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1.
Soil magnetometry was used for detailed mapping of immission load over the territory of the Giant Mountains National Park. This project is a continuation of our previous study, which suggested that low-field magnetic susceptibility of topsoils in this region is controlled by atmospherically deposited anthropogenic ferromagnetic particles. In the present study, we have compiled a map of topsoil magnetic susceptibility on the basis of measurements on more than 460 sites. Elevated values of magnetic susceptibility can be attributed to local sources of pollution, located within and at the margins of the Park. We have identified a group of heavy metals of anthropogenic origin, present in the topsoils, and found a positive correlation between the concentration of Pb and magnetic susceptibility. Our results prove that magnetic mapping is a sensitive, fast and robust method, which can be advantageously applied to regions with relatively low degree of pollution, such as the Giant Mountains National Park.  相似文献   

2.
Measurements of magnetic susceptibility of soils, reflecting magnetic enhancement of topsoils due to atmospherically deposited magnetic particles of industrial origin, are used recently in studies dealing with outlining polluted areas, as well as with approximate determination of soil contamination with heavy metals. One of the natural limitations of this method is magnetic enhancement of soils caused by weathering magnetically rich parent rock material. In this study we compare magnetic properties of soils from regions with different geological and environmental settings. Four areas in the Czech Republic and Austria were investigated, representing both magnetically rich and poor geology, as well as point-like and diffuse pollution sources. Topsoil and subsoil samples were investigated and the effect of geology and pollution was examined. Magnetic data including mass and volume magnetic susceptibility, frequency-dependent susceptibility, and main magnetic characteristics such as coercivity (Hc and Hcr) and magnetization (Ms and Mrs) parameters are compared with heavy metal contents. The aim of the paper is to assess the applicability of soil magnetometry under different geological-environmental conditions in terms of magnetic discrimination of dominant lithogenic/anthropogenic contributions to soil magnetic signature. Our results suggest that lithology represents the primary effect on soil magnetic properties. However, in case of significant atmospheric deposition of anthropogenic particles, this contribution can be clearly recognized, independent of the type of pollution source (point-like or diffuse), and discriminated from the lithogenic one. Different soil types apparently play no role. Possible effects of climate were not investigated in this study.  相似文献   

3.
Magnetic measurements of soils are an effective research tool in assessing soil erosion. This approach is based on detecting layers showing different magnetic properties in vertical soil profiles and lateral catenas. The objective of this research is to compile data on magnetic susceptibility (MS) of soils in Eastern Ukraine to assess the soil erosion rates. The chernozems of Tcherkascy Tishki (Kharkov Region, Ukraine) have undergone a field crop rotation without proper soil conservation technologies being applied. We conducted an intrinsic element grouping of the magnetic susceptibility values and demonstrated that they can be used as MS cartograms in soil erosion mapping. The study showed a strong correlation between the MS values and the erosion index. MS and the erosion index were found to correlate with the humus content. Magnetic mineralogical analyses suggest the presence of highly magnetic minerals (magnetite and maghemite) as well as weakly magnetic goethite, ferrihydrite, and hematite. Stable pseudosingle-domain (PSD), single-domain (SD), and superparamagnetic (SP) grains of pedogenic origin dominate in the studied chernozems. Being an effective, quick and low cost alternative, magnetic methods can be successfully used in the soil erosion investigations.  相似文献   

