首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S2) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S2) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S2 = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S2 to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S2–TOC plots can be used in order to check the forward modelling results against observed values.  相似文献   

2.
Comprehensive quantitative evaluation of shale gas content and the controlling factors in different occurrence states is of great significance for accurately assessing gas-bearing capacity and providing effective well-production strategies. A total of 122 core samples from well JY-A in the Fuling shale gas field were studied to reveal the characteristics of S_1 l shale,15 of which were selected to further predict the shale gas content in different occurrence states, which are dependent on geological factors in the thermal evolution process. Geological parameters were researched by a number of laboratory programs, and the factors influential in controlling shale gas content were extracted by both PCA and GRA methods and prediction models were confirmed by the BE method using SPSS software. Results reveal that the adsorbed gas content is mainly controlled by TOC, Ro, SSA, PD and pyrite content, and the free gas content is mainly controlled by S_2, quartz content, gas saturation and formation pressure for S_1 l in well JY-A. Three methods, including the on-site gas desorption method, the empirical formula method, and the multiple regression analysis method were used in combination to evaluate the shale gas capacity of well JY-A, all of which show that the overall shale gas content of well JY-A is in the range of 2.0–5.0 m~3/t and that the free gas ratio is about 50%, lower than that of well JY-1. Cause analysis further confirms the tectonics and preservation conditions of S_1 l in the geological processes, especially the influence of eastern boundary faults on well JY-A, as the fundamental reasons for the differences in shale gas enrichment in the Jiaoshiba area.  相似文献   

3.
Summary Most empirical methods of subsidence prediction are based on the prior knowledge of the maximum possible subsidence, Smax, for a particular coalfield. The subsidence profile and other associated parameters along a desired line may be derived, in most cases, as a function of S max. These methods are site specific and are not based upon the rational concepts of mechanics. Purely mechanistic methods, on the other hand, could not find wide application because of their limitations in representing the complex behaviour of a rockmass.Therefore a semi-empirical method of calculation of S max or S, which is an improvement over the empirical method reported elsewhere (Bahuguna et al., 1991a), has been derived from combining the mechanistic and empirical approach. The effects of various parameters are studied by numerical modelling. These qualitative results are then used to influence the development of a more general semiempirical method. The method has been tested for 125 coal mine workings in India and 22 mines of the North Appalachian basin. The method is easily adaptable to other countries.  相似文献   

4.
Mineral shapes, sizes and proportions in mica rich (M) and quartz-mica (QM) domains of an S4 metamorphic layering have been compared in two mutually perpendicular orientations with shapes, sizes and proportions in mildly crenulated S2 enclaves preserved within a rock from part of the Willyama Complex, N.S.W., Australia. The study has shown that data from two orientations are necessary to place constraints on the movement of mineral components dissolved in solution during formation of the layering. Comparison of mineral data has shown that SiO2 has been dissolved from quartz grains in both M and QM domains. The SiO2 lost from M domains has not migrated into QM domains. Measurements have also shown that biotite has undergone less solution than quartz. Most of the biotite components have probably undergone reaction to form probable syn—S4 muscovite and chlorite. The muscovite-forming reaction requíres some silica on the lefthand side of the reaction, probably more than can be supplied by the chlorite-forming reaction. Some of this extra silica was supplied from dissolved quartz grains. However, only a small amount is needed for this purpose and most of the SiO2 has left the system. Some syn—S4 muscovite may have formed in M domains where it lies within the crenulated S2. Direct evidence for its growth is hard to find.  相似文献   

