共查询到20条相似文献，搜索用时 46 毫秒
1.
北山造山带位于中亚巨型造山带南缘,是剖析中亚造山带南缘增生构造过程的关键地区之一,古亚洲洋闭合时间存在较大争议,聚焦于泥盆纪古亚洲洋仍在俯冲还是已经闭合。作者在北山造山带南缘黑山头一带首次识别出具典型埃达克岩特征的中酸性侵入体,对其进行了岩石地球化学和锆石U-Pb年代学研究。黑山头岩体中花岗闪长岩LA-ICP-MS锆石U-Pb加权平均年龄为407.7±1.6 Ma,形成于早泥盆世。地球化学数据表明,黑山头岩体为过铝质,属钙碱性系列,具典型埃达克岩特征:高硅(SiO_2=60.85%～67.81%)、高铝(Al_2O_3=15.59%～16.98%)、低镁(MgO=0.55%～1.53%,Mg~#=0.36～0.46)、富钠贫钾(Na_2O=2.65%～3.54%,K_2O=1.09%～3.16%,Na_2O/K_2O=0.96～2.44)、高Sr(Sr=253×10~(-6)～487×10~(-6))、低Y和Yb(Y=5.65×10~(-6)～16.70×10~(-6),Yb=0.37×10~(-6)～0.96×10~(-6))、高Sr/Y值(25.75～73.58);轻稀土元素富集,轻重稀土元素分馏明显,样品不具明显的Eu异常(0.66～1.31,平均0.92);微量元素富集大离子亲石元素Rb、K、Th、U,亏损高场强元素Nb、Ta、Ti、P。地球化学特征显示其为俯冲洋壳部分熔融形成的埃达克岩,残留相为石榴子石+金红石。结合前人研究认识,认为柳园洋(古亚洲洋)具有自西向东呈"剪刀式"闭合的特征,柳园洋(古亚洲洋)在早泥盆世仍处于俯冲碰撞阶段,早石炭世是北山地区古生代洋盆闭合时限上限。 相似文献
2.
Rare-earth elements as source indicators of Pan-African granites from Obudu Plateau,Southeastern Nigeria 总被引：1，自引：1，他引：0
The rare-earth element （REE） concentrations of representative granite samples from the southeast of the Obudu Plateau, Nigeria, were analyzed with an attempt to determine the signatures of their source, evolutionary history and tectonic setting. Results indicated that the granites have high absolute REE concentrations （190×10^-6-1191×10^-6; av.=549×10^-6） with the chondrite-normalized REE patterns characterized by steep negative slopes and prominent to slight or no negative Eu anomalies. All the samples are also characterized by high and variable concentrations of the LREE （151×10^-6-1169×10^-6; av.= 466×10^-6）, while the HREE show low abundance （4×10^-6-107×10^-6; av.=28×10^-6）. These are consistent with the variable levels of REE fractionation, and differentiation of the granites. This is further supported by the range of REE contents, the chondrite-normalized patterns and the ratios of LaN/YbN （2.30-343.37）, CeN/YbN （5.94-716.87）, LaN/SmN （3.14-11.68） and TbN/YbN （0.58-1.65）. The general parallelism of the REE patterns, suggest that all the granites were comagmatic in origin, while the high Eu/Eu＊ ratios （0.085-2.807; av.=0.9398） indicate high fo2 at the source. Similarly, irregular variations in LaN/YbN, CeN/YbN and Eu/Eu＊ ratios and REE abundances among the samples suggest behaviors that are related to mantle and crustal sources. 相似文献
3.
