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1.
Abstract— Cumulate eucrite, noncumulate eucrite, and diogenite meteorites are considered to have come from the crust of one (or similar) parent asteroid. Howardites are regarded as regolith breccias of eucrites and diogenites, and polymict eucrites are regarded as polymict breccias of eucrites. These polymict breccias show many textural and chemical features. In order to gain a better understanding of the origin of polymict breccias and the origin of their components, we investigated four polymict breccias, Yamato (Y)-791439, Y-791192, Y-82009, and Y-82049 with a scanning electron microscope (SEM) equipped with a chemical mapping system, and by electron probe microanalysis (EPMA). We analyzed all pyroxene grains with chemical maps, classified them by chemical composition, and observed their chemistry and mineralogy in detail. The characteristics of pyroxenes suggest that the polymict breccias were generated by gathering locally ordinary eucrites and cumulate eucrites. The chemical-evolutionary features of the pyroxenes (such as homogenization, chemical zoning, and exsolution lamellae) suggest that there were at least two long annealing events and one short (or low-temperature) annealing event, separated by mixing events. Local heterogeneity on the asteroidal crust is also suggested.  相似文献   

2.
Abstract— Mineralogical information recovered from the howardite, eucrite, diogenite (HED) meteorites was employed to reconstruct the history of the parent body and relate it to 4 Vesta. These interpreted crustal evolution processes were then compared to the expected geological features on the surface of a likely proto-planet, 4 Vesta. The original crustal materials of the HED parent body were preserved as mineral grains and lithic clasts, but in many eucrites, Fe/Mg ratios in pyroxenes were homogenized by diffusion after crystallization. The crystallization trend of the protocrust has been deciphered by (1) examining monomict and crystalline samples and using their mineralogical and chemical information to formulate a sequence of crystallization and cooling trends; and by (2) reconstructing the original crust prior to cratering events from lithic clasts and mineral fragments in polymict breccias such as howardites and polymict eucrites. Mineral components are identical, both in the individual HED and in polymict breccias, and no remnants of primitive materials were preserved in the polymict breccias. A layered crust model reconstructed from such breccias consists of an upper crust with extrusive lava-like eucrites that have been brecciated and metamorphosed, diogenite mantle, and cumulate eucrites of varying thickness between them. This model can be used to explain the surface geological features of Vesta observed from the Hubble space telescope. A large crater with diogenitic orthopyroxene at the crater floor is consistent with the deepest diogenitic layer of the layered crust model; and an underlying olivine layer is expected from early crystallized olivine in the crystal fractionation model. The old terrain of eucritic surface materials of Vesta can be howardites, polymict eucrites, or regolith-like eucrites produced from eucrites extruded and impacted on the surface. Partial melting models of eucrites seem to be favored by the rare-earth element (REE) chemistry and experimental studies. Unfortunately, partial melting models have not demonstrated how the HED parent body is converted to a layered crust without producing any metamorphosed primitive material in the layered crust. The origin of cumulate eucrites with systematic variation of textures and chemistries of pyroxene can be explained by the layered crust model with excavation and mixing of trapped liquid. Discovery of basaltic materials with Na-rich plagioclase and augite in iron meteorites, which are the products of partial melting, suggests that eucrites may be unique to a body that underwent large-scale differentiation and metamorphism.  相似文献   

3.
Abstract— We have investigated 10 new specimens of the Millbillillie eucrite to study its textures and mineral compositions by electron probe microanalyser and scanning electron microscope. Although originally described as having fine-grained texture, the new specimens show diversity of texture. The compositions (Mg/Fe ratios) of the host pigeonites and augite lamellae are homogeneous, respectively, in spite of the textural variation. In addition to their chemical homogeneity, pyroxenes in coarse and fine-grained clasts are partly inverted to orthopyroxene. Chemical zoning of plagioclase during crystal growth is preserved. This eucrite includes areas of granulitic breccias and impact melts. Large scale textures show a subparallel layering suggesting incomplete mixing and deposition of impact melt and lithic fragments. An 39Ar-40Ar age determination for a coarse-grained clast indicates a strong degassing event at 3.55 ± 0.02 Ga. We conclude that Millbillillie is among the most equilibrated eucrites produced by thermal annealing after impact brecciation. According to the classification of impact breccias, Millbillillie can be classified as a mixture of granulitic breccias and impact melts. The last significant thermal event is characterized by network-like glassy veins that run through clasts and matrices. Consideration of textural observations and requirements for Ar-degassing suggests that the 39Ar-40Ar age could in principle date either the earilier brecciation and annealing event or the event which produced the veins.  相似文献   

