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1.
A paleomagnetic study has been conducted on intrusive doleritic rocks cropping out within Devonian horizontal tabular formations of the Saharan craton (Tin Serririne basin, South of Hoggar shield). The 40K/40Ar dating of the dolerites gave an age of 347.6 ± 8.1 Ma, i.e. Tournaisian. The paleomagnetic data present three different directions. The first has a paleomagnetic pole close to the previous African poles of Permian age. This direction is therefore interpreted as a Permian remagnetization. The second direction, which is defined by both linear regression and remagnetization circles analysis, is considered as the primary magnetization. It yields a new African Tournaisian paleomagnetic pole (λ = 18.8° S,  = 31.2° E, K = 29, A95 = 7.5°) very close to the Ben Zireg Tounaisian pole [Aifa, T., Feinberg, H., Pozzi, J.P., 1990. Devonian/Carboniferous paleopoles for Africa. Consequences for Hercynian geodynamics. Tectonophysics, 179, 288–304]. The third direction has intermediate orientation between those of the first or second directions and that of the Upper Cenozoic field. It is interpreted as related to a composite magnetization. This new Tin Serririne pole improves the APWP of Gondwana, for this key period of the evolution of the Pangea. This APWP confirms the previous paleogeographic reconstruction which shows that the pre-Hercynian ocean between Gondwana and Laurussia is still not close during the beginning of the Carboniferous.  相似文献   

2.
A paleomagnetic study of subsurface core samples from dolomitized carbonates of two producing reservoirs in the Upper Ordovician Trenton Formation, collected from four wells in southwestern Ontario yielded a paleomagnetic direction of D = 152.3°, I = − 12.3° (N = 49, α95 = 8.7). This characteristic remanent magnetization (ChRM) direction was azimuth-corrected by aligning the viscous remanence magnetization (VRM) with the present Earth's magnetic field direction. A drilling-induced magnetization (VRMdi) was present in less than half the specimens sampled in this study. In addition, where the VRM correction could not be made, a paleolatitudinal arc calculated from the inclination-only mean of I = − 9.0° (N = 34, α95 = 3.0°) intersected the apparent polar wander path in the Late Permian–Early Triassic. These paleodirections are similar to the paleomagnetic directions observed in Ordovician Trenton carbonates from the Michigan Basin and New York State, U.S.A., suggesting a related regional late Paleozoic remagnetization.  相似文献   

3.
The 92.5 Ma Fort Knox granodiorite stock, near the western end of the Fairbanks Belt in the Yukon–Tanana terrane (YTT) of central Alaska, hosts a world-class gold mine. The stock has been analysed paleomagnetically using thermal and alternating-field step demagnetization and isothermal remanence methods. This pluton retains a primary thermoremanent magnetization at 18 sites (232 specimens) that resides mainly in single-to pseudosingle-domain magnetite with a direction of D = 228.8°, I = 84.3° (N = 18, k = 130, α95 = 3.0°), giving a paleopole at 56.5°N, 197.1°E (dp = 5.9°, dm = 5.8°). The pluton's host rock, the Fairbanks schist, does not retain a stable coherent remanence. Relative to the North American craton, the stock's paleoinclination indicates that the Fairbanks Belt has undergone nonsignificant poleward (northwesterly) translation of 25 ± 750 km only. Analysed in concert with the few available paleoinclinations available for the YTT in Yukon, the paleoinclination suggests further that the YTT has undergone only  250 to 450 km of dextral displacement along the Tintina fault in the past  100 Ma and, therefore, is parautocthonous since the mid-Cretaceous. The stock's paleodeclination records 121 ± 35° of counterclockwise rotation relative to the North American craton. Consideration of models published for Alaska's tectonic evolution suggests that this paleodeclination discordance is caused by rotations associated with the opening of the Canada Basin, with dextral displacement on the Tintina fault, and with development of the western Alaskan orocline. Thus the paleomagnetic results for the Fort Knox stock support a thin-skin tectonic model for the accretion of the YTT and Intermontane Belt terranes to the northern Cordillera.  相似文献   