岩浆活动在板块构造机制中可以看作是大洋板块俯冲或者大陆板块碰撞等过程所伴随的深部作用响应,也是探索深部作用过程的"岩石探针"。土鲁音岩体位于东昆仑东部,紧邻昆中断裂南部区域。在详细野外调研基础上,主要对土鲁音花岗岩体进行岩石学、地球化学以及年代学的研究。结果显示,土鲁音岩体主要岩性为花岗闪长岩,其Si O2为68.49%~70.87%,全碱含量为5.94%~7.16%,K2O/Na2O比值为0.34~0.57,Mg#值中等(35.92~41.86),A/CNK值(1~1.07)均小于1.1,属弱过铝质钙碱性I型花岗岩。岩体稀土总量较低(118.91×10-6~143.97×10-6),(La/Yb)N为4.17~9.14,具有轻稀土元素富集、重稀土元素平坦分布的特征,弱负Eu异常,且显著亏损Nb、Ta、P、Ti等高场强元素,富集Rb、Ba、Th等大离子亲石元素。锆石LA-ICP-MS U-Pb测年结果显示土鲁音花岗岩体侵位时代(245.1±3.3)Ma,和区域内下得波利、埃坑德勒斯特花岗岩体具有一致的成岩年龄,同属印支早期产物。地球化学特征反映壳源部分熔融成因,并有幔源物质及热流参与,结合区域已有的年代学、地球化学以及地质资料,笔者认为土鲁音岩体形成于阿尼玛卿—古特提斯洋北向俯冲的地球动力学背景。 相似文献
4.
A gabbro-diorite plutonic complex from the Southeast Obudu Plateau, representing limited volumes of magma, was studied for its trace and rare-earth element characteristics, in an attempt to document its genetic and geodynamic history. Geochemical studies indicate that the gabbro samples are characterized by variable concentrations and low averages of such index elements as Cr (40×10-6–200×10-6; av. 80×10-6), Ni (40×10-6–170×10-6; 53.33×10-6) and Zr (110×10-6–240×10-6; 116.67×10-6); variable and high average... 相似文献
5.
The Duolanasayi gold deposit, 60 km NW of Habahe County, Xinjiang Uygur Autonomous Region, is a mid-large-scale gold deposit controlled by brittle-ductile shearing, and superimposed by albitite veins and late-stage magma hydrothermal solutions. There are four types of pyrite, which are contained in the light metamorphosed rocks (limestone, siltstone), altered-mineralized rocks (chlorite-schist, altered albite-granite, mineralized phyllite), quartz veins and carbonatite veinlets. The pyrite is the most common ore mineral. The Au-barren pyrite is present mainly in a simple form and gold-bearing pyrite is present mainly in a composite form. From the top downwards, the pyrite varies in crystal form from {100} and {210} {100} to {210} {100} {111} to {100} {111}. Geochemical studies indicate that the molecular contents of pyrite range from Fe1.057S2 to Fe0.941S2. Gold positively correlates with Mn, Sr, Zn, Te, Pb, Ba and Ag. There are four groups of trace elements: Fe-Cu-Sr-Ag, Au-Te-Co, As-Pb-Zn and Mn-V-Ti-Ba-Ni-Cr in pyrite. The REE characteristics show that the total amount of REE (ΣREE) ranges from 32.35×10 -6 to 132.18×10 -6; LREE/HREE, 4.466-9.142; (La/Yb)N, 3.719-11.133; (Eu/Sm)N, 0.553-1.656; (Sm/Nd)N, 0.602-0.717; La/Yb, 6.26-18.75; δEu, 0.628-2.309; δCe, 0.308-0.816. Sulfur isotopic compositions (δ 34S=-2.46‰--7.02‰) suggest that the sulfur associated with gold mineralization was derived from the upper mantle or lower crust. 相似文献
6.
内蒙古乌兰沟埃达克岩锆石U-Pb年龄及构造环境 总被引：2，自引：1，他引：1
内蒙古中部贺根山缝合带的梅劳特乌拉蛇绿岩中,新发现乌兰沟埃达克岩,岩性为花岗闪长岩。LA-ICP-MS锆石UPb测年结果表明,乌兰沟埃达克岩的侵位年龄为279.3±1.4Ma,其形成时代为早二叠世。乌兰沟埃达克岩SiO_2含量为65.92%~69.65%,MgO为1.34%~2.16%,Al_2O_3为15.30%~17.33%,Na_2O/K_2O值为3.95~14.09,Sr=359.60×10~(-6)~734.00×10~(-6),Yb=0.83×10~(-6)~2.02×10~(-6),Y=6.65×10~(-6)~12.84×10~(-6);富集K、Rb、Sr等大离子亲石元素,亏损Nb、Ta、Ti、P等高场强元素;稀土元素总量为32.18×10~(-6)~65.41×10~(-6),明显较低,轻、重稀土元素分馏明显,(La/Yb)N值为2.84~7.56,无明显Eu异常,显示出高硅埃达克岩(HSA)的地球化学特征。该埃达克岩具有岛弧型岩浆岩特征,形成于俯冲带岛弧环境,可能为洋内俯冲洋壳+俯冲深积物部分熔融并与上覆地幔楔橄榄岩反应成因。根据乌兰沟埃达克岩与梅劳特乌拉蛇绿岩的时空分布与演化特征,贺根山缝合带在早二叠世可能存在洋内俯冲作用。 相似文献
7.
