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1.
Acfer 217-A new member of the Rumuruti chondrite group (R)   总被引：1，自引：0，他引：1  
Abstract— Previously, three meteorites from Australia and Antarctica were described as a new chondritic “grouplet” (Carlisle Lakes, Allan Hills (ALH) 85151, Yamato (Y) ?75302; Rubin and Kallemeyn, 1989). This grouplet was classified as the “Carlisle Lakes-type” chondrites (Weisberg et al., 1991). Recently, one Saharan sample and four more Antarctic meteorites were identified to belong to this group (Acfer 217, Y-793575, Y-82002, PCA91002, PCA91241). The latter two are probably paired. With the meteorite Rumuruti, the first fall of this type of chondrite is known (Schulze et al., 1994). We report here on the Saharan meteorite Acfer 217 which has chemical and mineralogical properties very similar to Rumuruti and Carlisle Lakes. All eight members of this group, Rumuruti, Carlisle Lakes, ALH85151, Y-75302, Y-793575, Y-82002, Acfer 217, and the paired samples PCA91002 and PCA91241 justify the introduction of a new group of chondritic meteorites, the Rumuruti meteorites (R). Acfer 217 is a regolith breccia consisting of up to cm-sized clasts (～33 vol%) embedded in a fine-grained, well-lithified clastic matrix. The most abundant mineral is olivine (～72 vol%), which has a high Fa-content of 37–39 mol%. The major minerals (olivine, low-Ca pyroxene, Ca-pyroxene, and plagioclase) show some compositional variability indicating a slightly unequilibrated nature of the meteorite. Considering the mean olivine composition of Fa37.8 ± 5.7, a classification of Acfer 217 as a R3.8 chondrite would result; however, Acfer 217 is a regolith breccia consisting of clasts of various petrologic types. Therefore, we suggest to classify Acfer 217 as a R3–5 chondrite regolith breccia. The bulk meteorite is very weakly shocked (S2). The bulk composition of Acfer 217 and other R-meteorites show that the R-meteorites are basically chondritic in composition. The pattern of moderately volatile elements is unique in R chondrites; Na and Mn are essentially undepleted, similar to ordinary chondrites, while Zn and Se contents are similar to concentrations in CM chondrites. The oxygen isotopic composition in Acfer 217 is similar to that of Rumuruti, Carlisle Lakes, ALH 85151, and Y-75302. In a δ17O vs. δ18O-diagram, the R-meteorites form a group well resolved from other chondrite groups. Acfer 217 was a meteoroid of common size with a radius between 15–65 cm and with a single stage exposure history. Based on 21Ne, an exposure age of about 35 Ma was calculated.  相似文献   

2.
Abstract— The Rumuruti meteorite shower fell in Rumuruti, Kenya, on 1934 January 28 at 10:43 p.m. Rumuruti is an olivine-rich chondritic breccia with light-dark structure. Based on the coexistence of highly recrystallized fragments and unequilibrated components, Rumuruti is classified as a type 3–6 chondrite breccia. The most abundant phase of Rumuruti is olivine (mostly Fa～39) with about 70 vol%. Feldspar (～14 vol%; mainly plagioclase), Ca-pyroxene (5 vol%), pyrrhotite (4.4 vol%), and pentlandite (3.6 vol%) are major constituents. All other phases have abundances below 1 vol%, including low-Ca pyroxene, chrome spinels, phosphates (chlorapatite and whitlockite), chalcopyrite, ilmenite, tridymite, Ni-rich and Ge-containing metals, kamacite, and various particles enriched in noble metals like Pt, Ir, arid Au. The chemical composition of Rumuruti is chondritic. The depletion in refractory elements (Sc, REE, etc.) and the comparatively high Mn, Na, and K contents are characteristic of ordinary chondrites and distinguish Rumuruti from carbonaceous chondrites. However, S, Se, and Zn contents in Rumuruti are significantly above the level expected for ordinary chondrites. The oxygen isotope composition of Rumuruti is high in δ17O (5.52 ‰) and δ18O (5.07 ‰). Previously, a small number of chondritic meteorites with strong similarities to Rumuruti were described. They were called Carlisle Lakes-type chondrites and they comprise: Carlisle Lakes, ALH85151, Y-75302, Y-793575, Y-82002, Acfer 217, PCA91002, and PCA91241, as well as clasts in the Weatherford chondrite. All these meteorites are finds from hot and cold deserts having experienced various degrees of weathering. With Rumuruti, the first meteorite fall has been recognized that preserves the primary mineralogical and chemical characteristics of a new group of meteorites. Comparing all chondrites, the characteristic features can be summarized as follows: (a) basically chondritic chemistry with ordinary chondrite element patterns of refractory and moderately volatile lithophiles but higher abundances of S, Se, and Zn; (b) high degree of oxidation (37–41 mol% Fa in olivine, only traces of Fe, Ni-metals, occurrence of chalcopyrite); (c) exceptionally high Δ17O values of about 2.7 for bulk samples; (d) high modal abundance of olivine (～70 vol%); (e) Ti-Fe3+?rich chromite (～5.5 wt% TiO2); (f) occurrence of various noble metal-rich particles; (g) abundant chondritic breccias consisting of equilibrated clasts and unequilibrated lithologies. With Rumuruti, nine meteorite samples exist that are chemically and mineralogically very similar. These meteorites are attributed to at least eight different fall events. It is proposed in this paper to call this group R chondrites (rumurutiites) after the first and only fall among these meteorites. These meteorites have a close relationship to ordinary chondrites. However, they are more oxidized than any of the existing groups of ordinary chondrites. Small, but significant differences in chemical composition and in oxygen isotopes between R chondrites and ordinary chondrites exclude formation of R chondrites from ordinary chondrites by oxidation. This implies a separate, independent R chondrite parent body.  相似文献   