4.
The subgroups within the basaltic achondrite suite are defined using the structural criterion of Wahl (1952). The ‘monomict’ meteorites are samples of a single lithology while the polymict meteorites are those containing two or more lithologies. The ‘monomict’ subgroups eucrites, cumulate eucrites and diogenites are subdivided into both brecciated and unbrecciated meteorites. The polymict achondrites sample a petrological-compositional continuum that contains both mafic and ultramafic rock types and may be subdivided into several groups. Two groups of polymict basaltic achondrites, the polymict eucrites and howardites are separated using an arbitrarily defined criterion. The recommended criterion is based on the amount of magnesian ortho-pyroxenite (diogenite) component in the meteorite. Howardites contain more than 10% and polymict eucrites contain less than 10%. The criteria proposed (perhaps with minor variations), appear to reconcile the ambiguities caused by the polymict eucrites. These meteorites, using earlier structural criteria, are howardites, but using mineralogical-chemical criteria are eucrites. As a subgroup of the polymict achondrites, their relationship with the howardites is clear, and the preservation of the term ‘eucrite’ in their name highlights their modal affinity to the monomict eucrites.  相似文献   

5.
Abstract— The polymict eucrite Macibini is a fragmental breccia, predominantly composed of eucritic materials with minor proportions (maximum 2 vol%) of diogenitic material. Hence, it is intermediate between the Yamato‐74159‐type polymict eucrites, which contain negligible amounts of magnesian orthopyroxene, and the howardites. The present study provides mineralogical and bulk compositional data for the meteorite breccia and for six clasts. These clasts include both volcanic and igneous rocks and a variety of impact‐generated rocks. A broad range of degrees of postcrystallization metamorphism affected these materials before the final aggregation of the breccia. Clast A is a fragment of unequilibrated eucrite with subophitic texture. The edges of the zoned pyroxenes in this clast are composed of a host of Fe‐rich augite containing vermicules (blebs) and lamellae composed of a mixture of Fe‐rich olivine and silica. Similar features occur as fragments in lunar breccias and are attributed by some workers to the breakdown of pyroxferroite, an Fe‐rich pyroxenoid. However, textures and compositions of these augite‐olivine‐silica intergrowths in clast A suggest that, in this case, they are the result of decomposition in a series of steps of Fe‐rich subcalcic augite. Among the fragments of impact‐generated material in Macibini is clast 2, an earlier‐formed clastic breccia that was lithified before being broken apart and included in the meteorite breccia. Clast 3 is an impact‐melt breccia that is composed of rock and mineral fragments in a devitrified groundmass. Clast C is also an impact‐melt breccia that has a coarser‐grained, hornfelsic groundmass that resulted from extensive metamorphism after formation.  相似文献   

