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1.
Laser-induced plasmas in various gas mixtures were used to simulate lightning in other planetary atmospheres. This method of simulation has the advantage of producing short-duration, high-temperature plasmas free from electrode contamination. The laser-induced plasma discharges in air are shown to accurately simulate terrestrial lightning and can be expected to simulate lightning spectra in other planetary atmospheres. Spectra from 240 to 880 nm are presented for simulated lightning in the atmospheres of Venus, Earth, Jupiter, and Titan. The spectra of lightning on the other giant planets are expected to be similar to that of Jupiter because the atmospheres of these planets are composed mainly of hydrogen and helium. The spectra of Venus and Titan show substantial amounts of radiation due to the presence of carbon atoms and ions and show CN Violet radiation. Although small amounts of CH4 and NH3 are present in the Jovian atmosphere, only emission from hydrogen and helium is observed. Most differences in the spectra can be understood in terms of the elemental ratios of the gas mixtures. Consequently, observations of the spectra of lightning on other planets should provide in situ estimates of the atmospheric and aerosol composition in the cloud layers in which lightning is occuring. In particular, the detection of inert gases such as helium should be possible and the relative abundance of these gases compared to major constituents might be determined.  相似文献   

2.
The chemical compositions of the primordial atmospheres of Venus, Earth and Mars have long been a topic of debate between the experts. Some believe that the original atmospheres were a product of outgassed volatiles from the newly accreted terrestrial planets and that these atmospheres consisted primarily of carbon dioxide, nitrogen, water vapor and residual hydrogen and helium (e.g., Lewis and Prinn, <it>Planets and their Atmospheres,</it> Academic Press, Orlando, FL, 1984, pp. 62–63, 81–84, 228–231, 383). Still others think the earliest atmospheres were composed of the gas components of the solar nebula from which the solar system formed (i.e., hydrogen, helium, methane, ammonia and water). I consider the latter to be the correct scenario. Presented herein is a proposed mechanism by which the original atmospheres of Venus, Earth and Mars were transformed to atmospheres rich in carbon dioxide and nitrogen. An explanation is proposed for why water is so common on the surface of Earth and so scarce on the surfaces of Venus and Mars. Also presented are the effects the “great impact” (single cataclysmic event that was responsible for producing the Earth–Moon system) had upon the early atmosphere of Earth. The origin, structure and composition of the impacting object are determined through deductive analyses.  相似文献   

3.
There is good evidence for the existence of very small amounts of methane, ammonia and carbon dioxide in the very tenuous lunar atmosphere which consists primarily of the rare gases helium, neon and argon. All of these gases, except40Ar, originate from solar wind particles which impinge on the lunar surface and are imbedded in the surface material. Here they may form molecules before being released into the atmosphere, or may be released directly, as is the case for rare gases. Evidence for the existence of the molecular gas species is based on the pre-dawn enhancement of the mass peaks attributable to these compounds in the data from the Apollo 17 Lunar Mass Spectrometer. Methane is the most abundant molecular gas but its concentration is exceedingly low, 1 × 103 mol cm?3, slightly less than36Ar, whereas the solar wind flux of carbon is approximately 2000 times that of36Ar. Several reasons are advanced for the very low concentration of methane in the lunar atmosphere.  相似文献   

4.
Photochemical reaction pathways in Titan's atmosphere were investigated by irradiation of the individual components and the mixture containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene. The quantum yields for the loss of the reactants and the formation of products were determined. Photolysis of ethylene yields mainly saturated compounds (ethane, propane, and butane) while photolysis of acetylene yields the same saturated compounds as well as ethylene and diacetylene. Irradiation of cyanoacetylene yields mainly hydrogen cyanide and small amounts of acetonitrile. When an amount of methane corresponding to its mixing ratio on Titan was added to these mixtures the quantum yields for the loss of reactants decreased and the quantum yields for hydrocarbon formation increased indicative of a hydrogen atom abstraction from methane by the photochemically generated radicals. GC/MS analysis of the products formed by irradiation of mixtures of all these gases generated over 120 compounds which were mainly aliphatic hydrocarbons containing double and triple bonds along with much smaller amounts of aromatic compounds like benzene, toluene and phenylacetylene. The reaction pathways were investigated by the use of 13C acetylene in these gas mixtures. No polycyclic aromatic compounds were detected. Vapor pressures of these compounds under conditions present in Titan's atmosphere were calculated. The low molecular weight compounds likely to be present in the atmosphere and aerosols of Titan as a result of photochemical processes are proposed.  相似文献   

