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1.
The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH3OH, H2CO, H2S, CS, CH3CN and HNC) were monitored. CS, H2S, H2CO, CH3CN were detected up to rh= 3–4 AU from the Sun, while HCN and CH3OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at rh= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as rh -0.4 within 7 AU from the Sun, but remained close to 0.4 km s-1 further away. The CO spectra obtained at large rhare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about 10 K at 7 AU to 110 K around perihelion.  相似文献   

2.
Comet 9P/Tempel 1 was the target of a multi-wavelength worldwide investigation in 2005. The NASA Deep Impact mission reached the comet on 4.24 July 2005, delivering a 370-kg impactor which hit the comet at 10.3 km s−1. Following this impact, a cloud of gas and dust was excavated from the comet nucleus. The comet was observed in 2005 prior to and after the impact, at 18-cm wavelength with the Nançay radio telescope, in the millimeter range with the IRAM and CSO radio telescopes, and at 557 GHz with the Odin satellite. OH observations at Nançay provided a 4-month monitoring of the outgassing of the comet from March to June, followed by the observation of H2O with Odin from June to August 2005. The peak of outgassing was found to be around between May and July. Observations conducted with the IRAM 30-m radio telescope in May and July 2005 resulted in detections of HCN, CH3OH and H2S with classical abundances relative to water (0.12, 2.7 and 0.5%, respectively). In addition, a variation of the HCN production rate with a period of 1.73±0.10 days was observed in May 2005, consistent with the 1.7-day rotation period of the nucleus. The phase of these variations, as well as those of CN seen in July by Jehin et al. [Jehin, E., Manfroid, J., Hutsemékers, D., Cochran, A.L., Arpigny, C., Jackson, W.M., Rauer, H., Schulz, R., Zucconi, J.-M., 2006. Astrophys. J. 641, L145-L148], is consistent with a rotation period of the nucleus of 1.715 days and a strong variation of the outgassing activity by a factor 3 from minimum to maximum. This also implies that the impact took place on the rising phase of the “natural” outgassing which reached its maximum ≈4 h after the impact. Post-impact observations at IRAM and CSO did not reveal a significant change of the outgassing rates and relative abundances, with the exception of CH3OH which may have been more abundant by up to one order of magnitude in the ejecta. Most other variations are linked to the intrinsic variability of the comet. The Odin satellite monitored nearly continuously the H2O line at 557 GHz during the 38 h following the impact on the 4th of July, in addition to weekly monitoring. Once the periodic variations related to the nucleus rotation are removed, a small increase of outgassing related to the impact is present, which corresponds to the release of ≈5000±2000 tons of water. Two other bursts of activity, also observed at other wavelengths, were seen on 23 June and 7 July; they correspond to even larger releases of gas.  相似文献   

3.
The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H13CN, HNC, HNCO, CO, CH3OH, and H2CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H13CN (4–3) and HNCO (160,16–150,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H13CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System12C/13C ratio. The low HCN/H13CN abundance ratio may be in part due to contamination by an SO2line blended with the H13CN (4–3) line. In addition, chemical models suggest that the HCN/H13CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H13CN ratio observed in a comet is not inconsistent with the solar system12C/13C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10−4. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H2CO, and CH3OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H2CO emission suggests production of this species from dust grains.  相似文献   

4.
The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N2/H2/CO/CO2 gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N2, 5.89% H2, 2.21% CO, and 0.11% CO2), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×10−3 (0.1 nmol J−1). In this atmosphere localized HCN concentrations possibly could approach the 10−2 M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N2, 0.1% H2, 27.2% CO, 27.2% CO2) are significantly less as expected, with HCN at G∼3×10−5 (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH4 conditions (99.9% N2, 0.1% CH4) are significant with HCN at G∼1×10−2 (1 nmol J−1) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N2, 28.8% H2, 3.60% CO2, and 3.56% CH4), representing a high CH4 and H2 abundance early Earth atmosphere had HCN yields of G∼5×10−3 (0.5 nmol J−1). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO2 removed (66.43% N2, 29.88% H2, 0% CO2, and 3.69% CH4) had HCN yields of G∼1×10−3 (0.1 nmol J−1) but more significant tholin yields.  相似文献   

5.
C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 1031 molecules s−1. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H2O, CH4, C2H2, C2H6, HCN, CO, NH3, H2CO) and two daughter fragments (OH and NH2) were detected, enabling the determination of a rotational temperature and production rate for H2O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH4 (relative to H2O) are slightly depleted while C2H2, NH2 and possibly NH3 are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.  相似文献   

