首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 46 毫秒
1.
This study aims to remove of Cu2+, Cd2+, and Pb2+ ions from solution and to investigate the adsorption isotherms, adsorption kinetics, and ion‐exchange affinities of these metals using waste activated sludge (AS) biomass. The adsorptions of the metals on biomass were optimal at an acidic pH value of 6.0 based on its monolayer capacities. Maximum monolayer capacities of AS biomass (qmax) were calculated as 0.478, 0.358, and 0.280 mmol g?1 for Cu2+, Cd2+, and Pb2+, respectively, and the adsorption equilibrium time was found as 60 min for each metal. The adsorbed amount of metal rose with increasing of initial metal ion concentration. The equilibrium adsorption capacity of AS for initial 0.25 mmol L?1 metal concentration was determined as 0.200, 0.167, and 0.155 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively. These relevant values were determined as 0.420, 0.305, and 0.282 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively, when initial metal concentration was 0.50 mmol L?1. In the multi‐metal sorption system, the adsorption capacity of AS biomass was observed in the order of Cu2+ > Cd2+ > Pb2+. In the presence of 100 mmol L?1 H+ ion, the order of ion‐exchange affinity with H+ was found as Cu2+ > Cd2+ > Pb2+. The adsorption kinetics were also found to be well described by the pseudo‐second‐order and intraparticle diffusion models. Two different rate constants were obtained as ki1 and ki2 and ki1 (first stage) was found to be higher than ki2 (second stage).  相似文献   

2.
Observations of soil moisture and salt content were conducted from May to August at Neleger station in eastern Siberia. Seasonal changes of salt and soil moisture distribution in the active layer of larch forest (undisturbed) and a thermokarst depression known as an alas (disturbed) were studied. Electric conductivity ECe of the intact forest revealed higher concentrations that increased with depth from the soil surface into the active layer and the underlying permafrost: 1 mS cm?1 at 1·1 m, to 2·6 mS cm?1 at 160 cm depth in the permafrost. However, a maximum value of 5·4 mS cm?1 at 0·6 m depth was found in the dry area of the alas. The concentration of ions, especially Na+, Mg2+, Ca2+, SO42? and HCO3? in the upper layers of this long‐term disturbed site, indicates the upward movement of ions together with water. A higher concentration of solutes was found in profiles with deeper seasonal thawing. The accumulation of salts in the alas occurs from spring through into the growing season. The low concentration of salt in the surface soil layers appears to be linked to leaching of salts by rainfall. There are substantial differences between water content and electric conductivity of soil in the forest and alas. Modern salinization of the active layer in the alas is epigenetic, and it happens in summer as a result of spring water collection and high summer evaporation; the gradual salt accumulation in the alas in comparison with the forest is controlled by the annual balance of water and salts in the active layer. Present climatic trends point to continuous permafrost degradation in eastern Siberia increasing the risk of surface salinization, which has already contributed to changing the landscape by hindering the growth of forest. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

3.
Alan R. Hill 《水文研究》2012,26(20):3135-3146
The effect of preferential flow in soil pipes on nitrate retention in riparian zones is poorly understood. The characteristics of soil pipes and their influence on patterns of groundwater transport and nitrate dynamics were studied along four transects in a 1‐ to >3‐m deep layer of peat and marl overlying an oxic sand aquifer in a riparian zone in southern Ontario, Canada. The peat‐marl deposit, which consisted of several horizontal layers with large differences in bulk density, contained soil pipes that were generally 0.1 to 0.2 m in diameter and often extended vertically for 1 to >2 m. Springs that produced overland flow across the riparian area occurred at some sites where pipes extended to the peat surface. Concentrations of NO3?–N (20–30 mg L?1) and dissolved oxygen (DO) (4–6 mg L?1) observed in peat pipe systems and surface springs were similar to values in the underlying sand aquifer, indicating that preferential flow transported groundwater with limited nitrate depletion. Low NO3?–N concentrations of <5 mg L?1 and enriched δ15N values indicated that denitrification was restricted to small areas of the peat where pipes were absent. Groundwater DO concentrations declined rapidly to <2 mg L?1 in the peat matrix adjacent to pipes, whereas high NO3?–N concentrations of >15 mg L?1 extended over a larger zone. Low dissolved organic carbon values at these locations suggest that supplies of organic carbon were not sufficient to support high rates of denitrification, despite low DO conditions. These data indicate that it is important to develop a greater understanding of pipes in peat deposits, which function as sites where the transport of large fluxes of water with low biogeochemical reaction rates can limit the nitrate removal capacity of riparian zones. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

