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1.
Summary. TRM, ARM and Isr stabilities with respect to alternating fields and high- and low-temperature treatment are compared for a set of artificial rock specimens. The specimens contain grain-size fractions of a homogeneous natural magnetite and a natural magnetite showing exsolution lamellae. The grain-size fractions are in the PSD-MD range and vary between < 5 and 250 μm. For large MD grains the coercivity spectra of ARM are similar to those of Isr but differ from those of TRM particularly in the lower part of the spectrum. For small (< 5μm) grains the coercivity spectrum of ARM is similar to that of TRM, and both spectra are different from the coercivity spectrum of Isr. The use of ARM instead of TRM to determine palaeo-intensities is discussed in relation to the results obtained. During high- and low-temperature treatment ARM behaves similarly to Isr but unlike TRM for all grain sizes studied. The results of this study are discussed in terms of a remanence composed of PSD surface moments and MD and PSD bulk moments.  相似文献   

2.
Summary. Remanent acquisition curves, remanent hysteresis curves and alternating field demagnetization curves were determined for a number of artificial rock specimens containing well-defined grain-size fractions between 5 and 250 μm of natural magnetite, titanomagnetite and hematite. From these curves, the remanent acquisition coercive force H 'cr, the remanent coercive force H cr and the median destructive field of IRM H ½I were determined. Theoretically these parameters should be the same for an assembly of non-interacting, homogeneously distributed, randomly oriented single-domain grains. For a given hematite specimen H 'cr, H cr and H ½I have about the same value in spite of the strong grain-size dependence of these parameters. For each specimen of magnetite and titanomagnetite the value of H 'cr is larger than H cr which again is larger than H ½I. However, the ratios H 'cr/ H cr and H ½I/ H cr appear to have a (different) constant value. An interesting relationship which appears to hold for dispersed magnetite, titanomagnetite or hematite grains between 5 and 250 μm, independently of grain-size, quantity and packing density of the magnetic material, is:   相似文献   

3.
The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDFRRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe3O4 tape particles, acquired Bg values between -3 and -14 μT, and MDFRRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDFRRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDFRRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.  相似文献   

4.
Summary. Initial susceptibility, coercive force and several types of remanent coercive forces were measured on a set of artificial rock specimens containing grain-size fractions of a natural magnetite and titanomagnetite, both of which are optically homogeneous and a natural titanomagnetite and titanomaghemite, both of which show exsolution phenomena. It was found subsequently that the optically homogeneous titanomagnetite contains some submicroscopic Fe-rich inclusions. These inclusions are magnetically screened in coarse grains; only for the lower grain sizes studied they have an appreciable influence on the data. The size of the fractions varied from < 5 to 250 μm. The parameters and several parameter ratios are plotted as a function of grain size. Several of these parameters can be used as mineralogical and grain-size indicators. The varying degree of exsolution of the minerals is reflected in the gradients of the plots. From plots of initial susceptibility versus grain size it is concluded that the shape of the grains does not play a dominant role in determining the change of this parameter with grain size. Variation of the various parameters with grain size is explained in terms of a gradual transition from large PSD grains to MD grains without there being any sharp transition. For titanomagnetite ( x = 0.55) the transition takes place at grain sizes that are about 15 μm larger than for magnetite.  相似文献   

5.
Summary. Palaeomagnetic investigations were carried out on nine lava flows around the Dhar region, which constitute the northern part of the Deccan traps. The stability of remanent magnetism of these specimens was analysed by an alternating magnetic field, thermal demagnetization and memory tests. Six flows exhibited characteristic components of magnetization, with a mean direction of D =143°, I =+46° ( K = 107.1, α95=5.5°). This gives a VGP located at 29° N, 67° W (δp=4.5°, δm= 7.0°). The lower site with normal magnetization and the upper five sites with reverse magnetization indicate a geomagnetic field reversal during the initial phases of Deccan volcanism in the Early Tertiary period. A rapid northward migration of about 18° in latitude and a simultaneous anticlockwise rotation of 37° is calculated for the subcontinent.  相似文献   