3.
Abstract— A series of 59 impacts in the laboratory reduced a coherent 460 g piece of the L6 ordinary chondrite ALH 85017 to a coarse‐grained “regolith.” We then subjected the 125–250 μm fines from this sample to reverberation shock stresses of 14.5–67 GPa in order to delineate the melting behavior of porous, unconsolidated, chondritic asteroid surfaces during meteorite impact. The initial pore space (40–50%) was completely closed at 14.5 GPa and a dense aggregate of interlocking grains resulted. Grain‐boundary melting commenced at <27 GPa and ?50% of the total charge was molten at 67 GPa; this stress corresponds to typical asteroid impacts at ?5 km/sec. Melting of the entire sample most likely mandates >80 GPa, which is associated with impact velocities >8 km/sec. The Fe‐Ni and troilite clasts of the original meteorite melted with particular ease, forming immiscible melts that are finely disseminated throughout the silicate glass. These metal droplets are highly variable in size, extending to <100 nm and most likely to superparamagnetic domains; such opaques are also observed in the natural melt veins of ordinary chondrites. It follows that melting and dissemination of pre‐existing, Fe‐rich phases may substantially affect the optical properties of asteroidal surfaces. It seems unnecessary to invoke reduction of Fe2+ (or Fe3+) by sputtering or impact‐processes—in analogy to the lunar surface—to produce “space weathering” effects on S‐type asteroids. We note that HED meteorites contain ample FeO (comparable to that in lunar basalts) for reduction processes to take place, yet their probable parent object(s), Vesta and its collisional fragments, display substantially unweathered surfaces. Howardites, eucrites, and diogenites (HEDs), however, contain little native metal (typically <0.5%), in contrast to ordinary chondrites (commonly 10–15%) and their S‐type parent objects. These considerations suggest that the modal content of native metal and sulfides is more important for space weathering on asteroids than total FeO.  相似文献   

4.
Abstract— The Brunflo fossil meteorite was found in the 1950s in mid‐Ordovician marine limestone in the Gärde quarry in Jämtland. It originates from strata that are about 5 million years younger than similar limestone that more recently has yielded >50 fossil meteorites in the Thorsberg quarry at Kinnekulle, 600 km to the south. Based primarily on the low TiO2 content (about 1.8 wt%) of its relict chromite the Brunflo meteorite had been tentatively classified as an H chondrite. The meteorite hence appears to be an anomaly in relation to the Kinnekulle meteorites, in which chromite composition, chondrule mean diameter and oxygen isotopic composition all indicate an L‐chondritic origin, reflecting an enhanced flux of meteorites to Earth following the disruption of the L chondrite parent body 470 Ma. New chondrule‐size measurements for the Brunflo meteorite indicate that it too is an L chondrite, related to the same parent‐body breakup. Chromite maximum diameters and well‐defined chondrule structures further show that Brunflo belongs to the L4 or L5 type. Chromites in recently fallen L4 chondrites commonly have low TiO2 contents similar to the Brunflo chromites, adding support for Brunflo being an L4 chondrite. The limestone in the Gärde quarry is relatively rich (about 0.45 grain kg−1) in sediment‐dispersed extraterrestrial chromite grains (>63 μm) with chemical composition similar to those in L chondrites and the limestone (1–3 grains kg−1) at Kinnekulle, suggesting that the enhanced flux of L chondrites prevailed, although somewhat diminished, at the time when the Brunflo meteorite fell.  相似文献   

