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1.
Experimental Petrology of Melilite Nephelinites 总被引：3，自引：1，他引：3
Experimental study of natural melilite nephelinite lavas ofintermediate K/Na ratio at low pressure (fo2 reveals the presenceof a peritectic ‘point’ of distributary type (1090?C)for liquids saturated with leucite, nepheline, and spinel. Withdecreasing temperature on the olivine + melilite cotectic, botholivine and melilite react with such liquids to produce high-calciumpyroxene at the peritectic. Both the olivine + high-calciumpyroxene and melilite + high-calcium pyroxene cotectics arestable at temperatures below the peritectic. Olivines coexistingwith such liquids are much more magnesian than those in comparabletholeiitic liquids. The olivine-liquid Fe-Mg distribution coefficient is a monotonically increasing function of silica activity over the composition range spannedby melilite nephelinite, ugandite, alkali basalt, and tholeiitebasalt liquids. The analogous Fe-Mg distribution coefficientfor melilite and liquid is effectively constant , while that for high-calcium pyroxene and liquidis highly dependent on the chemistry of high-calcium pyroxene(cf., Sack & Carmichael, 1984). Pseudoternary liquidus projectionsof multiply saturated liquids coexisting with nepheline, leucite,and spinel (?olivine?high-calcium pyroxene?melilite) have beenprepared to facilitate graphical analysis of the evolution oflava compositions during hypabyssal cooling. Major element chemicalanalyses and petrographic features of lavas from Mt. Nyiragongo,East Africa and Oahu, Hawaii (e.g., Denaeyer et al., 1965; Wilkinson& Stolz, 1983) confirm the validity of these diagrams andthe systematics established from the experimental data.
*Reprint requests to R.O. Sack 相似文献
2.
One mantle xenolith from a basanite host of the Mt. Melbourne Volcanic Field (Ross Sea Rift) is extraordinary in containing
veins filled with leucite, plagioclase, clinopyroxene, nepheline, Mg-ilmenite, apatite, titaniferous mica, and the rare mineral
zirconolite. These veins show extensive reaction with the dunitic or lherzolitic host (olivine+spinel+orthopyroxene+clinopyroxene).
The reaction areas contain skeletal olivine and diopside crystals, plagioclase, phlogopite, aluminous spinel and ilmenite
in a fine grained groundmass of aluminous spinel, clinopyroxene, olivine, plagioclase and interstitial leucite. The vein composition
estimated from modal abundances and microprobe analyses is a mafic leucite-phonolite with high amounts of K, Al, Ti, Zr and
Nb but low volatile contents. The melt is unrelated to the host basanite and was probably derived by smallscale melting of
incompatible element-enriched phlogopite-bearing mantle material and must have lost most of its volatile content during migration,
crystallization and reaction with the host dunite. While the veins are completely undeformed the dunitic host shows slight
deformation. Vein minerals crystallized at high temperatures above 1000°C and pressures below 5 kbar according to the phase
assemblage including leucite, nepheline and K-feldspar. Spinel/olivine geothermometry yielded 800–920°C for the re-equilibration
of the host peridotite. Thus the xenolith must have been at shallow depth prior to and during the late veining event. Mantle
material at shallow depths is consistent with rifting and the regional extreme displacement at the transition from the rifted
Victoria Land Basin in the Ross Sea to the uplifted Trans-Antarctic Mountains. 相似文献
3.
The alkalic pyroxenite nodule consists of megacrysts of diopside, apatite, perovskite and titanomagnetite in a groundmass consisting of diopside, apatite, titanomagnetite, nepheline, melilite, garnet and vishnevite crystals of various shapes, including previously undescribed skeletal and dendritic shapes, together with vesicles and residual glass. The residual glass is poor in SiO2 (38–40 wt%), and extraordinarily rich in Na2O (12.8–15 wt%), SO3 (1–1.5 wt%), and Cl (0.25–0.7 wt%), as a result of rapid, non-equilibrium crystallization of groundmass phases from a CO2-rich nephelinite melt.The Oldoinyo Lengai alkalic carbonatite lavas do not represent extreme products of the fractional crystallization of pyroxene, wollastonite, nepheline and alkali feldspar from the carbonated nephelinite melt. The most likely connection between the carbonatite and silicate magma types is one of liquid immiscibility, probably involving phonolite melt. 相似文献
4.