6.
We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH3CN,CH3OH, H2CO, CO, CS, H2S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets. From the sub-sample of comets for which contemporary H2O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH3OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H2CO/HCN varies between 1.6 and 10; and H2S/HCN varies between 1.5 and 7.6. This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.  相似文献   

7.
We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H2O, OH∗, C2H6, CH3OH, H2CO, CH4, HCN, C2H2, NH3, NH2, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H2O and CH4, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H2O and CH3OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C2H6 and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.  相似文献   

8.
K. Jockers  S. Szutowicz  T. Bonev 《Icarus》2011,215(1):153-185
Axisymmetric models of the outgassing of a cometary nucleus have been constructed. Such models can be used to describe a nucleus with a single active region. The models may include a solar zenith angle dependence of the outgassing. They retrieve the outgassing flux at distances from the nucleus where collisions between molecules are unimportant, as function of the angle with respect to the outgassing axis. The observed emissions must be optically thin. Furthermore the models assume that the outflow speed at large distance from the nucleus does not depend on direction. The value of the outflow speed is retrieved. The models are applied to CN images and HCN spectra of Comet 2P/Encke, obtained nearly simultaneously in November 2003 with the 2 m optical telescope on Mount Rozhen, Bulgaria, and with the 10 m Heinrich Hertz Submillimeter Telescope on Mount Graham, Arizona, USA. According to Sekanina (1988), Astron. J. 95, 911-924, at that time a single outgassing source was active. Input parameters to the models like the rotation period of the nucleus and a small correction to Sekanina’s rotation axis are determined from a simpler jet position angle model. The rotation is prograde with a sideric period of 11.056 ± 0.024 h, in agreement with literature values. The best fit model has an outflow speed of 0.95 ± 0.04 km s−1. The same value has been derived from the corkscrew appearing in the CN images. The location of the outgassing axis is at colatitude δa = 7.4° ± 2.9° and longitude λa = 235° ± 17° (a definition of zero longitude is provided). Comet Encke’s outgassing corresponds approximately to the longitudinally averaged solar input on a spherical nucleus (i.e. very likely comes from deeper layers) but with some deficiency of outgassing at mid-latitudes and non-zero outgassing from the dark polar cap. The presence of gas flow from the dark polar cap is explained as evidence of gas flow across the terminator. The models rely mostly on the CN images. The HCN spectra are more noisy. They provide information how to determine the best fit outflow velocity and the sense of rotation. The model HCN spectra are distinctly non-Gaussian. Within error limits they are consistent with the observations. Models based solely on the HCN spectra are also presented but, because of the lower quality of the data and the unfavorable observing geometry, yield inferior results. As a by-product we determine the CN parent life time from our CN observations. The solar EUV and Lyα radiation field at the time of our observations is taken into account.  相似文献   

9.
We used the NIRSPEC instrument on the Keck-2 telescope atop Mauna Kea, HI to observe Comet C/2001 A2 (LINEAR) in a Target of Opportunity campaign on UT 2001 July 9.5, 10.5 August 4.4, 10.5. We measured seven organic parent volatiles (C2H6, C2H2, HCN, CH4, CO, CH3OH, H2CO) simultaneously with H2O. We obtained absolute production rates and relative abundances for parent volatiles, and also measured rotational temperatures for several of these species. The chemical composition of C/2001 A2 differs substantially from any comet we have observed to date. The abundances we measure (relative to H2O) for C2H6, C2H2, HCN, and CH3OH are enriched by a factor of ∼2 to 3 in C/2001 A2 compared with most comets in our database. Other molecular species were detected within the typical range of measured abundances. C/2001 A2 presented a unique opportunity to study the chemistry of a fragmenting comet where pristine areas are exposed to the Sun.  相似文献   

10.
We investigated the parent volatile composition of the Oort cloud Comet C/2000 WM1 (LINEAR) on 23-25 November 2001, using the Near Infrared Echelle Spectrograph on the Keck II telescope. Flux-calibrated spectra, absolute production rates, and mixing ratios are presented for H2O, HCN, CH4, C2H2, C2H6, H2CO, CH3OH and CO. Compared with “organics-normal” comets, WM1 is moderately depleted in HCN, CH4 and CH3OH, and is even more depleted in C2H2 and CO. Its composition is thus intermediate to comets that are severely depleted in their organic volatile composition and those that exhibit “normal” organic volatile abundances. We argue that WM1 may have formed closer to the young Sun than “organics-normal” comets, but at greater distance than the severely depleted comets, before its ejection to the Oort cloud. The mixing ratios of the above-listed organic volatiles agree day-by-day for 23-25 November 2001. Thus, there is no evidence of macroscopic heterogeneity in chemistry of this comet’s nucleus at the achieved measurement accuracy. As the first comet to show moderate organic depletion in parent volatiles, WM1 represents an important addition to the emerging taxonomic classification based on chemical composition.  相似文献   