The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes. 相似文献
8.
《International Geology Review》2012,54(16):1885-1905
Late Mesozoic granitoid plutons of four distinct ages intrude the lower plate of the Hohhot metamorphic core complex along the northern margin of the North China craton. The plutons belong to two main groups: (1) Group I, deformed granitoids (148 and 140 Ma subgroups) with high Sr, LREE, and Na2O, low Y and Yb contents, high Sr/Y and La/Yb ratios, weak or no Eu anomalies, low Rb/Ba ratios, similar initial 87Sr/86Sr values (0.7064–0.7071) and low Mg# (<37 mostly, 100?×?molar MgO/MgO + FeO t ); (2) Group II, non-deformed granitoids (132 and 114 Ma subgroups) with low Sr, relatively low Na2O, high Y and Yb contents, pronounced negative Eu anomalies, high Rb/Ba ratios, and initial 87Sr/86Sr values (0.7098–0.7161). The two groups share geochemical similarities in ?Nd(t) (–11.3 to –15.4) and T DM2 ages (1.85–2.18 thousand million years) as well as Hf isotopic ratios in zircons. Geochemical modelling (using the MELTS code) suggests that similar sources but different depths of magma generation produced the early, high-pressure low-Mg adakitic granitoids and late, low-pressure granitoids with A-type characteristics. The early granitoids likely represent a partially melted, deep-seated, thickened lower continental crust that involved a minor contribution from young materials, whereas the later group partially melted at shallower depths. This granitic magmatic evolution coincided with the tectonic transition from crustal contraction to extension. 相似文献
9.
《Resource Geology》2018,68(4):395-424
Petrochemical characteristics of Permo‐Triassic granitoids from five regions (i) Mung Loei, (ii) Phu Thap Fah – Phu Thep, (iii) Phetchabun, (iv) Nakon Sawan – Lobburi, and (v) Rayong – Chantaburi along the Loei Fold Belt (LFB), northeastern Thailand were studied. The LFB is a north–south trending 800 km fold belt that hosts several gold and base‐metal deposits. The granitoids consist of monzogranite, granodiorite, monzodiorite, tonalite, quartz‐syenite, and quartz‐rich granitoids. These are composed of quartz, plagioclase, and K‐feldspar with mafic minerals such as hornblende and biotite. Accessory minerals, such as titanite, zircon, magnetite, ilmenite, apatite, garnet, rutile, and allanite are also present. Magnetic susceptibilities in the SI unit of granitoids vary from 6.5 × 10−3 to 15.2 × 10−3 in Muang Loei, from 0.1 × 10−3 to 29.4 × 10−3 in Phu Thap Fah – Phu Thep, from 2.7 × 10−3 to 34.6 × 10−3 in Petchabun, from 2.4 × 10−3 to 14.1 × 10−3 in Nakon Sawan – Lobburi, and from 0.03 × 10−3 to 2.8 × 10−3 in Rayong – Chantaburi. Concentration of major elements suggests that these intermediate to felsic plutonic rocks have calc‐alkaline affinities. Concentration of REE of the granitoids normalized to chondrite displays moderately elevated light REE (LREE) and relatively flat heavy (HREE) patterns, with distinct depletion of Eu. Rb versus Y/Nb and Nb/Y tectonic discrimination diagrams illustrate that the granitoids from Muang Loei, Phu Thap Fah – Phu Thep, Phetchabun, Nakon Sawan – Lobburi, and Rayong – Chantaburi formed in continental volcanic‐arc setting. New age data from radiometric K‐Ar dating on K‐feldspar from granodiorite in Loei and Nakhon Sawan