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1.
《水文科学杂志》2013,58(3)
Abstract Two multi-tracer tests were performed in fissured rocks accessible in underground laboratories to examine a new fluorescent dye: pyrene-1,3,6,8-tetra sulphonic acid (PTS). The first test was carried out at the Lindau Rock Laboratory (LRL), Germany, in a highly permeable ore dike, and the second, at the Grimsel Test Site (GTS), Switzerland, in a heterogeneous granite fault zone (AU 126). At the LRL new tracer was injected together with uranine in a convergent flow field (monopole test), and slightly different tracer breakthrough curves were observed according to different diffusion coefficients of both tracers. The matrix porosity calculated with the aid of the one-dimensional (1-D) single-fissure dispersion model (SFDM) agrees well with that found in earlier tracer tests and with measurements performed on core samples. At the GTS, the PTS tracer was applied together with pyranine in two-well injection–withdrawal (dipole) tests. Both tracers yielded identical tracer concentration curves, which confirm their conservative behaviour. Mathematical simulations performed with the aid of a 3-D numerical model (FRAC3DVS) yielded equally good fits for different sets of parameters, independent of whether matrix porosity was included or neglected. That lack of unique solution and the difficulty in observing the influence of matrix diffusion result from a wide distribution of the transit times of particular streamlines, which is characteristic for injection–withdrawal tests. However, both tracer tests clearly indicated that the new tracer (PTS) behaves conservatively at high pH values and can be successfully used for groundwater labelling. 相似文献
2.
《Journal of Hydrology》2006,316(1-4):84-97
Dyes are important hydrological tracers. Many different dyes have been proposed as optimal tracers, but none of these dyes can be considered an ideal water tracer. Some dyes are toxic and most sorb to subsurface materials. The objective of this study was to find the molecular structure of an optimal water tracer. We used QSAR to screen a large number of hypothetical molecules, belonging to the class of triarylmethane dyes, in regard to their sorption characteristics to a sandy soil. The QSAR model was based on experimental sorption data obtained from four triarylmethane dyes: C.I. Food Blue 2 (C.I. 42090; Brilliant Blue FCF), C.I. Food Green 3 (C.I. 42053; FD&C Green No. 3), C.I. Acid Blue 7 (C.I. 42080; ORCOacid Blue A 150%), and C.I. Acid Green 9 (C.I. 42100; ORCOacid Fast Green B). Sorption characteristics of the dyes to the sandy soil were expressed with the Langmuir isotherm. Our premise was that dye sorption can be reduced by attachment of sulfonic acid (SO3) groups to the triarylmethane template. About 70 hypothetical dyes were created and QSAR were used to estimate sorption characteristics. The results indicated that both the position and the number of SO3 groups affected dye sorption. Sorption decreased with increasing number of SO3 groups attached to the molecule. Increasing the number of sulfonic acid groups also decreases the toxicity of the compounds. An optimal triarylmethane water tracer contains 4 to 6 SO3 groups. 相似文献
3.
Fluorescent dyes are commonly used as hydrologic tracers in a variety of surface and subsurface environments, including karst aquifers and caves, but the fragile nature of karstic groundwater ecosystems suggests a cautious approach to selecting dyes. This study tested the effects of four fluorescent dye tracers (uranine, eosin, pyranine, sulforhodamine B) on microorganisms from Fort Stanton Cave, New Mexico, United States. Toxicity of the dyes was tested on bacteria isolated from the cave and on a sediment sample collected adjacent to Snowy River in Fort Stanton Cave. The isolates showed minimal inhibition by the four dyes in an agar diffusions assay. Minimum inhibitory concentrations calculated from liquid culture assays of one isolate were 35 g/L for uranine, 3.5 g/L for eosin, 0.1 g/L for pyranine, and 10 mg/L for sulforhodamine B. A 14C-glucose radiotracer experiment showed zero inhibition of overall microbial activity in a sediment sample at all dye concentrations, except at 350 g/L eosin. Thus, there are no cave-specific findings to indicate that Fort Stanton's microbes are especially sensitive to these commonly used dyes. Moreover, a literature survey of mutagenicity tests on these dyes indicates they are safe for environmental use. These results corroborate previous dye toxicity tests and suggest that these four dyes are suitable for use at Fort Stanton Cave in the concentration ranges commonly used for groundwater tracing. While broader testing of dyes with microbes from other caves is advised, the results suggest the dyes may be safe for all karst aquifers. 相似文献
4.
