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1.
The Gemericum is a segment of the Variscan orogen subsequently deformed by the Alpine–Carpathian orogeny. The unit contains abundant siderite–sulphide and quartz–antimony veins together with stratabound siderite replacement deposits in limestones and stratiform sulphide mineralization in volcano-sedimentary sequences. The siderite–sulphide veins and siderite replacement deposits of the Gemericum represent one of the largest accumulations of siderite in the world, with about 160 million tonnes of mineable FeCO3. More than 1200 steeply dipping hydrothermal veins are arranged in a regional tectonic and compositional pattern, reflecting the distribution of regional metamorphic zones. Siderite–sulphide veins are typically contained in low-grade (chlorite zone) sedimentary, volcano-sedimentary or volcanic Lower and Upper Paleozoic rocks. Quartz–antimony veins are hosted by higher-grade units (biotite zone). Siderite–sulphide veins are dominated by early siderite followed by a complex set of stages, including quartz–sulphide (chalcopyrite, tetrahedrite), barite, tourmaline–quartz, and sulphide-remobilization stages. The temporal evolution of these stages is difficult to study because of the widespread and repeated tectonic processes, within-vein replacement and recrystallization. Siderite–sulphide veins show considerable vertical (up to 1200 m) and lateral (up to 15 km) extent, and a thickness typically reaching several metres. Carbonate-replacement siderite deposits of the Gemericum are hosted by a Silurian limestone belt and are similar to stratabound siderite deposits of the Eastern Alps (e.g., Erzberg, Austria).Based on a review of geological, petrological and geochronological data for the Gemericum, and extensive stable and radiogenic isotope data and fluid inclusion data on hydrothermal minerals, the siderite–sulphide veins and siderite replacement deposits are classified as metamorphogenic in a broad sense. The deposits were formed during several stages of regional crustal-scale fluid flow. Isotope (S, C, Sr, Pb) fingerprinting identifies the metamorphosed rock complexes of the Gemericum as a source of most components of hydrothermal fluids. Fluid inclusion and stable isotope data evidence the participation of several contrasting fluid types, and the existence of contrasting P–T conditions during vein evolution. A high-δ18O, medium- to high-salinity, H2O-type fluid is the most important component during siderite deposition, whereas H2O–CO2-type fluid inclusion containing dense liquid CO2 and corresponding to minimal pressures between 1 and 3 kbar were found in a younger tourmaline–quartz stage. Younger quartz–ankerite(±siderite)–sulphide stages are characterized by high-salinity (17 to 35 wt.% NaCl equivalent) and low-temperature (Th=90 to 180 °C) H2O-type fluids.The vein deposits are interpreted as a result of multistage hydrothermal circulation, with Variscan and Alpine mineralization phases. Based on available indirect data, the most important mineralization phase was related to regional fluid flow during the uplift of a Variscan metamorphic core complex, producing siderite–sulphide (±barite) mineralization, while tourmaline–quartz stage and sulphide remobilization stages are related to Alpine processes. Two phases of vein evolution are evident from two groups of 87Sr/86Sr isotope ratios of Sr-rich, Rb-poor hydrothermal minerals: 0.71042–0.71541 in older barite and 0.7190–0.7220 in late-stage celestine and strontianite.  相似文献   

