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1.
The chemical compositions of shergottite meteorites, basaltic rocks from Mars, provide a broad view of the origins and differentiation of these Martian magmas. The shergottite basalts are subdivided based on their Al contents: high‐Al basalts (Al > 5% wt) are distinct from low‐Al basalts and olivine‐phyric basalts (both with Al < 4.5% wt). Abundance ratios of highly incompatible elements (e.g., Th, La) are comparable in all the shergottites. Abundances of less incompatible elements (e.g., Ti, Lu, Hf) in olivine‐phyric and low‐Al basalts correlate well with each other, but the element abundance ratios are not constant; this suggests mixing between components, both depleted and enriched. High‐Al shergottites deviate from these trends consistent with silicate mineral fractionation. The “depleted” component is similar to the Yamato‐980459 magma; approximately, 67% crystal fractionation of this magma would yield a melt with trace element abundances like QUE 94201. The “enriched” component is like the parent magma for NWA 1068; approximately, 30% crystal fractionation from it would yield a melt with trace element abundances like the Los Angeles shergottite. This component mixing is consistent with radiogenic isotope and oxygen fugacity data. These mixing relations are consistent with the compositions of many of the Gusev crater basalts analyzed on Mars by the Spirit rover (although with only a few elements to compare). Other Mars basalts fall off the mixing relations (e.g., Wishstone at Gusev, Gale crater rocks). Their compositions imply that basalt source areas in Mars include significant complexities that are not present in the source areas for the shergottite basalts.  相似文献   

2.
Abstract— Until recently, the SNC meteorites represented the only source of information about the chemistry and petrology of the Martian surface and mantle. The Mars Exploration Rovers have now analyzed rocks on the Martian surface, giving additional insight into the petrology and geochemistry of the planet. The Adirondack basalts, analyzed by the MER Spirit in Gusev crater, are olivine‐phyric basaltic rocks which have been suggested to represent liquids, and might therefore provide new insights into the chemistry of the Martian mantle. Experiments have been conducted on a synthetic Humphrey composition at upper mantle and crustal conditions to investigate whether this composition might represent a primary mantle‐derived melt. The Humphrey composition is multiply saturated at 12.5 kbar and 1375 °C with olivine and pigeonite; a primary anhydrous melt derived from a “chondritic” mantle would be expected to be saturated in orthopyroxene, not pigeonite. In addition, the olivine and pigeonite present at the multiple saturation are too ferroan to have been from a Martian mantle as is understood now. Therefore, it seems likely that the Humphrey composition does not represent a primary anhydrous melt from the Martian mantle, but was affected by mineral/melt fractionations at lower (crustal) pressures.  相似文献   

3.
Abstract— Phase equilibrium experiments have been performed on a synthetic analog of the Gusev plains basalt composition from the Spirit landing site on Mars. Near‐liquidus phase relations were determined over the pressure range of 0.1 to 1.5 GPa and at temperatures from 1125 to 1390 °C in a piston cylinder apparatus and 1 atm gas mixing furnace. The composition is multiply saturated with olivine, orthopyroxene, and spinel near its liquidus at 1320 °C and 1.0 GPa, or 85 km depth on Mars, placing an upper limit constraint on the thickness of the Martian lithosphere at the time of eruption. Our experimental work suggests that the Gusev basalts are anhydrous batch melts of a primitive Martian mantle similar to the composition estimated by Dreibus and Wänke (1984). The temperature of multiple saturation indicates the persistence of high mantle potential temperatures on Mars, similar to those on the modern Earth, until at least the very latest Noachian (3.7 Ga). These high mantle temperatures would be responsible for persistent basaltic volcanism throughout the southern highlands during the first billion years of Mars's history. The source for Gusev basalts differs strongly from the source for shergottite meteorites, reinforcing the idea of the absence of global mantle convection and mixing on Mars. The existence of a relatively primitive mantle reservoir requires that at least part of the mantle underwent little modification during early planetary differentiation.  相似文献   