11.
In July 1994, the Shoemaker-Levy 9 (SL9) impacts introduced hydrogen cyanide (HCN) to Jupiter at a well confined latitude band around −44°, over a range of specific longitudes corresponding to each of the 21 fragments (Bézard et al. 1997, Icarus 125, 94-120). This newcomer to Jupiter's stratosphere traces jovian dynamics. HCN rapidly mixed with longitude, so that observations recorded later than several months after impact witnessed primarily the meridional transport of HCN north and south of the impact latitude band. We report spatially resolved spectroscopy of HCN emission 10 months and 6 years following the impacts. We detect a total mass of HCN in Jupiter's stratosphere of 1.5±0.7×1013 g in 1995 and 1.7±0.4×1013 g in 2000, comparable to that observed several days following the impacts (Bézard et al. 1997, Icarus 125, 94-120). In 1995, 10 months after impact, HCN spread to −30° and −65° latitude (half column masses), consistent with a horizontal eddy diffusion coefficient of Kyy=2-3×1010 cm2 s−1. Six years following impact HCN is observed in the northern hemisphere, while still being concentrated at 44° south latitude. Our meridional distribution of HCN suggests that mixing occurred rapidly north of the equator, with Kyy=2-5×1011 cm2 s−1, consistent with the findings of Moreno et al. (2003, Planet. Space Sci. 51, 591-611) and Lellouch et al. (2002, Icarus 159, 112-131). These inferred eddy diffusion coefficients for Jupiter's stratosphere at 0.1-0.5 mbar generally exceed those that characterize transport on Earth. The low abundance of HCN detected at high latitudes suggests that, like on Earth, polar regions are dynamically isolated from lower latitudes.  相似文献   

12.
Comet 29P/Schwassmann-Wachmann 1 has been studied during seven days in August 1998 with the SEST submillimeter telescope at ESO, La Silla, Chile. The CO (J=2−1) emission at 230 GHz was mapped by directing the telescope beam at the nucleus and six off-nucleus positions. The CO line profiles exhibit the blue- and redshifted components previously observed by various observers. The strength of the observed lines does not decrease with projected distance to the nucleus as expected if CO molecules were coming from the nucleus only. Instead, the line area is nearly constant throughout the map. This can be explained if CO molecules are being released from both the sunlit side of the nucleus and CO-bearing particles distributed in a shell-like cloud. The extended source must consist of icy grains globally moving toward the Sun at ∼50 m s−1 released ∼30 days before the observations were made. The nuclear and extended sources produce (7±1)×1027 and 2.4×1028 molecules s−1, respectively. Our 1996 observations of the comet (Festou, M., M. Gunnarsson, A. Winnberg, H. Rickman, and G. Tancredi 2001. Icarus150, 140-150) were reexamined using this new two-source model. In this case, the nuclear and extended CO sources produced 10±1×1027 and 2.9×1028 CO molecules s−1, respectively. It is not necessary to postulate night side outgassing, but a large quantity of solid grains has to be expelled into the coma.  相似文献   

