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1.
Abstract— Concentration and isotopic composition of the light noble gases as well as of 84Kr, 129Xe, and 132Xe have been measured in bulk samples of 60 carbonaceous chondrites; 45 were measured for the first time. Solar noble gases were found in nine specimens (Arch, Acfer 094, Dar al Gani 056, Graves Nunataks 95229, Grosnaja, Isna, Mt. Prestrud 95404, Yamato (Y) 86009, and Y 86751). These meteorites are thus regolith breccias. The CV and CO chondrites contain abundant planetary‐type noble gases, but not CK chondrites. Characteristic features of CK chondrites are high 129Xe/132Xe ratios. The petrologic type of carbonaceous chondrites is correlated with the concentration of trapped heavy noble gases, similar to observations shown for ordinary chondrites. However, this correlation is disturbed for several meteorites due to a contribution of atmospheric noble gases, an effect correlated to terrestrial weathering effects. Cosmic‐ray exposure ages are calculated from cosmogenic 21Ne. They range from about 1 to 63.5 Ma for CO, CV, and CK classes, which is longer than exposure ages reported for CM and CI chondrites. Only the CO3 chondrite Isna has an exceptionally low exposure age of 0.15 Ma. No dominant clusters are observed in the cosmic‐ray exposure age distribution; only for CV and CK chondrites do potential peaks seem to develop at ～9 and ～29 Ma. Several pairings among the chondrites from hot deserts are suggested, but 52 of the 60 investigated meteorites are individual falls. In general, we confirm the results of Mazor et al. (1970) regarding cosmic‐ray exposure and trapped heavy noble gases. With this study, a considerable number of new carbonaceous chondrites were added to the noble gas data base, but this is still not sufficient to obtain a clear picture of the collisional history of the carbonaceous chondrite groups. Obviously, the exposure histories of CI and CM chondrites differ from those of CV, CO, and CK chondrites that have much longer exposure ages. The close relationship among the latter three is also evident from the similar cosmic‐ray exposure age patterns that do not reveal a clear picture of major breakup events. The CK chondrites, however, with their wide range of petrologic types, form the only carbonaceous chondrite group which so far lacks a solar‐gas‐bearing regolith breccia. The CK chondrites contain only minute amounts of trapped noble gases and their noble gas fingerprint is thus distinguishable from the other groups. In the future, more analyses of newly collected CK chondrites are needed to unravel the genetic and historic evolution of this group. It is also evident that the problems of weathering and pairing have to be considered when noble gas data of carbonaceous chondrite are interpreted.  相似文献   

2.
Abstract— The trapped noble gas record of 57 enstatite chondrites (E chondrites) has been investigated. Basically, two different gas patterns have been identified dependent on the petrologic type. All E chondrites of type 4 to 6 show a mixture of trapped common chondritic rare gases (Q) and a subsolar component (range of elemental ratios for E4–6 chondrites: 36Ar/132Xe = 582 ± 270 and 36Ar/84Kr = 242 ± 88). E3 chondrites usually contain Q gases, but also a composition with lower 36Ar/132Xe and 36Ar/84Kr ratios, which we call sub‐Q (36Ar/132Xe = 37.0 ± 18.0 and 36Ar/84Kr = 41.7 ± 18.1). The presence of either the subsolar or the sub‐Q signature in particular petrologic types cannot be readily explained by parent body metamorphism as postulated for ordinary chondrites. We therefore present a different model that can explain the bimodal distribution and composition of trapped heavy noble gases in E chondrites. Trapped solar noble gases have been observed only in some E3 chondrites. About 30% of each group, EH3 and EL3 chondrites, amounting to 9% of all analyzed E chondrites show the solar signature. Notably, only one of those meteorites has been explicitly described as a regolith breccia.  相似文献   

