共查询到20条相似文献，搜索用时 15 毫秒
1.
吴大清 《中国地球化学学报》1990,9(2):155-160
Phase relations in the system Pb-Sn-Fe-Sb-S were investigated through the diagrams of projecting plane 8x(PbS-SnS-SnS2)from the vertrex point Fe0.96Sb2.04S4.12by vacuum silica tube technique.Experimental results have shown that franckeite has a wide solid solution with substitution of Pb^2 by Sn^2 ,In franckeite s.s.the content of Sn^2 varies from 0 to 4.8 atoms (total metal atoms are 11 atoms per formula) at 500℃ and 0-4.0 atoms at 400℃,respectively,Meanwhile,the content of Sn^4 ranges from 1.3to 2.0 atoms at 500℃ and 1.5-2.1 atoms at 400℃ in franckeite s.s.These results are consistent well with analytic data on natural franckeite.The cylindrite solid solutiopn has a relatively small range with Sn^2 -1.8atoms and Sm^4 =3.2-4.2 atoms per formula at 500℃ and ,Sn^2 =0.5-1.7 atoms and Sm^4 =3.3-4.2 atoms at 400℃ which are comparable with natural cylindrite.The phases coexisting in equilibrium with franckeite s.s. are galena,boulangerite,robinsonite.teallite,SnS,cylindrite.s.s.and synthetic phase Ⅲ ss or I ss.The cylindrite s.s.coexists with SnS2 and the above mentioned phases,but not with galena.teallite and SnS,and probably not with boulangerite in this projecting plane. 相似文献
2.
Presented in this paper are the rypes,salinities,homogenization temperatures and organic components of fluid inclusions formed at the four stages of diagenetic authigenesis in the Eogene of the Biyang Depression.The results of cooling experiments on fluid inclusions were used to determine the fluid system and composition of saline aqueous solution in each of the stages .The homogenization temperatures of saline aqueous solution inclusions and hydrocarbon organic inclu-sions have been corrected by two approaches ,and the trapping temperatures and pressures of fluid inclusions at each of the stages have been obtained.This strdy has shed light on the physicochemistry and evolution of diagenetic fluids.The diagentic fluid system is a system which was transformed from a chloride-bearing to a carbonate-bearing system along with the diagenic evolu-tion.The decrease of diagenetic temperature at Stage III of diagenetic authigenesis suggests that the depression would have experiences uplifting at that time.The fluorescent characteristics of fluid inclusions indicate the varieties of organic components in fluid inclusions both in time and in space. 相似文献
3.
Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed. 相似文献
4.
Laihunite, a mineral of ferric and ferrous iron silicate discovered in China in recent years, occurs in high grade metamorphic BIF coexisting with magnetite, quartz,fayaiite, ferrosilite and almandine. Complete nets based on Sehreinemakers bundles and partial nets with maximum closure after the method described by H. W. Day have been constructed by taking into account the existance of this minertl in order to illustrate phase relations for the (n 3) multisystem in the system of Fe2O3-FeO-SiO2. Judging from Lindsley‘s experimental data on ferrosilits, laihunite is expected to be stable at pressures probably higher than 15 Kb. Two-pyroxene and olivine-clinopyroxene geothermometere give temperatures of formation between 600--700℃. Free energy of laihunite calcultted according to the method of Chert and estimated values of heat capacity allow oxygen fugacity to be plotted against temperature at different total pressures with respect to a number of univariant reactions in which lailunite is involved. The log fo2 -T diagram demonstrates that to a first approximation the stability flels of laihunite overlaps the upper part of the magnetite field, but its upper limit is a little beyond the hematite-magnetite equilibrium. The three major requirements for laihunite stability, i.e., an unusual high pressure, a temperature in the order of 600--700℃ and a relatively higher oxygen fugacity are mutually, exclusive in common geological environment, which may probably account for the rare occurrence of this mineral in nature. For the BIF in which laihunite occurs, the pressure caused by the weight of overlying strata is not high enough to give rise to its formation even in the extreme case of geothermal gradient.So it is suggested that additional tectonic pressure in response to plate activity might have been involved. 相似文献
5.
