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1.
The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N2/H2/CO/CO2 gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N2, 5.89% H2, 2.21% CO, and 0.11% CO2), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×10−3 (0.1 nmol J−1). In this atmosphere localized HCN concentrations possibly could approach the 10−2 M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N2, 0.1% H2, 27.2% CO, 27.2% CO2) are significantly less as expected, with HCN at G∼3×10−5 (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH4 conditions (99.9% N2, 0.1% CH4) are significant with HCN at G∼1×10−2 (1 nmol J−1) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N2, 28.8% H2, 3.60% CO2, and 3.56% CH4), representing a high CH4 and H2 abundance early Earth atmosphere had HCN yields of G∼5×10−3 (0.5 nmol J−1). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO2 removed (66.43% N2, 29.88% H2, 0% CO2, and 3.69% CH4) had HCN yields of G∼1×10−3 (0.1 nmol J−1) but more significant tholin yields. 相似文献
2.
E. LellouchB. Bézard J.I. MosesG.R. Davis P. DrossartH. Feuchtgruber E.A. BerginR. Moreno T. Encrenaz 《Icarus》2002,159(1):112-131
Observations of H2O rotational lines from the Infrared Space Observatory (ISO) and the Submillimeter Wave Astronomy Satellite (SWAS) and of the CO2 ν2 band by ISO are analyzed jointly to determine the origin of water vapor and carbon dioxide in Jupiter's stratosphere. Simultaneous modelling of ISO/LWS and ISO/SWS observations acquired in 1997 indicates that most of the stratospheric jovian water is restricted to pressures less than 0.5±0.2 mbar, with a disk-averaged column density of (2.0±0.5)×1015 cm−2. Disk-resolved observations of CO2 by ISO/SWS reveal latitudinal variations of the CO2 abundance, with a decrease of at least a factor of 7 from mid-southern to mid-northern latitudes, and a disk-center column density of (3.4±0.7)×1014 cm−2. These results strongly suggest that the observed H2O and CO2 primarily result from the production, at midsouthern latitudes, of oxygenated material in the form of CO and H2O by the Shoemaker-Levy 9 (SL9) impacts in July 1994 and subsequent chemical and transport evolution, rather than from a permanent interplanetary dust particle or satellite source. This conclusion is supported by quantitative evolution model calculations. Given the characteristic vertical mixing times in Jupiter's stratosphere, material deposited at ∼0.1 mbar by the SL9 impacts is indeed expected to diffuse down to the ∼0.5 mbar level after 3 years. A coupled chemical-horizontal transport model indicates that the stability of water vapor against photolysis and conversion to CO2 is maintained over typically ∼50 years by the decrease of the local CO mixing ratio associated with horizontal spreading. A model with an initial (i.e., SL9-produced) H2O/CO mass mixing ratio of 0.07, not inconsistent with immediate post-impact observations, matches the observed H2O abunda nce and CO2 horizontal distribution 3 years after the impacts. In contrast, the production of CO2 from SL9-produced CO and a water component deriving from an interplanetary dust component is insufficient to account for the observed CO2 amounts. The observations can further be used to place a stringent upper limit (8×104 cm−2 s−1) on the permanent water influx into Jupiter. This may indicate that the much larger flux observed at Saturn derives dominantly from a ring source, or that the ablation of micrometeoroids leads dominantly to different species at Saturn (H2O) and Jupiter (CO). Finally, the SWAS H2O spectra do not appear fully consistent with the ISO data and should be confirmed by future ODIN and Herschel observations. 相似文献
3.
