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1.
Entrapped gas bubbles in peat can alter the buoyancy, storativity, void ratio and expansion/contraction properties of the peat. Moreover, when gas bubbles block water‐conducting pores they can significantly reduce saturated hydraulic conductivity and create zones of over‐pressuring, perhaps leading to an alteration in the magnitude and direction of groundwater flow and solute transport. Some previous researches have demonstrated that these zones of over‐pressuring are not observed by the measurements of pore‐water pressures using open‐pipe piezometers in peat; rather, they are only observed with pressure transducers sealed in the peat. In has been hypothesized that open‐pipe piezometers vent entrapped CH4 to the atmosphere and thereby do not permit the natural development of zones of entrapped gas. Here we present findings of the study to investigate whether piezometers vent subsurface CH4 to the atmosphere and whether the presence of piezometers alters the subsurface concentration of dissolved CH4. We measured the flux of methane venting from the piezometers and also determined changes in pore‐water CH4 concentration at a rich fen in southern Ontario and a poor fen in southern Quebec, in the summer of 2004. Seasonally averaged CH4 flux from piezometers was 1450 and 37·8‐mg CH4 m?2 d?1 at the southern Ontario site and Quebec site, respectively. The flux at the Ontario site was two orders of magnitude greater than the diffusive flux at the site. CH4 pore‐water concentrations were significantly lower in open piezometers than in water taken from sealed samplers at both the Ontario and Quebec sites. The flux of CH4 from piezometers decreased throughout the season suggesting that CH4 venting through the piezometer exceeded the rate of methanogenesis in the peat. Consequently we conclude that piezometers may alter the gas dynamics of some peatlands. We suggest that less‐invasive techniques (e.g. buried pressure transducers, tracer experiments) are needed for the accurate measurement of pore‐water pressures and hydraulic conductivity in peatlands with a large entrapped gas component. Furthermore, we argue that caution must be made in interpreting results from previous peatland hydrology studies that use these traditional methods. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

2.
Baseline characterization of concentrations and isotopic values of dissolved natural gases is needed to identify contamination caused by the leakage of fugitive gases from oil and gas activities. Methods to collect and analyze baseline concentration‐depth profiles of dissolved CH4 and C2H6 and δ13C‐CH4 in shales and Quaternary clayey tills were assessed at two sites in the Williston Basin, Canada. Core and cuttings samples were stored in Isojars® in a low O2 headspace prior to analysis. Measurements and multiphase diffusion modeling show that the gas concentrations in core samples yield well‐defined and reproducible depth profiles after 31‐d equilibration. No measurable oxidative loss or production during core sample storage was observed. Concentrations from cuttings and mud gas logging (including IsoTubes®) were much lower than from cores, but correlated well. Simulations suggest the lower concentrations from cuttings can be attributed to drilling time, and therefore their use to define gas concentration profiles may have inherent limitations. Calculations based on mud gas logging show the method can provide estimates of core concentrations if operational parameters for the mud gas capture cylinder are quantified. The δ13C‐CH4 measured from mud gas, IsoTubes®, cuttings, and core samples are consistent, exhibiting slight variations that should not alter the implications of the results in identifying the sources of the gases. This study shows core and mud gas techniques and, to a lesser extent, cuttings, can generate high‐resolution depth profiles of dissolved hydrocarbon gas concentrations and their isotopes.  相似文献   

3.
Northern peatlands are a large source of atmospheric methane (CH4) and both a source and a sink of atmospheric carbon dioxide (CO2). The rate and temporal variability in gas exchanges with peat soils is directly related to the spatial distribution of these free‐phase gases within the peat column. In this paper, we present results from surface and borehole ground‐penetrating radar surveys – constrained with direct soil and gas sampling – that compare the spatial distribution of gas accumulations in two raised bogs: one in Wales (UK), the other in Maine (USA). Although the two peatlands have similar average thickness, physical properties of the peat matrix differ, particularly in terms of peat type and degree of humification. We hypothesize that these variations in physical properties are responsible for the differences in gas distribution between the two peatlands characterized by (1) gas content up to 10.8% associated with woody peat and presence of wood layers in Caribou Bog (Maine) and (2) a more homogenous distribution with gas content up to 5.7% at the surface (i.e. <0.5 m deep) in Cors Fochno (Wales). Our results highlight the variability in biogenic gas accumulation and distribution across peatlands and suggest that the nature of the peat matrix has a key role in defining how biogenic gas accumulates within and is released to the atmosphere from peat soils. © 2015 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.  相似文献   