6.
Summary. Continuous recordings were made of thermal demagnetizations of Isr, ARM and TRM induced in artificial rock specimens. The artificial rock specimens contained well-defined grain-size fractions of a natural titanomagnetite, which under an optical microscope was homogeneous. Using a Transmission Electron Microscope it was shown that submicroscopic inclusions exist within the titanomagnetite. Screening of the remanence of these inclusions by the surrounding titanomagnetite is thought to be responsible for the occurrence of 'peaks' in the continuous thermal decay curves of Isr and ARM; higher 'peaks' observed in the case of TRM are thought to be caused by the combined effects of screening and an anti-parallel remanence in the titanomagnetite. Further submicroscopic exsolution processes, which occur in the titanomagnetite as a result of repeated heating, can be deduced from the development of new 'peaks', from changes in the temperature at which the 'peak(s)'occur, their shape and their relative height. The use of stepwise demagnetization techniques on the titanomagnetite yielded erroneous directional results due to the screening in the titanomagnetite; the biasing effects due to screening could be avoided by using continuous thermal demagnetization techniques.  相似文献   

7.
A detailed record of mineral magnetic properties of a loess–palaeosol profile comprising seven loess horizons, six interbedded palaeosols and recent soil at the top in NE Bulgaria is analysed. A strong contrast between the soil and loess susceptibilities as well as other concentration-dependent hysteresis parameters is present, similar to the well-documented magnetic characteristics of the Chinese loess ( Hus & Han 1992 ; Maher & Thompson 1992 ; Heller & Evans 1995 ; Hunt et al. 1995 ). The magnetic enhancement of the palaeosol units is caused by very fine-grained pedogenic magnetite with superparamagnetic behaviour. Thermomagnetic analyses on bulk material suggest magnetite and maghemite as the main ferrimagnetic carriers in both soil and loess horizons. Their relative proportions are shown to reflect different palaeoclimatic conditions. Chernozem soils, which include recent soil S0 and first and second palaeosols S1 and S2 developed under steppe vegetation, show a high degree of low-temperature oxidation of the pedogenic magnetite to maghemite. This material is characterized by coercive force H c showing even higher values than those of the parent loess material. The older palaeosols (S4 to S6 ) were formed during more humid climatic conditions and therefore probably developed as forest types. Rock magnetic data suggest the existence here of only partly oxidized magnetite grains. The behaviour of the thermomagnetic curves, characterized by a kink at 200 °C, may be due to either a release of internal stress (built up as a result of partial low-temperature oxidation) or interactions between two phases.  相似文献   

8.
Rock magnetic parameters are often used to recognize variations in the original magnetic mineralogy and for normalizing purposes in palaeointensity studies. Incipient weathering, however, is shown to have a profound but partly reversible influence on the rock magnetic properties of the marls of the Early Pliocene Trubi formation in southern Sicily (Italy). The remanence in the marls resides in single-domain (SD) magnetite grains, but the remanent coercive force (Hcr) shows a strong variation and most values observed are anomalously high ( Hcr) range 36–188 mT).
The enhanced coercivities are attributed to stress in the magnetite grains induced by surface oxidation at low temperature. Upon heating to 150 °C a reduction of coercivities occurs that can be explained by a stress reduction as a result of a reduction of Fe2- gradient due to a higher diffusion rate at elevated temperature. After heating to 150 °C, coercivities are quite uniform throughout the outcrop and the values are characteristic of SD magnetite (Hcr range 30–38 mT). The bulk susceptibility increases by 4–24 per cent, and the isothermal remanent magnetization (IRM) decreases by 5–11 per cent. The increase in anhysteretic remanent magnetization (ARM) is large: 20–242 per cent. The magnitude of the changes is related to the degree of weathering.
Another effect of heating the marl samples to 150 °C is a substantial reduction of the coercivities of the secondary overprint in the natural remanent magnetization. After heating. separation of the secondary and primary components by alternating-field demagnetization is more efficient. The usual difficulties of thermal demagnetization above 300 °C may thus be avoided by a combination of moderate heating to 150 °C and subsequent alternating-field demagnetization.  相似文献   

9.
Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na6[H2W12O40], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.  相似文献   

