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1.
The July–August 2001 eruption of Mt. Etna stimulated widespread public and media interest, caused significant damage to tourist facilities, and for several days threatened the town of Nicolosi on the S flank of the volcano. Seven eruptive fissures were active, five on the S flank between 3,050 and 2,100 m altitude, and two on the NE flank between 3,080 and 2,600 m elevation. All produced lava flows over various periods during the eruption, the most voluminous of which reached a length of 6.9 km. Mineralogically, the 2001 lavas fall into two distinct groups, indicating that magma was supplied through two different and largely independent pathways, one extending laterally from the central conduit system through radial fissures, the other being a vertically ascending eccentric dike. Furthermore, one of the eccentric vents, at 2,570 m elevation, was the site of vigorous phreatomagmatic activity as the dike cut through a shallow aquifer, during both the initial and closing stages of the eruption. For 6 days the magma column feeding this vent was more or less effectively sealed from the aquifer, permitting powerful explosive and effusive magmatic activity. While the eruption was characterized by a highly dynamic evolution, complex interactions between some of the eruptive fissures, and changing eruptive styles, its total volume (~25×10 6 m 3 of lava and 5–10×10 6 m 3 of pyroclastics) was relatively small in comparison with other recent eruptions of Etna. Effusion rates were calculated on a daily basis and reached peaks of 14–16 m 3 s -1, while the average effusion rate at all fissures was about 11 m 3 s -1, which is not exceptionally high. The eruption showed a number of peculiar features, but none of these (except the contemporaneous lateral and eccentric activity) represented a significant deviation from Etna's eruptive behavior in the long term. However, the 2001 eruption could be but the first in a series of flank eruptions, some of which might be more voluminous and hazardous. Placed in a long-term context, the eruption confirms a distinct trend, initiated during the past 50 years, toward higher production rates and more frequent eruptions, which might bring Etna back to similar levels of activity as during the early to mid seventeenth century.  相似文献   

2.
Soil gas sampling for 1,4‐dioxane at elevated soil temperatures, such as those experienced during in‐situ thermal treatment, has the potential to yield low results due to condensation of water vapor in the ambient temperature sampling vessel and the partitioning of 1,4‐dioxane into that condensate. A simple vapor/condensate sampling apparatus was developed to collect both condensate and vapor samples to allow for determination of a reconstituted effective soil gas concentration for 1,4‐dioxane. Results using the vapor/condensate sampling apparatus during a heated air injection SVE field demonstration are presented, along with those of a comparable laboratory system. Substantial 1,4‐dioxane mass was found in the condensate in both the lab and field (as high as ~50% in field). As soil temperatures increased, less 1,4‐dioxane mass was detected in field condensate samples than expected based on laboratory experiments. Extraction well effluent sampling at the wellhead by direct vapor canister sampling provided erratic results (several biased low by a factor of 5 or more) compared to those of the vapor/condensate apparatus. Direct vapor canister sampling of extraction well effluent after the air‐water separator, however, provided results reasonably comparable (within 35%) to those using the vapor/condensate apparatus at the wellhead. Soil gas sampling at elevated temperatures using the vapor/condensate apparatus alleviates potential low sampling bias due to condensation.  相似文献   

3.
This paper presents the results from the simulation of a phreatomagmatic eruption, in which the formation of the eruptive column is controlled by interaction between magma and water or ice. The process leads to intensive fragmentation of the magma and to mixing of ash and steam with ambient air. Such processes were typical of the initial phase in the April 2010 eruption of Eyjafjallajökull Volcano. It is hypothesized that phreatic explosions produce a dynamic pulsating system that consists of buoyant volumes of the mixture (thermals) that are forming at the base of the eruptive column. A 3-D simulation was used to assess two possible regimes in the evolution of the eruptive column: (1) continuous transport of the mixture into the eruptive column through its base for the case in which the thermals are generated at a high rate and (2) periodic flotation of the thermals whose diameters are comparable with that of the base of the eruptive column. It is shown that one can find a suitable selection of the initial concentrations of ash, steam, and air to achieve a satisfactory agreement between theory and actually observed heights of the gas–ash “clouds” that were formed during the Eyjafjallajökull eruption. The data for our calculations were taken from publications. We also investigated how wind and the changes in the initial parameters affect the process.  相似文献   