13.
A two-dimensional kinetic model calculation for the water group species (H2O, H2, O2, OH, O, H) in Europa's atmosphere is undertaken to determine its basic compositional structure, gas escape rates, and velocity distribution information to initialize neutral cloud model calculations for the most important gas tori. The dominant atmospheric species is O2 at low altitudes and H2 at higher altitudes with average day-night column densities of 4.5×1014 and 7.7×1013 cm−2, respectively. H2 forms the most important gas torus with an escape rate of ∼2×1027 s−1 followed by O with an escape rate of ∼5×1026 s−1, created primarily as exothermic O products from O2 dissociation by magnetospheric electrons. The circumplanetary distributions of H2 and O are highly peaked about the satellite location and asymmetrically distributed near Europa's orbit about Jupiter, have substantial forward clouds extending radially inward to Io's orbit, and have spatially integrated cloud populations of 4.2×1033 molecules for H2 and 4.0×1032 atoms for O that are larger than their corresponding populations in Europa's local atmosphere by a factor of ∼200 and ∼1000, respectively. The cloud population for H2 is a factor of ∼3 times larger than that for the combined cloud population of Io's O and S neutral clouds and provides the dominant neutral population beyond the so-called ramp region at 7.4-7.8 RJ in the plasma torus. The calculated brightness of Europa's O cloud on the sky plane is very dim at the sub-Rayleigh level. The H2 and O tori provide a new source of europagenic molecular and atomic pickup ions for the thermal plasma and introduce a neutral barrier in which new plasma sinks are created for the cooler iogenic plasma as it is transported radially outward and in which new sinks are created to alter the population and pitch angle distribution of the energetic plasma as it is transported radially inward. The europagenic instantaneous pickup ion rates are peaked at Europa's orbit, dominate the iogenic pickup ion rates beyond the ramp region, and introduce new secondary plasma source peaks in the solution of the plasma transport problem. The H2 torus is identified as the unknown Europa gas torus that creates both the observed loss of energetic H+ ions at Europa's orbit and the corresponding measured ENA production rate for H.  相似文献   

14.
Mid- and far-infrared spectra from the Composite InfraRed Spectrometer (CIRS) have been used to determine volume mixing ratios of nitriles in Titan's atmosphere. HCN, HC3N, C2H2, and temperature were derived from 2.5 cm−1 spectral resolution mid-IR mapping sequences taken during three flybys, which provide almost complete global coverage of Titan for latitudes south of 60° N. Three 0.5 cm−1 spectral resolution far-IR observations were used to retrieve C2N2 and act as a check on the mid-IR results for HCN. Contribution functions peak at around 0.5-5 mbar for temperature and 0.1-10 mbar for the chemical species, well into the stratosphere. The retrieved mixing ratios of HCN, HC3N, and C2N2 show a marked increase in abundance towards the north, whereas C2H2 remains relatively constant. Variations with longitude were much smaller and are consistent with high zonal wind speeds. For 90°-20° S the retrieved HCN abundance is fairly constant with a volume mixing ratio of around 1 × 10−7 at 3 mbar. More northerly latitudes indicate a steady increase, reaching around 4 × 10−7 at 60° N, where the data coverage stops. This variation is consistent with previous measurements and suggests subsidence over the northern (winter) pole at approximately 2 × 10−4 m s−1. HC3N displays a very sharp increase towards the north pole, where it has a mixing ratio of around 4 × 10−8 at 60° N at the 0.1-mbar level. The difference in gradient for the HCN and HC3N latitude variations can be explained by HC3N's much shorter photochemical lifetime, which prevents it from mixing with air at lower latitude. It is also consistent with a polar vortex which inhibits mixing of volatile rich air inside the vortex with that at lower latitudes. Only one observation was far enough north to detect significant amounts of C2N2, giving a value of around 9 × 10−10 at 50° N at the 3-mbar level.  相似文献   

15.
P.A. Gerakines  M.H. Moore 《Icarus》2004,170(1):202-213
Hydrogen cyanide (HCN) has been identified in the gas phase of the interstellar medium as well as in the comae of several comets. Terrestrially, HCN is a key component in the synthesis of biologically important molecules such as amino acids. In this paper, we report the results of low-temperature (18 K) ice energetic processing experiments involving pure HCN and mixtures of HCN with H2O and NH3. Ice films, 0.1 to several microns in thickness, were exposed to either ultraviolet photons (110-250 nm) or 0.8-MeV protons to simulate the effects of space environments. Observed products include HCNO (isocyanic acid), NH4+ (ammonium ion), CN− (cyanide ion), OCN− (cyanate ion), HCONH2 (formamide), and species spectrally similar to HCN polymers. Product formation rates and HCN destruction rates were determined where possible. Results are discussed in terms of astrophysical situations in the ISM and the Solar System where HCN would likely play an important role in prebiotic chemistry. These results imply that if HCN is present in icy mixtures representative of the ISM or in comets, it will be quickly converted into other species in energetic environments; pure HCN seems to be polymerized by incident radiation.  相似文献   