Subsolidus phase relations have been determined in the systems SiO2-Cr-O and MgO-SiO2-Cr-O in equilibrium with metallic Cr, at 1100 to 1500℃ and 0 to 2.88 GPa. The results show that there are no ternary phases in the SiO2-Cr-O system at these conditions, i.e., only the assemblage eskolaite-Cr-metal-quartz (or tridymite) is found. In the MgO-containing system, however, extensive substitution of Cr2+ for Mg is observed in (Mg, Cr2+)2SiO4 olivine, (Mg, Cr2+)2Si2O6 pyroxene, and (Mg, Cr2+)Cr2O4 spinel. Cr3+ levels in olivine and pyroxene are below detection limits. The pyroxene is orthohombic at XCrPx2+ < 0.2, monoclinic at higher XCrPx2+ . Thestructure of the spinels becomes tetragonally distorted at XCr2+Sp >0.2. The experimental datahave been fitted to a thermodynamic model, and the authors obtained the mixing parameter (W) of Mg-Cr2+ in olivine, pyroxene and spinel, and the relation between temperatures and free energies of formation for the end-members: Cr2+-olivine (Cr2SiO4), Cr2+-pyroxene (Cr2Si2O6) 相似文献
6.
不同温度、压力条件下人造金刚石的晶体形态特征及优晶生长区的初步探讨 总被引：2，自引：0，他引：2
Crystal. habit and morphological peculiarities of synthetic diamond have been studied at various temperatures and. pressures.A diagram has been proposed based on experimental data for different erystal morphology with respect to different P.T conditions, Preliminary discussion has been given to the field of fine diamond crystal growth and a principle is presented for the optimum P-T conditions for fine diamond synthesis. 相似文献
7.
Based on the analytical results for 101 samples from 50 survey spots,this paper describes the changes in rations of various components in calcium carbonate from the sea area at the Pearl River mouth with pH.Relations of ∑CO2 with salinity,and Ca concentration with salinity in different parts of the river mouth have been established.The annual throughput of Ca from the Pearl River and the saturation degrees of calcite and aragonite have been calculated. 相似文献
8.
Three thermodynamical equations, for unitary two-phase fluid inclusions have been deduced. (1) The thermodynamical equation for mutual transformation between gas and liquid phases in fluid inclusions. The transformation direction from one phase to the other can be known in terms of the density and filling degree of gas and liquid. (2) The thermodynamical equation for pressure effect on temperature after homogenization of fluid inclusions. The coefficient of P-T variation is directly proportional to the fining degree of gas phase and inversely to the density of gas phase and liquid phase. Equations for homogenization, decrepitation and formation temperatures of fluid inclusions can be inferred from. this equation. (3) The thermodynomical equation for decrepitation temperatures of fluid inclusions. Many factors have effects on the decrepitation temperatures of fluid inclusions.Decrepitation temperature cannot be considered in any case as formation temperature.Thermal and vapor halos produced by decrepitation of minerals of the same kind and the same period from the same locality are worthy of consideration. 相似文献
9.
Based on researches done by other scholars,this paper summarized tiankeng’s landscape characteristics and analyzed them.By referring to the methods and standards of tourism resources evaluation,tiankeng landscape evaluation model has been built.The evaluation index system was built in terms of the model and tiankeng’s characters.After the evaluating factors and index were established,the weights of them have been figured out by AHP method.For the first time tiankeng has been studied from the view of landscape.However,this primary study about tiankeng landscape evaluation will offer reference for its tourism development and protection.It also lays the foundation for the construction of a better system. 相似文献
10.
