河入湖河口对污染河水的净化效果,当水力负荷为1500mm/d时,对TN和NH_4~+-N的平均去除率分别为81.1%、91.3%,对TP的平均去除率为72.7%,对PO_4~(3-)-p的平均去除率为92.5%,对有机物亦有较强的去除能力;处理1m~3水需要的曝气费用约为0.007元.微曝气生态浮床系统整体运行稳定、去除效率高、能耗低,适合流水环境,可直接在污染河道和人湖河口区对污染河水进行自流净化.  相似文献   

16.
Sulfate‐reduction data from various anaerobic reactor configurations, e. g., upflow anaerobic sludge blanket reactor (UASBR), completely stirred tank reactor (CSTR), and batch reactor (BR) with synthetic wastewaters, having glucose and acetate as the substrates and different levels of sulfate, were evaluated to determine the level of sulfate‐reducing activity by sulfate‐reducing bacteria coupled to organic matter removal. Anaerobic reactors were observed for the degree of competition between sulfate‐reducing sulfidogens and methane producing bacteria during the degradation of glucose and acetate. Low sulfate‐reducing activity was obtained with a maximum of 20% of organic matter degradation with glucose‐fed upflow anaerobic sludge bed reactors (UASBRs), while a minimum of 2% was observed with acetate‐fed batch reactors. The highest sulfate removal performance (72–89%) was obtained from glucose fed‐UASB reactors, with the best results observed with increasing COD/SO4 ratios. UASB reactors produced the highest level of sulfidogenic activity, with the highest sulfate removal and without a performance loss. Hence, this was shown to be the optimum reactor configuration. Dissolved sulfide produced as a result of sulfate reduction reached 325 mg/L and 390 mg/L in CST and UASB reactors, respectively, and these levels were tolerated. The sulfate removal rate was higher at lower COD/SO4 ratios, but the degree of sulfate removal improved with increasing COD/SO4 ratios.  相似文献   

17.
A backward location probability density function (BL-PDF) method capable of identifying location of point sources in surface waters is presented in this paper. The relation of forward location probability density function (FL-PDF) and backward location probability density, based on adjoint analysis, is validated using depth-averaged free-surface flow and mass transport models and several surface water test cases. The solutions of the backward location PDF transport equation agreed well to the forward location PDF computed using the pollutant concentration at the monitoring points. Using this relation and the distribution of the concentration detected at the monitoring points, an effective point source identification method is established. The numerical error of the backward location PDF simulation is found to be sensitive to the irregularity of the computational meshes, diffusivity, and velocity gradients. The performance of identification method is evaluated regarding the random error and number of observed values. In addition to hypothetical cases, a real case was studied to identify the source location where a dye tracer was instantaneously injected into a stream. The study indicated the proposed source identification method is effective, robust, and quite efficient in surface waters; the number of advection–diffusion equations needed to solve is equal to the number of observations.  相似文献   

18.
Perspectives, advances and environmental aspects concerning electrochemical ozone production applied to water purification are presented and discussed in relation to the conventional corona process (silent electric discharge). Ozone generated using a laboratory‐made electrochemical reactor was applied for the discoloration/degradation of dyes used in the Brazilian textile industry and for degradation of endocrine disruptors. A constant ozone load of 0.35 ± 0.02 g/h was used throughout. The study, concerning color removal from dye solutions, revealed that total discoloration is rapidly achieved. The degradation rate of the textile dyes evaluated by TOC is little affected by the dye composition and considerably influenced by the pH and ozonation time. Analysis of the COD/TOC‐ratio indicates that ozonation increases oxidation feasibility of the organic matter (dye by‐products) when compared to the original compounds. Ozonation of mixed aqueous solutions containing different endocrine disruptors revealed these compounds are totally degraded with a very high removal rate.  相似文献   

19.
This study reports the performance of a combined anaerobic–aerobic packed‐bed reactor that can be used to treat domestic sewage. Initially, a bench‐scale reactor was operated in three experimental phases. In the first phase, the anaerobic reactor was operated with an average organic matter removal efficiency of 77% for a hydraulic retention time (HRT) of 10 h. In the second phase, the reactor was operated with an anaerobic stage followed by an aerobic zone, resulting in a mean value of 91% efficiency. In the third and final phase, the anaerobic–aerobic reactor was operated with recirculation of the effluent of the reactor through the anaerobic zone. The system yielded mean total nitrogen removal percentages of 65 and 75% for recycle ratios (r) of 0.5 and 1.5, respectively, and the chemical oxygen demand (COD) removal efficiencies were higher than 90%. When the pilot‐scale reactor was operated with an HRT of 12 h and r values of 1.5 and 3.0, its performance was similar to that observed in the bench‐scale unit (92% COD removal for r = 3.0). However, the nitrogen removal was lower (55% N removal for r = 3.0) due to problems with the hydrodynamics in the aerobic zone. The anaerobic–aerobic fixed‐bed reactor with recirculation of the liquid phase allows for concomitant carbon and nitrogen removal without adding an exogenous source of electron donors and without requiring any additional alkalinity supplementation.  相似文献   

20.
This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L?1), dye concentration (50–300 mg L?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L?1, dye initial concentration of 50–50 mg L?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.  相似文献   

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