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1.
To evaluate the effect of sample preparation on the trace element composition of ostracod shells, fossil shells subjected to various cleaning steps were analyzed by ICP-AES. The variations in ostracod Mg/Ca ratios reveal that fossil ostracod samples cleaned by ultrasonic methanol yield lower values than those by other methods, including increasingly rigorous reductive cleaning. In our sample sets, shell Mg/Ca decreases ∼ ∼1.5 mmol/mol during clay removal. Sample Sr/Ca results do not seem to vary significantly under the equivalent cleaning steps. For ostracod analysis, pre-treatment using multiple methanol ultrasonic cleaning is suggested to be used for gaining an appropriate result.  相似文献   

2.
Prior to oxygen isotope analysis of biogenic silica by fluorination techniques, sediments must be cleaned of all organic compounds. Despite the expanding volume of research utilising oxygen isotope ratios in biogenic silica in palaeoclimatology, very little is known about the effects of different standard preparation methods for the removal of organic matter on the isotope values. Here we compare a number of methods for the removal of organic matter in order to assess their effectiveness and influence on subsequent isotope measurements. Not all the methods described here effectively removed organic matter, the best treatments were H2O2 and ignition in air at 550°C. Ignition in air at 950°C, and heating in vacuum at 250 and 450°C results in marked alteration of isotope values, whereas use of hydrogen peroxide (H2O2), nitric acid (HNO3) and plasma ashing have little or no effect, within the bounds of analytical error. Ignition in air at 550°C was the most effective technique, and induced no alteration of δ18Osilica, but practical constraints may limit the application of this method routinely. Our findings indicate that considerable caution is required when preparing sediment for isotope analysis of biogenic silica.  相似文献   

3.
Cleaning of lake sediment samples for diatom oxygen isotope analysis   总被引：1，自引：0，他引：1  
Detrital grain contamination in a diatom sample can considerably influence the δ18Odiatom signal. In order to obtain a meaningful signal, pure samples must be used. This can be achieved via a series of cleaning stages including organic and carbonate material removal, sieving, differential settling and heavy liquid separation. The method described here works best for sediments with >20% diatom content. Based on testing various clean-up methods, we propose a sequence of four clean-up stages to produce pure diatom samples from a range of lake sediments types starting with a few grams of sediment. The diatom content and the oxygen isotope composition of the samples at each stage were measured in order to assess the effect of differential amounts of contamination. Results show that a four stage clean-up is necessary to produce clean diatom samples and that contamination by silt and clay causes lower δ18O values.  相似文献   

4.
Frequent and serious aeolian disasters occur in the upper and middle reaches of the Yarlung Zangbo River, which runs through the high-elevation Tibet Plateau. Sediment geochemical characteristics can be used as a proxy to identify the sediment's provenance. To determine the provenance of aeolian sediments in the river's basin, we analysed major and trace element contents from surface samples and local clastic rocks throughout the basin. We found that the major and trace elements differed between the middle reaches, upper reaches and regions south of the river. Major element contents were similar in the upper and middle reaches, but trace elements differed. Al2O3, MgO and Na2O concentrations increased from the upper reaches to the lower reaches, and in the lower reaches, MgO and Na2O were enriched compared with the crustal average. The similarities between samples in the lower part of the upper reaches and those in the middle reaches indicated that sediment transported by fluvial systems from the upper reaches were first deposited in the wide valleys near Xigaze, where they formed a large area of shifting sand. These deposits were then transported by the wind to the river's middle reaches, where they formed a large area of shifting sand. When we compared aeolian sediment in the middle reaches with the local clastic rocks, they appeared to be unrelated. The difference between sediments south of the river and those in the middle reaches means that the southern sediments were not transported to the middle reaches. Therefore, the aeolian sediment in the middle reaches of the Yarlung Zangbo River mainly came from the lower part of the upper reaches, not from the local clastic rocks.  相似文献   

5.
近年来的调查工作发现,柴达木盆地西部的一些背斜构造区油田卤水具有储量大、品位高的特点,表现出良好的开发和利用前景。在狮子沟背斜构造区深部有含卤层甚至盐岩层的发现。以狮子沟背斜构造区深层卤水为研究对象,采样测试其离子含量,进而分析卤水的离子比例系数,对其水化学特征、物质来源、演化过程进行分析,研究认为深部卤水主要是盐岩溶解作用形成的,其中不乏有沉积卤水的加入;其演化主要受控于蒸发和溶解的双重作用,同时白云岩化、酸性斜长石的溶解以及中酸性热液的淋滤作用也可能对该区卤水有某种程度的影响。  相似文献   

