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1.
The natural alteration products developed on mattes from lead metallurgy were determined: oxides and hydroxides (HFO, Cu(OH)2), sulphates (thenardite, gypsum), hydroxysulphates (jarosite, beaverite, brochantite) and carbonates (cerussite, malachite, NaOH·2 PbCO3). The large range of stability of newly formed phases confirms a significant variety of Eh–pH conditions of natural weathering of matte. Jarosite is stable at pH<3, but some hydroxides and carbonates typically form in neutral and alkaline environments. Consequently, the best dumping conditions for metallurgical mattes are difficult to determine. Such materials can have severe environmental effects and should be dumped in controlled waste-disposal sites. To cite this article: V. Ettler et al., C. R. Geoscience 335 (2003).  相似文献   

2.
Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å3, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu0.15Pb2(Pb0.53Sb0.47)(Pb0.46Sb0.54)(Sb0.75Pb0.19Bi0.06)S6; the reduced one: Cu0.58Pb12.72(Sb7.04Bi0.24)S24. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.  相似文献   

3.
The Mananjary emerald deposits are hosted in phlogopite-rich rocks formed through metasomatic alteration of meta-ultrabasites (hornblendites) at about 500 °C and 2 kbar due to infiltration of fluoride-rich fluids. A thermodynamic model explains the role of fluoride-complexation in the transport of Be and points to co-precipitation of F-phlogopite as the cause of beryl deposition. To cite this article: B. Moine et al., C. R. Geoscience 336 (2004).  相似文献   

4.
Thermal and hydrothermal effects of Triassic–Liassic basalt flow deposition on sedimentary series of the Argana Basin are responsible for major modifications in detrital clays, until 20 m in depth. It expressed by transformation of detrital smectite to corrensite and moreover to chlorite, and by increasing illite crystallinity. On the 2 m of sediments located immediately under the flow, magnesium-rich hydrothermal fluids have caused precipitation of new mineral phases. To cite this article: L. Daoudi, J.-L. Pot de Vin, C. R. Geoscience 334 (2002) 463–468.  相似文献   

5.
This study was carried out in order to determine the concentration of heavy metals, e.g., lead (Pb), cadmium (Cd), copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), nickel (Ni) and chromium (Cr) in road dust in Kuala Lumpur’s city centre. Samples were collected from four sampling locations, each of which had four sampling points and three replications. Heavy metals from different fractions of particles separated by different diameter sizes: d < 63 μm (Fraction A), 63 < d < 125 μm (Fraction B) and 125 < d < 250 μm (Fraction C) were analyzed using inductively coupled plasma mass spectrometry. The results from this study showed that concentration of heavy metals was dominated by the smallest particle size: <63 μm and that Fe was the most abundant heavy metal overall, followed by Cu > Mn > Zn > Pb > Ni > Cr > Cd. The fact that Cd had the highest enrichment factor value (EF) for all particle sizes indicates that anthropogenic activities contributed to the presence of this metal. There was also a higher EF value for heavy metals in small particle (Fraction A), compared to Fraction B and C, which suggests that fine particles were being produced through anthropogenic activities. Cluster analysis and principal component analysis demonstrated the likelihood of the heavy metals detected in the road dust, originating from road traffic and industrial activities.  相似文献   

6.
New field and laboratory studies on the ophiolite of Khoy (northwestern corner of Iran) lead to the discovery that there are not one, but two ophiolitic complexes in the Khoy area: (1) an old, poly-metamorphic ophiolite, whose oldest metamorphic amphiboles yielded a Lower Jurassic apparent 40K–40Ar age, and whose primary magmatic age should logically be pre-Jurassic (Upper-Triassic?); (2) a younger non metamorphic ophiolite of well dated Upper Cretaceous age. To cite this article: M. Khalatbari-Jafari et al., C. R. Geoscience 335 (2003).  相似文献   

7.
The weathering of a rhyolitic lava flow of the Paraná Basin (Brazil) developed, on few centimeters only, simplified petrographic features. The initial meteoric fluid pass-way is marked by celadonite-to-nontronite transformation. The second step is the complete dissolution of plagioclases, and the last one is the massive precipitation of halloysite. The geochemical mass balances according to the alteration features demonstrate the progressive leaching of major and trace elements fractionated by plagioclases, glass and opaques, and the sorption of Cu>As>Sb in the halloysite matrix. To cite this article: M. Bernard et al., C. R. Geoscience 336 (2004).  相似文献   

8.
Ultrabasic xenoliths (pyroxenites, lherzolites, harzburgites) in recent (Neogene–Quaternary) volcanoes have been studied in three localities within Syria: Jubates (North), Mhailbeh (Center), Tel Thannoun (South). P–T conditions of mineral equilibration have been estimated by pyroxene thermometry (temperature) and maximum CO2 density in primary inclusions (minimum pressure). Pyroxenites equilibrate at significantly higher conditions (T about 1200 °C, P>15 kbar) than lherzolites and harzburgites (900<T<1100 °C, P between 10 and 15 kbar). All are within the spinel lherzolite field, whereas Cretaceous xenoliths originate within the garnet lherzolite field. To cite this article: A. Bilal, F. Sheleh, C. R. Geoscience 336 (2004).  相似文献   

