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1.
Smectite, illite, celadonite and chlorite are the major products of alteration of rhyolites and andesites, in the upper part of the Los Azufres geothermal system. Changes in mineral assemblages and composition of phases are observed as a function of depth and host rock lithology. Two different sequences characterize the rhyolites and the andesites from the surface to a depth of about 1500 m: kaolinitesmectite (±interlayered illite/smectite)illitemuscovite (rhyolites), and kaolinitesmectite (±interlayered illite/smectite)illite+celadoniteillite+chloritechlorite (andesites).Illite, and chlorite at depth, are largely dominant. Similar substitutions and correlations among chemical constituents characterize illites from rhyolites or andesites, but their compositions in the two host rock lithologies exhibit slight but significant differences, especially in their Fe and Mg contents which are the highest in illites from andesites. Illite exhibits progressive changes in composition with depth: a strong increase in the K content in the interlayer, together with an increase of the Fe content in the octahedral site. These changes correspond to a slight increase in the molar fraction of Fe-(Mg) celadonite end-members, and mostly to a dramatic decrease of pyrophyllite with increasing temperature.Temperature of the mineralogical and compositional changes was estimated from fluid inclusions studies, combined with other geothermometric approaches (chemical geothermometers and direct measurements). Variation of X-pyrophyllite with temperature is proposed as a geothermometer for different host rock lithologies. Transitions between the stability fields of illite±interstratified illite-smectite and illite+chlorite is around 200±30° C, and between illite+chlorite and chlorite around 290±20° C.  相似文献   

2.
Monomineralic domains of chlorite, corundum and Cr muscovite coexist over a kilometer scale within ultramafic schists of the Harare greenstone belt (2.73 Ga). This exotic lithological association includes the conjunction of some of the most aluminous (Al2O388 wt%) and potassic (K2O10 wt%) rocks known. The paragenetic sequence developed from chloritecorundumcorundum+ diaspore: Cr muscovite variably overprinted both the corundum and chloritite domains. Terminal stages were marked by sporadic production of andalusite+quartz, and finally margarite.Chlorite (Cr2O3=0.31–2.65 wt%), corundum (0.79–2.66 wt%), and diaspore are all Cr-rich varieties. The chromian (Cr2O33.86 wt%) paragonitic muscovite incorporates up to 17% of the paragonite molecule, and significant Mg and Fe substitutions.The suite of rocks are characterized by chondritic Ti/Zr ratios (–x=107), systematically enhanced Cr (up to 14000 ppm) and Ni (up to 1200 ppm) abundances, low levels of the alteration-insensitive incompatible elements Th, Ta, Nb. Chlorite, corundum and Cr muscovite represent progressive stages in the incremental metasomatic alteration of a komatiite precursor. Mass balance calculations, constrained by the isochemical behaviour of Ti, Zr and Hf reveal that the komatiite chloritite transformation involved volumetric contractions of 60% by hydrothermal leaching of Si, Fe, Mn, Ca and Na. Reaction of chloritite to corundum involved further volumetric reductions of 50% due to essentially quantitative loss of Si, Fe, Mn, Mg, K and Ca. Conversion of corundum to muscovite required additions of Si, K, Fe, Mn, Mg, Rb and Ba at 50–200% dilation. K, Rb, Ba, Li and Cs are enriched by up to 2×103 over background abundances in ultramafic rocks, and the suite is also enriched in B, Se, Te, Bi, As, Sb and Au. REE were extensively leached during chloritite-corundum stages, whereas LREE additions accompany development of muscovite. Ti, Zr, Hf and Al were all concentrated by selective leaching of mobile components, but absolute additions of Al accompanied development of the corundum domains due to Al precipitation in response to depressurization.Corundum ( 18O=3.5–4.8), muscovite ( 18O=6.7–7.5) and chlorite (4.5–5.6) are isotopically uniform and formed at 380–520° C from a fluid where 18O=5.6–6.9. The corundum is 18O depleted relative to either igneous or anatectic counterparts (Ocor=7.6–8.2), or to gibbsitic laterites ( 18O=12–17).Previous genetic schemes involving metamorphism of exhalites or bauxite, or Si-undersaturation of magmas, can all be ruled out from the data. The chloritite, corundum, Cr-muscovite association represents sequential alteration products of ultramafic rocks by high temperature, low pH hydrothermal solutions carrying LIL-elements, and in which excursions of pH and/or degree of quartz undersaturation account for the mineralogical transitions. A deep level acid epithermal system, or fluid advection across steep inverted thermal gradients in a thrust regime could account for required hydrothermal conditions.  相似文献   

3.
The pre-Cambrian granulites of Enderby Land Antarctica, contain coexisting spinel-quartz, sapphirine-quartz, hypersthene-sillimanite-quartz and osumilite on a regional extent. Osumilite is present in a variety of mineral assemblages, most of which are documented in granulites for the first time. The mineral assemblages, reactions and compositional zoning in minerals are discussed in terms of continuous and discontinuous reactions in response to changing conditions of metamorphism. The development of many of the mineral coronas can be explained by continuous rather than discontinuous reactions, due to the effects of Mg-Fe and (Mg,Fe)-2Al exchange equilibria with decreasing temperature. The highest P-T conditions of metamorphism (8–10 kb, 900 °–980 ° C, Ellis, in preparation) were beyond the stability limit of coexisting garnet-cordierite. Secondary cordierite has developed through a large number of mineral reactions in response to cooling of these granulites.A theoretical analysis of the phase relations involving osumilite in the chemical systems K2O-MgO-Al2O3-SiO2 and K2O-MgO-FeO-Al2O3-SiO2 is presented. In the pure Mg-system the lower temperature stability limit of Mg-osumilite is inferred to be defined with increasing pressure by the reactions OsCd+En+Kfeld+Qtz, OsSa+En+Kfeld+Qtz, OsSill+En+Kfeld+Qtz. In iron-bearing systems an important reaction involving osumilite is Os+GtCd+Hy+Kfeld+Qtz.At moderate temperatures and pressures, osumilite is limited to rocks which lie on the Mg-rich side of the Cd-Hy stable tie line on an AFM diagram. At higher pressures and temperatures osumilite occurs in a widerrange of rock compositions because of the stability of coexisting garnet and osumilite. Petrographic data, as well as chemographic relations indicate that for many common rock compositions, garnet, cordierite, hypersthene, sapphirine and sillimanite cannot coexist with both osumilite and K-feldspar.Published with the permission of the Director, Bureau of Mineral Resources  相似文献   

4.
Three kornerupine occurrences are reported in distinctive SiO2-poor, MgO- and Al2O3-rich paragneisses from the Namaqualand Metamorphic Complex in South Africa. Kornerupine coexists stably with phlogopite, cordierite, orthopyroxene, gedrite, sapphirine, sillimanite and plagioclase and, in sapphirine-free rocks, with spinel and corundum. Tourmaline of a texturally older generation than kornerupine is commonly present in the same samples.Ten analysed kornerupines show a variation in total Fe as FeO from 1.8 to 10.9 weight per cent. B2O3 contents are estimated from x-ray data and a few spectrochemical analyses to range from 0.9 to 3.5 weight per cent. There is a strong inverse correlation between B3+ and Al3+. Total iron content has a strong and systematic effect on refractive index, colour and dispersion. Fe and Mg are systematically partitioned with the other minerals, and Mg/(Mg+Fe) ratios increase as follows: spinel 相似文献   

5.
