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1.
In summer, atmospheric ozone was measured from an aircraft platform simultaneously with nitric oxide (NO), oxides of nitrogen (NO y ), and water vapor over the Pacific Ocean in east Asia from 34° N to 19° N along the longitude of 138±3°E. NO y was measured with the aid of a ferrous sulfate converter. The altitude covered was from 0.5 to 5 km. A good correlation in the smoothed meridional distributions between ozone and NO y was seen. In particular, north of 25° N, ozone and NO y mixing ratios were considerably higher than those observed in tropical marine air south of 25° N. NO y and O3 reached a minimum of 50 pptv and 4 ppbv respectively in the boundary layer at a latitude of 20° N. The NO concentration between 2 and 5 km at the same latitude was 30 pptv. The profiles of ozone and water vapor mixing ratios were highly anti-correlated between 25° N and 20° N. In contrast, it was much poorer at the latitude of 33° N, suggesting a net photochemical production of ozone there.  相似文献   

2.
Measurements of NOx (NO +NO2) and the sum of reactive nitrogenconstituents, NOy, were made near the surface atAlert (82.5°N), Canada during March and April1998. In early March when solar insolation was absentor very low, NOx mixing ratios were frequentlynear zero. After polar sunrise when the sun was abovethe horizon for much or all of the day a diurnalvariation in NOx and NOy was observed withamplitudes as large as 30–40 pptv. The source ofactive nitrogen is attributed to release from the snowsurface by a process that is apparently sensitized bysunlight. If the source from the snowpack is a largescale feature of the Arctic then the diurnal trendsalso require a competing process for removal to thesurface. From the diurnal change in the NO/NO2ratio, mid-April mixing ratios for the sum of peroxyand halogen oxide radicals of 10 pptv werederived for periods when ozone mixing ratios were inthe normal range of 30–50 ppbv. Mid-day ozoneproduction and loss rates with the active nitrogensource were estimated to be 1–2 ppbv/day and in nearbalance. NOy mixing ratios which averaged only295±66 pptv do not support a large accumulation inthe high Arctic surface layer in the winter and springof 1998. The small abundance of NOy relative tothe elevated mixing ratios of other long-livedanthropogenic constituents requires that reactivenitrogen be removed to the surface during transport toor during residence within the high Arctic.  相似文献   

3.
Field data for the unstable, baroclinic, atmospheric boundary layer over land and over the sea are considered in the context of a general similarity theory of vertical heat transfer. The dependence of δθ/θ* upon logarithmic functions of h c z T and stability (through the similarity function C) is clearly demonstrated in the data. The combined data support the conventional formulation for the heat transfer coefficient δθ/θ* when,
  1. the surface scaling length is z T (« z 0), the height at which the surface temperature over land is obtained by extrapolation of the temperature profile
  2. the height scale is taken as the depth of convective mixing h c
  3. the temperature profile equivalent of the von Karman constant is taken as 0.41
  4. areal average, rather than single point, values of δθ are employed in strongly baroclinic conditions. No significant effect of baroclinity or the height scale ratio as proposed in the general theory is found. Variations in C about a linear regression relation against stability are most probably due to uncertainties in the areal surface temperature and to experimental errors in general temperature measurements.
  相似文献   

4.
A modified infrared CO2 gas analyzer, a small thermocouple assembly, a heated-thermocouple anemometer for horizontal wind, and a propeller-type vertical wind sensor were used to measure the eddy fluxes of heat and CO2 above a corn crop. Experimental results of these fluxes are discussed. The main sources of errors of the eddy fluxes using these instruments were estimated:
  1. Sensors with a time constant of 0.5 s appear to be fast enough to detect most of the vertical CO2 transfer as long as the sensors are located at least one meter above the crop surface.
  2. The deviation from steady-state conditions for 10-min periods was found to have a significant effect on the eddy flux estimates.
  3. Temperature fluctuations of the air sample passing through the CO2 infrared gas analyzer were found to be non-negligible but could be easily corrected.
  4. A 1° misalignment of the vertical anemometer affected these eddy fluxes by less than 10% under all circumstances studied.
  相似文献   