Petrology of Mt Etinde Nephelinite Series 总被引：3，自引：1，他引：2
Mt Etinde is a volcano situated on the southwestern flank ofthe large Mt Cameroon. Its eruptions are dated at 065 Ma andtook place during the Mt Cameroon eruptive cycle (6 Ma withrecorded recent activity). The lava types, unrelated to theMt Cameroon alkali basalts, are melanephelinites, nephelinitessensu stricto, and numerous and varied nephelinites that containone or more of the following species: nosean, melilite, perovskite,garnet, aenigmatite, leucite, feldspar and haynophyres. Clinopyroxeneis the dominant mafic phase, with a variable composition betweenAl–Ti augite and aegirine. Zoning is also present in garnets,with conspicuous Ti enrichment in the border. Aenigmatite includesa fair proportion of Fe3+ Tschermak's component. Melilite issystematically Sr rich; its SrO contents increase continuouslywith MgO decrease, reaching 16 wt % in some facies. The chemicalcomposition of the lavas is extreme, with unusual concentrationsof volatiles (CO2, H2O, SO3), most incompatible elements, suchas Ba, Sr and Zr, and the light rare earth elements (LREE).The Mt Etinde lavas define two lineages (MgO poor and MgO rich)that partly overlap. The chemical evolution of these two lineagescan be reproduced for major elements using a simple model ofcrystal fractionation. The major fractionating phase is an aluminousclinopyroxene, in accord with the petrographical observations.The scheme proposed can only be validated if the alkalis arenot taken into account, a hypothesis warranted by observationsof other nephelinite provinces or ijolite massifs and theirfenite aureoles. Nephelinite magmas were obviously generatedat great mantle depth, but their exotic composition can onlybe produced by partial melting of a metasomatic mantle. Comparisonwith other provinces would point to a source that has undergonecarbonatitic mtasomatism. KEY WORDS: nephelinites; Mt Etinde; Cameroon; petrogenesis; differentiation
*Present address: Dpartement des Sciences de la Terre, Facult des Sciences, Universit de Yaound, BP 812, Yaound, Cameroon.Corresponding author. 相似文献
5.
Summary A suite of lithics (ejecta) collected from the latest erupted pyroclastic products of the Alban Hills volcano (Central Italy)
has been studied to determine their mineralogical composition and to investigate their genesis. The ejecta commonly have granular
texture and consist of coarse-grained crystals often associated with a fine- to medium-grained matrix. The mineralogical composition
is variable and consists of both typical igneous minerals and contact metamorphic phases. Garnet, clinopyroxene K-feldspar
are almost ubiquitous, whereas leucite, wollastonite, sodalite-group minerals, phlogopite, nepheline and phillipsite are present
in most of the ejecta; minor and accessory phases include cuspidine, amphibole, pyrrhotite, magnetite, apatite, uranpyrochlore,
sphene, kalsilite, and melilite; anorthite, zircon and fluorine-bearing Ca, Zr silicate phases, larnite, and baryte are found
sporadically. Ca, REE, Th silicophosphates occur in many samples generally disseminated along interstices and fractures of
main minerals. Calcite is present as discrete crystals sometimes enclosed in other minerals, as granules in the fine-grained
matrix and as late microcrystalline veins. It shows high oxygen and low carbon isotope ratios with δ18O = + 17.96 to + 27.19, and δ13C = −4.74 to −19.57.
Clinopyroxene ranges from diopside to compositions strongly enriched with both Ca-Tschermak’s and esseneite components. Feldspars
are generally potassic even though Ba and Sr are found in significant concentrations in some samples. K-feldspars from wollastonite-bearing
ejecta are often rimmed with elongated felty crystals identified by X-ray diffraction analysis as leucite. These feldspars
show a depletion in Si, and enrichment in Al and K from core to rim. Significant compositional variations are also shown by
various other phases such as nepheline, apatite, Ca, REE, Th silicophosphate.
The occurrence of igneous and contact metamorphic minerals, as well as the chemical variations of clinopyroxenes and feldspars
in the investigated ejecta reveal complex genetic processes related to the interaction between potassic magma and wall rocks.
The Ca-rich composition of most phases points to a carbonate nature for the wall rocks. Textural evidence suggests that coarse-grained
rocks formed at the margin of the magma chamber were invaded by a late, volatile rich potassic liquid which crystallized as
a fine-grained matrix and produced disaggregation and reaction of early formed minerals. Fluid phases percolating through
the rocks generated infiltration metasomatism and deposited some uncommon phases rich in Ca, REE, Th, U, which are found along
cracks and at the margins of early crystallized minerals.
Overall, the all spectrum of the minerals found in this study are also typical of carbonatitic rocks. Their presence in the
Alban Hills ejecta demonstrates that their genesis can be related to interaction between ultrapotassic melts and carbonate
wall rocks, in addition to precipitation from carbonatitic melts.
Received February 20, 2001; revised version accepted September 23, 2001 相似文献
6.