10.
The low-temperature magnetic properties of magnetite are reviewed, and implications for rock magnetism considered. The behaviour of fundamental properties of magnetite at low temperatures near the Verwey transition ( T v ) are documented, and attention is given to various Verwey transition theories. The low-temperature behaviour of the magnetic energies that control domain structure is reviewed in detail. For the first time in rock magnetic literature, the low-temperature anomaly in spontaneous magnetization ( M s ) is documented and the differences between the saturation magnetization and M s near the Verwey transition are discussed. It is argued that the low-temperature behaviour of the magnetocrystalline anisotropy, and in particular the anomaly at T v , is most likely to affect multidomain remanence during low-temperature cycling. For multidomain crystals it is calculated that the large increase in magnetocrystalline anisotropy intensity and reduction in symmetry on cooling through T v is likely to reduce the stability of closure domains.  相似文献   

11.
Sediments and soils often contain superparamagnetic (SP) magnetite or maghemite grains that cause a frequency dependence of low-field susceptibility X fd which does not exceed 15 per cent/decade of frequency. Present models predict very different volume distributions for samples with the largest observed frequency dependence of susceptibility. While Stephensons' (1971) power-law model predicts most grains to be smaller than the stable single domain (SSD) threshold, the phenomenological model of >Dearing et al . (1996) suggests that most grains are between 10 and 25 nm in diameter. Finally, the recent calculations of Eyre (1997) indicate very broad volume distributions. This study reviews the nature of the superparamagnetic–stable single domain (SP–SSD) transition. The change of AC susceptibilities with grain size (or temperature) at the SP–SSD boundary is more gradual than commonly assumed. When distributions of particle coercivities and volumes are also considered, X fd values are much smaller than those calculated by Eyre (1997). Nonetheless, X fd can be larger than 15 per cent, and a larger frequency dependence has indeed been measured for some samples. The question whether the observed limited X fd of soils and sediments is a result of a broad distribution or of a bimodal distribution, where SP and SSD grains are restricted to a certain relative abundance, can potentially be answered by susceptibility determinations at more than two frequencies and by measurements of the temperature dependence of susceptibility.  相似文献   

12.
Summary An extension of the Love-Larmor theory to a low-loss unelastic earth model, leads to the surprisingly simple approximation
   
where τs= 447.4 sidereal day is the static wobble period, τR= 306 sidereal day is the rigid-earth wobble period and τw= 433 sidereal day is the observed Chandler period. Q W, Q μ are the respective average Q values of the wobble and the Earth's mantle at τW. The known numerical factor F is only slightly dependent on the Earth structure.  相似文献   

13.
Summary. Titanomagnetites of composition Fe2.4-δAlδTi0.6O4 and Fe2.6-δAlδTi0–4O4(δ=0, 0.1 and 0.2 in both cases) were prepared in the monodomain state by pulverization of sintered synthetic material. In low fields, the thermoremanence (TRM) was found to be linear with inducing field and of high enough intensity to account for typical natural remanent magnetizations of fresh submarine basalts. The higher field TRM acquisition curves follow the Néel model curve for an assemblage of non-interacting identical particles in a general way only, the differences being due to interactions, or the range of particle blocking temperatures and volumes or other features of the samples not included in the model. The unblocking temperatures of low field TRM lie in a narrow range below the Curie point. The low field TRM is very resistant to alternating field demagnetization and provides a very striking illustration of the strength of the TRM mechanism in preserving a stable record of a weak magnetic field. The result of a Lowrie-Fuller test on the material is consistent with the monodomain state.  相似文献   

14.
Summary The magnetotelluric (MT) response is studied of a uniformly stratified earth which contains a magnetized layer. The impedance as a function of the layer parameters (resistivity, ρ permeability, μ and thickness h ) is discussed. The MT response from a layer (μ, ρ, h ) is equivalent to that from a layer (μ/μr=μ0, μrρ, μr h ) where μr is the relative permeability of the layer. Thus the effect of a magnetized layer is to make it apppear μr times more resistive and μr times thicker than an unmagnetized equivalent layer. Master curves of apparent resistivity and phase are computed for three-layer models with varying permeability associated with varying resistivity in each layer. An example of MT field data is presented in which the most reasonable interpretation is that a magnetized layer exists beneath the observatory site.  相似文献   