6.
Although previous investigations of the trace elements in snow and ice from the Qinghai-Tibetan Plateau obtained interesting information about pollution from human activities on the plateau, most were based on traditional acidification methods. To emphasize the influence of the different sample-preparation methods on the records of trace elements and rare earth elements, snow samples were collected from glaciers on the Qinghai-Tibetan Plateau in China and prepared using two methods: traditional acidification and total digestion. Concentrations of 18 trace elements (Al, Ti, Fe, Rb, Sr, Ba, V, Cr, Mn, Li, Cu, Co, Mo, Cs, Sb, Pb, Tl, and U), along with 14 rare earth elements (REEs: La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu), Y, and Th in the snow samples, were measured using inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The results showed that the mass fraction of the trace elements (defined as ratio of concentration in the acid-leachable fraction to that in the digested sample) such as Mo, Ti, Al, Rb, and V, varied from 0.06 to 0.5. The mass fraction of other trace elements varied from about 0.6 to more than 0.9; those of the REEs, Y, and Th varied from 0.34 to 0.75. Lower mass fractions will lead to an overestimated contribution of other sources, especially human activities, and the underestimated fluxes of these trace elements (especially REEs, Y, and Th, as well as dust) if the REEs are used as the proxy for the crust dust. The two sample-preparation methods exhibited different REE normalized distribution patterns, REE ratios, and provenance-tracing results. The REE normalized distribution patterns and proxies in the digested samples are more reliable and integrated than those found in traditional acidification method for dust-provenance tracing.  相似文献   

7.
Paleothermal indicators based on clay mineral and organic matter analyses, were integrated with mudrock geochemistry and stratigraphic data to define the sedimentary evolution of the southwestern Thrace Basin during the Eocene to Oligocene. This multi‐method approach allowed us to reconstruct the burial evolution of the basin in Eocene and Oligocene times and to study the mudrock composition and relate this to their provenance and source area weathering. The studied mudrocks show similar chemical variations. The distribution of some major and trace elements for the studied samples reflect heterogeneous source areas containing both felsic to mafic rocks. In particular, the Light Rare Earth Elements/Transition elements (LREEs/TEs) ratios are very high for the Avdira and Organi samples (on the average between 1.5 and 2.2 for (La + Ce)/Cr and 3.5–8 for (La + Ce)/Ni), suggesting a felsic source(s), and very low for the Samothraki, Limnos, Paterma and Iasmos samples (on the average between 0.4 and 0.6 for (La + Ce)/Cr and 0.6–1 for (La + Ce)/Ni), suggesting a mainly basic source(s). The mineralogical composition coupled with the A‐CN‐K and A‐N‐K plots suggest a complex evolution. The clay mineral data (illite percentage in I/S and the stacking order R and the Kübler Index) coupled to vitrinite reflectance analysis indicate a high to intermediate diagenetic grade for the Middle to Upper Eocene samples (from Iasmos, Gratini, Organi, Paterma, Esimi and Samotraki sections) and a low diagenetic grade for the Upper Eocene to Oligocene samples (from Limnos and Avdira sections). These data helped in interpreting the geodynamic evolution of the studied basins where the magmatic activity plays an important role. In particular, Middle to Upper Eocene sediments show high to intermediate diagenetic grade since they are located in a portion of the basin dominated by Eocene to Oligocene magmatic activity and intrusion of granitoids, whereas, the Upper Eocene to Oligocene sediments are not involved in important magmatic activity and intrusion of granitoids and, thus, show low diagenetic grade. Furthermore, Middle to Upper Eocene sediments experienced deeper burial processes caused by lithostatic load, rather than the uppermost Eocene and Oligocene sediments, in relation of their position along the stratigraphic succession. These data suggest a burial depth of at least 3–4 km with a tectonic exhumation mainly related to the extensional phases of the Miocene age.  相似文献   

8.
干旱区典型流域土壤微量元素的空间变异特征研究   总被引：10，自引：0，他引：10  
采用地统计方法,以新疆三工河流域为例,研究了干旱区流域土壤微量元素的空间异质性特征。结果表明,四种微量元素为对数正态分布;流域内土壤微量元素的空间异质性明显,微量元素含量绿洲区普遍高于荒漠区;其中,有效铁和有效锌含量基本属正常范围,有效锰含量处于普遍缺乏状态,有效铜含量较高;微量元素变异系数在42.28%~83.24%;四种微量元素含量空间变异具有各向异性特征,为中等强度的空间自相关性,表现为二阶趋势效应。用简单克立格法进行最优内插,考虑各向异性及趋势效应,制作研究区土壤微量元素含量的等值线图,分析结果表明其具有明显的空间分布规律。利用地统计学方法,对认识本区土壤微量元素的空间变异结构,流域农业生产合理布局、土壤资源综合治理都具有重要的意义。  相似文献   

