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1.
To aid rock art conservation, rock temperatures have been monitored at different depths and at low (30 min) and high (1 min) acquisition rates in a painted rock shelter in the uKhahlamba‐Drakensberg Park (South Africa). Preliminary data for winter (cold and dry) show that in that season cryoclasty is unlikely to occur (rare subzero thermal events and probable reduced moisture availability) and thermal shocks are improbable (highest measured ΔT/Δt < 2 °C min?1). High amplitude (about 30 °C) rock temperature cycles accompanied by reversals of the thermal gradient have been observed to occur almost daily and hint at the possibility of thermal stress fatigue. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

2.
Consideration of the mechanisms associated with the granular disintegration of rock has been limited by available data. In most instances, both the size of the transducer and the nature of the study have negated any applicability of the resulting data to the understanding of grain‐to‐grain separation within rock. The application of microthermocouples (≤0·15 mm diameter) and high‐frequency logging (20 s intervals) at a taffoni site on southern Alexander Island and from a rock outcrop on Adelaide Island (Antarctica) provide new data pertaining to the thermal conditions, at the grain scale, of the rock surface. The results show that thermal changes (ΔT/t) can be very high, with values of 22 °C min?1 being recorded. Although available data indicate that there can be differences in frequency and magnitude of ?uctuations as a function of aspect, all aspects experienced some large magnitude (≥2 °C min?1) ?uctuations. Further, in many instances, large thermal changes in more than one direction could occur within 1 min or in subsequent minutes. These data suggest that the surface grains experience rapidly changing stress ?elds that may, with time, effect fatigue at the grain boundaries; albedo differences between grains and the resulting thermal variations are thought to exacerbate this. The available data failed to show any indication of water freezing (an exotherm) and thus it is suggested that microgelivation may not play as large a role in granular breakdown as is often postulated for cold regions, and that in this dry, Antarctic region thermal stress may play a signi?cant role. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

3.
A laboratory instrument was developed to investigate the electrical properties of rock samples with respect to changes of frequency, temperature and pressure. The instrument can be used to obtain general trends and typical values for geological media. It should be of particular interest in geothermal studies and research in the geophysical properties of rocks. The design intervals for quantities under investigation were 20–300°C, 105-4 × 107 Pa and 5 × 10?4-103 Hz. Certain limitations exist on the simultaneous use of the highest values of temperature and pressure. The main features of the instrument are: analog electrical outputs recorded by an x-y recorder or observed on a scope with an attached camera (according to the frequency range); pressures produced by an oil hydraulic system in order to ensure electrical insulation of the sample; temperatures obtained by placing the pressure vessel into a thermostatically controlled room. Thus the monitoring instrumentation is directly accessible during the experiment. Information is also given about calibration procedures and examples of rock sample data are given.  相似文献   

4.
Different satellite-based radiation (Makkink) and temperature (Hargreaves-Samani, Penman-Monteith temperature, PMT) reference evapotranspiration (ETo) models were compared with the FAO56-PM method over the Cauvery basin, India. Maximum air temperature (Tmax) required in the ETo models was estimated using the temperature–vegetation index (TVX) and an advanced statistical approach (ASA), and evaluated with observed Tmax obtained from automatic weather stations. Minimum air temperature (Tmin) was estimated using ASA. Land surface temperature was employed in the ETo models in place of air temperature (Ta) to check the potency of its applicability. The results suggest that the PMT model with Ta as input performed better than the other ETo models, with correlation coefficient (r), averaged root mean square error (RMSE) and mean bias error (MBE) of 0.77, 0.80 mm d?1 and ?0.69 for all land cover classes. The ASA yielded better Tmax and Tmin values (r and RMSE of 0.87 and 2.17°C, and 0.87 and 2.27°C, respectively).  相似文献   