Felsic alkalic rocks are a minor component of many ocean island volcanic suites, and include trachyte and phonolite as well as various types of alkaline and peralkaline rhyolite. However, there is considerable debate on the nature of their formation; for example, are they formed by partial melting of anomalous mantle or the final products of fractional crystallization of mafic magmas. The phonolites and foidal phonolites on Rarotonga were formed by low pressure crystal fractionation of two chemically distinct parental magmas. Low silica and high silica mafic magmas produced a basanite-foidal phonolite series and an alkali basalt-phonolite series, respectively. The foidal phonolite composition evolved from the low silica mafic magmas by approximately 60% fractionation of titanaugite + leucite + nepheline + magnetite + apatite. Fractionation continued with the crystallization of aegirine-augite + nepheline + kaersutite + magnetite + apatite. The phonolites formed from the alkali basalts by approximately 40% fractionation of kaersutite + titanaugite + Fe-Ti oxide + plagioclase + apatite and continued to evolve further by fractionation of anorthoclase + nepheline + aegerine-augite + Fe-Ti oxides. As the magmas fractionated in both suites, their overall viscosities (solid + liquid) increased until a point was reached whereby viscosity inhibited the eruption of magmas with compositions intermediate between the mafic rocks and the felsic rocks. However, the magmas continued to fractionate under static conditions with the residual fluid becoming foidal phonolitic in the low silica suite or phonolitic in the high silica suite. These phonolitic liquids, as a result of an increase in volatiles and enrichment of alkalis over aluminum, would actually have a lower viscosity than the intermediate liquids. This decrease in viscosity and the switch from a magma chamber being predominantly a liquid with suspended solids to a solid crystalline network with an interstitial liquid enabled phonolitic liquids to migrate, pool, and eventually erupt on the surface. 相似文献
7.
A considerable part of the nephelinite lavas of the volcanoMt. Nyiragongo in the eastern Belgian Congo contains kalsiliteas one of the main constituents. The mineral never occurs asthe only feldspathoid of the rock but is accompanied by nepheline,abundant melilite, and, sometimes, by small to moderate amountsof leucite. Other important constituents of these kalsilite-bearingrocks are clinopyroxene, olivine, perovskite, titanomagnetite,sodalite, &c. The feldspars are lacking. Kalsilite occurs both as complex nepheline-kalsilite phenocrystsin which these phases are strictly co-axial and in the fine-grainedgroundmass as grains separate from those of nepheline. The complex nepheline-kalsilite phenocrysts exhibit a continuousseries of progressing exsolution schematically presented inFig. 5. The series begins with a perthite-like nepheline-kalsilitecore surrounded by a drop-like development of nepheline in themargin of the crystal and ends up with a homogeneous kalsilitecore surrounded by a nepheline margin. The complex phenocrysts occur mostly as aggregates causing atypically glomeroporphyritic texture. Evidence is presentedindicating that, in the very first stages of crystallization,some of the Nyiragongo lavas are able to precipitate small amountsof phenocrysts of approximate composition K3NaAl4Si4O16. Throughcrystal-rise under turbulent currents in the molten lava massthese phenocrysts have been accumulated into aggregates andthus have been preserved until extrusion. Granted sufficientlyslow cooling under static conditions, the phenocrysts wouldhave reacted with the molten lava. The roles of the crystal-riseand of the turbulent currents in lava are illustrated by theoccurrence of the ‘giant’ leucite aggregates foundin the inner walls of the crater and by observations on thelava lake of the mountain. The occurrence of kalsilite in the groundmass is explained bythe existence of a two-phase area in the sub-solidus range inthe nepheline-kalsilite system. The Nepheline Aggregate lavas represent the last extrusionsemitted by the Nyiragongo main crater. The nepheline phenocrystscharacteristic of these lavas range considerably higher in potassiumcontent than the nephelines found in other Nyiragongo flows.The crystals are slightly zoned with a large potassium-richcore coated by a narrow margin with gradually decreasing potassiumcontent. The zoning may be detected only by using special methods.The history of crystallization of the nepheline phenocrystsis considered analogous to that of the complex nepheline-kalsilitephenocrysts with the only difference that the nepheline phenocrystsof the Nepheline Aggregate lavas are less rich in potassiumand, consequently, have not been subjected to exsolution. 相似文献
8.
I.P. Solovova A.V. Girnis L.N. Kogarko N.N. Kononkova F. Stoppa G. Rosatelli 《Lithos》2005,85(1-4):113-128
This paper presents a study of melt and fluid inclusions in minerals of an olivine-leucite phonolitic nephelinite bomb from the Monticchio Lake Formation, Vulture. The rock contains 50 vol.% clinopyroxene, 12% leucite, 10% alkali feldspars, 8% hauyne/sodalite, 7.5% nepheline, 4.5% apatite, 3.2% olivine, 2% opaques, 2.6% plagioclase, and < 1% amphibole. We distinguished three generations of clinopyroxene differing in composition and morphology. All the phenocrysts bear primary and secondary melt and fluid inclusions, which recorded successive stages of melt evolution. The most primitive melts were found in the most magnesian olivine and the earliest clinopyroxene phenocrysts. The melts are near primary mantle liquids and are rich in Ca, Mg and incompatible and volatile elements. Thermometric experiments with the melt inclusions suggested that melt crystallization began at temperatures of about 1200 °C. Because of the partial leakage of all primary fluid inclusions, the pressure of crystallization is constrained only to minimum of 3.5 kbar. Combined silicate–carbonate melt inclusions were found in apatite phenocrysts. They are indicative of carbonate–silicate liquid immiscibility, which occurred during magma evolution. Large hydrous secondary melt inclusions were found in olivine and clinopyroxene. The inclusions in the phenocrysts recorded an open-system magma evolution during its rise towards the surface including crystallization, degassing, oxidation, and liquid immiscibility processes. 相似文献
9.