2.
A carbonate-hosted stratabound siliceous crust type (SCT) mineralization (base metal sulphides, barite, fluorite) occurs over large areas of Carnic Alps and Karawanken in the Eastern Alps. It concerns a pervasively silicified lithological unit, up to some tens of metres thick, which caps the unconformity landscapes developed on epicontinental Devonian–Dinantian carbonates. The SCT mineralization is directly overlaid by different transgressive siliciclastic sediments, which range from Lower Carboniferous to Lower Permian. The presence of fragments of the SCT mineralization in the transgressive siliciclastic sediment bounds its whole lithological evolution within a short stratigraphic interval of Lower Carboniferous age. Selected features of the regional and lithostratigraphic setting are discussed. The chemical characterisation is based on the statistical evaluation of compositional data of 581 selected samples. Three significant groups of elements have been distinguished: (1) the hydrological and metasomatically active elements (Si, Ba, F), which show a strong negative correlation amongst themselves and characterise the silica-saturated aqueous solutions; (2) the terrigenous elements (Al2O3, K2O, Fetot, TiO2, B, Be, Ce, La, Nb, V, Y, Zr), which suggest a continental margin environment for silica deposition; (3) the sulphide metals (Cu, Pb, Zn, Ni, Sb, As, Hg, Cd), which define the metalliferous signature of the SCT mineralization.Some consistent, but still debatable genetic aspects of the SCT mineralization are as follow: (1) silica may be supplied by illitization of clay-rich basinal sediments during their diagenesis. δ18O of microcrystalline quartz ranges from +18.5‰ and +24.6‰ and is very similar to δ18O of authigenic quartz deriving from diagenetic processes of illitization of clay-rich basinal sequences. (2) The diagenetic evolution of these sediments may trigger off the movement of silica-rich marine pore waters. δ34S of barite ranges from +15.5‰ to +19.3‰ with an average of +17.7‰ and are in good agreement with δ34S of sulphate in ocean waters of Upper Devonian–Lower Carboniferous age. (3) A convective hydrological system, connected with sinsedimentary transtensive tectonics, active in the Carnic Alps since the Frasnian, may be the transport mechanism of aqueous solutions. (4) A weak drop in pH in the dominant carbonate environment represents the conditions for silica precipitation.SCT mineralization, showing persistent, independent and distinct characters, occurs over large areas also in other sites of the Alpine belt and outside Italy and Austria. Therefore, it points to important markers for some sedimentary sequences as well as to a worldwide significant cyclic metallogenic event. It represents a new ore deposit-type within the carbonate-hosted mineralization.  相似文献   

3.
The Dadeldhura thrust sheet inm western Nepal consists of Proterozoic–Lower Paleozoic sedimentary and plutonic rocks, and their metamorphic equivalents, that rest structurally on Proterozoic strata of the Lesser Himalayan sequence. Although regional metamorphism and ductile deformation were widespread during Tertiary thrust emplacement, relicts of early Paleozoic tectonism are preserved locally. New field and geochronologic studies, together with the findings of previous workers, indicate that this early Paleozoic tectonism included: (1) regional metamorphism to at least garnet grade, (2) regional folding of a thick metamorphic sequence into a broad east–west trending syncline, (3) outcrop-scale folding of metasedimentary rocks, (4) emplacement of Cambro–Ordovician granitic bodies during and after the metamorphism and deformation, (5) uplift and erosion of the metamorphic sequence, with garnet-grade rocks locally exposed at the surface, and (6) derivation of Ordovician conglomeratic sandstones from the early Paleozoic orogen. Similar records of metamorphism, deformation, and uplift/erosion have been found in other regions of the Himalaya, indicating that rocks of the Dadeldhura thrust sheet were originally involved in a regionally extensive orogenic system. Future tectonic models of Himalayan orogenesis must accommodate this early Paleozoic event.  相似文献   

4.
In this paper, we compare the petrological histories of the Kemp Land Coast (east Antarctica), and Gokavaram area (Eastern Ghats), that were supposed to have been juxtaposed. The area around Gokavaram is dominated by different varieties of paragneisses (pelitic, quartzofeldspathic, and calcareous composition) with relatively minor amounts of orthogneisses (mafic, enderbitic, and granitic composition). The rocks were involved in three major phases of deformation, and were finally affected by localised shear movement. On the basis of reaction textures, well preserved in high Mg-Al granulites, and calc-silicate granulites, and geothermobarometric data we deduce a polymetamorphic evolution of the rocks. Following an early M1 metamorphism culminating at 9.2–9.4 kbar, > 950°C, the rocks cooled nearly isobarically down to 850°C. During a subsequent M2 metamorphism, near isothermal decompression to 5–6 kbar occurred. This was followed by near isobaric cooling down to 600–650°C. M3 is a weak amphibolite facies overprint, largely restricted to late shears, which involved hydration as well. Available radiometric data from this area can be interpreted in terms of partial resetting of U-Pb systematics in older sphenes due to M3 metamorphism at ca. 550 Ma. Despite the absence of sufficient isotopic data on the Eastern Ghats granulites, we document a remarkable similarity in the petrological history of the two supposedly erstwhile neighbours.  相似文献   