4.
The frequency and intensity of drought is projected to increase within the boreal region under future climatic conditions. Peatlands are widely considered to regulate water loss under drought conditions, increasing surface resistance (rs) and reducing evaporative losses. This maintains peat moisture content, increasing the resilience of these globally important carbon stores. However, the magnitude and form of this important negative feedback response remains uncertain. To address this, we monitored the response of rs to drought within four peat cores under controlled meteorological conditions. When the water‐table was dropped to a depth of 0.30 m and the humidity reduced to ≤40%, a step shift in rs from ~50 s m‐1 up to 1000 s m‐1 was observed within burned and unburned peat, which virtually shuts down evaporation, limiting water loss. We show that measured near‐surface tension cannot be used to directly calculate this transition in peat surface resistance. However, empirical relationships that account for strong vertical variations in tension through the near‐surface and/or disequilibrium between pore air and near‐surface pore water pressure provide the potential to incorporate this negative feedback response into peatland ecohydrological models. Further observations are necessary to examine this response under dynamic atmospheric conditions. We suggest that the link between surface temperature and evaporation provides potential to further examine this feedback in either burned peatlands or peatlands with a low vascular vegetation cover. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

5.
Spatial and seasonal variations in CO2 and CH4 concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO2 concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO2 concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO2 were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO2 concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO2 concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO2. Streamwater CH4 concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l?1) than those of CO2 and showed no seasonal variation, nor any relationship with soil atmospheric CH4 concentrations. However, stream CH4 was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO2 can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

6.
康满春  刘流  刘佳  肖尚斌 《湖泊科学》2024,36(2):339-352
冒泡排放是湖、库水体CH4排放的主要方式之一,其排放通量和占CH4总排放量比例均具有极其显著的时空差异性,是当前水体CH4排放估算不确定性的主要来源之一。然而,目前关于湖、库水体CH4冒泡排放通量监测、时空分布规律、过程机制和模型模拟的系统梳理鲜有报道。本研究对比了目前水体CH4冒泡的监测方法技术的适用性及优缺点,分析总结湖、库水体CH4冒泡排放及通量的时空分布特征,梳理CH4气泡在沉积物-水体中的产生-成长-迁移-释放的过程、影响因素及模型,并提出了水体CH4冒泡过程模型框架。最后,本研究提出未来研究应基于湖、库水体分类、设备开发和改进来构建适应性的湖、库水体CH4冒泡排放监测标准体系,开发基于过程的CH4冒泡机理模型,为认识变化环境下湖、库水体CH4冒泡过程和准确估算CH4排放量提供支撑。  相似文献   

7.
Methane emissions from hydroelectric reservoirs can comprise a considerable portion of anthropogenic methane. However, lack of data on CH4 emissions in different geographical regions and high spatial‐temporal variability in the emission rates of reservoirs has led to uncertainties regarding regional emission estimates of CH4. In the subtropical plateau climate region, we used the Ertan hydroelectric reservoir as a study area. The CH4 flux at the air‐water interface was assessed by floating chambers and factors influencing emissions, including the distance from the dam, water depth, seasonal variation in wet and dry season, air‐water temperature gradient and wind speed, and was also studied through a year‐long systematic sampling and monitoring experiment. The results showed that the surface of the reservoir was a source of CH4 during the sampling period and the annual average CH4 flux was 2·80 ± 1·52 mg m?2 d?1. CH4 flux (and its variation) was higher in the shallow water areas than in the deep‐water areas. CH4 flux near the dam was significantly higher than that of other locations farther from the dam in the dry season. The seasonal variations of CH4 emission in wet and dry seasons were minor and significant diurnal variations were observed in wet and dry seasons. Exponential relationships between the CH4 flux and air‐water temperature gradient were found. Air‐water temperature gradient was an important factor influencing diurnal variations of CH4 flux in the Ertan hydroelectric reservoir. These results indicate that systematic sampling is needed to better estimate CH4 flux through coverage of the spatial variation of different water depths, measuring‐point distance from the dam, seasonal variation in wet and dry seasons and changes in climate factors (such as air‐water temperature gradient). Our results also provide a fundamental parameter for CH4 emission estimation of global reservoirs. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