An experimental investigation of olivine morphology   总被引：1，自引：0，他引：1  
Olivine crystals can adopt ten types of shape. Experimental crystallization of eight rock melts shows that there is a systematic change from polyhedral or granular olivines hopper olivines branching olivines randomly oriented chain olivines parallel-growth chain olivines chain+lattice olivines plate or feather olivines, with increase in cooling rate and with increase in degree of supercooling. This sequence involves changes from complete to progressively less complete crystals and from equant habit to elongate bladed habit (c>ab) to tabular habit (ac b). The sequence is not affected by the phase relations of the melt. The larger the olivine content of a melt the slower the cooling rate at which a particular olivine shape grows, whereas the lower the melt viscosity, the greater the cooling rate. Irrespective of the melt composition, comparable crystal shapes grow at the same degrees of supercooling. By comparison of the shapes of olivine crystals in experiments with those in rocks of similar composition, it is possible to deduce the cooling rate through the olivine crystallization interval and the approximate degree of supercooling at which the olivine crystals nucleated and grew in the rocks. The various shapes of skeletal olivines in many picrites, olivine-rich basalts and the Archaean spinifex rocks are not due to rapid cooling, but to rapid olivine growth caused by the high normative olivine content of the magma.  相似文献   

6.
Sapphirine occurs in the orthopyroxene-cordierite and feldspar-sillimanite granulites in the Sipiwesk Lake area of the Pikwitonei granulite terrain, Manitoba (97°40W, 55°05N). The orthopyroxene-cordierite granulites have extremely high Al2O3 (24.5 wt%) and MgO (24.6 wt%) contents and contain sapphirine (up to 69.2 wt% Al2O3), aluminous orthopyroxene (up to 8.93 wt% Al2O3), cordierite, spinel, phlogopite, and corundum. Sapphirine forms coronas mantling spinel and corundum. Corona sapphirine is zoned and its composition varies through the substitution (Mg, Fe, Mn) Si=2 Al as a function of the phases with which it is in contact. Textural and chemical relationships of sapphirine with coexisting phases indicate that spinel + cordierite reacted to form orthopyroxene + sapphirine under conditions of increasing pressure. Moreover, decreasing core to rim variation of Al2O3 in orthopyroxene porphyroblasts suggests decreasing temperature during sapphirine formation. On the basis of experimentally determined P-T stability of the assemblage enstatite + sapphirine + cordierite, and the Al content of hypothetical Fe2+-free orthopyroxene associated with sapphirine and cordierite, metamorphic temperatures and pressures are estimated to be 860–890° C and 3.0–11.2 kbar.In the feldspar-sillimanite granulites, sapphirine occurs as a relict phase mantled by sillimanite and/or by successive coronas of sillimanite and garnet. These textural relations suggest the reaction sapphirine + garnet + quartz = orthopyroxene + sillimanite with decreasing temperature. Compositions of minerals in the assemblage garnet-orthopyroxene-sillimanite-plagioclase-quartz, indicate metamorphic P-T conditions of 780–880° C and 9±1 kb.The metamorphic conditions estimated in this study suggest that the sapphirine bearing granulites in the Sipiwesk Lake area represent Archean lower crustal rocks. Their formation might be related to the crustal thickening processes in this area as suggested by Hubregtse (1980) and Weber (1983).  相似文献   

7.
NaBe-cordierites (Fe/(Fe+Mn+Mg)=0.49–0.57) with BeO contents up to 1.16 weight % and additional Li2O contents up to 0.21 wt.% occur in cordierite-apatite-uraninite-muscovite-biotite-chlorite-feldspar-quartz nodules within pegmatites penetrating gneissic roof pendants of a lower Palaeozoic granite batholith. Occasional small crystals of beryl are interpreted to coexist stably with unaltered cordierite. Be and Li are incorporated in cordieriteaccording to the substitutions Na[Channel] + Be[4] Al[4] and Na[Ch]+Li[6]R2+[6], respectively. The coexisting phyllosilicates do apparently not contain appreciable amounts of Li. According to powder IR-data, the analyzed water contents of the cordierites are dominantly of type II, and there is also little CO2. Their distortion indices are rather low (0.121–0.145) and so are their optic angles (2V=50-51°). Considering all eleven NaBeLi-cordierites known thus far there is a strong positive correlation between Na and (Be+Li) with a slope close to 1.0. However, there is virtually no correlation between Be and Li, their incorporation into cordierite depending on the local geochemical environment. A strong negative correlation exists between the distortion indices of the NaBeLi-cordierites and their Be contents. Li has a disturbing influence on this relationship, and the versus Na correlation is also statistically worse than versus Be.Deceased December 20, 1984  相似文献   

8.
Staurolite and corundum are found as inclusions in tourmaline in a talc-phlogopite-chlorite-albite chist near Mount Bernstein (71°37S, 163°07E), northern Victoria Land, Antarctica. These inclusions are interpreted as relics of a staurolite-talc-corundum-chlorite assemblage that was stable during an early stage in the metamorphic cycle and subsequently armored by tourmaline, probably during the middle stage. Pressures and temperatures during the middle stage are estimated to be 650–700°C and 5.5–6.4 kbar. The transition from the early to the middle stage represents a roughly isothermal decrease in pressure of 2–3 kbar. During a late retrograde stage (T=300–370°C, P=3–5 kbar), staurolite was partly replaced by a muscovitic aggregate containing clinozoisite, pumpellyite, and margarite.The staurolite is unusually Si-poor (26.77, 25.85 weight % SiO2 or 7.275, 7.091 Si per formula unit for 46 oxygens anhydrous), Al-rich (58.00, 57.85% Al2O3, 18.579, 18.702 Al), low in divalent cations (Fe+Mg+Mn+Zn=3.301, 3.560) and magnesian (atomic Mg/(Mg+Fe)=0.42, 0.40). Ion microprobe analysis of the first grain indicates about 0.2% Li2O (0.219 Li) is present. The following substitutions are proposed to explain the unusual chemistry of this staurolite (crystallographic site notation of Smith 1968, in bold letters): Al(Si)+Al(Al(3A,B))Si(Si)+Fe(Fe), Li(Fe)+Al(Al(3A,B))2 Fe(Fe), and 2 Al(Al(3A,B)) 3 Fe(Fe).According to a pressure-temperature diagram constructed by the method of Schreinemakers for the model system FeO-MgO-Al2O3-SiO2 (H2O in excess), the talc-staurolite assemblage should be stable only in quartz-free rocks at temperatures near 700° C and pressures of 8 kbar or more. The rarity of the staurolite-talc assemblage even in Mg-Al-rich rocks metamorphosed at the appropriate pressure-temperature conditions is attributed to the appearance of anthophyllite or, in Na2O-bearing rocks, gedrite. Orthoamphibole-cordierite and orthoamphibolekyanite assemblages with chlorite or corundum are incompatible with staurolite-talc±albite. In rocks lacking corundum and formed at pressures above the stability limit of cordierite, staurolite-talc may be metastable relative to orthoamphibole-kyanite, while in corundum-bearing rocks, staurolite-talc may appear under certain conditions, possibly at higher water activities than the orthoamphibole-kyanite assemblage.  相似文献   

9.