4.
The effects of oxygen supply rate and the presence or absence of nutrients on the kinetics of phenol degradation and oxygen consumption by a mixed microbial population were tested in a model system. The values for the maximum specific rate of phenol degradation (qSmax), the saturation constant (KS), and the inhibition concentration (SCR) were determined for unlimited growth (KLa = 340 h?1, growth medium) with 1.7 mmol g?1 h?1, 65 mg L?1, and 190 mg L?1. Under limitation conditions, alterations occur depending on the type of limitation. Nutrient limitations lead to values of 0.8 mmol g?1 h?1, 45 mg L?1, and 160 mg L?1, and oxygen limitations lead to 1.2 mmol g?1 h?1. 30 mg L?1, and 120 mg L?1, respectively. The results suggest that with excess oxygen, the rate of phenol degradation was higher and the inhibition effect of phenol was suppressed to some extent. Under the same high oxygen supply rate, the presence of nutrients in the model water significantly supported the phenol degradation rate.  相似文献   

5.
Limited information exists on one of the mechanisms governing sediment input to streams: streambank erosion by ground water seepage. The objective of this research was to demonstrate the importance of streambank composition and stratigraphy in controlling seepage flow and to quantify correlation of seepage flow/erosion with precipitation, stream stage and soil pore water pressure. The streambank site was located in Northern Mississippi in the Goodwin Creek watershed. Soil samples from layers on the streambank face suggested less than an order of magnitude difference in vertical hydraulic conductivity (Ks) with depth, but differences between lateral Ks of a concretion layer and the vertical Ks of the underlying layers contributed to the propensity for lateral flow. Goodwin Creek seeps were not similar to other seeps reported in the literature, in that eroded sediment originated from layers underneath the primary seepage layer. Subsurface flow and sediment load, quantified using 50 cm wide collection pans, were dependent on the type of seep: intermittent low‐flow (LF) seeps (flow rates typically less than 0·05 L min?1), persistent high‐flow (HF) seeps (average flow rate of 0·39 L min?1) and buried seeps, which eroded unconsolidated bank material from previous bank failures. The timing of LF seeps correlated to river stage and precipitation. The HF seeps at Goodwin Creek began after rainfall events resulted in the adjacent streambank reaching near saturation (i.e. soil pore water pressures greater than ?5 kPa). Seep discharge from HF seeps reached a maximum of 1·0 L min?1 and sediment concentrations commonly approached 100 g L?1. Buried seeps were intermittent but exhibited the most significant erosion rates (738 g min?1) and sediment concentrations (989 g L?1). In cases where perched water table conditions exist and persistent HF seeps occur, seepage erosion and bank collapse of streambank sediment may be significant. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

6.
This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L?1), dye concentration (50–300 mg L?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L?1, dye initial concentration of 50–50 mg L?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.  相似文献   

7.
Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al3+ and Be2+ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10?4 mol L?1 CAS, 0.5 mg L?1 Al3+ or 0.4 mg L?1 Be2+ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.  相似文献   

8.
Avi Gafni  Yechiel Zohar 《水文研究》2007,21(16):2164-2173
The bio‐drainage–commercial forestry strategy was applied in five plots in the Yizre'el Valley, northern Israel, to evaluate the hydrological and salinity impacts of eucalypt plantations. Each plot contained a mix of 11 selected eucalyptus species/ecotypes. Two plots (Nahalal and Genigar), representing the two extreme waterlogging/salinity conditions in the valley, were selected for in‐depth monitoring over a 10‐year period to assess the likely environmental improvement through bio‐drainage. Despite impressive growth rates of genetically improved Eucalyptus camaldulensis in the year‐round waterlogged, slightly saline Nahalal site (650 mm annual rainfall), the water uptake by the trees was insufficient to control the rising water table caused by excessive water inputs, both natural and human. In the more saline, alkaline and drier Genigar plot (450 mm annual rainfall), where rainfall is the only water input, the ground water dropped to below 3 m from soil surface in the fourth year after planting, i.e. deeper than the adjacent ground water levels. Both sites showed appreciable rise in wells that penetrated the 3‐ to 4‐m confining layer. The 10‐year salinity (EC) trend of the top layer in Nahalal varied because the drainage was limited by the positive water balance and the above‐average spells of dry winters. In and below the 4 m deep layer the EC remained below 1·5 dS m?1 throughout the entire 10‐year study. The last EC measurement, taken in 2003, showed values not higher than 4 dS m?1 throughout the 6 m soil profile. In Genigar, there was significant leaching of salts from the top layer (1 m) during the 9‐year monitoring period, but recently a salts ‘bulge’ was gradually developed in the 1–5 m strata indicating that the expected downward movement of leached salts was impeded by the 3–4 m deep low‐permeability clayey layer that lies over a coarser, far more conductive and notably confined layer, which leads to a perched water body. The last EC measurement at the end of 2003 showed a maximum value of 5·5 dS m?1 at 3 m depth. No signs of tree stress were observed in either site, at any soil depth during the 10 years of monitoring. Theoretical considerations do not support the hypothesis that there would be a fatal long‐term accumulation of salts in the root zone. The Israeli experience has shown that the bio‐drainage technique can effectively lower a shallow water table and reverse salinity trends, provided that the overall water balance is negative, i.e. that the water inputs match the water use by the tree plantation and local drainage characteristics. However, the rate of improvement of the hydraulic, salinity, sodicity and soil physical properties is site specific. Excess fresh water inputs into the plantation, although they create waterlogging conditions, supply unlimited water to the trees, which, in turn, show exceptional growth rates, with usable commercial value. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

