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1.
Biological Degradation of 2,4-Dinitrotoluene in a Continuous Bioreactor and Kinetic Studies Experimental results on the aerobic biological degradation with complete mineralization of 2,4-dinitrotoluene (2,4-DNT) are presented. A culture of Pseudomonas sp. DNT from Spain and Nishino was used. The degradation was examined with batch cultures for the determination of kinetic and stoichiometric coefficients. Further experiments were carried out with a continuous culture in a fixed-bed reactor with recirculation in order to obtain high degradation rates. The reactor was packed with ceramic Raschig rings (55 mL) and had a liquid reaction volume of 160 mL. The minimal salt media from Spanggord et al. with and without (NH4)2S)4 as nitrogen source was used as substrate. 2,4-DNT was the sole source of carbon and energy. From batch experiments a yield coefficient YB/S = (0.30 ± 0.05) g g?1 was calculated from a mass balance of the elements. This result was confirmed by calculations using literature data. Fitting the experimental data to the Monod equation, μmax = 0.1 h?1 and KS = 0.01…0.03 mmol L?1 were obtained. It was demonstrated by batch experiments that 2,4-DNT is not only used as the source of carbon and energy but also as the nitrogen source. In the fixed-bed reactor, a degradation of 92…97% was reached with a maximal 2,4-DNT load of 95 mg L?1 h?1. The rate of continuous degradation could be described by a pseudo-first-order reaction (k = 9.73 h?1). The complete mineralization of 2,4-DNT was verified by the measurement of DOC and the formed nitrite and nitrate. The formed nitrite was nitrified simultaneously. It was demonstrated by these experiments that large scale biological treatment of industrial effluent containing 2,4-DNT may be successful. 相似文献
2.
The degradation behaviour of a phenolic waste-water from coking containing easily utilizable carbon sources (volatile fatty acids), substances with toxic effects (phenols and phenolic compounds), and non-biodegradable organic substances (humic-like substances) by an adapted activated sludge is investigated depending on dissolved oxygen concentration (DO) and temperature. In addition, the degradation of an acetate model water with the same population was investigated. The investigations were carried out in a special respiration fermenter system by recording oxygen consumption in DO-static experiments. The oxygen consumption curves were subjected to linear regression analysis, and the maximum oxygen consumption rates were used for further calculations. Evaluation of the degradation kinetics was carried out with non-linear regression analysis via commercial software utilizing the Marquardt-Levenberg algorithm and which tested various kinetic models to obtain the best curve fit. It is shown that the dependence of growth on DO in acetate model water is well represented by Monod kinetics but by contrast can only be described in phenolic wastewater with acceptable goodness by Hill kinetics, modified by a maintenance term. The kinetic constants calculated for the mesophilic range (37 °C) are for the model water as follows: maximum specific growth rate = 0.218 h?1, half saturation constant with respect to oxygen = 0.297 g L?1, and for the waste-water: maximum specific growth rate = 0.387 h?1, half saturation constant with respect to oxygen = 0.013 gL?1 and maintenance coefficient for oxygen = 0.107 g g?1 h?1. For the thermophilic range (55 °C), a higher growth rate but a significant lower yield coefficient are to be observed. The kinetic constants calculated are: maximum specific growth rate = 0.8 h?1, half saturation constant with respect to oxygen = 0.14 gL?1 and maintenance coefficient for oxygen = 0.3 g g?1 h?1. Therefore, it can be concluded that the toxic effect of the biodegradable phenols causes a maintenance metabolism which leads to higher oxygen demand. The diminution of the limiting DO and the increased maintenance metabolism confirm the assumption that a higher maintenance metabolism leads to increased sensitivity with respect to the cosubstrate oxygen. It can be concluded that the experimental and mathematical methods used permit the maintenance metabolism with respect to oxygen caused by toxic substrates and milieu influences to be accurately determined. 相似文献
3.