4.
杭州城区土壤的磁性与磁性矿物学及其环境意义   总被引：18，自引：0，他引：18       下载免费PDF全文
对杭州城区四个不同功能区块土壤进行了系统的环境磁学测定,结果表明城市土壤的磁化率平均值为128×10-8m3·kg-1,频率磁化率平均值3.6%(样品数=182),城市土壤呈现明显的磁性增强. 城市土壤的磁化率与频率磁化率呈极显著指数负相关,表明城市土壤磁性增强明显区别于自然成土过程引起的以超顺磁性(SP)颗粒为主的表土磁性增强机理. 统计分析表明,城市土壤磁化率与软剩磁和饱和等温剩磁(SIRM)呈显著直线正相关,说明亚铁磁性矿物是城市土壤剩余磁性的主要载体. 综合等温剩磁获得曲线、热磁曲线、磁滞回线等岩石磁学测定和SEM/EDX分析,城市土壤的磁性矿物以磁铁矿和赤铁矿为主,磁性矿物以假单畴-多畴（PSD-MD）颗粒存在,粒度明显大于成土过程形成的磁性颗粒,这些磁性颗粒主要来自燃料燃烧、汽车尾气等环境污染物. 因此,城市土壤磁测可作为城市土壤污染监测、污染空间分布和污染物来源判断的新手段.  相似文献   

5.
Magnetic susceptibility is a non‐conventional way that can be used for evaluating proxy soil heavy metals pollution. The paper monitors available heavy metals (Cu, Fe, Zn, and Mn) present in cultivated soils around iron–steel plant by soil magnetic susceptibility. Our study was located in an area with high pollution with small grid density of 250 m in China. Results showed that low field magnetic susceptibility was significantly correlated with available Cu, Zn, and Mn. No clear association exists between magnetic susceptibility and available Fe, soil organic matter, pH. Frequency dependent susceptibility >5% suggests the possible presence of super‐paramagnetic particles, fly ashes produced during coal combustion.  相似文献   

6.
This paper reports on magnetic and magnetomineralogical studies of soils influenced by ironworks activity. Researches were conducted in five areas, of which Ostrowiec Świętokrzyski ironworks area is described in detail. A map of magnetic susceptibility was created based on field measurements and samples taken from soil profile were analyzed in laboratory. Measurements of magnetic susceptibility in two frequency ranges, anhysteretic remanent magnetization, isothermal remanent magnetization thermomagnetic and geochemical analysis were carried out. SEM was used to identify ferromagnetic fractions. As a result the horizontal and vertical extent of heavy metals pollution was established.  相似文献   

7.
The relationship between the anisotropy of frequency-dependent magnetic susceptibility (fdAMS) and the anisotropy of out-of-phase magnetic susceptibility (opAMS) was investigated theoretically and also empirically at three loess/palaoesol profiles in Prague and in Southern Moravia. The data treatment was made in terms of mean susceptibility, degree of AMS, and orientations of principal susceptibilities. It has shown that the fdAMS and opAMS can serve as indicators of the preferred orientations of ultrafine magnetic particles that are on transition between superparamagnetic and stable single domain states in rocks, soils and environmental materials. In loess/palaeosol sequences, the fdAMS and opAMS correlate reasonably, because they are due to magnetic particles of similar grain sizes. The fdAMS and opAMS can be both coaxial with standard AMS (i.e. anisotropy of in-phase susceptibility - ipAMS) or non-coaxial indicating slightly different orientations of viscous magnetic particles.  相似文献   

8.
Magnetic properties of hydrocarbon (HC) containing soils and sediments from two sites (Site A and B) of the former oil-field H?nigsen were analyzed in order to determine whether magnetic methods can be employed to delineate HC contamination of soils and sediments. Magnetic parameters such as magnetic susceptibility and induced isothermal remanent magnetizations, as well as soil and sediment properties such as pH, iron content and water content, HC content and most probable number counts of iron-metabolizing microorganisms were determined. The magnetic concentration-dependent parameters for HC contaminated samples were 25 times higher in soils from Site A than in sediment samples from Site B. However, at Site B the magnetic susceptibility was still four times higher in comparison to lithologically similar non-contaminated sediment samples from a third Site C. Newly formed magnetite containing mainly single domain particles was responsible for the magnetic enhancement, whereas superparamagnetic grains represented only a minor component. Site A had an acidic pH compared to neutral pH at Site B, and a higher crystalline and bioavailable total iron content. Nevertheless, Site B samples contained significant numbers of both iron(II)-oxidizing and iron(III)-reducing microorganisms indicating that microbial iron cycling might have taken place at this site and potentially played a role for iron mineral transformation, including magnetite (trans)formation. The content of total non-polar hydrocarbons (TNPH) at Site A was one order of magnitude higher than at Site B. Only at Site A magnetic susceptibility correlated well with TNPH. Our results demonstrate that HC contaminated samples had an enhanced magnetite content compared to non-contaminated soils and sediments. Therefore, magnetic methods may provide a quick and cost-effective way to assess HC contamination in soils and sediments. However, more field sites and laboratory investigations are needed to reveal the complex nature of the processes involved.  相似文献   