4.
J.D.A. Piper   《Tectonophysics》2007,432(1-4):133-157
The Southern Uplands terrane is an Ordovician–Silurian back-arc/foreland basin emplaced at the northern margin of the Iapetus Ocean and intruded by granite complexes including Loch Doon (408.3 ± 1.5 Ma) during Early Devonian times. Protracted cooling of this 130 km3 intrusion recorded magnetic remanence comprising a predominant (‘A’) magnetisation linked to initial cooling with dual polarity and mean direction D / I = 237 / 64° (α95 = 4°, palaeopole at 316°E, 21°N). Subsidiary magnetisations include Mesozoic remanence correlating with extensional tectonism in the adjoining Irish Sea Basin (‘B’, D / I = 234/− 59°) and minority populations (‘C’, D / I = 106/− 2° and ‘D’, D / I = 199/1°) recording emplacement of younger ( 395 Ma) granites in adjoining terranes and the Variscan orogenic event. The ‘A’ directions have an arcuate distribution identifying anticlockwise rotation during cooling. A comparable rotation is identified in the Orthotectonic Caledonides to the north and the Paratectonic Caledonides to the south following closure of Iapetus. Continental motion from midsoutherly latitudes ( 40°S) at 408 Ma to equatorial palaeolatitudes by  395 Ma is identified and implies minimum rates of continental movement between 430 and 390 Ma of 30–70 cm/year, more than double maximum rates induced by plate forces and interpreted as a signature of true polar wander. Silurian–Devonian palaeomagnetic data from the British–Scandinavian Caledonides define a 430–385 Ma closed loop comparable to the distributed contemporaneous palaeomagnetic poles from Gondwana. They reconcile pre-430 Ma and post-380 Ma APW from this supercontinent and show that Laurentia–Baltica–Avalonia lay to the west of South America with a relict Rheic Ocean opening to the north which closed to produce Variscan orogeny by a combination of pivotal closure and right lateral transpression.  相似文献   

5.
176 vertical-component, short period observations from aftershocks of the Mw 7.7, 26 January, 2001 Kachchh earthquake are used to estimate seismic wave attenuation in western India using uniform and two layer models. The magnitudes (Mw) of the earthquakes are less than 4.5, with depths less than 46 km and hypocentral distances up to 110 km. The studied frequencies are between 1 and 30 Hz. Two seismic wave attenuation factors, intrinsic absorption (Qi− 1) and scattering attenuation (Qs− 1) are estimated using the Multiple Lapse Time Window method which compares time integrated seismic wave energies with synthetic coda wave envelopes for a multiple isotropic scattering model. We first assume spatial uniformity of Qi− 1, Qs− 1 and S wave velocity (β). A second approach extends the multiple scattering hypothesis to media consisting of several layers characterized by vertically varying scattering coefficient (g), intrinsic absorption strength (h), density of the media (ρ) and shear wave velocity structure. The predicted coda envelopes are computed using Monte Carlo simulation. Results show that, under the assumption of spatial uniformity, scattering attenuation is greater than intrinsic absorption only for the lowest frequency band (1 to 2 Hz), whereas intrinsic absorption is predominant in the attenuation process at higher frequencies (2 to 30 Hz). The values of Q obtained range from Qt = 118, Qi = 246 and Qs = 227 at 1.5 Hz to Qt ≈ 4000, Qi ≈ 4600 and Qs ≈ 33,300 at 28 Hz center frequencies, being Qt− 1 a measure of total attenuation. Results also show that Qi− 1, Qs− 1 and Qt− 1 decrease proportional to f−ν. Two rates of decay are clearly observed for the low (1 to 6 Hz) and high (6 to 30 Hz) frequency ranges. Values of ν are estimated as 2.07 ± 0.05 and 0.44 ± 0.09 for total attenuation, 1.52 ± 0.21 and 0.48 ± 0.09 for intrinsic absorption and 3.63 ± 0.07 and 0.06 ± 0.08 for scattering attenuation for the low and high frequency ranges, respectively. Despite the lower resolution in deriving the attenuation parameters for a two layered crust, we find that scattering attenuation is comparable to or smaller than the intrinsic absorption in the crust whereas intrinsic absorption dominates in the mantle. Also, for a crustal layer of thickness 42 km, intrinsic absorption and scattering estimates in the crust are lower and greater than those of the mantle, respectively.  相似文献   

