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1.
This study examined the UV/H2O2 decolorization efficiency under high UV photon flux (intensity normalized by photon energy) irradiation; the incident UV was ranging from 3.13 × 10?8 to 3.13 × 10?6 einstein cm?2 s?1. The experimental results showed that complete decolorization of 20 mg L?1 methylene blue (MB) can be achieved within 5 s and 99% decolorization of 1000 mg L?1 MB can be achieved in 180 s under the best condition of high UV intensity UV/H2O2 process. To the best of our knowledge, UV/H2O2 decolorization process in such a short time has not been reported. The electrical energy per order of the process was 16.21 kWh m?3 order?1 and it is relatively economical compared with other advanced oxidation processes. The kinetics of decolorization follows pseudo‐first order. There is a linear relationship between rate constant and UV intensity, which indicates that increasing UV intensity does not cause decline in light utilization efficiency. The experiment related to initial substrate concentration shows decolorization rate of different substrate concentration (20–1000 mg L?1) are closed to each other. Besides, optimal H2O2 concentration, comparative study with low photon flux light, decolorization of other types of dyes and TOC removal were also studied.  相似文献   

2.
The Dinghushan flux observation site, as one of the four forest sites of ChinaFLUX, aims to acquire long-term measurements of CO2 flux over a typical southern subtropical evergreen coniferous and broad-leaved mixed forest ecosystem using the open path eddy covariance method. Based on two years of data from 2003 to 2004, the characteristics of temporal variation in CO2 flux and its response to environmental factors in the forest ecosystem are analyzed. Provided two-dimensional coordinate rotation, WPL correction and quality control, poor energy-balance and underestimation of ecosystem respiration during nighttime implied that there could be a CO2 leak during the nighttime at the site. Using daytime (PAR > 1.0 μmol?1·m?2·s?1) flux data during windy conditions (u* > 0.2 m·s?1), monthly ecosystem respiration (Reco) was derived through the Michaelis-Menten equation modeling the relationship between net ecosystem C02 exchange (NEE) and photosynthetically active radiation (PAR). Exponential function was employed to describe the relationship between Reco and soil temperature at 5 cm depth (Ts05), then Reco of both daytime and nighttime was calculated respectively by the function. The major results are: (i) Derived from the Michaelis-Menten equation, the apparent quantum yield (α) was 0.0027±0.0011 mgCO2·μmol?1 photons, and the maximum photosynthetic assimilation rate (Amax) was 1.102±0.288 mgCO2·m?2·s?1. Indistinctive seasonal variation of α or Amax was consistent with weak seasonal dynamics of leaf area index (LAf) in such a lower subtropical evergreen mixed forest, (ii) Monthly accumulated Reco was estimated as 95.3±21.1 gC·m?2mon?1, accounting for about 68% of the gross primary product (GPP). Monthly accumulated WEE was estimated as ?43.2±29.6 gC·m?2·mon?1. The forest ecosystem acted as carbon sink all year round without any seasonal carbon efflux period. Annual NEE of 2003 and 2004 was estimated as ?563.0 and ?441.2 gC·m?2·a?1 respectively, accounting for about 32% of GPP.  相似文献   

3.
The removal of chemical oxygen demand (COD) and phenol from olive oil mill wastewaters (OOMW) was investigated experimentally by using conventional Fenton (CFP) and Fenton type processes (FTP) with zero valent iron (ZVI). Different operational parameters such as initial pH, Fe2+, Fe0, and H2O2 concentrations were examined. Kinetic studies in terms of COD and phenol removals for both CFP and FTP were performed. The original pH value (4.6) of OOMW for CFP was found as the optimum pH. The determined optimum conditions are [Fe2+] = 1500 mg L?1, [H2O2] = 1750 mg L?1, and pH = 4.6 for CFP; [Fe0] = 2000 mg L?1, [H2O2] = 2000 mg L?1, and pH = 3 for FTP. 82.4% COD and 62% phenol removals were performed under the optimum conditions by CFP, while 82% COD and 63.4% phenol were removed by FTP. According to the results of kinetic studies, it was observed that COD and phenol were removed by FTP more rapidly, compared to CFP. Consequently, it was determined that both CFP and FTP were effective processes for the pretreatment of OOMW.  相似文献   

