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1.
The Changjiang uranium ore field, which contains >10,000 tonnes of recoverable U with a grade of 0.1–0.5%, is hosted by Triassic two-mica and Jurassic biotite granites, and is one of the most important uranium ore fields in South China. The minerals associated with alteration and mineralization can be divided into two stages, namely syn-ore and post-ore. The syn-ore minerals are primarily quartz, pitchblende, hematite, hydromica, chlorite, fluorite, and pyrite; the post-ore minerals include quartz, calcite, fluorite, pyrite, and hematite. The fluid inclusions of the early syn-ore stage characteristically contain O2, and those of the late syn-ore and post-ore stage contain H2 and CH4. The fluid inclusions in quartz of the syn-ore stage include H2O, H2O–CO2, and CO2 types, and they occur in clusters or along trails. Homogenization temperatures (Th) for the H2O–CO2 and two-phase H2O inclusions range from 106 °C to >350 °C and cluster in two distinct groups for each type; salinities are lower than 10 wt% NaCl equiv. The ore-forming fluids underwent CO2 effervescence or phase separation at ∼250 °C under a pressure of 1000–1100 bar. The U/Th values of the altered granites are lowest close to the ore, increase outwards, but subsequently decrease close to unaltered granites. From the unaltered granites to the ore, the lowest Fe2O3/FeO values become lower and the highest values higher. The REE patterns of the altered granites and the ores are similar to each other. The U contents of the ores show a positive correlation with total REE contents but a negative correlation with LREE/HREE ratios, indicating the pitchblende is REE-bearing and selectively HREE-rich. The δEu values of the ore show a positive correlation with U contents, indicating the early syn-ore fluids were oxidizing. The δCe values show a negative correlation, indicating the later mineralization environment became reducing. The water–rock interactions of the early syn-ore stage resulted in oxidization of altered granites and reduction of the ore-forming fluids, and it was this reduction that led to the uranium mineralization. During alteration in the early syn-ore stage, the oxidizing fluids leached uranium from granites close to faults, and Fe2O3/FeO ratios increased in the alteration zones. The late syn-ore and post-ore alteration decreased the Fe2O3/FeO ratios in the alteration zones. The δ18OW–SMOW values of the ore-forming fluids range from −1.8‰ to 5.4‰, and the δDW–SMOW values range from −104.4‰ to −51.6‰, suggesting meteoric water. The meteoric water underwent at least two stages of water–rock interaction: the first caused the fluids to become uranium-bearing, and the second stage, which was primarily associated with ore-bearing faults, led to uranium deposition as pitchblende, accompanied by CO2 effervescence.  相似文献   

2.
The Hanjiang River, the largest tributaries of the Changjiang (Yangtze) River, is the water source area of the Middle Route of China’s South-to-North Water Transfer Project. The chemical and strontium isotopic compositions of the river waters are determined with the main purpose of understanding the contribution of chemical weathering processes and anthropogenic inputs on river solutes, as well as the associated CO2 consumption in the carbonate-dominated basin. The major ion compositions of the Hanjiang River waters are characterized by the dominance of Ca2+ and HCO3 −, followed by Mg2+ and SO4 2−. The increase in TDS and major anions (Cl−, NO3 −, and SO4 2−) concentrations from upstream to downstream is ascribed to both extensive influences from agriculture and domestic activities over the Hanjiang basin. The chemical and Sr isotopic analyses indicate that three major weathering sources (dolomite, limestone, and silicates) contribute to the total dissolved loads. The contributions of the different end-members to the dissolved load are calculated with the mass balance approach. The calculated results show that the dissolved load is dominated by carbonates weathering, the contribution of which accounts for about 79.4% for the Hanjiang River. The silicate weathering and anthropogenic contributions are approximately 12.3 and 6.87%, respectively. The total TDS fluxes from chemical weathering calculated for the water source area (the upper Hanjiang basin) and the whole Hanjiang basin are approximately 3.8 × 106 and 6.1 × 106 ton/year, respectively. The total chemical weathering (carbonate and silicate) rate for the Hanjiang basin is approximately 38.5 ton/km2/year or 18.6 mm/k year, which is higher than global mean values. The fluxes of CO2 consumption by carbonate and silicate weathering are estimated to be 56.4 × 109 and 12.9 × 109 mol/year, respectively.  相似文献   