3.
The Kakangari chondrite has a cosmic-ray exposure age of 5.4 m.y. and a K-Ar age near 4 g.y. Its high cosmogenic 3He/21Ne ratio of 7.5 indicates a small preatmospheric mass. The He and Ne are largely of solar-wind origin, presumably implanted during exposure in the regolith of its parent body. The heavy gases Ar, Kr, Xe are largely of planetary origin. Taken together, the low 129Xe/132Xe (1.07), low 36Ar/132Xe (225), and high 132Xe content (45 × 10?10 cc STP/g) are more similar to the values for unequilibrated ordinary chondrites or even C1, C2 chondrites than to enstatite chondrites, and suggest that Kakangari has the same gas-bearing mineral assemblage as the former, in spite of its high degree of reduction (Fa4.9).  相似文献   

4.
Abstract— We present concentration and isotopic composition of He, Ne, and Ar in ten chondrites from the Nullarbor region in Western Australia as well as the concentrations of 84Ke, 129Xe, and 132Xe. From the measured cosmogenic 14C concentrations (Jull et al. 1995), shielding‐corrected production rates of 14C are deduced using cosmogenic 22Ne/21Ne ratios. For shielding conditions characterized by 22Ne/21Ne >1.10, this correction becomes significant and results in shorter terrestrial ages. The exposure ages of the ten Nullarbor chondrites are in the range of values usually observed in ordinary chondrites. Some of the meteorites have lost radiogenic gases as well as cosmogenic 3He. Most of the analyzed specimens show additional trapped Ar, Kr, and Xe of terrestrial origin. The incorporation of these gases into weathering products is common in chondrites from hot deserts.  相似文献   

5.
Abstract— Ar‐rich noble gases, the so‐called “subsolar” noble gases, are a major component of heavy primordial noble gases in unequilibrated ordinary chondrites and some classes of anhydrous carbonaceous chondrites, whereas they are almost absent in hydrous carbonaceous chondrites that suffered extensive aqueous alteration. To understand the effects of aqueous alteration on the abundance of Ar‐rich noble gases, we performed an aqueous alteration experiments on the Ningqiang type 3 carbonaceous chondrite that consists entirely of anhydrous minerals and contains Ar‐rich noble gases. Powdered samples and deionized neutral water were kept at 200 °C for 10 and 20 days, respectively. Mineralogical analyses show that, during the 10‐day alteration, serpentine and hematite formed at the expense of olivine, low‐Ca pyroxene, and sulfide. Noble gas analyses show that the 10‐day alteration of natural Ningqiang removed 79% of the primordial 36Ar, 68% of the 84Kr, and 60% of the 132Xe, but only 45% of the 4He and 53% of the primordial 20Ne. Calculated elemental ratios of the noble gases removed during the 10‐day alteration are in the range of those of Ar‐rich noble gases. These results indicate that Ar‐rich noble gases are located in materials that are very susceptible to aqueous alteration. In contrast, heavy primordial noble gases remaining in the altered samples are close to Q gas in elemental and isotope compositions. This indicates that phase Q is much more resistant to aqueous alteration than the host phases of Ar‐rich noble gases. In the 20‐day sample, the mineralogical and noble gas signatures are basically similar to those of the 10‐day sample, indicating that the loss of Ar‐rich noble gases was completed within the 10‐day alteration. Our results suggest that almost all of the Ar‐rich noble gases were lost from primitive asteroids during early, low‐temperature aqueous alteration.  相似文献   