4.
Abstract

Rivers have been channelized, deepened and constrained by embankments for centuries to increase agricultural productivity and improve flood defences. This has decreased the hydrological connectivity between rivers and their floodplains. We quantified the hydrological regime of a wet grassland meadow prior to and after the removal of river embankments. River and groundwater chemistry were also monitored to examine hydrological controls on floodplain nutrient status. Prior to restoration, the highest river flows (～2 m3 s?1) were retained by the embankments. Under these flow conditions the usual hydraulic gradient from the floodplain to the river was reversed so that subsurface flows were directed towards the floodplain. Groundwater was depleted in dissolved oxygen (mean: 0.6 mg O2 L?1) and nitrate (mean: 0.5 mg NO3 ?-N L?1) relative to river water (mean: 10.8 mg O2 L?1 and 6.2 mg NO3 ?-N L?1, respectively). Removal of the embankments has reduced the channel capacity by an average of 60%. This has facilitated over-bank flow which is likely to favour conditions for improved flood storage and removal of river nutrients by floodplain sediments.

Editor Z.W. Kundzewicz; Associate editor K. Heal

Citation Clilverd, H.M., Thompson, J.R., Heppell, C.M., Sayer, C.D., and Axmacher, J.C., 2013. River–floodplain hydrology of an embanked lowland Chalk river and initial response to embankment removal. Hydrological Sciences Journal, 58 (3), 627–650.  相似文献   

5.
The relationship between the ground-based inferred vertical E × B drifts, Vz, and the magnetic equatorial electrojet current during the year of solar minima was presented. Both the diurnal and seasonal Vz variations are positively directed during the daytime and negative at nighttime. The evening time pre-reversal enhancement occurs around 19:00 LT. The fairly strong linear relationship between the electrojet current strength and Vz exhibited higher correlations during the daytime (06:00–16:00 LT). The maximum morning time proxy parameter described by E = [d (ΔH ILR)/dt]max in the morning hours, indicating the east-west electric field in the EEJ, corresponds reasonably well with the E × B drift and, hence, can be used as a proxy parameter for representing Vz in the morning hours. The daytime EEJ magnitude seasonal changes are connected with a change in conductivity emerging from the action of turbulence and divergence of momentum flux. These waves above the dynamo region are suggested to lead to partial counter electrojet during the equinoctial months.  相似文献   

6.
Bezafibrate (BZF), a widely used lipid regulator, is a potential threat to ecosystems and human health in water, and the recent research showed that advanced oxidation processes (AOPs) are much more effective for BZF degradation. In this study, we investigated the photochemical decomposition of BZF in surface water and effluent from waste water treatment plants (WWTP) by UV/H2O2 process. The results showed that the UV/H2O2 process was a promising method to remove BZF at low concentration, generally at µg L?1 level. When initial concentrations reach 100 µg L?1 in the deionized water, >99.8% of BZF could be removed in 16 min under UV intensity of 61.4 µm cm?2, at the H2O2 concentration of 0.1 mg L?1, and neutral pH condition. Moreover, BZF degradation was inhibited in this process when humic acid (HA) and inorganic solution anions were added to the deionized water solutions, including chloride, nitrate, bicarbonate, and sulfate, significantly. In the surface water and effluent of WWTP, however, the removal efficiency of BZF was lower than that in the deionized water because of the interference of complex constituents in the surface water and effluent. Some main intermediates at the m/z range of 100–400 were observed by high performance LC‐MS (HPLC/MS) and a simple pathway of BZF degradation by UV/H2O2 was proposed.  相似文献   