4.
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5.
Data collected by a pressure sensor provide new insights into the 1999 eruption of Shishaldin volcano, Unimak Island, Alaska. On 19 April 1999, after 3 months of unrest and an extended period of low-level Strombolian activity, Shishaldin experienced a Subplinian eruption (ash plume to >16 km), followed by several episodes of strong Strombolian explosions. Acoustic data from the pressure sensor allow us to investigate the details of an eruption which was instrumentally well recorded, but with few visual observations. In the 12 h prior to the Subplinian phase, the pressure sensor detected a series of small, repeated pulses with a constant spectral peak at 2–3 Hz. The amplitude and occurrence rate of the pulses both grew such that the signal became a nearly continuous hum just before the Subplinian eruption. This humming signal may represent gas release from rising magma. The main Subplinian phase was heralded by (1) the abrupt end of the humming signal, (2) several pulses of low-frequency sound interpreted as ash bursts, and (3) a dramatic increase in seismic tremor amplitude. The change in acoustic signature at this time allows us to precisely time the start of the Subplinian eruption, previously approximated as the time of strongest tremor increase. The 50-min Subplinian phase actually contained several bursts of signal, each of which may represent a discrete volume of magma passing through the system. Following the Subplinian event, the pressure sensor recorded four discrete episodes of Strombolian gas explosions on 19–20 April and another on 22–23 April. Four of the five episodes were accompanied by strong seismic tremor; the fifth has not been previously recognized and was not associated with anomalous tremor amplitudes. In time series these events are similar to explosions recorded at other volcanoes but in general they are much larger, with maximum amplitudes of >65 Pa at 6.5 km from the vent, and they have low (0.7–1.5 Hz) peak frequencies. These large explosions occurred at rates of 3–20 per minute for 1–5 h in each episode. The explosions were accompanied by a small (<5 km above sea level) ash plume and only minor amounts of ejecta were produced. Thus, the explosion activity was dominated by gas release.  相似文献   

6.
The persistent activity of Yasur volcano, a post-caldera scoria cone in the southern Vanuatu Arc, along with the uniformity exhibited by its eruptive products, indicates that it is a “steady-state” volcano. This implies that rates of magma replenishment and tapping are in equilibrium. Examination of recently exposed tephra sequences suggests that Strombolian-style activity at Yasur has persisted in its current form for the last 630–850 years. Eruption of tephra with uniform grain size and texture throughout this period indicates invariant eruption magnitude and style. Based on tephra accumulation rates, a uniform, time-averaged eruption flux of ～410–480 m3 days?1 is estimated. Major and trace element analyses of glass shards and mineral grains from these tephra deposits show limited variation in magma composition throughout that time, consistent with a chemically buffered magma reservoir and models for steady-state volcanism. Similarly, mineral crystallisation temperature estimates are within error, suggesting the magma reservoir has retained a constant temperature through this time, while pressure estimates suggest shallow crystallisation. Eruptions appear to be driven by gas release, with small fluctuations in magma chemistry and eruptive behaviour governed by perturbations in volatile flux. This period of steady-state activity was preceded by ～600 years of higher-magnitude, lower-frequency eruptions during which less evolved compositions were erupted. Variation between these two styles of eruptive behaviour may be explained by a shift from a periodically closed to fully opened conduit, allowing more regular magma release and changes to degassing regimes. New radiocarbon ages suggest a period of irregular eruptive behaviour extending >1,400 year B.P. Overall, a transition from an irregular to a very steady magmatic system has occurred over the past ～2 kyr. Previously determined tectonic indicators for caldera resurgence in the area suggest revived magma replenishment after a hiatus following the caldera-forming Siwi eruption. This replenishment, while now supplying today’s constant activity, has not yet manifested itself in variations in composition or style/magnitude of eruptions.  相似文献   

