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1.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

2.
A pair of parallel cold wires separated in either the vertical or lateral direction was used to obtain the three components x, y, z of the temperature derivative in the streamwise, lateral and vertical directions, respectively. The average absolute skewness values of x and z are nonzero and approximately equal, while the skewness of y is approximately zero. These results appear to be consistent with the presence of a large, three-dimensional organised structure in the surface layer. There is an apparent low-frequency contamination in the spectral density of y and z due mainly to small errors in estimating the sensitivity of the cold wires. The temperature derivatives were high-pass filtered, the filter being set to remove possible contributions from the large structure and to minimise low-frequency sensitivity contamination. The filtered rms ratios \~x/\~y and \~x/\~z were in the range 0.7 to 0.9, a result in qualitative agreement with that obtained in the laboratory boundary layer by Sreenivasan et al. (1977). The skewness of filtered x or z is negligible, consistent with local isotropy of small-scale temperature fluctuations and in support of the high wavenumber spectral isotropy discussed in Antonia and Chambers (1978).  相似文献   

3.
Recently Wilson and Flesch (Boundary-Layer Meteorology, 84, 411-426, 1997) suggested that the average increment d z to the orientation = arctan(w/u) of the Lagrangian velocity-fluctuation vector can be used to distinguish the better Lagrangian stochastic models within the well-mixed class. Here it is demonstrated that the specification of d z constitutes neither a sufficient or universally applicable criterion to distinguish the better Lagrangian stochastic models within the well-mixed class. The hypothesis made by Wilson and Flesch that Lagrangian stochastic models with /PE irrotational are zero-spin models, having d z=0, is proven  相似文献   

4.
In the summer of 1988/89 flights were carried out in the Coorong coastal area of South Australia to investigate sea-breeze fronts. The flights yielded data sets of the structure of the fronts in the cross-frontal direction with a spatial resolution of approximately 3 m. The study is focused on the budgets of sensible and latent heat in the vicinity of the front and on frontogenesis/frontolysis processes which are closely related to budget considerations.The frontogenesis relationships and the budgets were established on a 2 km length scale by low-pass filtering of the space series. As the wind components were measured with high accuracy, all processes which determine frontogenesis could be evaluated and are displayed in x,z-cross-sections: these are the confluence, shear and diabatic effects, all of which play a role in q/x-, q/z-, /x- as well as /z-frontogenesis. A detailed analysis is given for two different states of frontal development. The presented results shed much light on the governing physical processes in the frontal region with strong emphasis on the effects of confluence-generated updrafts, on shear instabilities causing bulges and clefts in the frontal surface as well as producing the elevated frontal head, and on processes related to differential heating and moistening.  相似文献   

5.
It is shown that for the purpose of trajectory simulation, the vertical velocityw L (t) of a fluid element, which is moving in a system (such as a forest canopy, or the unstably stratified atmospheric surface layer) whose turbulent velocity scale w is height-dependent, must be chosen from a frequency-distribution which is asymmetric aboutw L = 0. If the gradient w /z varies only slowly with height, correct trajectories may be obtained by adding a bias (where L is the length scale) to a fluctuating velocity chosen from a symmetric distribution with variance w 2(z).  相似文献   