Rhodamine B and Rhodamine WT are fluorescent dyes commonly used as tracers in hydrological investigations. Since introducing
intensely red substances into rivers raises understandable doubts of ecological nature, the authors aimed at examining the
influence of these dyes on small water fauna using bioindication methods. Quantitative results, calculated with the use of
Bliss-Weber probit statistical method, were achieved by means of standardized ecotoxicological tests containing ready-to-hatch
resting forms of fairy shrimp (Thamnocephalus platyurus). Qualitative studies included observation of water flea crustacean (Daphnia magna) and horned planorbis snail (Planorbis corneus), both typically present in rivers and representative for temperate climate, as well as guppy fish (Poecilla reticulata), paramecium protozoan (Paramaecium caudatum) and the above-mentioned fairy shrimp. The investigation revealed that both dyes in concentrations used for hydrological
purposes are low enough to exert almost no toxic impact on water fauna considered. 相似文献
5.
In the present study, Oreganum onites L. stalks in natural and chemically modified with HNO3 and H3PO4 used as adsorbent for removal of both acidic and basic dyes from waters. The adsorption was studied as a function of pH and contact time by batch method. All tested biosorbents were characterized by FT‐IR, scanning electron microscopy, and measuring the pH dependence of the zeta potential. The adsorption isotherms were fitted to Langmuir isotherm. The maximum adsorption capacity of dyes was 280.73 mg g?1 for Basic Red 18, 147.06 mg g?1 for methylene blue and 112.36 for Acid Red 111, which is comparable to that of other lignocellulosic materials. The modification process was considerably increased the biosorption capacity of lignocellulosic material, resulting in a 56–63% increase in the biosorption capacity of basic dyes and a 125% increase in the biosorption capacity of acidic dye. The present study illustrated that the most effective factors in the adsorption of basic dye were surface charge and acidic groups on lignocellulosic biosorbents, while non‐electrostatic forces as well as electrostatic forces were also effective in the adsorption of acidic dye. In conclusion, Oreganum stalks can be considered as a very prospective adsorbent for the removal of tested basic and acidic dyes. 相似文献
6.
Textile wastewater contains huge quantities of nitrogen (N)‐containing azo‐dyes. Irrigation of crops with such wastewater adds toxic dyes into our healthy soils. One of the ways to prevent their entry to soils could be these waters after the dyes' biodegradation. Therefore, the present study was conducted to evaluate the impact of textile dyes on wheat growth, dye degradation efficiency of bacteria‐fungi consortium, and alleviation of dye toxicity in wheat by treatment with microbial consortium. Among dyes, Red‐S3B (3.19% N) was found to be the most toxic to germination and growth of seven‐day‐old wheat seedlings. Shewanella sp. NIAB‐BM15 and Aspergillus terreus NIAB‐FM10 were found to be efficient degraders of Red‐S3B. Their consortium completely decolorized 500 mg L?1 Red‐S3B within 4 h. Irrigation with Red‐S3B‐contaminated water after treatment with developed consortium increased root length, shoot length, root biomass, and shoot biomass of 30‐day‐old wheat seedlings by 47, 18, 6, and 25%, respectively, than untreated water. Moreover, irrigation after microbial treatment of dye‐contaminated water resulted in 20 and 51% increase in shoot N content and N uptake, respectively, than untreated water. Thus, co‐inoculation of bacteria and fungi could be a useful bioremediation strategy for the treatment of azo‐dye‐polluted water. 相似文献
7.