7.
The 1968–73 (and continuing) eruption of Arenal Volcano, Costa Rica, a small 1633 m strato-volcano with long periods of repose, defines an eruptive cycle which is typical of Arenal’s pre-historic eruptions. An intense, short explosive phase (July 29–31, 1968) grades into an effusive phase, and is followed by a block lava flow. The eruptive rocks become increasingly less differentiated with time in a given cycle, ranging from andesite to basaltic andesite. Nuées ardentes are a characteristic of the initial explosions, and are caused by fall-back ejecta on slopes around the main crater — an explosion crater in the 1968 eruption — which coalesce into hot avalanches and descend major drainage channels. Total volume of pyroclastic flows was small, about 1.8 ± 0.5 × 10n m3, in the July 29–31 explosions, and are block and ash flows, with much accidental material. Overpressures, ranging up to perhaps 5 kilobars just prior to major explosions, were estimated from velocities of large ejected blocks, which had velocities of up to 600 m/sec. Total kinetic energy and volume of ejecta of all explosions are an estimated 3 × 1022 ergs and 0.03 km3, respectively. The block lava flow, emitted from Sept., 1968 to 1973 (and continuing) has a volume greater than 0.06 km3, and covers 2.7 km2 at thicknesses ranging from 15 to over 100 m. The total volumes of the explosive and effusive phases for the 1968–73 eruption are about 0.05 km3 and 0.06 km3, respectively. The last eruption of Arenal occurred about 1500 AD. based on radiocarbon dating and archaeological means, and was about twice as voluminous as the current one (0.17 km3 versus 0.09 km3). The total thermal energies for this pre-historic eruption and the current one are 8 × 1023 and 18 × 1023, respectively. The total volume of Arenal’s cone is about 6 km3 from 1633 m (summit) to 500 m, and, estimates of age based on the average rate of cone growth from these two eruptions, suggest an age between 20,000 to 200,000 years.  相似文献   

8.
Atmospheric particulate matter (PM) is one of the pollutants that may have a significant impact on human health. Data collected over 7 years from the air quality monitoring station at the LD-III steelworks, belonging to the Arcelor-Mittal Steel Company, located in the metropolitan area of Avilés (Principality of Asturias, Northern Spain), is analyzed using four different mathematical models: vector autoregressive moving-average, autoregressive integrated moving-average (ARIMA), multilayer perceptron neural networks and support vector machines with regression. Measured monthly, the average concentration of pollutants (SO2, NO and NO2) and PM10 (particles with a diameter less than ?10 μm) is used as input to forecast the monthly average concentration of PM10 from one to 7 months ahead. Simulations showed that the ARIMA model performs better than the other models when forecasting 1 month ahead, while in the forecast from one to 9 months ahead the best performance is given by the support vector regression.  相似文献   

9.
Lava flows spanning the eruptive record of Graciosa Island (Azores archipelago) and a gabbro xenolith were dated by 40Ar/39Ar in order to constrain the Pleistocene and Holocene volcanic evolution of the island. The results range from 1.05 Ma to 3.9 ka, whereas prior published K–Ar and 14C ages range from 620 to 2 ka. The formation of the Serra das Fontes shield volcano started at minimum 1.05 Ma, and the magmatic system was active for ca. 600 ky, as suggested by the formation of the gabbro xenolith by magmatic differentiation. Evolved magmas making up the Serra das Fontes–Serra Branca composite volcano were generated at ca. 450 ka. After a period of ca. 110 ky of volcanic inactivity and erosion of volcanic edifices, volcanism was reactivated with the formation of the Vitória Unit NW platform. Later, the development of the Vulcão Central Unit started with the formation of monogenetic cones located to the south of the Serra das Fontes–Serra Branca–Vitória Unit. This volcanism became progressively more evolved and was concentrated in a main eruptive center, forming the Vulcão Central stratovolcano with an age older than 50 ka. The caldera related to this stratovolcano is older than 47 ka and was followed by effusion of basaltic magmas into the caldera, resulting in the formation of a lava lake, which ultimately spilled over the caldera rim at ca. 11 ka. The most recent eruptions on Graciosa formed two small pyroclastic cones within the caldera and the Pico do Timão cone within the Vitória Unit at ca 3.9 ka.  相似文献   

10.
Mt. Etna, in Sicily (Italy), is one of the world's most frequent emitters of volcanic plumes. During the last ten years, Etna has produced copious tephra emission and fallout that have damaged the inhabited and cultivated areas on its slopes and created serious hazards to air traffic. Recurrent closures of the Catania International airport have often been necessary, causing great losses to the local economy. Recently, frequent episodes of ash emission, lasting from a few hours to days, occurred from July to December 2006, necessitating a look at additional monitoring techniques, such as remote sensing. The combination of a ground monitoring system with polar satellite data represents a novel approach to monitor Etna's eruptive activity, and makes Etna one of the few volcanoes for which this surveillance combination is routinely available.In this work, ash emission information derived from an integrated approach, based on comparing ground and NOAA–AVHRR polar satellite observations, is presented. This approach permits us to define the utility of real time satellite monitoring systems for both sporadic and continuous ash emissions. Using field data (visible observations, collection of tephra samples and accounts by local inhabitants), the duration and intensity of most of the tephra fallout events were evaluated in detail and, in some cases, the order of magnitude of the erupted volume was estimated. The ground data vs. satellite data comparison allowed us to define five different categories of Etna volcanic plumes according to their dimensions and plume height, taking into account wind intensity. Using frequent and good quality satellite data in real time, this classification scheme could prove helpful for investigations into a possible correlation between eruptive intensity and the presence and concentration of ash in the volcanic plume. The development and improvement of this approach may constitute a powerful warning system for Civil Protection, thus preventing unnecessary airport closures.  相似文献   