9.
Estimating transpiration of the trees in agroforestry system is important in water management of the site. Sap flow of intercropped fast‐growing young poplar trees and microclimate factors in semiarid northeastern China was measured in two growing seasons (2008 and 2009). Sapwood growth and water storage of wood and leaf increment during the growing season were involved in the calculation of sap flow. The results showed that diurnal variation of sap flow followed to that of short wave solar radiation. Sap flows both in 10 min mean and daily gross values mainly depended on solar radiation and vapor pressure deficit, and the relations well fit hyperbolic function. The regression coefficients of monthly window data indicated that the seasonal variation of sap flow capacities decreased gradually from June to September. Moderate soil water stress of upper soil layer (0–50 cm) did not constrain the sap flow because the trees could use the water at deeper soil layer. The daily sap flow per tree ranged 0.8 to 18.1 and 3.7 to 23.8 kg d?1 tree?1, with averages of 8.7 and 14.3 kg d?1 tree?1 in 2008 and 2009 respectively. An empirical model was established to estimate the sap flow of the poplar trees by solar radiation, vapor pressure deficit, leaf area index and Julian days. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

10.
The rigin and fate of six phthalate esters (dimethyl phthalate (DMP), diethyl phthalate (DEP), di‐n‐butyl phthalate (DnBP), butyl benzyl phthalate (BBP), di (2‐ethylhexyl) phthalate (DEHP) and di‐n‐octyl phthalate (DnOP)), were investigated during 2005 and 2006 in the densely populated Seine river estuary. Four compounds, DMP, DEP, DnBP and DEHP were detected at all the stations with DEHP (160–314 ng L?1), followed by DEP (71–181 ng L?1) and next DnBP (67–319 ng L?1), except at la Bouille, where DnBP was the second most important compound. BBP and DnOP concentrations remained low and were not found at all the stations. Considering all six phthalates, Caudebec‐en‐Caux (beginning of the salinity gradient) was the least polluted station (464 ng L?1), whereas Honfleur (771 ng L?1) and La Bouille (716 ng L?1) displayed the highest contamination levels, probably related to important industrial plants. From Caudebec‐en‐Caux to Honfleur (maximum turbidity), variation of DEHP concentration was related to that of suspended matter. In addition, the salinity rise in that area might have facilitated DEHP sorption upon particles. A significant correlation between flow magnitude and DEHP concentration was found (P < 0·01, n = 12), supporting the influence of the hydrological cycle upon contamination. Runoff contribution (56·9 kg d?1) to river contamination was confirmed by the annual evolution of phthalate concentrations in the Seine river at Poses. Concentrations of DEHP in the tributaries were in the same range as those of the Seine River (100–350 ng L?1), except for two in densely populated and industrialized areas: Robec (800 ng L?1) and Cailly (970 ng L?1). The treatment plant discharge fluxes were in the same range as those of tributaries (30·4–250 g d?1). During high flow periods, the influence of tributaries and of treatment plants seemed to play a minor part in the contamination level of the Seine river estuary. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