areas yielded 171 ± 3 and 221 ± 5 Ma, respectively. K‐Ar dating on hornblende separated from diorite in Lobburi yielded 219 ± 8 Ma. These ages suggest that magmatism of Muang Loei occurred in the Middle Jurassic, and Nakon Sawan – Lobburi occurred in Late Triassic. Both Nb versus Y and Rb versus (Y + Nb) diagrams and age data indicate that Nakon Sawan – Lobburi granitoids intruded in Late Triassic at Nong Bua, Nakon Sawan province and Khao Wong Phra Jun, Lobburi province in volcanic arc setting. Muang Loei granitoids at the Loei province formed later in Middle Jurassic also in volcanic arc setting. The negative δ34SCDT values of ore minerals from the skarn deposit suggest that the I‐type magma has been influenced by light biogenic sulfur from local country rocks. The Au‐Cu‐Fe‐Sb deposits correlate with the magnetite‐series granitoids in Phetchabun, Nakon Sawan – Lobburi and Rayong – Chantaburi areas. Metallogeny of the Au and Cu‐Au skarn deposits and the epithermal Au deposit is related to adakitic rocks of magnetite‐series granitoids from Phetchabun and Nakon Sawan areas. All mineralizations along the LFB are generated in the volcanic arc related to the subduction of Paleo‐Tethys. The total Al (TAl) content of biotite of granitoids increases in the following order: granitoids associated with Fe and Au deposit < with Cu deposit < barren granitoids. XMg of biotite in granitoids in Muang Loei indicates the crystallization of biotite in magnetite‐series granitoids under high oxygen fugacity conditions. On the other hand, low XMg (<0.4) of biotite in magnetite‐series granitoids in Phu Thap Fah – Phu Thep and Rayong – Chantaburi indicates a reduced environment and low oxygen fugacity, associated with Au skarn deposit (Phu Thap Fah) and Sb‐Au deposit (Bo Thong), respectively. The magnetite‐series granitoids at Phu Thap Fah having low magnetic susceptibilities and low XMg of biotite were formed by reduction of initially oxidizing magnetite‐series granitic magma by interaction with reducing sedimentary country rocks as suggested by negative δ34SCDT values. 相似文献
10.
The thermal expansion of gehlenite, Ca2Al[AlSiO7], (up to T=830 K), TbCaAl[Al2O7] (up to T=1100 K) and SmCaAl[Al2O7] (up to T=1024 K) has been determined. All compounds are of the melilite structure type with space group
Thermal expansion data were obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches
Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α1=7.2(4)×10−6×K−1+3.6(7)×10−9ΔT×K−2 and α3=15.0(1)×10−6×K−1. For TbCaAl[Al2O7] the respective values are: α1=7.0(2)×10−6×K−1+2.0(2)×10−9ΔT×K−2 and α3=8.5(2)×10−6×K−1+2.0(3)×10−9ΔT×K−2, and the thermal expansion coefficients for SmCaAl[Al2O7] are: α1=6.9(2)×10−6×K−1+1.7(2)×10−9ΔT×K−2 and α3=9.344(5)×10−6×K−1. The expansion mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements
of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been
observed. While gehlenite behaves like a ‘proper’ layer structure, the aluminates show increased framework structure behavior.
This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging
cations due to the coupled substitution (Ca2++Si4+)–(Ln
3++Al3+) in the melilite-type structure.
This article has been mistakenly published twice. The first and original version of it is available at . 相似文献
11.