3.
The chemical and isotopic characteristics of the water and suspended particulate materials(SPM)in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007.TheδD andδ~(18)O values of the Yellow River water vary in large ranges from-32‰to-91‰and from-3.1‰to-12.5‰,respectively.The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water,and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity.The average SPM content(9.635g/L)of the Yellow River is the highest among the world large rivers.Compared with the Yangtze River,the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates.In comparison to the upper crust rocks,the Yellow River SPM contains less SiO_2,CaO,K_2O and Na_2O,but more TFe_2O_3,Co,Ni,Cu,Zn,Pb and Cd.The abnormal high Cd contents found in some sample may be related to local industrial activity.The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale.The averageδ~(30)Si_(SPM)in the Yellow River(-0.11‰)is slightly higher than the average value(-0.22‰)of the Yangtze River SPM.The major factors controlling theδ~(30)Si_(SPM)of the Yellow River are the soil supply,the isotopic composition of the soil and the climate conditions.The TDS in the Yellow River are the highest among those of world large rivers.Fair correlations are observed among Cl~-,Na~+,K~+,and Mg~(2+)contents of the Yellow River water,indicating the effect of evaporation.The Ca~(2+)and Sr~(2+)concentrations show good correlation to the SO_4~(2-)concentration rather than HCO_3~-concentration,reflecting its origin from evaporates.The NO_3~-contents are affected by farmland fertilization.The Cu,Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers,reflecting the effect of human activity.The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River.Theδ~(30)Si values of the dissolved silicon vary in a range from 0.4‰to 2.9‰,averaging1.34‰.The major processes controlling the D_(Si)andδ~(30)Si_(Diss)of the Yellow River water are the weathering process of silicate rocks,growth of phytolith in plants,evaporation,dissolution of phytolith in soil,growth of fresh water diatom,adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities.The averageδ~(30)Si_(Diss)value of the Yellow River is significantly lower than that of the Nile River,Yangtze River and Siberia rivers,but higher than those of other rivers,reflecting their differences in chemical weathering and biological activity.Theδ~(34)S_(SO4)values of the Yellow River water range from-3.8‰to 14.1‰,averaging 7.97‰.There is some correlation between SO_4~(2-)content andδ~(34)S_(SO4).The factors controlling theδ~(34)S_(SO4)of the Yellow River water are the SO_4 in the meteoric water,the SO_4 from gypsum or anhydrite in evaporite rocks,oxidation and dissolution of sulfides in the mineral deposits,magmatic rocks and sedimentary rocks,the sulfate reduction and precipitation process and the sulfate from fertilizer.The~(87)Sr/~(86)Sr ratios of all samplesrange from 0.71041 to 0.71237,averaging 0.71128.The variations in the~(87)Sr/~(86)Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different~(87)Sr/~(86)Sr ratios and Sr contents resulting from water-rock interaction with different rock types.  相似文献   

4.
The abandoned Sn-W Ribeira mine, northeast of Portugal, contained quartz veins with cassiterite, wolframite, scheelite, pyrite, arsenopyrite, sphalerite, chalcopyrite, manganocolumbite, bismuthinite, native bismuth, phosphates and carbonates. The exploration took place on the northern slope of the Viveiros stream, which is an affluent of the Sabor River. The waste-rock dumps and tailings were deposited on the hillside, close to the mine and are nowadays exposed to significant weathering and erosion, as they are not vegetated. The eroded material is transported by the Viveiros stream toward the Sabor River. A seasonal stream drains the tailings. The stream sediments samples were collected along the Viveiros stream, in the seasonal stream, in a seasonal spring at the bottom of the tailings, in the Sabor River and in other streams not affected by mine workings, following the mine influence along the Viveiros stream and in the Sabor River (1.2 km away from the mine workings). The data show that the degree of pollution increases along the Viveiros stream, especially in winter. The highest degree of pollution is for As, In, W, Sn and Bi. The sediments from the drainage of the main tailings are particularly polluted during winter, by Bi, In and Sn. The sedimentary precipitate from the spring is polluted in Cu, As, In, Sn, Ta, W, Bi, Zn, Nb, Ag, Sb and Ta. The sediments from the Sabor River are significantly polluted by As, Ag, In, Sn, W and Bi. The sediments from the regional streams, Viveiros stream and Sabor River have similar REE (NASC normalized) patterns (ΣREE = 131.7–185.9 mg/kg, LaN/LuN = 1.23–1.42 and Eu/Eu* = 1.02), while those from the seasonal stream, crossing the main tailings, are enriched in REE (ΣREE = 250.3–283.6 mg/kg, LaN/LuN = 1.6–2.09 and Eu/Eu* = 0.96). The general decrease in LaN/LuN values with increase in total Fe2O3 can be explained by the partitioning of HREE to the solid Fe-oxides phase. The sedimentary precipitate and coatings, which are mainly formed by Fe-oxy-hydroxides, but also contain jarosite, are impoverished in all REE. The impoverishment can be explained by the release of REE from the surface of the Fe-oxy-hydroxides, which occurs due to a local lowering of pH, caused by jarosite dissolution. During successive alternate cycles of wet and dry conditions, takes place the formation of Fe-oxy-hydroxides and jarosite in the sedimentary precipitate and coatings. The subsequent dissolution of jarosite releases acidity, thus promoting de-sorption of REE from the Fe-oxy-hydroxides mineral phases.  相似文献   