8.
Reservoirs are man‐made lakes that severely impact on river ecosystems, and in addition, the new lake ecosystem can be damaged by several processes. Thus, the benefits of a reservoir, including energy production and flood control, must be measured against their impact on nature. New investigations point out that shallow and tropical reservoirs have high emission rates of the greenhouse gases CO2 and CH4. The methane emissions contribute strongly to climate change because CH4 has a 25 times higher global warming potential than CO2. The pathways for its production include ebullition, diffuse emission via the water‐air interface, and degassing in turbines and downstream of the reservoir in the spillway and the initial river stretch. Greenhouse gas emissions are promoted by a eutrophic state of the reservoir, and, with higher trophic levels, anaerobic conditions occur with the emission of CH4. This means that a qualitative and quantitative jump in greenhouse gas emissions takes place. Available data from Petit Saut, French Guinea, provides a first quantification of these pathways. A simple evaluation of the global warming potential of a reservoir can be undertaken using the energy density, the ratio of the reservoir surface and the hydropower capacity; this parameter is mainly determined by the reservoir's morphometry but not by the hydropower capacity. Energy densities of some reservoirs are given and it is clearly seen that some reservoirs have a global warming potential higher than that of coal use for energy production.  相似文献   

9.
Surface waters associated with peatlands, supersaturated with CO2 and CH4 with respect to the atmosphere, act as important pathways linking a large and potentially unstable global repository of C to the atmosphere. Understanding the drivers and mechanisms which control C release from peatland systems to the atmosphere will contribute to better management and modelling of terrestrial C pools. We used non‐dispersive infra‐red (NDIR) CO2 sensors to continuously measure gas concentrations in a beaver pond at Mer Bleue peatland (Canada); measurements were made between July and August 2007. Concentrations of CO2 in the surface water (10 cm) reached 13 mg C l?1 (epCO2 72), and 26 mg C l?1 (epCO2 133) at depth (60 cm). The study also showed large diurnal fluctuations in dissolved CO2 which ranged in amplitude from ～1·6 mg C l?1 at 10 cm to ～0·2 mg C l?1 at 60 cm depth. CH4 concentration and supersaturation (epCH4) measured using headspace analysis averaged 1·47 mg C l?1 and 3252, respectively; diurnal cycling was also evident in CH4 concentrations. Mean estimated evasion rates of CO2 and CH4 over the summer period were 44·92 ± 7·86 and 0·44 ± 0·25 µg C m?2s?1, respectively. Open water at Mer Bleue is a significant summer hotspot for greenhouse gas emissions within the catchment. Our results suggest that CO2 concentrations during the summer in beaver ponds at Mer Bleue are strongly influenced by biological processes within the water column involving aquatic plants and algae (in situ photosynthesis and respiration). In terms of carbon cycling, soil‐stream connectivity at this time of year is therefore relatively weak. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

10.
Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH4). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