By‐products of various industrial fermentations can be good adsorbents for removing hazardous dyes from wastewater. However, after biosorption, regeneration of biomass is essential to minimize the solid waste generation or else the dye laden biomass should be suitably disposed off. In the present work, experiments were conducted on the Acid Navy Blue and Methylene Blue dyes which were biosorbed to the fungal biomass (strain closely related to Aspergillus lentulus) produced on corncob as the substrate through solid state fermentation. In order to dispose the dye laden biomass, it was vermicomposted along with cow dung (CD) employing Eisenia fetida. Results indicated that the dye laden biomass was not lethal toward the earthworms as no mortality was observed. However, as compared with control experiments (where dye laden biomass was absent), the reproductive potential of the earthworms was affected. Nevertheless, further investigations on optimization of biomass and CD ratios can facilitate vermicomposting as a potential route for disposing dye laden biomass. 相似文献
8.
Shekhar B. Jadhav Snehal M. Yedurkar Swapnil S. Phugare Jyoti P. Jadhav 《洁净——土壤、空气、水》2012,40(5):551-558
Acid violet 19 (AV) belongs to the triphenylmethane (TPM) class of dyes which are potentially mutagenic or carcinogenic. However, very little studies on biodegradation of AV were reported as compared to other TPM dyes such as malachite green and crystal violet. In this study, AV was decolorized up to 98% within 30 min by Pseudomonas aeruginosa BCH. The decolorization depends on the initial dye concentration, pH, and temperature. However, the dye was decolorized under wide pH and temperature ranges with an optimum of pH 7 and 30°C. Up to 250 mg L?1 of dye was found to be tolerated and decolorized by this strain. It showed decolorization ability for seven repeated dye addition cycles. The effect of additional carbon sources on dye decolorization was studied in which mannitol containing medium showed decolorization in 15 min. Induction in the enzyme activities of laccase, NADH‐DCIP reductase, and veratryl alcohol oxidase (VAO) indicates their involvement in AV degradation. Various analytical studies viz. UV–VIS, HPTLC, HPLC, and FTIR confirmed the biodegradation of AV by the bacterium. Based on GC‐MS analysis, a possible degradation pathway for AV was proposed. The phytotoxicity studies using Phaseolus mungo and Sorghum vulgare revealed the less toxic nature of metabolites formed after AV degradation. 相似文献
9.
M. C. Tom Kuo 《Ground water》2022,60(4):510-517
Few published data are available for two-phase flow in fractures from field studies. All measurements of relative permeability reported in the literature were done in laboratory-scale. The in situ water saturations are normally not known for multiphase flow in natural fractures; therefore, the direct measurements of relative permeability are difficult in field-scale. With the help of a case study before and after the 2008 Mw 5.4 Antung earthquake, groundwater radon was used as a tracer to determine the gas and water saturations in a small naturally fractured aquifer. Well tests were also conducted to estimate aquifer transmissivity before and after the 2008 Antung earthquake. Anomalous declines in both groundwater radon concentration and transmissivity were observed precursory to the 2008 Antung earthquake. Both declines are two precursory phenomena having a common effect of gas bubbles. Using the data from well tests and radon tracer, one data point of water relative permeability can be obtained for in situ fractures. This data point reveals strong phase interference between water and gas bubbles for multiphase flow in natural fractures. Both the data of well tests and radon tracer are essential to gain an improved understanding of mass transfer behavior of groundwater-dissolved gases between water and gas phases. 相似文献
10.
Two experiments were conducted in the Carboniferous Limestone aquifer of the Mendip Hills, Somerset, to compare the relative merits of differing groundwater tracers. The tracers employed were lithium acetate, polyethylene powder, Lycopodium spores and the fluorescent dye Pyranine Conc.; all were introduced into the aquifer at stream sinks. The first two tracers were totally unsuccessful. In the two experiments the rates of travel of the fluorescent dye and Lycopodium spores were very similar. Only relative concentrations can be measured from the recovery of spores as opposed to absoute concentration for dye which were determined using a field continuous flow fluorometer. The quantitative dye concentration data can be used with simultaneous measurements of discharge at the spring to deduce the flow geometry of the system; the input, tributary, distributary and maximum discharges in the system and the volume of the underground conduits. Data are presented which indicate that exchange takes place between the flooded conduit, and the surrounding fissured bedrock in a manner analogous to bank storage in rivers flowing on alluvium.In conclusion fluoresent tracers are valuable for the detailed investigation of a single sink to rising system; Lycopodium spores, which can be used to trace several sinks simultaneously, are a valuable technique in exploratory tracing. 相似文献
11.