The major and trace element chemistry of phonolites containing spinel Iherzolite xenoliths from Bokkos (Nigeria), Phonolite Hill (northeastern Australia) and Heldburg (East Germany) is consistent with an origin by fractional crystallization of basanitic magmas at upper mantle pressures (10–15 kbar). At Bokkos, spatially associated lavas ranging from hawaiitic nepheline mugearite to nepheline benmoreite can be modeled very well by fractional crystallization of kaersutitic amphibole + olivine + Fe-Ti-spinel + apatite, a crystal extract consistent with experimentally-determined near-liquidus phase relationships for mugearitic liquids. Further fractional crystallization of aluminous clinopyroxene + mica + apatite will yield the phonolites. A similar model relating the unusual Iherzolite-bearing mafic nepheline benmoreite from Pigroot (New Zealand) to basanitic lavas of the East Otago province is not supported by major and trace element data. The Pigroot lava is possibly the product of melting of a mantle source region previously enriched in Sr and light rare earth elements, with subsequent minor fractional crystallization of olivine + kaersutite. Dynamic flow crystallization processes operating within conduit systems from mantle pressures are capable of yielding large volumes of evolved phonolitic liquids from primary basanitic liquids, if magma flow rates are appropriate. This mechanism may provide an explanation for the volumetric bias towards salic differentiates in some alkalic provinces. 相似文献
10.
A considerable part of the nephelinite lavas of the volcanoMt. Nyiragongo in the eastern Belgian Congo contains kalsiliteas one of the main constituents. The mineral never occurs asthe only feldspathoid of the rock but is accompanied by nepheline,abundant melilite, and, sometimes, by small to moderate amountsof leucite. Other important constituents of these kalsilite-bearingrocks are clinopyroxene, olivine, perovskite, titanomagnetite,sodalite, &c. The feldspars are lacking. Kalsilite occurs both as complex nepheline-kalsilite phenocrystsin which these phases are strictly co-axial and in the fine-grainedgroundmass as grains separate from those of nephe-line. The complex nepheline-kalsilite phenocrysts exhibit a continuousseries of progressing exsolution schematically presented inFig. 5. The series begins with a perthite-like nepheline-kalsilitecore surrounded by a drop-like development of nepheline in themargin of the crystal and ends up with a homogeneous kalsilitecore surrounded by a nepheline margin. The complex phenocrysts occur mostly as aggregates causing atypically glomeroporphyritic texture. Evidence is presentedindicating that, in the very first stages of crystallization,some of the Nyiragongo lavas are able to precipitate small amountsof phenocrysts of approximate composition K3NaAl4Si4O16. Throughcrystal-rise under turbulent currents in the molten lava massthese phenocrysts have been accumulated into aggregates andthus have been preserved until extrusion. Granted sufficientlyslow cooling under static conditions, the phenocrysts wouldhave reacted with the molten lava. The roles of the crystal-riseand of the turbulent currents in lava are illustrated by theoccurrence of the ‘giant’ leucite aggregates foundin the inner walls of the crater and by observations on thelava lake of the mountain. The occurrence of kalsilite in the groundmass is explained bythe existence of a two-phase area in the sub-solidus range inthe nepheline-kalsilite system. The Nepheline Aggregate lavas represent the last extrusionsemitted by the Nyiragongo main crater. The nepheline phenocrystscharacteristic of these lavas range considerably higher in potassiumcontent than the nephelines found in other Nyiragongo flows.The crystals are slightly zoned with a large potassium-richcore coated by a narrow margin with gradually decreasing potassiumcontent. The zoning may be detected only by using special methods.The history of crystallization of the nepheline phenocrystsis considered analogous to that of the complex nepheline-kalsilitephenocrysts with the only difference that the nephe-line phenocrystsof the Nepheline Aggregate lavas are less rich in potassiumand, consequently, have not been subjected to exsolution. 相似文献
11.
Bernard Bingen Daniel Demaiffe Jan Hertogen 《Contributions to Mineralogy and Petrology》1990,105(3):275-288
The Sveconorwegian Augen Orthogneisses of Rogaland — Vest-Agder (SW Norway) were emplaced as amphibole- and biotite-bearing granodiorites at 1040 Ma (concordant Rb/Sr and zircon U/Pb ages). They underwent prograde metamorphism which increased from lower amphibolite-facies in the eastern zone to granulite-facies in the western zone, close to the Rogaland anorthosite complex. K-feldspar megacrysts initially crystallised as phenocrysts and were chemically equilibrated during metamorphism, as shown by the flat Ba concentration profiles and the increase of the anorthite content from An1.1 in the amphibolitefacies to An2.6 in the granulite-facies. This increase of the An content suggests an increase in metamorphic temperature. The REE content of the megacrysts is related to the associated accessory minerals which depend upon the metamorphic grade: sphene + allanite + apatite + zircon and rarely thorite in amphibolite-facies, and apatite + zircon + monazite ± thorite in lower amphibolite-and granulite-facies. Amphibole and biotite inclusions in megacrysts were also equilibrated during metamorphism. Groundmass K-feldspar and plagioclase experienced late-metamorphic changes during uplift. An internal Rb/Sr mineral isochron (plagioclase, apatite, K-feldspar) defines an age of 870 Ma, which represents the closure of the Rb/Sr isotopic system in minerals of the augen gneisses. This age also represents a K-feldspar cooling age in regionally distributed augen gneiss samples. The K-feldspar cooling age appears to be similar to or slightly older than the biotite cooling age. 相似文献
12.