11.
Horizontal drilling and hydraulic fracturing have enhanced unconventional hydrocarbon recovery but raised environmental concerns related to water quality. Because most basins targeted for shale‐gas development in the USA have histories of both active and legacy petroleum extraction, confusion about the hydrogeological context of naturally occurring methane in shallow aquifers overlying shales remains. The Karoo Basin, located in South Africa, provides a near‐pristine setting to evaluate these processes, without a history of conventional or unconventional energy extraction. We conducted a comprehensive pre‐industrial evaluation of water quality and gas geochemistry in 22 groundwater samples across the Karoo Basin, including dissolved ions, water isotopes, hydrocarbon molecular and isotopic composition, and noble gases. Methane‐rich samples were associated with high‐salinity, NaCl‐type groundwater and elevated levels of ethane, 4He, and other noble gases produced by radioactive decay. This endmember displayed less negative δ13C‐CH4 and evidence of mixing between thermogenic natural gases and hydrogenotrophic methane. Atmospheric noble gases in the methane‐rich samples record a history of fractionation during gas‐phase migration from source rocks to shallow aquifers. Conversely, methane‐poor samples have a paucity of ethane and 4He, near saturation levels of atmospheric noble gases, and more negative δ13C‐CH4; methane in these samples is biogenic and produced by a mixture of hydrogenotrophic and acetoclastic sources. These geochemical observations are consistent with other basins targeted for unconventional energy extraction in the USA and contribute to a growing data base of naturally occurring methane in shallow aquifers globally, which provide a framework for evaluating environmental concerns related to unconventional energy development (e.g., stray gas).  相似文献   

12.
Dissolved organic carbon (DOC) originating in peatlands can be mineralized to carbon dioxide (CO2) and methane (CH4), two potent greenhouse gases. Knowledge of the dynamics of DOC export via run‐off is needed for a more robust quantification of C cycling in peatland ecosystems, a prerequisite for realistic predictions of future climate change. We studied dispersion pathways of DOC in a mountain‐top peat bog in the Czech Republic (Central Europe), using a dual isotope approach. Although δ13CDOC values made it possible to link exported DOC with its within‐bog source, δ18OH2O values of precipitation and run‐off helped to understand run‐off generation. Our 2‐year DOC–H2O isotope monitoring was complemented by a laboratory peat incubation study generating an experimental time series of δ13CDOC values. DOC concentrations in run‐off during high‐flow periods were 20–30 mg L?1. The top 2 cm of the peat profile, composed of decaying green moss, contained isotopically lighter C than deeper peat, and this isotopically light C was present in run‐off in high‐flow periods. In contrast, baseflow contained only 2–10 mg DOC L?1, and its more variable C isotope composition intermittently fingerprinted deeper peat. DOC in run‐off occasionally contained isotopically extremely light C whose source in solid peat substrate was not identified. Pre‐event water made up on average 60% of the water run‐off flux, whereas direct precipitation contributed 40%. Run‐off response to precipitation was relatively fast. A highly leached horizon was identified in shallow catotelm. This peat layer was likely affected by a lateral influx of precipitation. Within 36 days of laboratory incubation, isotopically heavy DOC that had been initially released from the peat was replaced by isotopically lighter DOC, whose δ13C values converged to the solid substrate and natural run‐off. We suggest that δ13C systematics can be useful in identification of vertically stratified within‐bog DOC sources for peatland run‐off.  相似文献   

13.
Tommeliten is a prominent methane seep area in the Central North Sea. Previous surveys revealed shallow gas-bearing sediments and methane gas ebullition into the water column. In this study, the in situ methane flux at Tommeliten is re-assessed and the potential methane transport to the atmosphere is discussed, with regards to the hydrographic setting and gas bubble modeling. We have compiled previous data, acquired new video and acoustic evidence of gas bubble release, and have measured the methane concentration, and its C-isotopic composition in the water column. Parametric subbottom sonar data reveal the three-dimensional extent of shallow gas and morphologic features relevant for gas migration. Five methane ebullition areas are identified and the main seepage area appears to be 21 times larger than previously estimated. Our video, hydroacoustic, subbottom, and chemical data suggest that ～1.5×106 mol CH4/yr (～26 tons CH4/yr) of methane gas is being released from the seepage area of Tommeliten. Methane concentration profiles in the vicinity of the gas seeps show values of up to 268 nM (～100 times background) close to the seafloor. A decrease in δ13C-CH4 values at 40 m water depth indicates an unknown additional biogenic methane source within the well oxygenated thermocline between 30 and 40 m water depth. Numerical modeling of the methane bubbles due to their migration and dissolution was performed to estimate the bubble-derived vertical methane transport, the fate of this methane in the water column, and finally the flux to the atmosphere. Modeling indicates that less than ～4% of the gas initially released at the seafloor is transported via bubbles into the mixed layer and, ultimately, to the atmosphere. However, because of the strong seasonality of mixing in the North Sea, this flux is expected to increase as mixing increases, and almost all of the methane released at the seafloor could be transferred into the atmosphere in the stormy fall and winter time.  相似文献   