7.
In a headwater basin covered with boreal forest in northern Japan, the summer dry flow was monitored each summer from 1985 to 1993. Streamflow and specific electrical conductance fluctuated diurnally and these variations were attributed to daytime evapotranspiration. In 1989, the daytime reduction in streamflow and conductance were accompanied by a reduction in the HCO?3 concentration. The low flow hydrograph was separated into two components using HCO?3 and Cl? concentrations in August 1989, assuming low flow to be a mixture of delayed subsurface flow and of quick shallow flow. The slight diurnal variation in the ratio of shallow flow to subsurface flow caused the diurnal variation in conductance by changing the HCO?3 concentration.  相似文献   

8.
The effects of oxygen supply rate and the presence or absence of nutrients on the kinetics of phenol degradation and oxygen consumption by a mixed microbial population were tested in a model system. The values for the maximum specific rate of phenol degradation (qSmax), the saturation constant (KS), and the inhibition concentration (SCR) were determined for unlimited growth (KLa = 340 h?1, growth medium) with 1.7 mmol g?1 h?1, 65 mg L?1, and 190 mg L?1. Under limitation conditions, alterations occur depending on the type of limitation. Nutrient limitations lead to values of 0.8 mmol g?1 h?1, 45 mg L?1, and 160 mg L?1, and oxygen limitations lead to 1.2 mmol g?1 h?1. 30 mg L?1, and 120 mg L?1, respectively. The results suggest that with excess oxygen, the rate of phenol degradation was higher and the inhibition effect of phenol was suppressed to some extent. Under the same high oxygen supply rate, the presence of nutrients in the model water significantly supported the phenol degradation rate.  相似文献   

9.
Wang  Chunlin  Yu  Guirui  Zhou  Guoyi  Yan  Junhua  Zhang  Leiming  Wang  Xu  Tang  Xuli  Sun  Xiaomin 《中国科学:地球科学(英文版)》2006,49(2):127-138

The Dinghushan flux observation site, as one of the four forest sites of ChinaFLUX, aims to acquire long-term measurements of CO2 flux over a typical southern subtropical evergreen coniferous and broad-leaved mixed forest ecosystem using the open path eddy covariance method. Based on two years of data from 2003 to 2004, the characteristics of temporal variation in CO2 flux and its response to environmental factors in the forest ecosystem are analyzed. Provided two-dimensional coordinate rotation, WPL correction and quality control, poor energy-balance and underestimation of ecosystem respiration during nighttime implied that there could be a CO2 leak during the nighttime at the site. Using daytime (PAR > 1.0 μmol−1·m−2·s−1) flux data during windy conditions (u* > 0.2 m·s−1), monthly ecosystem respiration (Reco) was derived through the Michaelis-Menten equation modeling the relationship between net ecosystem C02 exchange (NEE) and photosynthetically active radiation (PAR). Exponential function was employed to describe the relationship between Reco and soil temperature at 5 cm depth (Ts05), then Reco of both daytime and nighttime was calculated respectively by the function. The major results are: (i) Derived from the Michaelis-Menten equation, the apparent quantum yield (α) was 0.0027±0.0011 mgCO2·μmol−1 photons, and the maximum photosynthetic assimilation rate (Amax) was 1.102±0.288 mgCO2·m−2·s−1. Indistinctive seasonal variation of α or Amax was consistent with weak seasonal dynamics of leaf area index (LAf) in such a lower subtropical evergreen mixed forest, (ii) Monthly accumulated Reco was estimated as 95.3±21.1 gC·m−2mon−1, accounting for about 68% of the gross primary product (GPP). Monthly accumulated WEE was estimated as −43.2±29.6 gC·m−2·mon−1. The forest ecosystem acted as carbon sink all year round without any seasonal carbon efflux period. Annual NEE of 2003 and 2004 was estimated as −563.0 and −441.2 gC·m−2·a−1 respectively, accounting for about 32% of GPP.