4.
The Mars Exploration Rover, Spirit, landed on 4 January 2004, in a lava field in Gusev crater on Mars. Samples interpreted as olivine basalt have been investigated with Mössbauer spectroscopy and chemically with Alpha-particle-X-ray spectrometry (APXS).In this contribution we present the results of a new analysis of the Mössbauer spectra of selected rock targets in Gusev crater. The results show that the rock surfaces investigated are inhomogeneous, and show strong enhancement of olivine in the surface layer. By subtraction of the surface signal to obtain the spectrum of the true interior of the rock samples, the measurements show the usual correlation between olivine and iron oxides of olivine basalt.It is argued that the compositional changes observed are related to high temperature oxidation of the rocks, probably during solidification, a process known to lead to anomalously magnetic rocks. The rock Mazatzal is discussed in some detail, and it is suggested that the surface is covered with deposits rich in ferric iron rather than these ferric phases being due to oxidation of the rock. The fact that all the surfaces in this investigation show this same pattern, suggests that the dominating erosion of the surface layer of basaltic rocks at Gusev crater has been mechanical rather than chemical.  相似文献   

5.
The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single‐laser‐shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg# = 54. We suggest that all of these igneous rocks resulted from low‐pressure, olivine‐dominated fractionation of Adirondack (MER) class‐type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe‐rich, relatively low‐Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine‐grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. The Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.  相似文献   

6.
The Mars Exploration Rover (MER) missions have confirmed aqueous activity on Mars. Here we review the analyses of the field-based MER data, and conclude that some weathering processes in Meridiani Planum and Gusev crater are better explained by late diagenetic water-rock interactions than by early diagenesis only. At Meridiani, the discovery of jarosite by MER-1 Opportunity indicates acidic aqueous activity, evaporation, and desiccation of rock materials. MER-based information, placed into the context of published data, point to local and limited aqueous activity during geologically recent times in Meridiani. Pre-Amazonian environmental changes (including important variations in the near-surface groundwater reservoirs, impact cratering, and global dust storms and other pervasive wind-related erosion) are too extreme for pulverulent jarosite to survive over extended time periods, and therefore we argue instead that jarosite deposits must have formed in a climatically more stable period. Any deposits of pre-existent concretionary jarosite surviving up to the Amazonian would not have reached completion in the highly saline and acidic brines occurring at Meridiani. MER-2 Spirit has also revealed evidence for local and limited Amazonian aqueous environmental conditions in Gusev crater, including chemical weathering leading to goethite and hematite precipitation, rock layering, and chemical enhancement of Cl, S, Br, and oxidized iron in rocks and soils. The estimated relative age of the impact crater materials in Gusev indicates that these processes have taken place during the last 2 billion years. We conclude that minor amounts of shallow acidic liquid water have been present on the surface of Mars at local scales during the Amazonian Period.  相似文献   

7.
John Carter  Francois Poulet 《Icarus》2012,219(1):250-253
Gusev crater was selected as the landing site of one of the two NASA Mars Exploration Rovers because water once could have ponded within the crater and partly filled it with sediments as suggested by the presence of a feeder channel and the fluvial-lacustrine morphology of the in-filling. However, the paucity of mineralogical evidence for fluvial-lacustrine activity revealed by the Spirit rover has remained a puzzle for years. Using orbital, near-infrared imaging spectroscopy, we report the detection of phyllosilicates and carbonates within and around the landing site of Spirit on the floor of Gusev crater. Placed in their geomorphological context, these minerals shed new light on the aqueous history of this crater, and offer a framework for the Spirit in situ measurements.  相似文献   

8.
The composition of the silicate portion of Martian regolith fines indicates derivation of the fines from mafic to ultramafic igneous rocks, probably rich in pyroxene. Rock types similar in chemical and mineralogical composition include terrestrial Archean basalts and certain achondrite meteorites. If these igneous rocks weathered nearly isochemically, the nontronitic clays proposed earlier as an analog to Martian fines could be formed. Flood basalts of pyroxenitic lavas may be widespread and characteristic of early volcanism on Mars, analogous to maria flood basalts on the Moon and early Precambrian basaltic komatiites on Earth. Compositional differences between lunar, terrestrial, and Martian flood basalts may be related to differences in planetary sizes and mantle compositions of the respective planetary objects.  相似文献   