Fischer-Tropsch catalysis, which converts CO and H2 into CH4 on the surface of iron catalyst, has been proposed to produce the CH4 on Titan during its formation process in a circum-planetary subnebula. However, Fischer-Tropsch reaction rate under the conditions of subnebula have not been measured quantitatively yet. In this study, we conduct laboratory experiments to determine CH4 formation rate and also conduct theoretical calculation of clathrate formation to clarify the significance of Fischer-Tropsch catalysis in a subnebula. Our experimental result indicates that the range of conditions where Fischer-Tropsch catalysis proceeds efficiently is narrow (T∼500-600 K) in a subnebula because the catalysts are poisoned at temperatures above 600 K under the condition of subnebula (i.e., H2/CO = 1000). This suggests that an entire subnebula may not become rich in CH4 but rather that only limited region of a subnebula may enriched in CH4 (i.e., CH4-rich band formation). Our experimental result also suggests that both CO and CO2 are converted into CH4 within time significantly shorter than the lifetime of the solar nebula at the optimal temperatures around 550 K. The calculation result of clathration shows that CO2-rich satellitesimals are formed in the catalytically inactive outer region of subnebula. In the catalytically active inner region, CH4-rich satellitesimals are formed. The resulting CH4-rich satellitesimals formed in this region play an important role in the origin of CH4 on Titan. When our experimental data are applied to a high-pressure model for subnebula evolution, it would predict that there should be CO2 underneath the Iapetus subsurface and no thick CO2 ice layer on Titan's icy crust. Such surface and subsurface composition, which may be observed by Cassini-Huygens mission, would provide crucial information on the origin of icy satellites. 相似文献
4.
High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH4, C2H6, HCN, C2H2, CH3OH, H2O, CO, and OH were detected. The rotational temperature of CH4 in the inner coma was Trot=110±20 K. Spatial profiles of CH4, C2H6, and H2O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H2O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H2O (in percent) were 1.1±0.3 (CH4), 0.39±0.10 (C2H6), 0.18±0.04 (HCN), 0.17±0.04 (C2H2), 1.7±0.5 (CH3OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary. 相似文献
5.
We present new experimental results on impact shock chemistry into icy satellites of the outer planets. Icy mixtures of pure water ice with CO2, Na2CO3, CH3OH, and CH3OH/(NH4)2SO4 at 77 K were ablated with a powerful pulsed laser—a new technique used to simulate shock processes which can occur during impacts. New products were identified by GC-MS and FTIR analyses after laser ablation. Our results show that hydrogen peroxide is formed in irradiated H2O/CO2 ices with a final concentration of 0.23%. CO and CH3OH were also detected as main products. The laser ablation of frozen H2O/Na2CO3 generates only CO and CO2 as destruction products from the salt. Pulsed irradiation of water ice containing methanol leads also to the formation of CO and CO2, generates methane and more complex molecules containing carbonyl groups like acetaldehyde, acetone, methyl formate, and a diether, dimethyl formal. The last three compounds are also produced when adding ammonium sulfate to H2O/CH3OH ice, but acetone is more abundant. The formation of two hydrocarbons, CH4 and C2H6 is observed as well as the production of three nitrogen compounds, nitrous oxide, hydrogen cyanide, and acetonitrile. 相似文献
6.
The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H2O, CO, H2CO, CO2, CH3OH, C2H6, C2H4, C2H2, HCN, NH3, and CH4) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H2, O, OH, C, CH, CH2, CH3, N, NH, NH2, C2, C2H, C2H5, CN, and HCO) from the comet’s surface all the way out to 106 km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO2 (2.5%), and H2CO (1.5%) relative to water without invoking unknown extended sources. 相似文献
7.
We have quantitatively studied, by infrared absorption spectroscopy, the CO/CO2 molecular number ratio after ion irradiation of ices and mixtures containing astrophysically relevant species such as CO,
CO2, H2O, CH4, CH3OH, NH3, O2, and N2 at 12–15 K. The ratios have also been measured after warm up to temperatures between 12 and 200 K. As a general result we
find that the CO/CO2 ratio decreases with the irradiation dose (amount of energy deposited on the sample). In all of the studied mixtures, as
expected, it decreases with increasing temperature because of CO sublimation. However the temperature where CO sublimes strongly
depends on the initial mixture, remaining at a temperature over 100 K in some cases. Our results might be relevant to interpret
the observed CO/CO2 ratio in several astrophysical scenarios such as planetary icy surfaces and ice mantles on grains in the interstellar medium.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides. 相似文献
9.