6.
Structural and thermochronological studies of the Kampa Dome provide constraints on timing and mechanisms of gneiss dome formation in southern Tibet. The core of Kampa Dome contains the Kampa Granite, a Cambrian orthogneiss that was deformed under high temperature (sub-solidus) conditions during Himalayan orogenesis. The Kampa Granite is intruded by syn-tectonic leucogranite dikes and sills of probable Oligocene to Miocene age. Overlying Paleozoic to Mesozoic metasedimentary rocks decrease in peak metamorphic grade from kyanite + staurolite grade at the base of the sequence to unmetamorphosed at the top. The Kampa Shear Zone traverses the Kampa Granite — metasediment contact and contains evidence for high-temperature to low-temperature ductile deformation and brittle faulting. The shear zone is interpreted to represent an exhumed portion of the South Tibetan Detachment System. Biotite and muscovite 40Ar/39Ar thermochronology from the metasedimentary sequence yields disturbed spectra with 14.22 ± 0.18 to 15.54 ± 0.39 Ma cooling ages and concordant spectra with 14.64 ± 0.15 to 14.68 ± 0.07 Ma cooling ages. Petrographic investigations suggest disturbed samples are associated with excess argon, intracrystalline deformation, mineral and fluid inclusions and/or chloritization that led to variations in argon systematics. We conclude that the entire metasedimentary sequence cooled rapidly through mica closure temperatures at  14.6 Ma. The Kampa Granite yields the youngest biotite 40Ar/39Ar ages of  13.7 Ma immediately below the granite–metasediment contact. We suggest that this age variation reflects either varying mica closure temperatures, re-heating of the Kampa Granite biotites above closure temperatures between 14.6 Ma and 13.7 Ma, or juxtaposition of rocks with different thermal histories. Our data do not corroborate the “inverse” mica cooling gradient observed in adjacent North Himalayan gneiss domes. Instead, we infer that mica cooling occurred in response to exhumation and conduction related to top-to-north normal faulting in the overlying sequence, top-to-south thrusting at depth, and coeval surface denudation.  相似文献   

7.
Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S1) in these rocks. The main foliation in the schists is a crenulation cleavage (S2), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe3+ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S1 chlorites down to 0.1 in syn-S2 chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).  相似文献   

8.
Twenty-eight samples of peat, peaty lignites and lignites (of both matrix and xylite-rich lithotypes) and subbituminous coals have been physically activated by pyrolysis. The results show that the surface area of the activated coal samples increases substantially and the higher the carbon content of the samples the higher the surface area.The adsorption capacity of the activated coals for NO, SO2, C3H6 and a mixture of light hydrocarbons (CH4, C2H6, C3H8 and C4H10) at various temperatures was measured on selected samples. The result shows a positive correlation between the surface area and the gas adsorption. In contrast, the gas adsorption is inversely correlated with the temperature. The maximum recorded adsorption values are: NO = 8.22 × 10− 5 mol/g at 35 °C; SO2 = 38.65 × 10− 5 mol/g at 60 °C; C3H6 = 38.9 × 10− 5 mol/g at 35 °C; and light hydrocarbons = 19.24 × 10− 5 mol/g at 35 °C. Adsorption of C3H6 cannot be correlated with either NO or SO2. However, there is a significant positive correlation between NO and SO2 adsorptions. The long chain hydrocarbons are preferentially adsorbed on activated lignites as compared to the short chain hydrocarbons.The results also suggest a positive correlation between surface area and the content of telohuminite maceral sub-group above the level of 45%.  相似文献   