In the Aritayn Volcaniclastic Formation, the formation of zeolites is associated with the transformation of sideromelane into palagonite by reaction with percolating water in an open hydrological system. Three vertical zones are described, characterised by fresh sideromelane at the top (zone 1), palagonite-smectite in the middle (zone 2), and zeolites at the bottom (zone 3). Within zone 3, a phillipsite-chabazite sub-zone overlies a faujasite — phillipsite sub-zone. The paragenetic sequence (fresh sideromelane palagonite smectites (saponite montmorillonite) faujasite phillipsite chabazite natrolite calcite) resembles those described in the literature, except for the early formation of smectites in the Jordanian occurrences. Faujasite is more abundant in these zeolitic tuffs than at any other locality in the world that has yet been described, and the tuffs are considered to have excellent potential for beneficiation.  相似文献   

10.
Summary Eclogitic rocks are hosted within gneisses and migmatites of the Hercynian basement of NE Sardinia. They are characterized by two compositional layers: garnet-pyroxene rich-layers and amphibole-plagioclase layers. The former contain structural, mineralogical and compositional relics of eclogite facies re-equilibration. Four stages of evolution have been identified: an eclogite stage, a granulite stage and a retrograde amphibolite to greenschist stage. A possible pre(?)-eclogite stage is documented by inclusions of euhedral tschermakitic amphibole + zoisite within the core of garnet. This early stage was followed by an increase in pressure under which the eclogite climax developed (T up to 700 °C, P =13-15 kbar), as documented by omphacite inclusions towards the rim of garnet.Characteristic mineral reactions after the eclogitic stage are: omphacite diopside + plagioclase (symplectite) and garnet orthopyroxene + plagioclase. These reactions testify the presence of a granulite stage during which the peak of metamorphism was reached (T up to 870'C, P 10 kbar). The orthopyroxene cummingtonite + quartz and garnet + diopside hornblende + plagioclase (kelyphite) transformations indicate extensive amphibolite retrogression (T = 550650 °C, P = 3-7 kbar). Finally, actinolite and chlorite developed (greenschist stage) at falling temperature and pressure (T = 300-400 °C, P < 2-3 kbar).
Mehrstufige metamorphe Reequilibration eklogitischer Gesteine aus dem hercynischen Basement NE Sardiniens (Italien)
Zusammenfassung Eklogitische Gesteine kommen in Gneisen und Migmatiten des hereynischen Basements in NE Sardinien vor. Sie sind durch einen modalen Zweitagenbau von einerseits Granat-Pyroxen andererseits Amphibol-Plagioklas charakterisiert. In ersteren sind Relikte einer strukturellen, mineralogischen und mineralchemischen Reequilibration unter eklogitfaziellen Bedingungen enthalten. Vier Entwicklungstadien sind unterscheidbar: ein Eklogit-, ein Granulit-, sowie ein retrogrades Amphibolit- und Grünschieferstadium. Ein mögliches prä(?)-eklogitisches Stadium ist durch die Einschlüsse von tschermakitischem Amphibol + Zoisit in Granatkernen angedeutet. Auf dieses Frühstadium folgte, dokumentiert durch Omphaziteinschlüsse im Granatrandbereich, Druckzunahme und es wurden eklogitfazielle Bedingungen (T bis zu 700 °C, P = 13-15 kbar) erreicht.Charakteristische Mineralreaktionen nach der Eklogitbildung sind Omphazit Diopsid + Plagioklas (Symplektite) und Granat Orthoyroxen + Plagioklas. Diese Reaktionen belegen das Vorliegen eines Granulitstadiums, während dem der Metamorphosehöhepunkt (T bis 870°C, P 10 kbar) erreicht wurde. Die Umwandlungen von Orthopyroxen Cummingtonit + Quarz und Granat + Diopsid Hornblende + Plagioklas (Kelyphit) belegen eine intensive retrograde amphibolitfazielle Überprägung (T = 550-650°C, P = 3-7 kbar). Aktinolith und Chlorit (Grünschieferstadium) bildeten sich bei weiter fallenden Temperaturen und Drucken (T = 300-400 °C, P < 2-3 kbar).
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11.
Summary In 1961–63 the Czechoslovakian Geological Survey drilled a 1596 m deep borehole in the Sn-W-mineralized Cinovec (Zinnwald) granite cupola. The hole traversed zinnwaldite granite (ZG) to 730 m, then protolithionite granite (PG). The boundary between the two granites is a transition zone (TZ) about 10 m thick. The oxides of Nb, Ta and Ti, present in accessory amounts, are columbite, ilmenorutile, rutile and pyrochlore. The columbite occurs in both granites, but in the PG only below 1558 m depth. Its crystals are strongly zoned, the zoning representing variations in Nb/(Nb + Ta) on the one hand, and non-uniform distribution of W on the other. The columbite in the TZ is strongly enriched in W, up to 32.6 wt% WO3. The columbites with W < M4+ show the substitutions W6+ + M4+ 2(Nb, Ta)5+, where (M4+ = Ti, Sn, Th, U, Zr) and 6M4+ + 3M3+ 4Fe2+ 5(Nb, Ta)5+, where (M3+ = Sc, Y). In columbites with W > M4+, tungsten is introduced by the substitution W6+ + M4+ 2(Nb, Ta)5+, but also through the appearance of Fe3+ in the B site according to the replacement 2W6+ + Fe3+ 3(Nb, Ta)5+. The ratio Fe/(Fe + Mn + Ca) increases with depth, and Nb/(Nb + Ta) is higher in the PG.The ZG is characterized by the presence of ilmenorutile, which does not occur in the PG, where rutile contains at most only 4 wt% Nb2O5. Two types of substitution have been found in the ilmenorutile: Fe3+ + (Nb, Ta)5+ 2Ti4+; (Fe, Mn)2+ + 2(Nb, Ta)5+ 3Ti4-. For the ilmenorutiles studied, the ratio [Fe3+/(Fe, Mn)2+]at is near 1.AU- and Nb-rich phase, containing up to 36.2 wt% UO2, included in protolithionite, and missing from the ZG, has the composition of a defect pyrochlore, A2+ 2 5+(O6), and forms a solid solution with U4+B2 4+(O6]), where B4-= Ti, Si, Zr, Sn. Electron microprobe analyses indicate that this phase is strongly hydrated.The crystal chemistry of Nb-, Ta- and Ti-oxides in the Cinovec cupola reflects the complex geochemistry of its component granites and the interaction of the minerals with an F- and CO2-rich fluid phase. Among the thermodynamic parameters, fO2 plays a predominant role in the early evolutionary stages.