5.
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6.
Results of the experiments on model impact vaporization of peridotite, a mineral analogue of stony asteroids, in a nitrogen–methane atmosphere are presented. Nd-glass laser (γ = 1.06 µm) was used for simulation. Pulse energy was ~600–700 J, pulse duration ~10–3 s, vaporization tempereature ~4000–5000 K. The gaseous medium (96% vol. of N2 and 4% vol. of CH4, P = 1 atm) was a possible analogue of early atmospheres of terrestrial planets and corresponded to the present-day atmosphere composition of Titan, a satellite of Saturn. By means of pyrolytic gas chromatography/mass spectrometry, it is shown that solid condensates obtained in laser experiments contain relatively complex lowand high-molecular weight (kerogen-like) organic compounds. The main products of condensate pyrolysis were benzene and alkyl benzenes (including long-chain ones), unbranched aliphatic hydrocarbons, and various nitrogen-containing compounds (aliphatic and aromatic nitriles and pyrrol). It is shown that the nitrogen–methane atmosphere favors the formation of complex organic compounds upon hypervelocity impacts with the participation of stony bodies even with a small methane content in it. In this process, falling bodies may not contain carbon, hydrogen, and other chemical elements necessary for the formation of the organic matter. In such conditions, a noticeable contribution to the impact-induced synthesis of complex organic substances is probably made by heterogeneous catalytic reactions, in particular, Fischer–Tropsch type reactions.  相似文献   

7.
New low-temperature methane absorption coefficients pertinent to the Titan environment are presented as derived from the Huygens DISR spectral measurements combined with the in-situ measurements of the methane gas abundance profile measured by the Huygens Gas Chromatograph/Mass Spectrometer (GCMS). The visible and near-infrared spectrometers of the descent imager/spectral radiometer (DISR) instrument on the Huygens probe looked upward and downward covering wavelengths from 480 to 1620 nm at altitudes from 150 km to the surface during the descent to Titan's surface. The measurements at continuum wavelengths were used to determine the vertical distribution, single-scattering albedos, and phase functions of the aerosols. The gas chromatograph/mass spectrometer (GCMS) instrument on the probe measured the methane mixing ratio throughout the descent. The DISR measurements are the first direct measurements of the absorbing properties of methane gas made in the atmosphere of Titan at the pathlengths, pressures, and temperatures that occur there. Here we use the DISR spectral measurements to determine the relative methane absorptions at different wavelengths along the path from the probe to the sun throughout the descent. These transmissions as functions of methane path length are fit by exponential sums and used in a haze radiative transfer model to compare the results to the spectra measured by DISR. We also compare the recent laboratory measurements of methane absorption at low temperatures [Irwin et al., 2006. Improved near-infrared methane band models and k-distribution parameters from 2000 to 9500 cm−1 and implications for interpretation of outer planet spectra. Icarus 181, 309-319] with the DISR measurements. We find that the strong bands formed at low pressures on Titan act as if they have roughly half the absorption predicted by the laboratory measurements, while the weak absorption regions absorb considerably more than suggested by some extrapolations of warm measurements to the cold Titan temperatures. We give factors as a function of wavelength that can be used with the published methane coefficients between 830 and 1620 nm to give agreement with the DISR measurements. We also give exponential sum coefficients for methane absorptions that fit the DISR observations. We find the DISR observations of the weaker methane bands shortward of 830 nm agree with the methane coefficients given by Karkoschka [1994. Spectrophotometry of the jovian planets and Titan at 300- to 1000-nm wavelength: the methane spectrum. Icarus 111, 174-192]. Finally, we discuss the implications of our results for computations of methane absorption in the atmospheres of the outer planets.  相似文献   

8.
Molecular nitrogen, the main component of the modern atmosphere of Titan, may have formed without significant changes in the nitrogen and hydrogen isotopic composition from the clathrate hydrate of ammonia NH3 · H2OSLD, which is the main accreted form of nitrogen. The most preferable transformation mechanism of NH3 · H2OSLD into atmospheric N2 is its thermal decomposition in the interior of Titan rather than the photochemical decomposition of ammonia in the upper atmosphere of early Titan. The photolysis of ammonia does not lead to a change in the isotopic composition of nitrogen, as all the nitrogen remains in Titan’s atmosphere. The photolysis of NH does not lead to a change in the isotopic composition of nitrogen in Titan’s atmosphere. Fractionation of hydrogen and nitrogen isotopes during the impacts of comets with Titan does not seem to be significant either. It will be possible to determine the dissociative fractionation factor, the original ratio 14N/15N, and the mass of Titan’s original atmosphere when fractionation of nitrogen isotopes in Titan’s atmosphere is examined in additional theoretical and experimental studies that take into account processes occurring during the formation of a system of Saturn’s satellites.  相似文献   