5.
Simultaneousindependent measurements of NOy and NOx(NOx= NO + NO2) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NOxmixing ratio was 27 pptv and did not show any cyclethrough the period. The NOy mixing ratio showeda maximum in late March, while the difference betweenNOy and PAN decreased during spring. This is anindication of the dominance of PAN in the NOybudget in the Arctic, but possible changes in theefficiency of the NOy converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.  相似文献   

6.
Local ozone production and loss rates for the arctic free troposphere (58–85° N, 1–6 km, February–May) during the TroposphericOzone Production about the Spring Equinox (TOPSE) campaign were calculated using a constrained photochemical box model. Estimates were made to assess the importance of local photochemical ozone production relative to transport in accounting for the springtime maximum in arctic free tropospheric ozone. Ozone production and loss rates from our diel steady-state box model constrained by median observations were first compared to two point box models, one run to instantaneous steady-state and the other run to diel steady-state. A consistent picture of local ozone photochemistry was derived by all three box models suggesting that differences between the approaches were not critical. Our model-derived ozone production rates increased by a factor of 28 in the 1–3 km layer and a factor of 7 in the 3–6 kmlayer between February and May. The arctic ozone budget required net import of ozone into the arctic free troposphere throughout the campaign; however, the transport term exceeded the photochemical production only in the lower free troposphere (1–3 km) between February and March. Gross ozone production rates were calculated to increase linearly with NOx mixing ratiosup to 300 pptv in February and for NOx mixing ratios up to 500 pptv in May. These NOx limits are an order of magnitude higher thanmedian NOx levels observed, illustrating the strong dependence ofgross ozone production rates on NOx mixing ratios for the majority of theobservations. The threshold NOx mixing ratio needed for netpositive ozone production was also calculated to increase from NOx 10pptv in February to 25 pptv in May, suggesting that the NOx levels needed to sustain net ozone production are lower in winter than spring. This lower NOx threshold explains how wintertime photochemical ozone production can impact the build-up of ozone over winter and early spring. There is also an altitude dependence as the threshold NOx neededto produce net ozone shifts to higher values at lower altitudes. This partly explains the calculation of net ozone destruction for the 1–3 km layerand net ozone production for the 3–6 km layer throughout the campaign.  相似文献   

7.
Ground based measurements which were carried out in the Northern Sahel in southern Tunisia showed the following results:
  1. The albedo difference between ground and protected land is about 10%, half of the amount Charney (1975) used in his model.
  2. Bare soil is always warmer during times of bright sunshine than vegetated soil, which is in agreement with Jackson and Idso (1975). Temperature differences in excess of the 10 °C were observed between plants and the surrounding soil.
  3. For bare soil, the surface temperature increases with declining albedo. However the opposite holds true for plants. Here, when lowering the albedo, a decrease in temperature was found.
  4. In a sand dune field, the surface temperature depends strongly on the exposure. Surface temperature differences of 8 °C were observed for slopes of different exposures for measurements carried out around noon.
  相似文献   

8.
Surface NO and NO2 mixing ratios were measured aboard the research vessel Polarstern during the mission ANT VII/1 from 24 September to 5 October 1988. The measurements were taken along the meridian at 30° W in the Atlantic region covering latitudes between 30° N and 30° S. The average mixing ratios were about 12 pptv NO/30 pptv NO2 in the Northern Hemisphere and about 7 pptv NO/22 pptv NO2 in the Southern. Elevated mixing ratios of 20 pptv NO/70 pptv NO2 were found at 12° N (probably due to air masses originating from the surface of West Africa) and in the region of the ITCZ between 8° N and 5° N. Because of probable contamination by the ship, the measured mixing ratios mostly represent upper limits.  相似文献   

9.
Analysis of wind profiles at the Boulder Tower (BAO) leads to these conclusions:
  1. The variation of roughness with wind direction found earlier is confirmed. Roughness lengths measured on the tower are larger than those measured close to the surface.
  2. The profiles and measurements of Reynolds stress are consistent with a von-Karman constant of 0.35.
  3. The form φm=(1?15z/L)-1/3 fits best in the range -0.6 < z/L < 0. In the range 0 < z/L < 0.5, θ m ～ 1 + 4.7z/L provides a good fit to the observations. For z/L < 0.1, φ m also depends on h, the thickness of the PBL. For z/L < -0.6, Φ m approaches the constant 0.5, in contrast to all previous suggestions. For larger stabilities, the upper level is usually not in the surface layer, and wind ratios become independent of z/L.
  4. With snow cover, the effective roughness diminishes to about 1 cm, even for directions for which the roughness length without snow is large.
  5. Estimation of winds at 100 or 150 m from information near the surface is best for similarity theory provided that the ratio of height to Monin-Obukhov L is less than 0.1. For larger z/L, simple power laws seem more appropriate.
  相似文献   