5.
The Mapocho river, which crosses downtown Santiago, is one of the most important rivers in contact with a population of about six million inhabitants. Anthropogenic activities, industrialization, farming activities, transport, urbanization, animal and human excretions, domestic wastes and copper mining have affected the river, contaminating it and its sediments with heavy metals. Concentration and distribution of Cu, Zn, Pb and Cd were studied with the purpose of determining their bioavailability and their relation with the characteristics of the sediments. Freshly deposited seasonal sediments were collected from 0–8 cm depths from 6 locations (S1 to S6) along the 30-km long channel length, in the four seasons of year on the following dates: May 2001 (D1, autumn); August 2001 (D2, winter); October 2001 (D3, spring) and January 2002 (D4, summer). The dried samples were sifted to obtain the < 63-μm sediment fraction, since it has been shown that large amounts of heavy metals are bound in the fine-grained fraction of the sediment. Cu and Zn were analyzed by atomic absorption spectrophotometry and Pb and Cd by square wave anodic stripping voltammetry. The highest concentrations of Cu (2850 μg g− 1) were found in the northern part of the river (S1, average D1–D4), near the mountains and a copper mine, and then decreased downstream to 209 μg g− 1 (S6). Total Zn showed an irregular variation, with higher values at S1 (1290 μg g− 1) and high values in some winter sampling (1384 μg g− 1 S4, S5–D2). Pb showed different trends, increasing from S1 to S6 (17 to 61 μg g− 1), with the highest values in the summer samples (83 μg g− 1, S4–S6, D4), and total Cd increased slightly from mean values of 0.2 and 0.5 μg g− 1. Partition into five fractions was made using Tessier's analytical sequential extraction technique; the residue was treated with aqua regia for recovery studies, although this step is not part of the Tessier procedure. The results show that Cu, Zn and Pb in the sediments were dependent on the sampling places along the river, and variation in two years was low (D1–D4). The highest values of total organic matter, carbonate and conductivity were found in S6, which has the smallest size particles, while at S1 the sediments were predominantly sand and contain larger amounts of silica. Cu associated with carbonate decreased gradually from 58% (1771 μg g− 1, S1) to 16% (32 μg g− 1, S6); Cu bonded to reducible fraction was almost constant (33% to 37%), and Cu associated with oxidizable fraction increased from 7% (S1) to 34% (S6), but copper content was lower (214 to 68 μg g− 1). Zn had a similar fractionation profile. However, Pb bound to oxidizable fraction did not show significant percent variation along the river (20% to 19%), but the amount bounded was 4 to 12 μg g− 1. The residual fraction increased from 24% to 41% (5 to 25 μg g− 1, S1 to S6). The distribution of Cd in the sediment was almost independent of the sampling stations and was bound to carbonate, reducible and residual fraction in similar proportion. Cu and Zn at S1 were mainly bound to carbonates and reducible phases with 91% and 73% (2779 and 965 μg g− 1, respectively), and with a change in the pH and/or the redox potential of the sediment–water system, these contaminants could easily enter the food chain. In S6 the amount of Cu and Zn in these phases was 50% and 53% (100 to 313 μg g− 1, respectively).  相似文献   

6.
The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S1, and is almost everywhere parallel to lithological layering, S0. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S0. S1 formed by coaxial pure shear flattening strain (Z normal to S0, i.e. vertical; with X and Y both extensional and lying in S1). This strain also produced chocolate tablet boudinage of some layers and S1-concordant sills and veins. S1 has a strong stretching lineation L1 with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L1-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F1 folds with hinges parallel to the stretching lineation. F1 fold asymmetry variations do not support previous models involving macroscopic F1 folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.  相似文献   

7.
Simple shear of deformable square objects   总被引：1，自引：0，他引：1  
Finite element models of square objects in a contrasting matrix in simple shear show that the objects deform to a variety of shapes. For a range of viscosity contrasts, we catalogue the changing shapes and orientations of objects in progressive simple shear. At moderate simple shear (γ=1.5), the shapes are virtually indistinguishable from those in equivalent pure shear models with the same bulk strain (RS=4), examined in a previous study. In theory, differences would be expected, especially for very stiff objects or at very large strain. In all our simple shear models, relatively competent square objects become asymmetric barrel shapes with concave shortened edges, similar to some types of boudin. Incompetent objects develop shapes surprisingly similar to mica fish described in mylonites.  相似文献   