5.
Low‐temperature specific heat capacities of meteorites provide valuable data for understanding the composition and evolution of meteorites and modeling the thermal behavior of their source asteroids. By liquid nitrogen immersion, we measured average low‐temperature heat capacities for 60 ordinary chondrite falls from the Vatican collection. We further characterized the temperature dependence of ordinary chondrite by direct measurement of Cp(T) over the range 5–320 K for five OC falls, coupled by composition‐based models for 94 ordinary chondrites. We find that the heat capacity as a function of temperature for typical ordinary chondrites can be closely approximated by a third‐order polynomial in temperature. Furthermore, those polynomial coefficients can be estimated from the single‐value average heat capacity measurement. These measurements have important implications for the orbital and spin evolution of S‐ and Q‐type asteroids via the various Yarkovsky effects and the thermal evolution of meteorite parent bodies.  相似文献   

6.
The abundances of highly siderophile elements (HSE; including Re, Os, Ir, Ru, Pt, and Pd) and 187Re‐187Os isotopic systematics were determined for two fragments from ungrouped achondrite NWA 7325. Rhenium‐Os systematics are consistent with closed‐system behavior since formation or soon after. The abundances of the HSE were therefore largely unaffected by late‐stage secondary processes such as shock or terrestrial weathering. As an olivine gabbro cumulate, this meteorite has a bulk composition consistent with derivation from a body that produced a core, mantle, and crust. Also consistent with derivation from a body that produced a core, both fragments of NWA 7325 have HSE abundances that are highly depleted compared to bulk chondrites. One fragment has ~0.002× CI chondrite Ir and relative HSE abundances similar to bulk chondrites. The other fragment has ~0.0002× CI chondrite Ir and relative HSE abundances that are fractionated compared to bulk chondrites. The chondritic relative HSE abundances of the fragment characterized by higher HSE abundances most likely reflect the addition of exogenous chondritic material during or after crystallization by surface impacts. The HSE in the other fragment is likely more representative of the parent body crust. One formation model that can broadly account for the HSE abundances in this fragment is multiple episodes of low‐pressure metal‐silicate equilibration, followed by limited late accretion and mantle homogenization. Given the different HSE compositions of the two adjoining fragments, this meteorite provides an example of the overprint of global processes (differentiation and late accretion) by localized impact contamination.  相似文献   

7.
We report and describe an L6 ordinary chondrite fall that occurred in Ardón, León province, Spain (longitude 5.5605°W, latitude 42.4364°N) on July 9th, 1931. The 5.5 g single stone was kept hidden for 83 yr by Rosa González Pérez, at the time an 11 yr old who had observed the fall and had recovered the meteorite. According to various newspaper reports, the event was widely observed in Northern Spain. Ardón is a very well‐preserved, fresh, strongly metamorphosed (petrologic type 6), and weakly shocked (S3) ordinary chondrite with well‐equilibrated and recrystallized minerals. The mineral compositions (olivine Fa23.7±0.3, low‐Ca pyroxene Fs20.4±0.2Wo1.5±0.2, plagioclase An10.3±0.5Ab84.3±1.2), magnetic susceptibility (log χ = 4.95 ± 0.05 × 10?9 m3 kg?1), bulk density (3.49 ± 0.05 g   cm?3), grain density (3.58 ± 0.05 g   cm?3), and porosity (2.5 vol%) are typical for L6 chondrites. Short‐lived radionuclides confirm that the meteorite constitutes a recent fall. The 21Ne and 38Ar cosmic ray exposure ages are both about 20–30 Ma, similar to values for many other L chondrites. The cosmogenic 22Ne/21Ne ratio indicates that preatmospheric Ardón was a relatively large body. The fact that the meteorite was hidden in private hands for 83 yr makes one wonder if other meteorite falls may have experienced the same fate, thus possibly explaining the anomalously low number of falls reported in continental Spain in the 20th century.  相似文献   