Celalettin Özdemir Hayrunnisa Tezcan Serkan Sahinkaya Erkan Kalipci 《洁净——土壤、空气、水》2010,38(12):1152-1158
The removal of chemical oxygen demand (COD) and phenol from olive oil mill wastewaters (OOMW) was investigated experimentally by using conventional Fenton (CFP) and Fenton type processes (FTP) with zero valent iron (ZVI). Different operational parameters such as initial pH, Fe2+, Fe0, and H2O2 concentrations were examined. Kinetic studies in terms of COD and phenol removals for both CFP and FTP were performed. The original pH value (4.6) of OOMW for CFP was found as the optimum pH. The determined optimum conditions are [Fe2+] = 1500 mg L?1, [H2O2] = 1750 mg L?1, and pH = 4.6 for CFP; [Fe0] = 2000 mg L?1, [H2O2] = 2000 mg L?1, and pH = 3 for FTP. 82.4% COD and 62% phenol removals were performed under the optimum conditions by CFP, while 82% COD and 63.4% phenol were removed by FTP. According to the results of kinetic studies, it was observed that COD and phenol were removed by FTP more rapidly, compared to CFP. Consequently, it was determined that both CFP and FTP were effective processes for the pretreatment of OOMW. 相似文献
4.
This study aims to remove of Cu2+, Cd2+, and Pb2+ ions from solution and to investigate the adsorption isotherms, adsorption kinetics, and ion‐exchange affinities of these metals using waste activated sludge (AS) biomass. The adsorptions of the metals on biomass were optimal at an acidic pH value of 6.0 based on its monolayer capacities. Maximum monolayer capacities of AS biomass (qmax) were calculated as 0.478, 0.358, and 0.280 mmol g?1 for Cu2+, Cd2+, and Pb2+, respectively, and the adsorption equilibrium time was found as 60 min for each metal. The adsorbed amount of metal rose with increasing of initial metal ion concentration. The equilibrium adsorption capacity of AS for initial 0.25 mmol L?1 metal concentration was determined as 0.200, 0.167, and 0.155 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively. These relevant values were determined as 0.420, 0.305, and 0.282 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively, when initial metal concentration was 0.50 mmol L?1. In the multi‐metal sorption system, the adsorption capacity of AS biomass was observed in the order of Cu2+ > Cd2+ > Pb2+. In the presence of 100 mmol L?1 H+ ion, the order of ion‐exchange affinity with H+ was found as Cu2+ > Cd2+ > Pb2+. The adsorption kinetics were also found to be well described by the pseudo‐second‐order and intraparticle diffusion models. Two different rate constants were obtained as ki1 and ki2 and ki1 (first stage) was found to be higher than ki2 (second stage). 相似文献
5.
Pseudomonas putida MHF 7109 has been isolated and identified from cow dung microbial consortium for biodegradation of selected petroleum hydrocarbon compounds – benzene, toluene, and o‐xylene (BTX). Each compound was applied separately at concentrations of 50, 100, 250, and 500 mg L?1 in minimal salt medium to evaluate degradation activity of the identified microbial strain. The results indicated that the strain used has high potential to degrade BTX at a concentration of 50 mg L?1 within a period of 48, 96, and 168 h, respectively; whereas the concentration of 100 mg L?1 of benzene and toluene was found to be completely degraded within 120 and 168 h, respectively. Sixty‐two percent of o‐xylene were degraded within 168 h at the 100 mg L?1 concentration level. The maximum degradation rates for BTX were 1.35, 1.04, and 0.51 mg L?1 h?1, respectively. At higher concentrations (250 and 500 mg L?1) BTX inhibited the activity of microorganisms. The mass spectrometry analysis identified the intermediates as catechol, 2‐hydroxymuconic semialdehyde, 3‐methylcatechol, cis‐2‐hydroxypenta‐2,4‐dienoate, 2‐methylbenzyl alcohol, and 1,2‐dihydroxy‐6‐methylcyclohexa‐3,5‐dienecarboxylate, for BTX, respectively. P. putida MHF 7109 has been found to have high potential for biodegradation of volatile petroleum hydrocarbons. 相似文献
6.