Résumé Un sondage profond (jusqu'à -1596m), a été réalisé en 1961–63 par le Service géologique tchécoslovaque, dans la coupole granitique, minéralisée en Sn-W, de Cinovec (Zinnwald), République tchèque. Ce sondage a recoupé un granite à zinnwaldite (ZG), relayé en profondeur (–730 m) par un granite à protolithionite (PG). Le contact entre ces deux granites est matérialisé par une zone de transition (TZ) puissante de 10 m environ. Les oxydes de Nb, Ta et Ti, présents en quantité accessoire, sont représentés par: columbite, ilménorutile, rutile et pyrochlore.La columbite apparaît tant dans ZG que dans PG, mais dans ce dernier uniquement dans la zone profonde (-1558.0 m). Ses cristaux sont fortement zonés. Le zonage reflète des variations du rapport Nb/(Nb + Ta) d'une part et une distribution hétérogène de W, d'autre part. La columbite de la zone de transition ZG-PG est très enrichie en W (jusqu'à 32.6 wt.~/ 0 W03). Les coiumbites à W < SM4+ présentent des substitutions W6+ + M4+ 2(Nb, Ta)5+, où (M44+ = Ti, Sn, Th, U, Zr) et 6M4+ + 3M3+ 4Fe2+ + 5(Nb, Ta)5-, où (M3+ = Se, Y). Dans celles à W > EM4+, outre la substitution W6+ + M4+ 2(Nb, T)5+, le tungstène est introduit grâce à l'apparition de Fe 3+ sur le site B suivant le schéma: 2W6+ + Fe3+ 3(Nb, Ta)5+. Le rapport Fe/(Fe + Mn + Ca) croit avec profondeur; celui Nb/(Nb + Ta) augmente dans PG.Le ZG est caractérisé par la présence de l'ilménorutile; par contre, celui-ci est absent dans PG, oú le rutile ne contient que 4 wt.% Nb205 au maximum. Deux types de substitution sont mis en évidence dans l'ilménorutile: Fe3+ + (Nb, Ta)5+ 2Ti4+; (Fe, Mn)2+ + 2(Nb, Ta)5+ 3Ti4+. Pour les ilménorutiles étudiés, le rapport [Fe3+/(Fe, Mn)2+]à, est proche de 1.Une phase riche en U (jusqu'à 36.2 wt.% UO2) et Nb, incluse dans la protolithionite et absente dans ZG, a composition d'un pyrochlore lacunaire A2+[B2 5+(06), formant une solution solide avec U4+E:B24+(O6), où B4+ = Ti, Si, Zr, Sn. Les analyses à la microsonde électronique indiquent que cette phase est fortement hydratée.La cristallochimie des oxydes de Nb, Ta et Ti dans la coupole de Cinovec reflète tant la complexité géochimique des granites qui la composent que l'interaction des minéraux avec une phase fluide riche en F et CO,. Parmi les paramètres thermodynamiques, fO2 joue un râle prépondérant lors des stades d'évolution précoces.
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12.
Zusammenfassung Es wurden Kalifeldspäte aus Orthogneisen, Paragneisen und Glimmerschiefern des westlichen Tauemfensters (Hohe Tauern, Tirol) mit optischen und röntgenographischen Methoden im Hinblick auf ihren Strukturzustand untersucht.Es zeigte sich, daß in den Randbereichen des Tauemfensters in Gesteinen der Grünschieferfazies weitgehend geordneter Mikroklin mit einem optischen Achsenwinkel 2 Vx 80°, Auslöschungswinkel Z (010)=15–20°, Doppelbrechung nz-nx= 0,0065, Triklinität=0,90-–0,95, ca. 0,88 Al auf T1O-Position und einem Ab-Gehalt von ca. 5 Gew.% auftritt. Dagegen wurden in Gesteinen der schwachtemperierten Amphibolitfazies des zentralen Bereichs Orthoklase bis intermediäre Mikrokline mit stark schwankenden optischen Eigenschaften, mit Triklinitäten zwischen 0 und 0,7, 0,8 bis 0,9 Al in T1-Positionen, 0,45–0,8 Al auf T1O und Ab-Gehalten von ca. 10 Gew.% festgestellt. Die Kalifeldspatkristalle zeigen ungleichmäßige Auslöschung mit Winkeln von Z (010) zwischen 0 und 15°, 2 Vx zwischen 50 und 75° und nz-nx=0,005 bis 0,006. Teilweise ist Zonarbau mit geringerer Triklinität am Kornrande erkennbar. Diese undulös auslöschenden Kalifeldspäte enthalten einzelne schmale Lamellen von maximal triklinem Mikroklin mit Z (010)=15–20° und nz-nx= 0,006–0,007.Die Grenze zwischen dem Verbreitungsgebiet von maximalem Mikroklin einerseits und Orthoklas bis intermediärem Mikroklin andererseits verläuft in den westlichen Hohen Tauern ungefähr konform mit der Albit-Oligoklas-Grenze (Morteani &Raase, 1974) und mit der aus Sauerstoff-Isotopen-Untersuchungen bestimmten 500° C-Isotherme (Hoernes &Friedrichsen, 1974).
The potassic feldspar in orthogneisses, paragneisses, and mica schists from the western Tauernfenster (Hohe Tauern, Tyrol) were studied by optical and X-ray methods with regard to their structural state and in relation to grade of metamorphism.In the peripheral region of the Tauernfenster in greenschist-facies rocks highly triclinic microcline occurs with an optic angle 2 Vx of about 80°, extinction angle Z (010) =15–20°, birefringence nz-nx=0.0065, triclinicity=0.90–0.95, approx. 0.88 Al in T1O-site, and an Ab-content of about 5 wt.%. In the central area with rocks of the low-grade amphibolite facies, on the other hand, orthoclase to intermediate microcline with highly variable optical properties, triclinicities in the range of 0–0.7, 0.8–0.9 Al in T1-sites, 0.45–0.8 Al in T1O-site, and an Ab-content of about 10 wt.% was recognized. The K-feldspar grains have nonuniform extinction Z (010) scattering in the range of 0–15°, 2 Vx in the range of 50–75°, and nz-nx= 0.005–0.006. Sometimes a zonal structure with lower triclinicity exists at the rim. These undulatory K-feldspar grains usually contain small lamellae of highly triclinic microcline with Z (010) =15–20° and nz-nx=0.006–0.007.From the occurrence of maximum microcline and of orthoclase to intermediate microcline in the Hohe Tauern area an isograd was defined that is approximately conformable with the albite-oligoclase isograd (Morteani &Raase, 1974) and with the 500° C isotherm based on oxygen isotope analyses (Hoernes &Friedrïchsen, 1974).
Résumé Les feldspaths potassiques d'orthogneiss, de paragneiss et de micaschistes de la Fenêtre des Tauern occidental (Hohe Tauern, Tirol) ont été étudiés du point de vue de leur état structural.Dans les roches du faciès schistes verts de la région périphérique de la Fenêtre des Tauern les microclines sont caractérisés par un angle des axes optiques 2 Vp =80°, un angle d'extinction ng (010)=15–20°, une biréfringence ng-np=0,0065, une triclinicité= 0,90–0,95, 0,88 Al dans le site T1O et par une teneur en albite d'environ 5%. Au contraire, dans les roches du faciès amphibolite à faible degré de la région centrale, ont été observées des orthoses allant à des microclines intermédiaires avec des propriétés optiques très variables, un degré de triclinicité de 0 à 0,7, 0,8–0,9 Al dans les sites T1, 0,45–0,8 Al dans T1O et avec une teneur en albite d'environ 10%.Les cristaux de feldspath montrent une extinction irrégulière avec des angles Z (010) variable de 0 à 15°, 2 Vp de 50 à 75° et ng-np=0,005–0,006.On peut voir quelquefois une structure zonée avec une triclinicité moindre au bord des cristaux. Ces feldspaths potassiques contiennent de minces lamelles de microcline à triclinicité maximum, avec ng (010)=15–20° et ng-np 0,006–0,007.La limite entre les régions à microcline maximum d'une part, et à orthose ou microcline intermédiaire d'autre part, suit, dans les Hohe Tauern, sensiblement l'isograde albite-oligoclase (Morteani &Raase, 1974) et, l'isotherme de 500° C telle qu'elle fut determinée les isotopes de l'oxygène (Hoernes &Friedrichsen, 1974).