5.
The fine structure of the region of formation of a protostar in the dense molecular cloud OMC-1 of the Orion Nebula was studied during a period of enhanced activity in 1998–1999, with an angular resolution of 50 μas and a velocity resolution of Δv = 0.053 km/s. Inclusions of ice granules in the bipolar outflow were detected and identified. The velocity of the outflow reaches ∼50 km/s, while that of the granules is <5 km/s. The outflow sublimates and accelerates H2O molecules, thereby exciting the maser emission. As a result, their relative velocity and, accordingly, pumping level decrease. The maser emission of the outflow is observed at distances out to ρ < 3 mas, or <1.5 AU. However, in the distant part (ρ > 5 mas), bullets corresponding to maser emission excited by the outflow in the surrounding medium are observed. The emission is amplified by the external medium at a velocity of v LSR = 7.65 km/s in the bandwidth Δ v ≈ 0.5 km/s. The sources of pumping are clusters of infrared sources. The bipolar outflow is inclined at a small angle to the plane of the sky. The acceleration of the maser inclusions also increases the longitudinal component of the velocity, reducing amplification of the emission. The brightness temperature of the components decreases: T b ∼ ρ −0.8±0.1. The activity terminates with the exponential decline of the maser emission, F ∼ exp(−0.5t 2); in the saturated mode this is determined by a decrease in the optical depth, τ ∼ t 2. The material of the surrounding space, including the ice granules, is drawn into the disk, moves along spirals toward the nozzle, and is ejected as a highly collimated bipolar flow. The density of material in the outflow exceeds the surrounding density by three to four orders of magnitude. The accretion of the surrounding material and ejection of the bipolar outflow are a unified process accompanying the initial phase of formation of protostars. The counter motion of material at the center stimulates the formation of a central massive object, whose gravitational field accelerates the process and stabilizes the system. The ratio of the durations of periods of high and low activity is determined by the rates of ejection and disk replenishment, and is ∼1:10. The rotating bipolar flow is self-focused.  相似文献   

6.
The Permian system of the Palaeozoic Erathem is divided into three series, the Early Permian Cisuralian Series, the Middle Permian Guadalupian Series, and the Late Permian Lopingian Series. The Cisuralian Series encompasses the Asselian to Kungurian stages which constitute the basal part of the Gondwana supersequence I. In India, they are represented lithostratigraphically by the Talchir, Karharbari, and Barakar formations. This paper presents the palynological results from the Barakar Formation of the Upper Cisuralian Series from Manuguru which lies in the southeastern part of the Godavari basin. The succession studied comprises 35 subsurface samples from bore hole 1007 represented by clay, shale, sandstone, and coal. The palynofloras in this sequence have a homogenous composition demonstrating that not many significant floral changes took place through the considered stratigraphic range. The entire sequence is characterized by the dominance of nonstriate bisaccate genus Scheuringipollenites and sub-dominance of striate bisaccate genus Faunipollenites(=Protohaploxypinus). The other pollen genera among the nonstriate bisaccates are Rhizomaspora, Primuspollenites, Ibisporites, and Platysaccus. The striate bisaccates include Striatites, Striatopodocarpites, and Stroterosporites. The taeniate taxa are represented by Lueckisporites and Lunatisporites. The common monosaccate genera include Caheniasaccites, Potoniesporites, and Barakarites. Spores are less common and include Latosporites, Brevitriletes, Horriditriletes, Microbaculispora, and Callumispora. They characterize the palynofloral composition of the Lower Barakar Formation. The correlation of this assemblage with some of the biostratigraphic palynozones proposed previously for the Cisuralian sequences of the Paraná Basin of South America, Kalahari Karoo Basin of South Africa, Ruhuhu Basin of Tanzania, East Africa as well as palynoassemblages from South Victoria Land and Dronning Maud Land, Antarctica and Collie Basin of west Australia point out to their Early Permian (Late Sakmarian–Early Artinskian) age. Palynomorphs such as Botryococcus sp., Tetraporinia sp., Balmeela sp. and Leiosphaeridia sp. are also recorded which suggest that these sediments were deposited during post-glacial near shore, cool and humid environment.  相似文献   