Palanivel Sathishkumar Kannan Balan Thayumanavan Palvannan Seralathan Kamala‐Kannan Byung‐Taek Oh Susana Rodríguez‐Couto 《洁净——土壤、空气、水》2013,41(7):665-672
Laccase from the white‐rot fungus Pleurotus florida, produced under solid‐state fermentation conditions, was used for the decolorization of reactive dye Remazol Brilliant Blue R (RBBR). RBBR was decolorized up to 46% by P. florida laccase alone in 10 min. In the presence of N‐hydroxybenzotriazole (HBT), the rate of decolorization was enhanced 1.56‐fold. Central composite design of response surface methodology with four variables namely, dye, enzyme, redox mediator concentrations, and time at five levels was applied to optimize the RBBR decolorization. The predicted optimum level of variables for maximum RBBR decolorization (87%) was found to be 52.90 mg L?1 (RBBR), 1.87 U mL?1 (laccase), 0.85 mM (HBT), and 7.17 min (time), respectively. The validation results showed that the experimental value of RBBR decolorization (82%) was close to the predicted one. The disappearance of C–N and C–X groups, and a small shift in N–H groups in Fourier‐transform infra red (FTIR) spectroscopy confirms the degradation of RBBR chromophore by laccase enzyme. The phytotoxicity of RBBR was considerably reduced after the treatment with laccase. RBBR decolorization kinetics; Km and Vmax were calculated to be 145.82 mg L?1 and 24.86 mg L?1 min, respectively. 相似文献
7.
Biomass char (BC) deriving from fast pyrolysis of biomass was a potential adsorption material due to its relative high fixed‐carbon content and the inherent porous structures. Adsorption of phosphate from aqueous solution by BC was investigated in this paper. The results showed that the adsorption capacity of BC was dependent on pyrolysis conditions, such as temperature and holding time. The maximum adsorption capacity for phosphate was approximately 15.11 mg g?1 at 298 K. The pseudo‐second order model of the adsorption kinetics indicated that the adsorption process was complex and several mechanisms were involved. Equilibrium isotherm was satisfactorily followed the Freundlich isotherm model. The KF value in Freundlich equation gradually increased with elevating temperature. Moreover, the thermodynamic constants: ΔG0, ΔH0, and ΔS0 were evaluated as ?6.49 kJ mol?1 (at 298 K), 13.41 kJ mol?1, and 66.70 J mol?1 K?1, respectively. Phosphate adsorption onto BC was spontaneous and endothermic. As a waste, BC was a potentially attractive adsorbent for phosphate removal from aqueous solution with low cost and high capability. 相似文献
8.
A start‐up study for biohydrogen production from palm oil mill effluent (POME) is carried out in a pilot‐scale up‐flow anaerobic sludge blanket fixed‐film reactor (UASFF). A substrate with a chemical oxygen demand (COD) of 30 g L?1 is used, starting with molasses solution for 30 days and followed by a 10% v/v increment of POME/molasses ratio. At 100% POME, a hydrogen content of 80%, hydrogen production rate of 36 L H2 per day, and maximum COD removal of 48.7% are achieved. Bio‐kinetic coefficients of Monod, first‐order, Grau second‐order, and Stover‐Kincannon kinetic models are calculated to describe the performance of the system. The steady‐state data with 100% POME shows that Monod and Stover‐Kincannon models with bio‐kinetic coefficients of half‐velocity constant (Ks) of 6000 mg COD L?1, microbial decay rate (Kd) of 0.0015 per day, growth yield constant (Y) of 0.786 mg volatile suspended solids (VSS)/mg COD, specific biomass growth rate (μmax) of 0.568 per day, and substrate consumption rate of (Umax) 3.98 g/L day could be considered as superior models with correlation coefficients (R2) of 0.918 and 0.989, respectively, compared to first‐order and Grau's second‐order models with coefficients of K1 1.08 per day, R2 0.739, and K2s 1.69 per day, a = 7.0 per day, b = 0.847. 相似文献
9.
