共查询到20条相似文献，搜索用时 15 毫秒
1.
I. A. Nemirovskaya 《Water Resources》2016,43(1):111-120
The presented results have been obtained in a study of the concentrations and composition of aliphatic and polycyclic hydrocarbons in bottom sediments of Volga delta branches and in its shallow zone (2009–2010), as well as the Caspian Sea proper (2010–2013). Oil hydrocarbon pollution has been found to manifest itself mostly in Volga delta branches, which, despite the low concentrations (up to 54.5 μg/g), showed higher hydrocarbons share in Corg (up to 33.8%), while the composition of alkanes suggested their oil genesis. The geochemical barrier the Volga–the Caspian Sea prevents anthropogenic hydrocarbons from entering the open parts of the Caspian. Bottom sediments in the shallow zone of the Northern Caspian, represented by coarse-grained material, are now polluted by oil hydrocarbons to a lesser extent compared with other areas. The highest concentrations of aliphatic hydrocarbons (up to 178 μg/g) were recorded in the deepsea bottom sediments of Derbent Depression and in depressions of the Middle and Southern Caspian. These areas show a higher concentration of Corg (up to 9.884%) and a low concentration of hydrocarbons in Corg (up to 0.16%), while odd high-molecular homologues (n-C25–C31) dominate in the composition of alkanes. 相似文献
2.
I. A. Nemirovskaya 《Water Resources》2012,39(5):533-545
Studies of water, suspension, and sediments of the Volga R. (from Konakovo Town to the delta) showed that at the confluence with tributaries, diffusion and dilution play the major role. Changes in conductivity, Biochemical oxygen demand (BOD5), pH, suspension, chlorophyll a, dissolved and organic carbon, lipids, and hydrocarbons take place mostly under the effect of natural processes. Typical features in the case of summer low-water period are low chlorophyll a, suspension, and BOD5. The accumulation of pollutants takes place in bottom sediments because of an increase in the share of Corg, and hydrocarbons have a petroleum and pyrogenic composition. 相似文献
3.
The concentrations of three groups of organochlorine compounds (HCCH, DDT, and PCB) in bottom sediments, zebra mussel, and
two fish species—zope and roach—in the Volga Pool of the Rybinsk Reservoir. The concentrations of the examined toxicants can
be ranked in the ascending order as follows: HCCH<DDT<PCB. The total concentration of organochlorine compounds (OCC) and their
metabolites are very low, thus allowing the Volga Pool to be regarded as a background region for the Upper and Middle Volga
Basin. A congener-specific determination of PCB was carried out, and priority congeners were identified for monitoring the
ecosystem pollution by dioxin-like compounds. 相似文献
4.
Z. A. Zhakovskaya V. N. Petrova L. O. Khoroshko G. I. Kukhareva A. A. Lukin 《Water Resources》2010,37(1):75-83
The quantitative concentrations of 21 congeners of polychlorinated biphenyls and 16 priority polycyclic aromatic hydrocarbons
were studied in bottom sediments of the Usa River, the largest Pechora’s tributary, and its tributaries located in the central
part of Timan-Pechora petroleum province. In accordance with the classification of the regional and international standards,
the pollution degree of bottom sediments by organic compounds of those classes was evaluated. Pollution profiles were examined
and the character of the dominating source of polychlorinated biphenyls and polycyclic aromatic hydrocarbons for bottom sediments
in the region under study was identified. Key words: bottom sediments, polychlorinated biphenyls, profiles of polycyclic aromatic hydrocarbons, petrogenic, pyrogenic pollution
source. 相似文献
5.
Brekhovskikh V. F. Volkova Z. V. Katunin D. N. Kazmiruk V. D. Kazmiruk T. N. Ostrovskaya E. V. 《Water Resources》2002,29(5):539-547
Heavy metal concentrations in bottom sediment in some reaches of the Upper (the Ivankovo Reservoir) and Lower Volga (from Volgograd to the mouth offshore area). The bottom sediment in the Ivankovo Reservoir are shown to be heavily polluted by Cu and Zn and to a lesser extent, by Co and Ni; heavy pollution with Ni and Cr and moderate pollution with Zn and Mn were recorded in the Lower Volga. Principal component procedure was used to assess bottom sediment pollution. The role of organic matter in the formation of the Ivankovo Reservoir bottom sediment pollution with heavy metals is shown to be moderate because of the weak correlation between heavy metal concentration and organic matter content of bottom sediment. The same is true for the Lower Volga because of low organic matter content of bottom sediment. The major role in the redox cycle of elements is shown to belong to Fe in the Ivankovo Reservoir and Mn in the Lower Volga. 相似文献
6.