8.
Many of the faults within the Lake Moondarra area cropout as wide zones which are filled with massive or fibrous milky quartz. Additionally, a variety of rock fragments from the surrounding metasediments are present in the fault zones. The second regional slaty cleavage, S2, is locally observed through the quartz and country rock fragments within some of the zones, indicating that these fault fills originated pre- or early syn-S2. The absence of the first regional slaty cleavage, S1, suggests that the fault fills developed post or late syn-S1. Evidence supporting an early syn-S2 timing for the development of these fills is provided by the results of oxygen isotope analysis carried out on quartz specimens collected from the faults and also by the nature of the quartz. Specimens of quartz taken from the various fault zones have δ18O values between 12.4 and 14.5‰. This suggests that metamorphic water isotopically equilibrated with connate formation water was the aqueous fluid which transported the silica. δ18O values for the silica in the quartz-rich, sometimes dolomitic, metasediments of the Mount Isa and Haslingden Groups within the Lake Moondarra area are similar to the quartz within the fault fills. The lack of any metamorphic event between the first and second deformation, together with the sometimes fibrous nature of the fault-filling material with fibres parallel to the mineral elongation in S2 (i.e. L22), suggests that the quartz in the faults was derived syntectonically at grain to grain contacts in the metasediments within the Lake Moondarra area, early in the development of S2. The quartz is believed to have moved by the process of solution transfer to the faults as they underwent dilation during D2. Subsequently the quartz was precipitated as a result of a chemical potential gradient.  相似文献   

9.
Silica-tube quenching experiments and gold-tube pressure experiments were used to study phase relations in the PbS-rich portion of the system Pb-As-S. Emphasis was placed on determining the P-T-X stability relations of jordanite, the most Pb-rich of the synthetic Pb-As-S compounds. Jordanite, Pb9As4S15, is stable below 549 ± 3° C, at which temperature it melts to galena, liquid, and a sulfur-rich vapor phase. Confining pressures of up to 2 Kb do not measurably change this reaction temperature. Density measurements on synthetic material show that the jordanite cell contains 3 (Pb9As4S15); space group P21/m requires that the cell content be expressed as either Pb28–xAs12S46–x or Pb26+xAs12S44+x, with the former much more probable from a structural point of view. In both cases 0.8 < x < 1.4 and the situation is thus quite different from the usual case of defect structures, such as pyrrhotite, Fe1–xS, which shows considerable range of solid solution. Heating experiments on natural gratonite (Pb9As4S15) show that this mineral is most probably a low-temperature dimorph of jordanite, the inversion occurring below 250° C. Experiments have also confirmed the extensive substitution of Sb for As in jordanite, as suspected from chemical analyses of the isostructural mineral geocronite (Pb28–x(As,Sb)12S46–x).
Zusammenfassung Durch Abschreckversuche mit Hilfe von Quarz- und Gold-Druckampullen wurden die Phasenbeziehungen im PbS-reichen Teil des Pb-As-S-Systems studiert. Besonderer Wert wurde auf die Feststellung der P-T-X-Stabilitätsverhältnisse des Jordanits, des Pb-reichsten Phase der synthetischen Pb-As-S-Reihe, gelegt. Jordanit (Pb9As4S15) ist unterhalb 549 ± 3° C stabil, wo er sich semikongruent zu PbS, einer Schmelze und einer schwefelreichen Dampfphase zersetzt. Drucke bis zu 2 kb ergaben keine meßbaren Änderungen dieser Reaktionstemperatur. Dichtemessungen am synthetischen Material weisen darauf hin, daß die Jordanitzelle 3 × (Pb9As4S15) enthält. Die Raumgruppe P21/m fordert entweder die Formel Pb28–xAs12S46–x oder Pb26+xAs12S44+x, wobei die erstere Form strukturell wahrscheinlicher zu sein scheint. In beiden Fällen ist 0.8 < x < 1.4 und weicht vom gebräuchlichen Begriff der Defektstrukturen, wie z.B. beim Pyrrhotin (Fe1–xS) ab, wie das bemerkenswerte Mischkristallfeld zeigt. Erhitzen von natürlichem Gratonit (Pb9As4S15) zeigt, daß dieses Mineral sehr wahrscheinlich eine dimorphe Tieftemperaturphase des Jordanits ist. Die Umwandlung erfolgt unterhalb 250° C. Außerdem wurde eine umfangreichere Substitution von As durch Sb im Jordanit festgestellt, was nach den chemischen Analysen des isostrukturellen Geochronits Pb28–x(As,Sb)12S46–x) zu erwarten war.
  相似文献   