11.
Impact of large-scale explosive eruptions largely depends on the dynamics of transport, dispersal and deposition of ash by the convective system. In fully convective eruptive columns, ejected gases and particles emitted at the vent are vertically injected into the atmosphere by a narrow, buoyant column and then dispersed by atmosphere dynamics on a regional scale. In fully collapsing explosive eruptions, ash partly generated by secondary fragmentation is carried and dispersed by broad co-ignimbrite columns ascending above pyroclastic currents. In this paper, we investigate the transport and dispersion dynamics of ash and lapillis during a transitional plinian eruption in which both plinian and co-ignimbrite columns coexisted and interacted. The 800 BP eruptive cycle of Quilotoa volcano (Ecuador) produced a well-exposed tephra sequence. Our study shows that the sequence was accumulated by a variety of eruptive dynamics, ranging from early small phreatic explosions, to sustained magmatic plinian eruptions, to late phreatomagmatic explosive pulses. The eruptive style of the main 800 BP plinian eruption (U1) progressively evolved from an early fully convective column (plinian fall bed), to a late fully collapsing fountain (dense density currents) passing through an intermediate transitional eruptive phase (fall + syn-plinian dilute density currents). In the transitional U1 regime, height of the convective plinian column and volume and runout of the contemporaneous pyroclastic density currents generated by partial collapses were inversely correlated. The convective system originated from merging of co-plinian and co-surge contributions. This hybrid column dispersed a bimodal lapilli and ash-fall bed whose grain size markedly differs from that of classic fall deposits accumulated by fully convective plinian columns. Sedimentological analysis suggests that ash dispersion during transitional eruptions is affected by early aggregation of dry particle clusters.  相似文献   

12.
The Mont-Dore Massif (500 km2), the youngest stratovolcano of the French Massif Central, consists of two volcanic edifices: the Guéry and the Sancy. To improve our knowledge of the oldest explosive stages of the Mont-Dore Massif, we studied 40Ar/39Ar-dated (through single-grain laser and step-heating experiments) 11 pyroclastic units from the Guéry stratovolcano. We demonstrate that the explosive history of the Guéry can be divided into four cycles of explosive eruption activity between 3.09 and 1.46 Ma (G.I to G.IV). We have also ascertained that deposits associated with the 3.1–3.0-Ma rhyolitic activity, which includes the 5-km3 “Grande Nappe” ignimbrite, are not recorded in the central part of the Mont-Dore Massif. All the pyroclastites found in the left bank of the Dordogne River belong to a later explosive phase (2.86–2.58 Ma, G.II) and were channelled down into valleys or topographic lows where they are currently nested. This later activity also gave rise to most of the volcanic products in the Perrier Plateau (30 km east of the Mont-Dore Massif); three quarters of the volcano-sedimentary sequence (up to 100 m thick) was emplaced within less than 20 ky, associated with several flank collapses in the northeastern part of the Guéry. The age of the “Fournet flora” (2.69?±?0.01 Ma) found within an ash bed belonging to G.II suggests that temperate forests already existed in the French Massif Central before the Pliocene/Pleistocene boundary. The Guéry’s third explosive eruption activity cycle (G.III) lasted between 2.36 and 1.91 Ma. It encompassed the Guéry Lake and Morangie pumice and ash deposits, as well as seven other important events recorded as centimetric ash beds some 60 to 100 km southeast of the Massif in the Velay region. We propose a general tephrochronology for the Mont-Dore stratovolcano covering the last 3.1 My. This chronology is based on 44 40Ar/39Ar-dated events belonging to eight explosive eruption cycles each lasting between 100 and 200 ky. The occurrence of only one pumice deposit in the 800-ky period between 1.9 and 1.1 Ma suggests that volcanic explosive activity was strongly reduced or quiescent.  相似文献   