In this paper we report the results of the analysis of rare earth (REE), large-ion lithophile (LILE), and high field strength (HFSE) elements in minerals from the alkaline lamprophyre dikes of the Kola region and the Kaiserstuhl province by the local method of laser ablation inductively coupled plasma mass spectrometry. The contents of Y, Li, Rb, Ba, Th, U, Ta, Nb, Sr, Hf, Zr, Pb, Be, Sc, V, Cr, Ni, Co, Cu, Zn, Ga, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu were measured in olivine, melilite, clinopyroxene, amphibole, phlogopite, nepheline, apatite, perovskite, and the host fine-grained groundmass. The obtained data on trace element partitioning among the mineral phases of the alkaline ultrabasic rocks of the dike series indicate that the main mineral hosts for the HFSEs and REEs in alkaline picrites, olivine melanephelinites, and melilitites are perovskite and apatite comprising more than 90% of these elements. Among major rock-forming minerals, melilite, clinopyroxene, and highly magnesian amphibole make a significant contribution to the balance of REEs during the evolution of melanephelinite melts. The partition coefficients of Ni, Co, Cu, Zn, Sc, V, Cr, Ga, Y, Li, Rb, Ba, Th, U, Ta, Nb, Sr, Hf, Zr, Pb, Be, and all of the REEs were calculated for olivine, clinopyroxene, amphibole, phlogopite, nepheline, perovskite, and apatite on the basis of mineral/groundmass ratios. Variations in the composition of complex zoned clinopyroxene phenocrysts reflect the conditions of polybaric crystallization of melanephelinite melt, which began when the magmas arrived at the base of the lower crust and continued during the whole period of their ascent to the surface. The formation of green cores in clinopyroxene is an indicator of mixing between primary melanephelinite melts and phonolite magmas under upper mantle conditions. The estimation of the composition of primary melts for the rocks of the alkaline ultrabasic series of the Kola province indicated a single primary magma for the whole series. This magma produced pyroxene cumulates and complementary melilitolites, foidolites, and nepheline syenites. 相似文献
13.
Excelso Ruberti Gaston E. R. Enrich Rogério G. Azzone Piero Comin-Chiaramonti Angelo De Min Celso B. Gomes 《Mineralogy and Petrology》2012,104(1-2):63-80
The Cretaceous Banhad?o alkaline complex in southeastern Brazil presents two potassic SiO2-undersaturated series. The high-Ca magmatic series consist of initially fractionated olivine (Fo92-91) + diopside (Wo48-43En49-35Ae0-7), as evidenced by the presence of xenocrysts and xenoliths. In that sequence, diopside (Wo47-38En46-37Ae0-8) + phlogopite + apatite + perovskite (Prv>92) crystallized to form the phlogopite melteigite and led to the Ca enrichment of the magma. Diopside (Wo47-41En32-24 Ae3-14) continued to crystallize as an early mafic mineral, followed by nepheline (Ne74.8-70.1Ks26.3-21.2Qz7.6-0.9) and leucite (Lc65-56) and subsequently by melanite and potassic feldspar (Or85-99Ab1-7) to form melanite ijolites, wollastonite-melanite urtites and melanite-nepheline syenites. Melanite-pseudoleucite-nepheline syenites are interpreted to be a leucite accumulation. Melanite nephelinite dykes are believed to represent some of the magmatic differentiation steps. The low-Ca magmatic series is representative of a typical fractionation of aegirine-augite (Wo36-29En25-4Ae39-18) + alkali feldspar (Or57-96Ab3-43) + nepheline (Ne76.5-69.0Ks19.9-14.4Qz15.1-7.7) + titanite from phonolite magma. The evolution of this series from potassic nepheline syenites to sodic sodalite syenites and sodalitolites is attributed to an extensive fractionation of potassic feldspar, which led to an increase of the NaCl activity in the melt during the final stages forming sodalite-rich rocks. Phonolite dykes followed a similar evolutionary process and also registered some crustal assimilation. The mesocratic nepheline syenites showed interactions with phlogopite melteigites, such as compatible trace element enrichments and the presence of diopside xenocrysts, which were interpreted to be due to a mixing/mingling process of phonolite and nephelinite magmas. The geochemical data show higher TiO2 and P2O5 contents and lower SiO2 contents for the high-Ca series and different LILE evolution trends and REE chondrite-normalized patterns as compared to the low-Ca series. The 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb and 208Pb/204Pb initial ratios for the high-Ca series (0.70407–0.70526, 0.51242–0.51251, 17.782–19.266 and 38.051–39.521, respectively) were slightly different from those of the low-Ca series (0.70542–0.70583, 0.51232–0.51240, 17.758–17.772 and 38.021–38.061, respectively). For both series, a CO2-rich potassic metasomatized lithospheric mantle enriched the source with rutile-bearing phlogopite clinopyroxenite veins. Kamafugite-like parental magma is attributed to the high-Ca series with major contributions from the melting of the veins. Potassic nephelinite-like parental magma is assigned to the low-Ca series, where the metasomatized wall-rock played a more significant role in the melting process. 相似文献
14.