7.
The distribution and partitioning of trace metals (Co, Cu, Fe, Mn, Ni, and Zn) between dissolved and particulate phases were studied in the Tanshui Estuary. The upper reach of the estuary is hypoxic and heavily polluted due to domestic and industrial discharges. The concentration ranges of dissolved and leachable particulate trace metals in the Tanshui Estuary were: Co: 0.3–6.1 nM, 1.8–18.6 mg kg−1; Cu: 5–53 nM, 22–500 mg kg−1; Fe: 388–3,364 nM, 1.08–6.67%; Mn: 57–2,914 nM, 209–1,169 mg kg−1; Ni: 7–310 nM, 6–108 mg kg−1; and Zn: 12–176 nM, 62–1,316 mg kg−1; respectively. The dissolved concentrations of the metals were 2–35 times higher than the average values of the world river water. The distributions of dissolved and particulate studied metals, except Mn, in the estuary showed scattering, which could be attributed to the discharges from many industrial wastewater disposal works located in the upper tributaries. The daily input of dissolved metals from the disposal works to the Tanshui Estuary ranged from 0.1–0.4 tons. Dissolved Mn was nearly conservative in the region with salinity higher than 10 psu, while particulate Mn decreased in the region with salinity of 10–15 psu. The concentration increased significantly seawards, corresponding with the distribution of dissolved oxygen. The distribution coefficient (KD) for Mn in the lower estuary was nearly three orders of magnitude higher than in the upper estuary. This phenomenon may be attributed to the diffusion of Mn from the anoxic sediment in the upper estuary and gradual oxidation into particulate Mn in the middle and lower estuary as the estuarine water became more oxygenated. The distribution coefficient for Cu decreased with increasing salinity. The percentages of trace metals bound by suspended particulate matter decreased in the following order: Fe>Zn, Cu>Co>Mn>Ni.  相似文献   

8.
The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pale-yellow coarse grain, low Fe sphalerite, pyrite with pits, barite and biotite. The mineral assemblages of hydrothermal stage II are black-brown cryptocrystalline, high Fe shalerite, pyrite without pits, marcasite or arsenopyrite replace the pyrite with pits, K-feldspar. The features of hydrothermal stage III are calcite-quartz-sulfide vein cutting the laminated, banded ore body. Forty-two sulfur isotope analyses, twenty-five lead isotope analyses and nineteen carbon and oxygen isotope analyses were determined on sphalerite, pyrite, galena and calcite. The δ34 S values of stage I(20.3 to 29.0‰) are consistent with the δ34 S of sulfate(barite) in the stratum. Combined with geological feature, inclusion characteristics and EPMA data, we propose that TSR has played a key role in the formation of the sulfides in stage I. The δ34 S values of stage II sphalerite and pyrite(15.1 to 23.0‰) are between sulfides in the host rock, magmatic sulfur and the sulfate(barite) in the stratum. This result suggests that multiple S reservoirs were the sources for S2-in stage II. The δ34 S values of stage III(13.1 to 22‰) combined with the structure of the geological and mineral features suggest a magmatic hydrothermal origin of the mineralization. The lead isotope compositions of the sulfides have 206 Pb/204 Pb ranging from 17.9480 to 17.9782, 207 Pb/204 Pb ranging from 15.611 to 15.622, and 208 Pb/204 Pb ranging from 38.1368 to 38.1691 in the three ore-forming stages. The narrow and symmetric distributions of the lead isotope values reflect homogenization of granite and mantle sources before the Pb-Zn mineralization. The δ13 CPDB and δ18 OSMOW values of stage I range from-0.1 to 2.4‰ and from 18.8 to 21.7‰. The values and inclusion data indicate that the source of fluids in stage I was the dissolution of marine carbonate. The δ13 CPDB and δ18 OSMOW values of stage II range from-4 to 1‰ and from 12.3 to 20.3‰, suggesting multiple C-O reservoirs in the Changba deposit and the addition of mantle-source fluid to the system. The values in stage III are-3.1‰ and 19.7‰, respectively. We infer that the process of mineralization involved evaporitic salt and sedimentary organic-bearing units interacting through thermochemical sulfate reduction through the isotopic, mineralogy and inclusion evidences. Subsequently, the geology feature, mineral assemblages, EPMA data and isotopic values support the conclusion that the ore-forming hydrothermal fluids were mixed with magmatic hydrothermal fluids and forming the massive dark sphalerite, then yielding the calcite-quartz-sulfide vein ore type at the last stage. The genesis of this ore deposit was epigenetic rather than the previously-proposed sedimentary-exhalative(SEDEX) type.  相似文献   