8.
Abstract— Bencubbin is an unclassified meteorite breccia which consists mainly of host silicate (～40 vol.%) and host metal (～60%) components. Rare (< 1%) ordinary chondrite clasts and a dark xenolith (formerly called a carbonaceous chondrite clast) are also found. A petrologic study of the host silicates shows that they have textures, modes, mineralogy and bulk compositions that are essentially the same as that of barred olivine (BO) chondrules, and they are considered to be BO chondritic material. Bulk compositions of individual host silicate clasts are identical and differ only in their textures which are a continuum from coarsely barred, to finely barred, to feathery microcrystalline; these result from differing cooling rates. The host silicates differ from average BO chondrules only in being angular clasts rather than fluid droplet-shaped objects, and in being larger in size (up to 1 cm) than most chondrules; but large angular to droplet-shaped chondrules occur in many chondrites. Bencubbin host metallic FeNi clasts have a positive Ni-Co trend, which coincides with that of a calculated equilibrium nebular condensation path. This appears to indicate a chondritic, rather than impact, origin for this component as well. The rare ordinary chondrite clast and dark xenolith also contain FeNi metal with compositions similar to that of the host metal. Two scenarios are offered for the origin of the Bencubbin breccia. One is that the Bencubbin components are chondritic and were produced in the solar nebula. Later brecciation, reaggregation and minor melting of the chondritic material resulted in it becoming a monomict chondritic breccia. The alternative scenario is that the Bencubbin components formed as a result of major impact melting on a chondritic parent body; the silicate fragments were formed from an impact-induced lava flow and are analogous to the spinifex-textured rocks characteristic of terrestrial komatiites. Both scenarios have difficulties, but the petrologic, chemical and isotopic data are more consistent with Bencubbin being a brecciated chondrite. Bencubbin has a number of important chemical and isotopic characteristics in common with the major components in the CR (Renazzo-type) chondrites and the unique ALH85085 chondrite, which suggests that their major components may be related. These include: (1) Mafic silicates that are similarly Mg-rich and formed in similar reducing environments. (2) Similarly low volatiles; TiO2, Al2O3 and Cr2O3 contents are also similar. (3) Similar metallic FeNi compositions that sharply differ from those in other chondrites. (4) Remarkable enrichments in 15N. (5) Similar oxygen isotopic compositions that lie on the same mixing line. Thus, the major components of the Bencubbin breccia are highly similar to those of the ALH85085 and CR chondrites and they may have all formed in the same isotopic reservoir, under similar conditions, in the CR region of the solar nebula.  相似文献   

9.
Abstract— We have measured O‐isotopic ratios in a variety of olivine grains in the CO3 chondrite Allan Hills (ALH) A77307 using secondary ion mass spectrometry in order to study the chondrule formation process and the origin of isolated olivine grains in unequilibrated chondrites. Oxygen‐isotopic ratios of olivines in this chondrite are variable from δ17O = ?15.5 to +4.5% and δ18O = ?11.5 to +3.9%, with Δ17O varying from ?10.4 to +3.5%. Forsteritic olivines, Fa<1, are enriched in 16O relative to the bulk chondrite, whereas more FeO‐rich olivines are more depleted in 16O. Most ratios lie close to the carbonaceous chondrite anhydrous minerals (CCAM) line with negative values of Δ17O, although one grain of composition Fa4 has a mean Δ17O of +1.6%. Marked O‐isotopic heterogeneity within one FeO‐rich chondrule is the result of incorporation of relic, 16O‐rich, Mg‐rich grains into a more 16O‐depleted host. Isolated olivine grains, including isolated forsterites, have similar O‐isotopic ratios to olivine in chondrules of corresponding chemical composition. This is consistent with derivation of isolated olivine from chondrules, as well as the possibility that isolated grains are chondrule precursors. The high 16O in forsteritic olivine is similar to that observed in forsterite in CV and CI chondrites and the ordinary chondrite Julesburg and suggests nebula‐wide processes for the origin of forsterite that appears to be a primitive nebular component.  相似文献   

