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1.
Abstract: K–Ar datings and oxygen isotope analyses revealed a cooling history of the Uchiyama granitic pluton, which is genetically related to the Pb-Zn deposits (Taishu mine) in the Tsushima Islands, Japan. The pluton intrudes into the Paleogene Taishu Group to form the biotite-hornfels zone, while the Taishu vein-type Pb–Zn deposits occur in fissures developed in the non-hornfels zone about 1 to 3 km westward from the contact. Amphibole and biotite K-Ar ages of the pluton have a wide range from 19 to 13 Ma. Oxygen isotopes of the biotite and coexisting quartz grains indicate that isotopic exchange reactions have occurred under subsolidus conditions, and that the K-Ar ages are affected by various cooling rates in the pluton. The mineralization age of the Taishu ore deposits is obtained for the first time to be 15.40.8 Ma by a K-Ar age of 2 M 1–muscovite in a calcite–quartz–muscovite–chlorite veinlet of the Shintomi orebody. Whole rock K-Ar ages of biotite-hornfels near the pluton represent similar ages to the ore deposits. Using blocking temperature calculated from reported diffusivity for argon, the pluton was cooled from 560 to 350C in the period of 17 to 14 Ma. The vein formation took place after the time when temperature in wall rocks of the pluton had dropped below the brittle-plastic transition (about 400C). These results imply that the cooling of the pluton has caused injection of magmatic fluids into meteoric hydrothermal systems, and the Pb-Zn mineralization has occurred due to this mixing at the age of about 15 Ma.  相似文献   

2.
Abstract: Seven zircon fission-track ages and 30 magnetic susceptibilities were measured on welded pyroclastic rocks from the Bogopol and Sijanov Groups of the Cretaceous to Paleogene volcanic rocks in the southeastern part of the eastern Sikhote Alin volcano-plutonic belt, Far East Russia. The fission-track ages range from 42. 7 Ma to 64. O Ma which indicate that both the groups are of Early Paleogene time. Two thirds of the samples from the Bogopol Group have high magnetic susceptibility values, more than 3 A- 10-3 SI unit, which imply that they are of the magnetite–series, whereas the samples from the Sijanov Group show 3 A- 10-3 to 8 A- 10-5 SI unit which suggest this group of probably the ilmenite-series.
The Paleogene age and high magnetic susceptibility of the Bogopol Group are quite similar to the Paleogene igneous rocks of the San'in belt, Southwest Japan. This suggests, taking accounts of the opening of the Japan Sea, that the eastern Sikhote Alin volcano-plutonic belt continued to the San'in Belt, and that the Paleogene igneous rocks along the Japan Sea coast of Northeast Japan were situated along the volcanic front of the eastern Sikhote Alin volcano-plutonic belt.  相似文献   

3.
Abstract Petrological study of highly strained carbonate and pelitic rocks within the contact aureole surrounding the western part of the Papoose Flat pluton yields thermal profiles (plots of metamorphic temperature versus distance) across the aureole that show temperature gradients which are relatively flat and narrow (<100m). The gradients occur close to the contact and indicate a slight decrease in temperature from 500–550°C at the pluton/wall rock contact to 450–500°C at the outer margin of the aureole. One thermal profile across low-strain metasedimentary rocks located in the southern part of the aureole shows that thermal effects from emplacement extend no further than 600 m from the contact. Coexistence of andalusite and cordierite in pelitic rocks of the aureole constrain pressures to <4 kbar. Thermal modelling using an analytical solution of the conductive heat flow equation for a rectangular-shaped pluton reproduces the observed thermal maxima and profile shape. Conductive rather than convective cooling also is supported by isotopic and field evidence for limited fluid flow along the strongly deformed margin of the pluton. Simple thermal models coupled with observed high-temperature deformation features and a measured 90% attenuation of stratigraphic units in the plastically deformed western part of the pluton's aureole indicate that strain rates may have been of the order of 10-12s-1. Evidence for episodic heating, such as two distinct generations of andalusite growth in pelites from the aureole, alternatively may indicate a longer heating event and, therefore, slower strain rates. Thermal models also indicate that parts of the pluton still may have been above the solidus during deformation of the pluton margin and aureole.  相似文献   

4.
Abstract Clinopyroxenes and garnets from 11 blueschist-facies Fe-rich eclogite samples from the Voltri Group show a wide range of chemical compositions. Detailed analyses of single pyroxene and garnet grains show wide and scattered chemical inhomogeneity, the KD(KD= (Fe2+/Mg)Gt/(Fe2+/Mg)Cpx) ranges from 20 to 87 based on rim analyses only. The data obtained indicate that the mineral pairs never attained equilibrium under uniform P-T conditions and that the compositions of the metamorphic minerals were influenced mainly by the composition of the pre-metamorphic minerals and by topotactical reactions.  相似文献   