Tracer experiments were carried out in groyne fields (GF) of the river Elbe near Havelberg (Germany) in order to estimate the hydraulic connectivity with the river channel. The characteristic times of the five groyne fields, which were estimated from the exponentially declining tracer curves in 43 runs, ranged between 15 min and 69 min and did not correlate with the water level. Methodological investigations show that single point injection and two measurements (in the outflowing water and in the dominant region) are sufficient to provide robust in‐situ tracer curves. Using simplified mathematical simulations with connected stirred tanks, the conditions are investigated for the development of breaks in tracer curves and for the occurrence of significant errors in the estimation of intrinsic residence times. It was shown that an initial uniform dye distribution is not mandatory for the estimation during steady states. In special cases, point injections are more advisable. Moreover, the mean hydraulic residence time was found to be not equivalent to the estimated characteristic time. In fact, it is mostly overestimated by tracer experiments. The degree of overestimation depends on mixing and the volumetric proportions between the different parts of the GF and can be calculated from measured dye concentration differences. For example, an overestimation of 32% was calculated for a groyne field with a commonly found circulation flow pattern. 相似文献
12.
Stephen R.H. Worthington 《Ground water》2022,60(2):169-179
Flow in many bedrock aquifers is through fracture networks. Point to point tracer tests using applied tracers provide a direct measure of time of travel and are most useful for determining effective porosity. Calculated values from these tests are typically between 10−4 and 10−2 (0.01% to 1%), with these low values indicating preferential flow through fracture and channel networks. Tracer tests are not commonly used in site investigations, and specific yield is often used as a proxy for effective porosity. The most popular methods have used centrifuge measurements, water table fluctuations, pumping tests, and packer tests. Specific yield varies substantially with the testing method. No method is as reliable as tracer testing for providing estimates of effective porosity, but all methods provide complementary insights on aquifer structure. Temporal and spatial scaling effects suggest that bedrock aquifers have hierarchical structures, with a network of more permeable fractures and channels, which are connected to less permeable fractures and to the matrix. Consequences of the low effective porosities include groundwater velocities that often exceed 100 m/d and more frequent microbial contamination than in aquifers in unconsolidated sediments. The large uncertainty over the magnitude of effective porosity in bedrock aquifers makes it an important parameter to determine in studies where time of travel is of interest. 相似文献
13.
Daniela Suteu Doina Bilba Magdalena Aflori Florica Doroftei Gabriela Lisa Marinela Badeanu Teodor Malutan 《洁净——土壤、空气、水》2012,40(2):198-205
This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L?1), dye concentration (50–300 mg L?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L?1, dye initial concentration of 50–50 mg L?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters. 相似文献
14.
Bian Yin-ju 《地震学报(英文版)》2005,18(4):441-450
We try to give a quantitative and global discrimination function by studying m
b/M
S data using Fisher method that is a kind of pattern recognition methods. The reliability of the function is also analyzed.
The results show that this criterion works well and has a global feature, which can be used as first-level filtering criterions
in event identification. The quantitative and linear discrimination function makes it possible to identify events automatically
and achieve the goal to react the events quickly and effectively.
Contribution No.05FE3018, Institute of Geophysics, China Earthquake Administrtion. 相似文献
15.
This research (1) integrated a fluorescent dye injection and monitoring system for measuring the mixing of a fluorescent dye tracer (fluorescein) in permeable (sandy) sediments with a cabled ocean observatory, Kilo Nalu, Oahu, Hawaii, and (2) used this system to conduct remotely controlled in situ measurements of wave-enhanced porewater mixing in a physically well-characterized wave-dominated setting. Laboratory results indicated that the fiber-optic sensor is effective at measuring fluorescence-traced enhanced mixing in sandy sediments. Observed dye mixing, driven by paddle-generated surface waves in a laboratory wave channel was 2–3 orders of magnitude greater than molecular diffusion, and decreased with depth in the sediments. Similarly, field experiments used a remotely controlled submersible syringe pump for fluorescent tracer injection into sediment that was monitored with a fiber-optic sensor. These experiments were carried out at 10 m water depth, with mean wave heights of 0.3–1.5 m and periods of ∼15 s. At 15 cm sediment depth, transport rates of 0–5 cm h−1 were measured, with maximum dispersion coefficients 2–3 orders of magnitude faster than sedimentary molecular diffusion. Hydrodynamic measurements collected simultaneously via Kilo Nalu correlated with porewater transport, with significant wave height and diffusion having the strongest covariation. 相似文献
16.
