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1.
根据2003～2008年松辽平原中南部地区多目标区域地球化学调查成果,研究了典型黑土区有机质的分布特征,提出了绥化-哈尔滨-四平一线典型黑土区有机质含量具有纬度地带性分布特点,有机质由北向南逐渐降低.分析了土壤有机质的影响因素,认为土壤的成土母质和土壤质地是决定有机质含量的重要基础,湖相沉积物和土壤质地细腻,黏粒成分多,有机质含量高.气温和降水等气候条件是影响土壤有机质的主要因素,低温湿润气候条件有利于有机质积累.耕地开垦时间长、作物连作和化肥使用等人为因素降低了有机质含量. 相似文献
2.
Taking limestone soil and yellow soil, the two major soil types in karst areas as examples, analyzing stable carbon isotope composition (δ13C value) of soil organic matter (SOM) in bulk soils and particle-size fractions of four soil profiles under three vegetable forms, the following results are reached: in the limestone soil profile, soil organic carbon contents are all above 1.0%, the highest value is 7.1% in the surface soil; however, they are between 0.3% and 4.6% in the three yellow soil profiles. From the surface to the bottom of the soil profiles, the variation of δ13C value of soil organic carbon for limestone soil profile is only between −24.1‰ and −23.0‰, however, it’s between −24.8‰ and −21.1‰ for yellow soil profiles. The variation range of δ13C value of soil organic carbon associated with particle-size separates is slight for limestone soil but is considerable for yellow soil. The contrast research indicates that the changes between the contents and the δ13C value of soil organic carbon with depth are complex. The vertical patterns of stable carbon isotope in soil organic matter have a distinct regional characteristic in karst areas. 相似文献
3.
Assessment of degradation of agricultural soils arising from brick burning in selected soil profiles
H. R. Khan Ph.D. K. Rahman Ph.D. A. J. M. Abdur Rouf Ph.D. G. S. Sattar Y. Oki Ph.D. T. Adachi 《International Journal of Environmental Science and Technology》2007,4(4):471-480
The study was conducted with the selected soil profile of burnt (soil around brick kilns) and unburnt (agricultural land) soils in the Dinajpur, Rangpur, Rajshahi, Khulna and Patuakhali districts at the western part of Bangladesh to evaluate the effects of brick kilns on soil degradation and environmental pollution. The pH values of the unburnt soils increased as a function of the soil depth for Rangpur, Khulna and Patuakhali, while decreased for the soil profiles in Dinajpur. Burning of soils significantly (p<0.05) decreased the average pH values of soils by 0.4 pH units (7 % increased over average content = IOAC), but strikingly increased the average EC values from 0.26 to 1.77 mS/cm (592 % IOAC) and the effect was pronounced with the depth function. The average sand content of the soil profiles increased by 330%, while the silt and clay contents decreased by 49 and 40 %, respectively. The average losses arising from the burning of agricultural soils were amounted to 63% for organic matter, 56 to 86 % and 23 to 88 % for available and total N, P, K and S, respectively. This huge loss through the burning of 1 m deep soil profile, i.e. almost 3/4th of the deterioration of soil fertility is not only reducing the crop production but also polluting the associated environment and atmosphere. The burning of enormous C, N and S not only degrade the agricultural soils but also contributing to the changes in the global climate. 相似文献
4.
选取内蒙古主要产粮基地之一的托克托地区作为研究对象,以多目标地球化学调查获取的1 556个表层土壤样品的测试数据为基础数据,基于多元地学数据空间数据管理与分析系统(GeoExpl)对土壤中有机质、全氮、全磷、全钾含量进行描述统计及空间分布分析,并采用模糊数学和改进的内梅罗指数对区内的土壤养分综合质量进行分级。结果表明：研究区表层土壤养分综合质量中等,土壤养分因子的含量水平为全钾＞全磷＞有机质＞全氮,磷元素和钾元素是土壤养分的主要贡献因子,氮元素为土壤养分的最主要限制性因子;从养分因子的空间分布状况看,研究区北部及西北部的土壤养分状况较好。在此基础上,根据土壤养分综合质量、地形及地表状况对研究区进行了简单的农业分区规划,认为研究区西北部的平原区为主要的农业生产区。 相似文献
5.