6.
Abstract— According to a currently popular model for petrogenesis on the howardite, eucrite, and diogenite (HED) parent asteroid, the diogenites are not comagmatic with most eucrites but instead formed in separate orthopyroxenite-dominated plutons. This model can be tested for consistency with mass balance for MgO and FeO, assuming the overall diogenite/(diogenite + eucrite) ratio, d, of the parent asteroid is at least comparable to the average d for the eucrite + diogenite dominated howardite regolith breccias. Average mg# (=MgO/[MgO + FeO]) is much lower for eucrites, especially noncumulate eucrites, than for diogenites. Unless the diogenite parent magmas eventually produced a large proportion of low-mg# residual basalt and gabbro (RBG), the implied initial magma's mg# is vastly higher than that of any noncumulate eucrite. Starting from a source previously depleted by putative primary eucrite genesis, melt mg# can be estimated as a function of the exchange reaction KD and degree of melting. Using several very conservative assumptions (e.g., assuming that the total [MgO + FeO] concentration is nearly the same in the nascent melt as in the residual solids), the degree of melting required to yield a melt with mg# high enough to satisfy mass balance, without implying an RBG component that accounts for >50% of all eucrites, is an implausibly high 60–80 wt%. The separate orthopyroxenitic plutons (SOP) model also seems inconsistent with the uniform density of melts across the diogenite-eucrite compositional spectrum (2.77–2.82 g/cm3), which implies that diogenitic magmas should have been as capable as eucrites of extruding to form lavas. This difficulty cannot be reduced by simply assuming that later-formed magmas were systematically both more plutonic and more MgO-rich than earlier ones, because the plutonic cumulate eucrites equilibrated with melts systematically lower in mg# than noncumulate eucrites. Conceivably, the bulk mg# of the asteroid's silicate system was increased between primary-melt eucrite genesis and SOP diogenite genesis by graphite-fueled reduction of FeO. However, the graphite oxidation process generates a huge proportion of gas, which would have enhanced the buoyancy of the nascent diogenite-parent magmas, thus exacerbating the difficulty of achieving the implied high degrees of partial melting. To avoid these difficulties but still form most eucrites as rapidly cooled extrusives, I propose the NERD (noncumulate eucrites as extruded residua of diogenites) model. In this model, the diogenites form as early cumulates from a large magma system (probably a global “magma ocean”) that yields a large proportion of eucritic melt as residuum. This residual melt zone undergoes relatively little crystallization during a period when it is episodically tapped to produce extrusions, dikes and sills of rapidly cooled noncumulate eucrites. Slight (～5–10%) porosity in the nascent eucritic crust keeps it marginally buoyant over the residual melt zone. The common thermal metamorphism of noncumulate eucrites results from baking by superjacent flows during the episodic venting of the melt zone. The NERD model's greatest advantage is that it does not require implausibly high degrees of localized melting in the mature stages of igneous evolution of the HED asteroid.  相似文献   

7.
We have done petrologic and compositional studies on a suite of polymict eucrites and howardites to better understand regolith processes on their parent asteroid, which we accept is (4) Vesta. Taking into account noble gas results from companion studies, we interpret five howardites to represent breccias assembled from the true regolith: Elephant Moraine (EET) 87513, Grosvenor Mountains (GRO) 95535, GRO 95602, Lewis Cliff (LEW) 85313, and Meteorite Hills (MET) 00423. We suggest that EET 87503 is paired with EET 87513, and thus is also regolithic. Pecora Escarpment (PCA) 02066 is dominated by melt‐matrix clasts, which may have been formed from true regolith by impact melting. These meteorites display a range in eucrite:diogenite mixing ratio from 55:45 to 76:24. There is no correlation between degree of regolith character and Ni content. The Ni contents of howardite, eucrite, and diogenites (HEDs) are mostly controlled by the distribution of coarse chondritic clasts and metal grains, which in some cases resulted from individual, low‐velocity accretion events, rather than extensive regolith gardening. Trace element compositions indicate that the mafic component of HED polymict breccias is mostly basalt similar to main‐group eucrites; Stannern‐trend basaltic debris is less common. Pyroxene compositions show that some trace element‐rich howardites contain abundant debris from evolved basalts, and that cumulate gabbro debris is present in some breccias. The scale of heterogeneity varies considerably; regolithic howardite EET 87513 is more homogeneous than fragmental howardite Queen Alexandra Range (QUE) 97001. Individual samples of a given howardite can have different compositions even at roughly 5 g masses, indicating that obtaining representative meteorite compositions requires multiple or large samples.  相似文献   

8.
Dawn has recently revealed that the surface of Vesta is heterogeneously covered by polymictic regoliths represented by mixtures of howardite, eucrite, and diogenite (HED) meteorites. Mixing relations of the HED suite are examined here using a new computational statistical approach of independent component analysis (ICA). We performed eight‐component ICA (Si, Ti, Al, Cr, Fe, Mn, Mg, and Ca) for 209 HED bulk‐rock compositions. The ICA results indicate that the HED bulk‐rock compositions can be reduced into three independent components (IC) and these IC vectors can reasonably explain compositional variation, petrographic observations, and the mixing relations of the HED suite. The IC‐1 vector represents a eucrite variation that extends from cumulate eucrite toward main‐group (MG) and incompatible‐element enriched eucrites. The IC‐2 vector represents a compositional variation of howardites that extends from diogenites to MG‐eucrites, indicating the well‐known two‐component mixing trend of diogenite and eucrite. The IC‐3 vector represents a compositional variation defined by diogenites and olivine‐bearing diogenites, suggesting mixing of olivine and orthopyroxene. Among the three ICs, the diogenite‐eucrite mixing trend IC‐2 is most statistically robust and dominates the compositional variations of the HED suite. Our ICA study further indicates that the combination of only three elements (Mg, Si, and Fe) approximates the eight‐component ICA model, and that the limited number of resolvable γ‐ray spectra obtained by the Dawn mission possibly discriminates olivine lithologies from the olivine‐free regolith breccias on the surface of Vesta.  相似文献   