6.
From measured one-dimensional spectra of velocity and temperature variance, the universal functions of the Monin-Obukhov similarity theory are calculated for the range –2 z/L + 2. The calculations show good agreement with observations with the exception of a range –1 z/L 0 in which the function m , i.e., the nondimensional mean shear, is overestimated. This overestimation is shown to be caused by neglecting the spectral divergence of a vertical transport of turbulent kinetic energy. The integral of the spectral divergence over the entire wave number space is suggested to be negligibly small in comparison with production and dissipation of turbulent kinetic energy.Notation a,b,c contants (see Equations (–4)) - Ci constants i=u, v, w, (see Equation (5) - kme,kmT peak wave numbers of 3-d moel spectra of turbulent kinetic energy and of temperature variance, respectively - kmi peak wave numbers of 1-d spectra of velocity components i=u, v, w and of temperature fluctuations i= - ksb, kc characteristics wave numbers of energy-feeding by mechanical effects being modified by mean buoyancy, and of convective energy feeding, respectively - L Monin-Obukhov length - % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% Gabeivayaaraaaaa!3C5B!\[{\rm{\bar T}}\] difference of mean temperature and mean potential temperature - T* Monin-Obukhov temperature scale - velocity of mean flow in positive x-direction - u* friction velocity - u, v, w components of velocity fluctuations - z height above ground - von Kármanán constant - temperature fluctuation - m nondimensional mean shear - H nondimensional mean temperature gradient - nondimensional rate of lolecular dissipation of turbulent kinetic energy - D nondimensional divergence of vertical transports of turbulent linetic energy  相似文献   

7.
Summary The effect of the Alpine orography on prototype cold fronts approaching from the west is investigated by three-dimensional numerical model simulations. The numerical experiments cover a range of parameter constellations which govern the prefrontal environment of the front. Especially, the appearance and intensity of prefrontal northern Alpine foehn varies from case to case.The behaviour of a cold front north of the Alps depends much on the prefrontal condition it encounters. It is found that prefrontal foehn can either accelerate or retard the approaching front.An important feature is the pressure depression along the northern Alpine rim that results from the southerly foehn flow. In cases where this depression compensates the eastward directed pressure gradient associated with the largescale flow, the front tends to accelerate and the foehn breaks down as soon as the front passes. In contrast, the foehn prevents the front from a rapid eastward propagation if it is connected with a strong southerly wind component.No-foehn experiments are performed for comparison, where either the mountains are removed, or the static stability is set to neutral. Also shown are effects of different crossfrontal temperature contrasts.List of Symbols c F propagation speed of a front - x, y horizontal grid spacing (cartesian system) - , horizontal grid spacing (geographic system) - t time step - z vertical grid spacing (cartesian system) - cross-frontal potential temperature difference - i potential temperature step at an inversion - E turbulent kinetic energy - f Coriolis parameter - FGP frontogenesis parameter (see section 2.2) - g gravity acceleration (g=9.81 m s–2) - vertical gradient of potential temperature - h terrain elevation (above MSL) - h i height of an inversion (h i =1000 m MSL) - H height of model lid (H=9000 m MSL) - K M exchange coefficient of momentum - K H exchange coefficient of heat and moisture - longitude - N Brunt-Väisäla-frequency - p pressure - Exner function (=T/) - latitude - q v specific humidity - R d gas constant of dry air (R d =287.06 J kg–1 K–1) - density of dry air - t time - T temperature - potential temperature - TFP thermal front parameter (see section 2.2) - u, v, w cartesian wind components - u g ,v g geostrophic wind components - horizontal wind vector - x, y, z cartesian coordinates Abbreviations GND (above) ground level - MSL (above) mean sea level - UTC universal time coordinated With 20 Figures  相似文献   

8.
Summary A fixed platform (Fig.3), installed 100 m from the shoreline in 3 m water depth, was instrumented with velocity, temperature and wave-height sensors. 132 data (10 minutes averages) were analysed to calculate the wind stress; from these, 99 data were used to investigate the vertical distribution of the wind stress; all data are presented with Table 1.It was postulated that the total stress, t being constant with height, is made up additively of two components, the wave-supporting stress, w , and the turbulent stress, c ; see Eq. 1. The vertical distribution of these two components is shown schematically in Fig. 1.The total stress, t , evaluated outside the zone of wave influence, is given in the classical way with Fig. 4. The wave-supporting stress, w (z), was evaluated from the data according to a relation proposed by Kitaigorodskii et al. (1984); it is given with Fig. 5. A height-dependency is clearly evident. The turbulent stress c (z), was evaluated with data of the velocity gradient; it is given with Fig. 6. A height-dependency is not evident.The field data from the lake of Geneva give evidence that the additive relation of Eq. 1 seems to be justified.With 6 Figures  相似文献   