5.
The fluorite-bearing hydrothermal mineralization in Sardinia mainly occurs within Paleozoic volcanic and metasedimentary rocks. Only 3 occurrences are located in volcanic and siliciclastic Cenozoic rocks. Most Sardinian fluorites exhibit relatively high rare earth and Y (REY) contents, strong positive Y anomalies, slightly negative Ce and generally positive Eu anomalies. These features indicate that the REY were mobilized mainly from non-carbonate rocks. Neither Sr nor Nd isotopes can be used to date radiometrically the Sardinian fluorites. However, the measured Sr-isotope ratios of the fluorites hosted by Paleozoic rocks fit mixing lines in the 1000/Sr versus 87Sr/86Sr plot once recalculated at 280 Ma, suggesting that the age inferred for the correction probably represents that of the formation of the fluorite mineralization. Mixing likely occurred between diluted surficial waters and brines circulating mainly through the Lower Paleozoic metasedimentary basement. The Cenozoic fluorites exhibit chemical and isotopic features similar to those of the Paleozoic fluorites, except the Nuraghe Onigu fluorite displaying a possible contribution of Sr from Cenozoic magmatic rocks. The initial εNd values of the Paleozoic fluorites fit the age proposed for the formation of the deposits. Moreover, the values suggest that radiogenic Nd was provided to the fluids from the Ordovician siliciclastic basement, except for 3 deposits where the potential source rocks of Nd were mainly Ordovician acidic magmatic rocks. The initial εNd values of the Cenozoic fluorites suggest a provenance of Nd essentially from the leaching of Variscan granitoids.  相似文献   

6.
Gold mineralization in the Eastern Desert of Egypt is confined, almost completely, to the basement rocks of the Nubian Shield that was cratonized during the Panafrican orogeny.Island-arc, orogenic and post-orogenic stages are indicated for the tectonic-magmatic evolution of the Nubian Shield in Late Proterozoic times. Different styles of gold mineralization recognised in the Eastern Desert are inferred to have developed during these stages.In the island-arc stage, which is characterized by volcanic and volcaniclastic rocks in an ensimatic environment, gold mineralization is hosted in stratiform to strata-bound Algoma-type BIF and associated tuffaceous sedimentary rocks. Both types represent exhalative deposits, formed during breaks in sub-marine basaltic and bastalic–andesite volcanic eruptions. The volcanic rocks have a tholeiitic affinity and reflect an immature arc stage. Gold hosted in massive-sulphide deposits within calc-alkaline rhyolites represents another style of gold mineralization connected with mature island arc stage.During the orogenic-stage, ophiolites and island arc volcanic and volcaniclastic rocks were thrust onto the Pre-Panafrican continental margin. Subduction was active beneath the continent while the thrusting was still operative. A phase of calc-alkaline magmatic activity developed during this stage and the compressional deformation event was synchronous with regional metamorphism (greenschist–amphibolite facies). Extensional shear fractures (brittle–ductile shear zones) were broadly contemporaneous with the intense compressional tectonic regime. These fractures opened spaces in which the mineralizing fluids penetrated.Gold mineralization associated with the orogenic-stage is represented by vein-type mineralization that constituted the main target for gold since Pharaonic times. Other styles of gold mineralization during this stage are represented by altered ophiolitic serpentinites (listwaenites), Gold mineralization associated with intrusion related deposits (possibly porphyry copper deposits), as well as, auriferous quartz veins at the contacts of younger gabbros and G-2 granites.The post-orogenic stage is characterized by the dominance of intra-plate magmatism. Small amounts of the element in disseminations, stockworks and quartz veins of Sn–W–Ta–Nb mineralization represent gold mineralization connected with this stage.The link between these tectonic–magmatic stages and gold mineralization can be used as a criterion at any exploration strategy for new targets of gold mineralization in Egypt.  相似文献   

7.
The Voltýov gold deposit in Central Bohemia is situated in the contact zone of granitic rocks of Variscan age and the Upper Proterozoic and Lower Paleozoic metasediments of the Krásná Hora Metamorphic Islet — the relict of an original sedimentary cover. Goldbearing quartz mineralization of vein and stockwork types is developed in rocks of both geological units, its form depending upon lithology. While ore shoots in metasediments and orthogneiss form generally regular bodies several tens of meters thick, those developed in granodiorite are rather irregular, without any indication of the tectonic control of the mineralization. The mineralized zone peters out extremely rapidly downwards, with a marked decrease both in extent and in gold contents. The gold-bearing mineralization is formed by two generations of gold, both of high fineness (over 900) and very fine-grained (5–20 m). The gold is accompanied by accessory arsenopyrite, maldonite and other Bi-Te minerals, scheelite, and exceptionally chalcopyrite, pyrite, and sulphosalts. Gold contents are 2–3 g/t on average. In addition, late quartz-carbonate mineralization, with U and Se minerals and remobilized gold, is also present. Detailed soil prospecting (25 × 50 m grid) of the deposit detected a large and constrasting gold halo with gold contents exceeding 2 ppm (–200 mesh fraction), accompanied by higher concentrations of characteristic pathfinders — above all As and Bi. The halo extent exceeds the area of the ore outcrop by several times. The origin of gold mineralization in the deposit is explained by remobilization of gold from orthogneiss by the intrusion of the Central Bohemian Pluton.  相似文献   