9.
The evolution and the internal architecture of an estuary type sand ridge has been studied with a set of bathymetric data recorded during the last two centuries and with a dense grid of recent very high resolution seismic profiles. Bathymetric data of the so-called, Longe de Boyard sand ridge, displays sand losts due to wave and tide erosion. Internal geometry, through seismic profile analysis, indicates two main phases of deposition recording both, a recent high energy environment and an older low energy one, respectively. Such an evolution is believed to record changes in sedimentation processes mainly related to the end of the Holocene transgression (8 000–5 000 yr BP). To cite this article: É. Chaumillon et al., C. R. Geoscience 334 (2002) 119–126.  相似文献   

10.
Field, petrographic and quantitative strain analysis have been performed on highly foliated limestones outcropping in northern Calabria and generally attributed to two distinct units (San Donato and Pollino) on the basis of presence/absence of metamorphism. The deformation, however, is comparable in all the studied outcrops indicating that the widely accepted distinction of units in the area should be revised. Deformation is very localized in narrow ductile shear-zones affecting Tertiary conglomerates and Jurassic oncoidal packstones. The former are more strained because of their closeness to siliciclastic beds. The main deformation mechanism was grain boundary sliding with minor intragranular strain and pressure solution. To cite this article: A. Iannace, S. Vitale, C. R. Geoscience 336 (2004).  相似文献   

11.
Heavy metals are governed by parent material of soils and influenced by the soil physicochemical properties and soil and crop management practices. This paper evaluates total heavy metal concentrations in rainfed soils under diverse management practices of tropical India. Vertisols (clayey soils with high shrink/swell capacity) had the highest concentrations of heavy metals. However, chromium (Cr) content was above the threshold value in Aridisol [calcium carbonate (CaCO3)]-containing soils of the arid environments with subsurface horizon development. Concentration increased at lower depths (>30 cm). Basaltic soils showed higher concentrations of nickel (Ni), copper (Cu) and manganese (Mn). Cadmium (Cd), cobalt (Co), Cu and Mn concentrations were higher in soils cultivated to cotton, whereas Cr concentration was above the threshold level of 110 mg kg?1 in food crop cultivated soils. As the specific soil surface is closely related to clay content and clay type, soil’s ability to retain heavy metals is more closely tied to the specific surface than to the soil cation exchange capacity. Higher positive correlations were found between heavy metal concentrations and clay content [Cd(r = 0.85; p ≤ 0.01); Co (r = 0.88; p ≤ 0.05); Ni (r = 0.87; p ≤ 0.01); Co (r = 0.81; p ≤ 0.05); Zn (r = 0.49; p ≤ 0.01); Cr (r = 0.80; p ≤ 0.05); Mn (r = 0.79; p ≤ 0.01)]. The amounts of nitrogen–phosphorus–potassium applied showed a positive correlation with Co and Ni (r = 0.62; p ≤ 0.05). As several soils used for growing food crops are high in Ni, Cr and Mn, the flow of these metals in soil–plant–livestock/human chain needs further attention.  相似文献   

12.
The so-called ‘Porphyro??des’ Unit of South Brittany is located below units marked by an early HP–LT event (blueschists from the Île de Groix) and above units marked by Upper Carboniferous HT metamorphism. P–T estimates in the Porphyro??des (at Belle-Île-en-Mer), using the phengite–chlorite thermobarometer, indicate pressures around 8 kbar and temperatures of 350–400 °C. These new estimates suggest that the early tectonic history of the ‘Porphyro??des’ should be linked to that of the overlying Blueschists, and imply a much larger areal extension of the HP–LT domain in this part of the Hercynian Belt. To cite this article: F. Le Hébel et al., C. R. Geoscience 334 (2002) 205–211.  相似文献   

13.
We propose a mechanical model for the behaviour of rocks based on progressive damage at the elementary scale and elastic interaction. It allows us to simulate several experimental observations: mechanical behaviour ranging from brittle to ductile, fractal structure of the damage, power-law distribution of the damage avalanches. These macroscopic properties are not incorporated at the elementary scale, but are the results of the interaction between elements. This emerging complexity permits us to consider the strain rock process as a complex system characterized by non-linear dynamics. To cite this article: D. Amitrano, C. R. Geoscience 336 (2004).  相似文献   

14.
The Kuhmo greenstone belt (Eastern Finland) is mainly formed by mafic volcanic rocks and metasediments. Although the geological observations indicate that this belt appears as a supracrustal synform overlying a gneissic basement, its deep structures are actually unknown. The present gravity study intends to provide a better understanding of these structures. Interpretation of gravity anomalies of the Kuhmo belt, using two-dimensional modelling suggests that the structures of the belt are controlled by granitoids diapirs. Most of the calculated models show that the belt displays in section pocket-like shapes (purses) terminated by a gully-shape close to the surface. This particular geometry corroborates the hypothesis of a gravitational formation with the heavy volcanic material sinking in a light sialic crust. To cite this article: M. Jaffal et al., C. R. Geoscience 335 (2003).  相似文献   