5.
Porphyroblast inclusion trails provide important information about the tectonometamorphic evolution of a metamorphic rock. However, there remains considerable controversy over whether porphyroblasts rotate during bulk non-coaxial deformation.
With reference to an area of the Scandinavian Caledonides and utilizing existing data from theoretical and experimental modelling, this study demonstrates that both 'straight' and 'S-shaped' inclusion trails are consistent with an interpretation in terms of syndeformational porphyroblast growth in a regime approximating to Newtonian simple shear. At crustal strain rates of 10-14 s-1 and porphyroblast growth times of 0.1–1.0 Ma, it is shown that a maximum of 5-9 angular rotation would occur during growth. At faster strain rates of 10-12 s-1 (e.g. those in a shear zone) porphyroblast angular rotations of 90 are shown to occur in 0.1–0.25 Ma (i.e. times comparable with or faster than porphyroblastesis). In view of this, 'S-shaped' inclusion trails are to be expected in porphyroblasts growing in active shear zones or other situations of high shear strain, whereas 'straight' inclusion trails can be interpreted as static overgrowth of an existing fabric or as syndeformational porphyroblastesis at low strain rates.  相似文献   

6.
This work presents the results of a fluid inclusion study of an amphibolite-granulite facies transition in West Uusimaa, S.W. Finland. Early fluid-inclusions in the granulite facies area are characteristically carbonic (CO2), in contrast to predominantly aqueous early inclusions in the amphibolite facies area. These early inclusions can be related to peak metamorphic conditions (750-820°C and 3-5 kbar for peak granulite facies metamorphism). Relatively young CO2 inclusions with low densities (<0.8g/cm3) indicate that the first part of the cooling history of the rocks was characterized by a near isothermal uplift.
N2-CH4 inclusions, with compositions ranging between pure CH4 and pure N2 (Raman spectral analysis), were found in the whole area. They are probably syn- or even pre-early inclusions. Only nearly critical homogenizing inclusions have been found (low density). Pressure estimates, based on densities of early fluid inclusions, show that the rapid transition of amphibolite towards granulite facies metamorphism is virtually isobaric. Granulite facies metamorphism in West Uusimaa is a thermal event, probably induced by the influx of hot, CO2-bearing fluids.  相似文献   

7.
Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O2 concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O2 concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10-9 at 25°C, 2.22 × 10-8 at 45°C, and 1.28 × 10-7 moles m-2 s-1 at 65°C.  相似文献   

8.
Abstract A Hercynian charnockite occurs within high-grade gneisses in the Agly Massif, French Pyrenees. Its thermal history has been evaluated using the Fe-Mg distribution coefticient ( K D) between garnet and biotite. These minerals have different origins but similar compositions in the charnockites and host gneisses. In the charnockite, the Bi–Ga pairs are the retrograde products of Opx alteration. This Opx reaction with feldspar can be written. Opx + PI + Fluid 1(H2O + Al + K + Fe + Ti) = Bi + Ga + Q + Fluid 2(H2O + Na). The garnets are relatively Ca poor (4–2.5% grossular); they are automorphic and zoned in the gneisses and poikiloblastic in the charnockites. Both types show a retrograde rim (of few hundred microns'width) across which Fe and Mn increase as Mg decreases. The biotites show a good correlation between the octahedral cations (Ti4++ Fe2+) and (Mg2++ Al3+VI); Ti and Fe both increase, whereas Mg and AlVI decrease. There is an inverse linear correlation between Fe2+ and Mg2+ and the Fe/Mg ratio increases as Ti increases. The relation between Ti and K Ga-BiDFe-Mg is less clear: it seems that K D slightly decreases as Ti increases. The equilibration temperatures of Ga–Bi pairs are discussed: the charnockite Ga-Bi pairs have equilibrated between 550°C and 600°C; whereas those of the gneisses have equilibrated between 550°C and 650°C. Two main thermal steps appear: one in the gneisses between 600-650°C and a second one in both the gneisses and the charnockites between 550°C and 600°C.  相似文献   

9.
Roof-to-floor exposures of mid-Miocene plutons in tilt blocks south of Las Vegas, NV, reveal distinct but strongly contrasting magma chamber statigraphy. The Searchlight and Aztec Wash plutons are well-exposed, stratified intrusions that show a similar broad range in composition from 45–75 wt.% SiO2. Homogeneous granites that comprise about one-third of each intrusion are virtually identical in texture and elemental and isotopic chemistry. Mafic rocks that are present in both plutons document basaltic input into felsic magma chambers. Isotopic compositions suggest that mafic magmas were derived from enriched lithospheric mantle with minor crustal contamination, whereas more felsic rocks are hybrids that are either juvenile basaltic magma+crustal melt mixtures or products of anatexis of ancient crust+young (Mesozoic or Miocene?) mafic intraplate.

