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Summary Niedermayrite, Cu4Cd(SO4)2(OH)6 · 4H2O, is a new mineral discovered in 1995 in the Km3-area of the Lavrion mining district, Greece. It forms tiny euhedral plates, commonly intergrown as green crusts up to several cm2 in size on a matrix consisting of a brecciated marble with sphalerite, chalcopyrite, galena, greenockite, hawleyite and pyrite. Associated secondary minerals are gypsum, malachite, chalcanthite, brochantite, hemimorphite, hydrozincite, aurichalcite, one unknown Cd-sulfate, monteponite and otavite. Niedermayrite is non-fluorescent and has a bluish-green colour with vitreous lustre, the streak is white. The crystals are brittle with perfect cleavage parallel {010}. Optics: biaxial (–) with n(calc.), n, and n =1.609, 1.642(2), and 1.661(2), respectively; orientation n//b. The calculated density is 3.292 gcm–3. The most prominent form is {010}. Analysis by electron microprobe gives CdO 16.5, CuO 45.7, SO3 21.6, H2O 16.2 wt.% (calc. to 100% sum) and the empirical formula Cu4.29Cd0.96S2.01O11.28 · 6.71 H2O (based on 18 oxygens p.f.u.). By TGA an H2O content of 18.9 wt.% was obtained. The ideal formula (confirmed by the crystal structure refinement) is Cu4Cd(SO4)2(OH)6 · 4H2O with a theoretical H2O content of 17.2 wt.%. The strongest lines in the X-ray powder diffraction pattern (Gandolfi camera, visually estimated I, refined lattice parameters a = 5.535(2), b = 21.947(9), c = 6.085(2) Å, = 91.98(3)°) are: (dobs[Å]/Iobs/hkl) (11.02/90/0 2 0), (5.874/20/0 1 1), (5.496/100/0 4 0), (5.322/25/0 2 1), (4.079/50/0 4 1), (3.660/20/0 6 0), (3. 437/30/1 5 0), (3.243/40/1 4 1), (2.470/30/2 4 0), (2.425/20/1 4 –2), (2.205/20/2 6 0) and (1.897/20/1 8 2). The mineral is monoclinic, P21/m, Z = 2, a = 5.543(1) Å, b = 21.995(4) Å, c = 6.079(1) Å, = 92.04(3)°, V = 740.7(2) Å3. The crystal structure was determined by single crystal X-ray methods and was refined to R1= 0.026, wR2 = 0.056. The structure of niedermayrite is characterized by
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[Cu4(OH)6O2]2– sheets of edgesharing Cu coordination octahedra parallel to (010) with attached SO4 tetrahedra, and intercalated CdO2(H2O)4 octahedra with a system of hydrogen bonds. Close relationships to the crystal structures of christelite and campigliaite exist. The new mineral is named for Dr. Gerhard Niedermayr, Naturhistorisches Museum Wien, Austria.
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Niedermayrit, Cu4Cd(SO4)2(OH)6 · 4H2O, ein neues Mineral aus dem Bergbaugebiet Lavrion, Griechenland
Zusammenfassung Niedermayrit, Cu4Cd(SO4)2(OH)6 · 4H2O, ist ein neues Mineral, das 1995 im Km3-Bereich des Bergbaugebietes Lavrion, Griechenland, gefunden wurde. Es bildet winzige gut ausgebildete Plättchen, häufig miteinander verwachsen in grünen Krusten bis zu mehreren cm2 Größe. Die Matrix besteht aus brecciösem Marmor mit Sphalerit, Chalcopyrit, Galenit, Greenockit, Hawleyit und Pyrit. Sekundäre Begleitminerale sind Gips, Malachit, Chalcanthit, Brochantit, Hemimorphit, Hydrozincit, Aurichalcit, ein unbekanntes Cd-Sulfat, Monteponit und Otavit. Niedermayrit fluoresziert nicht, besitzt blaugrüne Farbe mit Glasglanz, der Strich ist weiß. Die Kristalle sind spröd mit perfekter Spaltbarkeit parallel {010}. Optik: biaxial (–) mit n(ber.), n, und n=1.609, 1.642(2), und 1.661(2); Orientierung n//b. Die berechnete Dichte beträgt 3.292 gcm–3. Die auffallendste Flächenform ist {010}. Die chemische Analyse mittels Mikrosonde ergibt CdO 16.5, CuO 45.7, SO3 21.6, H2O 16.2wt.% (ber. auf 100% Summe) und die empirische Formel Cu4.29Cd0.96S2.01O11.28 · 6.71 H2O (basierend auf 18 Sauerstoffatomen pro Formeleinheit). Aus der TGA wurde ein H2O Gehalt von 18.9 Gew.