W. Scott Baldridge I. S. E. Carmichael A. L. Albee 《Contributions to Mineralogy and Petrology》1981,76(3):321-335
The salic phases found in leucite-basanites, -trachytes, and -phonolites may be used to portray crystallization in the system NaAlSiO4-KAlSiO4-CaAl2Si2O8-SiO2, the phonolite pentahedron. Only two lavas have been found that contain the assemblage leucite-nepheline-plagioclase-sanidine and liquid, a natural pseudo-invariant assemblage (at 900° C±100) equivalent to the isobaric invariant point of the four component system. The diversity of phases in this group of lavas illustrates the role of halogens in controlling their crystallization paths. Thus the presence of F in the leucite-basanites has stabilized magnesian biotite and suppressed sanidine, as has been found in other basanitic lavas (Brown and Carmichael 1969). The presence of Cl in these same lavas has induced the crystallization of sodalite, which takes the place of nepheline in the groundmass. However in the leucite-trachytes, biotite has suppressed olivine and coexists with sanidine and leucite. The presence of S may produce haüyne at the expense of nepheline, and in general sulphate minerals, which include apatite, have the role in lavas of low silica activity that pyrrhotite plays in liquids of high silica activity. Both pyroxenes and titaniferous magnetites in this suite of lavas are very aluminous. Groundmass crystals of pyroxene may have one-fifth of Si replaced by Al. Other phases which occur occasionally are melanite garnet and a potassium-rich hastingsite, but neither ilmenite nor a sulphide mineral has been found. Phenocryst equilibration temperatures, derived from olivine and Sr-rich plagioclase, are generally in the range from 1,050° C to 1,150° C. The high content of incompatible elements (e.g., K, Ba, Rb, F, Sr, P) in these lavas suggests that they represent a small liquid fraction from a mantle source which possibly contains phlogopite. 相似文献
15.
W. D. Birch 《Australian Journal of Earth Sciences》2013,60(7-8):369-385
Comparison of bulk chemistry confirms the comagmatic nature of the New South Wales leucitite belt and the olivine leucitite at Cosgrove, Victoria. This relationship was previously implied by general mineralogical, petrographical, and age similarities, as well as the meridional trend of the occurrences. Differences of a minor nature occur between the N.S.W. and Victorian rock types, the latter being less potassic and magnesian (poorer in leucite and olivine) and more calcic (richer in clinopyroxene). Trace‐element compositions for the Cosgrove leucitite are within the ranges recorded for the N.S.W. belt. Essentially one‐rock type—a melanocratic leucitite—characterizes the belt, with the essential minerals olivine, diopside/salite, leucite, titanomagnetite, ilmenite, nepheline, and Ti‐Ba biotite. However, a pegmatoid phase, relatively enriched in Ti, Fe, and P, is well developed at Cosgrove, with its mineralogy (salite‐titanian aegirine, sodic amphibole, K‐feldspar, nepheline, titanomagnetite, apatite, ilmenite, aenigma‐tite, sodalite, and analcite) demonstrating extreme peralkaline differentiation. Some evidence suggests that the analcite resulted from alteration of leucite. The role of volatiles such as F was significant in facilitating development of coarse textures as well as crystallization of the amphibole, apatite, and sodalite. Magmas for the southeastern Australian leucitite belt were probably generated by equilibrium fusion of phlogopite peridotites, of slightly variable mineralogy. Deep‐seated crustal fractures controlled the relatively limited appearance of the magmas at the surface. There is no regular age variation along the belt, despite the age range of from 7 to 13 m.y. 相似文献
16.