9.
Abstract— Available evidence strongly suggests that the HED (howardite, eucrite, diogenite) meteorites are samples of asteroid 4 Vesta. Abundances of the moderately siderophile elements (Ni, Co, Mo, W and P) in the HED mantle indicate that the parent body may have been completely molten during its early history. During cooling of a chondritic composition magma ocean, equilibrium crystallization is fostered by the suspension of crystals in a convecting magma ocean until the crystal fraction reaches a critical value near 0.80, when the convective system freezes and melts segregate from crystals by gravitational forces. The extruded liquids are similar in composition to Main Group and Stannern trend eucrites, and the last pyroxenes to precipitate out of this ocean (before convective lockup) span the compositional range of the diogenites. Subsequent fractional crystallization of a Main Group eucrite liquid, which has been isolated as a body of magma, produces the Nuevo Laredo trend and the cumulate eucrites. The predicted cumulate mineral compositions are in close agreement with phase compositions analyzed in the cumulate eucrites. Thus, eucrites and diogenites are shown to have formed as part of a simple and continuous crystallization sequence starting with a magma ocean environment on an asteroidal size parent body that is consistent with Vesta.  相似文献   

10.
Abstract— The 1.2 μm band in near‐infrared spectra of pyroxenes results from Fe2+in the M1 crystallographic site. The distribution of Fe and Mg between the M1 and M2 sites is in part a function of the cooling rate and thermal history of a pyroxene. Combining near‐infrared and Mössbauer spectra for a series of compositionally controlled synthetic Mg, Fe, Ca pyroxenes, we quantify the strength of the 1.2 μm band as a function of Fe2+in the M1 site. Near‐infrared spectra are deconvolved into component absorptions that can be assigned to the M1 and M2 sites using the modified Gaussian model. The relative strength of the 1.2 μm band is shown to be directly related to the amount of Fe2+in the M1 site measured by Mössbauer spectroscopy. The strength of the 1.2 μm band relative to the combined strengths of the 1.2 and 2 μm bands, or the M1 intensity ratio, is calculated for 51 howardite, eucrite, and diogenite (HED) meteorites. Diogenites and cumulate eucrites exhibit the lowest M1 intensity ratios, consistent with their formation as slowly cooled cumulates. Basaltic eucrites exhibit a large range of M1 intensity ratios, all of which are consistently higher than the diogenites and cumulate eucrites. This example illustrates how the M1 intensity ratio can be a used as a tool for characterizing the cooling history of remotely detected pyroxene‐dominated rocks.  相似文献   

11.
Abstract– This work describes two newly discovered eucrite breccias: three presumably paired meteorites, all named Northwest Africa (NWA) 6105, and NWA 6106. For each meteorite, major‐ and minor‐element compositions of minerals were determined using the electron microprobe. Pyroxene Fe‐Mn co‐variations and bulk‐rock oxygen isotope compositions confirm their classification as eucrites. Variations in mineral compositions and textures are attributed to differences in clast types present (i.e., basaltic or cumulate eucrite). The pyroxene compositions support the hypothesis that samples NWA 6105,1; 6105,2; and 6105,3 are paired polymict eucritic breccias, whereas sample NWA 6106 is a monomict basaltic eucritic breccia. Two‐pyroxene geothermometry yields temperatures too low for igneous crystallization. The variation in temperatures among samples suggests that metamorphism occurred prior to brecciation.  相似文献   