9.
阿拉善荒漠草地类微量元素含量特征的研究   总被引：13，自引：0，他引：13  
付华  周志宇  庄光辉 《中国沙漠》2000,20(4):426-429
对阿拉善所属的4个草地类6个亚类75个牧草25个土壤样本中的Fe、Mn、Zn、Cu、Co、Mo、Se等7种微量元素的含量及分布类型进行研究,并对各草地类牧草中微量元素的含量进行评价。研究结果表明,土壤中微量元素除滩地戈壁亚类,山前倾斜地亚类、河泛地低地亚类Se含量及冷温潮湿类的Cu和Zn含量正常外,其它都低于我国和世界正常土壤平均含量。微量元素的缺乏与成土母质相关。阿拉善地区气候、土壤等生态条件复杂,但牧草中微量元素的含量有一定范围,这与牧草本身对元素的吸收和积累能力相关。  相似文献   

10.
闽东南沿海老红砂的地球化学特征   总被引：5，自引：2，他引：3  
曾从盛 《中国沙漠》2000,20(3):248-251
闽东南沿海老红砂的地球化学分析表明,B、Ga、Sr、Ba、K、Cr、Ni和V等微量元素含量及B/Ga和Sr/Ba比值指示老红砂应为陆相沉积,其磷酸钙组分和古盐度亦指示为陆相。老红砂的化学全量组合特征与花岗岩风化壳相似,但SiO2含量较花岗岩风化壳大,而Al2O3的含量明显少于花岗岩风化壳。从老红砂垂直剖面变化看,其硅铝铁率一般从上往下增加,分解系数(Fe2O3/MgO)一般从上往下减少。  相似文献   

11.
Presented are the results from investigating Baikal’s water samples collected in June 2009 for two profiles in Middle Baikal. Mean concentrations of 34 elements were obtained by the ICP-MS method using high-resolution instrument ELEMENT-2, and Zn, Cu, Fe, Al, Pb and Mn content levels were quantified. The Mo, U and Sr concentrations in Baikal’s water characterize the geochemical background in the lake’s region. According to the occurrence scale, the contents of the other elements approach the mean values for the world’s fresh surface waters or are substantially below the worldwide values for clean surface waters.  相似文献   

12.
Stratigraphy of total metals in PIRLA sediment cores   总被引：1，自引：0，他引：1  
Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by 210Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO2, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm–2 yr–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO2 as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO2 from the atmosphere varies and is a significant fraction of the total flux of TiO2 to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.  相似文献   

13.
A method was developed to quantify a suite of organic compounds from snow melt water samples present at trace level concentrations, using a dichloromethane liquid–liquid extraction and GC–MS. Samples from a 3-m snow pit sampled in 2005 from Summit, Greenland were analyzed using the method developed, and a profile of organics over the past 4 years was compiled. Supporting data including the concentrations of total organic carbon (TOC), low molecular weight acids, and trace elements were determined using well established methods. The results show that low molecular weight acids contribute a significant percentage, up to 20%, of the measured TOC. Hopanes were measured quantitatively for the first time in Greenland snow. Hopanes, as well as PAHs, are at very low concentrations and contribute 0.0002–0.004% to TOC. Alkanes and alkanoic acids were also quantified, and contribute less than 1% and up to 7%, respectively to TOC. No apparent seasonal pattern was found for specific classes of organic compounds in the snow pit. The lack of seasonal pattern may be due to post-depositional processing.  相似文献   

14.
The basic materials used in packaging are glass, metals (primarily aluminum and steel), an ever-growing range of plastics, paper and paperboard, wood, textiles for bags, and miscellaneous other materials (such as glues, inks, and other supplies). They are fabricated into rigid, semirigid, or flexible containers. The most common forms of these containers include cans, drums, bottles, cartons, boxes, bags, pouches, and wraps. Packaging products are, for the most part, low cost, bulky products that are manufactured close to their customers. There is virtually no import or export of packaging products. A material flow analysis can be developed that looks at all inputs to an industrial sector, inventories the losses in processing, and tracks the fate of the material after its useful life. An example is presented that identifies the material inputs to the packaging industry, and addresses the ultimate fate of the materials used.Correspondence should be directed to Earle B. Amey, U.S. Geological Survey, National Center 983, Reston, Virginia 20192.  相似文献   

15.
Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ18Oshell and δ13Cshell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ13C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Cashell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Cashell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Cashell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ13C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.  相似文献   

16.
The detection of the freshwater genus Rhizosolenia (Bacillariophyceae) remains in sediments is affected by the oxidants used in the digestion procedures. The Rhizosolenia counts decrease from 30% H2O2>50% HNO3>50% chromic acid>100% HNO3>100% H2SO4. Rhizosolenia is mostly found in Ontario lakes with summer average pH ranging from 5.6 to 8.3, Gran alkalinity from 0.2 to 120 mg L–1 as CaCO3 and water colour from 4 to 105 Hazen units. Large Rhizosolenia populations are generally found in clear lakes, neutral pH and low alkalinity.  相似文献   

17.

