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1.
采用SWAT模型方法对滁州花山水文实验流域进行了径流与氮素耦合模拟,探讨了流域土地利用对氮素输移的影响。构建了花山水文实验流域SWAT模型,采用2008年1月~2013年12月的降雨、径流等数据对径流模型进行率定和验证,以2012年5月~2013年12月的氮浓度监测数据对氮负荷模型进行验证。利用所建立的模型对现状土地利用情形和土地利用变化情景假设下进行了径流与氮素耦合模拟,计算了现状和不同土地利用情景假设下流域的径流深和氮负荷。结果表明:汛期的氮流失量占全年氮流失的比重较大,每年的汛期是控制氮流失的关键时期;旱地的氮流失潜力较水田大,林地的增加对氮负荷具有一定的消减作用;控制氮肥的使用,加强水土保持能力,可以有效减少流域氮负荷。 相似文献
2.
Understanding the linkage between temporal climate variability and groundwater nitrate concentration variability in monitoring well records is key to interpreting the impacts of changes in land-use practices and assessing groundwater quality trends. This study explores the coupling of climate variability and groundwater nitrate concentration variability in the Abbotsford-Sumas aquifer. Over the period of 1992–2009, the average groundwater nitrate concentration in the aquifer remained fairly steady at approximately 15 mg/L nitrate-N. Normalized nitrate data for 19 individual monitoring wells were assessed for a range of intrinsic factors including precipitation, depth to water table, depth below water table, and apparent groundwater age. At a broad scale, there is a negative correlation between nitrate concentration and apparent groundwater age. Each dedicated monitoring well shows unique, non-uniform cyclical variability in nitrate concentrations that appears to correspond with seasonal (1 year) cycles in precipitation as well as longer-period cycles (~5 years), possibly due to ENSO (El Niño Southern Oscillation) or the Pacific North American (PNA) pattern. These precipitation cycles appear to influence nitrate concentrations by approximately ±30 % of the critical concentration (10 mg/L NO3–N). Not all wells show direct correlation due to many complex local-scale factors that influence nitrate leaching including spatially and temporally variable nutrient management practices and soil/crop nitrogen dynamics (anthropogenic and agronomic factors). 相似文献
3.
Nitrate is a common pollutant in surface water and groundwater of agricultural areas. It is essential to monitor this pollutant in groundwater, especially when it is used for drinking purposes without treatment. The present study was carried out in an intensively irrigated area which forms a part of Nalgonda district, Andhra Pradesh, India where groundwater meets all the water needs of the rural population living in this area. The objective was to assess the spatiotemporal variation in the concentration of nitrate in groundwater and soil. Based on the analysis of 496 groundwater samples collected from 45 wells over a period of 2 years from March 2008 to January 2010 by sampling every 2 months, it was observed that groundwater in 242 km2 of the total 724 km2 area had nitrate above the maximum permissible limit of 45 mg/l for drinking purposes. Nitrate concentration in groundwater showed a positive relation with potassium, chloride, and sulfate, indicating their source from fertilizers. Reasons for the high concentration of nitrate in domestic areas were the dumping of animal wastes and leakage from septic tanks. The pH of the soil samples showed that most of the area had basic soil. Apart from pH, organic carbon, available phosphorous, available potassium, ammoniacal nitrogen, and nitrate nitrogen were also analyzed in the 97 soil samples. 相似文献
4.