9.
This paper presents new paleomagnetic results on Cenozoic rocks from northern central Asia. Eighteen sites were sampled in Pliocene to Miocene clays and sandy clays of the Zaisan basin (southeastern Kazakhstan) and 12 sites in the upper Oligocene to Pleistocene clays and sandstones of the Chuya depression (Siberian Altai).Thermal demagnetization of isothermal remanent magnetization (IRM) showed that hematite and magnetite are the main ferromagnetic minerals in the deposits of the Zaisan basin. Stepwise thermal demagnetization up to 640–660 °C isolated a characteristic (ChRM) component of either normal or reverse polarity at nine sites. At two other sites, the great circles convergence method yielded a definite direction. Measurements of the anisotropy of magnetic susceptibility showed that the hematite-bearing sediments preserved their depositional fabric. These results suggest a primary origin of the ChRM and were substantiated by positive fold and reversal tests. The mean paleomagnetic direction for the Zaisan basin (D=9°, I=59°, k=19, α95=11°) is close to the expected direction derived from the APW path of Eurasia [J. Geophys. Res. 96 (1991) 4029] and shows that the basin did not rotated relative to stable Asia during the Tertiary.In the upper Pliocene–Pleistocene sandstones of the Chuya depression, a very stable ChRM carried by hematite was found. Its mean direction (D=9°, I=46°, k=25, α95=7°) is characterized by declination close to the one excepted for early Quaternary, whereas inclination is lower. In the middle Miocene to lower Pliocene clays and sandstones, a stable ChRM of both normal and reverse polarities carried by magnetite was isolated. Its mean direction (D=332°, I=63°, k=31, α95=4°) is deviated with respect to the reference direction and implies a Neogene, 39±8° counterclockwise rotation of the Chuya depression relative to stable Asia. These results and those from the literature suggest that the different amount of rotation found in the two basins is related to a sharp variation in their tectonic style, predominantly compressive in the Zaisan basin and transpressive in the Siberian Altai. At a larger scale, the pattern of vertical axis rotations deduced from paleomagnetic data in northern central Asia is consistent with the hypothesis of a large left-lateral shear zone running from the Pamirs to the Baikal. Heterogeneous rotations, however, indicate changes in style of faulting along the shear zone and local effect for the domains with the largest rotations.  相似文献   

10.
A novel one-step hydrothermal synthesis of 11 Å tobermorite, a cation exchanger, from a unique combination of waste materials is reported. 11 Å tobermorite was prepared from stoicheiometric quantities of cement bypass dust and waste container glass at 100 °C in water. The product also comprised 10 wt.% calcite and trace quartz as residual parent phases from the cement bypass dust. In a batch sorption study at 20 °C the uptakes of Cd2+ and Pb2+ by the waste-derived tobermorite product were found to be 171 mg g− 1 and 467 mg g− 1, respectively, and in both cases the removal process could be described using a simple pseudo-second-order rate model (k2 = 2.30 × 10− 5 g mg− 1 min− 1 and 5.09 × 10− 5 g mg− 1 min− 1, respectively). The sorption characteristics of the 11 Å tobermorite are compared with those of other waste-derived sorbents and potential applications are discussed.  相似文献   

11.
C.T. Klootwijk   《Tectonophysics》1974,21(3):181-195
From alternating-field and thermal demagnetization studies on two dolerite “Traps” in the Gwalior Series (Central India), dated at 1830 ±200 m.y., three different palaeomagnetic directions could be distinguished. The characteristic magnetization component, which is considered as the primary magnetization, has a mean direction: D=78°, I=+34.5°, α95=5°, k=369, N=4 (Pole): 155.5°E19°N, dp=3°, dm=5.5°.A comparison of the presented data with other Precambrian and Phanerozoic data from the Indian subcontinent might suggest that the Indian subcontinent underwent a continuous anticlockwise rotational movement during the last 1800 m.y.  相似文献   

12.
We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. 40Ar/39Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K2O + Na2O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (87Sr/86Sr = 0.70454–0.71264, 143Nd/144Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (87Sr/86Sr = 0.70466–0.70892, 143Nd/144Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial 87Sr/86Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (3He/4He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.  相似文献   

13.
The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.  相似文献   

14.
The motion of Adria, the largest lithospheric fragment in the Central Mediterranean region, has played an important role in the tectonic development of the surrounding mountain chains and even of distant areas, like the Eastern Alps or the Pannonian basin. The available paleomagnetic data were insufficient to constrain this motion, except in a general way. In this paper, new paleomagnetic results are presented from one of the stable parts of Adria which emerge from the Adriatic Sea. The results were obtained on weakly magnetic platform carbonates of the mud-supported type, collected from 21 geographically distributed localities.The results, combined with mean paleomagnetic directions from selected localities from a pioneer study in Istria that were chosen using statistical criteria, were divided into three age groups (Tithonian–Aptian, Albian–Cenomanian, Turonian–Coniacian). The paleomagnetic poles calculated for each of them (Tithonian–Aptian): λ(N) = 47°, (E) = 275°, k = 67, α95 = 9.4°, N = 5; Albian-Cenomanian: λ(N) = 58°, (E) = 253°, k = 145, α95 = 4.3°, N = 9; Turonian–Coniacian: λ(N) = 63°, (E) = 261°, k = 50, α95 = 7.3°, N = 9) reveal a moderate shift during the Cretataceous, which is comparable with that calculated from the African reference poles. However, the Istrian apparent polar wander path is slightly displaced from the African curve, as a consequence of about 10° counterclockwise rotation of Istria, with respect to Africa. This rotation angle is more that 10° smaller than the difference measured for the Mid-Late Eocene between the paleomagnetic direction of platform carbonates from Istria and the African reference direction. This difference may be the consequence of a small clockwise rotation of Istria, with respect to Africa, most probably at the end of Cretaceous.  相似文献   