6.
Abstract— This work reports on the noble gas inventory of 3 new acapulcoites, 3 brachinites, 2 new eucrites from the Dar al Gani region in Libya, the unique achondrite Dar al Gani (DaG) 896 from the same locality, the new eucrite‐like achondrite Northwest Africa (NWA) 011, and the controversial sample Tafassasset. We determined cosmic ray exposure and gas retention ages, evaluated shielding conditions, and discuss the trapped noble gas component of the specimens. All exposure ages are within the known range of stony meteorites and partly confirm previously established age clusters. Shielding conditions vary, suggesting substantial shielding for all 3 brachinites and Tafassasset. We cannot exclude, however, that the Mg‐rich composition of brachinites simply simulates heavy shielding. Regarding the trapped component, we found Q‐like compositions only for the acapulcoite Thiel Mountains (TIL) 99002. The brachinite Elephant Moraine (EET) 99402 yields a high, subsolar 36Ar/132Xe ratio of ?400 along with a slightly elevated 84Kr/132atio, indicating minor atmospheric contamination. All the other samples, particularly the eucrite DaG 983, are characterized by clearly elevated Ar/Kr/Xe ratios due to significant terrestrial alteration. Tafassasset exhibits noble gas parameters that are different from those of CR chondrites, including a relatively high cosmic ray exposure age, the absence of a solar component, low 132Xe concentrations, a low trapped 36Ar/132Xe ratio of ?30, and a noticeable amount of radiogenic 129Xe. Similar attributes have been observed for some primitive achondrites. These attributes are also consistent with the metamorphic character of the sample. We, therefore, consider Tafassasset's noble gas record to be inconclusive as to its classification (primitive achondrite versus metamorphosed CR chondrite).  相似文献   

7.
Abstract— The L/LL5 chondrite Knyahinya had an approximately spherical shape, and as it experienced a single stage exposure history, it represents a very interesting object to study depth profiles of cosmic-ray-produced nuclide concentrations. Such data are required to improve and to validate model calculations of production rates. We report Ne, Ar, Kr and Xe isotopic abundances in five bulk samples. The adopted procedure of noble gas extraction included two pyrolysis steps at 450 °C and 650 °C, respectively, followed by a combustion step in pure O2 at 650 °C before melting the sample. This procedure allows for the separation of a significant fraction of the trapped Kr and Xe, leading to an enrichment of the cosmic-ray produced component, which is released in the melting step. The isotopic composition of the trapped Xe component measured in the combustion step is found to be identical with the OC-Xe composition (Lavielle and Marti, 1992) and supports the suggestion that ordinary chondrites formed in a homogeneous trapped noble gas reservoir. Cosmic-ray produced Kr and Xe components and depth profiles were measured, including for the first time a 81Kr profile. The calculated exposure age of 39.5 ± 1.0 Ma, based on the 81Kr-Kr method, is found to be in excellent agreement with previous determinations. The concentrations of trapped and fissiogenic noble gas components are clearly lower than those generally observed in type 5 ordinary chondrites and may suggest diffusion losses before a meter-sized object was exposed to the cosmic radiation.  相似文献   

8.
Abstract— Considerable evidence points to a martian origin of the SNC meteorites. Noble gas isotopic compositions have been measured in most SNC meteorites. The 129Xe/132Xe vs. 84Kr/132Xe ratios in Chassigny, most shergottites, and lithology C of EETA 79001 define a linear array. This array is thought to be a mixing line between martian mantle and martian atmosphere. One of the SNC meteorites, Nakhla, contains a leachable component that has an elevated 129Xe/132Xe ratio relative to its 84Kr/132Xe ratio when compared to this approximately linear array. The leachable component probably consists in part of iddingsite, an alteration product produced by interaction of olivine with aqueous fluid at temperatures lower than 150 °C. The elevated Xe isotopic ratio may represent a distinct reservoir in the martian crust or mantle. More plausibly, it is elementally fractionated martian atmosphere. Formation of sediments fractionates the noble gases in the correct direction. The range of sediment/atmosphere fractionation factors is consistent with the elevated 129Xe/132Xe component in Nakhla being contained in iddingsite, a low temperature weathering product. The crystallization age of Nakhla is 1.3 Ga. Its low-shock state suggests that it was ejected from near the surface of Mars. As liquid water is required for the formation of iddingsite, these observations provide further evidence for the near surface existence of aqueous fluids on Mars more recently than 1.3 Ga.  相似文献   