8.
New 40Ar/39Ar geochronology places time constraints on several stages of the evolution of the Penninic realm in the Eastern Alps. A 186±2 Ma age for seafloor hydrothermal metamorphic biotite from the Reckner Ophiolite Complex of the Pennine–Austroalpine transition suggests that Penninic ocean spreading occurred in the Eastern Alps as early as the Toarcian (late Early Jurassic). A 57±3 Ma amphibole from the Penninic subduction–accretion Rechnitz Complex dates high-pressure metamorphism and records a snapshot in the evolution of the Penninic accretionary wedge. High-pressure amphibole, phengite, and phengite+paragonite mixtures from the Penninic Eclogite Zone of the Tauern Window document exhumation through ≤15 kbar and >500 °C at 42 Ma to 10 kbar and 400 °C at 39 Ma. The Tauern Eclogite Zone pressure–temperature path shows isothermal decompression at mantle depths and rapid cooling in the crust, suggesting rapid exhumation. Assuming exhumation rates slower or equal to high-pressure–ultrahigh-pressure terrains in the Western Alps, Tauern Eclogite Zone peak pressures were reached not long before our high-pressure amphibole age, probably at ≤45 Ma, in accordance with dates from the Western Alps. A late-stage thermal overprint, common to the entire Penninic thrust system, occurred within the Tauern Eclogite Zone rocks at 35 Ma. The high-pressure peak and switch from burial to exhumation of the Tauern Eclogite Zone is likely to date slab breakoff in the Alpine orogen. This is in contrast to the long-lasting and foreland-propagating Franciscan-style subduction–accretion processes that are recorded in the Rechnitz Complex.  相似文献   

9.
The Sr isotopic composition of sediment-hosted magnesites in Permian and Scythian series of Upper Austroalpine units (Eastern Alps) has been determined. The results suggest diagenetic-metasomatic magnesite formation by Mg-rich pore solutions. The depositional environment of the magnesite-bearing rocks is reflected by different isotopic compositions with initial 87Sr/86Sr ratios close to contemporaneous sea water in marine sediments (0.7071–0.7083) and higher ratios being typical for lacustrine and coastal environments influenced from the hinterland (0.7133–0.7139). Coarser grained recrystallized magnesite and magnesite veins show a distinct increase in their Sr isotopic ratios (0.7202–0.7220) which can be attributed to metamorphic fluids of Eoalpine age. The findings of these magnesite occurrences, which have been affected only by very low-grade metamorphism, are compared with similar results from spar magnesites associated with metamorphosed Paleozoic sedimentary rocks. A similar genetic model is proposed for the first magnesite mineralization in those Paleozoic strata, but with variably intense later recrystallisation during metamorphism.  相似文献   

10.
Tungsten mineralisation in the NE Hindu Kush terrain occurs 8 km NW of the Tirich Boundary Zone suture between Karakoram and Eastern Hindu Kush. Scheelite occurs mainly in calc-silicate rocks and subordinately in tourmalinites associated with metasediments at Miniki Gol, Chitral. The investigated area underwent two phases of deformation and was metamorphosed up to sillimanite grade, followed by the emplacement of leucogranite and hydrothermal activity. The mineral assemblages of the calc-silicate rocks, comprising clinozoisite, quartz, calcic-amphibole, plagioclase, chlorite, biotite, calcite, sphene, garnet and scheelite, clearly express a skarn type environment. The coexistence of the scheelite grains with clinozoisite and the occurrence of anomalous values of ZrO2 and Ta2O5 in the scheelite grains imply a genetic link between the scheelite mineralisation and post-magmatic hydrothermal fluids. The enrichment of Zr, Hf, Be, Sn, W, Th, U, Ga, Nb, F and Y along with total REE in the scheelite-bearing calc-silicate rocks compared with the associated metasediments assigns that the rocks at Miniki Gol have undergone a pronounced hydrothermal activity. Strong positive correlations between Zr, Hf, Nb, Y, Ta, F and REE, and the mobility of REE are consistent with this consideration. Aqueous fluid inclusions in the scheelite-bearing calc-silicate rocks display very low salinity, suggesting a mixing of magmatic fluids with meteoric water. The formation of intergrown scheelite and clinozoisite indicates a high pH and CO2-deficient fluid. The tungsten mineralization may be related to the Miniki Gol leucogranite which occurs at a distance of only 400 m.  相似文献   