The Mariner 6 and 7 infrared spectrometers provided data which, in principle, determine upper limits on the possible atmospheric abundance of every gaseous substance that was undetected but which has recognized absorptions in the accessible spectral region, 1.9 to 14.4 μ. Through supporting laboratory determinations of curves of growth under pressure broadening conditions appropriate to Mars, upper limits can be specified (expressed first in cm-atm, STP, for a vertical column and then in parts per million) for the following gases: NO2 (<0.0016, 0.23); NH3 (<0.0031, 0.44); C3O2 (<0.0032, 0.45); SO2 (?0.0037, 0.52); OCS (<0.0040, 0.56); NO (<0.0050, 0.70); O3 (<0.0061, 0.86); CH4 (<0.026, 3.7); N2O (<0.13, 18); HCl (<3.7, 520); HBr (?8.2, 1150); H2S (<27, 3800). In addition, considerations of band contours, moments of inertia, and experimental absorption coefficients permit us to place useful upper limits on twenty-seven additional substances that were not detected and for which curves of growth have not been measured: less than 1.0ppm (or, <0.0071cm-atm); SF6, NF3, Cl2CO, CF4, CHF3, Br2CO, SiF4; less than 6.0ppm (or, <0.035 cm-atm); C2F6, CO3, F2CO, C2H4, BF3, CS2, CHCl3, C2H6, H2CO, CH3F, C6H6, CH2I2; less than 50ppm (or, <0.35 cm-atm): C2H2, HCN, CH2Br2, CH2Cl2, CH3Br, PH3, CH3I, and CH3Cl. These upper limits are compared to earlier limits based upon terrestrial measurements. The present limits placed upon the possible atmospheric content of the molecules C3O2 and CO3 are of particular interest because of their relevance to the photochemistry of the Martian atmosphere. 相似文献
10.
The discovery of CO2, CH4, and N2 in a plume at Enceladus provides useful clues about the chemistry and evolution of this moon of Saturn. Here, we use chemical equilibrium and kinetic calculations to estimate the oxidation state of hydrothermal systems on early Enceladus, with the assumption that the plume's composition was inherited from early hydrothermal fluids. Chemical equilibrium calculations are performed using the CO2/CH4 ratio in the plume, and kinetic calculations are conducted using equations from fluid dynamics and chemical kinetics. Our results suggest that chemical equilibrium between CO2 and CH4 would have been reachable at temperatures above ∼200 °C in hydrothermal systems. The oxidation state of the hydrothermal systems would have been close to the pyrrhotite-pyrite-magnetite (PPM) or fayalite-magnetite-quartz (FMQ) redox buffer (i.e., terrestrial-like) if the plume's CO2 and CH4 equilibrated in hydrothermal systems long ago. As for minerals, we suggest that iron metal would have been oxidized to magnetite by the escape of H2 from the early satellite. Our calculations also indicate that, assuming CO2 and CH4 reached chemical equilibrium, magnetite would not have been oxidized to hematite in hydrothermal systems, perhaps due to insufficient H2 escape. It is shown that, if Enceladus accreted as much NH3 as comets contain, the presence of N2 and deficiency of NH3 in the plume can be understood in the context of chemical equilibrium in the C-N-O-H system. We conclude by proposing an evolutionary hypothesis in which the fairly oxidized nature of the plume can be explained by a brief episode of oxidation caused by short-lived radioactivity. These suggestions can be rigorously tested by acquiring gravity and isotopic data in the future. 相似文献
11.