9.
The aim of the study is to assess the natural background radiation in and around Rameswaram Island. In this context, samples were collected to measure the gamma radiations of 238U, 232Th, and 40K using NaI(Tl) detector-based gamma ray spectrometer. The average activity concentrations of 238U, 232Th, and 40K are noted to be well below the world average values. The calculated absorbed dose rate, radium equivalent activity, and hazard index values were below the prescribed limit. The grain size of the sediment was analyzed following Trefethen’s nomenclature, and its correlation with the natural background radioactivity was studied. The sample that contained clay show elevated activity of 40K. The percentage of heavy minerals shows concomitant variation in natural radioactivity, especially in the activity of 238U and 232Th.  相似文献   

10.
The fault-bounded Bolívar Ultramafic Complex (BUC) onthe eastern fringes of the Western Cordillera of Colombia wastectonically accreted onto the western coast of South Americain the late Cretaceous–early Tertiary, along with pillowbasalts of the Caribbean–Colombian Oceanic Plateau (CCOP).The complex consists of a lower sequence of ultramafic cumulates,successively overlain by layered and isotropic gabbroic rocks.The gabbros grade into, and are intruded by, mafic pegmatitesthat consist of large magnesiohornblende and plagioclase crystals.These pegmatites yield a weighted mean 40Ar–39Ar step-heatingage of 90·5 ± 0·9 Ma and thus coincidewith the timing of peak CCOP volcanism. The chemistry of theBUC is not consistent with a subduction-related origin. However,the similarity in Sr–Nd–Pb–Hf isotopes betweenthe CCOP and the BUC, in conjunction with their indistinguishableages, suggests that the BUC is an integral part of the plume-derivedCCOP. The parental magmas of the Bolívar complex wereprobably hydrous picrites that underwent 20–30% crystallization.The residual magmas from this fractionation contained  相似文献   

11.
The adsorptive removal of Cr(VI) was studied using activated carbon derived from Leucaena leucocephala (ACLL). The physico-chemical properties of ACLL were determined using proximate analysis and N2 BET surface area analysis. The N2 BET surface area of ACLL was determined to be 1131 m2 g?1. The point of zero charge (pHpzc) of 5.42 indicated that ACLL surface was positively charged for pH below the pHPZC, attracting anions. The effect of experimental operating parameters such as time of contact, ACLL dose, pH, initial concentration and temperature was investigated. The optimum values of parameters such as concentration of 100 mg L?1, 300 mg of ACLL dose, time of contact of 60 min, pH of 4 indicated the maximum Cr(VI) uptake of 13.85 mg g?1. The pseudo-second-order kinetic model best fitted with the Cr(VI) adsorption data. Adsorptive removal of Cr(VI) onto ACLL satisfactorily fitted in the order of Redlich–Peterson > Freundlich > Langmuir > Temkin adsorption isotherm model. The thermodynamic parameters showed the adsorption of Cr(VI) onto ACLL was an endothermic and spontaneously occurred process.  相似文献   