15.
Sediments and surface water contamination by the industrial effluents containing heavy metals is the most detrimental environmental impact. Therefore, the present work attempts to determine the status of eight heavy metal distribution in sediments and water samples, and their ecological risks’ assessment in the studied area. The distribution pattern of heavy metals in the water and sediment follows the sequences: Zn > Cu > Pb > Cr > Mn > Ni > As > Cd and Mn > Zn > Cr > Pb > Cu > Ni > As > Cd, respectively. Gross water pollution is observed at different sampling points of Dhalai Beel and Bangshi River. The comparison of sedimentary mean metal concentrations with several environmental contamination monitoring parameters, viz, threshold effect level (TEL), probable effect level (PEL), and severe effect lever (SEL) indicates that the metal levels are less than PEL except Cr. Moreover, the level of contamination degree (C d) and modified degree of contamination (mC d) indicates ‘low’ and ‘nil to low’ degree of contamination, respectively. Pollution load indices (PLI) of the studied area are lower than unity, indicates no pollution. Furthermore, a toxic-response factor is applied to assess the potential ecological risk of these heavy metals into the water body. The results of this study exhibit a low potential ecological risk of heavy metals. The Pearson’s correlation and cluster analysis are also performed to assess the heavy metal interactions in water and sediment samples.  相似文献   

16.
This study aimed to investigate the population of annelida communities in relation to environmental factors and heavy metals accumulated in sediments of the Gorgan Bay. The pollution load index and potential ecological risk (PER) were calculated. The results indicated mean concentrations (ppm) of heavy metals were (mean ± SD) Pb: 11.5 ± 4.88, Cu: 18 ± 8.83, Zn: 42 ± 22.15, Ni: 29.20 ± 14.68, Co: 10.56 ± 14.68, As: 7.77 ± 2.12, Sr: 1,449 ± 902.59 and V: 26.64 ± 10.25. Considering PER, sediments of the Gorgan Bay had low ecological risk. Based on abundance data, dominant species were Streblospio gynobranchiata, Nereis diversicolor, Tubificoides fraseri and Tubificidae unknown, respectively. Results of redundancy analysis displayed that T. fraseri and N. diversicolor were associated with high values of Sr. All the species were negatively correlated with As. There were positive correlation between S. gynobranchiata and N. diversicolor with values of clay, salinity, depth and silt. The present study provided the relative importance of heavy metals and environmental variables which partly assist in structuring assemblages of annelida in a transitional area.  相似文献   

17.
The metamorphic rocks of the Neyriz area (Sanandaj–Sirjan zone) represent a Palaeozoic sequence, the upper part of which being palaeontologically dated from the Carboniferous and the Permian. Field structural analysis of the whole sequence, detailed in laboratory by microstructural one and 40K–40Ar dating carried on separated minerals, lead to establish that the whole sequence, from gneisses to Permian rocks, has suffered a unique synmetamorphic deformation, of variable intensity, marked by a foliation. Isotopic ages measured on extracted amphiboles and micas, clustered in four groups between 300 and 60 Ma, show the successive stages of their slow exhumation, which ended by the end of the Cretaceous. To cite this article: R. Sheikholeslami et al., C. R. Geoscience 335 (2003).  相似文献   

18.
High-frequency stratigraphic cycles (10 s to 100 s ka) often show, at a specific location, an alternation of ‘dynamic’ (proximal-energetic), and ‘non-dynamic’ (distal-pelagic) processes with time. When sedimentation is syn-deformation, these processes tend respectively to fill-up tectonically-induced topography or to drape it. As a consequence, growth strata are alternatively thickened and isopach across the growth structure. High-resolution kinematic studies of growth structures (folds and faults), which assume that sedimentation always fills up topographies (‘fill-to-the-top’ model), may therefore mistake sedimentary cyclicity for tectonic cyclicity. We address this problem with one example of growth anticline in the Spanish Pyrenees, and we discuss the fill-to-the-top model. To cite this article: S. Castelltort et al., C. R. Geoscience 336 (2004).  相似文献   

19.
To evaluate the risk of contaminant transport by mobile colloids, it is necessary to understand how colloids and associated pollutants behave during their migration through uncontaminated soil or groundwater. In this study, we investigated the influence of aggregation induced by Ca2+ and trace metals (Pb2+, Cu2+) concentrations on the transport of humic-coated kaolinite colloids through a natural quartz sand at pH=4. Adsorbed divalent cations reduce the colloids surface charge and thereby induce aggregation and deposition in porous media. To cite this article: R. Ait Akbour et al., C. R. Geoscience 334 (2002) 981–985.  相似文献   

20.
Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).  相似文献   

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