As a basis of modern petrology,the equilibrium relations describing the melting of granite were established mainly on melting experiments of Powder samples.Such experiments,however,have serious limitations in providing information about the variations in compositional and fabric features of the minerals and in the composition and distribution of the melt.Our experiments using massive samples indicate that melt occure mainly at the quartz-plagioclase and quartz-potash feldspar boundaries and the composition of the melt is dependent on local characteristics in the melting system,showing no correlation with the bulk composition of the rock samples.At lower temperatures(740-760℃,0.2GPa),the melt plots at or near the eutectic point in Q-Ab-Or-An-H2O diagram,indicating equilibrium melting.At higher temperatures(790-800℃，0.2GPa)the melt becomes lower in SiO2 and higher in Na2O,deviating makedly from the eutectic line but without disappearance of any mineral phase,suggesting a non-equilibrium process.It is obvious that the phase-equilibrium relations in natural massive granites may be greatly different from those deduced from powder experiments. 相似文献
11.
《地球化学》1973,(4):272-275
The concentrations of radiogenic Ar^40 and cosmogenic Ar^32 in Anlung chondrite have been measured by the isotopic dilution technique. A ultrahigh-vacuum system have been designed for extracting and purifying the gases in the sample. These data provide a K^40-Ar^40 age of 3.28 b.y. and an exposure age of 3.0 m,y. for this chondrite.Based on these results, we have discussed the origin and the former environment of stone meteorite. 相似文献
12.
山东临朐地区新生代玄武岩同位素钾-氩年龄研究 总被引：9，自引：0，他引：9
Isotopic determinations were made on basalts intercalated in the strata with abundant Upper Tertiary fossils. In order to satisfy the needs of K-Ar age determina.tions of younger basalts with lower potasium content, we have made some modifications on the China-made ZhT-1301 massspectrometer, Meanwhile, some improvements and refinements have been made as well on the mass-spectrometer and the argon-extraction system and argen-measureing technique. Our results are: 7.86---13.Sm.y. for the youngest basalts ; 20--24 m.y. for the Shanwang Group with abundant Miocene fossils;and: 44 m.y. for basalts from the lower part of the Shanwang Group. The chronological results are basically in agreement with the stratigraphic sequence. 相似文献
13.
A new aproach to isotopic analysis of carbon,oxygen,sulfur and nitrogen in microsamples has been established.Samples were conventionally prepared by mixing microsamples to be analyzed with reference samples with known δ values in a proper proportion,and then analyzed for their stable isotopes as those at ordinary levels.According to the equilibrium relationships before and after mixing,the δvalues of unknown microsamples were calculated.The δ^15N of the atmosphere was estimated at zero by this approach,which is concordant with the internationally recommended value. 相似文献
14.
Wei Yan Yanyao Zhang Yunlu Ma Mingyue He Lifei Zhang Weidong Sun Christina Yan Wang Xi Liu 《地学前缘(英文版)》2021,12(1):313-326
A series of coesite,coexisting with or without a liquid phase,was synthesized in the nominal system SiO2-H2O at800-1450℃and 5 GPa.Micro-Raman spectroscopy was used to identity the crystalline phase,electron microprobe and LA-ICP-MS were employed to quantity some major and trace elements,and unpolarized FTIR spectroscopy was applied to probe the different types of hydrogen defects,explore water-incorporation mechanisms and quantify water contents.Trace amounts of A1 and B were detected in the coesite.Combining our results with the results in the literatures,we have found no positive correlation between the Al contents and the"Al"-based hydrogen concentrations,suggesting that previously proposed hydrogen-incorporation mechanism H^++Al^3+■Si^4+does not function in coesite.In contrast,we have confirmed the positive correlation between the B contents and the B-based hydrogen concentrations.The hydrogen-incorporation mechanism H^++B3^+■Si^4+readily takes place in coesite at different P-T conditions,and significantly increases the water content at both liquid-saturated and liquid-undersaturated conditions.For the SiO2-H2O system,we have found that type-Ⅰhydrogarnet substitution plays a dictating role in incorporating water into coesite at liquid-saturated condition,type-II hydrogarnet substitution contributes significantly at nearly dry condition,and both operate at conditions in between.The water solubility of coesite,as dictated by the type-Ⅰhydrogarnet substitution,positively correlates with both P and T,cH2O=-105(30)+5.2(32)×P+0.112(26)×T,with cH2O in wt ppm,P in GPa and T in℃.Due to its low water solubility and small fraction in subducted slabs,coesite may contribute insignificantly to the vertical water transport in subduction zones.Furthermore,the water solubility of any coesite in exhuming ultra-high pressure metamorphic rocks should be virtually zero as coesite becomes metastable.With an adequately fast waterdiffusion rate,this metastable coesite should be completely dry,which may have been the key factor to the partial preservation of most natural Coe.As a byproduct,a new IR experimental protocol for accurate water determination in optically anisotropic nominally anhydrous minerals has been found.Aided with the empirical method of Paterson(1982)it employs multiple unpolarized IR spectra,collected from randomly-orientated mineral grains,to approximate both total integrated absorbance and total integrated molar absorption coefficient.Its success relies on a high-level orientation randomness in the IR analyses. 相似文献
15.