9.
There are observational and theoretical evidences both in favor of and against hydrodynamic escape (HDE) on Titan, and the problem remains unsolved. A test presented here for a static thermosphere does not support HDE on Titan and Triton but favors HDE on Pluto. Cooling of the atmosphere by the HCN rotational lines is limited by rotational relaxation above 1100 km and self-absorption below 900 km on Titan. HDE can affect the structure and composition of the atmosphere and its evolution. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempts to calculate them separately may result in significant errors. Here we apply our photochemical model of Titan’s atmosphere and ionosphere to the case of no hydrodynamic escape. Our model is still the only after-Cassini self-consistent model of coupled neutral and ion chemistry. The lack of HDE is a distinct possibility, and comparing models with and without HDE is of practical interest. The mean difference between the models and the neutral and ion compositions observed by INMS are somewhat better for the model with HDE. A reaction of NH2 with H2CN suggested by Yelle et al. (2009) reduces but does not remove a significant difference between the ammonia abundances in the models and INMS observations. Losses of methane and nitrogen and production and deposition to the surface of hydrocarbons and nitriles are evaluated in the model, along with lifetimes and evolutionary aspects.  相似文献   

10.
Titan has a surface temperature of 94 K and a surface pressure of 1.4 atmospheres. These conditions make it possible for liquid methane solutions to be present on the surface. Here, we consider how Titan could have liquid methane while orbiting around an M4 red dwarf star, and a special case of Titan orbiting the red dwarf star Gliese 581. Because light from a red dwarf star has a higher fraction of infrared than the Sun, more of the starlight will reach the surface of Titan because its atmospheric haze is more transparent to infrared wavelengths. If Titan was placed at a distance from a red dwarf star such that it received the same average flux as it receives from the Sun, we calculate the increased infrared fraction, which will warm surface temperatures by an additional ∼10 K. Compared to the Sun, red dwarf stars have less blackbody ultraviolet light but can have more Lyman α and particle radiation associated with flares. Thus depending on the details, the haze production may be much higher or much lower than for the current Titan. With the haze reduced by a factor of 100, Titan would have a surface temperature of 94 K at a distance of 0.23 AU from an M4 star and at a distance of 1.66 AU, for Gliese 581. If the haze is increased by a factor of 100 the distances become 0.08 and 0.6 AU for the M4-star and Gliese 581, respectively. As a rogue planet, with no incident stellar flux, Titan would need 1.6 W/m2 of geothermal heat to maintain its current surface temperature, or an atmospheric opacity of 20× its present amount with 0.1 W/m2 of geothermal heat. Thus Titan-like worlds beyond our solar system may provide environment supporting surface liquid methane.  相似文献   

11.
Abstract— A simple thermal model is developed to determine the temperature history of the inlet tube of the Huygens probe gas chromatograph mass spectrometer (GCMS) after its fortuitous emplacement on the surface of Saturn's moon Titan. The model parameters are adjusted to match the recorded temperature history of a nearby heater, taking into account heat losses by conduction to the rest of the probe and to Titan's cold atmosphere. The model suggests that after impact when forced convective cooling ceased, the inlet temperature rose from ?110 K to an asymptotic value of only ?145 K. This requires that the inlet was embedded in a surface that acted as an effective heat sink, most plausibly interpreted as wet or damp with liquid methane. The data appear inconsistent with a tar or dry, fine‐grained surface, and the inlet was not warm enough to devolatilize methane hydrate.  相似文献   