12.
New data are used to confirm the positive correlation between Mg and Cr in howardites and eucrites, and the identity of the Mg/Cr ratio in the two meteorite groups is established, provided Chaves is treated as an anomalous howardite. Macibini, usually classed as a eucrite, has higher contents of Mg and Cr than all but the cumulate eucrites; the suggestion is made, on the basis of its polymict character, the wide compositional range of its constituent clasts, and its bulk chemistry, that it should be re-classified as a howardite. The Mg-Cr relationship in diogenites is one of almost constant Mg but extremely variable Cr. The “average diogenite” plots fairly close to the trend established for the howardites and eucrites, indicative of the genetic link between these three meteorite classes. The silicate fractions of nine mesosiderites studied do not show a close coherence of Mg and Cr. With the exception of Patwar, they contain more Cr than howardites and eucrites, and exhibit greater variation of Cr relative to Mg. The general lack of clear inter-element trends in these silicate fractions suggests that they had a more complex origin and evolution than the silicates of the achondrites. Preliminary results of quantitative computer modeling of major and trace elements in the eucrites indicate that about 32 percent fractional crystallization of a eucritic liquid of the composition of Sioux County yields a residual liquid similar to Nuevo Laredo; the cumulate produced has the approximate composition of the cumulate eucrite Moama. These results are in agreement with the model developed by Consolmagno and Drake (1977), using the rare earth elements, for a corresponding stage in the solidification of an initial eucritic liquid produced by equilibrium partial melting of the source region of the parent body (Stolper, 1977). Plotting of the Ti concentrations of the meteorites studied against their Fe/Fe+Mg ratios supports Stolper's idea that the eucrites and the Mg-rich achondrites do not lie on the same liquid line of descent, and shows that the mesosiderite silicates do not conform to either trend.  相似文献   

13.
Abstract— The Yamato nakhlites, Y‐000593, Y‐000749, and Y‐000802, were recovered in 2000 from the bare icefield around the Yamato mountains in Antarctica, consisting of three independent specimens with black fusion crusts. They are paired cumulate clinopyroxenites. We obtained the intercumulus melt composition of the Yamato nakhlites and here call it the Yamato intercumulus melt (YIM). The YIM crystallized to form the augite rims, the olivine rims and the mesostasis phases in the cumulates. The augite rims consist of two layers: inner and outer. The crystallization of the inner rim drove the interstitial melt into the plagioclase liquidus field. Subsequently, the residual melt crystallized pigeonites and plagioclase to form the outer rims and the mesostasis. Three types of inclusions were identified in olivine phenocrysts: rounded vitrophyric, angular vitrophyric, and monomineralic augite inclusions. The monomineralic augite inclusions are common and may have been captured by growing olivine phenocrysts. The rounded vitrophyric inclusions are rare and may represent the composition of middle‐stage melts, whereas the angular vitrophyric inclusions seem to have been derived from fractionated late‐stage melts. Glass inclusions occur in close association with titanomagnetite and ferroan augite halo in phenocryst core augites and the assemblages may be magmatic inclusions in augites. We compared the YIM with compositions of magmatic inclusions in olivine and augite. The composition of magmatic inclusions in augite is similar to the YIM. Phenocrystic olivines contain exsolution lamellae, augite‐magnetite aggregates, and symplectites in the cores. The symplectites often occur at the boundaries between olivine and augite grains. The aggregates, symplectite and lamellae formed by exsolution from the host olivine at magmatic temperatures. We present a formational scenario for nakhlites as follows: (1) accumulation of augite, olivine, and titanomagnetite phenocrysts took place on the floor of a magma chamber; (2) olivine exsolved augite and magnetite as augite‐magnetite aggregates, symplectites and lamellae; (3) the overgrowth on olivine phenocrysts formed their rims, and the inner rims crystallized on augite phenocryst cores; and finally, (4) the outer rim formed surrounding the inner rims of augite phenocrysts, and plagioclase and minor minerals crystallized to form mesostasis under a rapid cooling condition, probably in a lava flow or a sill.  相似文献   