Abstract Rivers have been channelized, deepened and constrained by embankments for centuries to increase agricultural productivity and improve flood defences. This has decreased the hydrological connectivity between rivers and their floodplains. We quantified the hydrological regime of a wet grassland meadow prior to and after the removal of river embankments. River and groundwater chemistry were also monitored to examine hydrological controls on floodplain nutrient status. Prior to restoration, the highest river flows (～2 m3 s?1) were retained by the embankments. Under these flow conditions the usual hydraulic gradient from the floodplain to the river was reversed so that subsurface flows were directed towards the floodplain. Groundwater was depleted in dissolved oxygen (mean: 0.6 mg O2 L?1) and nitrate (mean: 0.5 mg NO3 ?-N L?1) relative to river water (mean: 10.8 mg O2 L?1 and 6.2 mg NO3 ?-N L?1, respectively). Removal of the embankments has reduced the channel capacity by an average of 60%. This has facilitated over-bank flow which is likely to favour conditions for improved flood storage and removal of river nutrients by floodplain sediments. Editor Z.W. Kundzewicz; Associate editor K. Heal Citation Clilverd, H.M., Thompson, J.R., Heppell, C.M., Sayer, C.D., and Axmacher, J.C., 2013. River–floodplain hydrology of an embanked lowland Chalk river and initial response to embankment removal. Hydrological Sciences Journal, 58 (3), 627–650. 相似文献
10.
Synoptic water sampling at a fixed site monitoring station provides only limited ‘snap‐shots’ of the complex water quality dynamics within a surface water system. However, water quality often changes rapidly in both spatial and temporal dimensions, especially in highly polluted urban rivers. In this study, we designed and applied a continuous longitudinal sampling technique to monitor the fine‐scale spatial changes of water quality conditions, assess water pollutant sources, and determine the assimilative capacity for biochemical oxygen demand (BOD) in an urban segment of the hypoxic Wen‐Rui Tang River in eastern China. The continuous longitudinal sampling was capable of collecting dissolved oxygen (DO) data every 5 s yielding a ~11 m sampling interval with a precision of ±0.1 mg L?1. The Streeter and Phelps BOD‐DO model was used to calculate: (1) the oxygen consumption coefficient (K1) required for calibration of water quality models, (2) BOD assimilative capacity, and (3) BOD source and load identification. In the 2014 m river segment sampled, the oxygen consumption coefficient (K1) was 0.428 d?1 (20°C), the total BOD discharge was 916 kg d?1, and the BOD assimilative capacity was 382 kg d?1 when the minimum DO level was set to 2 mg L?1. In addition, the longitudinal analysis identified eight major drainage outlets (BOD point sources), which were verified by field observations. This new approach provides a simple, cost‐effective method of evaluating BOD‐DO dynamics over large spatial areas with rapidly changing water quality conditions, such as urban environments. It represents a major breakthrough in the development and application of water quality sampling techniques to obtain spatially distributed DO and BOD in real time. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
11.
In the dimict lake Arend (5.1 km2, 146 hm3, 49.5 m zmax), nitrogen is production-limiting with concentrations below the detection limit during the production period. Phytoplankton achieves biomasses of up to 18 mg/l fresh matter, essential contributions being made by Aphanizomenon with 2 mg/l and Anabaena with up to 10 mg/l. Nitrogen fixation was measured by the ethine reduction technique (acetylene reduction) during periods of the occurrence of heterocystforming Cyanophyceae and achieved peak values up to 6.59 μg N2 · h?1 · l?1 or 14.87 m?2 · h?1 g N2 · m?2 · h?1. The rates of fixation show a safe correlation with the biomass of heterocyst-containing Cyanophyceae (r = 0.88), their development beginning at values below the N : P-ratio of 2.66. 相似文献
12.