, ( , ) ., 2 Vx80°, Z (010)=15–20°, nz–nx=0,0065, =0,90–0,95, 0,88 l T1O Ab 5 .-%. , 0 0,7, 0,8-0,9 1 T1 l 10 .-%. Z V (010) 0 15°, 2 Vx 50 75° nz–nx=0,005–0,006. . Z V (010) =15-20° nz–nx=0,006–0,007. , Morteani & Raase (1974) 500° , Hoernes & Friedrichsen (1974).
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13.
Summary Baotite occurs in the Garaoulére orebody, at Pierreftte, France, as an accessory mineral, included in alstonite and celsian, and associated with sphalerite, galena, pyrite, siderite and calcite in hydrothermal veins crosscutting calcareous, rutile-bearing, siltstones. Microprobe analyses revealed high W03 concentrations (up to 6 wt.%) in baotite. The empirical formula of W-rich baotite is Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073 Cr0.048Nb0.024)3.823 Si4.05O28Cl1.166. The excess of charges due to the presence of W6+ and Nb5+ is compensated by the introduction of M3+ (Fe, Al, Cr) into Ti-octahedra, by the appearance of Al in Si-tetrahedra (for W-poor baotite) and by the appearance of vacancies in Ti-octahedra (3Ti4 -> 2W6+ + and in Ba-sites (Ti4+ Ba2+ W6+, ). The unit-cell parameters of W-rich baotite are: a = 19.92(2), c = 5.930(8) Å. Niobium-rich baotites (Baiyun-Obo,Semenov et al., 1961; Karlstein,Nmec, 1987) are characterized by substitutions: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) and 2Ti4+, Ba2+ 2Nb5+, .
Wolfram führender Baotit von Pierrefitte, Pyrenäen, Frankreich
Zusammenfassung Baotit kommt in dem Garaoulére Erzkórper in Pierrefitte, Frankreich als ein akzessorisches Mineral in Einschlÿussen in Alstonit und Celsian vor. Er ist mit Zinkblende, Bleiglanz, Pyrit, Siderit und Calcit assoziiert. Diese Paragenese ist an hydrothermale Gänge gebunden, die kalkige rutil-führende Siltsteine durchsetzen. Mikrosondenanalysen zeigen hohe W03 Gehalte (bis zu 6 Gew.%) in Baotit. Die empirische Formel von wolfram-reichem Baotit ist: Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073Cr0.048Nb0.024)3.823 Si4.05O28Cl1.66. Der durch die Anwesenheit von W6+ und Nb5+ erforderliche Ladungsausgleich ergibt sich durch das Eintreten von M3+ (Fe, Al; Cr) in Ti-Oktaeder, und von Al in Si-Tetraeder (für W-armen Baotit) und schließlich durch das Erscheinen von Leerstellen in Ti-Oktaedern (3Ti4+ 2W6+ + und in Ba-Stellen (Ti4+, Ba` W6+, Die Zellparameter von ldW-reichem Baotit sind: a = 19.92(2), c = 5.930(8) Å. Niob-reiche Baotite (Baiyun-Obo, Semenov et al., 1961; Karlstein, Nmec, 1987) sind durch Substitutionen charakterisiert: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) und 2Ti4+, Ba2+ 2Nb5+, .
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14.
The compositional variations in epidotes, Ca2Al2(Fe3+, Al)-Si3O12(OH), from a prograde Mesozoic rock series in the Eastern Alps, Austria, are systematically related to metamorphic grade and the oxidation state of the rock. With increasing metamorphic grade the average composition of the zoned epidotes shifts to Fe3+-poorer compositions reflecting not only the effect of temperature and total pressure but also the concomitant decrease of the oxidation state of the rocks. Oxidized hematite-bearing assemblages are: 90 mole % Al2FeEp (greenschists) 70 mole % Al2FeEp (garnet amphibolites) 58 mole % Al2FeEp (eclogites); reduced sulfidebearing assemblages are: 42 mole % Al2FeEp (greenschists) 24 mole % Al2FeEp (garnet amphibolites) 23 mole % Al2FeEp (eclogites).A similar compositional evolution of the epidotes as in the spatial sequence of the samples can be observed within the single zoned crystals, reflecting the temporal changes of temperature, total pressure and oxygen fugacity during the prograde crystallization. The Fe3+-contents of core and rim decrease with increasing metamorphic grade and decreasing oxidation state. Generally the zoned epidotes consist of a Fe3+-rich core (90 to 63 mole % Al2FeEp) and a Fe3+-poorer rim (55 to 23 mole % Al2FeEp). Core and rim of the epidote crystals are separated by a compositional gap the extension of which is independent of the bulk rock composition, the oxidation state, and the mineralogical composition of the assemblages but becomes smaller with increasing metamorphic grade: 7253 mole % Al2FeEp (low grade greenschists, 400° C) 6355 mole % Al2FeEp (higher grade greenschists, 500° C), and 6055 mole % Al2FeEp (garnet amphibolites, 500–550° C). At the temperature conditions of the highest grade garnet amphibolites and eclogites (550° C) the compositional gap closes at a composition of 58 mole % Al2FeEp.The data presented thus confirm clearly the existence of an asymmetric miscibility gap in the monoclinic Al-Fe(III)-epidote solid solution series, which, for the first time, has been assumed by Strens (1964, 1965).A model is proposed that describes the prograde compositional evolution of the epidotes studied through the competing mechanisms of growth and diffusional Al-Fe3+ exchange and their dependence on metamorphic grade and oxidation state.  相似文献   

15.
