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Harbour porpoises are one of the three cetacean species inhabiting the Black Sea. This is the first study to report on polybrominated diphenyl ethers (PBDEs) and naturally-produced compounds, methoxylated PBDEs (MeO-PBDEs) and polybrominated hexahydroxanthene derivatives (PBHDs), in tissues (kidney, brain, blubber, liver, muscle) of male harbour porpoises (11 adults, 9 juveniles) from the Black Sea. Lipid-normalized concentrations decreased from muscle > blubber > liver > kidney > brain for the sum of polychlorinated biphenyls (PCBs) and for the sum of PBDEs. Among the naturally-produced compounds, levels of PBHDs were higher than of MeO-PBDEs, with tri-BHD and 6-MeO-BDE 47 being the dominant compounds for both groups, respectively. Concentrations of naturally-produced compounds decreased from blubber to brain, similarly to the sum of DDT and metabolites (DDXs). Concentrations of DDXs were highest, followed by PCBs, HCB, PBHDs, PBDEs and MeO-PBDEs. Levels of PCBs and PBDEs in blubber were lower than concentrations reported for harbour porpoises from the North Sea, while concentrations of DDXs were higher. 相似文献
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Levels of estrogenic compounds in Xiamen Bay sediment, China 总被引：5，自引：0，他引：5
Xian Zhang 《Marine pollution bulletin》2009,58(8):1210-1216
Concentrations of seven estrogenic compounds, i.e., estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol(EE2), diethylstilbestrol (DES), nonylphenol (NP), octylphenol (OP) and bisphenol A (BPA), were determined in sediments and pore water from Xiamen Bay in China, and their distributions and potential risks in the Bay were assessed. Total estrogenic compounds concentrations varied from 49.20 to 1230.69 ng/g dw in sediments and from 102.33 to 4376.60 ng/L in pore water. The highest levels of these compounds were found at Yundang Lagoon. The results showed that estrogenic compounds in Xiamen Bay originated mainly from municipal wastewaters. Compared with other areas, Xiamen Bay was contaminated with high levels of estrogen hormones. This contamination poses a potential threat to benthic organisms. Although a good relationship (r = 0.94) was observed between the estrogenic compounds concentrations and total organic carbon (TOC) contents in sediments, which did not indicate that the sediment organic matter favors the accumulation of the detected estrogenic compounds. 相似文献
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In 1975, aerosols were collected with high-volume-samplers and impactors on the west coast of Ireland. The ether extractable organic material (EEOM) was separated into three main fractions: bases (B), acids (A), and neutral compounds (N). Each fraction is a very complex mixture of numerous species. Detailed investigations were carried out on these three main fractions. The individual species were determined quantitatively by gas chromatography. Qualitative identification was done by combined GC-MS.The concentration of total particulate matter (TPM) was in the range of 10 g/m3 (STP) air and the concentration of EEOM was 1 g/m3. The relative composition of the EEOM with regard to the main fractions A, B, and N was N>A>B — the same as in previous measurements. Particles with radii <1 m were investigated separately and showed an enrichment in organic matter.A comparison of individual species from several sample locations is now possible for then-paraffins C10 to C28. The concentrations of all thesen-paraffins are below 10 ng/m3, with no overall obvious preference for specific compounds and no obvious dependence on particle size above or below 1 m radius.A preliminary survey does not show any characteristic differences in the relative composition of the organic constituents of clean air aerosols from different sampling localities. The relative composition with regard to the three main fractions is rather uniform in clean air samples and in samples from polluted regions. 相似文献
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Differentiating depositional environments and maturity of crude oils using GC-AED benzothiophenic spectra 总被引：1，自引：0，他引：1
Organosulfur compounds of crude oils and light oils (condensates), collected from ten Chinese petroleumbearing basins and
representing different sedimentary environments, were analyzed and identified using a newly-developed GC-AED technique. The
results show that the distributions of organosulfur compounds of crude oils from different sedimentary environments are of
obvious difference. The crude oils from marine carbonates are rich in organosulfur compounds and those from the source rocks