5.
An apparatus designed to determine the complex shear modulus of rock samples by forced torsion oscillations at high temperature and in the seismic frequency band 0.003–30 Hz is briefly described. Measurements were performed on natural dunite from Åheim (Norway) up to 1400°C and on polycrystalline forsterite up to 1500°C at 1 atm pressure. The two materials were chosen to study, by comparison, the effect of melt on the elasticity and anelasticity of mantle rocks.Between 1000 and 1200°C the absolute values of the shear modulus G are almost equal for both materials. Above 1200°C G for natural dunite decreases progressively with temperature and at 1400°C and 1 Hz reaches ～13 of its value at 1100°C. In contrast, G of pure forsterite depends little on temperature. For petrological reasons, supported by simultaneous measurements of the electric resistivity, there is strong evidence that the decrease of G in dunite above 1200°C is due to melt from the lower melting components of the dunite. Based on different models estimates of the melt fraction are made.At high temperature, in both materials Q?1 is characterized by a monotonic decrease with frequency according to ω?α, with α ≈ 0.25. An apparent activation energy of 38±5 kcal mol?1 for forsterite and 48±8 kcal mol?1 for dunite was found with no significant change in the regime of partial melting. From this it is concluded that Q?1, even at partial melting, is dominated by solid state high temperature background absorption. There is no indication from these experiments for a constant-Q-band at low seismic frequencies or an increase of Q proportional to frequency as suggested by some seismologists. The present results are in good qualitative agreement with those for Young's modulus obtained previously by strain retardation experiments.  相似文献   

6.
The seasonal variations in biomass, abundance, and species composition of plankton in relation to hydrography were studied in saline lake Namuka Co, northern Tibet, China. The sampling was carried out at approximately monthly intervals from June 2001 to July 2002. The salinity ranged from 5.5 to 26 g/L. The mean annual air and water temperature showed a clear seasonal pattern, which was approximately 4.4 and 7.4°C, respectively, with the lowest water temperature in winter (from December to March, −1°C) and the highest in June and July (18°C). The results showed that 36 taxa of phytoplankton and 16 taxa of zooplankton were identified. Both the biomass and abundance of total phytoplankton were lower in the winter and peaked once or twice during the summer and spring in the early August (8.23 mg/L and 158.2 × 106 ind./L). The seasonal variation in total zooplankton biomass and abundance was characterized by lower values in both winter and early spring, and one maximum (90.5 mg/L and 935 ind. L−1) occurred in the late summer. Major phytoplankton species were Gloeothece linearis, Oscillatoria tenuis, Gloeocapsa punctata, Ctenocladus circinnatus, Ulothrix sp., and Spirogyra sp. And major zooplankton species included Vorticella campanula, Brachionus plicatilis, Daphniopsis tibetana, Cletocamptus dertersi, Arctodiaptomus stewartianus. The production of D. tibetana was 420.3 g m3 a−1. The total number of plankton species has a significant negative correlation with the salinity.  相似文献   

7.
For efficient combustion of aquatic biomass, the effects of heating rate on the combustion and dynamic characteristics of two typical aquatic species (water hyacinth, Pistia stratiotes), and the effects of temperature and additives on ash K and Cl concentrations are studied. The two types of pellets have ignition temperatures of 252.7 and 250.3 °C, respectively. At a heating rate of 10 °C min−1, where combustion is most stable, the comprehensive combustion efficiencies reach their maximum at 4.7 × 10−6 and 2.2 × 10−6 mg2min−1°C−2, respectively. The K and Cl concentrations in the ash decrease steadily with increasing temperature, falling to 10.3% and 0.41% for water hyacinth and 11.1% and 1.85% for P. stratiotes, respectively. X-ray diffraction (XRD)shows that abundant Ca minerals form in the ash after the addition of CaO, which inhibit KCl formation, and K and Al silicates form in the ash after the addition of kaoline, which reserve K in the ash. These findings provide a starting point for the development of efficient aquatic biomass combustion.  相似文献   

8.
Biofiltration is a commonly practiced biological technique to remove volatile compounds from waste gas streams. From an industrial view‐point, biofilter (BF) operation should be flexible to handle temperatures and inlet load (IL) variations. A compost BF was operated at different temperatures (30–45°C) and at various inlet loading rates (ILR; 8–598 g m?3 h?1) under intermittent loading conditions. Complete removal of n‐hexane was observed at 30 and 35°C at ILRs up to 330 g m?3 h?1. Besides, 20–75% of the pollutant was removed at 40°C, corresponding to the different ILs applied to the BF. Increasing the temperature to 45°C decreased the removal efficiency (RE) significantly. A feed forward neural network was used to predict the RE of BF with temperature and ILR as the input variables. The experimental data was divided into training (2/3) and test datasets (1/3). The best structure of neural network was obtained by trial and error on the basis of the least differences between predicted and experimental values, as ascertained from their coefficient of regression (R2) values. The modeling results showed that a multilayer network with the topology 2?10?1 was able to predict BF performance effectively with R2‐value of 0.995 for the test data. The results from this study showed the predicting capability of ANNs which can be considered as an alternative for conventional knowledge‐based models.  相似文献   