10.
Abstract— The magnetometer experiment (MAG) onboard the Near‐Earth Asteroid Rendezvous (NEAR)‐Shoemaker spacecraft detected no global scale magnetization and established a maximum magnetization of 2.1 times 10?6 Am2 kg?1 for asteroid 433 Eros. This is in sharp contrast with the estimated magnetization of other S‐class asteroids (Gaspra, ?2.4 times 10?2 Am2 kg?1; Braille, ?2.8 times 10?2 Am2 kg?1) and is below published values for all types of ordinary chondrites. This includes the L/LL types considered to most closely match 433 Eros based on preliminary interpretations of NEAR remote geochemical experiments. The ordinary chondrite meteorite magnetization intensity data was reviewed in order to assess the reasonableness of an asteroid‐meteorite match based on magnetic property measurements. Natural remanent magnetization (NRM) intensities for the ordinary chondrite meteorites show at least a 2 order of magnitude range within each of the H, L, and LL groups, all well above the 2.1 times 10?6 Am2 kg?1 level for 433 Eros. The REM values (ratio of the NRM to the SIRM (saturation remanent magnetization)) range over 3 orders of magnitude for all chondrite groups indicating no clear relationship between NRM and the amount of magnetic material. Levels of magnetic noise in chondrite meteorites can be as much as 70% or more of the NRM. Consequently, published values of the NRM should be considered suspect unless careful evaluation of the noise sources is done. NASA Goddard SFC studies of per unit mass intensities in large (>10 000 g) and small (down to <1 g) samples from the same meteorite demonstrate magnetic intensity decreases as size increases. This would appear to be explained by demagnetization due to magnetic vector randomness at unknown scale sizes in the larger samples. This would then argue for some level of demagnetization of large objects such as an asteroid. The possibility that 433 Eros is an LL chondrite cannot be discounted.  相似文献   

11.
Abstract— In order to investigate the distribution of 26A1 in chondrites, we measured aluminum‐magnesium systematics in four calcium‐aluminum‐rich inclusions (CAIs) and eleven aluminum‐rich chondrules from unequilibrated ordinary chondrites (UOCs). All four CAIs were found to contain radiogenic 26Mg (26Mg*) from the decay of 26A1. The inferred initial 26Al/27Al ratios for these objects ((26Al/27Al)0 ? 5 × 10?5) are indistinguishable from the (26Al/27Al)0 ratios found in most CAIs from carbonaceous chondrites. These observations, together with the similarities in mineralogy and oxygen isotopic compositions of the two sets of CAIs, imply that CAIs in UOCs and carbonaceous chondrites formed by similar processes from similar (or the same) isotopic reservoirs, or perhaps in a single location in the solar system. We also found 26Mg* in two of eleven aluminum‐rich chondrules. The (26Al/27Al)0 ratio inferred for both of these chondrules is ～1 × 10?5, clearly distinct from most CAIs but consistent with the values found in chondrules from type 3.0–3.1 UOCs and for aluminum‐rich chondrules from lightly metamorphosed carbonaceous chondrites (～0.5 × 10?5 to ～2 × 10?5). The consistency of the (26Al/27Al)0 ratios for CAIs and chondrules in primitive chondrites, independent of meteorite class, implies broad‐scale nebular homogeneity with respect to 26Al and indicates that the differences in initial ratios can be interpreted in terms of formation time. A timeline based on 26Al indicates that chondrules began to form 1 to 2 Ma after most CAIs formed, that accretion of meteorite parent bodies was essentially complete by 4 Ma after CAIs, and that metamorphism was essentially over in type 4 chondrite parent bodies by 5 to 6 Ma after CAIs formed. Type 6 chondrites apparently did not cool until more than 7 Ma after CAIs formed. This timeline is consistent with 26Al as a principal heat source for melting and metamorphism.  相似文献   

12.
The hornblende‐ and biotite‐bearing R chondrite LAP 04840 is a rare kind of meteorite possibly containing outer solar system water stored during metamorphism or postshock annealing deep within an asteroid. Because little is known regarding its age and origin, we determined 40Ar/39Ar ages on hornblende‐rich separates of the meteorite, and obtained plateau ages of 4340(±40) to 4380(±30) Ma. These well‐defined plateau ages, coupled with evidence for postshock annealing, indicate this meteorite records an ancient shock event and subsequent annealing. The age of 4340–4380 Ma (or 4.34–4.38 Ga) for this and other previously dated R chondrites is much older than most impact events recorded by ordinary chondrites and points to an ancient event or events that predated the late heavy bombardment that is recorded in so many meteorites and lunar samples.  相似文献   