12.
Carl Sagan 《Icarus》1973,18(4):649-656
Both non-gray radiative equilibrium and gray convective equilibrium calculations for Titan indicate that the discrepancy between the equilibrium temperature of an atmosphereless Titan and the observed infrared temperatures can be explained by a massive molecular hydrogen greenhouse effect. The convective calculations indicate a probable minimum optical depth of 14, corresponding to many tens of km-atm of H2, and total pressures of ～0.1 bar. The tropopause is several hundred km above the Titanian surface and at a temperature of about 90°K. Methane condensation is likely at this level. Such an atmosphere is unstable against atmospheric blow-off unless typical mesosphere scale heights are < 25km, an unlikely situation. Blow-off can also be circumvented by exospheric temperatures near the freezing point of hydrogen. It is considered more plausible that the present atmosphere is in equilibrium between outgassing and blow-off of the one hand and accretion from protons trapped in a hypothetical Saturnian magnetic field on the other; or exhibits uncompensated blow-off of outgassing products. To maintain the present blow-off rate without compensation for all of geological time requires an outgassing equivalent to the volatilization of a few km of subsurface ices. Photo-dissociation of these volatilized ices produces the observed high abundance of H2 as well as large quantities of complex organic chromophores which may explain the reddish coloration of the Titanian cloud deck. An extensive circum-Titanian hydrogen corona is postulated. Surface temperatures as high as 200°K are not excluded. Because of its high temperatures and pressures and the probable large abundance of organic compounds, Titan is a prime target for spacecraft exploration in the outer solar system.  相似文献   

13.
Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and converted to heavier hydrocarbons irreversibly on a relatively short timescale of approximately 10-100 million years. Without the warming provided by CH4-generated hydrocarbon hazes in the stratosphere and the pressure induced opacity in the infrared, particularly by CH4-N2 and H2-N2 collisions in the troposphere, the atmosphere could be gradually reduced to as low as tens of millibar pressure. An understanding of the source-sink cycle of methane is thus crucial to the evolutionary history of Titan and its atmosphere. In this paper we propose that a complex photochemical-meteorological-hydrogeochemical cycle of methane operates on Titan. We further suggest that although photochemistry leads to the loss of methane from the atmosphere, conversion to a global ocean of ethane is unlikely. The behavior of methane in the troposphere and the surface, as measured by the Cassini-Huygens gas chromatograph mass spectrometer, together with evidence of cryovolcanism reported by the Cassini visual and infrared mapping spectrometer, represents a “methalogical” cycle on Titan, somewhat akin to the hydrological cycle on Earth. In the absence of net loss to the interior, it would represent a closed cycle. However, a source is still needed to replenish the methane lost to photolysis. A hydrogeochemical source deep in the interior of Titan holds promise. It is well known that in serpentinization, hydration of ultramafic silicates in terrestrial oceans produces H2(aq), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas. Appropriate geological, thermal, and pressure conditions could have existed in and below Titan's purported water-ammonia ocean for “low-temperature” serpentinization to occur in Titan's accretionary heating phase. On the other hand, impacts could trigger the process at high temperatures. In either instance, storage of methane as a stable clathrate-hydrate in Titan's interior for later release to the atmosphere is quite plausible. There is also some likelihood that the production of methane on Titan by serpentinization is a gradual and continuous on-going process.  相似文献   

14.
A review of non-local, deep transport mechanisms in the atmosphere of Earth provides a good foundation for examining whether similar mechanisms are operating in the atmospheres of Mars and Titan. On Earth, deep convective clouds in the tropics constitute the upward branch of the Hadley Cell and provide a conduit through which energy, moisture, momentum, aerosols, and chemical species are moved from the boundary layer to the upper troposphere and lower stratosphere. This transport produces mid-tropospheric minima in quantities such as water vapor and moist static energy and maxima where the clouds detrain. Analogs to this terrestrial transport are found in the strong and deep thermal circulations associated with topography on Mars and with Mars dust storms. Observations of elevated dust layers on Mars further support the notion that non-local deep transport is an important mechanism in the atmosphere of Mars. On Titan, the presence of deep convective clouds almost assures that non-local, deep transport is occurring and these clouds may play a role in global cycling of energy, momentum, and methane. Based on the potential importance of non-local deep transport in Earth's atmosphere and supported by evidence for such transport in the atmospheres of Mars and Titan, greater attention to this mechanism in extraterrestrial atmospheres is warranted.  相似文献   

15.
In Titan's atmosphere consisting of N2 and CH4, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N2 and CH4 gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×10−3×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry.  相似文献   