Aliphatic and aromatic hydrocarbons in coastal Caspian Sea sediments 总被引：17，自引：0，他引：17
Tolosa I de Mora S Sheikholeslami MR Villeneuve JP Bartocci J Cattini C 《Marine pollution bulletin》2004,48(1-2):44-60
This investigation represents the first extensive study of the spatial distribution and sources of aliphatic (n-alkanes and unresolved complex mixture of fossil hydrocarbons) and polycyclic aromatic hydrocarbons (PAHs) in coastal sediments from the Caspian Sea. PAH concentrations, n-alkanes and biomarker profiles all suggested that there was limited petrogenic contamination in the shallow North Caspian Sea sediments, which are coarse with a low total organic carbon content. In contrast, moderate to high petrogenic contamination was found in the South Caspian Sea, in particular in the offshore oil fields near Baku, Azerbaijan. Contaminant patterns indicated that the PAHs were mainly from fossil sources, with higher contributions of pyrolytic only near industrialized and urban areas. A high contribution of perylene, a geochemically derived PAH, to the total PAHs was found in the west and south at sites influenced by the Kura, Safid Rud, Terek, Sulak and Samur Rivers. 相似文献
7.
Long-term observational data are used to compare and analyze time and space variations in the concentrations of nutrients in the water of major rivers flowing into the Caspian Sea and assess the nutrients runoff into the sea. Annual variations in the normal monthly values of river runoff and nutrient compound concentrations and input into the sea are considered (18 compounds and considered for the Volga, Ural, Terek, Sulak, and Samur, and 7 compounds are considered for the Kura). The Volga contribution to nutrient input into the sea is found to vary from 77 to 94% with the average of 86%. 相似文献
8.
Water Resources - New data on the contents of plant pigments and organic matter in bottom sediments of channel, floodplain and estuarine biotopes of the Gorky Reservoir (upstream Volga, Russia) are... 相似文献
9.
Organochlorine compounds in bottom sediments of a delta branch of the Northern Dvina have been studied. Data on the concentration and distribution of organically bound chlorine are given. The specific features of the formation of the levels and profiles of chlorinated phenolic compounds in bottom sediments under the effect of specific primary and secondary sources in the territory of Arkhangelsk Industrial Center are demonstrated. 相似文献
10.
M. V. Isupova 《Water Resources》2008,35(6):615-634
Long-term water level variations in the Volga mouth area and the effect exerted on them by the river’s flow and the Caspian Sea’s level variations are considered. Quantitative relationships were identified between the mean annual water levels at different gages in the mouth and the sea level. A backwater component was isolated in the long-term variations in water level in the Volga mouth area. Relationships between the daily water levels in the mouth and the Caspian Sea’s level at fixed water flow in the delta apex are presented. The magnitude and the propagation distance of backwater from the sea into the delta are specified. The responses of the mouth areas of rivers emptying into the Caspian Sea to sea level variations in the past century are compared. 相似文献
11.
Hung CC Gong GC Ko FC Lee HJ Chen HY Wu JM Hsu ML Peng SC Nan FH Santschi PH 《Marine pollution bulletin》2011,63(5-12):464-470
This study measured concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface sediments in the East China Sea (ECS) to investigate possible sources and fate of PAHs. Total concentration of PAHs in the sediments of the ECS ranged from 22 to 244 ng g(-1), with the highest levels in the coastal area and outer shelf. The observed PAH results showed elevated levels in both inner and outer shelf areas, a finding that is different from predictions by an ocean circulation model, suggesting that terrestrial sources are important for PAH contaminations in the ECS, while sediment resuspension, tidal changes and lateral transport may be important in affecting the distribution of PAHs in the outer shelf. The distribution of PAHs in the surface sediments of the ECS is similar to the distribution of carbonaceous materials (e.g., particulate organic carbon and black carbon), suggesting that carbonaceous materials may strongly affect the distribution of PAHs. 相似文献
12.
Polychlorinated biphenyls and organochlorine pesticides in bottom sediments of the Irkutsk Reservoir
The concentrations of organochlorine pesticides (HCCH, DDT, and HCB) and 34 congeners of polychlorinated biphenyls were studied in bottom sediments of the Irkutsk Reservoir, the first in the Angara Chain of Reservoirs. The degree of pollution of bottom sediments was evaluated in accordance with classifications of regional and international standards. A correlation was found to exist between the distribution of some organic compounds and organic carbon concentration. 相似文献
13.
The distribution of oil hydrocarbons in bottom sediments of Onega Lake was examined. Their qualitative and quantitative composition was examined by methods of IR-spectroscopy and chromatography-mass spectrometry. The background concentrations of oil hydrocarbons in bottom sediments are evaluated and the polluted area is determined. The major regularities in oil hydrocarbon transformations under natural conditions and anthropogenic impact are identified. The quantitative development of the bacterial groups that take part in the transformation of complex organic substances and oil product derivatives in the case of emergency pollution of Petrozavodsk Bay water area by oil products is demonstrated. 相似文献
14.