10.
The thermodynamic stability of selected alkylated, dealkylated and rearranged 17α- and 17β-hopane isomers in the C27, C28, C29, C30 and C31 families were calculated using molecular mechanics (MM2) methods and, where possible, calculated equilibrium ratios of certain isomers were compared with observed ratios of isomers in thermally mature crude oil samples. Those calculated and observed ratios having similar values include: (1) the relative distributions among 17β(H)/17α(H) and 21β(H)/21α(H)-hopanes including the absence of the 17β(H),21β(H)- and 17α(H),21α(H)-hopanes; (2) the 22R/22S ratios in 30-methyl-17α-hopane and 30-methyl-17β-moretane; (3) the relative distributions among 17α(H)/17β(H)- and 21α(H)/21β(H)-28,30-bisnorhopanes and among 25,28,30-trisnorhopanes, including the relatively greater stability of 17β(H) isomers in contrast to the regular hopane series; and (4) the ratios of 28(18−17S)abeo hopanes with respect to their unrearranged counterparts including the C27 compounds, Ts/Tm.  相似文献   

11.
To understand the generation mechanism of the Bam earthquake (Mw 6.6), we studied three-dimensional VP, VS and Poisson's ratio (σ) structures in the Bam area by using the seismic tomography method. We inverted accurate arrival times of 19490 P waves and 19015 S waves from 2396 aftershocks recorded by a temporal high-sensitivity seismic network. The 3-D velocity structure of the seismogenic region was well resolved to a depth of 14 km with significant velocity variations of up to 5%. The general pattern of aftershock distribution was relocated by using the 3-D structure to delineate a source fault for a length of approximately 20 km along a line 4.5 km west of the known geological Bam fault; this source fault dips steeply westward and strikes a nearly north–south line. The main shallow cluster of aftershocks south of the city of Bam is distributed just under the minor surface ruptures in the desert. The 3-D velocity structure shows a thick layer of high VS and low σ (minimum: 0.20) at a depth range of 2–6 km. The deeper layer, with a thickness of about 2 km, appears to have a low VS and high σ (maximum: 0.28) from 6 km depth beneath Bam to a depth of 9 km south of the city. The inferred increase of Poisson's ratio from 2 to 10 km in depth may be associated with a change from rigid and SiO2-rich rock to more mafic rock, including the probable existence of fluids. The main seismic gap of aftershock distribution at the depth range of 2 to 7 km coincides well with the large slip zone in the shallow thick layer of high VS and low σ. The large slip propagating mainly in the shallow rigid layer may be one of the main reasons why the Bam area suffered heavy damage.  相似文献   

12.
The Rock-Eval pyrolysis and TOC analysis have been widely used to evaluate the source rock quality. The atomic H/C ratio of kerogen, however, has been overlooked in source rock evaluation. In this study, coal and carbonaceous samples, including 26 from northwestern Taiwan, 12 from China, and 4 from the United States were analyzed, and integrated with 157 published data, to explore the significance of atomic H/C ratio as a parameter of source rock evaluation. Two different linear trends were observed in the cross-plot of S 1 versus S 2. Field outcropped shale or C-shale exhibits a steeper slope compared to that of coal samples which can be attributed to the compositional difference in their organic material. A rather strong positive correlation for H% versus S 2 illustrates the contribution of H-containing macerals, especially exinite. Organic matters in the samples studied are of type II/III kerogen based on the relationship between HI and T max. The H/C ratio, as well as the HI, S 1, and S 2, generally decreases with the maturity increasing. The H/C ratio decreases slightly from 1.1 to 0.7 with the maturity increasing from R o 0.55 to 0.85%. Samples with H/C ratio in this range show significant change in certain other geochemical parameters (e.g. HI, S 1, S 2, S 1 + S 2, S 1/(S 1 + S 2), S 1/TOC, (S 1 + S 2)/TOC, T max). The (S 1 + S 2)/TOC ratio (defined as QI) was used as an indicator of the hydrocarbon potential. The QI, HI, and H/C ratio show a certain correlation, all increasing accordingly. The QI of the samples analyzed in this study is approximately 100–380 (mgHC/gTOC), similar to that of most humic coals for oil and gas generation. Samples with R o value lower than 0.55% always show significant variation in their HI, ranging from 80 to 520 mgHC/gTOC. It is inferred that hydrocarbon potential started from R o 0.55% and atomic H/C ratio 1.1 in this study.  相似文献   