东秦岭钼矿带蟒岭矿集区南部侏罗系华阳村组底部出露一套粗面英安岩,对其进行LA-ICP-MS锆石定年,测得锆石206Pb/238U年龄为(150.92±0.70)Ma(95%置信度;MSWD=0.19),表明其形成于晚侏罗世。地球化学特征显示该岩石类似于中国东部燕山期C型埃达克质岩,表现为高硅(w(SiO_2)=59.75%～60.97%)、铝(w(Al2O3)=15.84%～16.01%)、钾(w(K2O)=3.74%～3.89%)、锶(w(Sr)=286×10~(-6)～338×10~(-6)),高Sr/Y比值(20.85～24.53),低镁(w(MgO)=2.37%～2.66%)、镱(w(Yb)=1.30×10~(-6)～1.50×10~(-6))、钇(w(Y)=13.3×10~(-6)～15.4×10~(-6)),重稀土元素明显亏损,轻重稀土元素分异明显(LREE/HREE=10.27～12.25),具有弱的正Eu异常(1.21～1.37),大离子亲石元素如Rb、Ba、Sr、U、K富集,相对亏损高场强元素Nb、Ti的地球化学特征,显示其为地壳加厚的构造背景下,下地壳部分熔融的产物,其源区相当于含10%的石榴子石角闪岩相。结合区域资料,认为晚侏罗世特提斯构造域和太平洋构造域构造已经发生构造体制的转换,太平洋板块向西俯冲导致地壳加厚,加厚的基性下地壳物质发生熔融形成岩浆,并沿构造薄弱带上升,喷发形成该套粗面英安岩,可能代表了燕山运动B幕的岩浆事件。综合研究认为,华阳村组粗面英安岩与调查区内多金属成矿关系作用不大,由于形成了特殊的具有埃达克岩性质的岩石,势必引起下地壳的折沉作用,随着拆沉作用的持续进行,地壳减薄导致周围软流圈地幔上涌,含有Mo、Cu等成矿元素的岩浆沿着构造薄弱地带侵入就位,并在上升过程萃取了围岩中的Pb、Zn、Ag、Au等成矿元素,形成调查区内蟒岭含矿斑岩体、蟒岭西侧含矿小斑岩体以及同期的黄家沟-上铺子一带脉状铅锌银矿体。 相似文献
12.
P. Comodi G. D. Gatta P. F. Zanazzi D. Levy W. Crichton 《Physics and Chemistry of Minerals》2002,29(8):538-544
Powder diffraction measurements at simultaneous high pressure and temperature on samples of 2M1 polytype of muscovite (Ms) and paragonite (Pg) were performed at the beamline ID30 of ESRF (Grenoble), using the Paris-Edinburgh
cell. The bulk moduli of Ms, calculated from the least-squares fitting of V–P data on each isotherm using a second-order Birch–Murnaghan EoS, were: 57.0(6), 55.1(7), 51.1(7) and 48.9(5) GPa on the isotherms
at 298, 573, 723 and 873 K, respectively. The value of (∂K
T
/∂T)
was −0.0146(2) GPa K−1. The thermal expansion coefficient α varied from 35.7(3) × 10−6 K−1 at P ambient to 20.1(3) × 10−6 K−1 at P = 4 GPa [(∂α/∂P)
T
= −3.9(1) × 10−6 GPa−1 K−1]. The corresponding values for Pg on the isotherms at 298, 723 and 823 K were: bulk moduli 59.9(5), 55.7(6) and 53.8(7) GPa,
(∂K
T
/∂T)
−0.0109(1) GPa K−1. The thermal expansion coefficient α varied from 44.1(2) × 10−6 K−1 at P ambient to 32.5(2) × 10−6 K−1 at P = 4 GPa [(∂α/∂P)
T
= −2.9(1) × 10−6 GPa−1 K−1]. Thermoelastic coefficients showed that Pg is stiffer than Ms; Ms softens more rapidly than Pg upon heating; thermal expansion
is greater and its variation with pressure is smaller in Pg than in Ms.
Received: 28 January 2002 / Accepted: 5 April 2002 相似文献
13.