9.
Thermal loading of rocks at high temperatures induces changes in their mechanical properties. In this study, a hard gabbro was tested in the laboratory. Specimens were slowly heated to a maximum temperature of 1,000°C. Subsequent to the thermal loading, specimens were subjected to uniaxial compression. A drastic decrease of both unconfined compressive strength and elastic moduli was observed. The thermal damage of the rock was also highlighted by measuring elastic wave velocities and by monitoring acoustic emissions during testing. The micromechanisms of rock degradation were investigated by analysis of thin sections after each stage of thermal loading. It was found that there is a critical temperature above which drastic changes in mechanical properties occur. Indeed, below a temperature of 600°C, microcracks start developing due to a difference in the thermal expansion coefficients of the crystals. At higher temperatures (above 600°C), oxidation of Fe2+ and Mg2+, as well as bursting of fluid inclusions, are the principal causes of damage. Such mechanical degradation may have dramatic consequences for many geoengineering structures.  相似文献   

10.
Pressure-induced temperature (PIT) variations are systematically observed in the atmosphere of underground cavities. Such PIT variations are due to the compressibility of the air, damped by heat exchange with the rock surface. It is important to characterize such processes for numerous applications, such as the preservation of painted caves or the assessment of the long-term stability of underground laboratories and underground waste repositories. In this paper we thoroughly study the spatiotemporal dependence of the PIT response versus frequency using vertical and horizontal profiles of temperature installed in an abandoned underground quarry located in Vincennes, near Paris. The PIT response varies from about 20 × 10?3°C hPa?1 at a frequency of 2 × 10?4 Hz to 2–3 × 10?3°C hPa?1 at a frequency of one cycle per day. An analytical expression based on a simple heat exchange model accounts for the observed features of the PIT response and allows for correcting the measured time series, having standard deviations of about 10?2°C, to residual variations with a standard deviation of about 2 × 10?3°C. However, a frequency-dependent attenuation of the response, corresponding to a reduction in amplitude with a factor varying from 2 to 3, is observed near the walls. This effect is not included in the simple analytical expression, but it can be accounted for by a one-dimensional differential equation, solved numerically, where temperature variations in the atmosphere are damped by an effective radiative coupling with the rock surface, complemented by a diffusive coupling near the walls. The TIP response is observed to remain stable over several years, but a large transient enhancement of about a factor of two is observed near the roof at one location from July to October 2005. In a cavity located below the Paris Observatory, an additional contribution is identified in the PIT response function versus frequency for frequencies smaller than 2 × 10?5 Hz. This contribution can be described using a modified analytical expression that includes the effect of heat diffusion into the surrounding rock. Using this expression, in this case also, the temperature time series can then be corrected, giving a residual standard deviation smaller than 1.6 × 10?3°C. Transient temporal variations of the PIT response are observed in all sites, with possible nonlinear components in the PIT. Such effects are not properly understood at this stage, and limit the reduction of time series to standard deviations of the order of 2 × 10?3°C, and consequently limit the search for new transient or seasonal temperature signals, for example due to the presence of tiny heat sources in the cavity or to geodynamical effects.  相似文献   

11.
Influence of the Temperature on the Formation of Magnetite as an Additive for Magnetic Separation To investigate the influence of the temperature on the formation of magnetite in aqueous solution, experiments were performed in which ferrous hydroxide was precipitated from oxygen-free ferrous sulfate solution (c0(Fe) = 5 mmol·dm?3) and subsequently oxidized with synthetic air. The precipitates so obtained are a mixture of solids whose compositions depend on the temperature and on the rate of aeration. Above all, magnetite, goethite, and δ-FeOOH had been formed. Magnetite occurs at temperatures above about 15 °C, goethite above 35 °C, and δ-FeOOH below about 10 °C. Referring to the thermogravimetric plots and to the relationship between the temperature of formation and the pH measured upon completion of the reaction, it is justified to assume that also sulfate is contained in the precipitates. The values of the magnetic moment of the precipitates, which are crucial in magnetic separation, made evident the dependence on the temperature of formation expected on the basis of solid analyses and confirmed the presence of δ-FeOOH at rather low temperatures. At the rates of aeration applied, it was possible to obtain from about 15 °C on solids having magnetic moments which are sufficient for magnetic separation.  相似文献   