15.
The integration of new and published geochronologic data with structural, magmatic/anatectic and pressure–temperature (P–T) process information allow the recognition of high-grade polymetamorphic granulites and associated high-grade shear zones in the Central Zone (CZ) of the Limpopo high-grade terrain in South Africa. Together, these two important features reflect a major high-grade D3/M3 event at ~ 2.02 Ga that overprinted the > 2.63 Ga high-grade Neoarchaean D2/M2 event, characterized by SW-plunging sheath folds. These major D2/M2 folds developed before ~ 2.63 Ga based on U–Pb zircon age data for precursors to leucocratic anatectic gneisses that cut the high-grade gneissic fabric. The D3/M3 shear event is accurately dated by U–Pb monazite (2017.1 ± 2.8 Ma) and PbSL garnet (2023 ± 11 Ma) age data obtained from syntectonic anatectic material, and from sheared metapelitic gneisses that were completely reworked during the high-grade shear event. The shear event was preceded by isobaric heating (P = ~ 6 kbar and T = ~ 670–780 °C), which resulted in the widespread formation of polymetamorphic granulites. Many efforts to date high-grade gneisses from the CZ using PbSL garnet dating resulted in a large spread of ages (~ 2.0–2.6 Ga) that reflect the polymetamorphic nature of these complexly deformed high-grade rocks.  相似文献   

16.
Cantilever torque magnetometry is utilized widely in physics and material science for the determination of magnetic properties of thin films and semiconductors. Here, we report on its first application in rock magnetism, namely the determination of K1 and K2 of single crystal octahedra of natural magnetite. The design of cantilever magnetometers allows optimization for the specific research question at hand. For the present study, a cantilever magnetometer was used that enables measurement of samples with a volume up to 64 mm3. It can be inserted into an electromagnet with a maximum field of 2 T. The cantilever spring is suitable for torque values ranging from 7.5 × 10− 7 N·m to 5 × 10− 6 N·m. The torque is detected capacitively; the measured capacitance is converted into torque by using a calibrated feedback coil. The magnetometer allows in-situ rotation of the sample in both directions and is, therefore, also suitable to analyze rotational hysteresis effects.The evaluation of the magnetite anisotropy constants involved Fourier analysis of the torque signal on the magnetite crystals' (001) and (110) planes. The absolute anisotropy constant has been computed using the extrapolation-to-infinite-field method. The value of K1 at room temperature is determined at − 1.28 × 104 [J m− 3] (± 0.13, i.e. 10%) and that of K2 at − 2.8 × 103 [J m− 3] (± 0.1, i.e. 2%). These values concur with earlier determinations that could not provide an instrumental error, in contrast with this work.The cantilever magnetometer performs four times faster than other torque magnetometers used for rock magnetic studies. This makes the instrument also suitable for magnetic fabric analysis.  相似文献   

17.
Holocene variations in annual precipitation (Pann) were reconstructed from pollen data from southern Argentinian Patagonia using a transfer function developed based on a weighted-averaging partial least squares (WA-PLS) regression. The pollen–climate calibration model consisted of 112 surface soil samples and 59 pollen types from the main vegetation units, and modern precipitation values obtained from a global climate database. The performance (r2 = 0.517; RMSEP = 126 mm) of the model was comparable or slightly lower than in other comparable pollen–climate models. Fossil pollen data were obtained from a sediment core from Cerro Frias site (50°24'S, 72°42'W) located at the forest-steppe ecotone. Reconstructed Pann values of about 200 mm suggest dry conditions during the Pleistocene–Holocene transition (12,500–10,500 cal yr BP). Pann values were about 300–350 mm from 10,500 to 8000 cal yr BP and increased to 400–500 mm between 8000 and 1000 cal yr BP. An abrupt decrease in Pann at about 1000 cal yr BP was associated with a Nothofagus decline. The reconstructed Pann suggests a weakening and southward shift of the westerlies during the early Holocene and intensification, with no major latitudinal shifts, during the mid-Holocene at high latitudes in southern Patagonia.  相似文献   