12.
The chromites from the alpine type ultramafic intrusive of Sukinda, India, display a typical partly inverse spinel form and occur in two distinct zones: Brown Ore Zone (BOZ) and Grey Ore Zone (GOZ). The host ultramafites are mostly altered and are represented by the serpentinite, tremolite-talc(chlorite) schist, talc-serpentine schist and chlorite rock. The less altered variants are dunite, harzburgite and websterite. A dyke of orthopyroxenite runs through the main ultramafic body.The composition of olivine (Fo92), orthopyroxene (En92–89) and Al2O3 contents of the parental liquid (10.40–11.45%) determined from chromites, suggest that the parent melt is of boninitic affinity. The chemical plot of TiO2 content against cr# of chromites corroborates a boninitic parental melt. The Fe–Mg partitioning in olivine and chromite depicts the temperature for chromitites as 1200 °C. A compositional plot of mg# and cr# suggests crystallization at high pressure conditions, corresponding to the kimberlite xenolith field. From the P–T diagram of pyrolite melting and mineral assemblage, the pressure of crystallization is stipulated to be ≥1.2 GPa. The fO2 values estimated from Fe3+/Cr+Al+Fe3+ ratios range from 10−8.3 to 10−9.3 for the GOZ and 10−7.1 to 10−7.3 for the BOZ. The fO2 values together with the pressure range suggest crystallization at upper mantle conditions. The heterogeneity in chemical composition and fO2 conditions for the GOZ and BOZ could be linked to heterogeneity in the upper mantle.  相似文献   

13.
The Carajás region, located in the southeastern part of the Amazon Craton, has been considered one of the most important mineral provinces in the world. The Serra do Rabo Granite (SRG) crops out near the eastern termination of the Carajás fault as two granite stocks, elongated approximately in an E–W direction, concordant with the regional structures. Leucomicrocline granite, hornblende–microcline granite, biotite–hornblende–microcline granite, hornblende syenogranite, and subordinate aplite are identified. The granites are grayish pink and coarse to medium grained and have mainly hypidiomorphic granular texture. Granophyric textures are common. The accessory minerals are ilmenite, apatite, zircon, allanite, and rare pyroxene.The SRG rocks are either massive or foliated, with a slightly anastomosed continuous S1 foliation (E–W/subvertical) outlined by the preferred orientation of quartz, feldspars, and mafic minerals. Locally, decimeter- to meter-wide mylonite/ultramylonite bands (S1m) occur along the E–W foliation. The S1 foliation was developed under higher temperatures than those of the S1m mylonite foliation. The SRG structural evolution was controlled by progressive deformation under decreasing temperature, indicative of syntectonic emplacement. The SRG also has relatively high SiO2, K2O, and Na2O contents; high FeO*/(FeO*+MgO) ratios; high Zr, Ba, Nb, and Ga; and very high rare-earth element contents. The chemical signature is moderately alkaline and metaluminous, comparable to that of the A-type, A2, and ALK-3 granites. The origin of the SRG magmas may be related to the partial melting of crustal sources, such as previously metamorphosed calc-alkaline granites.The SRG crosscuts supracrustal rocks, promoting low-pressure/high-temperature metamorphism. The interaction between regional compressive stresses and the ballooning effect of the granite stocks promoted slight aureole flattening and rheological changes in the supracrustal rocks. The U–Pb zircon age of 2743±1.6 Ma is interpreted as the age of zircon crystallization, granite stock emplacement, and regional horizontal shortening. Other 2.7 Ga syntectonic alkaline granites (e.g. Estrela, Plaquê, Planalto) have been reported in the region.  相似文献   

14.
The study presents the results of Cu, Pb, Zn, Mn and Fe determination in the samples of bottom sediments collected from the Oder and Warta rivers. The sequential extraction of metals in the samples of bottom sediments was performed after introducing the modification of the extraction scheme suggested by Tessier et al. (Anal Chem 51(7):844–851, 1979). The extraction times of particular stages were optimised. The fifth stage was altered by introducing the new methods of performing extraction. The samples of bottom sediments submitted the following granulometric analyses: dry, wet and wet with (HMP) dispersing reagent. Seven granulometric fractions with the following grain sizes were isolated: >2.0, 2.0–1.0, 1.0–0.5, 0.5–0.25, 0.25–0.1, 0.1–0.063 and <0.063 mm. The sequential extraction of particular granulometric fractions was performed. The concentration of metals variability was analysed depending on the method of sample preparation for the chemical analysis, granulometric fraction of sediments subjected to the analysis, extraction conditions and the site of samples collection. The lack of linearity between the metal concentration and the size of granulometric fraction was observed. The highest concentrations of metals were observed in fractions >2.0, 2.0–1.0 and 0.1–0.063 and <0.063 mm while the lowest concentrations occurred in fractions 1.0–0.5, 0.5–0.25, and 0.25–0.1 mm. The atomic absorption spectrometry with flame atomisation (F-AAS) was used for the determination of the investigated elements.  相似文献   