A close negative correlation was found to exist between oxygen concentration in winter and the latitude in rivers in the basins
of the Ob and Volga. This can be explained by an increase in the duration of the freeze-up period (during which oxygen is
consumed for oxidation of organic matter (OM) in water and bottom sediments) in the direction from the south to the north,
while the input from oxygen from the atmosphere and photosynthesis is practically zero. No inverse relationship was found
to exist between dissolved oxygen and the latitude, because in rivers of mountain and semimountain types, typical of this
basin, organic matter (OM) does not accumulate in bottom sediments and the conditions of atmospheric circulation are better
than in lowland rivers. The magnitude of seasonal variations in oxygen in lowland rivers is greater than in mountain ones
because of an abrupt drop in oxygen concentration in slowly flowing rivers in winter and the saturation of their water by
oxygen from photosynthesis in summer. 相似文献
15.
M. V. Martynova 《Water Resources》2008,35(3):339-345
Examples of the impact of the content of organic matter and compounds of Al and Fe in freshwater sediments on the phosphorus release from the bottom are studied. The relationships between the phosphorus release from bottom sediments and organic matter concentration in sediments of 22 lakes of the world are obtained and discussed as a result of generalization of actual data. 相似文献
16.
《Marine pollution bulletin》2012,64(5-12):464-470
This study measured concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface sediments in the East China Sea (ECS) to investigate possible sources and fate of PAHs. Total concentration of PAHs in the sediments of the ECS ranged from 22 to 244 ng g−1, with the highest levels in the coastal area and outer shelf. The observed PAH results showed elevated levels in both inner and outer shelf areas, a finding that is different from predictions by an ocean circulation model, suggesting that terrestrial sources are important for PAH contaminations in the ECS, while sediment resuspension, tidal changes and lateral transport may be important in affecting the distribution of PAHs in the outer shelf. The distribution of PAHs in the surface sediments of the ECS is similar to the distribution of carbonaceous materials (e.g., particulate organic carbon and black carbon), suggesting that carbonaceous materials may strongly affect the distribution of PAHs. 相似文献
17.
The Late Quaternary history of the Caspian Sea remains controversial. One of the major disagreements in this debate concerns the stratigraphic correlation of various deposits in the Caspian Basin. In this paper we identify and date, for the first time, the Enotaevka regression, lying between the two major phases of the largest Late Quaternary Caspian Sea transgression, the Khvalynian transgressive epoch, and provide a minimum estimate of sea level decrease during this regression. The River Volga is the major source of water to the Caspian; the Lower Volga region is unique in its record of palaeogeographic events, and this provides the opportunity to build a single stratigraphic and palaeogeographic history for the Pleistocene of Central Eurasia. Here we use luminescence to establish a new chronology for the largest Late Quaternary transgressive epoch of the Caspian Sea. The existing radiocarbon chronology does not allow the resolution of the two transgressive phases of this epoch (Early and Late Khvalynian). Based on clear palaeontological and geomorphological evidence, these must be very different in age, but shells associated with both transgressions gave very scattered ages of between 8 and 50 ka. This ambiguity has led to considerable discussion concerning the existence or otherwise of a deep Enotaevka regression phase between the two Khvalynian transgressions. Recently we have again identified these deposits at Kosika, on the right valley side of the Volga River. The new luminescence chronology described here, based on quartz OSL and K-feldspar pIRIR290 ages, allows us to reconstruct the complicated history of Late Quaternary sedimentation in the southern part of the Lower Volga valley. The Kosika section reflects the following major stages: (1) the earlier Khazarian transgressive epoch; (2) a decrease in the sea level with the development of a freshwater lake/lagoon in the Volga valley; and (3) the Khvalynian transgressive-regressive epoch, including both the Early and Late Khvalynian transgressive periods, and the intercalated Enotaevka regression. Sea level during the early stage of the Khvalynian transgression reached Kosika at about 23–22 ka (approx. −1 to −2 m asl). This event is of the same age as the “grey clay” strata at the base of the Leninsk section marine unit (Kurbanov et al., 2021), also formed at the beginning of the Early Khvalynian transgression. Around 15–14 ka the Khvalynian basin moved to a regressive stage, and in the northern part of the Lower Volga the top part of the well-known ‘Chocolate Clay’ accumulated. In the southern part of the valley marine accumulation stopped at about 12–13 ka. This allows us to reconstruct a decrease in Early Khvalynian basin sea level between 15–14 ka and 13–12 ka ago, of about ∼15 m. At the Kosika section sediments derived from the Enotayevka regression are visible as a weakly developed palaeosol with evidence of surficial erosion, and these sediments are now dated to 13–12 ka. At 8.6 ± 0.5 ka, during the period of the Mangyshlak regression, aeolian deflation processes reworked sediments deposited by immediately preceding Late Khvalynian transgression. 相似文献
18.