18.
The South Indian Craton is composed of low-grade and high-grade metamorphic rocks across different tectonic blocks between the Moyar–Bhavani and Palghat–Cauvery shear zones and an elongated belt of eastern margin of the peninsular shield. The Madras Block north of the Moyar–Bhavani shear zone, which evolved throughout the Precambrian period, mainly consists of high-grade metamorphic rocks. In order to constrain the evolution of the charnockitic region of the Pallavaram area in the Madras Block we have undertaken palaeomagnetic investigation at 12 sites. ChRM directions in 61 oriented block samples were investigated by Alternating Field (AF) and Thermal demagnetization. Titanomagnetite in Cation Deficient (CD) and Multi Domain (MD) states is the remanence carrier. The samples exhibit a ChRM with reverse magnetization of Dm = 148.1, Im = + 48.6 (K = 22.2, α95 = 9.0) and a palaeomagnetic pole at 37.5 °N, 295.6 °E (dp/dm = 7.8°/11.8°). This pole plots at a late Archaean location on the Indian Apparent Polar Wander Path (APWP) suggesting an age of magnetization in the Pallavaram charnockites as 2600 Ma. The nearby St. Thomas Mount charnockites indicate a period of emplacement at 1650 Ma (Mesoproterozoic). Thus the results of Madras Block granulites also reveal crustal evolution similar to those in the Eastern Ghats Belt with identical palaeopoles from both the areas.  相似文献   

19.
The Changkeng Au and Fuwang Ag deposits represent an economically significant and distinct member of the Au–Ag deposit association in China. The two deposits are immediately adjacent, but the Au and Ag orebodies separated from each other. Ores in the Au deposit, located at the upper stratigraphic section and in the southern parts of the orefield, contain low Ag contents (< 11 ppm); the Ag orebodies, in the lower stratigraphic section, are Au-poor (< 0.2 ppm). Changkeng is hosted in brecciated cherts and jasperoidal quartz and is characterized by disseminated ore minerals. Fuwang, hosted in the Lower Carboniferous Zimenqiao group bioclastic limestone, has vein and veinlet mineralization associated with alteration comprised of quartz, carbonate, sericite, and sulfides. Homogenization temperatures of fluid inclusions from quartz veinlets in the Changkeng and Fuwang deposits are in the range of 210 ± 80 °C and 230 ± 50 °C, respectively. Salinities of fluid inclusions from the two deposits range from 1.6 to 7.3 wt.% and 1.6 to 2.6 wt.% equiv. NaCl, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of the fluid inclusions from the Changkeng deposit range from − 80‰ to − 30‰, − 7.8‰ to − 3.0‰, − 16.6‰ to − 17.0‰ and 0.0100 to 0.0054 Ra, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of fluid inclusions from the Fuwang deposit range from − 59‰ to − 45‰, − 0.9‰ to 4.1‰, − 6.7‰ to − 0.6‰ and 0.5930 to 0.8357 Ra, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of the fluid inclusions suggest the ore fluids of the Changkeng Au-ore come from the meteoric water and the ore fluids of the Fuwang Ag-ore are derived from mixing of magmatic water and meteoric water. The two deposits also show different Pb-isotopic signatures. The Changkeng deposit has Pb isotope ratios (206Pb/204Pb: 18.580 to 19.251, 207Pb/204Pb: 15.672 to 15.801, 208Pb/204Pb: 38.700 to 39.104) similar to those (206Pb/204Pb: 18.578 to 19.433, 207Pb/204Pb: 15.640 to 15.775, 208Pb/204Pb: 38.925 to 39.920) of its host rocks and different from those (206Pb/204Pb: 18.820 to 18.891, 207Pb/204Pb: 15.848 to 15.914, 208Pb/204Pb: 39.579 to 39.786) of the Fuwang deposit. The different signatures indicate different sources of ore-forming material. Rb–Sr isochron age (68 ± 6 Ma) and 40Ar–39Ar age (64.3 ± 0.1 Ma) of the ore-related quartz veins from the Ag deposit indicate that the Fuwang deposit formed during the Cenozoic Himalayan tectonomagmatic event. Crosscutting relationships suggests that Au-ore predates Ag-ore. The adjacent Changkeng and Fuwang deposits could, however, represent a single evolved hydrothermal system. The ore fluids initially deposited Au in the brecciated siliceous rocks, and then mixing with the magmatic water resulted in Ag deposition within fracture zones in the limestone. The deposits are alternatively the product of the superposition of two different geological events. Age evidence for the Fuwang deposit, together with the Xiqiaoshan Tertiary volcanic-hosted Ag deposit in the same area, indicates that the Pacific Coastal Volcanic Belt in the South China Fold Belt has greater potential for Himalayan precious metal mineralization than previous realized.  相似文献   