11.
The Paleozoic sequences of the Gurktal nappe (Eastern Alps) can be divided into two tectonic units by means their facies development: (1) The lower Murau nappe is characterized by low grade metamorphic black schists, calcareous phyllites of predominantly Silurian age (?) and some hundred meters of carbonates of predominantly Lower Devonian age. (2) The higher Stolzalpe nappe, metamorphosed very low to low grade, contains Ordovician to Lower Silurian volcanic formations. There can be recognized three facies during Upper Silurian to Lower Devonian times. The higher Devonian to Lower Carboniferous is dominated by more or less pelagic carbonates. After the facies distribution of Paleozoic rocks other parts of southern Austroalpine show a similar tectonic feature. The Stolzalpe nappe is related to the upper nappes of Austroalpine (i. e. Noric nappe system, northern parts of Paleozoic of Graz) and also western Carnics. The clastic and carbonate complexes of Murau nappe, Schöckel nappe s. 1. (Paleozoic of Graz) and Murides crystalline (middle Austroalpine) are developed very similar. Some features of Paleozoic fades distribution show a NE to SW trend crossing the alpidic structure. Because of conglomerates with crystalline components near the base is postulated a preUpper Ordovician basement complex for this realm.  相似文献   

12.
This paper reports the occurrence of vesvianite + wollastonite + grossular + diopside + microcline + quartz assemblage in an enclave of calc-silicate rocks occurring within quartzofeldspathic gneiss near Tatapani in the western part of Chhotanagpur Gneissic Complex. The enclave contains phlogopite-absent and phlogopite-bearing calc-silicate rocks, the latter being much more abundant than the former. The above assemblage occurs in the phlogopite-absent rock. Phlogopite-bearing rock contains the assemblage phlogopite + salite + microcline + plagioclase + quartz. A strong schistosity is developed in both the calc-silicate rocks and the minerals are syntectonic with the major foliation-forming event in the area. The vesuvianite-bearing assemblage is formed by amphibolite facies regional metamorphism of a calcareous protolith at pressure < 4 kbar and XCO 2 (fluid) < 0.15.  相似文献   

13.
Tourmaline rocks of previously unclear genesis and spatially associated with W- (Cu)-bearing calc-silicate rocks occur in Palaeoproterozoic supracrustal and felsic intrusive rocks in the Bonya Hills in the eastern Arunta Inlier, central Australia. Tourmalinisation of metapelitic host rocks postdates the peak of regional low-pressure metamorphism (M1/D1, ~500 °C, ~0.2 GPa), and occurred synkinematically between the two main deformation events D1 and D2, coeval with emplacement of Late Strangways (~1.73 Ga) tourmaline-bearing leucogranites and pegmatites. Tourmaline is classified as schorl to dravite in tourmaline–quartz rocks and surrounding tourmaline-rich alteration zones, and as Fe-rich schorl to foitite in the leucogranites. Boron metasomatism resulted in systematic depletion of K, Li, Rb, Cs, Mn and enrichment of B, and in some samples of Na and Ca, in the tourmaline rocks compared to unaltered metasedimentary host rocks. Whole-rock REE concentrations and patterns of unaltered schist, tourmalinised schist and tourmaline–quartz veins—the latter were the zones of influx of the boron-rich hydrothermal fluid—are comparable to those of post-Archaean shales. Thus, the whole-rock REE patterns of these rocks are mostly controlled by the metapelitic precursor. In contrast, REE concentrations of leucogranitic rocks are low (10 times chondritic), and their flat REE patterns with pronounced negative Eu anomalies are typical for fractionated granitic melts coexisting with a fluid phase. REE patterns for tourmalines separated from metapelite-hosted tourmaline–quartz veins and tourmaline-bearing granites are very different from one another but each tourmaline pattern mirrors the REE distribution of its immediate host rock. Tourmalines occurring in tourmaline–quartz veins within tourmalinised metasediments have LREE-enriched (LaN/YbN=6.3–55), shale-like patterns with higher REE (54–108 ppm). In contrast, those formed in evolved leucogranites exhibit flat REE patterns (LaN/YbN=1.0–5.6) with pronounced negative Eu anomalies and are lower in REE (5.6–30 ppm). We therefore conclude that REE concentrations and patterns of tourmaline from the different tourmaline rocks studied are controlled by the host rock and not by the hydrothermal fluid causing boron metasomatism. From the similarity of the REE pattern of separated tourmaline with the host rock, we further conclude that incorporation of REEs in tourmaline is not intrinsically controlled (i.e. by crystal chemical factors). Tourmaline does not preferentially fractionate specific REEs or groups of REEs during crystallisation from evolved boron- and fluid-rich granitic melts or during alteration of clastic metasediments by boron-rich magmatic-hydrothermal fluids.Editorial responsibility: J. Hoefs  相似文献   