Zusammenfassung Die Triasablagerungen Australiens wurden primär von zwei tektonischen Ereignissen beeinflußt: Von der permo-triadischen Hunter-Bowen-Orogenese am Ostrande des Kontinents und von Riftbewegungen, welche den Westrand des Festlandes erfaßten. Syneklisen entwickelten sich unmittelbar westlich der Orogenzone.Die Sedimente der Orogenzone wurden in Rand- und Vortiefen abgelagert, und umfassen meist untere und mittlere Trias. Es sind überwiegend fluviatile Ablagerungen, an deren Basis Rotsedimente auftreten. Kohleführende Schichten sind vom Ladin ab häufig. Auch Vulkanite sind weit verbreitet. Die Syneklisen zeigen eine ähnliche Tendenz, doch kamen in den westlichen Becken nur obertriadische Schichten zur Ablagerung.Am Westrand Australiens erstrecken sich die Triasvorkommen über die gesamte Küstenregion, vom Perth Becken bis zum Bonaparte Gulf. Ihr Auftreten ist an Gräben und Halbgräben gebunden, welche das im Perm eingeleitete Aufbrechen Gondwanas verstärkt fortsetzen.Die Sedimentation wird hier durch eine im frühen Skyth vom Norden vordringende Transgression eingeleitet. Im Anis einsetzende Regression führt zu paralischen Ablagerungsbedingungen, welche mehr oder minder für den Rest der Trias herrschten.Die geologischen Abläufe während der Trias haben zur Bildung von wichtigen Lagerstätten beigetragen. Tektogene Vorgänge der frühen Trias sind für die Bildung von Erzlagerstätten (Au, Ag, Pb, Zn, Cu, Sn) entlang der Ostküste verantwortlich. Bei weitem die wichtigste Rolle kommt der Trias Australiens jedoch in der Bereitstellung fossiler Energiequellen zu. Bauwürdige triadische Kohlevorkommen finden sich in Tasmanien, Queensland und Südaustralien. Erdgaslagerstätten gigantischer Dimensionen sind im Dampier Becken am Nordwest-Schelf nachgewiesen, doch liefert die Trias wichtige Kohlenwasserstofflagerstätten auch in Queensland und in Südaustralien.
Triassic deposition in Australia was controlled primarily by two tectonic events: The eastern margin of the continent was affected by the Permo-Triassic Hunter-Bowen-Orogeny, whereas rift movements were experienced along the west coast of Australia. Syneclises developed adjacent to the orogenic belt.Within the orogenic belt the sediments were laid down in foredeeps and intramontane grabens. They generally comprise the lower and middle Triassic and are composed dominantly of fluviatile deposits. Red beds occure in the lower parts of the sequences. From the Ladinian onwards coal measures developed. Volcanics are widely distributed in some of the northern basins. Similar depositional trends existed in the syneclises, but only upper Triassic strata were laid down along their western limit.On the western margin of Australia Triassic deposits extend along the entire coastal region from the Perth Basin to the Bonaparte Gulf. The Sediments were laid down in a complex taphrogen system which continued the distensional development, initiated in the Permian. Deposition began with a marine transgression which advanced from the north in the early Skythian. In the Anisian regression commenced and led to paralic environments which remained more or less dominant for the rest of the Triassic.Geologic events of the Triassic led to the formation of important economic deposits. Tectogenesis is thought to be responsible for development of some mineral deposits along the east coast. By far the most important role play various fossil fuel deposits contained within Triassic strata. Economic coal deposits of Triassic age accure in Tasmania, Queensland and South Australia. Giant gas fields have been discovered within Triassic sandstones of the offshore Dampier Basin of the Northwest Shelf. Other important hydrocarbon deposits have been found in the Triassic of Queensland and South Australia.
Résumé Les dépôts triasiques de l'Australie ont été influencés initialement par deux évènments tectoniques: l'orogenèse permotriasique de Hunter-Bowen sur le bord oriental du continent, et des mouvements suivant des fractures affectant la bordure ouest du continent. Des synéclises se sont développées immédiatement à l'ouest de la zone orogénique. — Les sédiments de la zone orogénique se sont déposés dans des zones de bordure et avantfosses, le plus souvent du Trias inférieur et moyen. Ce sont surtout des sédiments fluviatiles avec des sédiments rouges à la base. Les formations houillères sont fréquentes au commencement du Ladinien. Les volcanites sont largement répandues. Les synéclises montrent une tendance analogue; pourtant dans les bassins de l'ouest, seuls des sédiments du Trias supérieur se sont déposés. — Sur la bordure occidentale de l'Australie les occurrences triasiques se sont étendues sur toute la région côtière du bassin de Perth au golfe de Bonaparte. Leur présence est liée à des fossés et demi-fossés qui accentuent le Gondwana qui a débuté au Permien. — La sédimentation a débuté par une transgression qui vient du Nord, au début du Skythien. La régression qui a commencé à l'Anisien a conduit à des conditions sédimentaires paraliques, qui ont plus ou moins pedduré pendant le reste du Trias. — Les apports géologiques pendants le Trias ont contribué à la formation de gisements importants. Des mécanismes tectoniques du Trias inférieur sont responsables de la formation de gisements de minerais (Au, Ag, Pb, Zn, Cu et Sn) le long de la côte de l'Est. Le rôle de loin le plus important du Trias australien est sa contribution aux sources énergétiques fossiles. Des formations houillères triasiques exploitables se trouvent en Tasmanie, au Queensland et au South Australia. Des gisements de gaz naturel de dimensions «gigantesques» sont pouvées dans le bassin de Dampier, au nord-est du plateau continental; en outre le Trias fournit aussi des formations hydrocarburées importantes au Queensland et au South Australia.
: - Hunter-Bowen'a , . . , . , . . . , . . , , . . , . . (Au, Ag, Pb, Zn, Cu, Sn) . . , , — Dampier - , — .
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16.
The synthesis boundaries of the phase transformation; ++ in (Mg0.9, Fe0.1)SiO4, have been clarified at temperatures to 2000° C and pressures up to 20 GPa in order to synthesize single crystals of high quality. A single crystal of (Mg0.9, Fe0.1)2SiO4 was grown successfully to a size of 500 m. The crystal structure has been refined from single-crystal X-ray intensities. The ferrous ions prefer M1 and M3 sites to over the larger M2 site. The volume change of all the occupied polyhedra does not contribute to the decrease of total volume in the transformation; rather it tends to increase the bulk volume through the expansion of occupied tetrahedra. The volume reduction in the phase transformations is accounted for by unoccupied polyhedra, with the octahedra contributory 60% and the tetrahedra 40% to the V of the transition. The volume change in the transformation is caused also partly by the volume decrease of MO 6 (25%), partly the unoccupied tetrahedra (45%) and octahedra (30%).  相似文献   

17.
Late Precambrian (575–600 Ma) igneous activity in the North Eastern Desert of Egypt produced large volumes of compositionally bimodal magmas. A single composite dike was studied to further examine petrogenetic relationships between andesitic and rhyolitic melts. The dike consists of 1.5–2 m of andesite on either side of a 5–6 m wide rhyolite core. Contact relations indicate that the andesite and rhyolite simultaneously existed as porphyritic liquids. Wholerock Rb-Sr dating indicates an age of 591 Ma, but with considerable scatter. Andesite and rhyolite had similar initial87Sr/86Sr of 0.7032±2, indicating derivation from a low Rb/Sr source, either the upper mantle, very young upper crust, or depleted lower crust. The composition of the andesites on either margin cannot be distinguished; these are very similar to andesites of the Dokhan Volcanics of similar age. Correspondingly, the rhyolite is compositionally similar to the epizonal Pink Granites. This dike and others like it represent hypabyssal feeders for the extrusive and shallow intrusive members of the North Eastern Desert bimodal suite.Major and trace element studies of the dike rocks show no evidence of mixing. With the exception of the alkaline earths, there is no evidence of diffusional transport across the rhyolite-andesite contacts. REE patterns indicate that petrogenesis of the andesite must have left a garnetiferous residue: either 10% melting of LREE-enriched garnet lherzolite or 25% melting of eclogite, followed by a small amount of shallow fractionation. Petrogenesis of the rhyolites remains enigmatic. Partitioning of trace elements and different plagioclase compositions in andesite and rhyolite argue against an origin by liquid immiscibility. Major and trace element models indicate that the rhyolite formed by fractional crystallization of the andesite or by anatexis of young amphibolite-facies crust.