10.
A numerical experiment has been conducted on the OH-initiated tropospheric oxidation of DMS. This involved the selection of a set of reactions describing the OH-initiated oxidation kinetics and the conversion of the present level of uncertainty of the system into uncertainty ranges and distributions for the relevant system parameters (kinetic constants and initial concentrations). Uncertainties have been propagated through the model onto the output variables of interest. This has allowed (a) the uncertainty in model prediction to be quantified and compared with observations (uncertainty analysis) and (b) the relative importance of each input parameter in determining the output uncertainty to be quantified (sensitivity analysis). Output considered were the ratio of MSA/(SO2 + H2SO4) concentration at a given time, the ratio SO2/H2SO4, the total peroxynitrate species concentrations and the relative fraction of SO2 and H2SO4 formed through the various pathways. Conditional upon the model and data assumptions underlying the experiment, the following main conclusions were drawn:
  1. The possibility of direct formation of SO3 without SO2 as intermediate as suggested by Bandyet al. (1992) and Yinet al. (1990), involving direct thermal decomposition of CH3SO3 · does not seem to play a major role in the overall generation of sulphate. This is relevant to the issue of gas to particle conversion over remote areas.
  2. Reaction of CH3SOO · intermediate may be the most important pathway to the formation of SO2.
  3. The dominating peroxynitrate is CH3S(O)2O2NO2.
Through sensitivity analysis the kinetic constants have been identified which — because of their uncertainty and of their impact on the output — mostly contribute to the output uncertainty.  相似文献   

11.
Atmospheric boundary layer research at Cabauw   总被引：1，自引：1，他引：0  
At Cabauw, The Netherlands, a 213 m high mast specifically built for meteorological research has been operational since 1973. Its site, construction, instrumentation and observation programs are reviewed. Regarding analysis of the boundary layer at Cabauw, the following subjects are discussed:
  • - terrain roughness;
  • - Monin-Obukhov theory in practice;
  • - the structure of stable boundary layers;
  • - observed evolution of fog layers;
  • - inversion rise and early morning entrainment;
  • - use of the geostrophic wind as a predictor for wind profiles;
  • - height variation of wind climate statistics;
  • - air pollution applications: long range transport and short range dispersion;
  • - dependence of sound wave propagation on boundary-layer structure;
  • - testing of weather and climate models.
    •   相似文献   

    12.
    Springtime measurements of NOx, ozone, PAN,J(NO2), and other compounds were made near Ny-Ålesund,Svalbard (78°54N, 11°53E), in 1994 and Poker Flat,Alaska (65°08N, 147°29W), in 1995. At Svalbard medianmixing ratios for PAN and NOx of 237 and 23.7 pptv,respectively, were observed. The median mixing ratios at Poker Flat for PANand NOx were 79.5 and 85.9 pptv, respectively. These data areused to estimate thermal PAN decomposition using several differentapproaches. At Svalbard PAN decomposition was very small, while at PokerFlat up to 30 pptv/h PAN decomposed. At both sites the NOx/PANratio increased with temperature between –10 and 20°C implyingthat PAN decomposition is an important NOx source. In-situozone production was calculated from the measured NO, NO2,O3, J(NO2), and temperature data, using thesteady state assumption Median ozone production was 605 pptv/h at PokerFlat, and one order of magnitude smaller at Svalbard during the daytime.Only at Poker Flat could a direct influence on the diurnal ozone cycle beobserved from in-situ production. These results imply that PAN decompositionis a major source of NOx in the high latitude troposphere, andthat this contributes to the observed spring maximum in surface ozone.  相似文献   