Radiocarbon Dating of Soil Organic Matter 总被引：2，自引：0，他引：2
Radiocarbon ages of soil organic matter are evaluated with a model which incorporates the dynamics of the14C content of soil organic matter. Measured14C ages of soil organic matter or its fractions are always younger than the true ages of soils due to continuous input of organic matter into soils. Differences in soil C dynamics due to climate or soil depth will result in significantly different14C signatures of soil organic matter for soils of the same age. As a result, the deviation of the measured14C age from the true age of soil formation could differ significantly among different soils or soil horizons. Our model calculations also suggest that14C ages of soil organic matter will eventually reach a steady state provided that no climatic or ecological perturbations occur. Once a soil or a soil horizon has reached a steady state,14C dating of soil organic matter will provide no useful information regarding the age of the soil. However, for soils in which steady state has not been reached, it is possible to estimate the age of soil formation by modeling the measured14C contents of soil organic matter. Radiocarbon dating of buried soils could, in general, overestimate the true age of the burial by as much as the steady-state age of the soil or soil horizon. 相似文献
6.
The influence of Zn speciation on Zn transport by drainage from different soils to surface water is examined in a stream catchment
in an agricultural area. Drainage waters were collected from two types of soils, a mineral soil (MS) and a soil rich in organic
matter (OS) by means of artificial drainage pipes. The speciation of dissolved Zn in the stream and the drainage waters was
determined using ligand-exchange and voltammetry. About 50–95% of dissolved Zn is bound in strong complexes, and the free
Zn2+ ion concentration is in the range of 1–16% of dissolved Zn. A substantial part of Zn is present in weaker organic or inorganic
complexes. The simulated Zn speciation using the WHAM VI model is compared to the determined speciation. Free Zn2+ concentrations predicted by the WHAM VI model are generally higher than the analytically determined free Zn2+, but are mostly within the same order of magnitude. Effects of different soil organic matter content on Zn speciation and
transport are discussed. Zn speciation in the drainage at the OS site is influenced by the distribution of organic matter
between the solid and solution phase. The abundant organic Zn complexes in solution contribute to facilitate Zn transport
from soil into surface waters, through the drainage at the OS site. Drainage from the OS site contributes about twice as much
Zn input to the receiving water as the MS soil, as related to specific area. The mineral soil contains much lower organic
matter, and a part of Zn bound with inorganic phases can hardly be released by dissolved organic ligands, leading to much
higher Zn retention at the MS site. 相似文献
7.
N has a controlling effect on litter biodegradation in the forest floor, while stabilization of organic matter in the mineral soil may be influenced by physical parameters related to soil texture. In this study, in order to understand the processes involved in soil organic matter (SOM) formation, the chemical composition of SOM was followed and evaluated with regards to N contents and soil texture. Samples were taken on sites covered with Norway spruce and displaying contrasting values of C/N ratios in the forest floor. The chemical structure of OM was characterized using solid-state CPMAS 13C and 15N nuclear magnetic resonance (NMR) spectroscopy, along with Proton Spin Relaxation Editing (PSRE) sequences. Four groups of sampling sites were defined based on the NMR spectra of Oh and A horizons. In each group displaying similar NMR characteristics, N content and soil texture could be highly different among sites. Some Oh horizons with similar NMR spectra had very different N contents. Highly humified OM in Oh horizons were observed mainly on sites with low N contents. Some A horizons with different soil texture displayed similar OM chemical structure. High contents of O-alkyl C in some A horizons could originate from higher fresh root material input. 相似文献
8.
To predict the long-term behavior of arsenic(As) in soil profiles,the solid-solution partitioning of As was studied in four paddy soil profiles obtained from agricultural areas in Chengdu Plain,Southwest China.Paddy soil profile samples were collected and soil solution samples were extracted.Total As contents in soil solution and soil solid were analyzed,along with the soil solid phase properties.The As in soil solution was significantly higher in the upper layer(0—20 cm) and had a definite tendency to decrease towards 40 cm regardless of the sampling locations.When the concentration of arsenic in soil solution decreased,its content in solid phase increased.Field-based partition coefficient(K_d) for As was determined by calculating the ratio of the amount of As in the soil solid phase to the As concentration in the soil solution.K_d values varied widely in vertical samples and correlated well with soil pH,total organic carbon(TOC) and total As. The results of this study would be useful for evaluating the accumulation trends of arsenic in soil profiles and in improving the management of the agricultural soils. 相似文献
9.