Zusammenfassung SpÄtprÄkambrische (575–600 Ma) magmatische AktivitÄt in der »North Eastern Desert« Ägyptens förderte gro\e Mengen bimodaler Magmen. Um die petrogenetischen Beziehungen zwischen andesitischen und rhyolitischen Schmelzen zu studieren, wurde ein einzelner, »bimodaler« Gang (composite dyke) untersucht.Der Gang besteht aus einem Rand von 1,5–2 m mÄchtigem Andesit auf beiden Seiten eines 5–6 m mÄchtigen Kernbereiches von Rhyolit. Die Kontaktbeziehungen zeigen, da\ Andesite und Rhyolite gleichzeitig als porphyritische Schmelzen existierten. »Whole-Rock« Rb-Sr Datierung ergab ein Alter von 591 Ma, jedoch mit einem erheblichen Fehler. Andesit und Rhyolith hatten Ähnliche initiale87Sr/86Sr VerhÄltnisse von 0.7032±2, die eine Herkunft aus Bereichen mit niedrigen Rb/Sr VerhÄltnissen erkennen lassen: Oberer Mantel, sehr junge obere Kruste, oder verarmte untere Kruste. Die Zusammensetzung der Andesite von den verschiedenen Seiten des Ganges ist nicht zu unterscheiden. Sie sind den Andesiten der Dokhan Vulkanite Ähnlich und etwa gleich alt. Entsprechend sind die Rhyolite den epizonalen rosa Graniten (»pink granite«) in der Zusammensetzung Ähnlich. Dieser Gang und andere gleich ihm stellen die Zufuhrspalten für die extrusiven und seichtintrusiven Magmatite der »North Eastern Desert« bimodalen Folge dar.Haupt- und Spurenelemente der Ganggesteine zeigen keine Anzeichen einer Mischung. Mit Ausnahme der Erdalkalien gibt es keinen Hinweis auf eine Diffusion der Elemente über den Rhyolit-Andesit Kontakt. Die Verteilung der Seltenen Erden deutet auf ein granatführendes Residuum bei der Petrogenese der Andesite: entweder10% Aufschmelzen von Granat-Lherzolit, angereichert an leichten Seltenen Erden, oder 25% Aufschmelzen von Eklogit, gefolgt von geringer Fraktionierung unter niedrigem Druck.Die Petrogenese der Rhyolite bleibt unklar. Die Verteilung der Spurenelemente und die unterschiedliche Plagioklas-Zusammensetzung in Andesit und Rhyolith sprechen gegen eine Entstehung aus unvermischbaren Schmelzen. Modelle basierend auf Haupt- und Spurenelementen deuten darauf hin, da\ der Rhyolit entweder durch fraktionierte Kristallisation des Andesits entstand oder durch Anatexis junger Kruste im Bereich der Amphibolit-Fazies.
Résumé L'activité magmatique au Précambrien supérieur (575–600 Ma) dans le »North Eastern Desert« d'Egypte a engendré de grandes quantités de magmas bimodaux. De manière à préciser les relations entre fusions andésitiques et rhyolitiques, un dyke composite a été étudié.Ce dyke est constitué d'un coeur rhyolitique de 5 à 6 m, encadré de deux bordures andésitiques de 1,5 à 2 m. Les contacts indiquent que ces deux roches ont coexisté sous la forme de liquides porphyriques. Une datation Rb-Sr sur roche totale donne un âge de 591 Ma, mais avec une approximation importante. L'andésite et la rhyolite ont un mÊme rapport initial de 0,7032±2, indiquant une source à faible rapport Rb/Sr: manteau supérieur, croûte supérieure jeune ou croûte inférieure appauvrie. Les compositions des deux bordures andésitiques sont identiques et très semblables à celle des andésites de mÊme âge du complexe volcanique du Dokhan. De mÊme, la rhyolite a une composition semblable à celle des granites roses épizonaux. Ce dyke et d'autres du mÊme type représentent les voies d'alimentation des termes extrusifs et intrusifs superficiels de la série bimodale du »North Eastern Desert«.L'étude des éléments majeurs et en traces ne montre aucun mélange entre les roches du dyke. A l'exception des alcalino-terreux, il n'existe aucune indication de diffusion des éléments à travers le contact rhyolite — andésite. La distribution des terres rares montre que la genèse de l'andésite doit avoir laissé un résidu grenatifère: soit une lherzolite à grenat enrichie en terres rares légères et représentant moins de 10% de taux de fusion, soit une éclogite (jusqu'à 25% de taux de fusion) suivie d'un léger fractionnement à basse pression.La pétrogenèse de la rhyolite reste obscure. La répartition des éléments en traces et la différence de composition du plagioclase entre l'andésite et la rhyolite plaident contre une origine par immiscibilité. Les modèles tirés des éléments majeurs et en traces indiquent comme origine pour la rhyolite soit la cristallisation fractionnée de l'andésite, soit l'anatexie de matériaux crustaux jeunes dans les conditions du facies des amphibolites.
, « - » . . 5–6 , 1,5–2 . , , . « », Rb/Sr, 591 , . 87Sr/86Sr 0,7032 ± 2, : , , . ; Dokhan . (pink granite). , , , , - «- ». , - . - / . , , : 10% - , , 25% , . . . , , , , , .
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18.
A mullion structure is described from a several meter thick amphibolite from the Precambrian bedrock of south-eastern Norway. The mullion axes deviate about 60–700 from the fold axis defined in the amphibolite by the constructed intersection of foliation planes. The fold axis is also reflected in the lineated hornblende grains. The orientation of the mullion axes is parallel to the trace of the amphibolite foliation on the mullioned surface. It is concluded that the mullions were formed on a discordant surface (probably a fracture surface) in responce to movement along the intersecting foliation planes at the same time as the hornblende lineation was developed.
Zusammenfassung Aus dem südostnorwegischen präkambrischen Grundgebirge wird aus einem mehrere Meter mächtigen verfalteten Amphibolit eine Mullion-Struktur beschrieben. Die Achsen der Mullions weichen 60–700 von der Faltenachse ab, welche aufgrund der Biotitfoliationen im Amphibolit konstruiert werden konnte. Diese Faltenachse wird auch von den linearen Hornblenden nachgezeichnet. Es wird angenommen, daß sich die Mullions auf einer diskordanten Fläche (wahrscheinlich einer Bruchfläche) gebildet haben. Auf dieser Fläche verlaufen die Mullion-Achsen parallel der Spur der Amphibolit-Foliation. Die Mullions entstanden gleichzeitig mit den linearen Hornblenden infolge einer Bewegung entlang der sich schneidenden Foliationsebenen.
Résumé Une structure en «mullion» a été étudiée dans des amphibolites, d'âge Précambrien, en Norvège. Les mullions proviennent d'une couche discordante, qui a été déformée avec les amphibolites. On observe que les axes des mullions font une angle de 60 à 70 degré avec la linéation (prismes de hornblende) qui est parallèle aux axes des plis; les axes des mullions et la linéation sont situés dans le plan de la foliation des amphibolites.