    13.
    Cross-spectra between horizontal wind components at different levels of the Boulder Atmospheric Observatory (BAO) tower lead to the following conclusions:
    1. Davenport's hypothesis is satisfied that coherence decays exponentially with the ratio of vertical separation to horizontal wave length, at least to very small values of coherence.
    2. The decay coefficients increase with z/L for z/L < 0.5. For larger stabilities, irregular fluctuations with periods of order 10–20 min have considerable vertical coherence. Results at BAO are quite consistent with those elsewhere.
    3. Eddy slopes in vertical planes increase with wind shear up to a point where the slope (horizontal delay over vertical separation) is just above 2. Beyond that point, the systematic increase of slopes with shear ceases. Since wind shear decreases upward, slopes tend to decrease upward. Slopes for lateral components are significantly larger than those for u-components.
      相似文献   

    14.
    A simplified land-surface parameterization is tested against bare-soil data collected during the EFEDA experiment conducted in Spain in June 1991. A complete data set, made up of soil properties as well as hydrological and atmospheric measurements, is described and discussed. The 11-day data set is characterized by very dry conditions and high surface temperatures during the day. Large values of sensible and soil heat fluxes and small values of surface evaporation (≈1 mm/day) were observed. This data set was modelled, leading to the following conclusions:
    1. In the model, the parameterization provides values of the soil thermal properties and subsequently of the predicted soil heat fluxes which are overestimated when compared with the observations.
    2. Following the literature, a value of the ratio between the roughness lengths for momentumZ oand heatZ ohof close to 10 for fairly homogeneous areas of bare soil and vegetation is used. This value leads to a fair prediction of the surface temperature. If the roughness lengths were taken to be equal, as is often assumed in atmospheric modelling, a poorer prediction results.
    3. Finally, the vapor phase transfer mode is found dominant close to the surface and a modified parameterization including this effect is proposed. It allows a fair prediction of both surface evaporation and near-surface water content.
      相似文献   

    15.
    In July 1974 an NO/O3 chemiluminescent instrument was used to obtain measurements of NO in the stratosphere during two balloon flights launched from Churchill (59°N, 95°W). On the first flight, an altitude profile was obtained in which the NO volume mixing ratio was observed to increase from 0.3 to 2.7 ppbv between 19 and 29.5 km. On the second flight, the mixing ratio was observed to increase from 0.25 to 2.7 ppbv between 19 and 29 km and to remain almost constant at about 2.7 ppbv from 29 to 34.5 km. On this flight, the sunset decay of NO was also obtained while the payload was at a constant float altitude of 34.5 km. These decay measurements are compared satisfactorily with the results obtained from a time dependent stratospheric model.  相似文献   

    16.
    This article presents the results of a study of the relationship between rainfall and Normalized Difference Vegetation Index (NDVI) in East Africa and the Sahel. Monthly data for the years 1982 to 1985 have been analyzed. We have evaluated NDVI-rainfall relationships by vegetation type, using the major formations described by White (1983). In the article, a comparison of the differential response of vegetation growth to rainfall in the two study regions is emphasized. The most important conclusions of our research are as follows:
    1. The spatial patterns of annually-integrated NDVI closely reflect mean annual rainfall.
    2. There is a good relationship between rainfall variations and NDVI on seasonal and interannual time scales for areas where mean annual rainfall ranges from approximately 200 to 1200 mm.
    3. In most cases, NDVI is best correlated with the rainfall total for the concurrent plus two antecedent months; the correlation is better in the Sahel than in East Africa.
    4. The ratios of NDVI to rainfall are considerably higher in East Africa than in the Sahel.
    5. Mean annually-integrated NDVI is linearly related to mean annual rainfall in the Sahel. In East Africa the relationship is approximately log-linear; above some threshold value of rainfall, NDVI values level off and vary minimally with rainfall.
    Two possible explanations of this last conclusion are suggested: above this threshold, rainfall is no longer the limiting factor in vegetation growth and/or NDVI is not a good indicator of vegetation growth. The latter is a likely possibility since NDVI directly reflects photosynthetic activity and becomes a poor indicator of biomass (i.e., growth) as high canopy densities are reached. The NDVI-rainfall relationship for East Africa is markedly similar to the relationship between NDVI and Leaf Area Index demonstrated by Sellers (1985) and Asrar et al. (1984).  相似文献   