青藏高原北拉萨板块上发育大规模的晚白垩世岩浆作用,长期以来,关于其岩石成因及构造属性一直存在较大争论。本次研究对产出于北拉萨板块尼玛县西约150km的拉木那勒晚白垩世岩体开展了锆石U-Pb年代学、地球化学等方面的工作。拉木那勒岩体主要为花岗闪长岩和二长花岗岩,具有较高的SiO_2(68. 12%～72. 21%)、Al_2O_3(12. 28%～17. 02%)含量和较高的Sr/Y比值(26. 7～145)、La/Yb比值(24. 1～28. 4),低含量的MgO(0. 88%～1. 86%)、Y(4. 58×10~(-6)～10. 03×10~(-6))和Yb(0. 33×10~(-6)～0. 73×10~(-6)),具有埃达克岩的典型特征。本文共对4件年代学样品进行了锆石U-Pb定年,其中2件样品获得了88. 4±0. 5Ma和88. 6±0. 4Ma的谐和年龄,另外2件样品获得了89Ma和95Ma的下交点年龄。结合区域地质资料,我们倾向于认为拉木那勒岩体形成于班公湖-怒江洋闭合之后,是陆-陆碰撞加厚下地壳部分熔融的产物。此外,地壳增厚可能是北拉萨板块晚白垩世岩浆岩的一个重要的形成机制。 相似文献
14.
R. K. Bikramaditya Singh 《Journal of the Geological Society of India》2010,75(4):618-631
Low to medium grade crystalline rocks locally known as Bomdila Group extensively covers the Lesser Himalayan region in Western
Arunachal Himalaya. This Group consists dominantly of mylonitic gneisses of granitic composition of Palaeoproterozoic age,
named as Bomdila mylonitic gneiss (BMG) and a small body of hornblende bearing granite of Mesoproterozoic age known as Salari
granite (SG). The BMG is affinity to peraluminous (A/CNK > 1.1) with high content of SiO2, K2O/Na2O ratio, normative corundum, high ratio of FeOt/MgO in biotite (3.21–5.11) that shows characteristics of S-type granite whereas SG has granodiorite composition with high
Na2O, low K2O, presence of hornblende, normative diopside, low A/CNK ratio (<1.1) and low FeOt/MgO ratio in biotite (1.58–1.60) indicates metaluminous I-type granite affinity. The SG has more fractionated nature of REE
[(Ce/Yb)N = 9.06–18.53] and minor negative Eu anomalies [EuN/Eu* = 0.69–0.94] as compared to BMG which has less fractionation of REE [(Ce/Yb)N = 5.95–9.16] and strong negative Eu anomalies [EuN/Eu* = 0.37–0.43]. Geochemical and petrological studies suggest that the SG and BMG are not genetically related; SG appears
to have derived from igneous source whereas the BMG have been derived from sedimentary source, however these granitoids might
have produced during the same thermal event. 相似文献
15.
Shuan-Hong Zhang Yue Zhao Alfred Kröner Xiao-Ming Liu Lie-Wen Xie Fu-Kun Chen 《International Journal of Earth Sciences》2009,98(6):1441-1467
Recent zircon dating identified several late Carboniferous to early Permian hornblende gabbro–diorite–quartz diorite–granodiorite–tonalite–granite
plutons in lithological assemblages at the northern margin of the North China Block (NCB) that were previously regarded as
Archaean to Palaeoproterozoic. Our geochronological results indicate that emplacement of these plutons was a continuous process
during the late Carboniferous to early Permian, from 324 ± 6 to 274 ± 6 Ma, and lasted for at least 50 Ma. In this paper,
the early Permian components with compositions from gabbro to granite within the intrusive complex were studied. The early
Permian plutons exhibit calc-alkaline or high-K calc-alkaline, metaluminous geochemical features and highly variable SiO2 contents. They have no significant Eu anomaly in their REE patterns, and in primitive-mantle-normalized spidergrams they
display depletion in Th, U, Nb, Ta, P and Ti, and enrichment in Ba, K, Pb and Sr. The granitoid bodies within these plutons
display I-type and adakitic geochemical signatures. The early Permian rocks exhibit low whole-rock initial 87Sr/86Sr ratios from 0.70520 to 0.70615 and have negative whole-rock ε
Nd(t) values ranging from −17.4 to −9.3 and zircon ε
Hf(t) values of −23.2 to −10.5. The gabbros exhibit higher ε
Nd(t) values from −11.1 to −9.3 and ε
Hf(t) values from −16.5 to −10.5, and one granodiorite exhibits an even lower ε
Nd(t) value of −17.4 and zircon ε
Hf(t) values of −23.2 to −15.1. Geochemical, Sr–Nd and in situ zircon Hf isotopic compositions suggest that the hornblende gabbros
were derived from a metasomatized lithospheric mantle, and the diorite and quartz diorite were generated from a gabbroic magma
by fractional crystallization, coupled with differential assimilation of ancient lower crustal material. The granodiorite
was likely derived from partial melting of ancient lower crust with involvement of some mantle components. Involvement of
both lithospheric mantle and ancient lower crust in the generation of the early Permian plutons indicates strong crust–mantle
interaction in the northern NCB. Petrological associations as well as geochemical and Sr–Nd–Hf isotopic results show that
the early Permian plutons were emplaced along an Andean-type active continental margin during southward subduction of the
Palaeo-Asian oceanic plate beneath the NCB. Integration of our results with previously published data for late Carboniferous
and late Permian to middle Triassic intrusions suggests that the continental arc on the northern margin of the NCB existed
for at least 50 Ma during the late Palaeozoic, and final amalgamation of the Mongolian arc terranes with the northern NCB
likely occurred during a period from ~270 to ~250 Ma, i.e, in the late Permian to earliest Triassic. 相似文献
16.