  相似文献   

10.

At present, using Eddy Covariance (EC) method to estimate the “true value” of carbon sequestration in terrestrial ecosystem arrests more attention. However, one issue is how to solve the uncertainty of observations (especially the nighttime CO2 flux data) appearing in post-processing CO2 flux data. The ratio of effective and reliable nighttime EC CO2 flux data to all nighttime data is relatively low (commonly, less than 50%) for all the long-term and continuous observation stations in the world. Thus, the processing method of nighttime CO2 flux data and its effect analysis on estimating CO2 flux annual sums are very important. In this paper, the authors analyze and discuss the reasons for underestimating nighttime CO2 flux using EC method, and introduce the general theory and method for processing nighttime CO2 flux data. By analyzing the relationship between nighttime CO2 flux and air fraction velocity u*, we present an alternate method, Average Values Test (AVT), to determine the thresholds of fraction velocity (u*c) for screening the effective nighttime CO2 flux data. Meanwhile, taking the data observed in Yucheng and Changbai Mountains stations for an example, we analyze and discuss the effects of different methods or parameters on nighttime CO2 flux estimations. Finally, based on the data of part ChinaFLUX stations and related literatures, empirical models of nighttime respiration at different sites in ChinaFLUX are summarized.

  相似文献   

11.
A. V. Pavlov 《Annales Geophysicae》1994,12(10-11):1085-1090
In this paper we present the results of a study of the effect of vibrationally excited oxygen, O* 2, and nitrogen, N* 2, on the electron density, N e, and the electron temperature, T e, in the D and E regions. The sources of O* 2 are O-atom recombination, the photodissociation of O3, and the reaction of O3 with O at D region altitudes. The first calculations of O* 2(j) number densities, N j , are obtained by solving continuity equations for the models of harmonic and anharmonic oscillator energy levels, j=1-22. It is found that day time values of N j are less than nighttime values. We also show that the photoionization of O* 2 (j\geq11) by L<alpha>-radiation has no influence on the D region N e . In the nighttime D region the photoionization O* 2 (j\geq11) by scattered L <alpha>-radiation can be a new source of O+ 2. We show that the N* 2 and O* 2 de-excitation effect on the electron temperature is small in the E region of the ionosphere and cannot explain experimentally observed higher electron temperatures.  相似文献   

12.
At present, using Eddy Covariance (EC) method to estimate the “true value” of carbon sequestration in terrestrial ecosystem arrests more attention. However, one issue is how to solve the uncertainty of observations (especially the nighttime CO2 flux data) appearing in post-processing CO2 flux data. The ratio of effective and reliable nighttime EC CO2 flux data to all nighttime data is relatively low (commonly, less than 50%) for all the long-term and continuous observation stations in the world. Thus, the processing method of nighttime CO2 flux data and its effect analysis on estimating CO2 flux annual sums are very important. In this paper, the authors analyze and discuss the reasons for underestimating nighttime CO2 flux using EC method, and introduce the general theory and method for processing nighttime CO2 flux data. By analyzing the relationship between nighttime CO2 flux and air fraction velocity u*, we present an alternate method, Average Values Test (AVT), to determine the thresholds of fraction velocity (u*c) for screening the effective nighttime CO2 flux data. Meanwhile, taking the data observed in Yucheng and Changbai Mountains stations for an example, we analyze and discuss the effects of different methods or parameters on nighttime CO2 flux estimations. Finally, based on the data of part ChinaFLUX stations and related literatures, empirical models of nighttime respiration at different sites in ChinaFLUX are summarized.  相似文献   