20.
Porphyry-type Cu (Mo, Au) deposits have been discovered along the Gangdese magmatic arc in the southern Tibetan Plateau. Extensive field investigations and systematic studies of geochemistry, S–Pb isotopic tracing, together with Re–Os and 40Ar/39Ar isotopic dating indicate that the mineralisation of the copper belt is genetically related to emplacement of late orogenic granitic porphyries during the post-collisional crustal relaxation period of the Late Himalayan epoch. These porphyries are petrochemically K-enriched and belong to shoshonitic to high-K calc-alkaline series. They display enrichment of large ion lithophile elements (LILE) Rb, K, U, Th, Sr, Pb and depletion of high field strength elements (HFSE) Nb, Ta, Ti and the heavy rare earth elements (HREE) and Y without Eu anomalies. These characteristics demonstrate that subduction played a dominant role in their petrogenesis and residual garnet was left in the magma sources. Pb isotope data show a linear correlation in the plumbotectonic framework diagram ranging from orogenic Pb in the eastern segment of the copper belt to mantle Pb in the western segment. These constitute a mixing line of the Indian Oceanic MORB with Indian Oceanic sediments and suggest that the porphyry magmas were dominantly derived from partial melting of subducted oceanic crusts mixed with a minor quantity of sediments and mantle wedge components.The Gangdese porphyry copper polymetallic belt has alteration characteristics and zonation typical of porphyry-type copper deposits which include potassic alteration (K-feldspathisation and biotitisation), silicification, sericitisation, and propylitisation. Mineralisation mainly occurs in strongly altered granitic cataclasite at the exo-contact with veinlet-disseminated textures. The porphyries themselves are weakly mineralised with disseminated pyrite and chalcopyrite. The copper deposits contain simple ore mineral associations consisting of chalcopyrite, pyrite, bornite, molybdenite, sphalerite and oxidised minerals of malachite, covellite and molybdite. During supergene oxidation, primary ores underwent secondary enrichment to form economic orebodies with Cu grade ranging from 1% to 5%.Ore sulphides of the copper belt display S and Pb isotopic compositions identical to the ore-bearing porphyries. Their δ34S values vary between − 3.8‰ and + 2.4‰ and are typical of mantle sulphur. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios vary in the ranges: 18.106 to 18.752, 15.501 to 15.638, and 37.394 to 39.058, respectively, and yielded radiogenetic lead-enriched signatures. Twelve molybdenite samples from the copper belt yielded isochron ages of 14.76 ± 0.22 Ma and 13.99 ± 0.16 Ma for the Nanmu and Chongjiang deposits and model ages of 13.5 to 13.6 Ma for the Lakang'e deposit. Meanwhile, 40Ar/39Ar isotopic dating of two biotite phenocrysts from the Chongjiang and Lakang'e deposits give plateau ages of 13.5 ± 1.0 Ma and 13.42 ±0.10 Ma, respectively. During the geodynamic evolution of the Gangdese collision-orogenic belt, intrusion of the ore-bearing porphyries took place just before the rapid uplift and E–W extension of the southern Plateau. And the ore-forming process may have occurred simultaneously with the uplift and extension (14 ± 0.1 Ma).  相似文献   

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