13.
Abstract– The Moss meteorite is the first CO chondrite fall after a time period of 70 yr and the least terrestrially contaminated member of its group. Its cosmic‐ray exposure (CRE) age (T3 ～ 13.5 Ma; T21 ～ 14.6 Ma) is distinct among CO chondrites and, within witnessed falls is the shortest after Lancé, which we have reanalyzed. Gas retention ages are approximately 3.95 × 109 yr (U/Th‐He) and approximately 4.43 × 109 yr (K/Ar), respectively. Trapped Ar, Kr, and Xe are present in Moss in abundances typical for CO chondrites, with “planetary” elemental and isotopic compositions. Presence of HL‐xenon from presolar diamonds is observed in the stepwise release analysis of Lancé. It may also be present in Moss, but it is difficult to ascertain in single‐step bulk analyses. It follows from our new data combined with a survey of the literature that the abundance of trapped gases in CO chondrites is not a good indicator of their petrological subtype.  相似文献   

14.
Abstract— Amoeboid olivine aggregates (AOAs) in the LL3.0 Semarkona chondrite have been studied by secondary ion mass spectrometry. The AOAs mainly consist of aggregates of olivine grains with interstitial Al‐Ti‐rich diopside and anorthite. Oxygen‐isotopic compositions of all phases are consistently enriched in 16O, with δ17,18O = ～?50‰. The initial 26Al/27Al ratios are calculated to be 5.6 ± 0.9 (2σ) × 10?5. These values are equivalent to those of AOAs and fine‐grained calcium‐aluminum‐rich inclusions (FGIs) from pristine carbonaceous chondrites. This suggests that AOAs in ordinary chondrites formed in the same 16O‐rich calcium‐aluminum‐rich inclusion (CAI)‐forming region of the solar nebula as AOAs and FGIs in carbonaceous chondrites, and subsequently moved to the accretion region of the ordinary chondrite parent body in the solar nebula.  相似文献   

15.
Abstract— Mössbauer absorption areas corresponding to 57Fe in olivine, pyroxene, troilite, and the metallic phase in ordinary chondrites are shown to exhibit certain systematic behaviors. H chondrites occupy 2 distinct regions on the plot of metallic phase absorption area versus silicate absorption area, while L/LL chondrites fall in a separate region. Similar separation is also observed when pyroxene absorption area is plotted against olivine absorption area. The one‐dimensional plot for the ratio of olivine area to pyroxene area separates L and LL chondrites. Based on these systematics, a newly fallen meteorite at Jodhpur, India is suggested to be an LL chondrite.  相似文献   

16.
The CI1 Orgueil meteorite is a highly aqueously altered carbonaceous chondrite. It has been extensively studied, and despite its extensive degree of aqueous alteration and some documented instances of contamination, several indigenous organic compounds including amino acids, carboxylic acids, and nucleobases have been detected in its carbon‐rich matrix. We recently developed a novel gas chromatographic method for the enantiomeric and compound‐specific isotopic analyses of meteoritic aliphatic monoamines in extracts and have now applied this method to investigate the monoamine content in Orgueil. We detected 12 amines in Orgueil, with concentrations ranging from 1.1 to 332 nmol g?1 of meteorite and compared this amine content in Orgueil with that of the CM2 Murchison meteorite, which experienced less parent‐body aqueous alteration. Methylamine is four times more abundant in Orgueil than in Murchison. As with other species, the amine content in Orgueil extracts shows less structural diversity than that in Murchison extracts. We measured the compound‐specific stable carbon isotopic ratios (δ13C) for 5 of the 12 monoamines detected in Orgueil and found a range of δ13C values from –20 to +59‰. These δ13C values fall into the range of other meteoritic organic compounds, although they are 13C‐depleted relative to their counterparts extracted from the Murchison meteorite. In addition, we measured the enantiomeric composition for the chiral monoamines (R)‐ and (S)‐sec‐butylamine in Orgueil, and found it was racemic within experimental error, in contrast with the l ‐enantiomeric excess found for its amino acid structural analog isovaline. The racemic nature of sec‐butylamine in Orgueil was comparable to that previously observed in Murchison, and to other CM2 and CR2 carbonaceous chondrites measured in this work (ALH 83100 [CM1/2], LON 94101 [CM2], LEW 90500 [CM2], LAP 02342 [CR2], and GRA 95229 [CR2]). These results allow us to place some constraints on the effects of aqueous alteration observed over the monoamine concentrations in Orgueil and Murchison, and to evaluate the primordial synthetic relationships between meteoritic monoamines and amino acids.  相似文献   