Early Mars serpentinization‐derived CH4 reservoirs,H2‐induced warming and paleopressure evolution 
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下载免费PDF全文 E. Chassefière J. Lasue B. Langlais Y. Quesnel 《Meteoritics & planetary science》2016,51(11):2234-2245
CH4 has been observed on Mars both by remote sensing and in situ during the past 15 yr. It could have been produced by early Mars serpentinization processes that could also explain the observed Martian remanent magnetic field. Assuming a cold early Mars, a cryosphere could trap such CH4 as clathrates in stable form at depth. The maximum storage capacity of such a clathrate cryosphere has been recently estimated to be 2 × 1019 to 2 × 1020 moles of methane. We estimate how large amounts of serpentinization‐derived CH4 stored in the cryosphere have been released into the atmosphere during the Noachian and the early Hesperian. Due to rapid clathrate dissociation and photochemical conversion of CH4 to H2, these episodes of massive CH4 release may have resulted in transient H2‐rich atmospheres, at typical levels of 10–20% in a background 1–2 bar CO2 atmosphere. The collision‐induced heating effect of H2 present in such an atmosphere has been shown to raise the surface temperature above the water freezing point. We show how local and rapid destabilization of the cryosphere can be induced by large events (such as the Hellas Basin or Tharsis bulge formation) and lead to such releases. Our results show that the early Mars cryosphere had a sufficient CH4 storage capacity to have maintained H2‐rich transient atmospheres during a total time period up to several million years or tens of million years, having potentially contributed to the formation of valley networks during the Noachian/early Hesperian. 相似文献
12.
《Planetary and Space Science》2007,55(10):1328-1345
The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45 μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45 μm.The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO2 ice, H2O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO2 ice grain sizes, water frost abundance, CO2 ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO2 ice and H2O ice grain sizes, dust and H2O ice contaminations in the form of intimate granular mixtures and spatial mixtures.A wide annulus of dusty water ice surrounds the recessing CO2 seasonal cap. The inner cap exhibits a layered structure with a thin CO2 layer with varying concentrations of dark dust, on top of an H2O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO2 ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800 cm−1, inside the strong 2.7-μm CO2 ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO2 ice deposits increases with latitude, ranging from 0.5–1 g cm−2 within region II to 60–80 g cm−2 within the highest-latitude (up to 84°N) region V.Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO2 ice is present in this region, which consists of relatively large grains of water ice (20 μm), highly contaminated by dust (0.15 wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO2 ice features are barely visible in these spectra, except for the strong saturated 2.7 μm band. It basically consists of a thin layer of 5-mm CO2 ice on top of an H2O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5 km in altitude and over only 2° of latitude and consists of CO2 ice with a large dust content. It is an admixture of CO2 ice (3–4 mm), with several tens of ppm by mass of water ice and more than 2 ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO2 ice and warmer dust/H2O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO2 grain size is 3 mm and strong CO2 ice features are present in the data, indicating a thicker CO2 ice layer than in region II (1–2 g cm−2). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO2 ice (no dust) of 5 mm grain sizes, with 30 ppm by weight of water ice. The CO2 ice features are very pronounced and the 2.7 μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40 g cm−2). Assuming a snowpack density of 0.5 g cm−3, we get a minimum thickness of 1–2 cm for the top-layer of regions II and III, 4–10 cm for region IV, and ⩾60–80 cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap.These results should provide new, useful constraints in models of the Martian climate system and volatile cycles. 相似文献
13.
We present results on the energy balance of the Deep Impact experiment based on analysis of 180 infrared spectra of the ejecta obtained by the Deep Impact spacecraft. We derive an output energy of 16.5 (+9.1/−4.1) GJ. With an input energy of 19.7 GJ, the error bars are large enough so that there may or may not be a balance between the kinetic energy of the impact and that of outflowing materials. Although possible, no other source of energy other than the impactor or the Sun is needed to explain the observations. Most of the energy (85%) goes into the hot plume in the first few seconds, which only represents a very small fraction (<0.01%) of the total ejected mass. The hot plume contains 190 (+263/−71) kg of H2O, 1.6 ± 0.5 kg of CO2, 8.2 (+11.3/3.1) kg of CO (assuming a CO/H2O ratio of 4.3%), 27.9 (+25.0/−8.9) kg of organic material and 255 ± 128 kg of dust, while the ejecta contains ∼107 kg of materials. About 12% of the energy goes into the ejecta (mostly water) and 3% to destroy the impactor. Volatiles species other than H2O (CO2, CO or organic molecules) contribute to <7% of the energy balance. In terms of physical processes, 68% of the energy is used to accelerate grains (kinetic energy), 16% to heat them, 6% to sublimate or melt them and 10% (upper limit) to break and compress dust and/or water ice aggregates into small micron size particles. For the hot plume, we derive a dust/H2O ratio of 1.3 (+1.9/−1.0), a CO2/H2O ratio of 0.008 (+0.009/−0.006), an organics/H2O ratio of 0.15 (+0.29/−0.11) and an organics/dust ratio of 0.11 (+0.30/−0.07). This composition refers to the impact site and is different from that of the bulk nucleus, consistent with the idea of layers of different composition in the nucleus sub-surface. Our results emphasize the importance of laboratory impact experiments to understand the physical processes involved at such a large scale. 相似文献
14.