The potassium supplying capacity of the waste mica powder (WMP) was evaluated through chemical and biological means. Four different size fractions of the WMP were studied in laboratory by different chemical extractants. At the same time, experiment of the plant growth was conducted in pot using K-deficient soil. The K release from the WMP by different extractants followed an increasing trend with an increase in the fineness of the particles. The highest K release was recorded by boiling 1 M HNO3 (376.4–1726.4 mg kg?1) followed by 1 M ammonium acetate (33.5–226.5 mg kg?1), 0.01 M citric acid (31.6–158.3 mg kg?1) and water (12.0–112.0 mg kg?1) irrespective of the various size fractions. Significantly, higher cumulative K release from the WMP in successive extraction was recorded with 1 M boiling HNO3 that predicts its slow-release property. The K release by different extractants was correlated significantly and positively with the biomass yield and K uptake by plants. 1 M boiling HNO3 extractable K showed higher correlation values with the biomass yield and K uptake. Therefore, it suggests that the extractant might be a better indicator of K supplying capacity of the WMP. The plant intervention was able to extract 32.8% of total K from the WMP simultaneously improving the exchangeable and non-exchangeable K pool in soil. These above-mentioned results conclude that plants can get access to a significant amount of K from the WMP and it could be an effective source of K in highly weathered tropical soils under K deficiency.

  相似文献   

18.
三种土壤铅和镉的质量基准初步研究*   总被引：8，自引：0，他引：8  
在制定地下水源保护区污染控制措施时,最常遇到的问题之一是缺少土壤包气带和含水层中化学物质的基准和标准。文中以铅、镉为例,结合北京、唐山地下水水源地实际情况,运用“平衡分配法”,根据土壤对铅和镉的吸附容量和分配系数研究包气带土壤中的铅和镉的质量基准。结果表明,土壤中铅和镉的质量基准与溶液pH值成对数线性关系,据此可计算不同pH条件下的土壤中重金属的质量基准。  相似文献   

19.
三工河流域下游绿洲土壤微量元素有效含量空间变异特征   总被引：4，自引：2，他引：2  
土壤微量元素空间分布特征是反映特定地区环境状况的一个重要因素。基于GIS技术,通过地统计学方法研究了天山北坡三工河流域冲积平原型绿洲土壤表层微量元素B、Mn、Zn、Fe及Cu等有效含量的空间变异特征。结果表明：①土壤微量元素B、Mn、Zn、Fe和Cu具有强烈的空间自相关性,自相关范围在520～3 970 m内变化,其中Zn和Fe的自相关性尺度相对较大,而B的自相关性尺度最小。②土壤微量元素均具有各向异性,其中在0°方向上变异最大。整体来看,研究区土壤有效B、Fe和Cu具有较强的各向异性,而有效Mn和Zn各向异性相对较弱。③采用Kriging和IDW两种插值方法分析研究区土壤微量元素的空间格局,结果表明,土壤微量元素呈现出明显的片状和斑块状分布特点。研究区中西部有效B含量较高,有效Mn、Zn、Fe和Cu含量均较低。  相似文献   

20.
In this paper, an abandoned waste coal pile, which is resulted from Alborz-Sharghi coal washing plant, NE of Iran was mineralogically and geochemically characterized to evaluate pyrite oxidation, acid mine drainage (AMD) generation, and trace element mobility. After digging ten trenches and vertical sampling, a quantitative method including the atomic absorption test, and the quality-based methods including optical study were carried out for determination of pyrite fractions in the waste pile. The geochemical results revealed that the fraction of remaining pyrite increased with depth, indicating that pyrite oxidation is limited to the shallower depths of the pile which were confirmed by variations of sulfate, pH, EC, and carbonate with depth of the pile. To evaluate the trend of trace elements and mineralogical constituents of the waste particles, the samples were analyzed by using XRD, ICP-MS, and ICP-OES methods. The results showed the secondary and neutralizing minerals comprising gypsum have been formed below the oxidation zone. Besides, positive values of net neutralization potential indicated that AMD generation has not taken in the waste pile. In addition, variations of trace elements with depth reveal that Pb and Zn exhibited increasing trends from pile surface toward the bottom sampling trenches while another of them such as Cu and Ni had decreasing trends with increasing depth of the waste pile.  相似文献   

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