桂林甑皮岩岩溶地下水硝酸盐来源与转化 总被引：1，自引：0，他引：1
峰林平原是人类活动和居住的密集区，也是岩溶地下水系统的主要径流、排泄地段，地下水资源丰富。随着城市化的发展，地下水硝酸盐污染问题日渐突出。为研究桂林甑皮岩岩溶地下水硝酸盐来源与转化，分别于2018年10月、2019年2月、3月和4月采集地下水样，利用常规水化学及氮氧同位素技术识别硝酸盐来源与转化。结果表明:甑皮岩地下水中NO3-浓度在0~19.523 mg?L-1，δ15N-NO3-和δ18O-NO3-分别在-0.17‰～45.12‰和-5.82‰~16.47‰。硝酸盐氮氧同位素数据表明，甑皮岩地下水硝酸盐来源主要为粪便及污废水，少量来自降雨中的NH4+和土壤有机氮。受岩溶介质不均一性的控制，甑皮岩地下水中NO3-浓度、δ15N-NO3-和δ18O-NO3-均表现出明显的空间变异性。甑皮岩地下水硝酸盐的转化过程复杂，受控于季节和岩溶介质不均一性，表现为旱季以反硝化为主，雨季则以硝化过程为主。厘清硝酸盐来源与转化为治理甑皮岩地下水硝酸盐污染提供一定的科学依据。 相似文献
5.
Nitrate in groundwater and N circulation in eastern Botswana 总被引：1，自引：0，他引：1
Nitrate pollution due to deep leaching from pit latrines has caused water supply wells in eastern Botswana to exceed health limits concerning nitrate. It was deduced from the estimated intake of salt and protein by the population that, as an average, about 10 percent of the human nitrogen excretion is leached to the groundwater. This fraction was also found in southern India, where on-the-ground excretion is customary. The nitrogen circulation in general in the savanna ecosystem is not appreciably affected in spite of a large livestock density. Overall nitrate leaching is in the order of 1.5 kg N/ha/y, similar to that in another semiarid area in southern India. However, in India, there seems to be a more diffuse areal leaching from agriculture as well as from villages.Measures to minimize the nitrate leaching could be to plant deep-rooted trees adjacent to pit latrines or to use latrines that separate the urine from the faces for a more near-surface infiltration facilitating plant uptake. Measures to minimize leaching will also lessen the rick for bacterial pollution of the groundwater. 相似文献
6.
High contents of nitrate in groundwater, ranging up to 1,500 mg/l, have been found. High concentrations are more common in village wells than in irrigation wells situated in the fields. The losses of nitrogen from the soil zone through deep leaching into the groundwater are small (260 kg N/km2); however, due to a small net infiltration (29 mm/year), the median content in groundwater still approaches the permissible limit of 50 mg/l NO 3 ? . In villages about 10–20% of the nitrogen from excreta are leached into the groundwater. Mineralization of soil nitrogen during a dry period, followed by heavy rains, caused extremely high contents of nitrate in groundwater. 相似文献
7.
安徽淮北平原浅层地下水硝酸盐分布特征及污染来源分析 总被引：4，自引：0，他引：4
地下水中硝酸盐污染是当今世界许多国家或地区普遍关注的问题,研究其分布特征意义重大。文章在水文地质调查基础上,通过取样分析,研究了安徽省淮北平原浅层地下水硝酸盐分布状况和污染来源,结果表明:硝酸盐含量在东北地区较高,在一定范围超过饮用水限制标准(88mg/L),最高达432.56mg/L,研究区南部较低;NO3-与Cl-的同步增长关系表明其主要来源为生活污物和人畜排泄物,且该地区的农田肥料和污水灌溉很可能是另一主要来源;根据R型因子分析发现研究区内浅层地下水水质主要受到三方面的影响,即自然作用、自然与人为的混合作用和人为作用,且贡献率分别为39%、28%、15%。而人为作用中硝酸盐的相关度最高,因此建议加强研究区内人类活动中硝酸盐氮污染控制。 相似文献
8.