Lipid components in a soil profile developed in an agricultural terrace at a Minoan site on Pseira Island, Crete, were analyzed to determine whether the practice of manuring in antiquity, as inferred by distributional and temporal sherd scatter, could be confirmed through the use of biomarker compounds as proxies for manuring. Analysis of total organic carbon and the abundance of n‐alkyl lipids (n‐alkanols and fatty acids) demonstrated that while the upper part of the soil profile had received more recent inputs of vegetation‐derived organic matter, the deeper archaeological strata remained essentially undisturbed. Further analysis of 5β‐stanols, sterol components which may be utilized as fecal biomarkers, revealed a signal indicative of manuring, with human or porcine‐derived fecal material, in the lower 15 cm of the profile. Additional appraisal of epicoprostanol abundance inferred the possible practice of composting in later periods. This study represents a detection of manuring, in the oldest samples to date, using organic geochemical methods. © 2001 John Wiley & Sons, Inc. 相似文献
10.
【研究目的】为仁怀市农业生产中土壤养分的合理利用、农业结构调整及土地利用价值的提升等提供科学依据。【研究方法】本文利用电感耦合等离子体发射光谱法、容量法及电位法获取了5486件表层土壤样品氮磷钾（全量和有效态）及有机质的含量，系统研究了其地球化学特征及含量影响因素。【研究结果】仁怀市耕地土壤氮、磷、钾、有机质、碱解氮、速效磷及速效钾的平均值分别为1.74 g/kg、0.75 g/kg、19.90 g/kg、30.90 g/kg、100.28 mg/kg、10.40 mg/kg和101.03 mg/kg。其中，氮、碱解氮、磷、钾及有机质的含量及分布与地层关系密切；速效磷及速效钾的含量及分布与地层关系较差。仁怀市耕地土壤肥力较好，以较丰富等级为主，较丰富及丰富等级占比为57.6%。其中，氮、磷及钾皆处于丰富水平；碱解氮及有机质处于中等水平；速效磷及速效钾处于缺乏水平。【结论】仁怀市耕地土壤养分的含量及分布不仅受地质背景、土壤类型、海拔高度、酸碱度及土壤深度等自然因素影响，还与土地利用方式等人为活动有关。创新点：系统统计了仁怀市耕地土壤氮磷钾（全量和有效态）及有机质的含量，对其地球化学等级开展了评价，并系统分析了它们的含量影响因素。耕地土壤养分的含量及分布不仅受地质背景、土壤类型等自然因素影响，还与土地利用方式等人为活动有关。 相似文献
11.
12.
Organic and inorganic geochemistry of some coastal plain rivers of the southeastern United States 总被引：1，自引：0，他引：1
In a comprehensive study of the distribution of organic and inorganic constituents in natural waters, the chemical compositions of several rivers flowing through the Coastal Plain of southeast Georgia (the Satilla River, in particular) have been investigated. These streams are generally characterized by low suspended load, low ionic strength, low pH values, and a predominance of organic over inorganic constituents. The dominance of sodium and chloride among inorganic ions indicates that rainfall is a major factor in determining the distribution of major elements in these waters. The low pH values and the relatively high concentrations of iron and aluminum appear to result from the high concentrations of organic matter. Chemical analysis (total acidity, carboxyl groups, amino acid residues, and CHN analysis) and spectroscopic analysis (i.r. and NMR) indicate that river water organic matter is chemically similar to soil fulvic acids.The dominance of organic matter over inorganic constituents and the resultant low pH values of these waters are in direct contrast with the chemical compositions of most of the rivers of the world which have been previously studied. Many large tributaries draining from the low relief tropical basins of the Amazon and other tropical rivers are expected to show similar characteristics; however, none of these has been studied extensively. 相似文献
13.