in an ocean-land interchanging facies and a littoral facies have a high abundance of organosulfur compounds, while no or less
organosulfur compounds of crude oils from a fresh-water lacustrine facies and a swamp facies were detected in the detectable
abundance range of the instrument. This analysis gives a new effective method for oil-source correlation. We also tried to
relate the various parameters of benzothiophenic compounds of crude oils with the methane carbon isotope of associated natural
gases to discuss the thermoevolutionary degree of crude oils and natural gases. 相似文献
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The paper deals with the atmospheric gaseous nitrogen-compounds under special consideration of the ocean being a source for NH3. The distribution of NH3 and NH4
+ in the ocean is discussed. Additionally a survey of measured marine pH-values is given. While in temperate latitudes the source-strength of the ocean seems to be low, no such statement can be made at present for tropical latitudes owing to lack of measurements. 相似文献
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巢湖表层沉积物中生物易降解物质成分特征与分布规律 总被引：3，自引：1，他引：2
富营养化湖泊的藻类残体大量沉降到湖底,其中易降解成分的降解和转化快速消耗底层水体中的溶解氧,极易造成水土界面缺氧,影响湖泊生态系统的健康.于2014年对巢湖12个样点的表层沉积物进行周年跟踪研究,分析样品中有机质来源、总有机碳(TOC)、蛋白质、总糖、总脂以及生物聚合物碳(BPC)等成分含量,揭示易降解有机质的成分特征及在巢湖的分布规律.研究表明:巢湖表层沉积物TOC含量较高,全湖样点平均含量达到1.24%.BPC含量占TOC含量的30.99%~60.48%,有机质中易降解成分含量较高,并且在冬季和夏季时在巢湖西北部湖区有明显累积;有机质及其中的生物易降解部分均主要集中在粒径4~8μm的表层沉积物上,在应用工程技术手段处理、降解表层沉积物中的过量有机质时,更应该关注粒径为4~8μm的沉积物颗粒. 相似文献
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Xiang Qin ChuanJin Li CunDe Xiao ShuGui Hou MingHu Ding JiaWen Ren DaHe Qin 《中国科学:地球科学(英文版)》2014,57(10):2366-2373
This study investigates the regional distribution of marine aerosol originated species(Na+, Cl-, nss-SO42- and MSA) in the snow pits(or firn cores) collected along a transect between Zhongshan Station and the Grove Mountain area(450 km inland) on the eastern side of the Lambert Glacier Basin. Concentrations of Na+ and Cl- decrease exponentially with distance from the coast to 100 km inland(i.e., 1500 m a.s.l.). Statistical results demonstrate that distance from the coast inland and elevation affect the concentration of sea-salt originated ions in inland areas significantly. Increase of Cl-/Na+ ratio and higher variability in its standard deviation suggest that there are other sources of ions in addition to sea-salt in inland areas of the Antarctic continent. The concentrations of Na+ and Cl- from nine sampling sites in the Grove Mountain area are relatively higher than those from sites along CHINARE transect, although all sites are at similar distance inland. This phenomenon indicates that the barrier effect of the mountain may be the most important factor influencing ion deposition. In addition, nss-SO42- and MSA vary differently, with nss-SO42- decreasing with distance more significantly. This implies that sources and transporting pathways influence the deposition of the two sulfur compounds considerably, being supported by the spatial pattern of correlation coefficients between the nss-SO42- and MSA. 相似文献
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Alfonso F. Davila Alberto G. Fairn Luis Gago-Duport Carol Stoker Ricardo Amils Rosalba Bonaccorsi Jhony Zavaleta Darlene Lim Dirk Schulze-Makuch Christopher P. McKay 《Earth and Planetary Science Letters》2008,272(1-2):456-463
Hydrogen peroxide can form through the interaction of pyrite and anoxic water. The oxidation of pyrite results in the precipitation of sulfates and iron oxides, high redox potentials (~ 1000 mV) and acidic pH (3–4). The oxidative potential of the resultant solution may be responsible for the oxidation of organic compounds, as observed in the subsurface of the Rio Tinto Mars analog. On Mars subsurface migration of groundwater interacting with volcanogenic massive pyrite deposits would have mobilized acidic and oxidizing fluids through large portions of the crust, resulting in the widespread deposition of sulfates and iron oxides. This groundwater could have leached substantial volumes of aquifer material and crustal rocks, thereby erasing any organic compounds possibly down to depths of hundreds of meters. Therefore, the preservation of organic biosignatures must have been severely constrained in the portions of the ancient Martian crust that were exposed to aqueous processes, calling for a redefinition of the future targets in the search for biomolecular traces of life on Mars. 相似文献