    17.
    Alkyl nitrate yields from the NO x photooxidations of neopentane, 2-methylbutane and 3-methylpentane have been determined over the temperature and pressure ranges 281–323 K and 54–740 torr, respectively. The formation of the alkyl nitrates is attributed to the reaction pathway (1b) $${\text{RO}}_{\text{2}} + {\text{NO}}^{{\text{ }}\underrightarrow {\text{M}}} {\text{ RONO}}_{\text{2}}$$ and rate constant ratios k 1b/(k 1a+k 1b) are estimated, where (1a) is the reaction pathway (1a) $${\text{RO}}_{\text{2}} + {\text{NO}} \to {\text{RONO}}_{\text{2}} .$$ A method for estimating this rate constant ratio for primary, secondary and tertiary alkyl peroxy radicals is presented.  相似文献   

    18.
    Multiple windbreaks: An aeolean ensemble   总被引：1，自引：0，他引：1  
    Near-neutral measurements of the turbulent wind field within and above a sequence of 15 parallel windbreaks on a flat pastoral site are presented. The windbreak fences each had a porosity of 60% and were equally-spaced at 6 times their height (h = 2 m). The following conclusions seem justified for wind directions within 10 ° of the normal to the array:
    1. Above the windbreaks (2h), mean windspeeds first decreased and then increased asymptotically to a value in equilibrium with the new surface roughness. At 0.5h, windspeeds exhibited a slow increase down the entire array.
    2. Reflecting differences in approach flows, the drag on the initial fence was almost twice that on barriers farther downstream. This reduction in momentum extraction per windbreak was associated with an elevation in the zero-plane displacement to a level equal to 0.8h.
    3. At positions well-removed from the initial fences, mean windspeeds were reduced throughout the entire region below shelter height. In this region, the flow became increasingly dominated by downward moving air with velocities much greater than the local average. The zone of reduced turbulence was small, extending only 2h downstream of a barrier at a height of 0.25h. This corresponded with the region excluded from smoke trails released at the top of windbreaks.
    4. An approximate TKE budget mid-way between windbreaks 7 and 8 suggests that shear and wake production peak near z = h and that production is balanced by dissipation and vertical transport components. Advective and inertial interaction terms are negligible at this midway position but are likely to be major sources of TKE closer to the windbreak. Local equilibrium is attained above z = 1.5h implying the existence of a constant-stress layer.
    The measurements show the practical difficulty of simultaneously reducing both mean windspeeds and turbulence levels with repeated windbreaks at conventional spacings for horticultural applications.  相似文献   