A major mode of transmission of Cryptosporidium parvum, a widespread waterborne pathogen, is via contaminated drinking and recreational waters. Oocyst transport to surface water
can occur by deposition of manure directly in the water or by wash off in surface runoff. Oocyst transport to groundwater
is less straightforward and requires that the oocysts move through soil and bedrock to reach the water table. The purpose
of this study was to determine the relative concentration and infectivity of C. parvum oocysts released from manure and leached through columns of undisturbed, macroporous karst soil. Modeling the fate of oocysts
in this system over time can provide baseline data for evaluating real world events. Substantially more oocysts leached from
undisturbed soil columns than disturbed soil columns. Oocyst survival studies using BALB/c neonatal suckling mice showed that
about 85% of oocysts were infective at the beginning of leaching experiments. The oocyst infectivity decreased to about 20%
after 12 weeks of leaching from soil columns maintained at 10°C. Cool (10°C) temperatures appear to increase survivability
and maintain infectivity of many oocysts for 3 months or longer. Cool temperatures also appear to increase rates of release
of oocysts from manure and leaching through soil. This study demonstrated that leaching is an important mechanism of oocyst
transport in karst soils where infiltration capacities are high and long, continuous macropores exist. Karst groundwater systems
might be especially vulnerable to contamination by leached oocysts, because of the prevalence of shallow soils and rapid groundwater
movement. Oocysts leaching from soils into the epikarst could accumulate and remain viable for months until hydrological conditions
are right for flushing the oocysts into the conduit flow system. 相似文献
9.
Cemeteries are known to be associated with soil and groundwater pollution from contaminants in coffin materials. However, possible contamination from embalming fluids such as formaldehyde has not been investigated. Formaldehyde is a recognised carcinogen, which is primarily toxic after inhalation, skin contact or ingestion. Although it is maintained that formaldehyde breaks down into innocuous compounds, this has not been established at sites such as cemeteries where there is a continuous addition of formaldehyde-preserved bodies, sometimes on a daily basis. It is also not confirmed whether different soil types and environmental conditions affect the leaching of formaldehyde into groundwater resources. This study comprises a laboratory study of the leaching potential of formaldehyde through different soils and environmental conditions. Twenty-seven containers with taps were filled with either sandy, silty or clayey soils. Samples of burial materials and a cloth saturated with formalin were buried within each column. These were exposed to conditions simulating that of the environment, i.e. (1) different temperatures, (2) heavy or prolonged rainfall and (3) using either acidic or slightly acid water. Leachate samples were collected every 2 weeks for a period of 24 weeks and analysed for formaldehyde using acid titration. The results showed that most formaldehyde percolated through the soil between week 6 and week 14 of interment, with a greater amount being leached from sand. Neither temperature nor pH affected the amount of formaldehyde leached; however, conditions simulating heavy rainfall facilitated leaching. Although a total of only 3% of the initial amount of formaldehyde mobilised, concentrations of up to 15 mg/L formaldehyde were recorded on two occasions, exceeding the tolerable concentration recommended by the World Health Organisation. 相似文献
10.
Gernot Klammler Hans Kupfersberger Gerhard Rock Johann Fank 《Environmental Earth Sciences》2013,69(2):663-678
The aquifer Westliches Leibnitzer Feld, Austria, is a significant resource for regional and supraregional drinking water supply for more than 100,000 inhabitants, but the region also provides excellent agricultural conditions. This dual use implicates conflicts (e.g., non-point source groundwater pollution by nitrogen leaching), which have to be harmonized for a sustainable coexistence. At the aquifer scale, numerical models are state-of-the-art tools to simulate the behavior of groundwater quantity and quality and serve as decision support system for implementing groundwater protecting measures. While fully and iteratively coupled simulation models consider feedback between the saturated and unsaturated zone, sandy soil conditions and groundwater depths beneath the root zone allow the use of a unidirectional sequential coupling of the unsaturated water flow and nitrate transport model SIMWASER/STOTRASIM with FEFLOW for the investigation area. Considering separated inputs of water and nitrogen into groundwater out of surface water bodies, agricultural, residential and forested areas, first simulation results match observed groundwater tables, but underestimate nitrate concentrations in general. Thus, multiple scenarios assuming higher nitrogen inputs at the surface are simulated to converge with measured nitrate concentrations. Preliminary results indicate that N-input into the groundwater is strongly dominated by contributions of agricultural land. 相似文献
11.