15.
The mineralogical composition of the meteorite of Kiel was analyzed microscopically and with the electron microprobe. The meteorite consists mainly of chondrules, which are recrystallized to some extend and which are embedded in a recrystallized ground-mass. The chondrite contains 55 Vol.-% olivine of composition (Fa24,2Fo75,3Te0,5), 28 Vol.-% orthopyroxene (Fs21,4 En76,8Wo1,8), 9 Vol.-% plagioclase (An9,4 Ab85,1 Or5,5), 4,5 Vol.-% troilite and 2,5 Vol.-% Fe-Ni-metal grains, consisting of kamazite, zonal taenite and plessite; furthermore the chondrite contains chromite, whitlockite and a very small amount of ilmenite, native copper, chalcopyrrhotine and valeriite.The kamazite is partly monocrystalline, in part polycrystalline and contains 6–7% Ni. The Ni-contents of the zonal taenites increase from approximately 30% in the core to 50% at the rim. The rim rich in Ni is broader adjacent to troilite and kamazite than adjacent to silicates. Some zonal taenite grains are partially replaced by a mixture of Ni-rich taenite, kamazite and troilite. The plessites have an average Ni-content of 15–20%. The two phases of a coarsely disintegrated plessite contain 55% and 4–5% Ni. According to Wood (1967) a primary cooling rate of 1–10° C per one million years can be deducted from the zonal structure of the taenite. The formation of the taenite rims rich in Ni, of the taenite-troilite-kamazite-replacements, and of the coarsely disintegrated plessites is probably due to a long lasting annealing or a very slow passage through the temperature range of about 300–400° C.The meteorite of Kiel is a L6-chondrite according to the petrological classification of chondrites (van Schmus and Wood, 1967). The deformation of the olivines, pyroxenes and plagioclases indicates a slight to moderate shock deformation with a peak pressure of about 150–200 kbar.

Dank. Die Mikrosonde wurde von der Stiftung Volkswagenwerk bereitgestellt. Wir bedanken uns bei Herrn Prof. Dr. F. Karl (gestorben am 15. 8. 1972) für sein Interesse an dieser Arbeit.  相似文献   

16.
The fine structure of the active region in the Orion KL gas-dust complex has been measured in polarized H2O maser emission (epoch December 12, 1998) with an angular resolution of 0.15 mas, or 0.07 AU, and a velocity resolution of 0.05 km/s. The maser emission is concentrated in a line with ΔV = 0.45 km/s, V LSR = 7.65 km/s, and a flux density of F = 2.1 MJy. The structure consists of a compact source (ejector), highly collimated bipolar outflow, and a toroidal component. The brightness temperature of the ejector is T b = 2 × 1016 K, and its degree of linear polarization reaches m ≈ 20%. The variation of the polarization angle across the profile is dX/dV = ?23°/(km/s), which considerably exceeds the Faraday rotation in the HII region foreground to the molecular cloud. The observed “rotation” is explained as an effect of different orientations for the polarization of the ejected outflows. The brightness temperature of the bipolar outflow is T b ≈ 1014 K, while that of individual components is T b ≈ 1015 K. The degree of polarization in the components exceeds that of the ejector and reaches m ≈ 50%. The position angle of the polarization is X ≈ 45° relative to the outflow. The torus, which is observed edge-on, has a diameter of 0.38 AU and a thickness of 0.08 AU. The brightness temperature of the tangential directions in the torus is T b ≈ 5 × 1015 K, and the rotational velocity is V rot ≈ 0.02 km/s. The degree of polarization is m ≈ 40%, and its position angle relative to the azimuthal plane is X ≈ 43°. The relative deviations of the polarization plane in the bipolar outflow and torus relative to the pumping direction are nearly the same and are determined by Faraday rotation within the HII region.  相似文献   