9.
This is one of a series of papers on the Askervein Hill Project. It presents results on the variations in mean wind speed at fixed heights (z) above the ground from linear arrays of anemometer posts and towers. Most of the data are for z = 10 m but some are for z = 3 m. Selected and directionally grouped data from the 55 Mean Flow runs are presented together with mean flow data from Askervein '83 Turbulence runs. Comparisons are made between the data and guideline estimates of fractional speed-up ratio at hilltop locations and between the data and MS3DJH/3 model predictions along the tower lines. There is good agreement in most cases.  相似文献   

10.
To investigate tubulence characteristics and organized motion within and above an urban canopy, field observations were conducted in July 1991 and November 1992 in Sapporo, Japan. The measurement heights were 5.4, 10.3, 18, 35 and 45 m above ground; the canopy height was 7 m. The profiles of u peaked slightly above the canopy, while v and w had nearly uniform profiles. Vertical profiles of Reynolds stress - peaked slightly at 1.5 times the canopy height and decreased slowly with height thereafter. A four-quadrant analysis showed that sweep and ejection motions caused high-velocity fluid from above moves downward toward the surface and low-velocity fluid from below moves upward. An ensemble-averaging technique was used to isolate typical features of the flow and temperature fields. A time-height cross-section of velocity vectors and temperature contours showed details of the flow structures associated with temperature ramps. It has been noted that the organized motions play important roles in the transport of heat near the urban canopy, where the sweep motion causes negative temperature fluctuations and the ejection motion causes positive temperature fluctuations.  相似文献   

11.
Horizontal u and vertical w velocity fluctuations have been measured together with temperature fluctuations in the atmospheric surface layer, at a small height above a wheat crop canopy. Marginal probability density functions are presented for both individual fluctuations u, w, and for the instantaneous Reynolds stress uw, and heat fluxes w and u. Probability density functions of the velocity fluctuations deviate less significantly from the Gaussian form than the probability density of temperature. There appears to be closer similarity between statistics of the instantaneous heat fluxes than between the momentum flux and either of the heat fluxes investigated. The mean momentum flux receives equal contributions from the events referred to as ejections and sweeps in laboratory boundary layers. Sweeps provide the largest contribution to the heat fluxes.  相似文献   

12.
Turbulence characteristics in a near neutrally stratified urban atmosphere   总被引：4，自引：1，他引：4  
Turbulence measurements from the city of Uppsala, Sweden, are analysed. Measurements were taken at two sites: one in the central area, ca. 6 m above roof level, the average building height being ca. 15 m; the other at ca. 8 and 50 m above the ground on a tower situated 100 m downwind of a sharp discontinuity between the densely built-up urban area and flat grass-covered land. The average stability was close to neutral, the range being -0.2 < z/L < 0.2. The main emphasis of the study is on the non-dimensional standard deviations of the velocity components i /u *t and on the corresponding non-dimensional energy spectra, u *t being a local velocity scale defined as i /( l is the local momentum flux). Comparison with results obtained from surface-layer measurements at ideal sites (with u *, being the ordinary friction velocity) shows good general agreement. The most complete agreement is found for the tower 50 m measurements, a result which is notable as this measurement point is found to be within a distinctly transitional zone between the urban and post-urban boundary layers. The results from the central city measurement point are also fairly close to the ideal results, the deviations found being small in view of the fact that the site is probably inside the layer in which the roughness elements (the buildings) have direct influence. The measurements at the tower 8 m level show certain distinct deviations from ideal results: all three i /u *l , are higher by ca. 10%, the excessive energy being found at the low frequency end of the spectrum. Arguments are presented for this feature to be due to a spectral lag effect.  相似文献   