    19.
    Important findings on the consequences of climate change for agriculture and forestry from the recently completed Third Assessment Report (TAR) of the Intergovernmental Panel on Climate Change (IPCC) are reviewed, with emphasis on new knowledge that emerged since the Second Assessment Report (SAR). The State-Pressure-Response-Adaptation model is used to organize the review. The major findings are:
    • Constant or declining food prices are expected for at least the next 25 yr, although food security problems will persist in many developing countries as those countries deal with population increases, political crisis, poor resource endowments, and steady environmental degradation. Most economic model projections suggest that low relative food prices will extend beyond the next 25 yr, although our confidence in these projections erodes farther out into the 21st century.
    • Although deforestation rates may have decreased since the early 1990s, degradation with a loss of forest productivity and biomass has occurred at large spatial scales as a result of fragmentation, non-sustainable practices and infrastructure development.
    • According to United Nations estimates, approximately 23% of all forest and agricultural lands were classified as degraded over the period since World War II.
    • At a worldwide scale, global change pressures (climate change, land-use practices and changes in atmospheric chemistry) are increasingly affecting the supply of goods and services from forests.
    • The most realistic experiments to date – free air experiments in an irrigated environment – indicate that C3 agricultural crops in particular respond favorably to gradually increasing atmospheric CO2 concentrations (e.g., wheat yield increases by an average of 28%), although extrapolation of experimental results to real world production where several factors (e.g., nutrients, temperature, precipitation, and others) are likely to be limiting at one time or another remains problematic. Moreover, little is known of crop response to elevated CO2 in the tropics, as most of the research has been conducted in the mid-latitudes.
    • Research suggests that for some crops, for example rice, CO2 benefits may decline quickly as temperatures warm beyond optimum photosynthetic levels. However, crop plant growth may benefit relatively more from CO2 enrichment in drought conditions than in wet conditions.
    • The unambiguous separation of the relative influences of elevated ambient CO2 levels, climate change responses, and direct human influences (such as present and historical land-use change) on trees at the global and regional scales is still problematic. In some regions such as the temperate and boreal forests, climate change impacts, direct human interventions (including nitrogen-bearing pollution), and the legacy of past human activities (land-use change) appear to be more significant than CO2 fertilization effects. This subject is, however an area of continuing scientific debate, although there does appear to be consensus that any CO2 fertilization effect will saturate (disappear) in the coming century.
    • Modeling studies suggest that any warming above current temperatures will diminish crop yields in the tropics while up to 2–3 °C of warming in the mid-latitudes may be tolerated by crops, especially if accompanied by increasing precipitation. The preponderance of developing countries lies in or near the tropics; this finding does not bode well for food production in those countries.
    • Where direct human pressures do not mask them, there is increasing evidence of the impacts of climate change on forests associated with changes in natural disturbance regimes, growing season length, and local climatic extremes.
    • Recent advances in modeling of vegetation response suggest that transient effects associated with dynamically responding ecosystems to climate change will increasingly dominate over the next century and that during these changes the global forest resource is likely to be adversely affected.
    • The ability of livestock producers to adapt their herds to the physiological stress of climate change appears encouraging due to a variety of techniques for dealing with climate stress, but this issue is not well constrained, in part because of the general lack of experimentation and simulations of livestock adaptation to climate change.
    • Crop and livestock farmers who have sufficient access to capital and technologies should be able to adapt their farming systems to climate change. Substantial changes in their mix of crops and livestock production may be necessary, however, as considerable costs could be involved in this process because investments in learning and gaining experience with different crops or irrigation.
    • Impacts of climate change on agriculture after adaptation are estimated to result in small percentage changes in overall global income. Nations with large resource endowments (i.e., developed countries) will fare better in adapting to climate change than those with poor resource endowments (i.e., developing countries and countries in transition, especially in the tropics and subtropics) which will fare worse. This, in turn, could worsen income disparities between developed and developing countries.
    • Although local forest ecosystems will be highly affected, with potentially significant local economic impacts, it is believed that, at regional and global scales, the global supply of timber and non-wood goods and services will adapt through changes in the global market place. However, there will be regional shifts in market share associated with changes in forest productivity with climate change: in contrast to the findings of the SAR, recent studies suggest that the changes will favor producers in developing countries, possibly at the expense of temperate and boreal suppliers.
    • Global agricultural vulnerability is assessed by the anticipated effects of climate change on food prices. Based on the accumulated evidence of modeling studies, a global temperature rise of greater than 2.5 °C is likely to reverse the trend of falling real food prices. This would greatly stress food security in many developing countries.
      相似文献   

    20.
    A model with spectral microphysics was developed to describe the scavenging of nitrate aerosol particles and HNO3 gas. This model was incorporated into the dynamic framework of an entraining air parcel model with which we computed the uptake of nitrate by cloud drops whose size distribution changes with time because of condensation, collision-coalescence and break-up. Significant differences were found between the scavenging behavior of nitrate and our former results on the scavenging behavior of sulfate. These reflect the following chemical and microphysical differences between the two systems:
    1. nitrate particles occur in a larger size range than sulfate particles.
    2. HNO3 has a much greater solubility than SO2 and is taken up irreversibly inside the drops in contrast to SO2.
    3. nitric acid in the cloud water is formed directly on uptake of HNO3 gas whereas on uptake of SO2 sulfuric acid is formed only after the reaction with oxidizing agents such as e.g., H2O2 or O3.
    4. nitrate resulting from uptake of HNO3 is confined mainly to small drops, whereas sulfate resulting from uptake of SO2 is most concentrated in the largest, oldest drops, which have had the greatest time for reaction.
    Sensitivity studies showed that the nitrate concentration of small drops is significantly affected by the mass accommodation coefficient.  相似文献   

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