本文对青海南山吾口正长花岗岩和花岗闪长岩进行了岩石学、岩石地球化学及年代学研究。首次测得吾口侵入岩体正长花岗岩的锆石206Pb/238U年龄为253. 8±3. 3Ma(MSWD=0. 96),形成时代为晚二叠世。岩石中Al_2O_3为(14. 13～16. 51)×10~(-2),K_2O为(1. 66～3. 59)×10~(-2),A/NK=1. 15～2. 35,A/CNK=0. 75～1. 03,TFe O/(TFe O+MgO)=0. 53～0. 81,岩石具偏铝质中-高钾钙碱性花岗岩特征;吾口岩体表现为富集大离子亲石元素Rb、K等,亏损高场强元素Nb、Ta、Ba等;轻重稀土分异较明显,具右倾特征,中等负Eu异常(δEu=0. 44～0. 68),具壳幔岩浆混合特征。吾口岩体代表了阿尼玛卿洋盆向北削减俯冲运动在青海南山构造带与西秦岭造山带和南祁连造山带的构造转换衔接部位的构造演化的地质记录。该侵入岩体形成时代及构造环境的确定,为研究印支早期青海南山构造演化及动力学机制提供重要依据。 相似文献
17.
K.-D. Grevel A. Navrotsky W. A. Kahl D. W. Fasshauer J. Majzlan 《Physics and Chemistry of Minerals》2001,28(7):475-487
Calorimetric and P–V–T data for the high-pressure phase Mg5Al5Si6O21(OH)7 (Mg-sursassite) have been obtained. The enthalpy of drop solution of three different samples was measured by high-temperature
oxide melt calorimetry in two laboratories (UC Davis, California, and Ruhr University Bochum, Germany) using lead borate (2PbO·B2O3) at T=700 ∘C as solvent. The resulting values were used to calculate the enthalpy of formation from different thermodynamic datasets;
they range from −221.1 to −259.4 kJ mol−1 (formation from the oxides) respectively −13892.2 to −13927.9 kJ mol−1 (formation from the elements). The heat capacity of Mg5Al5Si6O21(OH)7 has been measured from T=50 ∘C to T=500 ∘C by differential scanning calorimetry in step-scanning mode. A Berman and Brown (1985)-type four-term equation represents
the heat capacity over the entire temperature range to within the experimental uncertainty: C
P
(Mg-sursassite) =(1571.104 −10560.89×T
−0.5−26217890.0 ×T
−2+1798861000.0×T
−3) J K−1 mol−1 (T in K). The P
V
T behaviour of Mg-sursassite has been determined under high pressures and high temperatures up to 8 GPa and 800 ∘C using a MAX 80 cubic anvil high-pressure apparatus. The samples were mixed with Vaseline to ensure hydrostatic pressure-transmitting
conditions, NaCl served as an internal standard for pressure calibration. By fitting a Birch-Murnaghan EOS to the data, the
bulk modulus was determined as 116.0±1.3 GPa, (K
′=4), V
T,0
=446.49 3 exp[∫(0.33±0.05) × 10−4 + (0.65±0.85)×10−8
T dT], (K
T/T)
P
= −0.011± 0.004 GPa K−1. The thermodynamic data obtained for Mg-sursassite are consistent with phase equilibrium data reported recently (Fockenberg
1998); the best agreement was obtained with Δf
H
0
298 (Mg-sursassite) = −13901.33 kJ mol−1, and S
0
298 (Mg-sursassite) = 614.61 J K−1 mol−1.