% erhalten. Die Idealformel (bestätigt durch die Kristallstrukturverfeinerung) ist Cu4Cd(SO4)2(OH)6 · 4H2O bei einem theoretischen H2O-Gehalt von 17.2 Gew.%. Die stärksten Linien im Pulverdiffraktogramm (Gandolfi Kamera, visuell geschätzte I, verfeinerte Gitterkonstanten a = 5.535(2), b = 21.947(9), c = 6.085(2) Å, = 91.98(3)°) sind: (dobs[Å]/Iobs/hkl) (11.02/90/0 2 0), (5.874/20/0 1 1), (5.496/100/0 4 0), (5.322/25/0 2 1), (4.079/50/0 4 1), (3.660/20/0 6 0), (3.437/30/1 5 0), (3.243/40/1 4 1), (2.470/30/2 4 0), (2.425/20/1 4 –2), (2.205/20/2 6 0) und (1.897/20/1 8 2). Das Mineral ist monoklin, P21/m, Z = 2, a = 5.543(1) Å, b = 21.995(4) Å, c = 6.079(1) Å, = 92.04(3)°, V = 740.7(2) Å3 Die Kristallstruktur wurde mittels Einkristallröntgenmethoden bestimmt und zu R1 = 0.026, wR2 = 0.056 verfeinert. Die Struktur von Niedermayrit ist durch 2 [Cu4(OH)6O2]2– Schichten von kantenverknüpften Cu-Koordinationsoktaedern parallel (010) gekennzeichnet mit damit verbundenen SO4 Tetraedern und dazwischen befindlichen CdO2(H2O)4 Oktaedem mit einem Wasserstoffbrückensystem. Es bestehen enge Beziehungen mit den Kristallstrukturen von Christelit und Campigliait. Das neue Mineral ist nach Dr. Gerhard Niedermayr, Naturhistorisches Museum Wien, Österreich, benannt.
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Yakovenchuk Victor N. Ivanyuk Gregory Yu. Pakhomovsky Yakov A. Panikorovskii Taras L. Britvin Sergei N. Krivovichev Sergey V. Shilovskikh Vladimir V. Bocharov Vladimir N. 《Mineralogy and Petrology》2018,112(1):111-121
Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,... 相似文献
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20001575 Fang Lianyu(No.3 Hydrogeologyand Engineering Geologieal Team,Hebei Bu-reau of Geologieal Exploration,Hengshui,Hebei);Kang Qingpu The Primary Diseus-sion on the ProsPeets of Geothermal Ex-Ploitation in the Eastern Plain of XingtaiCity,Hebei Provinee(Aeta Geoseientia Sini-ea,ISSN 1006一3021,CN 11一3840/P,21(2),2000,p.155一59,一illus·,4 tables) On rhe basis of summarizing the distribu-t ion eharaeteristies of geologieal strueture,strata,georhermo一geologieal models,geother… 相似文献
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Igor V. Pekov Natalia V. Zubkova Vasiliy O. Yapaskurt Dmitriy I. Belakovskiy Nikita V. Chukanov Anatoly V. Kasatkin Aleksey M. Kuznetsov Dmitry Y. Pushcharovsky 《Mineralogy and Petrology》2013,107(2):201-210
A new mineral kobyashevite, Cu5(SO4)2(OH)6·4H2O (IMA 2011–066), was found at the Kapital’naya mine, Vishnevye Mountains, South Urals, Russia. It is a supergene mineral that occurs in cavities of a calcite-quartz vein with pyrite and chalcopyrite. Kobyashevite forms elongated crystals up to 0.2 mm typically curved or split and combined into thin crusts up to 1?×?2 mm. Kobyashevite is bluish-green to turquoise-coloured. Lustre is vitreous. Mohs hardness is 2½. Cleavage is {010} distinct. D(calc.) is 3.16 g/cm3. Kobyashevite is optically biaxial (?), α 1.602(4), β 1.666(5), γ 1.679(5), 2 V(meas.) 50(10)°. The chemical composition (wt%, electron-microprobe data) is: CuO 57.72, ZnO 0.09, FeO 0.28, SO3 23.52, H2O(calc.) 18.39, total 100.00. The empirical formula, calculated based on 18 O, is: Cu4.96Fe0.03Zn0.01S2.01O8.04(OH)5.96·4H2O. Kobyashevite is triclinic, $ P\overline{\,1 } $ , a 6.0731(6), b 11.0597(13), c 5.5094(6)?Å, α 102.883(9)°, β 92.348(8)°, γ 92.597(9)°, V 359.87(7)?Å3, Z?=?1. Strong reflections of the X-ray powder pattern [d,Å-I(hkl)] are: 10.84–100(010); 5.399–40(020); 5.178–12(110); 3.590–16(030); 2.691–16(20–1, 040, 002), 2.653–12(04–1, 02–2), 2.583–12(2–11, 201, 2–1–1), 2.425–12(03–2, 211, 131). The crystal structure (single-crystal X-ray data, R?=?0.0399) сontains [Cu4(SO4)2(OH)6] corrugated layers linked via isolated [CuO2(H2O)4] octahedra; the structural formula is CuCu4(SO4)2(OH)6·4H2O. Kobyashevite is a devilline-group member. It is named in memory of the Russian mineralogist Yuriy Stepanovich Kobyashev (1935–2009), a specialist on mineralogy of the Urals. 相似文献