9.
粉煤灰经工厂废气排放进入大气,对人类健康和生态系统都造成了无法弥补的破坏.本文选取具有高空间分辨率优势的树叶作为收集粉煤灰的载体,对临汾市大气中可吸入颗粒物进行磁学参数和重金属含量监测.结果表明,磁化率最大值出现在工厂污染源附近,磁化率空间分布呈现随污染源距离增加而降低的趋势.工业区收集到的磁性颗粒以低矫顽力、粗粒度的磁铁矿为主.夏季磁性矿物来源单一,主要为人为影响.冬季大气中悬浮的磁性颗粒有部分来自于西北风/北风的自然尘降.同一采样点磁化率随时间变化特征表明,树叶的磁学性质可以灵敏和有效地反映较短时期内大气污染的现状.统计分析表明磁化率和重金属元素(铁,铬,镍,铜,铅,钴)之间存在显著相关性.污染负荷指数用于评估研究区域内重金属各元素综合污染的程度.结果显示,在废弃的旧工业区附近无大气污染指示,但在运营中的工厂集中的地区,大气均受到严重污染.污染负荷指数与表征磁性矿物含量的磁化率呈相关性(r2=0.66),因此树叶的磁性参数可以作为大气重金属污染的替代指标.  相似文献   

10.
This study was conducted to determine the vertical and horizontal distribution of selected metals and magnetic susceptibility (χlf) in an industrial site located in Isfahan province, central Iran. For this purpose, we used a grid sampling methodology and excavated 202 profiles. Soil samples were then collected from 0–30, 60–90, and 120–150 cm depths. The mass magnetic susceptibility (χ) of the soil samples was measured at both low and high frequencies (χlf and χhf) using the Bartington MS2 dual frequency sensor; and χfd was also calculated. Soil samples were also analyzed for iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), copper (Cu), nickel (Ni), chromium (Cr) and cobalt (Co) concentrations. The results showed that there were positive significant correlations among selected metals including Zn, Pb, Fe and Mn, which were mainly added through coal fly ash from an iron smelting factory at the studied site, while the concentration of Ni, Cr and Co was mainly controlled by the parent material of the soils. The trends in results at the site of study were similar in vertical and horizontal distribution for the industrial originated metals as judged by pollution load index (PLI) using χlf. The results of SEM/EDX also confirmed the presence of spheroid of magnetic particles in the surface soil samples taken in close proximity of the factory. Based on the results using the contamination factors (CF) determined for selected metals, the following order was observed: Pb > Zn > Mn > Fe > Cu > Ni ≥ Co > Cr. The results also suggested that magnetic methods could be used to estimate the metal contamination from anthropogenic sources in industrial soils.  相似文献   