11.
This study investigates the influence of Ca2+ and Mg2+ on the removal of F? by magnesium potassium phosphate (MPP) from water. The kinetic experiments reveal that the F? concentration decreased from 3.5 to 3.31 mg L?1 in a single (F?) system and to 1.45 mg L?1 in a ternary system (F?, Ca2+, and Mg2+) after 1 min, respectively. Thus, the F? removal efficiencies are found to increase by about 53% with the co‐active effect of Ca2+ and Mg2+ in the solution. Moreover, Ca2+ and Mg2+ are almost completely removed in the F?, Ca2+, and Mg2+ system. According to the pseudo‐first‐order modeling, the rate constants k for F?, Ca2+, and Mg2+ are 0.00348, 0.0106, and 0.0159 min?1 respectively; thus, Mg2+ > Ca2+ > F?. In the ternary system, the removal efficiencies are 53.29–66.03% for F?, 99.99–100% for Ca2+, and 87.21–95.19% for Mg2+ with initial pH 5–10. The removal efficiencies of F? increases with increases in initial concentrations of F?, Ca2+, and Mg2+. The removal of F? is governed by two routes: 1) adsorption by electrostatic interactions and outer sphere surface complexation; 2) co‐precipitation with Ca3(PO4)2, CaHPO4, Mg3(PO4)2, and Mg(OH)2.  相似文献   

12.
The broad (～500 km) southeastern Bering Sea continental shelf contains three fronts; outer (shelf break, ～170-m depth), middle (～100-m depth), and inner (～50-m depth). The shelf break and inner fronts appear to be analogous to similar fronts reported from other mid-latitude continental shelves; extensively studied examples are from the mid-Atlantic bight, off Nova Scotia, and around the British Isles. The middle front may have counterparts on the broad North Sea and East China Sea shelves.One-month current and temperature records from either side of the middle front, ～150 km landward from the shelf break, showed convergence in the layers deeper than 30 m in both the cross-shelf flow field and heat flux. The convergence was ～3 cm s?1, so an average upwelling at ～1 × 10?3cm s?1 and divergence in the surface layer were required to maintain continuity. Variations in the degree of convergence arose primarily from 1 to 5-day fluctuations in sub-tidal flow across the outer shelf domain seaward of the front.Diffusive landward heat flux was dominated by tidal scales. Horizontal eddy conductivities describing the flux were ～1 ? 106 on the landward side and ～5 × 106cm2 s?1 on the seaward side, and were less in the layers above the bottom layer. Advective flux by the mean flow was the same order as diffusive flux, but landward in the bottom layer and seaward in the mid-water column layers, in agreement with deductions from water mass analyses. Frontal effects reduced the net cross-shelf heat flux beneath ～30 m by about 50%. The observation of a flow convergence in the middle of a broad, flat continental shelf poses an important question of dynamics.  相似文献   

13.
Soil salt accumulation is a widespread problem leading to diminished crop yield and threatening food security in many regions of the world. The soil salinization problem is particularly acute in areas that lack adequate soil water drainage and where a saline shallow water table (WT) is present. In this study, we present laboratory-scale column experiments, extending over a period of more than 400 days that focus on the processes contributing to soil salinization. We specifically examine the combined impact of soil compaction, surface water application model and water quality on salt dynamics in the presence of a saline shallow WT. The soil columns (60 cm height and 16 cm diameter) were packed with an agricultural soil with bulk densities of 1.15 and 1.34 g/cm−3 for uncompacted and compacted layers, respectively, and automatically monitored for water content, salinity and pressure. Two surface water compositions are considered: fresh (deionized, DI) and saline water (~3.4 mS/cm). To assess the sensitivity of compaction on salt dynamics, the experiments were numerically modelled with the HYDRUS-1D computer program. The results show that the saline WT led to rapid salinization of the soil column due to capillarity, with the salinity reaching levels much higher than that at the WT. However, compaction layer provided a barrier that limited the downwards moisture percolation and solute transport. Furthermore, the numerical simulations showed that the application of freshwater can temporarily reverse the accumulation of salts in agricultural soils. This irrigation strategy can help, in the short-term, alleviate soil salinization problem. The soil hydraulic properties, WT depth, water quality, evaporation demand and the availability of freshwater all play a role in the practicability of such short-term solutions. The presence of a saline shallow WT would, however, rapidly reverse these temporary measures, leading to the recurrence of topsoil salinization.  相似文献   