13.
In the present study, effects of operational parameters on the electrical energy consumption for photooxidative process (UV/H2O2) for the decolorization of C. I. Acid Red 88 (AR88) have been investigated. In a series of experiments, 20 mg L?1 of AR88 solution were irradiated in the presence of different concentrations of H2O2 (to find out optimum amount of H2O2) by UV light intensity of 30 W m?2 for certain irradiation times. The decolorization of the dye followed pseudo first‐order kinetics, and hence, the figure‐of‐merit electrical energy per order (EEO) is appropriate for estimating the electrical energy efficiency. The electrical energy consumption was determined during the variation of some parameters such as initial H2O2 concentration, initial dye concentration, UV light intensity, pH, and the gap size of solution. Results showed that electrical energy could be reduced by optimizing operational parameters.  相似文献   

14.
A wave flume experiment was conducted to study nutrient fluxes at water-sediment interface of Meiliang Bay under different hydrodynamic conditions. The results reveal that hydrodynamics has remarkable effects on nutrient fluxes in this area. With a bottom wave stress of 0.019 N m?2 (equivalent to disturbance caused by wind SE 5–7 m s?1 at the sediment sample site of Meiliang Bay), the fluxes of TN, TDN and NH4 +-N were separately 1.92 × 10?3, ?1.81 × 10?4 and 5.28 × 10?4 mg m?2 s?1 (positive for upward and negative for downward), but for TP, TDP and SRP, the fluxes were 5.69 × 10?4, 1.68 × 10?4 and ?1.29 × 10?4 mg m?2 s?1. In order to calculate the released amount of nutrients based on these results, statistic analysis on the long-term meteorological data was conducted. The result shows that the maximum lasting time for wind SE 5–7 m s?1 in this area is about 15 h in summer. Further calculation shows that 111 t TN, 32 t NH4 +-N, 34 t TP and 10 t TDP can be released into water (the sediment area was 47.45% of the whole surface area), resulting in concentration increase of 0.025, 0.007, 0.007 and 0.002 mg L?1 separately. With stronger disturbance (bottom wave stress is 0.217 N m?2 which is equivalent to disturbance caused by wind SE 10–11 m s?1 at the same site), there has been significant increase of nutrient fluxes (1.16 × 10?2, 6.76 × 10?3, 1.14 × 10?2 and 2.14 × 10?3 mg m?2 s?1 for TN, DTN and NH4 +-N and TP). The exceptions were TDP with flux having a decrease (measured to be 9.54 × 10?5 mg m?2 s?1) and SRP with flux having a small increase (measured to be 5.42 × 10?5 mg m?2 s?1). The same statistic analysis on meteorological data reveal that the maximum lasting time for wind SE 10–11 m s?1 is no more than 5 h. Based on the nutrient fluxes and the wind lasting-time, similar calculations were also made suggesting that 232 t TN, 134.9 t TDN, 228 t NH4 +-N, 42.7 t TP, 2.0 t TDP and 1.1 t SRP will be released from sediment at this hydrodynamic condition resulting in the concentration increases of 0.050, 0.029, 0.049, 0.009, 0.0004 and 0.0002 mg L?1. Therefore in shallow lakes, surface disturbance can lead to significant increase of nutrient concentrations although some components in water column had negative flux with weak disturbance (e.g. TDN and SRP in this experiment). In this case, sediment looks to be a source of nutrients. These nutrients deposited in sediment can be carried or released into water with sediment resuspension or changes of environmental conditions at water-sediment interface, which can have great effects on aquatic ecosystem and is also the characteristics of shallow lakes.  相似文献   