11.
In order to investigate the possibility of using low-frequency electromagnetic waves to detect and monitor oil contamination of soils, a series of laboratory measurements were performed. A new measurement system to monitor the resistivities of soil and sand samples while samples are being contaminated by diesel oil is presented. The frequency used in measurements is 100 kHz. Since the measurement system is composed of coil-type transmitters and receivers, there is no need for electrodes to be in contact with samples. The contamination process is simulated using diesel oil dripping on top of soil and sand samples. The conductivity distributions in samples along the sample length are recorded as a function of time. Water-wet sand and soil samples were measured during diesel oil contamination. The measured data show that the conductivities of soil and sand samples change during the contamination process. The change in resistivity for measured samples before and after diesel oil contamination is in the range of 20% to 50%, giving a reflection coefficient change in the low-frequency limit of 4.7% to 7%. This amount of change in the reflection coefficient makes it very challenging to detect and monitor oil contamination based on EM reflection from the contaminants. The results suggest that EM methods based on propagation and induction, such as tomography and borehole induction, could be used for this purpose.  相似文献   

12.
The mineral magnetic properties of deposited dusts collected along a broadly north‐to‐south transect across Niger have been investigated on both a bulk and particle size‐specific basis. Dusts display a general north‐to‐south gradient in fine‐grained ferrimagnetic mineral (magnetite/maghemite) concentrations, with samples south of the Sahara/Sahel transition (south of ~15·5o N) generally containing greater concentrations than dusts from further north where the climate is much drier. This distinction is seen especially clearly in the clay (< 2 µm) fraction, which harbours the products of weathering and pedogenesis. This gradient in ferrimagnetic mineral concentrations broadly parallels that previously reported for surface soils/sands across a similar latitudinal range. We suggest that the regional distinction in both dust and surface soil/sand magnetic properties can be related to differences in weathering regime between the arid Saharan parts of the transect and the Sahel sites where higher rainfall has permitted stronger weathering and pedogenesis. Given that the weathering‐related magnetic signatures in the clays dominate the magnetic properties of the < 16 µm fractions in these samples, and that this particle size component is most likely to be involved in long‐range transport, magnetic measurements hold out the potential of discriminating Sahara and Sahel dusts deposited in remote areas. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

13.
The use of magnetic susceptibility as a proxy for the relative degree of industrial pollution of soils and sediments is only qualitative and complications arise when unmixing the contributions from different sources. Detailed characterization of anthropogenic magnetic phases is needed in order to discriminate the input from different sources. The present study investigates magnetic fractions from fly ashes from different thermoelectric power plants and lagooned ash from metal works in Bulgaria, to further our knowledge of potential sources. Thermomagnetic analysis of saturation magnetization (Ms) and magnetic susceptibility (K) revealed a low-substituted magnetite-like phase in power-plant fly ashes and magnetite/maghemite phases in lagooned ash. Magnetic hysteresis measurements on single spherules from the wastes are combined with subsequent SEM/EDX examination of the same grains, allowing for the grain size dependence of the hysteresis parameters to be directly obtained for the studied anthropogenic phases. The results suggest that the structure-sensitive magnetic parameters for the lagooned ash show stronger size dependence compared to the published data for synthetic crushed magnetites, which is due to the complex internal structure and stress level in the anthropogenic phases formed under fast cooling conditions. Moreover, the Day plot for the studied single grains shows the presence of different correlation lines for fly ashes and the lagooned ash, i.e. it discriminates between the sources.  相似文献   

14.
This paper focuses on the study of the correlation between magnetic parameters with the level of contamination by heavy metals in urban soils. We report a magnetic investigation of urban soil samples from Merida, state of Yucatan, Southern Mexico. It appears that most of our samples contain ferrimagnetic minerals as the magnetic carriers, probably coming from the titanomagnetites/titanomaghemites series. This is inferred by the acquisition of isothermal remanent magnetization, which shows that most of samples are almost completely saturated at about 200 mT. The S−200 value (factor characterizing stability of remanent magnetization) is between 0.8 and 1.0, characteristic of ferrimagnetic minerals. The susceptibility vs. temperature measurements also point to some titanomaghemites and titanomagnetites as probable responsible for magnetization. On the other hand, measurements of magnetic susceptibility at high and low frequencies helped us to determine the high content of superparamagnetic grains in the majority of the samples, although not all of these showed high values of magnetic susceptibility. We found that the most contaminated samples by Pb and Zn showed the higher saturation isothermal remanent magnetization values, whereas the higher values in magnetic susceptibility correspond to samples contaminated by Cr. Finally, we noted that a high level in Sr decreases the magnetic susceptibility.  相似文献   