16.
《Icarus》1987,70(1):61-77
The origin of methane at the present surface of Titan is modeled in light of new high-pressure phase diagrams of ammonia-water compounds and clathrate hydrate. Using recently published experimental data on the ammonia-water system at kilobar pressures, temperature-composition slices of the phase diagram are constructed at a series of pressures up to 12 kbar. A new phase of ammonia dihydrate is proposed and incorporated in the diagrams, to allow consistency with low-pressure data. These results, along with the high-pressure phase diagram of methane clathrate hydrate recently caculated by J. I. Lunine and D. J. Stevenson (1985a, Astrophys. J. Suppl. 58, 493–531) are applied to a model for the origin of the methane presently on the surface of Titan. Using simple bounds on the accretional temperatures and postaccretional state of an ammonia-rich Titan, we show that an unstable interior configuration is likely immediately after accretion, in which a rock layer is positioned above a lower-density rock-ice core. When core overturns begins the methane in the core, which is released from the clathrate structure by virtue of the high pressures, migrates upward. A model for the cooling and freezing of an ammonia-water ocean in the upper mantle of Titan, based on the phase diagram, is applied and it is concluded that insufficient liquid water exists to retrap all of the upwelling methane as clathrate. However, alternative interpretations of the phase diagram permit an ocean thick enough to entrap the methane. For the bulk of the range of plausible accretion models, enough methane is available from the interior to account for the present-day surface hydrocarbon abundance; however, the amount of nitrogen extruded in this model may be much smaller.  相似文献   

17.
A simple steady-state photochemical model is developed in order to determine typical molecular oxygen concentrations for a comprehensive range of primitive abiotic atmospheres. Carbon dioxide is assumed to be the dominant constituent in these atmospheres since CO2 photodissociation may potentially result in the enhancement of the O2 partial pressure. The respective effects of the H2O content, temperature, eddy diffusion coefficient and UV flux on the results are investigated. It is shown that for any pressure at the surface, the partial pressure of molecular oxygen does not exceed 10 mbar. The peculiar case of a runaway greenhouse which has possibly taken place on Venus is qualitatively envisaged. Although O2 is basically absent in the present Venus atmosphere, a transient presence in a primitive stage cannot be ruled out. Possible mechanisms for O2 removal in such an atmosphere are reviewed. At the present stage, we think that the detection of large O2 amounts would be at least a good clue for the presence of life on an extrasolar planet.  相似文献   

18.
Hitherto Jupiter's spectrum at short millimeter wavelenghts showed a clear discrepancy with model calculations (e.g., G.L. Berge and S. Gulkis, 1976, In Jupiter (T. Gehrels, Ed.), pp. 621–692. Univ. of Arizona Press, Tucson). A similar although less pronounced, discrepancy appears to exist for Uranus and Neptune. One explanation of this discrepancy is that additional absorbers not included in the model calculations are present in the atmosphere. It was suggested that uncertainties in the absorption coefficient of ammonia, especially at millimeter wavelengths, may be responsible for at least part of the discrepancy. A comparison of various model atmosphere calculations with data for all four giant planets is shown. The absorption profile of ammonia at centimeter wavelengths was assumed to be rightly represented by a Ben Reuven line profile, which enabled the derivation of information on the vertical distribution of ammonia in these planets' atmospheres. It appeared that ammonia must be depleted in the upper atmospheres of all four planets by a factor of 4–5 with respect to the solar abundance for Jupiter (and Saturn) and by a factor of 100–200 for Uranus and Neptune. At deeper layers the optical depth is larger, due either to a larger abundance of ammonia or to absorption by the presence of water. Given the vertical ammonia distribution in the atmospheres as derived from the centimeter data, a best fit to the millimeter spectra of all four planets was found by changing the high frequency tail of the ammonium lineshape profile. This, we feel, is legitimate since the profile at millimeter wavelenghts is not or is only poorly known due to the absence of laboratory spectra for ammonia as a trace constituent in an otherwise hydrogen gas. It was found that a line profile which at millimeter wavelenghts more closely resembles a Van Vleck-Weisskopf lineshape than the usually adopted Ben Reuven profile gives a rather satisfactory fit to the data of all four gaseous planets.  相似文献   

19.
We develop a semiempirical grey radiative model to quantify Titan’s surface temperature as a function of pressure and composition of a nitrogen-methane-hydrogen atmosphere, solar flux and atmospheric haze. We then use this model, together with non-ideal gas-liquid equilibrium theory to investigate the behavior of the coupled surface-atmosphere system on Titan. We find that a volatile-rich Titan is unstable with respect to a runaway greenhouse—small increases in solar luminosity from the present value can lead to massive increases in surface temperature. If methane has been photolyzed throughout Titan’s history, then this runaway can only be avoided if the photolytic ethane is removed from the surface-atmosphere system.  相似文献   

20.
We have conducted high-pressure experiments in the H2O-CH4 and H2O-CH4-NH3 systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH3 solution decreases the dissociation temperature of methane clathrates by 14-25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia-water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.  相似文献   

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