15.
Extreme sedimentation in Swift Creek, located in the Cascades foothills in NW Washington (48°55′N, 122°16′W), results from erosion of the oversteepened, unvegetated toe of a large (55 hectares) active landslide. Deposition of landslide‐derived sediment has necessitated costly mitigation projects in the channel including annual dredging and temporary sediment traps in an attempt to reduce the risk of flooding and damage to man‐made structures downstream. This study attempts to understand the process of sediment production along with the corresponding erosion rates of the sediment source to help with the development of mitigation plans and construction of optimal sediment reservoirs. The bedload and suspended sediment in the creek are a direct result of the weathering process of the serpentinitic bedrock underlying the landslide. The serpentinite does not weather to smectite clay, as previously thought. Instead, it weathers to asbestiform chrysotile with minor amounts of chlorite, illite and hydrotalcite, all of which occur in clay seeps on the unvegetated surface of the landslide. The chrysotile fibers average 2 µm in length and make up at least 50%, by volume, of the suspended load transported in Swift Creek. This study does not address the environmental or health implications of the asbestiform chrysotile transport or deposition. During the sampled time between February 2005 and February 2006, 127 discrete suspended sediment samples were collected and discharge was measured 66 times. The suspended sediment concentrations ranged from 0·02 g L?1 to 41·6 g L?1 and the discharge ranged from 0·0 m3 s?1 to 0·5 m3 s?1. A nonlinear functional model estimated the total suspended sediment flux from detailed precipitation records and discrete suspended sediment concentration and discharge measurements to be 910 t km?2 yr?1. When the suspended sediment flux is coupled with estimates of downstream deposition of coarse sediment, the estimated erosion rate for the entire Swift Creek landslide is 158 mm yr?1. The majority of the material entering Swift Creek is presumed to originate on the unvegetated toe of the landslide, for which the erosion rate is thus approximately 1 m yr?1. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

16.
Wetlands often form the transition zone between upland soils and watershed streams, however, stream–wetland interactions and hydrobiogeochemical processes are poorly understood. We measured changes in stream nitrogen (N) through one riparian wetland and one beaver meadow in the Archer Creek watershed in the Adirondack Mountains of New York State, USA from 1 March to 31 July 1996. In the riparian wetland we also measured changes in groundwater N. Groundwater N changed significantly from tension lysimeters at the edge of the peatland to piezometer nests within the peatland. Mean N concentrations at the peatland perimeter were 1·5, 0·5 and 18·6 µmol L?1 for NH4+, NO3? and DON (dissolved organic nitrogen), respectively, whereas peatland groundwater N concentration was 56·9, 1·5 and 31·6 µmol L?1 for NH4+, NO3? and DON, respectively. The mean concentrations of stream water N species at the inlet to the wetlands were 1·5, 10·1 and 16·9 µmol L?1 for NH4+, NO3? and DON, respectively and 1·6, 28·1 and 8·4 µmol L?1 at the wetland outlet. Although groundwater total dissolved N (TDN) concentrations changed more than stream water TDN through the wetlands, hydrological cross‐sections for the peatland showed that wetland groundwater contributed minimally to stream flow during the study period. Therefore, surface water N chemistry was affected more by in‐stream N transformations than by groundwater N transformations because the in‐stream changes, although small, affected a much greater volume of water. Stream water N input–output budgets indicated that the riparian peatland retained 0·16 mol N ha?1 day?1 of total dissolved N and the beaver meadow retained 0·26 mol N ha?1 day?1 during the study period. Nitrate dominated surface water TDN flux from the wetlands during the spring whereas DON dominated during the summer. This study demonstrates that although groundwater N changed significantly in the riparian peatland, those changes were not reflected in the stream. Consequently, although in‐stream changes of N concentrations were less marked than those in groundwater, they had a greater effect on stream water chemistry—because wetland groundwater contributed minimally to stream flow. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

17.
The observations of the variations in the vertical component of the atmospheric electric field (E z ) at Swider midlatitude Poland observatory (geomagnetic latitude 47.8°) under the conditions of fair weather during 14 magnetic storms have been analyzed. The effect of the magnetic storm main phase in the daytime midlatitude variations in E z in the absence of local geomagnetic disturbances has been detected for the first time. Considerable (～100–300 V m?1) decreases in the electric field strength (E z ) at Swider observatory were observed in daytime simultaneously with the substorm onset in the nighttime sector of auroral latitudes (College observatory). The detected effects indicate that an intensification of the interplanetary electric field during the magnetic storm main phase, the development of magnetospheric substorms, and precipitation of energetic electrons into the nighttime auroral ionosphere can result in considerable disturbances in the midlatitude atmospheric electric field.  相似文献   