16.
R. de Kok  P.G.J. Irwin  N.A. Teanby 《Icarus》2008,197(2):572-578
In Titan's north polar region stratospheric clouds are expected to form due to a combination of low temperatures and downward motion of volatile-enriched air. Here we investigate possible sources of stratospheric clouds at Titan's pole using data from the Cassini Composite Infrared Spectrometer and a simple condensation model. An upper limit for C4N2 gas was determined to be 9×10−9, which is less than required to make the C4N2 cloud at the Voyager epoch. Hence, the presence of this cloud after equinox remains a mystery. The largest cloud seen in far-infrared spectra has a feature around 220 cm−1 and is located around an altitude of 140 km. The upper limit for propionitrile (C2H5CN) gas shows that the feature around 220 cm−1 is probably not due to pure propionitrile ice. Instead, our model calculations show that HCN should cause by far the largest cloud around 140 km. We therefore propose that HCN ice plays an important role in the formation of the massive polar cloud, because of the unavailability of sufficient condensable gas other than HCN to produce a strong enough condensate feature. However, the signature at 220 cm−1 is not consistent with that of pure HCN ice at 172 cm−1 and mixing of HCN ice with other ices, or chemical alteration of HCN ice might mask the HCN ice signature.  相似文献   

17.
Ronen Jacovi 《Icarus》2008,196(1):302-304
Titan's haze, formed by photolysis of C2H2, C2H4 and HCN, was found experimentally to trap Ar, Kr and Xe with efficiencies of 3.5 × 10−4, 1.9 × 10−3 and 6.5 × 10−2 [noble gas atom]/[carbon atom] in the polymer, respectively. The rate of aerosol formation and settling down of 3 × 10−13 kg m−2 s−1, as inferred from our experiments on CH4 photolysis in the far UV [Podolak, M., Bar-Nun, A., 1979. Icarus 39, 272-276], is sufficient to reduce the mixing ratios of 36Ar and 40Ar to their low values of (2.8 ± 0.3) × 10−7 and (4.3 ± 0.1) × 10−3, respectively, and those of Kr and Xe to below the detection limit of 10−8.  相似文献   

18.
M.H. Moore  R.L. Hudson 《Icarus》2003,161(2):486-500
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.  相似文献   

19.
T.Y Brooke  H.A Weaver  G Chin  S.J Kim 《Icarus》2003,166(1):167-187
High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH4, C2H6, HCN, C2H2, CH3OH, H2O, CO, and OH were detected. The rotational temperature of CH4 in the inner coma was Trot=110±20 K. Spatial profiles of CH4, C2H6, and H2O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H2O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H2O (in percent) were 1.1±0.3 (CH4), 0.39±0.10 (C2H6), 0.18±0.04 (HCN), 0.17±0.04 (C2H2), 1.7±0.5 (CH3OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.  相似文献   

20.
The European Space Agency (ESA) Rosetta spacecraft (Schulz, R., Alexander, C., Boehnhardt, H., Glassmeier, K.H. (Eds.) [2009]. “ROSETTA - ESA”) will encounter Comet 67P/Churyumov-Gerasimenko in 2014 and spend the next 18 months in the vicinity of the comet, permitting very high spatial and spectral resolution observations of the coma and nucleus. During this time, the heliocentric distance of the comet will change from ∼3.5 AU to ∼1.3 AU, accompanied by an increasing temperature of the nucleus and the development of the coma. The Microwave Instrument for the Rosetta Orbiter (MIRO) will observe the ground-state rotational transition (110-101) of H216O at 556.936 GHz, the two isotopologues H217O and H218O and other molecular transitions in the coma during this time (Gulkis, S. et al., [2007]. MIRO: Microwave Instrument for Rosetta Orbiter. Space Sci. Rev. 128, 561-597).The aim of this study is to simulate the water line spectra that could be obtained with the MIRO instrument and to understand how the observed line spectra with various viewing geometries can be used to study the physical conditions of the coma and the water excitation processes throughout the coma. We applied an accelerated Monte Carlo method to compute the excitations of the seven lowest rotational levels (101, 110, 212, 221, 303, 312, and 321) of ortho-water using a comet model with spherically symmetric water outgassing, density, temperature and expansion velocity at three different heliocentric distances 1.3 AU, 2.5 AU, and 3.5 AU. Mechanisms for the water excitation include water-water collisions, water-electron collisions, and infrared pumping by solar radiation.Synthetic line spectra are calculated at various observational locations and directions using the MIRO instrument parameters. We show that observations at varying viewing distances from the nucleus and directions have the potential to give diagnostic information on the continuum temperature and water outgassing rates at the surface of the nucleus, and the gas density, expansion velocity, and temperature of the coma as a function of distance from the nucleus. The gas expansion velocity and temperature affect the spectral line width and frequency shift of the line from the rest frequency, while the gas density (which is directly related to the outgassing rate) and the line excitation temperature determine the antenna temperature of the absorption and emission signal in the line profile.  相似文献   

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