为系统研究石煤矿山周边耕地富硒土壤地球化学特征及影响因素,在浙江省常山县辉埠石煤矿山周边耕地采集了表层土壤样品144件、农产品甘蔗样20件、土壤垂向剖面土壤样6件、岩石样5件和地表水样3件。通过样品Se、有机质、As、Cd、Cu、Pb、Zn、Ni、Hg、Cr等元素含量指标测定和统计,探究了该区富硒土壤地球化学特征。结果表明:区内表层土壤硒含量主要集中于0.47~1.34 mg/kg之间,平均含量0.87 mg/kg,远高于浙江省平均值,且硒含量高值区与辉埠石煤矿的走向一致;硒含量随着土壤深度增加而逐渐下降;89.58%的土壤样品和65%的甘蔗样品达到富硒标准,但存在土壤和农产品Cd等主要重金属元素含量超标的生态风险。土壤硒含量均值在寒武系下统荷塘组最高(1.31 mg/kg),奥陶系中—下统最低(0.64 mg/kg);旱地硒均值略高于水田,但差异不显著(p>0.05);硒含量均值高低变化为粗骨土>石灰岩土>水稻土>红壤。研究认为,土壤硒含量受地质背景、土壤类型和有机质等因素的影响,含石煤层黑色岩系和碳酸盐岩等富硒地层是形成富硒土壤的主要因素,小部分与矿山开采等人类活动有关。 相似文献
14.
Characteristics and distributions of humic acid (HA) and soil organic matter (SOM) in a yellow soil profile and a limestone soil profile of the southwest China Karst area were systematically investigated to reveal their evolutions in different soils of the study area. The results showed that characteristics and distribution of SOM along the two soil profiles were notably different. Total organic carbon (TOC) contents of soil samples decreased just slightly along the limestone soil profile but sharply along the yellow soil profile. TOCs of the limestone soils were significantly higher than those of the corresponding yellow soils, and C/N ratios of SOMs showed a similar variation trend to that of TOCs, indicating that SOM can be better conserved in the limestone soil than in the yellow soil. The soil humic acids were exhaustively extracted and further fractionated according to their apparent molecular weights using ultrafiltration techniques to explore underlying conservation mechanisms. The result showed that C/N ratios of HAs from different limestone soil layers were relatively stable and that large molecular HA fractions predominated the bulk HA of the top soil, indicating that HA in the limestone profile was protected while bio and chemical degradations were retarded. Combined with organic elements contents and mineral contents of two soils, we concluded that high calcium contents in limestone soils may play a key role in SOM conservation by forming complexation compounds with HAs or/and enclosing SOMs with hypergene CaCO3 precipitation. 相似文献
15.
《Applied Geochemistry》1998,13(5):607-617
Distribution and forms of transition metals (Ti, Zn, Ni, Co, Mn, Fe, Cu, V and Cr) were investigated in oxidised, partly oxidised and reduced zones of sulphide-bearing fine-grained sediments located in the coastal areas of western Finland. Samples for the analysis and study of vertical distribution of elements were taken from each vertical 10 cm section in pits ranging in depth between 2 and 3 metres, while bulk samples for characterisation of species and forms of metals were taken from 3 zones in each pit: the acid sulphate soil (characterised by acid and oxidising conditions), transition zone (characterised by a steep pH gradient and partly oxidising conditions) and the reduced zone (pH >6). The former samples were digested in aqua regia (3:1:2 HCl:HNO3:H2O), while the latter were digested in aqua regia and hot concentrated acids (HClO4–HNO3–HCl–HF) and were subjected to extractions with acid ammonium acetate, H2O2 and acid ammonium oxalate. Each leachate was analysed for metals with ICP–AES.The vertical variation in the concentrations of Ti were small at all the studied sites indicating that the sediments are homogeneous and that the total losses of other elements from the soil profiles (acid sulphate soil+transition zone) are not extensive. Field observations, extractions with ammonium oxalate, and concentration–variation patterns indicated that Fe-oxide is largely precipitated and retained also in these acid soils. There are, however, indications of redistribution of Fe within the soil profiles. The results also demonstrated that Mn, Ni, Zn, Co and Cu have been lost in considerable amounts from the acid sulphate soils. However, whereas Mn in general has been lost throughout the soil profile, part of the Zn, Ni and Co released in the acid sulphate soils have migrated downward and been reimmobilised in the transition zone immediately above the reduced zone. Also Cu has been lost from the acid sulphate soil, but generally in smaller proportions than Mn, Zn, Ni and Co. Dissolved metal sulphides seem to be major sources of the mobilised metal fractions. A main part of the V and Cr in the sediments are associated with weathering-resistant minerals. These metals are therefore, like Ti, only to a limited extent mobilised by the oxidation of the sulphide-bearing sediments. 相似文献
16.