14.
An understanding of the symbiotic water and gas exchange processes at the ecosystem scale is essential to the development of appropriate restoration plans of extracted peatlands. This paper presents ecosystem scale measurements of the atmospheric exchange of water and carbon dioxide (CO2) from a restored vacuum extracted peatland in eastern Québec, utilizing full‐scale micrometeorological measurements of both evaporation and CO2. The results indicate that the adopted restoration practices reduce the loss of water from the peat, but CO2 emissions are ～25% greater than an adjacent nonrestored comparison site. The blockage of drainage ditches and the existence of a mulch cover at the site keep the moisture conditions more or less constant. Consequently, the CO2 flux, which is predominantly soil respiration, is strongly controlled by peat temperature fluctuations. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

15.
The natural carbon storage function of peatland ecosystems can be severely affected by the abandonment of peat extraction, influencing peatland drainage, leading to large and persistent sources of atmospheric CO2. Moreover, these cutover peatlands have a low and variable water table position and high tension at the surface, creating harsh ecohydrological conditions for vegetation re‐establishment, particularly peat forming Sphagnum moss. Standard restoration techniques aim to restore the peatland to a carbon accumulating system through various water management techniques to improve hydrological conditions and by reintroducing Sphagnum at the surface. However, restoring the hydrology of peatlands can be expensive due to the cost of implementing the various restoration techniques. This study examines a peat extraction‐restoration technique where the acrotelm is preserved and replaced directly on the cutover peat surface. An experimental peatland adopting this acrotelm transplant technique had both a high water table and peat moisture conditions providing sufficient water at the surface for Sphagnum moss. Average water table conditions were higher at the experimental site (?8·4 ± 4·2 cm) compared to an adjacent natural site (?12·7 ± 6·0 cm) suggesting adequate moisture conditions at the restored surface. However, the experimental site experienced high variability in volumetric moisture content (VMC) in the capitula zone (upper 2 cm) where large diurnal changes in VMC (～30%) were observed, suggesting possible disturbance to the peat matrix structure during the extraction‐restoration process. However, soil–water retention analysis and physical peat properties (porosity and bulk density) suggest that no significant differences existed between the natural and experimental sites. Any structural changes within the peat matrix were therefore minimal. Moreover, low soil‐water tensions were maintained well above the laboratory measured critical Sphagnum threshold of 33% (?100 mb) VMC, further indicating favourable conditions for Sphagnum moss survival and growth. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

16.
A new dry gas extraction and analysis method for small (1 cm3) ice samples is presented. The extraction device, cooled to ?20°C, contains two movable steel needle matrices for crushing the ice. During the crushing process the gas escaping from the ice sample is continuously analyzed for CO2 with an infrared laserspectrometer. This method enables a fast measurement (few minutes) of the CO2 concentration in the air bubbles with high spatial resolution in the ice core and a minimum potential contamination. An important CO2 contamination source due to an interaction of water vapour with surfaces is shortly discussed.The reproducibility of extraction and analysis is ±2%. We analyzed CO2 concentrations in the trapped air from different ice cores originating from the Greenland ice sheet and from Antarctica.  相似文献   