《Russian Geology and Geophysics》2015,56(3):466-475
Inclusions of mineral-forming environments in apatite-containing ijolites and magnetite–phlogopite–apatite ores in carbonatites were studied to elucidate the genesis of apatite mineralization in the Guli alkaline ultramafic carbonatite massif. Primary inclusions of carbonate–salt and carbonate melts have been discovered and studied. The carbonate–salt melt inclusions are of alkaline high-Ca composition and are enriched in P, Sr, SO3, and F (wt.%): CaO—30–40, Na2O—5–12, K2O—2–4, P2O5—1–3, SO3—1.5–3, and SrO—1–3. They also contain minor MgO, FeO, BaO, and SiO2 (tenths and hundredths of percent). The homogenization temperature of these inclusions is 850–970 °C. The carbonate inclusions contain predominant CaO (54–67 wt.%) and minor MgO, FeO, SrO, Na2O, and P2O5 (tenths of percent). Their homogenization temperature is 840–860 °C. Similar primary carbonate–salt and carbonate inclusions were found in garnet, and secondary ones were detected in silicate minerals (clinopyroxene and nepheline) of ijolites. Clinopyroxenes of ijolites also contain primary inclusions of alkaline ultramafic high-Ca melts similar in composition to melilitite-melanephelinites highly enriched in P, SO3, and CO2 (wt.%): SiO2—41–46, Al2O3—8–16, FeO—2–8, MgO—3–6, CaO—12–20, Na2O—2–9, K2O—1–6, P2O5—0.4–2.1, SO3—0.2–2.3, and Cl—0.02–0.35. According to the obtained data, apatite of the magnetite–phlogopite–apatite ores and ijolites of the Guli pluton crystallized from phosphorus-rich alkaline carbonate–salt melts at 850–970 °C. The generation of these melts was, most likely, due to the silicate–salt immiscibility in melilitite-melanephelinite melts highly enriched in salts, which occurred either at the final stages of clinopyroxene crystallization or during the formation of melilite. The presence of alkalies, S, F, and CO2 in spatially separated carbonate–salt melts contributed to the concentration and preservation of phosphorus in them at low temperatures, which led to the formation of apatite mineralization in ijolites and ore deposit in carbonatites.© 2015, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved. 相似文献
17.
Tony D. Peterson 《Contributions to Mineralogy and Petrology》1989,101(4):458-478
Shombole, a nephelinite-carbonatite volcano in south Kenya, erupted silicate lavas, carbonatite dikes and tuffs, and pyroclastic rocks similar to those at other East African alkaline centres. Shombole lavas containing cpx + nepheline + accessory minerals range from perovskite-bearing nephelinites (43% SiO2, volatile-free) to sphene-bearing and phonolitic nephelinites (46–49% SiO2) and phonolites (49–56% SiO2) and have low peralkalinity ([Na+K]/Al 1.15) which does not correlate with SiO2. Early fractionation of olivine and clinopyroxene strongly depleted Ni and Cr concentrations (10 ppm); fractionation of perovskite, melanite, sphene, and apatite produced negative correlations of all REE with SiO2. Many lavas contain cognate intrusive xenoliths and xenocrysts and oscillatory zoning is a common feature of clinopyroxene, nepheline, and melanite crystals, indicating recycling of intrusive material. Irregular calcite-rich bodies in many samples are interpreted as quenched immiscible Ca-carbonatite liquid, and [Ca-carbonate]-silicate liquid immiscibility is observed in experiments with one nephelinite. Chemical variation in the Shombole suite can be modeled as a combination of crystal fractionation (clinopyroxene and heavy minor phases) and retention of neutral density nepheline derived from disaggregated xenoliths entrained during emplacement of dike swarms. Six newly analyzed lavas from Oldoinyo L'engai, northern Tanzania, are geochemically similar to Shombole nephelinites except that they have relatively high Na2O+K2O (average 18% vs 12%) and Zr (average 680 ppm vs 400 ppm). They are extremely peralkaline and are not typical of nephelinites from other centres. Three with [Na+K]/Al1.5 contain euhedral wollastonite phenocrysts; three with [Na+K]/Al2.0 contain combeite (Na2Ca2Si3O9) phenocrysts and pseudomorphs after wollastonite. Both types contain abundant sodalite phenocrysts (+nepheline+clinopyroxene+melanite+sphene). Seven other wollastonite nephelinite samples from L'engai have been described, but it is a lava type rarely seen in other centres. Combeite has been described from only two other locations (Mt. Shaheru, Zaire; Mayener Feld, Eifel). The hyperalkaline L'engai nephelinites have compositions similar to those of experimental silicate liquids immiscible with natrocarbonatite. Textural evidence for both carbonate-silicate (as carbonate globules) and silicate-silicate (as two optically discrete glasses with distinct compositions) liquid immiscibility is observed in the samples. 相似文献
18.
Rare-earth element distribution in the rocks and minerals of the olivinite-clinopyroxenitemelilitolite-melteigite-ijolite-nepheline syenite series was analyzed to study the evolution trends of the alkaline-ultrabasic series of the Kola province. The contents of REE and some other trace elements were determined in olivine, melilite, clinopyroxene, nepheline, apatite, perovskite, titanite, and magnetite. It was established that distribution of most elements in the rocks of the Kovdor, Afrikanda, Vuoriyarvi, and other massifs differ from that in the Khibiny ultrabasic-alkaline series, being controlled by perovskite crystallization. Primary olivine-melanephelinite melts of the minor ultrabasic-alkaline massifs are characterized by the early crystallization of perovskite, the main REE-Nb-Ta-Th-U depository. Precipitation of perovskite simultaneously with olivine and clinopyroxene results in the depletion of residual magma in rare-earth elements and formation of low-REE- and HFSE ijolite and nepheline syenite derivatives. In contrast, the formation of the Khibiny ultrabasic-alkaline series was complicated by mixing of olivine melanephelinite magma with small batches of phonolitic melt. This led to a change in crystallization order of REE-bearing titanates and Ti-silicates and accumulation of the most incompatible elements in the late batches of the melt. As a result, the Khibiny ijolites have the highest REE contents, which are accommodated by high-REE apatite and titanite. 相似文献
19.