13.
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14.
Gas samples were collected by aircraft entering volcanic eruption clouds of three Guatemalan volcanoes. Gas chromatographic analyses show higher H2 and S gas contents in ash eruption clouds and lower H2 and S gases in vaporous gas plumes. H isotopic data demonstrate lighter isotopic distribution of water vapor in ash eruption clouds than in vaporous gas plumes. Most of the H2O in the vaporous plumes is probably meteoric. The data are the first direct gas analyses of explosive eruptive clouds, and demonstrate that, in spite of atmospheric admixture, useful compositional information on eruptive gases can be obtained using aircraft.  相似文献   

15.
The violent August 16–17, 2006 Tungurahua eruption in Ecuador witnessed the emplacement of numerous scoria flows and the deposition of a widespread tephra layer west of the volcano. We assess the size of the eruption by determining a bulk tephra volume in the range 42–57 × 106 m3, which supports a Volcanic Explosivity Index 3 event, consistent with calculated column height of 16–18 km above the vent and making it the strongest eruptive phase since the volcano’s magmatic reactivation in 1999. Isopachs west of the volcano are sub-bilobate in shape, while sieve and laser diffraction grain-size analyses of tephra samples reveal strongly bimodal distributions. Based on a new grain-size deconvolution algorithm and extended sampling area, we propose here a mechanism to account for the bimodal grain-size distribution. The deconvolution procedure allows us to identify two particle subpopulations in the deposit with distinct characteristics that indicate dissimilar transport-depositional processes. The log-normal coarse-grained subpopulation is typical of particles transported downwind by the main volcanic plume. The positively skewed, fine-grained subpopulation in the tephra fall layer shares close similarities with the elutriated co-pyroclastic flow ash cloud layers preserved on top of the scoria flow deposits. The area with the higher fine particle content in the tephra layer coincides with the downwind prolongation of the pyroclastic flow deposits. These results indicate that the bimodal distribution of grain size in the Tungurahua fall deposit results from synchronous deposition of lapilli from the main plume and fine ash elutriated from scoria flows emplaced on the western flank of the volcano. Our study also reveals that inappropriate grain-size data processing may produce misleading determination of eruptive type.  相似文献   

16.
The behaviour of a magma plumbing system during a cycle of volcanic edifice growth is investigated with a simple physical model. Loading by an edifice at Earth's surface changes stresses in the upper crust and pressures in a magma reservoir. In turn, these changes affect magma ascent from a deep source to the reservoir and from reservoir to Earth's surface. The model plumbing system is such that a hydraulic connection is maintained at all times between the reservoir and a deep magma source at constant pressure. Consequently the input rate of magma into the reservoir is predicted by the model rather than imposed as an input parameter. The open hydraulic connection model is consistent with short-term measurements of deformation and seismicity at several active volcanoes. Threshold values for the reservoir pressure at the beginning and end of eruption evolve as the edifice grows and lead to long-term changes of eruption rate. Depending on the dimensions and depth of the reservoir, the eruption rate follows different trends as a function of time. For small reservoirs, the eruption rate initially increases as the edifice builds up and peaks at some value before going down. The edifice size at the peak eruption rate provides a constraint on the reservoir shape and depth. Edifice decay or destruction leads to resumption of eruptive activity and a new eruption cycle. A simple elastic model for country rock deformation is valid over a whole eruptive cycle extending to the cessation of eruptive activity. For large reservoirs, an elastic model is only valid over part of an eruptive cycle. Long-term stress changes eventually lead to reservoir instability in the form of either roof collapse and caldera formation or reservoir enlargement in the horizontal direction.  相似文献   

17.
The analyses which have so far been made of volcanic gases have only given instantaneous measurements of the composition of the gas phase which, however, is likely to be variable during periods of eruptive activity. A first step towards the continuous measurement of fluctuations in the composition of the gas phase during eruptions was made in 1963, by the use of sampling tubes permitting the rapid determination in the field of individual components of gaseous emanations. Since then, a technique has been developed of collecting samples of volatile constituents and preserving them for subsequent analyses in the laboratory. On the other hand, a technique has been developed for continuous sampling with a distant recording mechanism, which permits the study of the dynamics of eruptive phenomena. The first results of observations on several different types of emanations (submarine, high and low temperature fumaroles, and gas discharges from basalt flows) may considered satisfactory. The present paper is intended to encourage volcanologists concerned with the study of eruptive phenomena to employ new methodes for the study of this problem. The analysis of the eruptive mechanisms should start with a simultaneous observation and recording of the greatest possible number of parameters. The gas phase is of fundamental importance in the eruptive phenomena. It is therefore indispensable to understand its variations with time, both rapid and slow. It is very important to be able to show, on the same diagram, curves representing the simultaneous variations of all the measurable parameters, chemical, physical, and mechanical.  相似文献   