The point measurement of soil properties allows to explain and simulate plot scale hydrological processes. An intensive sampling was carried out at the surface of an unsaturated clay soil to measure, on two adjacent plots of 4 × 11 m2 and two different dates (May 2007 and February–March 2008), dry soil bulk density, ρb, and antecedent soil water content, θi, at 88 points. Field‐saturated soil hydraulic conductivity, Kfs, was also measured at 176 points by the transient Simplified Falling Head technique to determine the soil water permeability characteristics at the beginning of a possible rainfall event yielding measurable runoff. The ρb values did not differ significantly between the two dates, but wetter soil conditions (by 31%) and lower conductivities (1.95 times) were detected on the second date as compared with the first one. Significantly higher (by a factor of 1.8) Kfs values were obtained with the 0.30‐m‐diameter ring compared with the 0.15‐m‐diameter ring. A high Kfs (> 100 mm h?1) was generally obtained for low θi values (< 0.3 m3m?3), whereas a high θi yielded an increased percentage of low Kfs data (1–100 mm h?1). The median of Kfs for each plot/sampling date combination was not lower than 600 mm h?1, and rainfall intensities rarely exceeded 100 mm h?1 at the site. The occurrence of runoff at the base of the plot needs a substantial reduction of the surface soil permeability characteristics during the event, probably promoted by a higher water content than the one of this investigation (saturation degree = 0.44–0.62) and some soil compaction due to rainfall impact. An intensive soil sampling reduces the risk of an erroneous interpretation of hydrological processes. In an unstable clay soil, changes in Kfs during the event seem to have a noticeable effect on runoff generation, and they should be considered for modeling hydrological processes. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
13.
Soil denitrification in reservoir shoreline wetlands is an important process for removing excess inorganic nitrogen from upland runoff and controlling eutrophication in aquatic ecosystems. As yet, little is known about the influence of vegetation characteristics on the soil denitrification potential in reservoir shoreline wetlands, although vegetation can affect both denitrifying bacteria and soil properties. In this study, we measured the spatial variability of denitrification enzyme activity (DEA) using acetylene block method in shoreline wetlands of the Danjiangkou Reservoir, a water source of the South‐to‐North Water Transfer Project in China. Results indicated that DEA ranged from 0.001 to 2.449 µg N (N2O) g?1 h?1, with a mean of 0.384 µg N (N2O) g?1 h?1. DEA varied significantly among five representative plant communities and the highest DEA (0.248–2.449 µg N (N2O) g?1 h?1) was observed in the Polygonum hydropiper community. Plant biomass and vegetation cover were significantly and positively related to DEA and together explained 44.2% of the total variance. These results suggest that vegetation characteristics should also be considered in assessing soil denitrification capacity and restoring shoreline wetlands for nitrogen pollution removal in the Danjiangkou Reservoir after dam heightening. 相似文献
14.
Effect of Mixtures of Heavy Metals on the Biological Treatment of Sewages Containing Naphthalenesulfonic Acid Biological wastewater treatment processes can be destabilized considerably by heavy metals. In this investigation, the effect of loadings of heavy metals on the degradation of naphthalene-2-sulfonic acid (2NS) by immobilized bacteria in continuously operated airlift-loop reactors was studied. Shock loadings with mixtures of cadmium and nickel, or cadmium and zinc, respectively, resulted in increases in inhibition compared to those observed with the single metals. In contrast, the 2NS-degradation was less inhibited by shock loadings with mixtures of nickel and zinc than by the single metal ions. Repeated shock loadings up to 100 mg L?1 nickel and 1000 mg L?1 zinc effected an adaptation of the microorganisms. Continuous loadings with up to 10 mg L?1 cadmium and nickel each, or with 50 mg L?1 nickel and 210 mg L?1 zinc, respectively, did not inhibit the degradation of 2NS. The permanent loadings led to an adaptation of the bacteria with an increased biosynthesis of proteins from 0.2 to 0.5 g g?1 cell dry weight. However, if the immobilized cells were incubated with mixtures of cadmium and nickel, the specific polysaccharide content decreased to less than 0.2 g g?1 cell dry weight, resulting in a detachment of the biofilms. 相似文献
15.