Synthetic spectra of Comet Halley between 2.5 and 15 μm are calculated on the basis of current cometary models. This study shows that molecules which are most likely detectable in the infrared range include H2O, CO, CO2, CH4, NH3, N2H4, and H2CO. The flux emitted by these molecules, mostly due to resonant scattering, should be sufficient for detection by a flyby mission. 相似文献
15.
We used chemical equilibrium calculations to model thermal outgassing of ordinary chondritic material as a function of temperature, pressure, and bulk composition and use our results to discuss outgassing on asteroids and the early Earth. The calculations include ∼1000 solids and gases of the elements Al, C, Ca, Cl, Co, Cr, F, Fe, H, K, Mg, Mn, N, Na, Ni, O, P, S, Si, and Ti. The major outgassed volatiles from ordinary chondritic material are CH4, H2, H2O, N2, and NH3 (the latter at conditions where hydrous minerals form). Contrary to widely held assumptions, CO is never the major C-bearing gas during ordinary chondrite metamorphism. The calculated oxygen fugacity (partial pressure) of ordinary chondritic material is close to that of the quartz-fayalite-iron (QFI) buffer. Our results are insensitive to variable total pressure, variable volatile element abundances, and kinetic inhibition of C and N dissolution in Fe metal. Our results predict that Earth's early atmosphere contained CH4, H2, H2O, N2, and NH3; similar to that used in Miller—Urey synthesis of organic compounds. 相似文献
16.
We detected CH4 in eight Oort cloud comets using high-dispersion (λ/Δλ∼2×104) infrared spectra acquired with CSHELL at NASA's IRTF and NIRSPEC at the W.M. Keck Observatory. The observed comets were C/1995 O1 (Hale-Bopp), C/1996 B2 (Hyakutake), C/1999 H1 (Lee), C/1999 T1 (McNaught-Hartley), C/1999 S4 (LINEAR), C/2000 WM1 (LINEAR), C/2001 A2 (LINEAR), and 153/P Ikeya-Zhang (C/2002 C1). We detected the R0 and R1 lines of the ν3 vibrational band of CH4 near 3.3 μm in each comet, with the exception of McNaught-Hartley where only the R0 line was measured. In order to obtain production rates, a fluorescence model has been developed for this band of CH4. We report g-factors for the R0 and R1 transitions at several rotational temperatures typically found in comet comae and relevant to our observations. Using g-factors appropriate to Trot as determined from HCN, CO and/or H2O and C2H6, CH4 production rates and mixing ratios are presented. Abundances of CH4/H2O are compared among our existing sample of comets, in the context of establishing their place of origin. In addition, CH4 is compared to native CO, another hypervolatile species, and no correlation is found among the comets observed. 相似文献
17.
S.A. Haider 《Icarus》2005,177(1):196-216
In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH3OH+2, H3CO+, NH+4, H3S+, H2CN+, H2O+, NH+3, CO+, C3H+3, OH+, H3O+, CH3OH+, C3H+4, C2H+2, C2H+, HCO+, S+, CH+3, H2S+, O+, C+, CH+4, C+2, and O+2) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH+4, H3O+, CH3OH+2, H3S+, H2CN+, and H2O+, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H3O+, CH3OH+2, H2O+, H3CO+, C2H+2, and NH+4; along with ions CO+, OH+, and HCO+, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models. 相似文献
18.