9.
Abstract— We present an isotope study of noble gases in Divnoe, an anomalous meteorite, and also Rb-Sr and K-Ar dating of this meteorite. The relatively young Rb-Sr age obtained (3.39 Ga) seems doubtful and, most probably, results from weathering or contamination. The ancient K-Ar age (4.67+0.20–0.40), together with clear excess of 129Xe, allows the suggestion of very early formation of the Divnoe meteorite. Concentrations and isotope ratios of noble gases in Divnoe are: 17.9 ≤ 3He ≤ 29.0 × 10?8; 20Ne = 6.22 × 10?8; 2.44 ≤ 36Ar ≤ 5.10 × 10?8; 130Xe = 41.3 × 10?12 cm3/g; 0.079 ≤ 3He/4He ≤ 0.193; 20Ne/22Ne = 0.860; 21Ne/22Ne = 0.927; 3.47 ≤ 40Ar/36Ar ≤ 9.47; 2.22 ≤ 36Ar/38Ar ≤ 3.27; 129Xe/132Xe = 1.09. The exposure age calculated from cosmogenic 3He, 21Ne, and 38Ar is 17.9 ± 0.9 Ma. On the basis of the isotope data for the noble gases and O, and abundances of K, Rb, and Sr, an attempt was made to estimate the relationship of Divnoe to other meteorite types. The O-isotope characteristics of Divnoe are clearly distinct from those of ordinary chondrites, acapulcoites/lodranites, and SNC meteorites (Petaev et al., 1994, Clayton, 1993). In plots of 136Xe vs. 129Xe/130Xe, the Divnoe data fall outside of the data fields for carbonaceous and enstatite chondrites. The light noble gas data, especially the 40Ar/38Ar ratio, and the 40Ar, 38Ar, 3He, and 4He contents of Divnoe differ significantly from those of all meteorite types except diogenites. The K, Rb, and Sr abundances in Divnoe are substantially lower than in most other meteorites. In the concentrations of these elements, as well as in the REE pattern, the Divnoe meteorite is similar only to diogenites. Divnoe probably should be treated as a restite remaining after partial melting of the chondritic mantle of a parent asteroid body.  相似文献   

10.
Abstract— Noble gases in two ureilites, Kenna and Allan Hills (ALH) 78019, were measured with two extraction methods: mechanical crushing in a vacuum and heating. Large amounts of noble gases were released by crushing, up to 26.5% of 132Xe from ALH 78019 relative to the bulk concentration. Isotopic ratios of the crush‐released Ne of ALH 78019 resemble those of the trapped Ne components determined for some ureilites or terrestrial atmosphere, while the crush‐released He and Ne from Kenna are mostly cosmogenic. The crush‐released Xe of ALH 78019 and Kenna is similar in isotopic composition to Q gas, which indicates that the crush‐released noble gases are indigenous and not caused by contamination from terrestrial atmosphere. In contrast to the similarities in isotopic composition with the bulk samples, light elements in the crush‐released noble gases are depleted relative to Xe and distinct from those of each bulk sample. This depletion is prominent especially in the 20Ne/132Xe ratio of ALH 78019 and the 36Ar/132Xe ratio of Kenna. The values of measured 3He/21Ne for the gases released by crushing are significantly higher than those for heating‐released gases. This suggests that host phases of the crush‐released gases might be carbonaceous because cosmogenic Ne is produced mainly from elements with a mass number larger than Ne. Based on our optical microscopic observation, tabular‐foliated graphite is the major carbon mineral in ALH 78019, while Kenna contains abundant polycrystalline graphite aggregates and diamonds along with minor foliated graphite. There are many inclusions at the edge and within the interior of olivine grains that are reduced by carbonaceous material. Gaps can be seen at the boundary between carbonaceous material and silicates. Considering these petrologic and noble gas features, we infer that possible host phases of crush‐released noble gases are graphite, inclusions in reduction rims, and gaps between carbonaceous materials and silicates. The elemental ratios of noble gases released by crushing can be explained by fractionation, assuming that the starting noble gas composition is the same as that of amorphous carbon in ALH 78019. The crush‐released noble gases are the minor part of trapped noble gases in ureilites but could be an important clue to the thermal history of the ureilite parent body. Further investigation is needed to identify the host phases of the crush‐released noble gases.  相似文献   