Received: 21 September 2000 / Accepted: 26 February 2001 相似文献
18.
达克岩(adakite)是一种中酸性富钠火成岩(安山岩、英安岩、钠质流纹岩及相应的侵入岩),其突出的地球化学特征就是SiO2≥56%,Al2O3≥15%,低重稀土元素(HREE)与Y(如Yb≤1.9×10-6,Y≤18×10-6),高Sr(大多数>400×10-6,La/Yb(≥10.0)与Sr/Y(>20.0～40.0),一般具有正铕异常(少数具有极弱负铕异常).埃达克岩存在两种成因类型:一种由俯冲的年轻(≤25～30Ma)大洋板片熔融形成(O型埃达克岩);另一种由增厚地壳环境中的玄武质下地壳熔融形成(C型埃达克岩).文章从埃达克岩的特征、形成机制、成矿作用、构造背景、动力学意义等几个方面论述了埃达克岩的研究现状,并指出了未来埃达克岩研究的趋势. 相似文献
19.
蓬莱9-1花岗岩体是渤海海域首次发现的中生代花岗岩,鉴于渤海海域在华北克拉通中的重要构造位置,该花岗岩的形成时代和成因机制的研究对区域构造研究具有重大意义。锆石LA-ICP-MS U-Pb定年结果表明该花岗岩体形成于中侏罗世160~165Ma。花岗岩属于高钾钙碱性系列,为准铝质-过铝质花岗岩;富Al_2O_3(14.84%~17.19%)和Sr(485×10~(-6)~909×10~(-6)),贫Y(0.66×10~(-6)~1.39×10~(-6))和Yb(小于2.0×10~(-6)),无铕的负异常,多数样品表现为铕的弱正异常,表现出C-型埃达克岩特征。表明渤海地区在160~165Ma期间处于挤压地壳增厚环境下,以地壳减薄为标志的克拉通破坏过程彼时尚未发生,其区域动力学环境可能仍处于华北板块-华南板块碰撞拼接的影响范围内。 相似文献
20.
Elastic wave velocities for dense (99.8% of theoretical density) isotropic polycrystalline specimens of synthetic pyrope (Mg3Al2Si3O12) were measured to 1,000 K at 300 MPa by the phase comparison method of ultrasonic interferometry in an internally heated
gas-medium apparatus. The temperature derivatives of the elastic moduli [(∂Ks/∂T)
P
= −19.3(4); (∂G/∂T)
P
= −10.4(2) MPa K−1] measured in this study are consistent with previous acoustic measurements on both synthetic polycrystalline pyrope in a
DIA-type cubic anvil apparatus (Gwanmesia et al. in Phys Earth Planet Inter 155:179–190, 2006) and on a natural single crystal by the rectangular parallelepiped resonance (RPR; Suzuki and Anderson in J Phys Earth 31:125–138,
1983) method but |(∂Ks/∂T)
P
| is significantly larger than from a Brillouin spectroscopy study of single-crystal pyrope (Sinogeikin and Bass in Phys Earth
Planet Inter 203:549–555, 2002). Alternative approaches to the retrieval of mixed derivatives of the elastic moduli from joint analysis of data from this
study and from the solid-medium data of Gwanmesia et al. in Phys Earth Planet Inter 155:179–190 (2006) yield ∂2
G/∂P∂T = [0.07(12), 0.20(14)] × 10−3 K−1 and ∂2
K
S
/∂P∂T = [−0.20(24), 0.22(26)] × 10−3 K−1, both of order 10−4 K−1 and not significantly different from zero. More robust inference of the mixed derivatives will require solid-medium acoustic
measurements of precision significantly better than 1%. 相似文献