It has been suggested that the present release rate of methane to the Martian atmosphere could be the result of serpentinization in the deep subsurface, followed by the conversion of H2 to CH4 in a CO2-rich fluid. Making this assumption, we show that the cryosphere could act as a buffer storing, under the form of micron-size methane clathrate particles, the methane delivered from below by hydrothermal fluids and progressively releasing it to the atmosphere at the top. From an extrapolation of the present CH4 release rate back to the past, we calculate that up to several hundred millibars (～200–2000 mbar) of CO2, resulting from the oxidation of the released CH4, in addition to the volcanic supply (～400 mbar), should have accumulated in the atmosphere in the absence of a CO2 sink. We reassess the capability of escape to have removed CO2 from the atmosphere by C non-thermal escape and show that it is not significant. We suggest that atmospheric carbon is recycled to the crust through an active subsurface hydrological system, and precipitates as carbonates within the crust. During episodic periods of magmatic activity, these carbonates are decomposed to CO2 dissolved in running water, and CO2 can react with H2 formed by serpentinization to build CH4. CH4 is then buffered in the subsurface cryosphere, above the water table, and finally released to the atmosphere, before being recycled to the subsurface hydrological system, and converted back to carbonates. We propose a typical evolution curve of the CO2 pressure since the late Noachian based on our hypothesis. Contrary to the steady state carbon cycle at work on Earth, a progressive damping of the carbon cycle occurs on Mars due to the absence of plate tectonics and the progressive cooling of the planet. 相似文献
19.
C.Y. Robert WuD.L. Judge Bing-Ming ChengWen-Hao Shih Tai-Sone YihW.H. Ip 《Icarus》2002,156(2):456-473
Experimental results on the spectral identification of new infrared absorption features and the changes of their absorbances produced through vacuum ultraviolet-extreme ultraviolet (VUV-EUV) photon-induced chemical reactions in the C2H2-H2O mixed ices at 10 K are obtained. To the best of our knowledge, this is the first time that EUV photons have been employed in the study of the photolysis of ice analogues. Two different compositions, i.e., C2H2:H2O=1:4 and 1:1, were investigated in this work. A tunable intense synchrotron radiation light source available at the Synchrotron Radiation Research Center, Hsinchu, Taiwan, was employed to provide the required VUV-EUV photons. In this study, the photon wavelengths selected to irradiate the icy samples corresponded to the prominent solar hydrogen, helium, and helium ion lines at 121.6 nm, 58.4 nm, and 30.4 nm, respectively. The photon dosages used were typically in the range of 1×1015 to 2×1017 photons. Molecular species produced and identified in the ice samples at 10 K resulting from VUV-EUV photon irradiation are mainly CO, CO2, CH4, C2H6, CH3OH, and H2CO. In addition to several unidentified features, we have tentatively assigned several absorption features to HCO, C3H8, and C2H5OH. While new molecular species were formed, the original reactants, i.e., H2O and C2H2, were detectably depleted due to their conversion to other species. The new chemical species produced by irradiation of photons at 30.4 nm and 58.4 nm can be different from those produced by the 121.6-nm photolysis. In general, the product column density of CO reaches saturation at a lower photon dosage than that of CO2. Furthermore, the production yield of CO is higher than that of CO2 in the photon irradiation. In the present study, we also observe that the photon-induced chemical reaction yields are high using photons at 30.4 and 58.4 nm. The results presented in this work are essential to our understanding of chemical synthesis in ice analogues, e.g., the cometary-type ices and icy satellites of planetary systems. 相似文献
20.
Bockelée-Morvan D. Wink J. Despois D. Colom P. Biver N. Crovisier J. Gautier D. Gérard E. Lellouch E. Moreno R. Paubert G. Rauer H. Davies J. K. Dent W. R. F. 《Earth, Moon, and Planets》1997,78(1-3):67-67
Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de
Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first
detections of HCOOH,SO2, NH2CHO and HCOOCH3 in a comet. HDO was detected through its312–221 line at 225.897 GHz,complementing the observation of the 101–000 line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines
are present in the spectra. Observations of HC3N, HNCO, OCS, SO, CN, CO+, HCO+, in addition to more ‘classical’species CO, HCN, HNC, CH3CN, CH3OH, H2CO, CS and H2S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp
at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows,
which are believed to reflect the composition of interstellar grains.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献