15.
The Middle and Upper Jurassic Bathonian-Oxfordian shallow-water carbonate rocks from the Paris Basin, France, consist mainly of oolitic and bioclastic limestones that are hydrocarbon reservoirs in the subsurface. Despite a preliminary positive study, these deposits have been considered to be largely remagnetized (Rochette, private communication), and hence not amenable to palaeomagnetic dating. To establish their magnetic mineralogy and test this remagnetization hypothesis, we have used an integrated investigation combining petrographic, geochemical, rock-magnetic and palaeomagnetic measurements on samples extracted from five cores from the Paris Basin and from outcrops in Burgundy. Magnetic minerals in the Bathonian-Oxfordian carbonates include: (1) primary biogenic single-domain magnetite and detrital multi-domain Ti-magnetite and their oxidized form, maghemite; (2) authigenic spheres of magnetite probably related to hydrocarbons; and (3) goethite, either restricted to ferruginous ooid layers or resulting from surficial alteration, notably replacement of pyrite framboids. Rock-magnetic experiments carried out on 68 samples reveal H cr/ H c and M rs/ M s ratios ranging from 1.88 to 5.58 and 0.017 to 0.314, respectively. These values are clearly distinct from diagnostic values for a chemical remagnetization. Pyrrhotite was not identified within these sediments. Moreover, the average H cr/ H c ratio of 3.14 is significantly different from the value of 1.333 for natural pyrrhotite (Dekkers 1988). These results have a direct implication for the preservation of the primary magnetization; consequently, these deposits are selectively amenable for magnetostratigraphic dating and possible regional correlations.  相似文献   

16.
Coercive force of single crystals of magnetite at low temperatures   总被引：1，自引：0，他引：1  
The temperature dependence of coercive force H c was studied on well-characterized and stoichiometric millimetre-sized single crystals of magnetite at a series of 16 temperatures from 300 to 10 K using a SQUID magnetometer. H c decreases gradually with cooling to the isotropic temperature, T i = 130 K, where the first magnetocrystalline anisotropy constant K 1 becomes zero. H c exhibits a sharp increase at the Verwey transition, T v = 120 K, where the structure changes from cubic to monoclinic. In crossing the Verwey transition, H c increases by more than two orders of magnitude, from 20 μT to 2.4 mT, and the shape of the hysteresis loops becomes wasp-waisted.
Observed coercivity between 300 K and 170 K varies with temperature as λ s / M s , where λ s is the magnetostriction constant and M s is the saturation magnetization, indicating that the coercivity in MD magnetite is controlled mainly by internal stress associated with dislocations or other crystal defects. It seems likely that the stable single-domain-like magnetic memory observed in large MD magnetite crystals is due to magnetoelastically pinned domain walls. The discontinuous change in H c at the Verwey transition is controlled by abrupt changes in magnetocrystalline and magnetostriction constants due to crystal deformation from cubic to monoclinic structure.  相似文献   

17.
3-D images of P velocity and P - to S -velocity ratio have been produced for the upper crust of the Friuli area (northeastern Italy) using local earthquake tomography. The data consist of 2565 P and 930 S arrival times of high quality. The best-fitting V P and V P / V S 1-D models were computed before the 3-D inversion. V P was measured on two rock samples representative of the investigated upper layers of the Friuli crust. The tomographic V P model was used for modelling the gravity anomalies, by converting the velocity values into densities along three vertical cross-sections. The computed gravity anomalies were optimized with respect to the observed gravity anomalies. The crust investigated is characterized by sharp lateral and deep V P and V P / V S anomalies that are associated with the complex geological structure. High V P / V S values are associated with highly fractured zones related to the main faulting pattern. The relocated seismicity is generally associated with sharp variations in the V P / V S anomalies. The V P images show a high-velocity body below 6 km depth in the central part of the Friuli area, marked also by strong V P / V S heterogeneities, and this is interpreted as a tectonic wedge. Comparison with the distribution of earthquakes supports the hypothesis that the tectonic wedge controls most of the seismicity and can be considered to be the main seismogenic zone in the Friuli area.  相似文献   