Sorptive removal of Ni(II) from electroplating rinse wastewaters by cation exchange resin Dueolite C 20 was investigated at the temperature of 30°C under dynamic conditions in a packed bed. The effects of sorbent bed length 0.1–0.2 m, fixed flow rate 6 dm3 min?1, and the initial rinse water concentration (C0) 53.1 mg L?1 on the sorption characteristics of Dueolite C 20 were investigated at an influent pH of 6.5. More than 94.5% of Ni(II) was removed in the column experiments. The column performance was improved with increasing bed height and decreasing the flow rate. The Thomas, Yoon–Nelson, Clark, and Wolborska models were applied to the experimental data to represent the breakthrough curves and determine the characteristic design parameters of the column. The sorption performance of the Ni(II) ions through columns could be well described by the Thomas, Yoon–Nelson, and Wolborska models at effluent‐to‐influent concentration ratios (C/C0) >0.03 and <0.99. Among the all models, the Clark model showed the least average percentage time deviation. The sorptive capacity of electroplating rinse water using Ni(II) was found to be 45.98 mg g?1. 相似文献
16.
Biosorption potential of Cedrus deodara sawdust (CDS) in terms of sorption of Zn(II) ion across liquid phase has been evaluated in the present investigation. The surface of the CDS biomass before the sorption of Zn(II) ions seemed to be more porous, non‐crystalline and heterogeneous. The maximum uptake capacity of CDS was 97.39 mg g?1. Sorption of Zn(II) ion on the surface of CDS sawdust was maximum at pH 5, temperature 45°C, initial concentration of Zn(II) ion 100 mg L?1, biomass dose 1 g L?1, contact time 150 min, and agitation rate 160 rpm. Pseudo second‐order kinetics with the highest linear regression coefficient (R2 = 0.99), and lowest values of error functions, i.e., chi (χ2) and sum of square errors (SSE) against pseudo first‐order rate kinetics showed that the sorption of Zn(II) ion on the surface of CDS was mediated by chemosoprtive forces of attraction rather than physical adsorption. Mechanistically, relatively higher proportion of sorption of Zn(II) ion in early phase of contact time was profoundly explained by Bangham's equation and film diffusivity (Df). Intraparticle or pore diffusion (Dp) of Zn(II) ion inside the pores of CDS was rate limiting step at the later stage of contact time. Furthermore, the thermodynamic study on sorption of metal ion delineated the fact that the Zn(II) sorption on the surface of CDS was spontaneous, endothermic together with increased entropy at solid liquid interface. 相似文献
17.
Trace metal clean sampling and analysis techniques were used to examine the temporal patterns of Hg, Cu, and Zn concentrations in shallow ground water, and the relationships between metal concentrations in ground water and in a hydrologically connected river. Hg, Cu, and Zn concentrations in ground water ranged from 0.07 to 4.6 ng L−1, 0.07 to 3.10 μg L−1, and 0.17 to 2.18 μg L−1, respectively. There was no apparent seasonal pattern in any of the metal concentrations. Filtrable Hg, Cu, and Zn concentrations in the North Branch of the Milwaukee River ranged from below the detection limit to 2.65 ng Hg L−1,0.51 to 4.30 μg Cu L−1, and 0.34 to 2.33 μg Zn L−1. Thus, metal concentrations in ground water were sufficiently high to account for a substantial fraction of the filtrable trace metal concentration in the river. Metal concentrations in the soil ranged from 8 to 86 ng Hg g−1, 10 to 39 μg Cu g−1, and 15 to 84 μg Zn g−1. Distribution coefficients, KD, in the aquifer were 7900,22,000, and 23,000 L kg−1 for Hg, Cu, and Zn, respectively. These values were three to 40 times smaller than KD values observed in the Milwaukee River for suspended particulate matter. 相似文献
18.