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9621 19 Wang Feiyu(Perroleum Universlry,Beijing,102200);卜{e Ping CONTRIBUTIONOF ALGAE AND BACTERIA TO THE HU-MIC COAL FORMATION OF TAIYUANFORMATION IN NORTH CHINA(ES.ISSN 1000一2383,CN42一1233/P,20(6),1 995,p.719一722,2 graphs,2 tables,7 ref,w irh English abstraet)962120 Yin Shax一ehun(Departn、ent of Geo-logieal Survey,Minisrry of Geology andM ineral Resourees)THE EVOLUTION OFPEAT BOGS AND IT‘5 MECHANISM(CGE,ISSN 1001一1986,CN61一1… 相似文献
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971344 Dai Shifeng(Beijing GraduateSehool,CUMT,Beijing);Ren Deyi Fluetua-tion of Sea一Level and Division of Cyeles inYanzhou Coalfield,Shandong Provinee(JCUMT,ISSN 1000一1964,CN 32一1 152/TD,26(l),1997,p.43一47,2graphs,1,able,6 ref) Based on the analyses of eyelieity andtextura!fearure of the eoal measure inYanzhou eoalfield,Shandong Provinee,rhispaPer discusses the eharaeteristies of sea一Iev-el ehange and its eontrolling in the eoal一forming proeess,elueidaresthe asymmetriealfe… 相似文献
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20062354 Guo Li (China University of Min- ing &Technology, Beijing 100083, China); Duan Lindi Relationship Between Microlitho- type and Cleat Distribution in Coal Bed (Coal Geology & Exploration, ISSN1001- 1986, CN61-1155/P, 33(5), 2005, p.9- 12, 2 illus., 3 tables, 5 refs.) Key words: microlithotype of coal, cracks The relationship between microlithotype and the distribution of cleat in coal bed is dis- cussed through a case from Hedong coalfield, combining microstratigraphy and sta… 相似文献
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N. V. Chukanov R. K. Rastsvetaeva S. M. Aksenov I. V. Pekov D. I. Belakovskiy G. Blass G. Möhn 《Geology of Ore Deposits》2013,55(8):663-668
A new mineral, lahnsteinite, has been found in the dump of the Friedrichssegen Mine, Bad Ems district, Rhineland-Palatinate (Rheinland-Pfalz), Germany. Lahnsteinite, occurring as colorless tabular crystals in the cavities of goethite, is associated with pyromorphite, hydrozincite, quartz, and native copper. The Mohs’ hardness is 1.5; the cleavage is perfect parallel to (001). D calc = 2.995 g/cm3, D meas = 2.98(2) g/cm3. The IR spectrum is given. The new mineral is optically biaxial, negative, α = 1.568(2), β = 1.612(2), γ = 1.613(2), 2V meas = 18(3)°, 2V calc = 17°. The chemical composition (wt %, electron microprobe data; H2O was determined by gas chromatography of ignition products) is as follows: 3.87 FeO, 1.68 CuO, 57.85 ZnO, 15.83 SO3, 22.3 H2O, total is 101.53. The empirical formula is (Zn3.3Fe0.27Cu0.11)Σ3.91(S0.98O4)(OH)5 · 3H2.10O. The crystal structure has been studied on a single crystal. Lahnsteinite is triclinic, space group P1, a = 8.3125(6), b = 14.545(1), c = 18.504(2) Å, α = 89.71(1), β = 90.05(1), γ = 90.13(1)°, V = 2237.2(3) Å3, Z = 8. The strong reflections in the X-ray powder diffraction pattern [d, Å (I, %)] are: 9.30 (100), 4.175 (18), 3.476 (19), 3.290 (19), 2.723 (57), 2.624 (36), 2.503 (35), 1.574 (23). The mineral has been named after its type locality near the town of Lahnstein. The type specimen of lahnsteinite is deposited in the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, registration number 4252/1. 相似文献