以田间试验为基础,分别用平衡模型和动力学模型计算了3个小区农田水分渗漏量和氮素淋失量,并对其结果进行了比较,平衡模型计算的水分渗漏量为191～202mm,氮素淋失量为38～63kg·N/hm2;而用动力学模型计算的水分渗漏量为168～234mm,氮素淋失量为27～53kg·N/hm2。造成结果差异的主要原因是:平衡模型没有考虑向上的水流和非饱和流;而动力学模型同时考虑了二者。动力学模型需要大量的田间实测资料,主要应用于农田氮素循环、定量评价水氮资源利用率、优化水肥管理措施等方面。平衡模型仅需要非常少的资料,就能够得到农田水分渗漏量和氮素淋失量,这对精度要求不太高的农田水肥管理来说,不失为一种好方法。 相似文献
12.
西山岩溶水作为北京市重要的供水水源,在区域水文地质调查过程中发现西山岩溶水补给区一些样品硝酸盐浓度偏高,然而其周围岩溶水中硝酸盐浓度并未见明显变化（浓度均值为18.81 mg/L）,具点状硝酸盐源特征。岩溶含水层中硝酸盐分布特征和影响因素具有重要的研究意义。文章利用岩溶水化学和同位素分析结果研究了岩溶水硝酸盐分布和来源,利用IsoSource软件计算各来源的贡献率。结果表明:军庄—永丰屯径流区和军庄—古城—玉泉山泉径流区岩溶水中硝酸盐主要来源于生活废水、土壤有机氮矿化和大气沉降,贡献率值分别为37.1%、36.3%、26.6%;潭柘寺—四季青岩溶水中硝酸盐在潭柘寺补给区有养殖场废水下渗影响,径流区中硝酸盐含量低并发生反硝化降解作用。永定河水源硝酸盐不是岩溶水硝酸盐的主要来源。研究成果对西山岩溶水中硝酸盐的控制具有重要参考价值。 相似文献
13.
Determining the genetic origin of nitrate contamination in aquifers of Northern Gujarat,India 总被引：2，自引：0，他引：2
Kumari Rina P. S. Datta Chander Kumar Singh Saumitra Mukherjee 《Environmental Earth Sciences》2014,71(4):1711-1719
Over the past decades, the Gujarat state of India experienced intensive agricultural and industrial activities, fertilizer consumption and abstraction of groundwater, which in turn has degraded the ground water quality. Protection of aquifers from nitrate pollution is a matter of prime concern for the planners and decision-makers. The present study assessed the spatial and temporal variation of groundwater nitrate levels in areas with different land use/land cover activities for both pre- and post-monsoon period. The pre-monsoon nitrate level (1.6–630.7 mg/L) in groundwater was observed to be higher as compared to the post-monsoon level (2.7–131.7 mg/L), possibly due to insufficient recharge and evaporation induced enrichment of agrichemical salts in groundwater. High HCO3 ? (200–1,000 mg/L) as well as SO4 2?/Cl? (0.111–0.992) in post-monsoon period provides a favourable environment for denitrification, and lower the NO3 levels during the post-monsoon period. The K vs NO3 scatter plot suggests a common source of these ions when the concentration is <5 mg/L, the relationships between different pollutants and nitrate also suggest that fertilizers and other sources, such as, animal waste, crop residue, septic tanks and effluents from different food processing units present in the area can be attributed to higher nitrate levels in the groundwater. Appropriate agronomic practices such as application of fertilizers based on calibrated soil tests and proper irrigation with respect to crop can minimize the requirement for inorganic fertilizers, which can bring down the cost of cultivation considerably, and also protect groundwater from further degradation. 相似文献
14.
目前针对喀斯特山区及平原过渡带天然河流硝酸盐的来源识别与追踪的研究鲜有报道,也较少考虑湿润气候区反季节性干旱气候特征对硝酸盐迁移规律的影响.以汉江二级支流泉水河流域为例,分析了从源头喀斯特地区、中间过渡区、平原区地表水和地下水硝酸盐含量及组成的空间变化,采用氮氧同位素识别地表水和地下水硝酸盐来源,利用SIAR模型定量计算各污染源的贡献率.结果表明:土壤有机氮、污水粪便、化肥和大气沉降对地下水硝酸盐来源贡献占比分别为31.4%、20.0%、29.6%和19.0%,对地表水硝酸盐来源的比例分别为32.0%、30.0%、25.0%和13.0%,污水粪便对地表水硝酸盐贡献比例较地下水增高;坝上水样因水体较大,自净能力较强,受污水粪便的影响很小（仅为9.0%）,坝上水样硝酸盐土壤有机氮、大气沉降和化肥的贡献占比分别为43.0%、11.0%和37.0%.枯水期河水主要由地下水缓慢补给,无地表径流汇入,土壤有机氮为河流主要的硝酸盐来源,河流中下游更易受人类活动影响,生活污水和化肥对河流硝酸盐贡献增大. 相似文献
15.