13.
This paper describes the distribution of Fe and Ni between the octahedral and tetrahedral sites in pentlandite (Fe,Ni)9S8. The dependence of the distribution on pressure and temperature and the activation energy of the cation exchange reaction were determined through annealing experiments. Synthetic crystals were annealed at 433–723 K and pressures up to 4 GPa, and natural crystals were annealed at 423, 448 and 473 K in evacuated silica capillary tubes for various durations. The cation distributions in the synthetic crystals were determined with an X-ray powder method employing the anomalous dispersion effect of CuK. and FeK radiations, while those of natural crystals were calculated from the cell dimensions. The values of U, S and V for the Fe/Ni exchange reaction are –6818 J mol–1, 20.52 J K–1 mol–1, and 6.99 × 10–6 m3 mol–1, respectively. The dependence of the Fe/Ni distribution on pressure (Pa) and temperature (Kelvin) was determined as lnK = 2.47+8.20 × 102 T –1+8.41 x 10–7 T –1 P, where K = (Fe/Ni)octahedral /(Fe/Ni)tetrahedral. The activation energy of the cation exchange reaction was 185 kJ mol–1.  相似文献   

14.
A distribution-free estimator of the slope of a regression line is introduced. This estimator is designated Sm and is given by the median of the set of n(n – 1)/2 slope estimators, which may be calculated by inserting pairs of points (X i, Yi)and (X j, Yj)into the slope formula S i = (Y i – Yj)/(X i – Xj),1 i < j n Once S m is determined, outliers may be detected by calculating the residuals given by Ri = Yi – SmXi where 1 i n, and chosing the median Rm. Outliers are defined as points for which |Ri – Rm| > k (median {|R i – Rm|}). If no outliers are found, the Y-intercept is given by Rm. Confidence limits on Rm and Sm can be found from the sets of Ri and Si, respectively. The distribution-free estimators are compared with the least-squares estimators now in use by utilizing published data. Differences between the least-squares and distribution-free estimates are discussed, as are the drawbacks of the distribution-free techniques.  相似文献   

15.
Summary Pb–Bi–(Cu)-sulfosalts occur as minor minerals widely distributed in rocks of the Penninic unit (gneisses, schists, metavolcanics, etc.), Oberpinzgau, Salzburg. The sulfosalts have been investigated by ore microscopy, X-ray diffraction and electron microprobe analysis. The phases identified are: heyrovskyite, cosalite (Moaralm, Sedl, and Wiesbachrinne in the Habach Valley), lillianite (Moaralm, Sedl; Modereck near the Fuscher Valley), galenobismutite (Bärenbad in the Hollersbach Valley) and Bi-bearing galena. Heyrovskyite (Moaralm) has a composition close to Pb6Bi2S9, with Ag contents between 0.2 (Sedl) and 0.6 (Moaralm) wt.%. Lillianite has the composition Pb2.86–2.91 Bi2.08–2.17Ag0.04–0.08 S6, and cosalite, Pb1.81–2.04 Bi1.92–2.02 Ag0.02–0.06 Cu0.11–0.18S5. The average chemical composition of galenobismutite is Pb1.25Bi1.6Sb0.1Cu0.1Ag0.02Fe0.1S4. Needle-like inclusions of a joseite-type mineral, joseite-A (Bi,Pb)4.01 Te0.9S2.08, and irregular to needle-like grains of native bismuth usually occur along the elongation direction of the lath-like galenobismutite crystals.The occurrences can be divided into two types: 1) stratiform Pb–Bi sulfosalts which occur only in the quartzite intercalations of the Paleozoic Habach unit (Frasl, 1958), and 2) alpidic vein type Pb–Bi sulfosalts which occur in quartz veins intersecting gneisses and are considered to be the remobilization products of the first type. Temperature of formation for heyrovskyite in this region is estimated at between 400±25°C and 500°C. Most probably, the assemblage heyrovskyite-lillianite-galena (Moaralm) was formed at or below 473°C.
Pb–Bi–(Cu)-Sulfosalze in paläozoischen Gesteinen des Oberpinzgau, Salzburg, Österreich
Zusammenfassung Pb–Bi-Sulfosalze verschiedener Vorkommen des Oberpinzgau, Salzburg, wurden mittels Erzmikroskopie, röntgenographischer Methoden und Mikrosonde untersucht. Folgende Phasen wurden identifiziert: Heyrovskyit, Cosalit (Moaralm, Sedl und Wiesbachrinne; alle Habachtal), Lillianit (Moaralm, Sedl; Modereck nahe des Fuschertales), Galenobismutit (Bärenbad, Hollersbachtal) und Bi-hältiger Bleiglanz. Heyrovskyit (Moaralm) ist nahezu Pb6Bi2S9, mit Ag-Gehalten zwischen 0,2 (Sedl) und 0.6 (Moaralm) Gew.%, Lillianit Pb2,86–2,91Bi2,08–2,17Ag0,04–0,08S6, und Cosalit Pb1,81–2,04Bi1,92–2,02Ag0,02–0,06 Cu0,11–0,18S5. Galenobismutit ist Pb1,25Bi1,6Sb0,1Cu0,1Ag0,02Fe0,1S4. Nadelige Einschlüsse von Joseit-A, (Bi, Pb)4,01Te0,9S2,08, und unregelmäßige bis nadelige Körner von ged. Wismut treten entlang der Längsrichtung der Galenobismutit-Kristalle auf. Die Mineralisationen sind an stratiforme, sulfidreiche Quarzlagen (Typus 1, z. B. Bärenbad) oder an diskordante Quarzgänge (Typus 2; alle anderen Vorkommen) gebunden. Typus 1 tritt innerhalb der altpaläzozischen Habachserie (Frasl, 1958), Typus 2 in Randbereichen dieser zu den Gneismassen der Habachzunge (z. T. auch in letzteren) auf. Die dem Typus 2 zugerechneten Vererzungen werden als Remobilisationsprodukte der altpaläozoischen Mineralisationen (Typus 1) angesehen.Die Bildungstemperatur des Heyrovskyit dürfte im betrachteten Bereich zwischen 400±25°C und 500°C gelegen haben; eine Bildungstemperatur von 473°C oder wening darunter wird für die Assoziation Heyrovskyit-Lillianit-Bleiglanz in Anlehnung an experimentelle Untersuchungen vonSalanci undMoh (1969) angenommen.