Mullion-Struktur - . 60–70 , . . , (, ). . .
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19.
Silica-deficient rocks in which sapphirine coexists with cordierite, gedrite, chondrodite, spinel, corundum and phlogopite in various parageneses, occur in association with cordierite-garnet-sillimanitebearing granulitic gneisses in a Precambrian metamorphic terrain displaying amphibolite-granulite transition facies. Brucite coexists with spinel and corundum and its unusual stability in this environment has been attributed to its significant fluorine content. Kornerupine occurs as armoured relics within cordierite in one sample of the sapphirine-spinel-cordierite-phlogopite-bearing rock. Sapphirines (X Mg 0.77 to 0.92) plot near the 793 composition.X Mg varies in the order: chondrodite and brucite>gedrite>cordierite >phlogopite>sapphirine>spinel.The consistent topology of the observed mineral assemblages with reference to the system MgO-FeO-Al2O3-SiO2-H2O, systematic partitioning of Mg and Fe in the coexisting phases, and textural relations are in accord with attainment of chemical equilibrium during the regional metamorphism. The sequence of metamorphic reactions has been deduced as a function of changing MgO/(MgO+FeO) ratio in the bulk composition and it has been shown that the topology in the SiO2-(FeO+MgO)-Al2O3 diagram for more magnesian compositions is consistent with experimental data in the system MgO-SiO2-Al2O3-H2O. The stable occurrence of the spinel-cordierite and spinel-sillimanite joins in less magnesian bulk compositions suggests that these tie lines are stable to higher pressures and lower temperatures respectively as compared to the Fe-free synthetic system.Using experimental and theoretical data on garnet-cordierite, garnet-biotite, garnet-plagioclase and orthopyroxene-clinopyroxene equilibria, PT conditions have been estimated to be 750 °±50 °C/ 5±0.5 Kb for the thermal peak of metamorphism.It is suggested that the unusual bulk composition of the sapphirine-bearing rocks viz. higher Al2O3, MgO and MgO/(MgO+FeO) and lower SiO2, Na2O and CaO compared to the parent cordierite-bearing granulitic gneisses may be attributed to partial melting and removal of granitic melt. This is in agreement with the variation of oxides in the restites and parent rock. The restites consisted of the assemblage cordierite-spinel—corundum which then reacted to form sapphirine. This reaction, which in the synthetic Fe-free system is confined to extremely low-pressures (300 bars), is likely to occur at higher pressures with MgFe substitution.  相似文献   

20.
In previous work, relationsships between carbonate petrographic features and geochemical parameters were used in the development of a sedimentary model for Hauptdolomit. It was found useful to categorize the various facies subtypes into eight main facies units which correspond to environments ranging from supratidal to subtidal.Especially significant for stratigraphy and paleogeography are recurring, calcareous, subtidal intercalations (eastern Lechtal Alps), which interfinger with dolomitic to slightly calcareous transitional facies including bituminous marls (Seefeld facies). The latter facies is interpreted to be of lower intertidal to near-shore subtidal origin, because of its lateral and vertical association with subtidal facies on the one hand and with typical intertidal, dolomitic facies on the other hand.Three stratigraphic subdivisions (Lower Hd., Middle Hd., Upper Hd.) may be distinguished by correlating transgressional-regressional sequences.The Middle Hd./Upper Hd. transgression is especially useful for paleogeographic reconstructions. A shallow tongue-shaped lagoon encroached from the Dachstein area into the Lechtal Alps. It is partially obscured tectonically by the Inntal nappe. The lagoonal outline is accentuated by the transitional facies belt (subtidal to lower intertidal) which includes Seefeld facies.
Zusammenfassung In früheren Arbeiten wurde ein Sedimentationsmodell des Hauptdolomits mit Hilfe von karbonatpetrographischen Merkmalen und geochemischen Parametern entwickelt. Dabei war eine Gliederung der verschiedenen Faziestypen in acht Haupteinheiten hilfreich, welche Gezeiten-bis Lagunenmilieus (supratidal to subtidal) entsprechen.Besonders signifikant für Stratigraphie und Paläogeographie sind wiederkehrende, kalkige, lagunäre Zwischenschaltungen (östliche Lechtaler Alpen), welche sich mit einer dolomitischen bis schwach kalkigen Übergangsfazies einschließlich bituminösen Mergeln verzahnen (Seefelder Fazies). Wegen ihrer lateralen und vertikalen Verbindung mit lagunärer Fazies einerseits und typisch dolomitischer Watt-Fazies andererseits, stellen wir die Seefelder Fazies in den Bereich Niederwatt bis küstennahe Lagune (lower intertidal to near shore subtidal).Durch Korrelation von Transgressions-/Regressions-Folgen können drei stratigraphische Unterteilungen unterschieden werden (Unterer, Mittlerer und Oberer Hauptdolomit).Die Mittlerer/Oberer Hauptdolomit-Transgression ist besonders nützlich für paläogeographische Rekonstruktionen. Eine seichte zungenförmige Lagune dehnte sich ausgehend vom Dachsteingebiet bis in die Lechtaler Alpen aus. Sie ist teilweise tektonisch von der Inntaldecke überfahren. Der lagunäre Umriß wird hervorgehoben durch einen Gürtel mit Übergangs-(subtidal to lower intertidal) und Seefeldfazies.
Résumé Dans les travaux antérieurs on a développé un modèle sédimentaire de la Hauptdolomit à l'aide de caractères pétrographiques des carbonates et de paramètres géochimiques. Il s'est trouvé utile de grouper les différents types de facies en huit unités principales, qui correspondent à des milieux de marée jusqu'à ceux de lagune (supratidal à subtidal). - Sont particulièrement significatifs pour la stratigraphie et la paléogéographie les retours d'intercalations calcaires et lagunaires qui s'engrènent avec un facies de transition dolomitique à faiblement calcaire avec inclusions de marnes bitumineuses (facies de Seefeld). A cause de leurs connexions latérales et verticales avec des facies lagunaires dolomitiques d'une part, et avec des facies de Watt dolomitiques typiques, les facies de Seefeld sont interprétés comme des milieux de bas-fond inférieur allant jusqu'à des lagunes proches de la côte (lower intertidal to near-shore subtidal). Par la voie de corrélation de transgression/régression, on peut distinguer trois subdivisions stratigraphiques (Hauptdolomite inférieure, moyenne, supérieure). Pour la reconstruction paléogéographique, la transgression de la Hauptdolomite moyenne/supérieure se présente comme extrêmement utile. Une lagune peu profonde, en forme de langue, s'épanouissait à partir de la région de Dachstein jusqu'aux Alpes de la vallée de la Lech. Elle a été en partie recouverte tectoniquement par la nappe de la vallée de l'Inn. Le contour lagunaire est souligné par une ceinture des facies de transition (subtidal to lower intertidal), qui inclut aussi les facies de Seefeld.
- . 8 , - (supratidal to subtidal). , ( ), ( ). - , , (lower intertidal to near shore subtidal). : , . . . . (subtidal to lower intertidal).
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