15.
Magnetic properties and heavy-metal concentrations of vibrocore samples were found to be potential indicators of shipping contamination in seabed sediments in Hong Kong Harbour. Geochemical results of 74 vibrocores located off Penny's Bay on Lantau Island revealed an enrichment of heavy metals in the upper 1-2 m of the cores within the eastern part of the study site. Whole-core magnetic susceptibility measurements also showed a greater concentration of magnetic particles in the surficial layer of these cores. A significant correlation exists between the magnetic susceptibility and the concentrations of Pb, Zn and Cu, as well as the Tomlinson pollution load index (PLI). The proximity of these cores to a major navigation fairway and an anchorage site suggests probable contamination of the surficial seabed sediments by shipping-related wastes. A study of the magnetic properties of one of the cores, VT60, revealed a difference in the magnetic properties between the contaminated and the uncontaminated sediments. Samples from the contaminated zone exhibited relatively stronger magnetic remanence and susceptibility. The two groups of samples also formed distinct trends on the hysteresis ratios plot. A level of unusually high magnetic susceptibility within the contaminated zone was attributable to the presence of strongly magnetized granules, which were probably refuse from shipping-related activities. Geochemical and magnetic results were also conducted on samples of different size-fractions from this core. The < 63 microns fraction was found to contain a relatively higher magnetic susceptibility and greater heavy-metal content.  相似文献   

16.
In this work, we investigate the correlation between some magnetic parameters and the level of contamination by heavy metals in urban soils from Morelia city, western Mexico. The magnetic study was carried out on 98 urban soils samples belonging to distinct land uses. Most of analyzed samples contain ferrimagnetic minerals as the responsible for magnetization, most probably corresponding to the titanomagnetites/ titanomaghemites solid solutions. This is inferred from the susceptibility vs. temperature measurements and the isothermal remanent magnetization (IRM) experiments. These measurements also indicate that most of samples are almost completely saturated before 300 mT. Additionally, the S-200 values (S-200 = IRM-200/ SIRM, where IRM-200= Back-field of 200 mT after magnetic saturation) are between 0.7 and 1.0, characteristic of low coercivity magnetic minerals. The averaged saturation isothermal remanent magnetization (SIRM) curves can be used as an indicator of pollution level, as these curves show different saturation values according to the level of contamination by heavy metals: Cu, Ni, Cr and Sr. These associations of (titano)magnetite with heavy metals were observed by Scanning Electron Microscope revealing some complex aggregates rather than commonly detected spherules.  相似文献   

17.
在沙漠沉积环境中,成土作用对磁化率的贡献较小,往往被原生磁信号掩盖,因此分离两种磁组分对气候和粉尘代用指标的提取至关重要.本研究选取位于毛乌素沙地东缘的锦界风沙沉积剖面为研究对象,利用多变量一元线性回归中的"平均值概念"进行磁化率的原生碎屑组分0和次生成土组分Xpedo的分离,并探讨磁学参数所承载的气候和环境意义.结果显示,磁学比值参数(如Xpedo/X0、Xfd/HIRM、Xfd%和XARM/SIRM)彼此之间存在显著线性或指数/对数相关关系,它们对成土强度指示明确,可以在一定程度上减小或避免磁性矿物背景值差异所产生的误差,与磁化率相比更适宜用于该区的古降水量重建.HIRM主要由碎屑赤铁矿含量控制,HIRM与X0存在明显正相关关系,表明碎屑赤铁矿随原生磁性矿物总体含量的增加(减少)而增加(减少),在粉尘成因磁性矿物中所占比例大致稳定,从而HIRM可以指示源区粉尘通量的变化.锦界剖面的原生和次生磁性矿物浓度均明显低于黄土高原黄土,不同地层X0和Xpedo在磁化率中所占的比例存在较大差异,因此磁化率的环境意义比较复杂,在使用其恢复古气候古环境时需慎重.  相似文献   