Despite general similarities, the two plutons differ markedly in dimensions and lithologic stratigraphy. The Searchlight pluton is much thicker (10 vs. 3 km) and has thick quartz monzonite zones at its roof and floor that are absent in the Aztec Wash pluton. Isotopic and elemental data from Searchlight pluton suggest that the upper and lower zones are cogenetic with the granite; we interpret the finer grained, slightly more felsic upper zone to represent a downward migrating solidification front and the lower zone to be cumulate. In contrast, the upper part of the Aztec Wash pluton is granite, and a heterogeneous, mafic-rich injection zone with distinct isotopic chemistry forms the lower two-thirds of the intrusion. Similar mafic rocks are relatively sparse in Searchlight pluton and do not appear to have played a central role in construction of the pluton. Large felsic and composite dikes that attest to repeated recharging and intrachamber magma transfer are common in the Aztec Wash pluton but absent in the Searchlight pluton. Thus, although both intrusions were filled by similar magmas and both developed internal stratification, the two intrusions evolved very differently. The distinctions may be attributable to scale and resulting longevity and/or to subtle differences in tectonic setting.  相似文献   


10.
Abstract Chloritoid-bearing metasedimentary rocks occur in close proximity to blueschists and eclogites in the Tertiary high-pressure metamorphic belt of northern New Caledonia. The typical assemblage of chloritoid-bearing rocks in the epidote zone is quartzchlorite-muscovite-garnet-chloritoid. In the omphacite zone, epidote is an additional member of the chloritoid-bearing assemblage. Paragonite is rare, plagioclase was not detected, and rutile and ilmenite are the Fe-Ti oxide phases. Chloritoid-glaucophane is not a common assemblage. Chloritoid-bearing rocks have relatively low (Ca+K+Na)/Al ratios and the chloritoids are relatively Mg-rich with Mg/ (Mg+Fe) up to about 0.4. A comparison of the mineral assemblages and mineral chemistry with experimental and computed phase equilibria suggest an upper temperature limit near 560° C in the omphacite zone and a minimum temperature limit near 450° C at 10 kbar. An empirical garnet-chlorite Fe-Mg exchange thermometer does not yield consistent results for the higher-grade rocks, suggesting T s ranging from 390 to 535° C in the omphacite zone and 420–465° C in the epidote zone. The distribution coefficient K D = (Fe/Mg)ctd/(Fe/Mg)chl for chloritoid and chlorite ranges from 3.9 to 6.4, values which are lower than those (=10) from lower greenschist facies rocks, but are near those of upper greenschist facies and albite-epidote amphibolite facies.  相似文献   

11.
The proposed geothermobarometer is based on an empirical calibration which takes account of two equilibria involving the tremolite, edenite, pargasite and hastingsite components in amphiboles. It has applications to assemblages found in metabasic rocks of widely different chemical compositions (magnesian to Fe-rich metabasalts), and for metamorphism ranging from lower greenschist to highest amphibolite facies. Knowing the Si(T1), Aliv, Alvi, Fe3+, Fe2+, Mg, Ca, NaM4, NaA and A vacancy in an amphibole, and the Al3+ and X Mg in coexisting epidote and chlorite, it is possible to calculate two values of In K d for this assemblage. These equilibria involve edenite-tremolite and (pargasite/hastingsite)-tremolite end-members in amphibole (the calculation program is given). For these equilibria, the isopleths (iso-values of K d) have been calculated for 0.27 < X Mg < 0.75 and 0 < X Fe3+= Fe3+/(Fe3++ Alvi) < 0.8. It is then possible to determine pressure and temperature directly when X Mg, X Fe3+, In K d for tremoliteedenite and In K d for (pargasite/hastingsite)-tremolite are known. Application of this geothermobarometer is limited to Ca-free plagioclase assemblages, and complete P–T paths can be drawn only if all the minerals are considered together. Phase relations at successive stages of crystallization can be constrained by studying the relationships between the coexisting minerals, their zoning and the metamorphic fabrics.  相似文献   