18.
The degradation of two pesticides: atrazine and metazachlor was investigated in aqueous solution under UV-irradiation with and without H2O2. Rate constants of the photochemical degradation were determined applying a first order kinetics and quantum yields of the processes were calculated. This approach leads to an apparent decrease of the quantum yield with increasing initial pesticide concentration. At low H2O2 initial concentrations, the pesticide degradation was shown to be much more efficient than the degradation under UV-irradiation only. However, at high H2O2 concentrations (>2 mmol L?1), the efficiency of the UV/H2O2 system dropped down and the quantum yields of degradation were lower than for the direct photolysis. In the absence of H2O2, no influence of the pH value on the photodegradation of the pesticides could be noticed in a range between pH 3 and pH 11. At low H2O2 initial concentrations, the photochemical degradation of the pesticides was much faster at pH 3 and pH 7 compared with the degradation at pH 11. The results emphasize the potential of optimized reaction conditions in advanced oxidation.  相似文献   

19.
The inactivation of Fusarium solani in water was assessed by solar driven Fenton-like processes using three different iron salts: ferric acetylacetonate (Fe(acac)3), ferric chloride (FeCl3) and ferrous sulfate (FeSO4). The experimental conditions tested were [Fe] ≈ 5 mg L−1, [H2O2] ≈ 10 mg L−1 and [Fe] ≈ 10 mg L−1; [H2O2] ≈ 20 mg L−1 mild and high, respectively, and pH 3.0 and 5.0, under solar radiation. The highest inactivation rates were observed at high reaction conditions for the three iron salts tested at pH 5.0 with less than 3.0 kJ L−1 of accumulate energy (QUV) to achieve over 99.9% of F. solani inactivation. Fe(acac)3 was the best iron salt to accomplishing F. solani inactivation. The modified Fermi equation was used to fix the experimental inactivation, data showed it was helpful for modeling the process, adequately describing dose–response curves. Inactivation process using FeSO4 at pH 3.0 was modeled fairly with r2 = 0.98 and 0.99 (mild and high concentration, respectively). Fe(acac)3, FeCl3 and FeSO4 at high concentration (i.e. [Fe] ≈ 10 mg L−1; [H2O2] ≈ 20 mg L−1) and pH 5.0 showed the highest fitting values (r2 = 0.99). Iron salt type showed a remarkable influence on the Fenton-like inactivation process.  相似文献   

20.
Eddy covariance technique was used to measure carbon flux during two growing seasons in 2003 and 2004 over typical steppe in the Inner Mongolia Plateau, China. The results showed that there were two different CO2 flux diurnal patterns at the grassland ecosystem. One had a dual peak in diurnal course of CO2 fluxes with a depression of CO2 flux after noon, and the other had a single peak. In 2003, the maximum diurnal uptake and emitting value of CO2 were ?7.4 and 5.4 g·m?2·d?1 respectively and both occurred in July. While in 2004, the maximum diurnal uptake and release of CO2 were ?12.8 and 5.8 g·m?2·d?1 and occurred both in August. The grassland fixed 294.66 and 467.46 g CO2·m?2 in 2003 and 2004, and released 333.14 and 437.17 g CO2·m?2 in 2003 and 2004, respectively from May to September. Water availability and photosynthetic active radiation (PAR) are two important factors of controlling CO2 flux. Consecutive precipitation can cause reduction in the ability of ecosystem carbon exchange. Under favorable soil water conditions, daytime CO2 flux is dependent on PAR. CO2 flux, under soil water stress conditions, is obviously less than those under favorable soil water conditions, and there is a light saturation phenomena at PAR=1200 μmol·m?2·s?1. Soil respiration was temperature dependent when there was no soil water stress; otherwise, this response became accumulatively decoupled from soil temperature.  相似文献   

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