14.
A generalised crustal structure of Fiordland is proposed.Detailed mapping in part of Western Fiordland has led to the recognition of a basement granulite facies lower crustal material, probably Precambrian in age) separated by a regional thrust zone from a cover sequence (amphibolite facies gneisses, of Lower Paleozoic age). With the recognition of the basement—cover relationship and the aid of aeromagnetic anomalies Fiordland has been divided into four, generally north-northeast trending, regions. The Western Fiordland region is composed chiefly of basement rocks. The Central Fiordland and Southwestern Fiordland regions are made up predominantly of amphibolite and greenschist-facies metasediments and gneissic granodiorites of the cover sequence, which in Central Fiordland have a regional dip to the east, off the basement. The Eastern Fiordland region is characterised by a series of basic, intermediate and acid intrusive rocks. The more prominent magnetic anomalies in Eastern Fiordland, Southwestern Fiordland, and a large anomaly off the coast of Western Fiordland, are all considered to be caused by intrusive bodies. The presence of a positive gravity anomaly over Western Fiordland, coupled with a gravity low offshore, is consistent with the lower crust being uplifted and exposed in this area. Continuing shallow and intermediate-depth seismic activity beneath Fiordland, as well as the large size of the gravity anomaly, suggest that tectonic forces are currently acting to maintain Western Fiordland at its unusually high level.Fiordland thus displays a cross-section of continental crust: Precambrian(?) metaigneous granulites in the lower crust; Lower Paleozoic metasedimentary amphibolitefacies gneisses and melted equivalents in the middle crust; Mesozoic intrusives, and overlying Cretaceous and Tertiary sediments in the upper crust.  相似文献   

15.
The methamorphic history of the Patapedia thermal zone, Gaspé, Quebec, is re-evaluated in the light of results obtained from a study of fluid inclusions contained in quartz phenocrysts of felsic dyke rocks. The thermal zone is characterised by calc-silicate bodies that have outwardly telescoping prograde metamorphic isograds and display extensive retrograde metamorphism with associated copper mineralization. Three distinct fluid inclusion types are recognized: a low to moderate salinity, high density aqueous fluid (Type I); a low density CO2 fluid (Type II); and a high salinity, high density aqueous fluid (Type III). Fluid inclusion Types I and II predominate whereas Type III inclusions form <10% of the fluid inclusion population. All three fluid types are interpreted to have been present during prograde metamorphism. Temperatures and pressures of metamorphism estimated from fluid inclusion microthermometry and isochore calculations are 450°–500° C and 700–1000 bars, respectively. A model is proposed in which the metamorphism at Patapedia was caused by heat transferred from a low to moderate salinity fluid of partly orthomagmatic origin (Type I inclusions). During the early stages, and particularly in the deeper parts of the system, CO2 produced by metamorphism was completely miscible in the aqueous hydrothermal fluid and locally resulted in high XCO2 fluids. On cooling and/or migrating to higher levels these latter fluids exsolved high salinity aqueous fluids represented by the Type III inclusions. Most of the metamorphism, however, took place at temperature-pressure conditions consistent with the immiscibility of CO2 and the hydrothermal fluid and was consequently accompanied by the release of large volumes of CO2 vapour which is represented by Type II inclusions. The final stage of the history of the Patapedia aureole was marked by retrograde metamorphism and copper mineralization of a calcite-free calc-silicate hornfels in the presence of a low XCO2 fluid.  相似文献   