14.
We attempted to clarify the runoff characteristics of a permafrost watershed in the southern mountainous region of eastern Siberia using hydrological and meteorological data obtained by the State Hydrological Institute in Russia from 1976 to 1985. We analysed seasonal changes in the direct runoff ratio and recession gradient during the permafrost thawing period. Thawing depth began to increase from the beginning of May and continued to increase until the end of September, exceeding 150 cm. Annual precipitation and discharge were in the range 525–649 mm and 205–391 mm respectively. The sum of the annual evapotranspiration and changes in water storage ranged from 235 to 365 mm. The mean daily evapotranspiration in June, July, August and September was 1·5 mm day?1, 1·7 mm day?1, 1·5 mm day?1, and 0·5 mm day?1 respectively. The direct runoff ratio was highest in June, decreasing from 0·8 in June to 0·2 in September. The recession gradient also decreased from June to September. Since the frozen soil functioned as an impermeable layer, the soil water storage capacity in the thawing part of the soil, the depth of which changed over time, controlled the runoff characteristics. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

15.
In this study the occurrence of diclofenac and sub‐products in effluent emerging from the University Hospital at the Federal University of Santa Maria was investigated. One metabolite was identified and, in aqueous solution, three degradation products. The quantification was conducted by means of HPLC‐DAD, and the determination of metabolite and degradation products by LC–ESI–MS/MS–QTrap. For the HPLC‐DAD method, a 70:30 mixture of methanol/sodium phosphate was used in isocratic mode. For the LC–ESI–MS/MS–QTrap determinations, a mobile phase, where phase A was an ammonium acetate solution 5 × 10?3 mol L?1, and phase B was methanol (5 × 10?3 mol L?1)/ammonium acetate (9:1, v/v), on gradient mode. The LDs for the HPLC and LC–MS/MS methods, respectively, were 2.5 and 0.02 µg L?1, the LQs, 8.3 and 0.05 µg L?1, and the linear range from 10 up to 2000 µg L?1 and 0.05 up to 10 µg L?1. As expected, the LC–ESI–MS/MS–QTrap method was more sensitive and less laborious. The metabolite 4′‐hydroxy‐diclofenac was identified. Photolysis was used for the degradation studies and three products of diclofenac were identified (m/z of 214, 286 and 303) in aqueous solution. These results notwithstanding, no degradation products of diclofenac were found in the hospital effluent.  相似文献   

16.
Zeyong Gao  Fujun Niu  Zhanju Lin 《水文研究》2020,34(26):5659-5673
Thermokarst lakes play a key role in the hydrological and biogeochemical cycles of permafrost regions. Current knowledge regarding the changes caused by permafrost degradation to the hydrochemistry of lakes in the Qinghai-Tibet Plateau (QTP) is limited. To address this gap, a systematic investigation of thermokarst lake water, suprapermafrost water, ground ice, and precipitation was conducted in the hinterland of the QTP. The thermokarst lake water in the QTP was identified to be of the Na-HCO3-Cl type. The mean concentrations of HCO3− and Na+ were 281.8 mg L−1 (146.0–546.2 mg L−1) and 73.3 mg L−1 (9.2–345.8 mg L−1), respectively. The concentrations of Li+, NH4+, K+, F−, NO2−, and NO3− were relatively low. Freeze-out fractionation concentrated the dissolved solids within the lake water during winter, which was deeply deepened on lake depth and lake ice thickness. Owing to solute enrichment, the ground ice was characterized by high salinity. Conversely, repeated replenishment via precipitation led to lower solute concentrations in the ground ice near the permafrost table compared to that within the permafrost. Although lower solute concentration existed in precipitation, the soil leaching and saline ground ice melting processes enhanced the solute load in suprapermafrost water, which is considered an important water and solute resource in thermokarst lakes. The influencing mechanism of permafrost degradation on thermokarst lake hydrochemistry is presumably linked to: (1) the liberation of soluble materials sequestered in ground ice; (2) the increase of solutes in suprapermafrost water and soil pore water; and (3) the changes in lake morphometry. These results have major implications on the understanding of the effects of ground ice melting on ecosystem functions, biogeochemical processes, and energy balance in a rapidly changing climate.  相似文献   