12.
The experimental studies done at high temperature and high pressure find that increased temperature can lead to dramatic velocity and strength reductions of most of rocks at high confining pressure[1,2]. What causes this phenomenon? Is it due to dehydrati…  相似文献   

13.
Relaxation experiments on vitreous SiO2, densified at 900°C, 20 kbar to a permanent density of 2.36 g cm?3 yield an activation energy of69 ± 5kcal mol?1 in the temperature range 700–800°C. The data can be used to estimate minimum cooling rates, maximum depositional temperatures or maximum thicknesses of shock-metamorphosed rocks containing diaplectic glasses, if relaxation of a glass densified under dynamic conditions is assumed to be similar to that of statically densified glass.  相似文献   

14.
The matrix of 77135 would not be a liquid at less than 1280°C, 1 atm pressure. The petrography and lack of evidence of crystallization in the 1280-1150°C interval suggest that the matrix is either a devitrified, shock-melted and supercooled glass, or a devitrified, depressurised liquid whose liquidus temperature had been depressed by the presence of a small amount of water at pressures attainable in the upper part of the lunar crust. Devitrification fronts would have advanced faster than 1 mm min?1 in 77135 glass at 1050°C under lunar surface conditions.  相似文献   

15.
Runoff from a small glacierized catchment in the Canadian high Arctic was monitored throughout one melt season. The stream discharge record is one aspect of a larger project involving glacier mass balance, superimposed ice formation and local climate on a glacier in the Sawtooth Range, Ellesmere Island, Northwest Territories, Canada. To better understand the main factors influencing the production of runoff on the glacier during the period of main summer melt, regression analyses were performed relating daily air temperature, shortwave incoming and net radiation, absorptivity and wind speed to daily glacier discharge. Air temperature at the glacier meteorological station on rain-free days is the element with the greatest correlation with runoff (r2 = 0.57; n = 34). A multiple regression of discharge with air temperature, shortwave incoming radiation, net radiation hours and wind speed achieved the best fit (r2 = 0.84; n = 34). Rain events (> 10mmd?1) can dominate daily discharge when they occur during the period of ice melt, creating more runoff per unit area than can be produced by melt alone, and significantly reduce the accuracy of runoff predictions.  相似文献   

16.
The effects of temperature, diffusive boundary-layer thickness, and sediment composition on fluxes of inorganic N and P were estimated for sediment cores with oxidized surfaces from nearshore waters (2?C10?m) of a montane oligotrophic lake. Fluxes of N and P were not affected by diffusive boundary-layer thickness but were strongly affected by temperature. Below 16?°C, sediments sequestered small amounts of P and released small amounts of N. Above 16?°C, the seasonal maximum water temperature, sediments were substantial sources of N (NH4 +?CN?=?2?C24?mg?m?2 d?1; NO3 ??+?NO2 ??CN?=?2?C5?mg?m?2 d?1) and P (0.1?C0.4?mg?m?2 d?1), indicating potential responsiveness of sediment?Cwater nutrient exchange, and of corresponding phytoplankton growth, to synoptic warming.  相似文献   

17.
The adsorption of fluoxetine onto activated carbons (ACs) prepared from almond tree pruning by steam and CO2 activation under different temperature conditions (650–950°C), was studied. In both series increasing the temperature caused an increase in the BET apparent surface area, yielding ACs with SBET up to 870 and 710 m2 g?1 after steam and CO2 activation, respectively. Also, a slight widening of the porosity was found in both cases. In order to modify the functionality of the ACs, two of them were impregnated with triethylenediamine (TEDA) prior to the adsorption process, which caused a decrease in the AC apparent surface mainly due to micropore blockage. The fluoxetine adsorption isotherms at 25°C showed maximum adsorption capacities between 110 and 224 mg g?1. The adsorption isotherms were analyzed using Langmuir and Freundlich models. Although the impregnation reduced the pore volume, it did not cause a decrease in the fluoxetine maximum adsorption capacity, but a modification in the adsorption mechanism was observed.  相似文献   