13.
The impact of urbanization is assessed by comparing values of the radiation parameters at an urban location with those of a rural site. Urban Delhi was divided according to land-use and the effects of urbanization was studied on incoming short-wave (K), albedo, incoming longwave (L, outgoing longwave (L), and net radiation (Q *), were individually studied at four representative sites (Rural, Commercial, Residential and Industrial). MaximumK was observed in the rural and commercial areas whereas highL was observed in the commercial and industrial locations. High depletion ofK of the order of 13% was observed for the industrial location in the winter season. An increase ofL in, the industrial location is of the same order as that of the commercial location, i.e. 20%. The residential location shows quite moderate (4.6%) depletion ofK in comparison with other sites.Nomenclature U Urban - R Rural - K Incoming Short-wave radiation - L Incoming Long-wave radiation - L Outgoing Long-wave radiation - Q * Net Radiation - Albedo - K * Net Short-wave radiation - L * Net Long-wave radiation  相似文献   

14.
Summary A dispersion model is proposed to predict the continuous vertical variation of the dispersion parameters y and z in case of hot pollutant release to the atmosphere. In such a case, the plume rises far above the ground and is subject to varying levels of turbulence. The framework in this paper can be divided into three approaches: (1) determination of the eddy diffusivitiesK y (z, y ) andK z (z, z ) as functions of height above ground and plume dimensions, (2) determination of both the plume rise and its vertical velocity using a modified version of Brigg's formula, and (3) numerical solution of actual problems with buoyant plumes at each time step. The model results have been applied to a case of pollutant release from fire destruction of a chemical storehouse roof.With 15 Figures  相似文献   

15.
Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.  相似文献   

16.
In a recent paper, the author introduced a new viscous boundary layer, called the mesolayer, in turbulent shear flow. Its importance stems from its location between the inner and outer regions which are controlled by the law of the wall and Reynolds number similarity, respectively. This intrusion prevents the classical overlap assumption which appears to be fundamental in the derivation of the classical logarithmic behavior. The mesolayer has a thickness proportional to Taylor's microscale . This, and the analogy between the energy equation for the spectrum function of isotropic turbulence and the momentum equation for shear flow, suggest the existence of a similar region in wavenumber space with wavenumber k ~ -1. This mesoregion separates the inner region k ~ k s(where k s-1 and is the Kolmogorov length) and the outer region k k e(where k e -1 and l is the energy-containing eddy size) and again invalidates the overlap assumption which appears to be fundamental in the derivation of the classical k -5/3-behavior of the inertial subrange.Incorporation of the mesoregion into the argument leads to a new theory with k -5/3-behavior in two regions (-1 k k s) and (k e k -1) although with two different coefficients of proportionality (Kolmogorov constants). This leads to a wandering of the spectrum curve about the classical k -5/3 line similar to a wandering in turbulent shear flow about the logarithmic curve. This is clearly indicated by the data for the variation of the Kolmogorov constant.Other data support the new theory. In particular, the location of the point k mwhere the curve of the nonlinear energy-transfer function goes through zero shows agreement with the theory, i.e., k m-1.  相似文献   

17.
The commonly reported temperature coefficient of P. the equilibrium partial pressure of CO2, is (P/T) A,C ,which is about 15 ppm/°C, or 5% of the atmospheric partial pressure of CO2. This coefficient, however, applies only to deep water, not to surface water which can exchange CO2 with the atmosphere. The coefficient (P/T) A,C ,, where designates constancy of the sum of atmospheric and surface-ocean CO2, is the appropriate value for air-sea exchange. Numerical values are mass-dependent because the depth of the exchanging ocean layer must be specified. For a 100-m surface layer, the value is ca. 1.5 ppm/°C, or 0.5% of ambient CO2. Editor's Note:In view of the interdisciplinary importance of the carbon dioxide-climate problem, this note on seawater chemistry should be of interest to specialists beyond the discipline of ocean chemistry.  相似文献   