14.
The Howardite–Eucrite–Diogenite (HED) suite is a family of differentiated meteorites that provide a unique opportunity to study the differentiation of small bodies. The likely parent-body of this meteorite group, (4) Vesta is presently under study by the Dawn mission, scrutinizing its surface in the visible and NIR infrared range. Here, we discuss how well the magmatic trends observed in HED might be retrieved from NIR spectroscopy, by studying laboratory spectra of 10 HED meteorites together with spectra from the RELAB database. We show that although an exsolution process did occur for most eucrites (i.e. decomposition of a primary calcic pyroxene into a high-Ca and low-Ca pyroxene), it does not affect the “bulk pyroxene” trend retrieved from the location of the pyroxene crystal field bands (Band I with a maximum of absorption around at about 1 μm and Band II around 2 μm). Absolute values of the chemical composition appears however to deviate from the expected chemical composition. We show that mechanical mixture (i.e. impact gardening) will produce a linear mixing in the pyroxenes band position diagram (Band I position vs Band II position). This diagram also reveals that howardite are not pure mixtures of an average eucrite and average diogenite. Because asteroid surfaces are expected to show topography, we also study the effect of observation geometry on the NIR spectra of an eucrite and a diogenite by measuring the bi-directional reflectance spectra from 0.4 to 4.6 μm. Results show that these meteorites tend to act as forward scatterers, leading to a decrease of integrated band area (relative to the continuum) at high phase angles. The position of the two strong crystal field bands shows only small variability with observation geometry. Retrieval of the magmatic trends from the Band I vs Band II diagram should not be affected by observation geometry effects. Finally we performed NIR reflectance measurement on olivine diogenites. The presence of olivine can be suggested by using the Band Area Ratio vs Band I diagram, but this phase might affect the retrieval of pyroxene composition from the position of Band I and Band II.  相似文献   

15.
The Yamato (j), (k), (l), and (m) meteorites collected from near the Yamato Mountains in December, 1973, are respectively an H-4 and L-5 chondrite, a howardite, and an L-5 chondrite. Yamato (l), the howardite, is a polymict breccia of diogenite and eucrite clasts. Olivine in the chondrites ranges in composition from Fo75 to Fo80, whereas in the howardite, where it is rare, the composition is about Fo60. Pyroxenes in the chondrites are mostly orthopyroxenes and (En83), while the pyroxenes in the howardite are more complex, comprising orthopyroxene, pigeonite, augite, and rare clinohypersthene (in the order of decreasing abundance), with the range from En80 to En37. They form a definite trend, probably formed by the fractional crystallization of the parental magma of the achondrite, and later subjected to exsolution phenomena during the slow cooling. Plagioclase is high-temperature oligoclase in the chondrites, and anorthite in the howardite. Maskelynitization is sometimes observed. Other shock effects are also observed. Opaque phases consist mostly of nickel-iron, troilite, chromite, and rarely ilmenite. Intergrowth of these minerals are common. The accessory minerals comprise quartz, cristobalite, apatite, spinel, and rare uranium-bearing minerals. The bulk composition and genetic significance are discussed.  相似文献   

16.
Abstract– A few relatively unbrecciated olivine‐rich diogenites consist of an equilibrium assemblage of olivine and magnesian orthopyroxene (harzburgite). More common diogenites with smaller amounts of olivine are breccias containing two distinct orthopyroxenes—one magnesian and one ferroan. These diogenites are mixtures of a harzburgite lithology that is more magnesian, with the “normal” orthopyroxenite lithology that is ferroan and may contain small amounts of plagioclase. Both lithologies likely formed by fractional crystallization in multiple plutons emplaced within the crust of asteroid 4 Vesta. Minor element trends in orthopyroxenes indicate that these plutons exhibited a range of compositions. We propose a revised taxonomy for the HED (howardites, eucrites, and diogenites) suite where all ultramafic samples are referred to as diogenites. Within this group, the prefixes dunitic, harzburgitic, and orthopyroxenitic are used to distinguish diogenites consisting of more than or equal to 90% olivine, olivine + orthopyroxene, and more than or equal to 90% orthopyroxene, respectively. The prefix polymict is used to describe brecciated mixtures of any of these rock types. The recognition that olivine is a significant phase in some diogenites is consistent with spectral interpretations of olivine in a deeply excavated crater on Vesta, and has important implications for the bulk composition and petrogenesis of that body.  相似文献   