With 4 Figures

This investigation forms part of a wider study Genetic types of gold deposits in the Alps.  相似文献   

16.
雷祥义 《第四纪研究》1992,12(2):128-135,194
黄土高原南部晚更新世黄土地层包括三层黄土（L11、L12、L13）和三层古土壤(S01、S02、S1),共六个层次。Q4/Q3界线划在S0/L11界面上,年龄约为10000aB.P.;Q3/Q2界线划在S1/L2界面上,年龄约为120000aB.P.。在区域上自北向南,晚更新世黄土的显微结构由微胶结结构组合逐渐过渡为半胶结结构组合,直到胶结结构组合,黄土的力学性质相应地由差变好。在剖面中自上而下,黄土的显微结构类型与其力学性质指标之间亦存在着上述变化规律。研究结果表明,黄土的显微结构类型作为评价黄土工程性质的一种简便方法大有在工程实践中推广使用的前景。  相似文献   

17.
The magnitude of the in situ stresses in the Cooper–Eromanga Basins have been determined using an extensive petroleum exploration database from over 40 years of drilling. The magnitude of the vertical stress (Sv) was calculated based on density and velocity checkshot data in 24 wells. Upper and lower bound values of the vertical stress magnitude are approximated by Sv = (14.39 × Z)1.12 and Sv = (11.67 × Z)1.15 functions respectively (where Z is depth in km and Sv is in MPa). Leak-off test data from the two basins constrain the lower bound estimate for the minimum horizontal stress (Shmin) magnitude to 15.5 MPa/km. Closure pressures from a large number of minifrac tests indicate considerable scatter in the minimum horizontal stress magnitude, with values approaching the magnitude of the vertical stress in some areas. The magnitude of the maximum horizontal stress (SHmax) was constrained by the frictional limits to stress beyond which faulting occurs and by the presence of drilling-induced tensile fractures in some wells. The maximum horizontal stress magnitude can only be loosely constrained regionally using frictional limits, due to the variability of both the minimum horizontal stress and vertical stress estimates. However, the maximum horizontal stress and thus the full stress tensor can be better constrained at individual well locations, as demonstrated in Bulyeroo-1 and Dullingari North-8, where the necessary data (i.e. image logs, minifrac tests and density logs) are available. The stress magnitudes determined indicate a predominantly strike-slip fault stress regime (SHmax > Sv > Shmin) at a depth of between 1 and 3 km in the Cooper–Eromanga Basins. However, some areas of the basin are transitional between strike-slip and reverse fault stress regimes (SHmax > Sv ≈ Shmin). Large differential stresses in the Cooper–Eromanga Basins indicate a high upper crustal strength for the region, consistent with other intraplate regions. We propose that the in situ stress field in the Cooper–Eromanga Basins is a direct result of the complex interaction of tectonic stresses from the convergent plate boundaries surrounding the Indo-Australian plate that are transmitted into the center of the plate through a high-strength upper crust.  相似文献   