This paper reviews the features of several tungsten ore deposits in southern China, including the Shezhuyuan, Yaogangxian, Xihuashan, Danping, Yiatang and Dajishan mines. The authors think that the formation depth of greisen-type deposits is intermediate between the depths of pegmatite- and porphyry- type deposits. Using phase diagrams of the model system K2O-AhO3-SiO2-H2O-HF, the formation mechanism of greisens has been argued. The variation of mineral assemblages from K-feldspar, muscovite to topaz reflects a gradual increase in acidity. This variation can be used as a criterion to appreciate the depth of mineralization. Equilibria of tungsten minerals in greisen and skarn deposits can be depicted on chemical potential diagrams of the model system CaO-FeO-WO3-CO2-F2O-1. The assemblage wolframite fluorite is shown to have been transformed to scheelite magnetite with decreasing μHP. Depending on CO2 activity in the fluids, there are two distinct phase diagrams.One shows that wolframite is incompatible with calcite, and the other demonstrates that scheelite is incompatible with rhodochrosite. On the phase diagrams of the model system FeO-MnO-WO3-F2S-1, huebnerite is transformed to ferberite with increasing μP1O-1orμF2S-1,During the replacement of wolframite by scheelite, the wolframite residue must have been enriched in Mn. 相似文献
16.
Preliminary Statistics of Temperatures and Pressures for Formation of Eclogites, Granulites and Peridotites in China 总被引：1，自引：0，他引：1
HuBaoqun WangFangzheng SunZhanxue LiuChengdong BaiLihong 《中国地质大学学报(英文版)》2004,15(2):183-192
The rock-forming temperatures and pressures represent the p-T points of the local regions in the lithosphere at a certain age, providing some important information on rock formation. Based on the preliminary statistics on the temperatures and pressures for the formation of eclogites, granulites and peridotites in China, the variant ranges are given, in this paper, of temperatures, pressures and linear geothermal gradients of eclogites, granulites and peridotites. In addition, since the eclogite is different from granulite and peridotite in the p-T diagram, these three rocks can be classified into two groups: the first group includes eclogites and the second group granulites and peridotites. Then, the p-T correlation functions of these two groups of rocks are provided. Finally, the two groups of rocks have different geothermal gradients at the same pressure gradient or have different pressure gradients at the same geothermul gradient. The temperatures and pressures for the formation of the rocks can be calculated from the mineral chemical compositions, but the depths (H) for the rock formation can be calculated only under the hypotheses of given p-H (or T-H) correlation functions. The explanations for the ultrahigh pressure metamorphism vary obviously with different hypotheses. 相似文献
17.