12.
碱性系列岩浆岩和埃达克岩是通常产生于汇聚板块边缘的特殊岩石类型,记录了俯冲物质与地幔橄榄岩相互作用的过程.笔者对中祁连南缘党河南山地区贾公台杂岩体和鸡叫沟岩体进行了岩石学、地球化学和锆石U-Pb年代学研究.LA-ICP-MS锆石U-Pb定年表明,鸡叫沟岩体中的二长闪长岩形成于(467±4.7)Ma,贾公台岩体花岗闪长岩...  相似文献   

13.
Lower Miocene rocks of the Taishu Group accumulated in the Tsushima pull-apart graben, which downwarped and was filled with sediments at a particularly high rate (about 2700 m/Ma), in the background of northeastern regional shortening. A considerable part of the sedimentary prism is composed of material supplied by landslide blocks from the shallow shelf. Folding and penetration of granite intrusions on Tsushima Island occurred ca. 15 Ma ago, simultaneously with the main phase of opening of the Sea of Japan, in the field of different, northwestern shortening, which had a local character and was related to clockwise rotation of the Southwestern Japan block. These rotations in turn could have been the result of an intensive rifting episode in the Central and Honshu basins of the Sea of Japan, which are located north of Tsushima Island.  相似文献   

14.
The south-east Reynolds Range, central Australia, is cut by steep north-west-trending Alice Springs age ( c. 334  Ma) shear zones that are up to hundreds of metres wide and several kilometres long with reverse senses of movement. Amphibolite facies (550–600  °C, 500–600  MPa) shear zones cut metapelites, while greenschist facies shear zones (420–535  °C, 400–650  MPa) cut metagranites. The sheared rocks commonly underwent metasomatism implying that the shear zones were the pathways of significant fluid flow. Altered granites within greenschist facies shear zones have gained Si and K but lost Ca and Na relative to their unsheared counterparts, suggesting that the fluid flowed down-temperature (and hence probably upward) through the shear zones. Time-integrated fluid fluxes calculated from silica addition are up to 2.1×1010 mol  m−2 ( c. 4.2×105  m3  m−2). Similar time-integrated fluid fluxes are also estimated from changes in K and Na. The sheared granitic rocks locally have δ18O values as low as 0 which is much lower than the δ18O values of the adjacent unsheared granites (7 to 9), implying that the fluid which flowed through these shear zones was derived from the surface. For the estimated time-integrated fluid fluxes, the fluids would be able to retain their isotopic signature for many tens to hundreds of kilometres. The flow of surface-derived fluids into the ductile middle crust, with subsequent expulsion upwards through the shear zones, may have been driven by seismic activity accompanying the Alice Springs deformation.  相似文献   

15.
四川会理 会东及邻区中元古界昆阳群 ,由下而上可分为力马河组、凤山营组和天宝山组 ,与古元古界河口群为不整合接触 ,其代表年龄值为 1 70 0± 1 0 0Ma～ 1 2 0 0± 1 0 0Ma。对这套地层的沉积学研究 ,前人涉及甚少。笔者在野外考察和室内分析的基础上 ,对其沉积相和沉积环境进行了详细的研究。初步认为研究区的中元古界昆阳群可分为 7种沉积相 ,进而探讨了该区的沉积演化历史。  相似文献   

16.
Abstract: The Hishikari deposits comprise the Honko (Main), Yamada, and Sanjin deposits. The horizontal strain in the direction (approx. N40°W normal to the general NE-SW strike of the Hishikari vein system was calculated, based on the measured total vein widths to the distance along three crosscuts. Veins were assumed to accompany no significant fault displacement in the calculation. Veins in the eastern and the middle parts of the Honko-Sanjin deposits spatially occupy 3. 2% and 1. 3%, respectively, and veins in the Yamada deposit occupy 6. 7%. Significant local variation of strain is observed in some areas. Reported K-Ar ages on adularia-quartz veins indicate the duration of vein opening to be 2. 6 × 105 yr in the Honko-Sanjin deposits and 5. 9 × 105 yr in the Yamada deposit. Horizontal strain rates were calculated to be 5. 0–12 × 10-8 yr-1through the Hishikari deposits. The calculated strain rates at the Hishikari deposits are roughly comparable to the regional horizontal strain rate in the Recent. Widespread extensional movement in southern Kyushu seems to have been able to provide sufficient strain for the formation of the Hishikari deposits, rather than contribution of local movements.  相似文献   