17.
The physico-chemical and hydrochemical characteristics of run-off of the Neglinka River Basin (northwest Russia) monitored for a year are different for the upstream and downstream sections. The river known hydrologically as the Neglinka, consists hydrochemically of two different streams: one represented by the upstream part of the basin, and the other one by the downstream. The upstream water is characterized by low mineralization (water hardness 0.08–0.43 mmol L?1) and low δ53Cr values (+0.30 to +0.42‰), whereas the lower part is characterized by high mineralization (water hardness 0.37–3.46 mmol L?1) and high δ53Cr values (+0.92 to +1.73‰). The difference in chemical composition of the upstream and downstream waters could be due to the underground discharge input. Aqueous chromium (Cr) mobilized from weathering profiles may have been reduced from soluble Cr(VI) to insoluble Cr(III) during the riverine transportation. Partial removal of Cr from the water balance resulted in a decrease in Cr concentration and an increase in δ53Cr values.  相似文献   

18.
Abstract

The multi-layered Jeffara de Gabes aquifer system is greatly influenced by tectonics. This system is limited at the base and laterally by evaporite layers and has lateral contacts with the sebkhas (salt flats). The groundwater in this aquifer is characterized by high salinity (3–10 g L-1). Multivariate statistical analysis and a geochemical approach were applied to determine the influence of the evaporite layers and sebkhas on the hydrochemical quality of the Jeffara de Gabes aquifer, and to understand the processes governing its salinity. According to these methods, and based in part on the Sr2+/Ca2+ ratio, it is demonstrated that the strong salinity of the groundwater is due to interactions between water and the evaporite layers that act as a substratum of this aquifer, as well as saltwater intrusion from the sebkhas. Moreover, the medium- to poor-quality groundwaters are characterized by geochemical interactions: cationic exchange and the precipitation/dissolution process of minerals in the aquifer formations.

Editeur Z.W. Kundzewicz

Citation Ben Alaya, M., Zemni, T., Mamou, A. et Zargouni, F., 2014. Acquisition de salinité et qualité des eaux d’une nappe profonde, Tunisie: approche statistique et géochimique. Hydrological Sciences Journal, 59 (2), 395–419.  相似文献   

19.
A simple and reliable method for rapid and selective extraction and determination of trace levels of Ni2+ and Mn2+ was developed by ionic liquid (IL) based dispersive liquid–liquid microextraction coupled to flame atomic absorption spectrometry (FAAS) detection. The proposed method was successfully applied to the preconcentration and determination of nickel and manganese in soil, vegetable, and water samples. After preconcentration, the settled IL‐phase was dissolved in 100 µL of ethanol and aspirated into the FAAS using a home‐made microsample introduction system. Injection of 50 µL of each analyte into an air–acetylene flame provided very sensitive spike‐like and reproducible signals. Effective parameters such as pH, amount of IL, volume of the disperser solvent, concentration of the chelating agent, and effect of salt concentration were inspected by a (25‐1) fractional factorial design to identify the most important parameters and their interactions. Under optimum conditions, preconcentration of 10 mL sample solution permitted the detection of 0.93 µg L?1 Ni2+ and 0.52 µg L?1 Mn2+ with enrichment factors 77.2 and 82.6 for Ni2+ and Mn2+, respectively. The accuracy of the procedure was evaluated by analysis of a certified reference material (CRM TMDW‐500, drinking water).  相似文献   

20.
The thermal conductivity of a simulated Apollo 12 lunar soil sample was measured with a needle probe under vacuum. The result showed that the sample, with bulk densities of 1.70–1.85 g cm?3 held in a vertical cylinder (2.54 cm in diameter and 6.99 cm long) has a thermal conductivity ranging from 8.8 to 10.9 mW m?1 K?1. This is comparable to the lunar regolith's thermal conductivity as determined in situ. Besides the dense packing of the soil particles, an enhanced intergranular thermal contact, due to the self-compression of the sample, is necessary to raise the sample's thermal conductivity from the level of loose soil (< 5 mW m?1 K?1) to that of the lunar regolith deeper than 35 cm (～ 10 mW m?1 K?1). A model of the lunar regolith, a thin layer of loose soil resting on a compacted self-compressed substratum, is consistent with the lunar regolith's surface structure as deduced from an observation of the lunar surface's brightness temperature. Martian regolith surface structure is similar, except that its surface layer may be missing in places because of aeolian activity. Measurements of thermal conductivity under simulated martian surface conditions showed that the thermal properties of loose and compacted soils agreed with the two peak values of the martian surface's thermal inertia as observed from “Viking” orbiters, suggesting that drifted loose soil and exposed compacted soil are responsible for the bimodal distribution of the martian surface's thermal inertia near zero elevation. For compacted soil exposed to the martian surface to have the same thermal conductivity as that buried under the surface layer, a cohesion of the soil particles must be assumed.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号