17.
A. Tazioli 《水文科学杂志》2013,58(7):1314-1324
Abstract Discharge measurements in natural watercourses are performed in order to determine the value of the surface outflow of a basin, its temporal variability, and the outflow characteristics. The methods conventionally used for these measurements utilize an immersed current meter in different points of a river section, which acquires the mean flow velocity. Using this measurement, the discharge can be calculated. Some experimental problems arise, however, when there is a very high discharge. An important method, valid in such cases, is the artificial tracing method. In particular, the use of chemical tracers for small watercourses is very convenient because they are low cost, easily handled, low impact and provide satisfactory results. In the past, radioactive tracers such as tritium have been used in large rivers, while fluorescent tracers have been commonly exploited in the USA and now elsewhere. However, if the water is turbid, the suspended sediments may easily absorb some tracers. In this paper, the preliminary results of a comparison between current meter and artificial tracer measurements are reported. In particular, field tests in a small tributary have been performed, in order to investigate the behaviour of different tracers. Citation Tazioli, A. (2011) Experimental methods for river discharge measurements: comparison among tracers and current meter. Hydrol. Sci. J. 56(7), 1314–1324. 相似文献
18.
Flow dynamics within a peatland are governed by hydraulic parameters such as hydraulic conductivity, dispersivity and specific yield, as well as by anisotropy and heterogeneity. The aim of this study is to investigate hydraulic parameters variability in peat through the use of different field and laboratory methods. An experimental site located in the Lanoraie peatland complex (southern Quebec, Canada) was used to test the different approaches. Slug and bail tests were performed in piezometer standpipes to investigate catotelm hydraulic conductivity. Combined Darcy tests and tracer experiments were conducted on cubic samples using the modified cube method (MCM) to assess catotelm hydraulic conductivity, anisotropy and dispersivity. A new laboratory method is proposed for assessing acrotelm hydraulic conductivity and gravity drainage using a laboratory experimental tank. Most of slug tests' recovery curves were characteristic of compressible media, and important variability was observed depending on the initial head difference. The Darcy experiments on cubic samples provided reproducible results, and anisotropy (Kh > Kv) was observed for most of samples. All tracer experiments displayed asymmetrical breakthrough curves, suggesting the presence of retardation and/or dual porosity. Hydraulic conductivity estimates performed using the experimental tank showed K variations over a factor of 44 within the upper 40 cm of the acrotelm. The results demonstrate that the intrinsic variability associated with the different field and laboratory methods is small compared with the spatial variability of hydraulic parameters. It is suggested that a comprehensive assessment of peat hydrological properties can be obtained through the combined use of complementary field and laboratory investigations. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
19.
20.
Batch sorption technique was carried out for the removal of anionic dye Congo red (CR) from aqueous solution using raw rectorite (R‐REC) and organified rectorite (CTA+‐REC) modified by cetyltrimethylammonium bromide (CTAB) as adsorbents. The effects of organification degree of CTA+‐REC as well as the process parameters including the pH of dye solution, sorption time, and initial dye concentration on adsorption capacity for CR were investigated and the sorption kinetics was also evaluated. The results showed that the sorption behaviors of R‐REC and CTA+‐REC for CR followed pseudo‐second‐order kinetic model and the sorption equilibrium data perfectly obeyed the Langmuir isotherm. The thermodynamic parameters including entropy of sorption (ΔS0), enthalpy of sorption (ΔH0), and Gibbs free energy of sorption (ΔG0) were obtained and analyzed. Fourier transform infrared study revealed that a chemisorption process occurred between CR and CTA+‐REC. REC modified by cationic surfactants showed the higher adsorption capacities for CR compared to R‐REC and in theory would be used as an efficient and promising adsorbent for the removal of anionic dyes in wastewater treatment. 相似文献