Nitrogen isotope studies of nitrate contamination of the thick vadose zones in the wastewater-irrigated area 总被引：1，自引：0，他引：1
Cui-Yun Zhang Sheng Zhang Mi-Ying Yin Lin-Na Ma Ze He Zhuo Ning 《Environmental Earth Sciences》2013,68(5):1475-1483
The objective of this study was to investigate natural abundance and the distribution of nitrogen isotopic compositions to assess denitrification in two ~30 m thick vadose zones beneath the different land uses in the wastewater-irrigated area located in southern Shijiazhuang, China. Sediment samples were collected from cores of boreholes drilled in the vegetable growth plot and the wastewater-irrigated farmland for analyses of nitrogen isotopes, physical and chemical properties, respectively. The profile of borehole A drilled in the vegetable growth plot only applied animal wastes had lower δ15N values of mean +7.5 ‰ in the upper vadose zone, but higher values of mean +10.9 ‰ in the lower vadose zone. δ15N values in each part varied little with depth, indicating no or little denitrification occurred in the deep vadose zone below the soil zone. The profile of borehole B drilled in the wastewater-irrigated farmland had low δ15N values of mean +5.7 ‰ below the soil zone and little variations of δ15N values with depth, indicating no or little denitrification occurred in the deep vadose zone below the soil zone. This was also verified by consistent variations of NO3 ? and SO4 2? contents with Cl? contents. Our results suggested most of leachable nitrate from the soil zone was hardly subjected to biological attenuation into groundwater. 相似文献
16.
Daniele Pittalis Raul Carrey Stefania Da Pelo Alberto Carletti Riccardo Biddau Rosa Cidu Fulvio Celico Albert Soler Giorgio Ghiglieri 《Hydrogeology Journal》2018,26(6):2021-2040
Agricultural coastal areas are frequently affected by the superimposition of various processes, with a combination of anthropogenic and natural sources, which degrade groundwater quality. In the coastal multi-aquifer system of Arborea (Italy)—a reclaimed morass area identified as a nitrate vulnerable zone, according to Nitrate Directive 91/676/EEC—intensive agricultural and livestock activities contribute to substantial nitrate contamination. For this reason, the area can be considered a bench test for tuning an appropriate methodology aiming to trace the nitrate contamination in different conditions. An approach combining environmental isotopes, water quality and hydrogeological indicators was therefore used to understand the origins and attenuation mechanisms of nitrate pollution and to define the relationship between contaminant and groundwater flow dynamics through the multi-aquifer characterized by sandy (SHU), alluvial (AHU), and volcanic hydrogeological (VHU) units. Various groundwater chemical pathways were consistent with both different nitrogen sources and groundwater dynamics. Isotope composition suggests a mixed source for nitrate (organic and synthetic fertilizer), especially for the AHU and SHU groundwater. Moreover, marked heterotrophic denitrification and sulfate reduction processes were detected; although, for the contamination related to synthetic fertilizer, the attenuation was inefficient at removing NO3? to less than the human consumption threshold of 50 mg/L. Various factors contributed to control the distribution of the redox processes, such as the availability of carbon sources (organic fertilizer and the presence of lagoon-deposited aquitards), well depth, and groundwater flow paths. The characterization of these processes supports water-resource management plans, future actions, and regulations, particularly in nitrate vulnerable zones. 相似文献
17.