18.
Cross correlations of ambient seismic noise recordings are studied to infer shear-wave velocities (VS) profiles versus depth. Experiments are performed, over inter-station distances ranging from 60 m to about 400 m, in the crowded and noisy historical centre of Napoli, where the conditions for the use of active (controlled source) seismic spreadings are prohibitive, even for just one receiver. From the noise cross correlation, group velocity dispersion curves are extracted, with FTAN method, and their non-linear inversion supplies VS profiles versus depth. The information of nearby stratigraphies and the range of VS variability for samples of Neapolitan soils and rocks confirms the validity and reliability of the results obtained with our expeditious procedure. If successfully tested in other geological settings, the proposed approach is a low cost methodology to get reliable VS velocity profiles versus depth.  相似文献   

19.
We have performed experiments to constrain the effect of sulfur fugacity (fS2) and sulfide saturation on the fractionation and partitioning behavior of Pt, Pd and Au in a silicate melt–sulfide crystal/melt–oxide–supercritical aqueous fluid phase–Pt–Pd–Au system. Experiments were performed at 800 °C, 150 MPa, with oxygen fugacity (fO2) fixed at approximately the nickel–nickel oxide buffer (NNO). Sulfur fugacity in the experiments was varied five orders of magnitude from approximately log fS2 = 0 to log fS2 = −5 by using two different sulfide phase assemblages. Assemblage one consisted initially of chalcopyrite plus pyrrhotite and assemblage two was loaded with chalcopyrite plus bornite. At run conditions pyrrhotite transformed compositionally to monosulfide solid solution (mss), chalcopyrite to intermediate solid solution (iss), and in assemblage two chalcopyrite and bornite formed a sulfide melt. Run-product silicate glass (i.e., quenched silicate melt) and crystalline materials were analyzed by using both electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry. The measured concentrations of Pt, Pd and Au in quenched silicate melt in runs with log fS2 values ranging from approximately 0.0 to −5.0 do not exhibit any apparent dependence on fS2. The measured Pt, Pd and Au concentrations in mss do vary as a function of fS2. The measured Pt, Pd and Au concentrations in iss do not appear dependent on fS2. The data suggest that fS2, working in concert with fO2, via the determinant role that these variables play in controlling the magmatic sulfide phase assemblage and the solubility of Pt, Pd and Au as lattice bound components in magmatic sulfide phases, is a controlling factor on the budgets of Pt, Pd and Au during the evolution of magmatic systems.  相似文献   

20.
The role of the uppermost mantle strength in the pattern of lithosphere rifting is investigated using a thermo-mechanical finite-element code. In the lithosphere, the mantle/crust strength ratio (SM/SC) that decreases with increasing Moho temperature TM allows two strength regimes to be defined: mantle dominated (SM > SC) and crust dominated (SM < SC). The transition between the two regimes corresponds to the disappearance of a high strength uppermost mantle for TM > 700 °C. 2D numerical simulations for different values of SM/SC show how the uppermost mantle strength controls the style of continental rifting. A high strength mantle leads to strain localisation at lithosphere scale, with two main patterns of narrow rifting: “coupled crust–mantle” at the lowest TM values and “deep crustal décollement” for increasing TM values, typical of some continental rifts and non-volcanic passive margins. The absence of a high strength mantle leads to distributed deformations and wide rifting in the upper crust. These numerical results are compared and discussed in relation with series of classical rift examples.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号