Bezafibrate (BZF), a widely used lipid regulator, is a potential threat to ecosystems and human health in water, and the recent research showed that advanced oxidation processes (AOPs) are much more effective for BZF degradation. In this study, we investigated the photochemical decomposition of BZF in surface water and effluent from waste water treatment plants (WWTP) by UV/H2O2 process. The results showed that the UV/H2O2 process was a promising method to remove BZF at low concentration, generally at µg L?1 level. When initial concentrations reach 100 µg L?1 in the deionized water, >99.8% of BZF could be removed in 16 min under UV intensity of 61.4 µm cm?2, at the H2O2 concentration of 0.1 mg L?1, and neutral pH condition. Moreover, BZF degradation was inhibited in this process when humic acid (HA) and inorganic solution anions were added to the deionized water solutions, including chloride, nitrate, bicarbonate, and sulfate, significantly. In the surface water and effluent of WWTP, however, the removal efficiency of BZF was lower than that in the deionized water because of the interference of complex constituents in the surface water and effluent. Some main intermediates at the m/z range of 100–400 were observed by high performance LC‐MS (HPLC/MS) and a simple pathway of BZF degradation by UV/H2O2 was proposed. 相似文献
19.
The present investigation evaluates the adsorption effectiveness of Cd(II) ions on Ficus religiosa leaf powder (FRL). The experimental parameters chosen included time, pH, particle size, temperature, adsorbate, anion, and Pb(II) concentrations. The time data followed pseudo‐second‐order kinetics. Cd(II) adsorption increased from 1.38 to 75.17% with the increase in pH from 2 to 4 and further increase in pH to 5.5 resulted in its marginal increase to 77.52%. Based on regression coefficient values, the isothermic data fitted the various models in the order Langmuir > Redlich–Peterson > Temkin > Freundlich model. The maximum loading capacity of FRL was estimated to be 27.14 mg g?1. The presence of Cl?, , or Pb2+ exhibited adverse effect on Cd(II) uptake. The thermodynamic parameters of enthalpy (ΔH0) and entropy (ΔS0) were estimated to be 8.31 kJ mol?1 and 38.22 J mol?1 K?1, respectively. SEM‐EPMA of the loaded FRL showed Cd(II) distribution at specific sites. The XRD patterns of Cd(II) loaded FRL sample showed disappearance of some peaks corresponding to β‐Ca(PO3)2; shifting of peaks and decrease in %RI corresponding to γ‐CaSO4 phase. Positive shift of IR bands for the Cd(II) loaded sample was observed. 相似文献
20.
Streambed horizontal hydraulic conductivity (Kh) has a substantial role in controlling exchanges between stream water and groundwater. We propose a new approach for determining Kh of the shallow streambed sediments. Undisturbed sediment samples were collected using tubes that were horizontally driven into streambeds. The sediment columns were analysed using a permeameter test (PT) on site. This new test approach minimizes uncertainties due to vertical flow in the vicinity of test tube and stream stage fluctuations in the computation of the Kh values. Ninety‐eight PTs using the new approach were conducted at eight sites in four tributaries of the Platte River, east‐central Nebraska, USA. The Kh values were compared with the nondirectional hydraulic conductivity values (Kg) determined from 12 empirical grain‐size analysis methods. The grain‐size analysis methods used the same sediment samples as Kh tests. Only two methods, the Terzaghi and Shepherd methods, yielded Kg values close to the Kh values. Although the Sauerbrei method produced a value relatively closer to Kh than other nine grain‐size analysis methods, the values from this method were not as reliable as the methods of Terzaghi and Shepherd due to the inconsistent fluctuation of the average estimates at each of the test sites. The Zunker, Zamarin, Hazen, Beyer, and Kozeny methods overestimated Kh, while the Slichter, US Bureau of Reclamation (USBR), Harleman, and Alyamani and Sen methods underestimated Kh. Any of these specific grain‐size methods might yield good estimates of streambed Kh at some sites, but give poor estimates at other sites, indicating that the relationship between Kg and Kh is significantly site dependent in our study. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献