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A simple and selective solid phase extraction procedure for the trace analysis of iron(III) in water samples has been developed. Sodium dodecyl sulfate coated alumina, modified with polyphenolic compounds (extracted from black tea) was used for the extraction and preconcentration of iron(III) from water samples before determination by flame atomic absorption spectrometry. Due to the complexation reaction between iron(III) and polyphenol compounds, iron(III) was quantitatively extracted on the proposed sorbent and then eluted by 2.0 mL of HCl (1.0 mol/L). The effects of extraction parameters, such as pH and volume of sample solution, amount of polyphenolic compounds, type of eluting agent and the effect of interfering ions on the extraction of iron(III), were investigated. It was found that the proposed method had a good linear range (15.0–100.0 μg/L) and a low detection limit (10.0 μg/L). The procedure was successfully applied for iron determination in drinking water samples. 相似文献
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Li-Peng Zhang Xin-Hong Wang Miao-Lei Ya Yu-Ling Wu Yong-Yu Li Zu-lin Zhang 《Marine pollution bulletin》2014
The occurrence of estrogens in the aquatic environment has become a major concern worldwide because of their strong endocrine disrupting potency. In this study, concentrations of four estrogenic compounds, estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), estriol (E3) were determined with liquid chromatography-tandem mass spectrometry analyses in surface water from South China Sea, and distributions and potential risks of their estrogenic activity were assessed. The estrogenic compounds E1, E2 and E3 were detected in most of the samples, with their concentrations up to 11.16, 3.71 and 21.63 ng L−1. However, EE2 was only detected in 3 samples. Causality analysis, EEQ values from chemical analysis identified E2 as the main responsible compounds. Based on the EEQ values in the surface water, high estrogenic risks were in the coastal water, and low estrogenic risks in the open sea. 相似文献
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The emission of large amounts of solvent vapors with exhaust air from industrial production into the environment is a serious problem. In Germany, industry‐sector‐specific threshold values are applied and technical measures for pollution reduction are required. Different techniques for exhaust air cleaning are in use but still posing problems concerning costs and reliability. For these reasons, the development of processes for exhaust air treatment is the subject of the current research. A new concept for exhaust air cleaning is introduced that combines absorption of a solvent vapor by an organic fluid and a subsequent adsorption by a molecular sieve placed in the absorber. It was managed to close the loops of solvent recovery and sorbents regeneration. In laboratory‐scale experiments it was possible to reduce an initial ethylacetate pollution of 800 mg/m3 or 349 mg C/m3 below the limit value of 75 mg C/m3 over 60 h duration. Thermogravimetric measurements assisted to define optimum conditions for solvent recovery at 180°C from the molecular sieve. One unexpected positive finding was the considerable increase in the solvent release in the presence of the absorption fluid while adsorption isotherms revealed first insight into this process. 相似文献
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Environmental behavior of organotin compounds in the coastal environment of Xiamen, China 总被引：2，自引：0，他引：2
In 2006, organotins pollution were investigated in the coastal environment of Xiamen, China. Six species of organotin compounds including tributyltin, triphenyltin and their degradation compounds were quantified in the dissolved and particulate phases of the water, and in the sediment using GC-FPD. The concentrations of organotin compounds ranged from 2.2 to 160 ng (Sn) L(-1) dissolved in the water, 0.14-6.7 ng (Sn) L(-1) in suspended particulate matter and nd approximately 26 ng (Sn) g(-1) (dry weight) in the sediment. The highest concentration of total organotin or tributyltin in water was found in a shipyard and at a station near the inlet of the harbor, indicating fresh inputs of antifouling paints to Xiamen's coastal environment. Organotin speciation was performed on sediment cores to investigate contamination trends over the past ten years in the harbor. The results of (210)Pb dating indicated that Xiamen western harbor suffered contamination during 2000. The environmental behavior of organotins such as the enhancement of the microlayer, partitioning between water/suspended particulate matter and between water/sediment are also discussed in this paper. 相似文献
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