17.
Abstract— Black ordinary chondrite meteorites sample the spectral effects of shock on ordinary chondrite material in the space environment. Since shock is an important regolith process, these meteorites may provide insight into the spectral properties of the regoliths on ordinary chondrite parent bodies. To determine how common black chondrites are in the meteorite collection and, by analogy, the frequency of shock-alteration in ordinary chondrites, several of the world's major meteorite collections were examined to identify black chondrites. Over 80% of all catalogued ordinary chondrites were examined and, using an optical definition, 61 black chondrites were identified. Black chondrites account for approximately 13.7% of ordinary chondrite falls. If the optically altered gas-rich ordinary chondrites are included, the proportion of falls that exhibit some form of altered spectral properties increases to 16.7%. This suggests that optical alteration of asteroidal material in the space environment is a relatively common process.  相似文献   

18.
Abstract– In situ secondary ion mass spectrometry analyses of 32S, 33S, and 34S in iron‐nickel sulfide grains in two CI1 chondrites and six CM chondrites were performed. The results show a wider range of both enrichment and depletion in δ34S relative to troilite from the Canyon Diablo meteorite (CDT) than has been observed in previous studies. All data points lie within error of a single mass dependent fractionation line. Sulfides from CI1 chondrites show δ34SCDT from ?0.7 to 6.8‰, while sulfide grains in the CM1 chondrite are generally depleted in heavy sulfur relative to CDT (δ34S from ?2.9 to 1.8‰). CM2 chondrites contain sulfide grains that show enrichment and depletion in 34S (δ34SCDT from ?7.0 to 6.8‰). Sulfates forming from sulfide grains during aqueous alteration on the chondrite parent body are suggested to concentrate light sulfur, leaving the remaining sulfide grains enriched in the heavy isotopes of sulfur. The average degree of enrichment in 34S in CM chondrite sulfides is broadly consistent with previously suggested alteration sequences.  相似文献   

19.
Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ17O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.  相似文献   

20.
Abstract— Correlated in situ analyses of the oxygen and magnesium isotopic compositions of aluminum‐rich chondrules from unequilibrated enstatite chondrites were obtained using an ion microprobe. Among eleven aluminum‐rich chondrules and two plagioclase fragments measured for 26Al‐26Mg systematics, only one aluminum‐rich chondrule contains excess 26Mg from the in situ decay of 26Al; the inferred initial ratio (26Al/27Al)o = (6.8 ± 2.4) × 10?6 is consistent with ratios observed in chondrules from carbonaceous chondrites and unequilibrated ordinary chondrites. The oxygen isotopic compositions of five aluminum‐rich chondrules and one plagioclase fragment define a line of slope ?0.6 ± 0.1 on a three‐oxygen‐isotope diagram, overlapping the field defined by ferromagnesian chondrules in enstatite chondrites but extending to more 16O‐rich compositions with a range in δ18O of about ?12‰. Based on their oxygen isotopic compositions, aluminum‐rich chondrules in unequilibrated enstatite chondrites are probably genetically related to ferromagnesian chondrules and are not simple mixtures of materials from ferromagnesian chondrules and calcium‐aluminum‐rich inclusions (CAIs). Relative to their counterparts from unequilibrated ordinary chondrites, aluminum‐rich chondrules from unequilibrated enstatite chondrites show a narrower oxygen isotopic range and much less resolvable excess 26Mg from the in situ decay of 26Al, probably resulting from higher degrees of equilibration and isotopic exchange during post‐crystallization metamorphism. However, the presence of 26Al‐bearing chondrules within the primitive ordinary, carbonaceous, and now enstatite chondrites suggests that 26Al was at least approximately homogeneously distributed across the chondrite‐forming region.  相似文献   

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