The transportation of magma in sedimentary basins often occurs through extensive dyke-sill networks. The role of sills on the plumbing system in rifted margins and the impact of sills on hydrocarbon reservoirs of prospective sedimentary basins has long been an area of great industrial interest and scientific debate. Based on 2D seismic reflection, we present data on how the sills emplaced to form a magmatic plumbing system of the volcanic system for the Zhongjiannan Basin(ZJNB). The results show... 相似文献
18.
Liang Xiangji Qiao Li Wang Fusheng Yang Chonghui Institute of Geology Chinese Academy of Geological Sciences Beijing 《《地质学报》英文版》1994,68(2)
Experimental results have proved that the Xuefengian Sn-bearing biotite granites were formed by remelting and recrystallization of the Proterozoic metamorphic rocks of the Sibao Group at 500× 105-2000× 105 Pa and 750-570℃ and further testified that the F- and B-bear-ing aqueous solution played an important part in decreasing the formation temperature of the rocks. The results tally with the reality of the field geology. The authors have thus brought to light the mechanism for the formation of the Sn-bearing biotite granites and expounded the significance of their formation in the crust dynamics of South China. 相似文献
19.
ZHANG Yueqiao Institute of Geomechanics Chinese Academy of Geology Beijing ChinaPierre Vergely Jacques-Louis Mercier URA-CNRS: Geophysique et Geodynamique Interne Universite de Parie-Su Bdtment F- Orsay-Cedex France WANG Yongmin ZHANG Yong HUANG DezhiInstitute of Geology Bureau of Geology Mineral Resouces of Anhui Province Hefei China 《《地质学报》英文版》1999,73(3):264-274
Since the mid-late Eocene, North China has been subjected to extensional stress, resulting in the formation and development of basins. The dynamic origin of this crustal extension has long been an issue of debate. This paper presents the results of kinematic analyses of faults obtained from two seperated areas in North China. In the Weihe graben situated on the southernmost margin of the Ordos block, analyses of fault kinematics were coupled with an analysis of the basin's subsidence history. Three successive extensional tectonic phases accompaning the basin's formation and development have been distinguished. The Palaeogene extension was oriented in a WNW-ESE direction; the Neogene extension in a NE-SW direction and the Pliocene-Quaternary extension in a NW-SE direction. Such changes have also been recorded by fault kinematics along the southern Tanlu fault zone. This has been demonstrated by three successive sets of fault striations indicating normal dip slip resulting from NW-SE extension, then left- 相似文献
20.
《《地质学报》英文版》2010,(6)
<正>Zabuye Salt Lake in Tibet,China is a carbonate-type salt lake,which has some unique characteristics that make it different from other types of salt lakes.The lake is at the latter period in its evolution and contains liquid and solid resources.Its brine is rich in Li,B,K and other useful minor elements that are of great economic value.We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15℃and 25℃.The crystallization sequence of the primary salts from the brine at 25℃is halite(NaCl)→aphthitalite (3K_2SO_4·Na_2SO_4)→zabuyelite(Li_2CO_3)→trona(Na_2CO_3·NaHCO_3·2H_2O)→thermonatrite (Na_2CO_3·H_2O)→sylvite(KCl),while the sequence is halite(NaCl)→sylvite(KCl)→trona (Na_2CO_3·NaHCO_3·2H_2O)→zabuyelite(Li_2CO_3)→thermonatrite(Na_2CO_3·H_2O)→aphthitalite (3K_2SO_4·Na_2SO_4) at 15℃.They are in accordance with the metastable phase diagram of the Na~+,K~+-Cl~-, CO_3~(2-),SO_4~(2-)-H_2O quinary system at 25℃,except for Na_2CO_3·7H_2O which is replaced by trona and thermonatrite.In the 25℃experiment,zabuyelite(Li_2CO_3) was precipitated in the early stage because Li_2CO_3 is supersaturated in the brine at 25℃,in contrast with that at 15℃,it precipitated in the later stage.Potash was precipitated in the middle and late stages in both experiments,while boron was concentrated in the early and middle stages and precipitated in the late stage. 相似文献