18.
末次冰期时,在雅鲁藏布大峡谷入口处发育了一个古冰川堰塞湖,称为格嘎古堰塞湖.该堰塞湖是认识冰川阻江地貌效应的重要地质证据.古冰川堰塞湖可能会发生多次溃决洪水,通过堰塞湖沉积的分析可以获取堰塞期间的水文事件的信息.本文通过对古堰塞湖沉积39个样品多种磁学参数的详细分析发现,湖相沉积中的砂层低频磁化率（Xlf）为291×10-8m3/kg,泥质沉积的Xlf仅为42×10-8m3/kg;而非磁滞剩磁磁化率（XARM）和饱和等温剩磁（SIRM）的差别则较小.进一步的X-T、Loop和IRM研究以及XARM/Xlf表明,砂层中包含较多的粗颗粒磁铁矿是Xlf较高的主要原因,说明砂层中的磁性矿物没有经过风化破坏,应为近源沉积,并且快速埋藏,指示了溃决事件.本文的结果表明,利用岩石磁学性质以检测古堰塞湖溃决事件是一种可行的新方法.  相似文献   

19.
Coal combustion processes lead to release of gases and particulate matter (PM) into the atmosphere that are often harmful to human health. These airborne pollutants seem to be dispersed and deposited in soils mainly according to the prevailing atmospheric conditions. Several trace elements can be found attached to PM as well as Fe-rich magnetic particles that can produce magnetic enhancement in the uppermost soil horizons. In the present work, we use a simple Gaussian Dispersion Model (GDM) for modelling the distribution of fine PM emission coming from a small coal (coke) burning factory in order to evaluate the relationship between such modelled data (PM distribution) and measured data (soil magnetic properties and trace metal contents). Our results show a strong spatial variation of concentration-dependent magnetic parameters based on a uniform magnetomineralogy in the overall study area. In addition, these results were analysed using multivariate statistics for 13 magnetic and chemical variables and the GDM results for two different atmospheric stability classes, and hence the in-situ magnetic susceptibility, anhysteretic and saturation remanent magnetization showed positive and statistically significant correlation with the GDM results (R = 0.70). Therefore, these results demonstrate the usefulness of magnetic properties in monitoring the PM distribution in soils or other environmental PM collectors.  相似文献   

20.
Human health and environmental problems related to particulate matter emission from vehicles has become a topic of research interest in recent years. These airborne particles can not only be directly inhaled, but are also present as suspended and deposited particles on paved areas and roadside soils. Here we report on magnetic studies, scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS) and chemical analyses of vehicle-derived particles collected from both primary sources and as deposited particles on roads and soils. Preliminary results, recently published by the authors, have revealed that the magnetic signal of such particles is controlled by a magnetite-like phase with magnetic grain size ranging between 0.1 μm and 5 μm. An enrichment of some trace elements: Ba, Cr, Cu, Zn and Pb was also found. In this study we focus on SEM and EDS complementary studies of magnetic extracts. SEM observations showed small individual particles or spherulites, small aggregates in the form of chains or clusters, large aggregates of spherules, flake-like bodies, fibre-like particles, sheet-like particles, irregular debris and large particle agglomerates, i.e. a wide variety of shapes. Grain size distribution is also in agreement with magnetic grain size estimations. Additionally the following elements: C, O, Na, Mg, Al, Si, S, K, Ca, V, Ba, Ti, Cr, Mn, Fe, Cu, Zn and Pb were detected by EDS analysis.  相似文献   

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