9.
Abstract– Sample preparation, involving physical and chemical methods, is an unavoidable step in geochemical analysis. From a noble gas perspective, the two important effects are loss of sample gas and/or incorporation of air, which are significant sources of analytical artifacts. This article reports on the effects of sample exposure to laboratory air without mechanical influence and during sample grinding. The experiments include pure adsorption on terrestrial analog materials (gibbsite and olivine) and grinding of Martian meteorites. A consistent observation is the presence of an elementally fractionated air component in the samples studied. This is a critical form of terrestrial contamination in meteorites as it often mimics the heavy noble gas signatures of known extra‐terrestrial end‐members that are the basis of important conclusions about the origin and evolution of a meteorite. Although the effects of such contamination can be minimized by avoiding elaborate sample preparation protocols, caution should be exercised in interpreting the elemental ratios (Ar/Xe, Kr/Xe), especially in the low‐temperature step extractions. The experiments can also be transferred to the investigation of Martian meteorites with long terrestrial residence times, and to Mars, where the Mars Science Laboratory mission will be able to measure noble gas signatures in the current atmosphere and in rocks and soils collected on the surface in Gale crater.  相似文献   

10.
Abstract— The Lonar crater, India, is the only well‐preserved simple crater on Earth in continental flood basalts; it is excavated in the Deccan trap basalts of Cretaceous‐Tertiary age. A representative set of target basalts, including the basalt flows excavated by the crater, and a variety of impact breccias and impact glasses, were analyzed for their major and trace element compositions. Impact glasses and breccias were found inside and outside the crater rim in a variety of morphological forms and shapes. Comparable geochemical patterns of immobile elements (e.g., REEs) for glass, melt rock and basalt indicates minimal fractionation between the target rocks and the impactites. We found only little indication of post‐impact hydrothermal alteration in terms of volatile trace element changes. No clear indication of an extraterrestrial component was found in any of our breccias and impact glasses, indicating either a low level of contamination, or a non‐chondritic or otherwise iridium‐poor impactor.  相似文献   

11.
Abstract— Martian meteorites (MMs) have been launched from an estimated 5–9 sites on Mars within the last 20 Myr. Some 80–89% of these launch sites sampled igneous rock formations from only the last 29% of Martian time. We hypothesize that this imbalance arises not merely from poor statistics, but because the launch processes are dominated by two main phenomena: first, much of the older Martian surface is inefficient in launching rocks during impacts, and second, the volumetrically enormous reservoir of original cumulate crust enhances launch probability for 4.5 Gyr old rocks. There are four lines of evidence for the first point, not all of equal strength. First, impact theory implies that MM launch is favored by surface exposures of near‐surface coherent rock (≤102 m deep), whereas Noachian surfaces generally should have ≥102 m of loose or weakly cemented regolith with high ice content, reducing efficiency of rock launch. Second, similarly, both Mars Exploration Rovers found sedimentary strata, 1–2 orders of magnitude weaker than Martian igneous rocks, favoring low launch efficiency among some fluvial‐derived Hesperian and Noachian rocks. Even if launched, such rocks may be unrecognized as meteorites on Earth. Third, statistics of MM formation age versus cosmic‐ray exposure (CRE) age weakly suggest that older surfaces may need larger, deeper craters to launch rocks. Fourth, in direct confirmation, one of us (N. G. B.) has found that older surfaces need larger craters to produce secondary impact crater fields (cf. Barlow and Block 2004). In a survey of 200 craters, the smallest Noachian, Hesperian, and Amazonian craters with prominent fields of secondaries have diameters of ?45 km, ?19 km, and ?10 km, respectively. Because 40% of Mars is Noachian, and 74% is either Noachian or Hesperian, the subsurface geologic characteristics of the older areas probably affect statistics of recognized MMs and production rates of secondary crater populations, and the MM and secondary crater statistics may give us clues to those properties.  相似文献   