17.
Hydration of eclogite, Pam Peninsula, New Caledonia   总被引：2，自引：0，他引：2  
Garnet glaucophanite and greenschist facies assemblages were formed by the recrystallization of barroisite-bearing eclogite facies metabasites in northern New Caledonia. The mineralogical evolution can be modelled by calculated P–T and P–X H2O diagrams for appropriate bulk rock compositions in the model system CaO–Na2O–FeO–MgO–Al2O3–SiO2–H2O. The eclogites, having developed in a clockwise P–T path that reached P ≈19 kbar and T  ≈590 °C, underwent decompression with the consumption of free H2O as the volume of hydrous minerals increased. Eclogite is preserved in domains that experienced no fluid influx following the loss of this fluid. Garnet glaucophanite formed at P ≈16 kbar during semi-pervasive fluid influx. Fluid influx, after further isothermal decompression, was focused in shear zones, and resulted in chlorite–albite-bearing greenschist facies mineral assemblages that reflect P ≈9 kbar.  相似文献   

18.
Timing constraints on shear zones can provide an insight into the kinematic and exhumation evolution of metamorphic belts. In the Musgrave Block, central Australia, granulite facies gneisses have been affected, to varying degrees, by mylonitic deformation, some of which attained eclogite facies. The Davenport Shear Zone is a dominant strike-slip system that formed at eclogite facies conditions ( T  ≈650  °C and P ≈12.0  kbar). Sm–Nd mineral isochrons obtained from equilibrated high-pressure assemblages, as well as 40Ar–39Ar data, show that the eclogite and greenschist facies high-strain overprints were coeval, at c .  550  Ma. Mylonitic processes do not appear to have reset the U–Pb system in zircon, but may have partially disturbed it. The thermal gradient in the Musgrave Block crust at c .  550  Ma was c .  16  °C  km−1 and at c .  535  Ma was c .  18  °C  km−1, based on P – T  estimates of eclogite and greenschist facies shear zones, respectively. These estimates are similar to present-day geothermal gradients in many stable continental shield areas, suggesting that the region did not undergo a significant transient perturbation of the geotherm. Therefore, in the Musgrave Block, cooling subsequent to eclogite facies metamorphism appears to have been controlled by exhumation, rather than by the removal of a heat source. Estimated exhumation rates in the range 0.2 to ≥1.5  mm year−1 are comparable with other orogenic belts, rather than cratonic areas elsewhere.  相似文献   

19.
云南新平鲁奎山地区铁矿床总体上可分成两种类型,一是矿体呈似层状、层状赋存于昆阳群大龙口组下部(Pt2d1)及富良棚组(Pt2f2)上部,其显示了沉积-改造型矿床的特征;另一种是矿体为脉状、大透镜状赋存于断层破碎带内,显示了热液型脉状矿床的特点。该地区铁矿明显受层位、构造、岩浆岩三重因素控制。  相似文献   

20.
Abstract Ductile shearing in the core of the Tauern Window, Austria, transformed metagranodiorite into Si-undersaturated garnet-chlorite-staurolite schist at a depth of c. 35–40 km during the Alpine orogeny. Four distinct zones have been recognized extending from the wallrock into the centre of the shear zone: Zone I—unaltered metagranodiorite with subordinate amphibolite; Zone II—biotite-white mica-garnet schist; Zone III—biotite-phengite schist; Zone IV—quartz-absent, garnet-chlorite-staurolite schist with garnets up to 10 cm across. Whole-rock analyses show a dramatic decrease in SiO2 from >65 wt% in Zone I to <35 wt% in Zone IV; Ca, Na, and Sr also decrease across the shear zone, whereas Al, Ti, Fe, Mg, P, Cr, Ni, Zn, and Rb all increase towards Zone IV. Mass-balance calculations indicate that shearing was accompanied by up to 60% volume loss near the centre of the shear zone. Comparison of the Tauern Window samples with other shear zones in granitic hosts indicates that silica loss accompanied by gains in Mg, Fe, and Ti is typical for volume-loss shear zones, but is distinctly different from the element behaviour exhibited in shear zones that are thought to represent approximately isovolumetric behaviour. In the samples studied here, volume loss appears to have resulted from channellized fluid flow during shearing, producing time-integrated fluid fluxes of ± 108 cm3 cm−2 in Zone IV. This large volume of fluid may have originated, in part, from dehydration of flysch carried beneath the metagranodiorites during Eocene movement on the North Penninic subduction zone. Development of an inverted thermal gradient during subduction would have allowed the fluid to scavenge large amounts of silica from the shear zone during ascent and heating.  相似文献   

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