18.
Summary. One hundred and fifty oriented samples were collected from 12 sites from the Tertiary basalts of Wadi Abu Tereifiya (30.0°N, 32.1° E). After alternating field demagnetization the mean direction of the natural remanent magnetization is, D = 187.9°, I = -20.8° with α95= 5.8°. This yields a palaeopole at 69.4°N, 188.3° E.
Also, 30 oriented samples were collected from two sites from Mandisha in Bahariya Oasis (28.4°N, 28.9° E). After cleaning, the mean direction of the NRM is D = 191.0°, I = 5.2° with α95= 9.9°. This yields a palaeopole position at 58.2°N, 186.7° E.
Besides, the NRM of 70 oriented samples collected from seven dioritic dykes from Wadi Abu Shihat (26.3°N, 33.2° E) was found to have a mean direction, D = 142.0°, I = -0.3°, which leads to a palaeopole position at, 44.9°N, 273.0° E. This agrees with other Mesozoic pole positions from Africa.  相似文献   

19.
New palaeomagnetic data from the Lower and Middle Cambrian sedimentary rocks of northern Siberia are presented. During stepwise thermal demagnetization the stable characteristic remanence (ChRM) directions have been isolated for three Cambrian formations. Both polarities have been observed, and mean ChRM directions (for normal polarity) are: Kessyusa Formation (Lower Cambrian) D = 145°, I = -40°, N = 12, α95= 12.8°; pole position: φ= 38°S, A = 165°E; Erkeket Formation (Lower Cambrian, stratigraphically highly) D = 152°, I = - 47°, N = 23, α95= 6.8°; pole position: φ= 45°S, A = 159°E; Yunkyulyabit-Yuryakh Formation (Middle Cambrian) D = 166°, I = - 33°, N = 38, α95= 4.6°; pole position: φ= 36°S, L = 140°E. These poles are in good agreement with the apparent polar wander path based on the bulk of existing Cambrian palaeomagnetic data from the Siberian platform. In Cambrian times, the Siberian platform probably occupied southerly latitudes stretching from about 35° to 0°, and was oriented 'reversely' with respect to its present position. Siberia moved northwards during the Cambrian by about 10° of latitude. This movement was accompanied by anticlockwise rotation of about 30°. The magnetostratigraphic results show the predominance of reversed polarity in the Early Cambrian and an approximately equal occurrence of both polarities in the part of the Middle Cambrian studied. These results are in good agreement with the palaeomagnetic polarity timescale for the Cambrian of the Siberian platform constructed previously by Khramov et al. (1987).  相似文献   

20.
Summary. After thermal and alternating field (AF) cleaning, the characteristic high blocking temperature A component of natural remanent magnetization (NRM) of the Tudor gabbro of southern Ontario has a mean direction D = 326°, I =–46° ( k = 132, α95= 4.8°, N = 8 sites). The corresponding palaeopole, 133°E, 12°N ( dp = 4°, dm = 6°), confirms the palaeopole 137°E, 17°N (α95= 8.4°) reported earlier by Palmer & Carmichael, based on AF cleaning only. The A NRM has unblocking temperatures > 515–525°C which exceed the estimated 500°C peak temperature reached locally during ∼ 1050 Ma Grenvillian regional metamorphism. The A NRM therefore predates metamorphism and is probably a primary thermoremanence (TRM). The age of the Tudor NRM has previously been taken to be about 675 Ma, but recent 40Ar/39Ar dating by Baksi has shown that this is the time of post-metamorphic cooling to 200–250°C. Hornblendes record initial cooling of the intrusion to 590±20°C at 1110 Ma and this is the best estimate of the age of the A remanence. Successful Thellier-type palaeointensity determinations on 11 Tudor samples confirm that the A NRM is a TRM and indicate a palaeofield at this time of 18–27 μT, about 50–70 per cent of the present field intensity at 27° magnetic latitude. The anomalous Tudor A palaeopole, which lies well to the west of both 1000–800 Ma Grenvillian palaeopoles and 1100–1050 Ma poles from Interior Laurentia, is interpreted as recording divergence between Grenvillia and Interior Laurentia just before the Grenvillian orogeny, rather than a post-metamorphic extension of the apparent polar wander path as previously assumed.  相似文献   

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