SIMON H. BOTTRELL ROBERT J.G. MORTIMER IAN M. DAVIES† S. MARTYN HARVEY‡ MICHAEL D. KROM 《Sedimentology》2009,56(4):1159-1173
In this study, the biogeochemical transformations of sulphur in organic‐rich marine sediments in a Scottish fjord are investigated by a combination of pore water and sediment geochemistry with sulphide diffusive gradient thin‐film probes and sulphate isotopic data (δ34S and δ18O). Particular attention is paid to sulphur cycling in the upper sediment profile where sulphate reduction occurs but free sulphide is below the detection limits of conventional pore water geochemical analysis but quantifiable by sulphide diffusive gradient thin film. In the uppermost part of the sediment core, δ18O sulphate decreased from near‐sea water values to +7‰, indicating that anoxic sulphide oxidation dominated during this interval. Sulphate δ34S remained unchanged as there was no net sulphate reduction (i.e. reduction was balanced by re‐oxidation). Below 4 cm depth, there was a slight increase in sulphate δ34S from 20‰ to 23‰ associated with minor accumulation of iron sulphide. The δ18O of the sulphate also increased, to around +10‰ at 10 cm depth, as a result of the isotopic exchange of sulphate–oxygen with pore water and/or sulphur disproportionation reactions mediated during sulphur cycling. These processes continued to increase the δ18O of the sulphate to 14‰ at 20 cm depth with no further change in the δ34S of the sulphate. Below 20 cm depth, free sulphide is detectable in pore waters and both the δ34S of the sulphate and sulphide increase with depth with an offset controlled by kinetic fractionation during bacterial sulphate reduction. The δ34S of the sedimentary organic fraction shifted towards lower, more bacteriogenic, values with depth in the profile, without any increase in the size of this sulphur pool. Thus, the organic sulphur fraction was open to interaction with bacteriogenic sulphide without the occurrence of net addition. Therefore, caution should be exercised when using sulphur isotopic compositions to infer simple net addition of bacteriogenic sulphide to the organic sulphur fraction. 相似文献
17.
In the area surrounding the El Teniente giant porphyry copper deposit, eight soil sites were sampled at three depth levels
in the summer 2004. The sites were selected for their theoretical potential of being influenced by past SO2 emissions from the smelter and/or seepage from a now idle tailings impoundment. The soil mineralogy, grain size distribution,
total organic matter contents, major element composition, cation exchange capacity, and Cu, Mo, Pb, Zn, As and SO4
2− concentrations were determined for all samples after nitric acid extraction and separate leaches by ammonium acetate (pH
7) and sodium acetate (pH 5). For water rinses, only Cu could be determined with the analytical set-up used. Cu and SO4
2− enrichment in topsoils was found at six sites either downwind from the smelter or within the combined influence of the smelter
and the tailings impoundment. Both elements were released partially by ammonium and sodium acetate extractions. Due to the
scarce background trace element concentrations of soil and rock outside the immediate mine area, assessment of trace element
mobility for Mo, Zn, Pb and As was difficult. Arsenic was found to be concentrated in soil horizons with high smectite and/or
organic matter contents. Mo appears to be linked to the presence of windblown tailings sediment in the soils. Mobilization
of Mo, Zn, and As for the acetate extractions was minimal or below the detection limits for the AAS technique used. The presence
of windblown tailings is considered to be an additional impact on the soils in the foothills of the El Teniente compound,
together with the potential of acidity surges and Cu mobilization in topsoils after rainfalls. Two sites located at the western
limit of the former SO2 saturated zone with strongly zeolitized soils and underlying rock did not show any Cu or SO4
2− enrichment in the topsoils, and remaining total trace element concentrations were below the known regional background levels. 相似文献
18.