17.
Gas‐saturated groundwater forms bubbles when brought to atmospheric pressure, preventing precise determination of its in situ dissolved gas concentrations. To overcome this problem, a modeling approach called the atmospheric sampling method is suggested here to recover the in situ dissolved gas concentrations of groundwater collected ex situ under atmospheric conditions at the Horonobe Underground Research Laboratory, Japan. The results from this method were compared with results measured at the same locations using two special techniques, the sealed sampler and pre‐evacuated vial methods, that have been developed to collect groundwater under its in situ conditions. In gas‐saturated groundwater cases, dissolved methane and inorganic carbon concentrations derived using the atmospheric sampling method were mostly within ±4 and ±10%, respectively, of values from the sealed sampler and pre‐evacuated vial methods. In gas‐unsaturated groundwater, however, the atmospheric sampling method overestimated the in situ dissolved methane concentrations, because the groundwater pressure at which bubbles appear (Pcritical) was overestimated. The atmospheric sampling method is recommended for use where gas‐saturated groundwater can be collected only ex situ under atmospheric conditions.  相似文献   

18.
Wei  Lin  Masaki  Enami 《Island Arc》2006,15(4):483-502
Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (Xjd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge.  相似文献   

19.
Two comparative simulation experiments(a normal atmospheric-pressure opening system and a 20 MPa closed system)were conducted to study the geochemical evolution of n-alkane,sterane,and terpane biomarkers in the process of oil cracking into gas under different pressures.With an initial experimental temperature set at 300°C,the temperature was increased to 650°C at a heating rate of 30°C/h.The products were tested every 50°C starting at 300°C,and a pressure of 20 MPa was achieved using a water column.The low-maturity crude oil sample was from the Paleogene system in the Dongying sag in eastern China.The threshold temperature obtained for the primary oil cracking process in both pressure systems was 450°C.Before the oil was cracked into gas,some components,including macromolecular n-alkanes,were cracked into medium-or small-sized n-alkanes.The secondary oil cracking of heavy hydrocarbon gases of C2–5to methane mainly occurred between 550°C to 650°C,and the parameters Ln(C1/C2)and Ln(C1/C3),as well as the dry coefficients,increased.Overpressure inhibited the oil cracking process.In the 20 MPa system,the oil conversion rate decreased,the temperature threshold for gas generation rose,and oil cracking was inhibited.Compared with the normal pressure system,high-carbon n-alkanes and other compounds in the 20 MPa pressure system were reserved.Furthermore,the parameters∑C21-/∑22+,Ln(C1/C2),and Ln(C1/C3),as well as the dry coefficients,decreased within the main temperature range.During secondary oil cracking(550°C to 600°C),the Ph/nC18and Pr/nC17decreased.High pressure influenced the evolution of the biomarkers Ts and Tm,C31homohopane,C29sterane,and their related maturity parameters to different extents during oil cracking under different temperature ranges.  相似文献   

20.
We evaluated tools and methods for in situ freezing of cores in unconsolidated subsurface media. Our approach, referred to as cryogenic core collection (C3), has key aspects that include downhole circulation of liquid nitrogen (LN) via a cooling system, strategic use of thermal insulation to focus cooling into the core, and controlling LN back pressure to optimize cooling. Two cooling systems (copper coil and dual‐wall cylinder) are described. For both systems, the time to freeze a single 2.5‐foot (76‐cm) long by 2.5‐inch (63‐mm) diameter core is 5 to 7 min. Frozen core collection rates of about 30 feet/day (10 m/day) were achieved at two field sites, one impacted by petroleum‐based light nonaqueous phase liquids (LNAPLs) and the other by chlorinated solvents. Merits of C3 include (1) improved core recovery, (2) potential control of flowing sand, and (3) improved preservation of critical sediment attributes. Development of the C3 method creates novel opportunities to characterize sediment with respect to physical, chemical, and biological properties. For example, we were able to resolve water, LNAPL, and gas saturations above and below the water table. By eliminating drainage of water, gas and LNAPL saturations in the range of 6 to 23% and 1 to 3% of pore space, respectively, were measured in LNAPL‐impacted intervals below the water table.  相似文献   

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