17.
We present global lithological maps of the Vestan surface based on Dawn mission's Visible InfraRed (VIR) Spectrometer acquisitions with a spatial sampling of 200 m. The maps confirm the results obtained with the data set acquired by VIR with a spatial sampling of 700 m, that the reflectance spectra of Vesta's surface are dominated by pyroxene absorptions that can be interpreted within the context of the distribution of howardites, eucrites, and diogenites (HEDs). The maps also partially agree with the ground and Hubble Space Telescope observations: they confirm the background surface being an assemblage of howardite or polymict eucrite, as well as the location of a diogenitic‐rich spot; however, there is no evidence of extended olivine‐rich regions in the equatorial latitudes. Diogenite is revealed on the Rheasilvia basin floor, indicating that material of the lower crust/mantle was exposed. VIR also detected diogenites along the scarp of Matronalia Rupes, and the rims of Severina and a nearby, unnamed crater, and as ejecta of Antonia crater. The diogenite distribution is fully consistent with petrological constraints; although the mapped distribution does not provide unambiguous constraints, it favors the hypothesis of a magma ocean.  相似文献   

18.
Trace element concentrations in pyroxene, plagioclase, and olivine were measured in five diogenite breccias previously identified as containing distinct harzburgitic (ol+opx) and orthopyroxenitic (opx) lithologies (dimict). Three samples show two distinct populations of pyroxene trace element abundances, supporting their classification as dimict. These three meteorites show increases in Y, Yb, and HREE concentrations from harzburgitic to orthopyroxenitic pyroxenes, supporting the hypothesis that the lithologies are related through fractional crystallization whereby harzburgite olivine and pyroxene crystallized from the magma first followed by orthopyroxenite pyroxene. Depletions in LREE and Eu concentrations in the orthopyroxenitic lithology are most likely due to equilibration with LREE and Eu‐rich phases, likely plagioclase, which is found primarily in that lithology. Two samples do not show evidence supporting a dimict classification. Large pyroxene trace element variation in one sample indicates that it is polymict, while uniform trace element distribution in the other suggests that it may be a monomict breccia.  相似文献   

19.
Monticello is a new howardite similar to Malvern in that it contains abundant (15%) glass fragments. These fragments show a range of compositions from olivine-normative to quartz-normative. Like Kapoeta, it contains pyroxene grains that range up to highly magnesian compositions, Fs16. Because their pyroxenes are more magnesian than those occurring in diogenites, Monticello and Kapoeta are exceptions to the simple two-component mixing model in which howardites are considered to be mechanical mixtures of fragmented eucrites and diogenites. Monticello also contains clasts of what appear to be a cumulate eucrite and a non-cumulate eucrite, as well as a radiating pyroxene chondrule from a chondrite. Monticello is a regolith breccia containing more evolved components than are usually considered in eucrite-diogenite genesis models. As such, it supports those models that involve reworking of a complex parent body crust rather than straightforward partial melting of primitive chondritic parent material.  相似文献   

20.
Abstract– We have done bulk rock compositional analyses (INAA, ICP‐MS) and petrologic study of a suite of diogenite meteorites. Most contain orthopyroxenes with mg#s of 70.6–79.0. Meteorite Hills (MET) 00425 is magnesian (mg# of 83.9). Lewis Cliff (LEW) 88011 contains orthopyroxene grains of varying mg# (76.3–68.6). Queen Alexandra Range (QUE) 93009 (orthopyroxene mg# 70.6) contains coarse‐grained noritic clasts (plagioclase An84.7–88.3), and is rich in incompatible trace elements. It has Eu/Eu* < 1, indicating that cumulate norites do not dominate its trace element inventory. Queen Alexandra Range 93009 may be transitional between diogenites and magnesian cumulate eucrites. Lewis Cliff 88679, a dimict breccia of harzburgite and orthopyroxenite, has anomalously low concentrations of highly incompatible elements (e.g., Nb, La, Ta, U) compared to other diogenites, but is similar to them in less highly incompatible elements (e.g., Y, Zr, Yb, Hf). It is unlikely that this characteristic reflects a low proportion of a trapped melt component. The highly incompatible elements were likely mobilized after impact mixing of the two parent lithologies. Graves Nunataks 98108 shows an extreme range in Eu/Eu* attributable to the heterogeneous distribution of plagioclase; one sample has the lowest Eu/Eu* among diogenites. We find no compelling evidence to support the hypothesis that diogenite parent magmas were contaminated by partial melts of the eucritic crust. We posit that subsolidus equilibration between orthopyroxene and minor/trace phases (including phosphates) resulted in preferential redistribution of Eu2+ relative to Eu3+ and other rare earth elements, and results in anomalously low Eu/Eu* in samples leached in acids that dissolve phosphates.  相似文献   

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