18.
Volcanic tremor at the Hekla volcano is directly related to eruptive activity. It starts simultaneously with the eruptions and dies down at the end of them. No tremor at Hekla has been observed during non-eruptive times. The 1991 Hekla eruption began on 17 January, after a short warning time. Local seismograph stations recorded small premonitory earthquakes from 16:30 GMT on. At 17:02 GMT, low-frequency volcanic tremor became visible on the seismograph records, marking the onset of the eruption. The initial plinian phase of the eruption was short-lived. During the first day several fissures were active but, by the second day, the activity was already limited to a segment of one principal fissure. The eruption lasted almost 53 days. At the end of it, during the early hours of 11 March, volcanic tremor disappeared under the detection threshold and was followed by a swarm of small earthquakes. At the start of the eruption, the tremor amplitude rose rapidly and reached a maximum in only 10 min. The tremor was most vigorous during the first hour and started to decline sharply during the next hour, and later on more gently. During the eruption as a whole, the tremor had a continuous declining trend, with occasional increases lasting up to about 2 days. Spectral analysis of the tremor during the first 7 h of the eruption shows that it settled quickly, within a couple of minutes, to its characteristic frequency band, 0.5–1.5 Hz. The spectrum had typically one dominant peak at 0.7–0.9 Hz, and a few subdominant peaks. Hekla tremor likely has a shallow source. Particle motion plots suggest that it contains a significant component of surface waves. The tremor started first when the connection of the magma conduit with the atmosphere was reached, suggesting that degassing may contribute to its generation.  相似文献   

19.
The Nevado de Toluca is a quiescent volcano located 20 km southwest of the City of Toluca and 70 km west of Mexico City. It has been quiescent since its last eruptive activity, dated at ∼ 3.3 ka BP. During the Pleistocene and Holocene, it experienced several eruptive phases, including five dome collapses with the emplacement of block-and-ash flows and four Plinian eruptions, including the 10.5 ka BP Plinian eruption that deposited more than 10 cm of sand-sized pumice in the area occupied today by Mexico City. A detailed geological map coupled with computer simulations (FLOW3D, TITAN2D, LAHARZ and HAZMAP softwares) were used to produce the volcanic hazard assessment. Based on the final hazard zonation the northern and eastern sectors of Nevado de Toluca would be affected by a greater number of phenomena in case of reappraisal activity. Block-and-ash flows will affect deep ravines up to a distance of 15 km and associated ash clouds could blanket the Toluca basin, whereas ash falls from Plinian events will have catastrophic effects for populated areas within a radius of 70 km, including the Mexico City Metropolitan area, inhabited by more than 20 million people. Independently of the activity of the volcano, lahars occur every year, affecting small villages settled down flow from main ravines.  相似文献   

20.
The vent-hosted hydrothermal system of Ruapehu volcano is normally covered by a c. 10 million m3 acidic crater lake where volcanic gases accumulate. Through analysis of eruption observations, granulometry, mineralogy and chemistry of volcanic ash from the 1995–1996 Ruapehu eruptions we report on the varying influences on environmental hazards associated with the deposits. All measured parameters are more dependent on the eruptive style than on distance from the vent. Early phreatic and phreatomagmatic eruption phases from crater lakes similar to that on Ruapehu are likely to contain the greatest concentrations of environmentally significant elements, especially sulphur and fluoride. These elements are contained within altered xenolithic material extracted from the hydrothermal system by steam explosions, as well as in residue hydrothermal fluids adsorbed on to particle surfaces. In particular, total F in the ash may be enriched by a factor of 6 relative to original magmatic contents, although immediately soluble F does not show such dramatic increases. Highly soluble NaF and CaSiF6 phases, demonstrated to be the carriers of ‘available’ F in purely magmatic eruptive systems, are probably not dominant in the products of phreatomagmatic eruptions through hydrothermal systems. Instead, slowly soluble compounds such as CaF2, AlF3 and Ca5(PO4)3F dominate. Fluoride in these phases is released over longer periods, where only one third is leached in a single 24-h water extraction. This implies that estimation of soluble F in such ashes based on a single leach leads to underestimation of the F impact, especially of a potential longer-term environmental hazard. In addition, a large proportion of the total F in the ash is apparently soluble in the digestive system of grazing animals. In the Ruapehu case this led to several thousand sheep deaths from fluorosis.  相似文献   

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