17.
The accuracy of differential scanning calorimetry (DSC) on a heat capacity measurement was evaluated using MgO. The result indicated that the deviation of the result in comparison to literature values was less than 0.4% at temperatures above 300 K and 2.1% below this temperature. Since this experiment proved the reliability of DSC, heat capacity, compressibility, and thermal expansion of ilmenite-type MgGeO3 were measured by means of DSC, a diamond anvil high pressure device, and a high-temperature X-ray camera, respectively. The heat capacity was approximated by C p = a + b·T + c·T ?2 at high temperatures and by the Debye function at low temperatures. The compressibility was well-represented by the Murnaghan-Birch equation of 2nd order. The thermal expansion coefficient was constant up to 1073 K.  相似文献   

18.
The Iju Cu porphyry is located in the NW part of the Kerman Magmatic Copper Belt (KMCB). It is related to a ~ 9 Ma granodiorite porphyry intrusion, with three main stages of hydrothermal activity. The homogenization temperatures for the fluid inclusions are in the ranges of 200–494 °C, and their salinities vary from 4.0 to 42.8 wt% NaCl equiv., which are typical magmatic-hydrothermal fluids. The δ34S values of sulfides range from −0.4 to +3.2 ‰ (V-CDT), and the δ34S values of anhydrite samples range from +11.6 to +16.8 ‰. The δ34S values of sulfides show a narrow range, implying a homogeneous sulfur source. The oxygen isotopic composition of hydrothermal water in equilibrium with quartz samples ranges from +3.4 to +6.0 ‰ (V-SMOW) consistent with the hydrothermal fluids having a magmatic signature, but diluted with meteoric waters in the main mineralizing stage. The most important factors responsible for metal precipitation in the Iju porphyry deposit are fluid boiling, oxygen fugacity decrease and cooling followed by dilution with meteoric water. The primary fluids of the Iju Cu deposit are characterized by relatively high temperature and moderate salinity, and are CO2-rich, indicating a typical post-collisional porphyry system.  相似文献   

19.
The shallow marine sedimentary sequence of the Jaisalmer Basin exhibits one of the important and well-developed Tithonian sedimentary outcrops for western India. The ichnology and ichnofabric of the lower part of Bhadasar Formation (i.e., Kolar Dongar Member) belonging to Tithonian age are presented and discussed. The Kolar Dongar Member represents a shallow marine succession that contains 16 ichnotaxa: Ancorichnus ancorichnus, Conichnus conicus, Gyrochorte comosa, cf. Jamesonichnites heinbergi, Imponoglyphus kevadiensis, Laevicyclus mongraensis, Monocraterion tentaculatum, Ophiomorpha nodosa, Palaeophycus tubularis, P. bolbiterminus, Phycodes palmatus, Planolites beverleyensis, Rhizocorallium isp., Rosselia rotatus, R. socialis, and Teichichnus rectus. The ichnofabric analysis divulges five distinct ichnofabrics, each typifying distinct depositional environment within shallow marine conditions. The ichnofabric Ophiomorpha 1 with syn-sedimentary faulting exemplifies high energy conditions typical of lower shoreface environment, whereas the Ophiomorpha 2 ichnofabric typifies upper shoreface environment. The Ancorichnus ichnofabric reflects lower offshore condition of deposition. The high ichnodiversity Ancorichnus–Rosselia ichnofabric is indicative of inner shelf conditions, while low ichno-diversity Teichichnus ichnofabric indicates prevalence of low energy brackish bay environment. Thus, Tithonian Kolar Dongar Member indicates depositional environment ranging from shoreface to offshore to inner shelf and finally to brackish bay environment.  相似文献   

20.
The Albian-Danian limestones of Cauvery Basin show a wide range of d13C and d18O values (–13.2 to +1.1% and –9.0 to –2.5%, respectively). The cement samples show negative carbon and oxygen isotope values (–18.9 to –3.9% and –9.0 to –4.3%, respectively). The petrographic study reveals the presence of algae, molluscs, bryozoans, foraminifers and ostracods as major framework constituents. The limestones have microspar and equant sparry calcite cements. The pore spaces and vugs are filled with sparry calcite cement. The bivariate plot of d13C and d18O suggests that most of the samples fall in the freshwater limestone and meteoric field, while few samples fall in the marine limestone and soil calcite fields. The presence of sparry calcite cement, together with negative carbon and oxygen isotope values, indicates that these limestones have undergone meteoric diagenesis.  相似文献   

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