18.
A study of the temperature field for the Baltimore-Washington region reveals that since 1950 there has been the development of an urban heat corridor. Trend surface analysis shows that there has been an inversion of the thermal topography in the region as a saddle of rising temperatures has emerged, replacing a trough of lowered temperatures through three decades. Steady population growth throughout the area is seen to be the most important contributor. The strengthening of the heat corridor is best expressed in the summer months and weakest during the winter months. As population continues to grow in this region, the thermal topography is sure to be modified even further.It is recommended that further study be devoted to temperature and precipitation changes in regions experiencing urban growth.  相似文献   

19.
This study details the observed effects ofatmospheric stability on characteristics of thesurface layer in a low wind speed (U = 1.5 m s-1)regime of tropical West Africa. Theaerodynamic roughness length, z0, anddisplacement height, d, obtained from profilewind-speed data at our bush land site (height 2 m)have values of 0.24 ± 0.10 m and 1.54 ± 0.04 mrespectively. In the unstable range (-2.5 < Ri < -0.1; Riis gradient Richardson number), thestandard deviation in wind speed fluctuations, u, increased from 0.57 ± 0.19 m s-1 toa maximum of 0.7 ± 0.2 m s-1 in near-neutralconditions, and in the stable range, the parameterdecreased rapidly to 0.41 ± 0.15 m s-1 at Ri 0.2.In the same stability range, the horizontal winddispersion, , decreased withincreasing stability from 19 ± 8 deg. to 13 ± 5 deg.The surface-layer integral quantity, u/u*, when plottedas a function of stability, is in agreement with theempirical results. The ratio ofsensible heat flux (estimated) to the net radiationranged between 0.1 and 0.2 at nighttime,increasing to about 0.5 during the daytime, and showeda strong dependency on season.  相似文献   

20.
Thermal comfort of man in different urban environments   总被引：2，自引：4，他引：2  
Summary On July 29, 1985, a hot summer day, biometeorological measurements were performed simultaneously in three different urban structures within the city of Munich and in the trunk space of a nearby tall spruce forest. Based on the results of these experiments the following thermophysiologically relevant biometeorological indices were calculated: Predicted mean vote, skin wettedness and physiologically equivalent temperature. These three indices are derived from different models for the human energy balance. They allow the assessment of the thermal components of the microclimates at the selected sites with regard to application in urban planning. The results quantitatively show the great heat stress in the urban structure street canyon, exposed to south, whereas in the trunk space of the tall spruce forest there is nearly an optimal climate even on hot summer days. Between these extremes the results for street canyon, exposed to north show a little higher heat load than for backyard with trees.
Zusammenfassung An einem heißen Sommertag, dem 29. Juli 1985, wurden in drei Stadtstrukturen in München und im Stammraum eines nahegelegenen Fichtenhochwaldes zeitgleich biometeorologische Messungen durchgeführt. Mit den Meßergebnissen wurden folgende thermophysiologisch relevante biometeorologische Indizes berechnet: Predicted mean vote, Hautbenetzungsgrad und physiologisch äquivalente Temperatur. Diese drei Indizes beruhen auf verschiedenen Modellen zur menschlichen Energiebilanz. Mit den drei Indizes wurden die thermischen Komponenten der Mikroklimate an den ausgewählten Meßplätzen im Hinblick auf Stadtplanungsaufgaben bewertet. Die Ergebnisse zeigen quantitativ die relativ große Hitzebelastung bei der Stadtstruktur Straßenschlucht, nach Süd exponiert, während im Stammraum des Fichtenhochwaldes selbst an heißen Sommertagen nahezu optimale Bedingungen herrschen. Zwischen diesen Extremen liegen die Ergebnisse für die anderen Meßplätze, wobei für Straßenschlucht, nach Nord exponiert die Wärmebelastung etwas höher als für Innenhof mit Bäumen ist.

With 6 Figures  相似文献   

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