18.
Here we characterize the nutrient content in the outflow of the Green Lake 5 rock glacier, located in the Green Lakes Valley of the Colorado Front Range. Dissolved organic carbon (DOC) was present in all samples with a mean concentration of 0·85 mg L?1 . A one‐way analysis of variance test shows no statistical difference in DOC amounts among surface waters (p = 0·42). Average nitrate concentrations were 69 µmoles L?1 in the outflow of the rock glacier, compared to 7 µmoles L?1 in snow and 25 µmoles L?1 in rain. Nitrate concentrations from the rock glacier generally increased with time, with maximum concentrations of 135 µmoles L?1 in October, among the highest nitrate concentrations reported for high‐elevation surface waters. These high nitrate concentrations appear to be characteristic of rock glacier outflow in the Rocky Mountains, as a paired‐difference t‐test shows that nitrate concentrations from the outflow of 7 additional rock glaciers were significantly greater compared to their reference streams (p = 0·003). End‐member mixing analysis suggest that snow was the dominant source of nitrate in June, ‘soil’ solution was the dominant nitrate source in July, and base flow was the dominant source in September. Fluoresence index values and PARAFAC analyses of dissolved organic matter (DOM) are also consistent with a switch from terrestrial DOM in the summer time period to an increasing aquatic‐like microbial source during the autumn months. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

19.
Sorptive removal of Ni(II) from electroplating rinse wastewaters by cation exchange resin Dueolite C 20 was investigated at the temperature of 30°C under dynamic conditions in a packed bed. The effects of sorbent bed length 0.1–0.2 m, fixed flow rate 6 dm3 min?1, and the initial rinse water concentration (C0) 53.1 mg L?1 on the sorption characteristics of Dueolite C 20 were investigated at an influent pH of 6.5. More than 94.5% of Ni(II) was removed in the column experiments. The column performance was improved with increasing bed height and decreasing the flow rate. The Thomas, Yoon–Nelson, Clark, and Wolborska models were applied to the experimental data to represent the breakthrough curves and determine the characteristic design parameters of the column. The sorption performance of the Ni(II) ions through columns could be well described by the Thomas, Yoon–Nelson, and Wolborska models at effluent‐to‐influent concentration ratios (C/C0) >0.03 and <0.99. Among the all models, the Clark model showed the least average percentage time deviation. The sorptive capacity of electroplating rinse water using Ni(II) was found to be 45.98 mg g?1.  相似文献   

20.
The accumulation of crimidin in total samples and in some organs of five fish species was studied under experimental conditions. The species were Cyprinus carpio, Carassius carassius, Tinca tinca, Scardinus erythrophthalmus and Leucaspius delineatus. Fish were exposed to concentrations of 10 mg · l?l and 50 mg · l?1. During short-term experiments water and fish samples were taken at intervals of t = 0, 6, 12, 24, 48 and 72 hours, during the long-term experiment sampling was performed weekly for six weeks. Total samples were analysed for C. carassius, T. tinca, S. erythrophthalmus and L. delineatus. Samples of individual organs and tissues were taken as follows: C. carpio – gills, digestive tract, muscular tissue, kidneys, gonads; C. carassius – gills, digestive tract, muscular tissue, ovaries, testes. Crimidin was determined by gas chromatography. In samples from the short-term experiments at a concentration of 10 mg · l?1 in the water the amount was roughly 101–10 mg · kg?1, at a concentration of 50 mg · l?1 in the water roughly 101 mg · kg?1. In most cases the accumulation coefficient was lower than 1.0. The accumulation capacity of individual fish species did not differ greatly. Of the internal organs only the kidneys had a high accumulation capacity, otherwise the highest values were found in muscular tissue and the gills. After one – three weeks the amount of crimidin in most organs falls, and after transfer to clean water there is a general sharp decline. Thus crimidin is not firmly bound in the body.  相似文献   

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