The development of oil and gas recovery offshore of the Mississippi River delta began in shallow water in the 1950s, expanded into deeper waters, and peaked in the 1990s. This area of the outer continental shelf (OCS) is the historical and present location of >90% of all US OCS oil and gas production and reserves. The juxtaposition of its 4000 producing platforms, recovering $10 billion yr(-1) of oil, gas and produced water in the same area where about 28% of the US fisheries catch (by weight) is made and near 40% of the US coastal wetlands, makes this an area worth monitoring for regional pollutant loading. This loading may come from several sources, including sources related to OCS development, but also from the Mississippi River watershed. In this context, any contaminant loading on this shelf may be neither detectable nor significant against a background of climatic or biological variability. We examined the sedimentary record for indicators of industrial byproducts from OCS oil and gas development and of industrial products entering via the Mississippi River, primarily using vanadium (V) and barium (Ba) concentrations normalized for aluminum (Al). Barium is primarily used in drilling muds in the form of barite, whereas V is an important strengthening component of metal alloys, including steel. The fluctuations in the accumulation of Ba, but not V, were coincidental with the presumed use of barite. The fluctuations in V concentration in the sediments were coincidental with the national consumption of V. Copper (Cu), cadmium (Cd) and zinc (Zn) concentrations in sediments fluctuate coincidentally with V, not Ba, thus indicating that the dominant source of these trace metals in offshore sediments were derived from riverine sources, and were not primarily from in situ industrial processes releasing them on the shelf. This is not to suggest that local site-specific contamination is not a significant management or health concern. The low oxygen (hypoxia; < or = 2 mg l(-1)) zone that consistently covers much of this continental shelf's bottom layer in summer is attributed to nitrate loading from the Mississippi River. Increased nitrogen loading from river to shelf stimulates diatom production whose loading to the bottom layer and subsequent metabolism results in oxygen being depleted faster than it is replaced. In the last two decades there has been an increased accumulation of organic matter in sediments near the mouth of the Mississippi River. This coupling between river water, surface water and bottom water has recently expanded westward of the Atchafalaya River delta towards the Texas coast. The accumulation of biogenic silica (BSi) and carbon in dated sediments is coincidental with variations in riverine nitrate flux, but not with either V or Ba accumulation rates. These analyses indicate that both OCS development and riverine sources exert strong influences on the sediment constituents offshore, and that these influences may be independent of one another. 相似文献
19.
The results of determinations of macro- and microelement concentrations (Mn, Fe, Ba, Sr, Rb, Si, Pb, and U) in the interstitial water in four cores of bottom sediments sampled in the deep-water areas of the Southern and Middle Caspian Sea are compared with the concentrations of these elements in the free water of the Caspian Sea. The data obtained amplify the present-day concept on the geochemical and ecological states of the sea. 相似文献
20.
Troy P. Sampere Thomas S. Bianchi Stuart G. Wakeham Mead A. Allison 《Continental Shelf Research》2008,28(17):2472-2487
Lignin and pigment biomarkers were analyzed in surface sediments of the Louisiana Continental margin (LCM) to distinguish differences in the degradative state of sedimentary organic matter along and between two major depositional pathways (along shore and offshore to the Mississippi Canyon) from Southwest (SW) Pass in July 2003. Barataria Bay, an inter-distributary estuary, was also assessed as a potential source of terrestrial organic matter to the LCM. Sediment signatures taken along the same pathways after Hurricane Ivan (October 2004) were compared with the pre-Ivan signature to elucidate carbon dynamics after major hurricane events. Density fractions were investigated at key stages across the LCM. Mississippi Canyon sediments are a depocenter for labile and refractory organic matter derived from river and previously deposited shelf sediments. Barataria Bay material may be a contributing source of sedimentary organic matter in shallow shelf areas bordering the bay and is thus potentially important in carbon cycling in sediments of these shallow areas; however, our results show that organic matter inputs from the bay were likely rapidly decomposed and/or diluted. Hurricane Ivan mobilized sedimentary organic carbon (SOC) offshore and homogenized terrestrial sediment parameters and gradients. As observed through pigment concentrations sediments tended to equilibrate to a more steady-state condition within months of the disturbance. Insights from density fractions show that selective degradation and aggregation/flocculation processes were also very important processes during cross-shelf transport. Zooplankton grazing, largely on diatoms and other algae, was a shelf wide phenomenon, however, grazing products dominated the marine-derived SOC in margin sediments west of the birdsfoot delta indicated by the abundance of steryl chlorin esters (SCEs). 相似文献