16.
A newly identified skarn occurrence is described from the Neoproterozoic rocks of the SW Arabian shield. It is exposed to the SE, E and NE of the Al-Madhiq town. The skarn attributes correspond to those typical of the calcic skarns that host W-deposits. It is characterized as an exoskarn of the proximal type, related to a granitoid contact close to an impure quartzite bed within the regional metamorphic rocks of mixed sedimentary and volcanic derivation. The skarn is localized along a shear zone parallel to the regional faults and other major shear zones. Samples from the studied area contain characteristic skarn minerals that include both the prograde (brownish red grossular, ferrosalite, aluminian titanite-grothite, albite-oligoclase, scapolite), and retrograde (epidote, quartz, hornblende, calcite) assemblages. The pyroxenes are ferrosalites, Mn-bearing, and more like those from “oxidized” skarns; although garnets indicate it to be a “reduced” type skarn. Epidote mimicks that from typical skarns, as it bears a pistacite content of 15.9–20.7%. Grossular composition reflects a largely reduced genetic environment; as it is in solid solution with 6.5–21.6% andradite, 0–0.15% uvarovite, 0–0.47% pyrope, 4.33–18.75% almandine, and 0.4–8.58% spessartine molecules. Titanite composition varies from aluminian titanite to grothite, that may be analogous to the newly described Al-rich titanite from the low-pressure calc-silicate rocks.  相似文献   

17.
Under the flatlands east of the Andes, the crustal basement is exposed in a few places, composed mainly of the Mitú migmatitic complex and the Parguaza granite, whose ages range between 1.78 and 1.45 Ga. Extensive outcrops of high-grade metamorphic rocks are found in several places. Two metamorphisms are dated between 1.2–1.1 and 1.0–0.9 Ga. They are considered blocks that formed during the Grenville orogeny and have Sm–Nd TDM model ages of 1.87–1.47. The Andaquí terrane is formed mainly by the Garzón Massif, composed of granulites, migmatites, and granites, and the metamorphic rocks of the Sierra de la Macarena, which are covered by undeformed Cambrian sediments. It is believed that after the Grenville orogeny, this unit remained attached to the Amazonic Craton. All the other areas grouped in the Chibcha terrane, though they formed during the Grenville orogeny, are believed to have remained either as part of another continental block or dispersed islands to be amalgamated to the Amazonic Craton during the Lower Paleozoic orogeny, which in the Quetame Massif is dated between the Silurian and Devonian and is named the Quetame orogenic event.  相似文献   

18.
The Gorny Altai region in southern Siberia is one of the key areas in reconstructing the tectonic evolution of the western segment of the Central Asian Orogenic Belt (CAOB). This region features various orogenic elements of Late Neoproterozoic–Early Paleozoic age, such as an accretionary complex (AC), high-P/T metamorphic (HP) rocks, and ophiolite (OP), all formed by ancient subduction–accretion processes. This study investigated the detailed geology of the Upper Neoproterozoic to Lower Paleozoic rocks in a traverse between Gorno-Altaisk city and Lake Teletskoy in the northern part of the region, and in the Kurai to Chagan-Uzun area in the southern part. The tectonic units of the studied areas consist of (1) the Ediacaran (=Vendian)–Early Cambrian AC, (2) ca. 630 Ma HP complex, (3) the Ediacaran–Early Cambrian OP complex, (4) the Cryogenian–Cambrian island arc complex, and (5) the Middle Paleozoic fore-arc sedimentary rocks. The AC consists mostly of paleo-atoll limestone and underlying oceanic island basalt with minor amount of chert and serpentinite. The basaltic lavas show petrochemistry similar to modern oceanic plateau basalt. The 630 Ma HP complex records a maximum peak metamorphism at 660 °C and 2.0 GPa that corresponds to 60 km-deep burial in a subduction zone, and exhumation at ca. 570 Ma. The Cryogenian island arc complex includes boninitic rocks that suggest an incipient stage of arc development. The Upper Neoproterozoic–Lower Paleozoic complexes in the Gorno-Altaisk city to Lake Teletskoy and the Kurai to Chagan-Uzun areas are totally involved in a subhorizontal piled-nappe structure, and overprinted by Late Paleozoic strike-slip faulting. The HP complex occurs as a nappe tectonically sandwiched between the non- to weakly metamorphosed AC and the OP complex. These lithologic assemblages and geologic structure newly documented in the Gorny Altai region are essentially similar to those of the circum-Pacific (Miyashiro-type) orogenic belts, such as the Japan Islands in East Asia and the Cordillera in western North America. The Cryogenian boninite-bearing arc volcanism indicates that the initial stage of arc development occurred in a transient setting from a transform zone to an incipient subduction zone. The less abundant of terrigenous clastics from mature continental crust and thick deep-sea chert in the Ediacaran–Early Cambrian AC may suggest that the southern Gorny Altai region evolved in an intra-oceanic arc-trench setting like the modern Mariana arc, rather than along the continental arc of a major continental margin. Based on geological, petrochemical, and geochronological data, we synthesize the Late Neoproterozoic to Early Paleozoic tectonic history of the Gorny Altai region in the western CAOB.  相似文献   