湖州市不同土壤重金属的污染现状 总被引：3，自引：1，他引：3
湖州市是主要的农产品基地，其主要土壤类型有四种，即黄泥土、青紫泥、白泥土和湖松土。样品分析表明重金属元素在黄泥土和青紫泥中较高，白泥土和湖松土中较低。大多数重金属元素相对下蜀土是富集的，超过自然背景值的元素有Cu,Cd及部门土壤中的Pb和Hg。有机质、pH值和Eh值对重金属的含量和化学形态有影响，有机质愈高，重金属的含量愈高；pH值接近中性，重金属的含量亦高。土壤的氧化条件可使大多数重金属变为高价离子，它们的化合物活性较低，但Cr^6 易被植物吸收。湖州土壤中重金属的高值点与工业污水排放和大气沉降有关。土壤中对农作物有危害的重金属元素为Cd和Hg，局部地方为Pb。 相似文献
19.
Rakesh Mohindra 《地学学报》1995,7(3):305-314
Systematic variations in soil characteristics related to degree of soil profile development in part of the Middle Gangetic Plain suggest a soil chronoassociation similar to the soil chronosequences observed on some river terrace formed by tectonic uplift. This chronoassociation has five members QG1 to QG5, the youngest being QG1 (< 500 yr BP). Variations in degree of horizon differentiation, profile thickness, clay accumulation, plasma separation, argillan thickness, weathering stage and day mineralogy have been used to determine the degree of soil development.
Pedogenic processes active in these soils are decalcification, translocation of clay, sesquioxide and organic matter, plasma separation and weathering of minerals. The amount and variability of clay minerals are significantly related to the type and duration of pedogenesis in different parts of the area. The oldest soils with pedogenic calcite (10 000 yr BP) developed during a dry period. Since 8000 yr BP climatic conditions of higher rainfall and better drainage have prevailed in the area.
Neotectonic movements have tilted the Gandak megafan block and have caused shifting of the Gandak river to the east about 105 km from its original course, leaving behind numerous channels, ponds, lakes and other features of impeded drainage. 相似文献
Pedogenic processes active in these soils are decalcification, translocation of clay, sesquioxide and organic matter, plasma separation and weathering of minerals. The amount and variability of clay minerals are significantly related to the type and duration of pedogenesis in different parts of the area. The oldest soils with pedogenic calcite (10 000 yr BP) developed during a dry period. Since 8000 yr BP climatic conditions of higher rainfall and better drainage have prevailed in the area.
Neotectonic movements have tilted the Gandak megafan block and have caused shifting of the Gandak river to the east about 105 km from its original course, leaving behind numerous channels, ponds, lakes and other features of impeded drainage. 相似文献
20.
J. Y. Huang H. Richard S. F. Zheng 《International Journal of Environmental Science and Technology》2014,11(7):2009-2014
During the past 50 years, the amount of agricultural fertilizer used in Northern China increased from about 7.5 kg ha?1 in the 1950s to approximately 348 kg ha?1 in the 1990s. Given that little is known about the effects of nitrogen fertilization on soil labile carbon fraction in Northern China, this paper evaluated such effects in terms of microbial biomass and dissolved organic carbon in the Sanjiang Plain located in Northeast China. Soils with different cultivation time and undisturbed marsh with Deyeuxia angustifolia were selected to study the effects of nitrogen fertilization on the soil labile organic fractions microbial C (biomass C, microbial quotient, and basal respiration) and to estimate the contributions of nitrogen input on the dynamics of soil labile carbon. Continuous nitrogen application decreased total organic and dissolved organic carbon concentrations significantly, leading to the lack of carbon source for microbes. Therefore, continuous nitrogen fertilizer application induced negative effects on measured soil microbiological properties. However, a moderate nitrogen application rate (60 kg N ha?1) stimulated soil microbial activity in the short term (about 2 months), whereas a high nitrogen application rate (150 kg N ha?1) inhibited measured soil microbiological properties in the same period. 相似文献