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We present the results of twenty-year observations of a complete sample of 68 flat-spectrum radio sources with flux densities S 3.9 GHz > 200 mJy carried out at centimeter wavelengths with the RATAN-600 radio telescope. Since 1995, we have observed simultaneously at six frequencies between 0.97 and 21.7 GHz. Of the 56 sources identified with optical objects, 41 are quasars with redshifts between 0.293 and 3.263. Based on our analysis of the spectral shapes, we divide the sources into four classes. Changes of spectral class for individual sources are fairly rare. Based on the light curves and spectra, in most cases, a flare’s evolution is in accordance with a model in which the variations result from the evolution of a shock in the radio jet. The main result of our study is that there is no redshift dependence for the true linear sizes of the radiating regions, the variability indices derived for all 20 years of data or for individual flares, or the peak frequencies of the spectra of the compact radio emission. We suggest that this testifies to an absence of cosmological evolution of the sample quasars, at least to z ≈ 3. 相似文献
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《Geochimica et cosmochimica acta》1999,63(13-14):1969-1980
The solubility of ettringite (Ca6[Al(OH)6]2(SO4)3 · 26H2O) was measured in a series of dissolution and precipitation experiments at 5–75°C and at pH between 10.5 and 13.0 using synthesized material. Equilibrium was established within 4 to 6 days, with samples collected between 10 and 36 days. The log KSP for the reaction Ca6[Al(OH)6]2(SO4)3 · 26H2O ⇌ 6Ca2+ + 2Al(OH)4− + 3SO42− + 4OH− + 26H2O at 25°C calculated for dissolution experiments (−45.0 ± 0.2) is not significantly different from the log KSP calculated for precipitation experiments (−44.8 ± 0.4) at the 95% confidence level. There is no apparent trend in log KSP with pH and the mean log KSP,298 is −44.9 ± 0.3. The solubility product decreased linearly with the inverse of temperature indicating a constant enthalpy of reaction from 5 to 75°C. The enthalpy and entropy of reaction ΔH°r and ΔS°r, were determined from the linear regression to be 204.6 ± 0.6 kJ mol−1 and 170 ± 38 J mol−1 K−1. Using our values for log KSP, ΔH°r, and ΔS°r and published partial molal quantities for the constituent ions, we calculated the free energy of formation ΔG°f,298, the enthalpy of formation ΔH°f,298, and the entropy of formation ΔS°f,298 to be −15211 ± 20, −17550 ± 16 kJ mol−1, and 1867 ± 59 J mol−1 K−1. Assuming ΔCP,r is zero, the heat capacity of ettringite is 590 ± 140 J mol−1 K−1. 相似文献
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Yakovenchuk Victor N. Pakhomovsky Yakov A. Konopleva Nataliya G. Panikorovskii Taras L. Bazai Ayya Mikhailova Julia A. Bocharov Vladimir N. Ivanyuk Gregory Yu. Krivovichev Sergey V. 《Mineralogy and Petrology》2018,112(4):591-601
Mineralogy and Petrology - Batagayite, CaZn2(Zn,Cu)6(PO4)4(PO3OH)3·12H2O, is a new secondary phosphate mineral from the Këster deposit, Arga-Ynnykh-Khai massif, NE Yakutia, Russia. It is... 相似文献
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用绳索取心钻具的岩心钻探用绳索取心钻具进行岩心钻探往往会比用常规岩心钻具所获得的钻进效率更高、岩心采取率更高，钻头的费用也低得多。如果钻孔深度增加，或者地层变化得破碎或出现断层时，这种优点就更为突出。 相似文献
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<正>上期刊登了矿产资源评价篇第二节的第一部分矿产资源储量评价的前3个小节,本期继续刊登矿产资源储量评价的最后1个小节。第二节矿产资源宏观评价1矿产资源储量评价1.4资源储量宏观评价的基本内容在矿产资源宏观评价中,资源储量分析是主要的途径与手段,目前各级决策单位都将资源储量分析所获 相似文献
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石榴石宝石是石榴石(garnet)族矿物的总称,岛状硅酸盐、等轴晶系矿物。根据其化学成分可划分成2个系列。铝质系列镁铝榴石:橙红色、红色铁铝榴石:橙红—红色、紫红—红紫色锰铝榴石:橙色—橙红色钙质系列钙铝榴石: 相似文献
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Yakovenchuk V. N. Pakhomovsky Y. A. Konopleva N. G. Panikorovskii T. L. Bazai A. V. Mikhailova J. A. Bocharov V. N. Krivovichev S. V. 《Doklady Earth Sciences》2022,505(2):549-552
Doklady Earth Sciences - Sergeysmirnovite, MgZn2(PO4)2 · 4H2O, is a new mineral from the oxidation zone of the Kester mineral deposit, Sakha-Yakutia, Russia. This mineral forms... 相似文献