19.
The Gold Bar district contains five Carlin-type gold deposits and four resources for a combined gold endowment of 1.6 M oz [50 t]. The gold deposits are hosted in Devonian carbonate rocks below parautochthonous and allochthonous Paleozoic siliciclastic rocks emplaced during the Early Mississippian Antler orogeny. The district is in the Battle Mountain-Eureka trend, a long-lived structural feature that localized intrusions and ore deposits of different types and ages.The whole-rock geochemistry of four different mineralized and unmineralized Devonian carbonate rock units (two favorable and two unfavorable) were determined and interpreted in the context of the regional geology. A combination of basic statistics, R-mode factor analysis, isocon plots, and alteration diagrams were utilized to (1) identify favorable geochemical attributes of the host rocks, (2) characterize alteration and associated element enrichments and depletions, and (3) identify the mechanism of gold precipitation. This approach also led to the recognition of other types of alteration and mineralization in host rocks previously thought to be solely affected by Carlin-type mineralization.Unit 2 of the Upper Member of the Denay Formation, with the highest Al2O3, Fe2O3 and SiO2 contents and the lowest CaO content, is the most favorable host rock. Based on the high regression coefficients of data arrays on X–Y plots that project toward the origin, Al2O3 and TiO2 were immobile and K2O and Fe2O3 were relatively immobile during alteration and mineralization. Specific element associations identified by factor analysis are also prominent on isocon diagrams that compare the composition of fresh and altered equivalents of the same rock units. The most prominent associations are: Au, As, Sb, SiO2, Tl, –CaO and –LOI, the main gold mineralizing event and related silicification and decalcification; Cd, Zn, Ag, P, Ni and Tl, an early base metal event; and MgO, early dolomitization. Alteration diagrams, consisting of X–Y plots of SiO2/Al2O3, K2O/Al2O3, CO2/Al2O3, [S/Al2O3]/[Fe2O3/Al2O3], provide evidence for progressive silicification, decarbonation (decalcification and dedolomitization), argillization (illite), and sulfidation as a function of gold mineralization. The latter process is identified as the principal mechanism of gold precipitation.The lithogeochemistry of the ores in the Gold Bar district is typical of that documented in classic Carlin-type gold deposits in the region, but the size of the deposits and the intensity of alteration and mineralization are less. The presence of other types of mineralization in the Gold Bar district is also common to most of the other Carlin-type districts located in major mineral belts. The approach used in this study is well suited to the interpretation of multi-element geochemical data from other study areas with superimposed alteration and mineralization.  相似文献   

20.
Summary This paper describes corundum formation in a metasomatic reaction zonation around an ultramafic body within a metapelitic sequence. The investigated body is about 100 m in diameter and is located in the Saualpe of the Austroalpine nappe complex in the Eastern Alps. The body is surrounded by a 10 m wide reaction zone (here called zone 3) containing the paragenesis garnet–staurolite–biotite–margarite–chlorite–corundum. Beyond a further metasomatic transition zone (here called zone 2), there are undisturbed metapelitic host rocks (zone 1) that have the metamorphic peak paragenesis garnet–biotite–plagioclase–staurolite–muscovite–quartz. It is shown that reaction zonation formed around 7.2kbar and 615°C during regional metamorphism, just above the serpentine breakdown reactions in the system MgO–SiO2–H2O. Detailed analysis of the whole rock compositions shows that the reaction zonation formed by infiltration metasomatism that caused significant mass loss in the two alteration zones. These zones are particularly depleted in SiO2, Na2O and possibly K2O. An XNa2O–XSiO2 thermodynamic pseudosection is presented that includes the parageneses of both the unaltered metapelitic host rock and the corundum-bearing parageneses. This suggests that the metasomatic process can be explained by the transfer of SiO2 and Na2O alone. We interpret that the process is driven by water liberated from the previously serpentinised ultramafic body during prograde dehydration during regional Eo-Alpine metamorphism. This fluid flowed outwards from the ultramafic body depleting the surrounding pelites in silica and causing margarite formation from plagioclase and muscovite. This interpretation of the driving mechanism is consistent with our knowledge of the low water activities of the Saualpe during the Eo-Alpine orogenic cycle.  相似文献   

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