11.
Abstract— Fine material that floats during freeze-thaw disaggregation of the Allende meteorite is greatly enriched in noble gases compared to the bulk meteorite. Not only the elemental concentrations, but also most isotopic ratios of the noble gases in this fraction, strongly suggest that this material is very similar to the gas-rich carbonaceous residue isolated from the bulk meteorite by chemical treatment. The only significant difference in noble gas signature between our separated fraction and the chemical residues is that the 129Xe/132Xe ratio in the former is significantly lower than that in the latter, which suggests readsorption of 129Xe released from the dissolved minerals during the chemical treatment. This is the first time that a gas-rich residue of a meteorite has been separated by a purely physical method alone. We also show that noble gases in phase Q and presolar diamond may be separable physically, although both are closely associated.  相似文献   

12.
Abstract– We have determined the elemental abundances and the isotopic compositions of noble gases in a bulk sample and an HF/HCl residue of the Saratov (L4) chondrite using stepwise heating. The Ar, Kr, and Xe concentrations in the HF/HCl residue are two orders of magnitude higher than those in the bulk sample, while He and Ne concentrations from both are comparable. The residue contains only a portion of the trapped heavy noble gases in Saratov; 40 ± 9% for 36Ar, 58 ± 12% for 84Kr, and 48 ± 10% for 132Xe, respectively. The heavy noble gas elemental pattern in the dissolved fraction is similar to that in the residue but has high release temperatures. Xenon isotopic ratios of the HF/HCl residue indicate that there is no Xe‐HL in Saratov, but Ne isotopic ratios in the HF/HCl residue lie on a straight line connecting the cosmogenic component and a composition between Ne‐Q and Ne‐HL. This implies that the Ne isotopic composition of Q has been changed by incorporating Ne‐HL (Huss et al. 1996) or by being mass fractionated during the thermal metamorphism. However, it is most likely that the Ne‐Q in Saratov is intrinsically different from this component in other meteorites. The evidence of this is a lack of correlation between the isotopic ratio of Ne‐Q and petrologic types of meteorites (Busemann et al. 2000). A neutron capture effect was observed in the Kr isotopes, and this process also affected the 128Xe/132Xe ratio. The 3He and 21Ne exposure ages for the bulk sample are 33 and 35 Ma, respectively.  相似文献   

13.
Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped 20Ne and 36Ar, and the ratio (36Ar/20Ne)t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (36Ar/20Ne)t and trapped 36Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (36Ar/20Ne)t ratio, Ne‐isotopic composition, and excess of 4He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (21Ne/22Ne)c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.  相似文献   

14.
The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of 40Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of 40Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H2 resulting from efficient H2O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in 20Ne and 36Ar from Venus to Earth to Mars; (2) a nearly constant 20Ne/36Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for 36Ar/132Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO2 and N2.  相似文献   

15.
The isotopic composition of the noble gases of the new Martian meteorite, the Dhofar 019 shergottite, found in the desert in the territory of the Sultanate of Oman on January 24, 2001, was investigated. Stepwise thermal annealing with isotopic analysis of each of the noble-gas temperature fractions was employed to determine the component composition. The concentration of the trapped noble gases in the new Martian meteorite Dhofar 019 is relatively high, although it lies within the range of concentrations in known SNC meteorites. A characteristic feature of all the trapped noble gases is the presence of two main components: a low-temperature, probably terrestrial atmospheric, component, trapped during the weathering of the meteorite on Earth, and a high-temperature trapped Martian component. Owing to the different ratios of the quantities of the two components, the trapped neon, argon, krypton, and xenon differ markedly in the kinetics of their release. The isotopic composition of the noble gases varies accordingly. The trapped xenon was found to contain two Martian components. One of them, with typical ratios of 129Xe/132Xe and 132Xe/84Kr, is representative of xenon and krypton of the Martian atmosphere; the other, of gases of the Martian mantle. Variations of the isotopic compositions of helium, neon, and argon (and also, to a lesser extent, of krypton and xenon) during the thermal annealing of the Dhofar 019 meteorite clearly point to a large proportion of cosmogenic as well as trapped components. The concentration of cosmogenic neon and argon in the meteorite is unusually high. This corresponds to a maximum exposure age among other SNC meteorites: 20 million years. Estimates of the potassium–argon age (gas-retention age) yielded the figure of 560 million years, which is within the range of values obtained for SNC meteorites by other authors, who used the rubidium–strontium and the potassium–argon technique.  相似文献   