M. M. Matinzadeh J. Abedi Koupai A. Sadeghi-Lari H. Nozari M. Shayannejad 《International Journal of Environmental Science and Technology》2017,14(3):563-576
The excessive loss of soil nitrogen through drainage losses causes different environmental problems. The depth and spacing drain of drains play an important role in the quality and quantity of discharged drainage into the environment. In this paper, a simple but comprehensive model using system dynamic approach for water cycle and nitrogen dynamics was used to simulate the effect of drain depth and spacing on nitrate and ammonium losses in a sugarcane agro-industrial company. Twenty-four scenarios were modeled including the combination of four different drain depths and six drain spacing to compare the effect of drain depth and spacing on the nitrogen uptake by plant, denitrification, net mineralization, the amount of ammonium losses through runoff, nitrate and ammonium losses through drainage water, the sum of excessive water, the stress day index and the relative yield. The results indicated that optimal drainage system density is obtained in the depth of 1.1 m and spacing of 80 m, in a way that the total drainage losses would be reduced up to an acceptable level. The optimum designing of the drainage systems according to environmental criteria can control nitrogen pollution load at farm level and can therefore have appropriate results both in terms of economic and environmental considerations. 相似文献
18.
The nitrate concentration in groundwater is associated with the nitrate content in soil. However, nitrate is not in the current list of soil security standards, which makes it difficult to study nitrate pollution in soil. Because the nitrate content in the soil may affect human and ecological health, the evaluation of nitrate pollution in the soil and its current situation are both particularly important. In this study, the background value of nitrate in soil in the proluvial fan agriculture irrigation district of Hunhe River in northeast China was estimated by analyzing the factors influencing the vertical and horizontal, spatial distribution characteristics of soil nitrate. Evaluation and analysis were also carried out on the pollution of soil by nitrate using the single factor index evaluation method along with the Nermero pollution index evaluation method. Results of the study showed that the estimated background value of soil nitrate in this area was 2.58 mg/kg, and the soil was moderately polluted by nitrate. 相似文献
19.
云南滇池流域西芹种植区不同施肥条件下的地下水环境氮素污染 总被引：1，自引：1，他引：0
通过野外田间实验,研究了高量施肥处理、低量施肥处理、不施肥处理以及空白对照裸地等不同施肥处理条件下土壤水中各种形态氮的时空分布情况,探讨了地下水环境中氮素在不同施肥处理条件下的迁移转化特征.结果表明,在各种处理条件下,土壤水中硝态氮质量浓度随深度的增大而减小,而亚硝态氮与铵态氮质量浓度在剖面上的变化幅度较大,这种变化主要受土壤水氧化还原电位的影响.硝态氮随时间的变化趋势在4个处理区表现各异:在高量施肥处理区,各层位的土壤水中硝态氮质量浓度总体上呈增大趋势;在低量施肥处理区,硝态氮受作物生长和灌溉的影响呈拍岸浪式向下迁移;在不施肥处理区和空白对照裸地处理区,由于表层土壤中硝态氮背景值较高(0～30 cm处土壤硝态氮平均质量分数达到15.59 g/kg),灌溉水的下渗也导致硝态氮向下迁移.高量施肥处理区和空白对照裸地处理区土壤水的对比表明,施肥可促进0.6～1.5 m深处土壤的反硝化作用,从而增大这些层位土壤水中亚硝态氮和铵态氮的质量浓度. 相似文献
20.
土壤无机氮素的损失主要是铵氮的挥发损失和硝氮的反硝化和淋失.土壤水分和氮素含量的增加,都将增加氮肥淋失的潜在威胁,如处置不当,获得高产可能需要以环境的污染为代价.节水条件下土壤无机氮素的损失量有所减少,但是氮素利用效率也同时受到了土壤水分状况的限制.探讨了作物产量、氮素损失和农业生产要素(水分、氮素)实际投入量之间的关系,建立了节水条件下土壤氮素损失和环境评价概念型模型,通过在北京水利科学研究所永乐店灌溉试验站3年的试验资料对模型进行了参数求解及校验. 相似文献