12.
Abstract— The mobilization of K, rare earth elements (REE), Th, and U from Martian surface material upon contact with acidic solutions probably occurred extensively on Mars about 4 to 3.5 Ga ago and seems to have occurred locally in more recent times. We have studied the dissolution of these elements by leaching the basaltic shergottite Zagami and the terrestrial basalt BE‐N at constant pH values ranging from 5 to 1 in the absence and presence of added salts. Potassium is nearly immobile in Zagami and mobilized readily from BE‐N. The REE reside mostly in calcium phosphates and dissolve readily, with those in whitlockite of Zagami reacting slightly better than those in apatite of BE‐N. Thorium and U also reside mostly in calcium phosphates. Both dissolve similarly for both basalts and less readily than the REE. The experiments indicate the extent of the mobilization of K, REE, Th, and U, when acidic water leached the surface of Mars. Potassium was released slowly and in a small relative amount. The REE, and particularly the LREE, became mobile readily and were possibly distributed over large areas before immobilization. Thorium and U dissolved more slowly than the REE and were distributed less widely.  相似文献   

13.
Knowledge of Martian igneous basaltic compositions is crucial for constraining mantle evolution, including early differentiation and mantle convection. Primitive magmas provide direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The recently discovered Martian meteorite Northwest Africa (NWA) 5789 is an olivine‐phyric shergottite. NWA 5789 has special significance among the Martian meteorites because it appears to represent one of the most magnesian Martian magmas known, other than Yamato (Y) 980459. Its most magnesian olivine cores (Fo85) are in Mg‐Fe equilibrium with a magma of the bulk rock composition, suggesting that the bulk represents a magma composition. Based on the Al/Ti ratio of its pyroxenes, we infer that the rock began to crystallize at a high pressure consistent with conditions in Mars’ lower crust/upper mantle. It continued and completed its crystallization closer to the surface, where cooling was rapid and produced a mesostasis of radiating sprays of plagioclase and pyroxene. The mineralogy, petrology, mineral chemistry, and bulk rock composition of NWA 5789 are very similar to those of Y‐980459. The similarities between the two meteorites suggest that NWA 5789 (like Y‐980459) represents a primitive, mantle‐derived magma composition. They also suggest the possibility that NWA 5789 and Y‐980459 formed in the same lava flow. However, based on the mineralogy and texture of its mesostasis, NWA 5789 must have cooled more slowly than Y‐980459. NWA 5789 will help elucidate the igneous geology and geochemistry of Mars.  相似文献   

14.
Mars appears to have experienced little compositional differentiation of primitive lithosphere, and thus much of the surface of Mars is covered by mafic lavas. On Earth, mafic and ultramafic rocks present in ophiolites, oceanic crust and upper mantle that have been obducted onto land, are therefore good analogs for Mars. The characteristic mineralogy, aqueous geochemistry, and microbial communities of cold-water alkaline springs associated with these mafic and ultramafic rocks represent a particularly compelling analog for potential life-bearing systems. Serpentinization, the reaction of water with mafic minerals such as olivine and pyroxene, yields fluids with unusual chemistry (Mg–OH and Ca–OH waters with pH values up to ～12), as well as heat and hydrogen gas that can sustain subsurface, chemosynthetic ecosystems. The recent observation of seeps from pole-facing crater and canyon walls in the higher Martian latitudes supports the hypothesis that even present conditions might allow for a rock-hosted chemosynthetic biosphere in near-surface regions of the Martian crust. The generation of methane within a zone of active serpentinization, through either abiogenic or biogenic processes, could account for the presence of methane detected in the Martian atmosphere. For all of these reasons, studies of terrestrial alkaline springs associated with mafic and ultramafic rocks are particularly timely. This study focuses on the alkaline Adobe Springs, emanating from mafic and ultramafic rocks of the California Coast Range, where a community of novel bacteria is associated with the precipitation of Mg–Ca carbonate cements. The carbonates may serve as a biosignature that could be used in the search for evidence of life on Mars.  相似文献   