16.
Abstract— The HF/HCI‐resistant residues of the chondrites CM2 Cold Bokkeveld, CV3 (ox.) Grosnaja, CO3.4 Lancé, CO3.7 Isna, LL3.4 Chainpur, and H3.7 Dimmitt have been measured by closed‐system stepped etching (CSSE) in order to better characterise the noble gases in “phase Q”, a major carrier of primordial noble gases. All isotopic ratios in phase Q of the different meteorites are quite uniform, except for (20Ne/22Ne)Q. As already suggested by precise earlier measurements (Schelhaas et al., 1990; Wieler et al., 1991, 1992), (20Ne/22Ne)Q is the least uniform isotopic ratio of the Q noble gases. The data cluster ～10.1 for Cold Bokkeveld and Lancé and 10.7 for Chainpur, Grosnaja, and Dimmitt, respectively. No correlation of (20Ne/22Ne)Q with the classification or the alteration history of the meteorites has been found. The Ar, Kr, and Xe isotopic ratios for all six samples are identical within their uncertainties and similar to earlier Q determinations as well as to Ar‐Xe in ureilites. Thus, an unknown process probably accounts for the alteration of the originally incorporated Ne‐Q. The noble gas elemental compositions provide evidence that Q consists of at least two carbonaceous carrier phases “Q1” and “Q2” with slightly distinct chemical properties. Ratios (Ar/Xe)Q and (Kr/Xe)Q reflect both thermal metamorphism and aqueous alteration. These parent‐body processes have led to larger depletions of Ar and Kr relative to Xe. In contrast, meteorites that suffered severe aqueous alteration, such as the CM chondrites, do not show depletions of He and Ne relative to Ar but rather the highest (He/Ar)Q and (Ne/Ar)Q ratios. This suggests that Q1 is less susceptible to aqueous alteration than Q2. Both subphases may well have incorporated noble gases from the same reservoir, as indicated by the nearly constant, though very large, depletion of the lighter noble gases relative to solar abundances. However, the elemental ratios show that Q1 and Q2 must have acquired (or lost) noble gases in slightly different element proportions. Cold Bokkeveld suggests that Q1 may be related to presolar graphite. Phases Q1 and Q2 might be related to the subphases that have been suggested by Gros and Anders (1977). The distribution of the 20Ne/22Ne ratios cannot be attributed to the carriers Q1 and Q2. The residues of Chainpur and Cold Bokkeveld contain significant amounts of Ne‐E(L), and the data confirm the suggestion of Huss (1997) that the 22Ne‐E(L) content, and thus the presolar graphite abundances, are correlated with the metamorphic history of the meteorites.  相似文献   

17.
Analysis of abundance patterns of rare gases Ne22, Ar36, Kr84 and Xe130 on Earth and in ordinary and carbonaceous chondrites is presented. A mechanism of chemical adsorption of rare gases at the planetesimal stage during their accretion is proposed to generate the abundance pattern of the heavy rare gases on the Earth. The calculated values for Xe and Kr agree well with the observed values whereas for Ar, the agreement is poor.  相似文献   