青藏高原岩石圈演化的记录：藏北超钾质及钠质火山岩的岩石学与地球化学特征 总被引：56，自引：12，他引：44
藏北鱼鳞山超钾质火山岩为一中等规模的熔岩被, 可分为三期。前两期主要为霞石黝方白榴石响岩、霞石白榴斑岩等, 后期主要为方钠石霓石粗面岩、霓霞粗面岩等。时代为１８～３０ Ｍａ。本区超钾质岩浆 Ｓｉ Ｏ２ 强烈不饱和、强碱性、高度富集 Ｌ Ｒ Ｅ Ｅ及 Ｌ Ｉ Ｌ Ｅ、放射成因 Ｓｒ、 Ｐｂ 及非放射成因 Ｎｄ 同位素 （８６ Ｓｒ／８７ Ｓｒ＝ ０７０８７６６～０７０９１６２, ２０６ Ｐｂ／２０４ Ｐｂ＝ １８８８２８８８～ １９１０４７５１, ２０７ Ｐｂ／２０４ Ｐｂ＝ １５６４２０３７ ～ １５８２８４５８, ２０８ Ｐｂ／２０４ Ｐｂ＝ ３９１３８９２１ ～ ３９６８６８３５ 及１４３ Ｎｄ／１４４ Ｎｄ＝ ０５１２１１６ ～０５１２３４２）,其上述特征指示岩浆源区为受到地壳物质强烈交代的富集 Ｅ Ｍ Ｉ Ｉ型地幔。藏北拉嘎拉钠质碱性橄榄玄武岩为高原面上的剥蚀残丘, 时代为６０ Ｍａ。其岩石学、 Ｒ Ｅ Ｅ、微量元素及 Ｓｒ Ｎｄ Ｐｂ 同位素指示了岩浆源区为受到洋壳俯冲物质交代的轻度富集地幔。本研究结果指示, 羌塘高原南部富集地幔的形成可能是受到印度板块俯冲的影响。 相似文献
20.
AbstractIntermediate orthogranulites were collected on the western flank of the Galicia bank during the Galinaute II cruise in 1995. The petrography of these rocks reveals two types of granulites. The first type is hydrous granulites with K-feldspar + plagioclase + quartz + orthopyroxene + hornblende + garnet + biotite + opaque + zircon + apatite assemblage. Both hornblende and orthopyroxene define a weak foliation plane. A late deformation event is expressed by some fractures cross-cutting the foliation. The second is anhydrous granulites with K-feldspar + plagioclase + quartz + orthopyroxene + clinopyroxene + opaque + zircon + apatite assemblage. The rocks display a granoblastic texture and are affected by brittle deformation as testified by the development of numerous microfractures. The P-T conditions (7 ± 1 Kbar, 750 ± 50 °C) calculated from two representative samples demonstrate that the rocks equilibrated under granulite facies conditions. Ar-Ar dating gives Precambrian ages ranging between ca. 2500–2000 Ma for the amphibole from the hydrous granulite and 1600–1500 Ma for the core of the K-feldspar from the anhydrous and hydrous granulites. A younger age of 900 Ma is obtained from the recrystallized rims of the K-feldspar from the two samples. These data indicate that the granulitic rocks in the Galicia Bank had already been exhumed and cooled below ca. 140–400 °C (blocking T° for K-feldspar) in Precambrian times (900 Ma). Given the very well preserved granulitic minerals assemblage of the rocks, the granulites behaved as competent and metastable boudins during their exhumation. The granulitic samples were previously interpreted as fragments of the lower continental crust sampled by the main detachment fault during Cretaceous rifting, but they were part of an upper continental crust from the Precambrian. Geochronological data and petrological assemblages suggest that the granulite blocks in the Galicia Bank probably were derived from the North Armorican Domain (northern part of France) where a Precambrian terrain outcrops. The opening of the Bay of Biscay could be responsible for the scattering of the Precambrian terrain and may explain the presence of the granulitic blocks on both sides of the Bay of Biscay. During the subduction of Europe below the Iberian peninsula the granulite blocks were transported southward and incorporated into a Cretaceous conglomerate forming the accrecionary prism on the Northern Iberia Margin. The granulite facies blocks found on the Galicia Bank represent another example of Gondwanian relics supporting the idea that the West European plate belonged to the West African craton during the Proterozoic. © 2000 Éditions scientifiques et médicales Elsevier SAS 相似文献