15.
Analytical estimates of melt volumes produced by a given projectile and contained in a given impact crater are derived as a function of impact velocity, impact angle, planetary gravity, target and projectile densities, and specific internal energy of melting. Applications to impact events and impact craters on the Earth, Moon, and Mars are demonstrated and discussed. The most probable oblique impact (45°) produces ～1.6 times less melt volume than a vertical impact, and ～1.6 and 3.7 times more melt volume than impacts with 30° and 15° trajectories, respectively. The melt volume for a particular crater diameter increases with planetary gravity, so a crater on Earth should have more melt than similar-size craters on Mars and the Moon. The melt volume for a particular projectile diameter does not depend on gravity, but has a strong dependence on impact velocity, so the melt generated by a given projectile on the Moon is significantly larger than on Mars. Higher surface temperatures and geothermal gradients increase melt production, as do lower energies of melting. Collectively, the results imply thinner central melt sheets and a smaller proportion of melt particles in impact breccias on the Moon and Mars than on Earth. These effects are illustrated in a comparison of the Chicxulub crater on Earth, linked to the Cretaceous–Tertiary mass extinction, Gusev crater on Mars, where the Mars Exploration Rover Spirit landed, and Tsiolkovsky crater on the Moon. The results are comparable to those obtained from field and spacecraft observations, other analytical expressions, and hydrocode simulations.  相似文献   

16.
Hydrous alteration of olivine macrocrysts in a Martian olivine phyric basalt, NWA 10416, and a terrestrial basalt from southern Colorado are examined using SEM, EPMA, TEM, and µXRD techniques. The olivines in the meteorite contain linear nanotubes of hydrous material, amorphous areas, and fluid dissolution textures quite distinct from alteration identified in other Martian meteorites. Instead, they bear resemblance to terrestrial deuteric alteration features. The presence of the hydrous alteration phase Mg‐laihunite within the olivines has been confirmed by µXRD analysis. The cores of the olivines in both Martian and terrestrial samples are overgrown by unaltered rims whose compositions match those of a separate population of groundmass olivines, suggesting that the core olivines are xenocrysts whose alteration preceded crystallization of the groundmass. The terrestrial sample is linked to deep crustal metasomatism and the “ignimbrite flare‐up” of the Oligocene epoch. The comparison of the two samples suggests the existence of an analogous relatively water‐rich magmatic reservoir on Mars.  相似文献   

17.
Abstract— We investigated the transfer of meteorites from Mars to Earth with a combined mineralogical and numerical approach. We used quantitative shock pressure barometry and thermodynamic calculations of post‐shock temperatures to constrain the pressure/temperature conditions for the ejection of Martian meteorites. The results show that shock pressures allowing the ejection of Martian meteorites range from 5 to 55 GPa, with corresponding post‐shock temperature elevations of 10 to about 1000 °C. With respect to shock pressures and post‐shock temperatures, an ejection of potentially viable organisms in Martian surface rocks seems possible. A calculation of the cooling time in space for the most highly shocked Martian meteorite Allan Hills (ALH) 77005 was performed and yielded a best‐fit for a post‐shock temperature of 1000 °C and a meteoroid size of 0.4 to 0.6 m. The final burial depths of the sub‐volcanic to volcanic Martian rocks as indicated by textures and mineral compositions of meteorites are in good agreement with the postulated size of the potential source region for Martian meteorites during the impact of a small projectile (200 m), as defined by numerical modeling (Artemieva and Ivanov 2004). A comparison of shock pressures and ejection and terrestrial ages indicates that, on average, highly shocked fragments reach Earth‐crossing orbits faster than weakly shocked fragments. If climatic changes on Mars have a significant influence on the atmospheric pressure, they could account for the increase of recorded ejection events of Martian meteorites in the last 5 Ma.  相似文献   