18.
Abstract— The noble gases He, Ne, Ar, Kr, and Xe were measured in 27 individual Antarctic micrometeorites (AMMs) in the size range 60 to 250 μm that were collected at the Dome Fuji Station. Eleven of the AMMs were collected in 1996 (F96 series) and 16 were collected in 1997 (F97 series). One of the F97 AMMs is a totally melted spherule, whereas all other particles are irregular in shape. Noble gases were extracted using a Nd‐YAG continuous wave laser with an output power of 2.5‐3.5 W for ?5 min. Most particles released measurable amounts of noble gases. 3He/4He ratios are determined for 26 AMMs ((0.85‐9.65) × 10?4). Solar energetic particles (SEP) are the dominant source of helium in most AMMs rather than solar wind (SW) and cosmogenic He. Three samples had higher 3He/4He ratios compared to that of SW, showing the presence of spallogenic 3He. The Ne isotopic composition of most AMMs resembled that of SEP as in the case of helium. Spallogenic 21Ne was detected in three samples, two of which had extremely long cosmic‐ray exposure ages (> 100 Ma), calculated by assuming solar cosmic‐ray (SCR) + galactic cosmic‐ray (GCR) production. These two particles may have come to Earth directly from the Kuiper Belt. Most AMMs had negligible amounts of cosmogenic 21 Ne and exposure ages of <1 Ma. 40Ar/36Ar ratios for all particles (3.9–289) were lower than that of the terrestrial atmosphere (296), indicating an extraterrestrial origin of part of the Ar with a very low 40Ar/36Ar ratio plus some atmospheric contamination. Indeed, 40Ar/36Ar ratios for the AMMs are higher than SW, SEP, and Q‐Ar values, which is explained by the presence of atmospheric 40Ar. The average 38Ar/36Ar ratio of 24 AMMs (0.194) is slightly higher than the value of atmospheric or Q‐Ar, suggesting the presence of SEP‐Ar which has a relatively high 38Ar/36Ar ratio. According to the elemental compositions of the heavy noble gases, Dome Fuji AMMs can be classified into three groups: chondritic (eight particles), air‐affected (nine particles), and solar‐affected (eight particles). The eight AMMs classified as chondritic preserve the heavy noble gas composition of primordial trapped component due to lack of atmospheric adsorption and solar implantation. The average of 129Xe/132Xe ratio for the 16 AMMs not affected by atmospheric contamination (1.05) corresponds to the values in matrices of carbonaceous chondrites (?1.04). One AMM, F96DK038, has high 129Xe/132Xe in excess of this ratio. Our results imply that most Dome Fuji AMMs originally had chondritic heavy noble gas compositions, and carbonaceous chondrite‐like objects are appropriate candidate sources for most AMMs.  相似文献   

19.
Abstract— Elemental and isotopic compositions of the noble gases have been determined in six North American tektites (4 bediasites and 2 georgiaites) and one Ivory Coast tektite. Radiogenically produced 4He may explain the large 4He/36Ar ratios measured relative to air, despite significant diffusive losses. The Ne isotopic composition is enriched in 20Ne consistent with a single stage mass fractionation process. The enormous 20Ne/36Ar enrichments observed in all tektite samples, similar to those reported from other tektites and impact glasses, are attributed to atmospheric diffusion into the samples following solidification. The North American tektites show a systematic increase in 84Kr/36Ar and 132Xe/36Ar relative to air, with enrichments greater than those determined for any other tektite group or terrestrial samples other than shales. These enrichments are inconsistent with existing models of dissolving Kr and Xe in tektite glass without elemental fractionation at atmospheric pressures equivalent to ∼40 km altitude. The Kr and Xe isotopic compositions are indistinguishable from atmospheric within experimental uncertainty.  相似文献   

20.
Abstract— Iodine-xenon ages (based on 15.7 Ma 129I) of meteoritic samples are highly susceptible to secondary alteration processes, so they have the potential to determine both the timing, and in some cases the location, of those secondary processes. Iodine-xenon studies can determine the location in two cases. First, if the length of time required is greater than the lifetime of the nebula, then the process must have occurred on a parent body. Ages from sodalite in Allende, dark inclusions in Efremovka (CV3), and some samples from CM chondrites all suggest durations of several million years, in some cases marginally longer than the predicted duration of the nebula. Second, in some cases the evolution of the 129Xe/132Xe ratio can be used to determine the I/Xe elemental ratio of the reservoir in which the evolution occurred. For chondrules from the unequilibrated ordinary chondrites Chainpur and Tieschitz, the isotopic evolution is quantitatively consistent with evolution in a chondritic (parent body), rather than nebular, reservoir.  相似文献   

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