18.
Images from Mars Global Surveyor and later images from Mars Reconnaissance Orbiter reveal that roughly half of the meteoroids striking Mars (at meter to few decameter crater diameters) fragment in the Martian atmosphere, producing small clusters of primary impact craters. Statistics of these “primary clusters” yield valuable information about important Martian phenomena and properties of interplanetary bodies, including meteoroid behavior in the Martian atmosphere, bulk strengths of bodies striking Mars, and the fraction of Martian “field secondary” craters, a datum that would improve crater count chronometry. Many Martian impactors fragment at altitudes significantly higher than 18 km above the mean surface of Mars, and we find that most bodies striking Mars and Earth have low bulk strengths, consistent with crumbly or highly fractured objects. Applying statistics of primary clusters at various elevations and independent diameter bins, we describe a technique to estimate the percentage of semirandomly scattered “field secondary” craters. Our provisional estimate of this percentage, in the diameter range ~250 m down to ~22 m, is ~40% to ~80% of the total impacts, with the higher percentages at smaller diameters. Our data argue against earlier suggestions of overwhelming dominance by either primaries or secondaries in this diameter range.  相似文献   

19.
Abstract— Radiometric age dating of Martian rocks and surfaces at known locations for which crater densities can be determined is highly desirable in order to fully understand Martian history. Performing K‐Ar age dating of igneous rocks on Mars by robots, however, presents technical challenges. Some of these challenges can be defined by examining Ar‐Ar data acquired on Martian meteorites, and others can be evaluated through numerical modeling of simulated K‐Ar isochrons like those that would be acquired robotically on Martian rocks. Excess 40Ar is present in all shergottites. Thus for Martian rocks, the slopes of K‐Ar isochrons must be determined to reasonable precision in order to calculate reliable ages. Model simulations of possible isochrons give an indication of some requirements in order to define a precise rock age: Issues addressed here are: how many K‐Ar analyses should be made of rocks thought to have the same age; what range of K concentrations should these analyzed samples have; and what analytical uncertainty in K‐Ar measurements is desirable. Meteorite data also are used to determine the D/a2 diffusion parameters for Ar in plagioclase and pyroxene separates of several shergottites and nakhlites. These data indicate the required temperatures and times for heating similar Martian rocks in order to extract Ar. Quantitatively extracting radiogenic 40Ar could be difficult, and degassing cosmogenic Ar from mafic phases even more so. Considering all these factors, robotic K‐Ar dating of Martian rocks may be achievable, but will be challenging.  相似文献   

20.
Abstract— Eighteen new lithic fragments from the Soviet Luna missions have been analyzed with electron microprobe and 40Ar‐39Ar methods. Luna 16 basalt fragments have aluminous compositions consistent with previous analyses, but have two distinct sets of well‐constrained ages (3347 ± 24 Ma, 3421 ± 30 Ma). These data, combined with other Luna 16 basalt ages, imply that there were multiple volcanic events filling Mare Fecunditatis. The returned basalt fragments have relatively old cosmicray exposure (CRE) ages and may have been recovered from the ejecta blanket of a young (1 Ga), nearby crater. A suite of highlands rocks (troctolites and gabbros) is represented in the new Luna 20 fragments. One fragment is the most compositionally primitive (Mg# = 91–92) spinel troctolite yet found. Both troctolites have apparent crystallization ages of 4.19 Ga; other rocks in the suite have progressively younger ages and lower Mg#s. The age and composition progression suggests that these rocks may have crystallized from a single source magma, or from similar sources mobilized at the same time. Within the new Luna 24 basalt fragments is a quench‐textured olivine vitrophyre with the most primitive composition yet analyzed for a Luna 24 basalt, and several much more evolved olivine‐bearing basalts. Both new and previously studied Luna 24 very low‐Ti (VLT) basalt fragments have a unimodal age distribution (3273 ± 83 Ma), indicating that most returned samples come from a single extrusive episode within Mare Crisium much later than the Apollo 17 VLT basalts (3.6–3.7 Ga).  相似文献   

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